NZ519593A - Method for production of N-phosphonomethylglycine - Google Patents
Method for production of N-phosphonomethylglycineInfo
- Publication number
- NZ519593A NZ519593A NZ519593A NZ51959300A NZ519593A NZ 519593 A NZ519593 A NZ 519593A NZ 519593 A NZ519593 A NZ 519593A NZ 51959300 A NZ51959300 A NZ 51959300A NZ 519593 A NZ519593 A NZ 519593A
- Authority
- NZ
- New Zealand
- Prior art keywords
- alkyl
- phosphonomethylglycine
- formula
- solvent
- substituted
- Prior art date
Links
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 title claims abstract 8
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims abstract 26
- OYWRDHBGMCXGFY-UHFFFAOYSA-N 1,2,3-triazinane Chemical class C1CNNNC1 OYWRDHBGMCXGFY-UHFFFAOYSA-N 0.000 claims abstract 6
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims abstract 5
- 238000002360 preparation method Methods 0.000 claims abstract 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 9
- 125000003118 aryl group Chemical group 0.000 claims 6
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 6
- -1 phosphono compound Chemical class 0.000 claims 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 5
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 4
- 229910052783 alkali metal Inorganic materials 0.000 claims 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 4
- 150000001875 compounds Chemical class 0.000 claims 4
- 239000011574 phosphorus Substances 0.000 claims 4
- 229910052698 phosphorus Inorganic materials 0.000 claims 4
- 239000002904 solvent Substances 0.000 claims 4
- 239000005711 Benzoic acid Substances 0.000 claims 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- 150000001340 alkali metals Chemical class 0.000 claims 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 3
- 150000001342 alkaline earth metals Chemical class 0.000 claims 3
- 235000010233 benzoic acid Nutrition 0.000 claims 3
- 238000006243 chemical reaction Methods 0.000 claims 3
- 239000000706 filtrate Substances 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- 239000003960 organic solvent Substances 0.000 claims 3
- 238000004064 recycling Methods 0.000 claims 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 239000008346 aqueous phase Substances 0.000 claims 2
- 239000012071 phase Substances 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims 2
- 235000010234 sodium benzoate Nutrition 0.000 claims 2
- 239000004299 sodium benzoate Substances 0.000 claims 2
- 238000003756 stirring Methods 0.000 claims 2
- 239000000725 suspension Substances 0.000 claims 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims 1
- 238000005160 1H NMR spectroscopy Methods 0.000 claims 1
- 238000004679 31P NMR spectroscopy Methods 0.000 claims 1
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 150000003863 ammonium salts Chemical class 0.000 claims 1
- 238000004458 analytical method Methods 0.000 claims 1
- 239000011260 aqueous acid Substances 0.000 claims 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 1
- 239000002585 base Substances 0.000 claims 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 claims 1
- BJZIAVRHKGVWOH-UHFFFAOYSA-N dibenzoyloxyphosphanyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OP(OC(=O)C=1C=CC=CC=1)OC(=O)C1=CC=CC=C1 BJZIAVRHKGVWOH-UHFFFAOYSA-N 0.000 claims 1
- 238000004821 distillation Methods 0.000 claims 1
- 230000007717 exclusion Effects 0.000 claims 1
- 238000000605 extraction Methods 0.000 claims 1
- 238000004128 high performance liquid chromatography Methods 0.000 claims 1
- 230000007062 hydrolysis Effects 0.000 claims 1
- 238000006460 hydrolysis reaction Methods 0.000 claims 1
- 239000012452 mother liquor Substances 0.000 claims 1
- 238000005191 phase separation Methods 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 150000003018 phosphorus compounds Chemical class 0.000 claims 1
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 claims 1
- 238000001556 precipitation Methods 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 1
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 abstract 1
- 125000003107 substituted aryl group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/409—Compounds containing the structure P(=X)-X-acyl, P(=X) -X-heteroatom, P(=X)-X-CN (X = O, S, Se)
- C07F9/4093—Compounds containing the structure P(=X)-X-C(=X)- (X = O, S, Se)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19962601 | 1999-12-23 | ||
| PCT/EP2000/013162 WO2001047938A1 (de) | 1999-12-23 | 2000-12-22 | Verfahren zur herstellung von n-phosphonomethylglycin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NZ519593A true NZ519593A (en) | 2003-05-30 |
Family
ID=7934229
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NZ519593A NZ519593A (en) | 1999-12-23 | 2000-12-22 | Method for production of N-phosphonomethylglycine |
Country Status (22)
| Country | Link |
|---|---|
| US (4) | US6818793B2 (enExample) |
| EP (1) | EP1240173B1 (enExample) |
| JP (1) | JP4860080B2 (enExample) |
| KR (1) | KR100742796B1 (enExample) |
| CN (1) | CN1195763C (enExample) |
| AR (1) | AR027024A1 (enExample) |
| AT (1) | ATE240337T1 (enExample) |
| AU (1) | AU779799B2 (enExample) |
| BR (1) | BR0016668B1 (enExample) |
| CA (1) | CA2395420C (enExample) |
| DE (1) | DE50002226D1 (enExample) |
| DK (1) | DK1240173T3 (enExample) |
| ES (1) | ES2199898T3 (enExample) |
| IL (2) | IL150173A0 (enExample) |
| IN (1) | IN2002CH00933A (enExample) |
| MX (1) | MX225445B (enExample) |
| NZ (1) | NZ519593A (enExample) |
| PT (1) | PT1240173E (enExample) |
| RU (1) | RU2260010C2 (enExample) |
| SI (1) | SI1240173T1 (enExample) |
| TW (1) | TWI276635B (enExample) |
| WO (1) | WO2001047938A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10130135A1 (de) * | 2001-06-22 | 2003-01-02 | Basf Ag | Verfahren zur Herstellung von N-Phosphonomethylglycin |
| DE10130134A1 (de) * | 2001-06-22 | 2003-01-02 | Basf Ag | Verfahren zur Herstellung von alpha-Aminophosphonsäuren |
| DE10130136A1 (de) * | 2001-06-22 | 2003-01-02 | Basf Ag | Verfahren zur Gewinnung von N-Phosphonomethylglycin |
| DE10142284A1 (de) * | 2001-08-29 | 2003-03-20 | Basf Ag | Fest/Flüssig-Reaktion |
| DE10216638A1 (de) * | 2002-04-15 | 2003-10-23 | Basf Ag | Verfahren zur Herstellung von Ethern, Estern oder Säureanhydriden |
| TW200538459A (en) * | 2004-05-21 | 2005-12-01 | Dow Agrosciences Llc | Purification of n-(phosphonomethyl)glycine |
| EP3245810A1 (en) * | 2015-01-15 | 2017-11-22 | Telefonaktiebolaget LM Ericsson (publ) | Event signalling in a wireless backhaul network |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE141929C (enExample) | ||||
| DE118435C (enExample) | ||||
| NL133081C (enExample) * | 1966-07-27 | |||
| US4008296A (en) * | 1972-11-08 | 1977-02-15 | Imperial Chemical Industries Limited | Esters of N-phosphonomethylglycinonitrile |
| GB1445087A (en) * | 1972-11-08 | 1976-08-04 | Ici Ltd | Preparing n-phosphonomethylglycine and nitrile intermediates therefor |
| GB1570278A (en) * | 1975-10-06 | 1980-06-25 | Fujisawa Pharmaceutical Co | O-substituted-2-azetidinone derivatives and the preparation thereof |
| US4053505A (en) * | 1976-01-05 | 1977-10-11 | Monsanto Company | Preparation of n-phosphonomethyl glycine |
| EG12818A (en) | 1976-12-13 | 1980-07-31 | Monsanto Co | O-aryl-n-phisohonomethylglycinonitriles and herbicidal use thereof |
| US4067719A (en) * | 1976-12-13 | 1978-01-10 | Monsanto Company | O-Aryl N-phosphonomethylglycinonitriles and the herbicidal use thereof |
| US4442044A (en) * | 1981-06-19 | 1984-04-10 | Monsanto Company | Process for preparing monoesters and diesters of N-alkyl substituted amino methyl phosphonic acid |
| DE3132809A1 (de) * | 1981-08-19 | 1983-03-10 | Siemens AG, 1000 Berlin und 8000 München | Verfahren zum herstellen von integrierten mos-feldeffekttransistoren, insbesondere von komplementaeren mos-feldeffekttransistorenschaltungen mit einer aus metallsiliziden bestehenden zusaetzlichen leiterbahnebene |
| US4427599A (en) * | 1982-06-22 | 1984-01-24 | Stauffer Chemical Company | Method for preparation of N-phosphonomethylglycine |
| JPS597197A (ja) * | 1982-06-22 | 1984-01-14 | ストウフア−・ケミカル・カンパニ− | Ｎ−ホスホノメチルグリシンの製造方法 |
| US4428888A (en) * | 1982-08-16 | 1984-01-31 | Stauffer Chemical Company | Method for preparation of N-phosphonomethylglycine |
| US4429124A (en) * | 1982-08-23 | 1984-01-31 | Stauffer Chemical Company | Method for preparation of N-phosphonomethylglycine |
| US4454063A (en) * | 1982-08-23 | 1984-06-12 | Stauffer Chemical Company | O,O-dialkyl-N-phosphonomethyl-N-halomethyl acetamide |
| US4487724A (en) * | 1982-08-23 | 1984-12-11 | Stauffer Chemical Company | Method for preparation of N-phosphonomethylglycine |
| US4425284A (en) * | 1982-08-30 | 1984-01-10 | Stauffer Chemical Company | Method for preparation of N-phosphonomethylglycine |
| US4482504A (en) * | 1982-08-30 | 1984-11-13 | Stauffer Chemical Company | Method for preparation of N-phosphonomethylglycine |
| US4415503A (en) * | 1982-09-28 | 1983-11-15 | Stauffer Chemical Company | Method for preparation of N-phosphonomethylglycine |
| EP0141794A1 (en) * | 1983-08-04 | 1985-05-15 | Monsanto Company | Aralower alkyl and substituted aralower alkyl esters of N-phosphonomethylglycines |
| ATE36162T1 (de) * | 1984-06-04 | 1988-08-15 | Stauffer Chemical Co | Verfahren zur herstellung von nphosphonomethylglycin. |
| KR930005008B1 (ko) * | 1990-05-25 | 1993-06-11 | 한국과학기술연구원 | N-포스포노메틸글리신의 제조방법 |
| GB9307234D0 (en) * | 1993-04-07 | 1993-06-02 | Zeneca Ltd | Process |
-
2000
- 2000-12-20 AR ARP000106770A patent/AR027024A1/es active IP Right Grant
- 2000-12-22 NZ NZ519593A patent/NZ519593A/en unknown
- 2000-12-22 EP EP00993613A patent/EP1240173B1/de not_active Expired - Lifetime
- 2000-12-22 MX MXPA02006081 patent/MX225445B/es active IP Right Grant
- 2000-12-22 CN CNB008156530A patent/CN1195763C/zh not_active Expired - Fee Related
- 2000-12-22 IL IL15017300A patent/IL150173A0/xx active IP Right Grant
- 2000-12-22 KR KR1020027008026A patent/KR100742796B1/ko not_active Expired - Fee Related
- 2000-12-22 AT AT00993613T patent/ATE240337T1/de active
- 2000-12-22 WO PCT/EP2000/013162 patent/WO2001047938A1/de not_active Ceased
- 2000-12-22 AU AU57873/01A patent/AU779799B2/en not_active Ceased
- 2000-12-22 PT PT00993613T patent/PT1240173E/pt unknown
- 2000-12-22 JP JP2001549408A patent/JP4860080B2/ja not_active Expired - Fee Related
- 2000-12-22 RU RU2002119555/04A patent/RU2260010C2/ru not_active IP Right Cessation
- 2000-12-22 CA CA002395420A patent/CA2395420C/en not_active Expired - Fee Related
- 2000-12-22 DE DE50002226T patent/DE50002226D1/de not_active Expired - Lifetime
- 2000-12-22 TW TW089127700A patent/TWI276635B/zh not_active IP Right Cessation
- 2000-12-22 DK DK00993613T patent/DK1240173T3/da active
- 2000-12-22 ES ES00993613T patent/ES2199898T3/es not_active Expired - Lifetime
- 2000-12-22 US US10/168,717 patent/US6818793B2/en not_active Expired - Fee Related
- 2000-12-22 SI SI200030154T patent/SI1240173T1/xx unknown
- 2000-12-22 BR BRPI0016668-5A patent/BR0016668B1/pt not_active IP Right Cessation
-
2002
- 2002-06-12 IL IL150173A patent/IL150173A/en not_active IP Right Cessation
- 2002-06-20 IN IN933CH2002 patent/IN2002CH00933A/en unknown
-
2003
- 2003-02-20 US US10/368,577 patent/US6660878B2/en not_active Expired - Fee Related
- 2003-09-22 US US10/664,892 patent/US6855841B2/en not_active Expired - Fee Related
- 2003-10-06 US US10/678,626 patent/US20040092765A1/en not_active Abandoned
Also Published As
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PSEA | Patent sealed | ||
| RENW | Renewal (renewal fees accepted) | ||
| RENW | Renewal (renewal fees accepted) | ||
| ERR | Error or correction |
Free format text: THE OWNER HAS BEEN CORRECTED TO 3004745, BASF SE, CARL-BOSCH-STRASSE 38, 67056 LUDWIGSHAFEN, DE Effective date: 20141118 |