NZ534085A - Composite material for light-, gas- and liquid-tight heat-sealing packages with base material of paper or cardboard, and metal layer and sealing layer - Google Patents

Abstract

A composite material is disclosed, made from paper or cardboard as support material (1) with a plastic coating, in particular for light-, gas- and liquid-tight heat-sealing packagings, whereby the plastic coatings each have external sealing layers (3) and a barrier layer (2) made from metal is arranged between the support material layer (1) and a sealing layer (3). The invention also relates to a method for production thereof. According to the invention, the support material layer (1) is protected in the composite material such that a packaging, made therefrom with the product therein, may be sterilised in an autoclave or similar and said composite material may be simply and economically produced, whereby a further barrier layer (2) is provided on the other side of the support material layer (1).

Description

534085 COMPOSITE MATERIAL FOR LIGHT-, GAS- AND LIQUID-TIGHT, The invention relates to a composite material made of paper or cardboard as a base material with a plastic coating, in particular for light-, gas- and liquid-tight heat-sealable packages, whereby the plastic coating in each case has outer sealing layers and a barrier layer of metal is present between the base material layer and each sealing layer and whereby as sealing layer a thermoplastic polymer is used.

Heat-sealable composite materials for the production of packages, in particular beverage packages, are known in the most varied designs. Generally, paper or cardboard serve as the base material; a lamination consisting of different layers ensures the tightness required for the particular intended use and thus the shelf life of the particular filled product. The outer sealing layers consist of a suitable thermoplastic polymer.

Numerous products to be filled, such as milk and juice for example, retain their quality under aseptic conditions only if they are also adequately protected against light, aromas and oxygen. To achieve this, a composite of cardboard coated with polyethylene is preferably used, whereby a layer of aluminium foil as a gas and aroma barrier on the inside (relative to the subsequent package) is laminated with the sealing layer onto the cardboard base material.

HEAT-SEALABLE PACKAGES INTELLECTUAL PROPERTY OFFICE OF N.Z.

TH/bs 01134DWO - 1 AUS 2006 ItBOBIVKD Such packages have been tried and tested in practice for holding perishable goods, such as for example H-milk and fruit juices. The packaged product has already been sterilised by suitable steps before the aseptic filling.

The composite structure existing according to the prior art, however, has only one protecting barrier layer made of material impermeable to water and water vapour protecting the cardboard. Normally, this layer is arranged on the product side and protects the base material against moisture from the product. The polymer layer lying on the outside on the base material is used solely for sealability, printability and as protection against "normal" environmental influences.

For this reason, it is not possible to fill such products in a first step - in the same way as preserves - and to sterilise the product subsequently by heating in an autoclave. The autoclave water (when the barrier layer is arranged on the inside) or the water of the filled product (when the barrier layer is arranged on the outside) penetrates through the less well protected side of the cardboard composite during the autoclave process into the cardboard and thus impairs the strength/stiffness of the composite material, i.e. the package.

In order to minimise this problem, use has to be made of thick and expensive polymer layers, paint and lacquer coats, which guarantee a certain minimal water barrier. A relatively thick and chemically specially treated INTELLECTUAL PROPERTY OFFICE OF N.Z. - 1 AUG 2006 fttOIIVED —as— cardboard has to be used, which is respectively expensive.

In the document US-A-4 355 756 a package for receiving foodstuffs is disclosed, wherein the coating on the outside occurs using a synthetic resin and wherein the two outer layers are made of such resin.

Despite the increased outlay, the resistance capacity of such cardboard composites in the autoclave process is very limited, in particular in respect of the permitted maximum sterilisation temperature. The effect of this is that the sterilisation times have to be relatively long in order to guarantee an adequate germ destruction rate.

Long autoclave cycle times, however, reduce the autoclave capacity and increase costs. Furthermore, long sterilisation times lead to a lower quality, i.e. spoil the taste, in the case of many products/foodstuffs to be packaged.

The lower resistance of the known composite material during the autoclavin.g process means in some cases that the water vapour/gas mixture is shifted in terms of concentration composition towards a "drier" mixture during the autoclaving process and particularly towards the end of the process. Due to the poorer heat transport, a further undesired lengthening of the autoclaving process is thus obtained.

The usage of polyethylen, polyamide and further thermoplastic foils is described with an other composite material known per se, wherein the specific properties of INTELLECTUAL PROPERTY OFFICE OF N.Z. - 1 AUS 2006 received the composite material are dependent on the properties of the thermoplastics used.

Proceeding from this, it is the object of the invention to make available a composite material of the type mentioned at the outset and described in greater detail above, with which the base material layer is protected in such a way that a package produced therefrom can be sterilised with the product contained therein in an autoclave or suchlike. Here, an optimal protection of the product as well as of the composite material itself should be achieved. It is further desirable for the composite material to be able to be produced simply and cost-effectively. The above objects are to be read disjunctively with the object of at least providing the public with a useful alternative.

This problem is solved by the fact that the thermoplastic polymer is a compound of polypropylene (PP) , polyethylene terephthalate (PET), polyethylene (PE), liquid crystalline polymers (LPC) , ethylene/vinyl alcohol (EVOH) and or polyamide (PA).

Because of the thermoplastic polymer used according to the invention is a compound of multiple polymers the specific problems appearing duing sterilisation of certain products can much better and more selective dwelled on. According to the products contained in the packages of the composite material according to the invention sealing layers can be used which allow an optimal protection of the product as well as the composite material itself during sterilisation procedure.

INTELLECTUAL PROPERTY OFFICE OF N.Z. -1 AUG 2006 received This also enables higher sterilisation temperatures in the autoclave. This results in a shortening of the sterilisation time, an improvement in the taste, and an increase in the quality of the packaged product. Due to the improved protection of the cardboard, thinner and less special types of cardboard can be used.

The barrier layers of metal applied on both sides of the cardboard are ^absolute' barrier layers and, moreover, also have the advantage that the holes and defects on and in a barrier layer occasionally occurring in the processing operation, in particular during creasing and folding, and during transport etc., are not able to have such an unfavourable effect on the shelf life of the packaged product due to the intact second layer lying in front or to the rear thereof. The doubled metal layer thus leads to increased assurance of product quality in respect of, for example, the shelf life.

According to a further teaching of the invention, at least one connecting layer is arranged between the base material layer and the barrier layer in each case. Such a layer also designated as a bonding layer provides for better contact between the base material and the barrier layers.

A further development of the invention makes provision such that at least one further connecting layer is arranged in each case between the barrier layer and the outer sealing layer. The adhesion between the barrier INTELLECTUAL PROPERTY OFFICE OF N.Z. - 1 AUG 2006 RBCIIVIO layer and in the respective outer sealing layer is also improved by this measure.

In a further development of the invention, the oxygen barrier layer is made of Al-foil. A bonding agent based on a polymer or an adhesive can be used as the connecting layer.

The sealing layer consists, according to a further teaching of the invention, of a thermoplastic polymer, whereby the thermoplastic polymer can be polypropylene (PP), polyethylene terephthalate (PET), polyethylene (PE), of liquid crystalline polymers (LCP), ethylene/vinyl alcohol (EVOH) or polyamide (PA).

In a further development of the invention, the outer sealing layers have a layer thickness of 10 to 40 g/m2. The outer (relative to the subsequent composite package) sealing layer preferably has a layer thickness of 10 to 20 g/m2 and the inner (relative to the subsequent package) sealing layer a layer thickness of 20 to 35 g/m2.

According to another preferred development of the invention, an aluminium foil with a layer thickness of 5 to 10 |jm, preferably 6 to 8 jxm, is provided as the barrier layer.

A further development of the invention makes provision such that the connecting layer (bonding layer) has a layer thickness of 4 to 20 g/m2, preferably 5 to 10 g/m2. It is particularly expedient here for the connecting layer present between the base material layer and the INTELLECTUAL PROPERTY OFFICE OF N.Z. •1 AU3 2006 RlOtlVlB barrier layers to be thicker than the connecting layer between the barrier layers and the outer sealing layers.

In a further development of the invention, the composite material according to the invention can be produced in a single work cycle in the co-extrusion process.

The invention will be explained below in greater detail with the aid of a drawing representing solely preferred examples of embodiment. The drawing shows the following: Fig. 1 a first example of embodiment of a composite material according to the invention, Fig. 2 a second example of embodiment of a composite material according to the invention, Fig. 3 a further example of embodiment of a composite material according to the invention.

In the figures, examples of composite materials according to the invention are represented schematically in cross-section and not true to scale.

Fig. 1 shows, as the base material, a cardboard layer 1, which is surrounded by two barrier layers 2 to protect the cardboard against the surface attack by water during the autoclaving process. Al-foil or layers of SiOx, LCP (liquid crystalline polymers), etc. can be used as barrier layers 2.

INTELLECTUAL PROPERTY OFFICE OF N.Z. - 1 AUG 2006 rftcbivftd On the outside, the composite is provided with two sealing layers 3, which are made of a thermoplastic polymer, whereby the thermoplastic polymer can be a compound of polypropylene (PP), polyethylene terephthalate (PET), polyethylene (PE), of liquid crystalline polymers (LCP), ethylene/vinyl alcohol (EVOH) or polyamide (PA). Sealing layers 3 enable a fusion of the composite and can also be constituted by several polymer layers.

Fig. 2 shows a further example of embodiment of a composite material according to the invention, with which an improved composite adhesion is enabled by additional connecting layers 4 between cardboard layer 1 and barrier layers 2. The connecting layers 4 consist of a bonding agent on a polymer or adhesive base.

Finally, Fig. 3 represents a third example of embodiment, with which two further connecting layers 4 are provided between barrier layers 2 and outer sealing layers 3.

INTELLECTUAL PROPERTY OFFICE OF N.Z. - 1 AUG 2006 received

Claims (15)

1. A composite material made of paper or cardboard as a base material with a plastic coating, in particular for light-, gas- and liquid-tight heat-sealable packages, whereby the plastic coating in each case has outer sealing layers and a barrier layer of metal is present between the base material layer and each sealing layer and whereby as sealing layer a thermoplastic polymer is used, wherein the thermoplastic polymer is a compound of polypropylene, polyethylene terephthalate, polyethylene, liquid crystalline polymers, ethylene/vinyl alcohol and or polyamide.

2. The composite material according to claim 1, wherein in each case at least one connecting layer is arranged between the base material layer and the barrier layer.

3. The composite material according to 2, wherein in each case at least one further connecting layer is arranged between the barrier layer and the outer sealing layer.

4. The composite material according to any one of claims 1 to 3, wherein the barrier layer consists of Al-foil. INTELLECTUAL PROPERTY OFFICE OF N.Z. -1 AU3 2006 i received - 10 -

5. The composite material according to any one of claims 2 to 4, wherein a bonding agent based on a polymer is used as the connecting layer.

6. The composite material according to any one of claims 2 to 4, wherein a bonding agent based on an adhesive is used as the connecting layer.

7. The composite material according to any one of claims 1 to 6, wherein the outer sealing layers have a layer thickness of 10 to 40 g/m2.

8. The composite material according to claim 7, wherein the outer (relative to the subsequent composite package) sealing layer has a layer thickness of 10 to 20 g/m2.

9. The composite material according to claim 7 or 8, wherein the inner (relative to the subsequent composite package) sealing layer has a layer thickness of 20 to 35 g/m2.

10. The composite material according to any one of claims 7 to 9, wherein an Al-foil with a layer thickness of 5 to 10 pm is provided as the barrier layer.

11. The composite material according to claim 10, INTELLECTUAL PROPERTY OFFICE OF N.7 - 1 AU3 2006 RBOIIVED - 11 - wherein the Al-foil has a layer thickness of 6 to 8 lam.

12. The composite material according to any one of claims 2 to 11, wherein the connecting layer has a layer thickness of 4 to 20 g/m2.

13. The composite material according to claim 12, wherein the connecting layer has a layer thickness of 5 to 10 g/m2.

14. The composite material according to any one of claims 3 to 13, wherein the connecting layer present between the base material layer and the barrier layers is thicker than the connecting layer between the barrier layers and the outer sealing layers.

15. A composite material substantially as herein described with reference to any one of the accompanying figures. INTELLECTUAL PROPERTY OFFICE OF N.Z - 1 AUG 2006