NZ511228A - Method and apparatus for screening catalyst libraries using addressable microreactors - Google Patents
Method and apparatus for screening catalyst libraries using addressable microreactorsInfo
- Publication number
- NZ511228A NZ511228A NZ511228A NZ51122899A NZ511228A NZ 511228 A NZ511228 A NZ 511228A NZ 511228 A NZ511228 A NZ 511228A NZ 51122899 A NZ51122899 A NZ 51122899A NZ 511228 A NZ511228 A NZ 511228A
- Authority
- NZ
- New Zealand
- Prior art keywords
- addressable
- test sites
- sample
- product
- orifice
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 238000012216 screening Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 239000000523 sample Substances 0.000 abstract 5
- 239000000047 product Substances 0.000 abstract 4
- 238000012360 testing method Methods 0.000 abstract 3
- 238000005070 sampling Methods 0.000 abstract 2
- 238000012546 transfer Methods 0.000 abstract 2
- 238000004458 analytical method Methods 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 238000001514 detection method Methods 0.000 abstract 1
- 238000011156 evaluation Methods 0.000 abstract 1
- 238000000752 ionisation method Methods 0.000 abstract 1
- 238000004949 mass spectrometry Methods 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J49/00—Particle spectrometers or separator tubes
- H01J49/02—Details
- H01J49/10—Ion sources; Ion guns
- H01J49/16—Ion sources; Ion guns using surface ionisation, e.g. field-, thermionic- or photo-emission
- H01J49/161—Ion sources; Ion guns using surface ionisation, e.g. field-, thermionic- or photo-emission using photoionisation, e.g. by laser
- H01J49/162—Direct photo-ionisation, e.g. single photon or multi-photon ionisation
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
- G01N31/10—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using catalysis
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0046—Sequential or parallel reactions, e.g. for the synthesis of polypeptides or polynucleotides; Apparatus and devices for combinatorial chemistry or for making molecular arrays
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
- B01J2219/00277—Apparatus
- B01J2219/00279—Features relating to reactor vessels
- B01J2219/00281—Individual reactor vessels
- B01J2219/00286—Reactor vessels with top and bottom openings
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
- B01J2219/00277—Apparatus
- B01J2219/00279—Features relating to reactor vessels
- B01J2219/00306—Reactor vessels in a multiple arrangement
- B01J2219/00308—Reactor vessels in a multiple arrangement interchangeably mounted in racks or blocks
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
- B01J2219/00277—Apparatus
- B01J2219/00279—Features relating to reactor vessels
- B01J2219/00306—Reactor vessels in a multiple arrangement
- B01J2219/00308—Reactor vessels in a multiple arrangement interchangeably mounted in racks or blocks
- B01J2219/0031—Reactor vessels in a multiple arrangement interchangeably mounted in racks or blocks the racks or blocks being mounted in stacked arrangements
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
- B01J2219/00277—Apparatus
- B01J2219/00279—Features relating to reactor vessels
- B01J2219/00306—Reactor vessels in a multiple arrangement
- B01J2219/00313—Reactor vessels in a multiple arrangement the reactor vessels being formed by arrays of wells in blocks
- B01J2219/00315—Microtiter plates
- B01J2219/00317—Microwell devices, i.e. having large numbers of wells
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
- B01J2219/00277—Apparatus
- B01J2219/00351—Means for dispensing and evacuation of reagents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
- B01J2219/00277—Apparatus
- B01J2219/00351—Means for dispensing and evacuation of reagents
- B01J2219/00364—Pipettes
- B01J2219/00367—Pipettes capillary
- B01J2219/00369—Pipettes capillary in multiple or parallel arrangements
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
- B01J2219/00277—Apparatus
- B01J2219/00351—Means for dispensing and evacuation of reagents
- B01J2219/00378—Piezoelectric or ink jet dispensers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
- B01J2219/00277—Apparatus
- B01J2219/00351—Means for dispensing and evacuation of reagents
- B01J2219/00423—Means for dispensing and evacuation of reagents using filtration, e.g. through porous frits
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
- B01J2219/00277—Apparatus
- B01J2219/00497—Features relating to the solid phase supports
- B01J2219/005—Beads
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
- B01J2219/00583—Features relative to the processes being carried out
- B01J2219/00585—Parallel processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
- B01J2219/00583—Features relative to the processes being carried out
- B01J2219/0059—Sequential processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
- B01J2219/00583—Features relative to the processes being carried out
- B01J2219/00596—Solid-phase processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
- B01J2219/00583—Features relative to the processes being carried out
- B01J2219/00603—Making arrays on substantially continuous surfaces
- B01J2219/00653—Making arrays on substantially continuous surfaces the compounds being bound to electrodes embedded in or on the solid supports
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
- B01J2219/00583—Features relative to the processes being carried out
- B01J2219/00603—Making arrays on substantially continuous surfaces
- B01J2219/00659—Two-dimensional arrays
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
- B01J2219/0068—Means for controlling the apparatus of the process
- B01J2219/00702—Processes involving means for analysing and characterising the products
- B01J2219/00704—Processes involving means for analysing and characterising the products integrated with the reactor apparatus
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
- B01J2219/00718—Type of compounds synthesised
- B01J2219/00745—Inorganic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
- B01J2219/00718—Type of compounds synthesised
- B01J2219/00745—Inorganic compounds
- B01J2219/00747—Catalysts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
- B01J2219/00718—Type of compounds synthesised
- B01J2219/00745—Inorganic compounds
- B01J2219/0075—Metal based compounds
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- C—CHEMISTRY; METALLURGY
- C40—COMBINATORIAL TECHNOLOGY
- C40B—COMBINATORIAL CHEMISTRY; LIBRARIES, e.g. CHEMICAL LIBRARIES
- C40B30/00—Methods of screening libraries
- C40B30/08—Methods of screening libraries by measuring catalytic activity
-
- C—CHEMISTRY; METALLURGY
- C40—COMBINATORIAL TECHNOLOGY
- C40B—COMBINATORIAL CHEMISTRY; LIBRARIES, e.g. CHEMICAL LIBRARIES
- C40B40/00—Libraries per se, e.g. arrays, mixtures
- C40B40/18—Libraries containing only inorganic compounds or inorganic materials
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Optics & Photonics (AREA)
- Plasma & Fusion (AREA)
- Engineering & Computer Science (AREA)
- Molecular Biology (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Sampling And Sample Adjustment (AREA)
Abstract
Rapid screening for activities and selectivities of catalyst libraries having addressable test sites is achieved by contacting potential catalysts at the test sites with reactant streams forming product plumes at the addressable test sites. The product plumes are screened by translating a sample probe (108) and/or the library to a position that one addressable site is in proximity to the sampling probe sample orifice (117) and passing a portion of the reaction products through the sampling orifice forming a free jet expanded volume in at least one vacuum stage and passing a portion of the cooled and reduced pressure jet stream through an inlet orifice of a mass spectrometer for analysis. The mass spectrometric analysis may be combined with resonance enhanced multi-photon ionisation methods of detection for very rapid library evaluation. Suitable reactors, micro-reactors, and product transfer sample microprobes for product transfer to a mass spectrometer are disclosed.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US19184998A | 1998-11-12 | 1998-11-12 | |
PCT/GB1999/003767 WO2000029844A1 (en) | 1998-11-12 | 1999-11-11 | Method and apparatus for screening catalyst libraries |
Publications (1)
Publication Number | Publication Date |
---|---|
NZ511228A true NZ511228A (en) | 2003-01-31 |
Family
ID=22707151
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NZ511228A NZ511228A (en) | 1998-11-12 | 1999-11-11 | Method and apparatus for screening catalyst libraries using addressable microreactors |
Country Status (13)
Country | Link |
---|---|
EP (1) | EP1129348A1 (en) |
JP (1) | JP2002530647A (en) |
KR (1) | KR20010092734A (en) |
CN (1) | CN1333871A (en) |
AU (1) | AU1064200A (en) |
BR (1) | BR9915268A (en) |
CA (1) | CA2347697A1 (en) |
ID (1) | ID29172A (en) |
MX (1) | MXPA01004785A (en) |
NO (1) | NO20012341L (en) |
NZ (1) | NZ511228A (en) |
PL (1) | PL348157A1 (en) |
WO (1) | WO2000029844A1 (en) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19642261A1 (en) * | 1996-10-11 | 1998-04-16 | Hoechst Ag | Method and device for detecting the catalytic activity of solids |
US7491677B2 (en) | 1999-01-15 | 2009-02-17 | Basf Catalysts Llc | Combinatorial synthesis |
DE19959973A1 (en) * | 1999-12-13 | 2001-06-21 | Basf Ag | Process for combinatorial production and testing of heterogeneous catalysts |
WO2002014854A1 (en) * | 2000-08-14 | 2002-02-21 | Chevron U.S.A. Inc. | Use of microchannel reactors in combinatorial chemistry |
US6864091B1 (en) * | 2000-08-31 | 2005-03-08 | Symyx Technologies, Inc. | Sampling probe |
US6692708B2 (en) | 2001-04-05 | 2004-02-17 | Symyx Technologies, Inc. | Parallel reactor for sampling and conducting in situ flow-through reactions and a method of using same |
DE10117275B4 (en) * | 2001-04-06 | 2005-02-24 | Hte Ag The High Throughput Experimentation Company | Device for archiving and analyzing materials |
DE10117274B4 (en) * | 2001-04-06 | 2005-03-03 | Hte Ag The High Throughput Experimentation Company | Method for analyzing and archiving at least one material library |
WO2002094431A2 (en) * | 2001-05-23 | 2002-11-28 | Nanoscape Ag | Integrated miniaturized chemical laboratory |
US6838052B2 (en) * | 2001-06-29 | 2005-01-04 | Symyx Technologies, Inc. | In-situ injection and materials screening device |
US6923939B1 (en) | 2001-07-05 | 2005-08-02 | Uop Llc | Heat activated membrane introduction apparatus and method for screening materials |
US6949267B2 (en) | 2002-04-08 | 2005-09-27 | Engelhard Corporation | Combinatorial synthesis |
WO2005033712A1 (en) * | 2002-10-29 | 2005-04-14 | E. I. Du Pont De Nemours And Company | Method and apparatus for performing chemical reactions in a plurality of samples |
CN1695061A (en) | 2002-10-29 | 2005-11-09 | 纳幕尔杜邦公司 | Method and apparatus for performing chemical reactions in a plurality of samples |
US7390664B2 (en) | 2002-12-20 | 2008-06-24 | Exxonmobil Research And Engineering Company | Method and apparatus for high throughput catalysts screening and optimization |
CN105784917B (en) * | 2014-12-26 | 2018-06-29 | 中国科学院大连化学物理研究所 | Application of the mass spectrograph during detection is catalyzed reactive ion intermediate |
CN105823820B (en) * | 2015-11-13 | 2019-02-15 | 亚申科技研发中心(上海)有限公司 | Catalyst test apparatus |
WO2018119194A1 (en) * | 2016-12-22 | 2018-06-28 | Ventana Medical Systems, Inc. | System and method for sample processing |
CN107024560B (en) * | 2017-02-24 | 2023-11-21 | 金华职业技术学院 | Testing device for heterogeneous catalysis of gas and reaction surface |
GB2566326A (en) * | 2017-09-11 | 2019-03-13 | Owlstone Inc | Ion mobility filter |
CN109884168B (en) * | 2017-12-06 | 2021-11-05 | 中国科学院大连化学物理研究所 | Device and method for real-time online analysis of catalytic reaction process |
CN113295763B (en) * | 2021-06-03 | 2023-07-25 | 浙江师范大学 | Cross molecular beam detection device capable of eliminating background signal interference of reactants |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR900005250B1 (en) * | 1986-10-28 | 1990-07-21 | 몬산토 캄파니 | Method and apparatus for carrying out catalyzed chemical reactions and for studing catalysis |
US6063633A (en) * | 1996-02-28 | 2000-05-16 | The University Of Houston | Catalyst testing process and apparatus |
DE69735411T2 (en) * | 1996-10-09 | 2006-09-07 | Symyx Technologies, Inc., Santa Clara | INFRARED SPECTROSCOPY AND LIBRARY IMAGING |
EP1019713A1 (en) * | 1997-10-10 | 2000-07-19 | Bp Chemicals (Additives) Limited | Radiation activation and screening of catalyst libraries for catalyst evaluation and reactors therefor |
-
1999
- 1999-11-11 EP EP99954228A patent/EP1129348A1/en not_active Withdrawn
- 1999-11-11 AU AU10642/00A patent/AU1064200A/en not_active Abandoned
- 1999-11-11 WO PCT/GB1999/003767 patent/WO2000029844A1/en not_active Application Discontinuation
- 1999-11-11 CN CN99815596A patent/CN1333871A/en active Pending
- 1999-11-11 JP JP2000582796A patent/JP2002530647A/en active Pending
- 1999-11-11 BR BR9915268-1A patent/BR9915268A/en not_active Application Discontinuation
- 1999-11-11 MX MXPA01004785A patent/MXPA01004785A/en unknown
- 1999-11-11 ID IDW00200101044A patent/ID29172A/en unknown
- 1999-11-11 PL PL99348157A patent/PL348157A1/en unknown
- 1999-11-11 CA CA002347697A patent/CA2347697A1/en not_active Abandoned
- 1999-11-11 NZ NZ511228A patent/NZ511228A/en unknown
- 1999-11-11 KR KR1020017005945A patent/KR20010092734A/en not_active Application Discontinuation
-
2001
- 2001-05-11 NO NO20012341A patent/NO20012341L/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
WO2000029844A1 (en) | 2000-05-25 |
CA2347697A1 (en) | 2000-05-25 |
NO20012341D0 (en) | 2001-05-11 |
EP1129348A1 (en) | 2001-09-05 |
CN1333871A (en) | 2002-01-30 |
AU1064200A (en) | 2000-06-05 |
PL348157A1 (en) | 2002-05-06 |
JP2002530647A (en) | 2002-09-17 |
ID29172A (en) | 2001-08-09 |
BR9915268A (en) | 2001-08-07 |
NO20012341L (en) | 2001-05-11 |
MXPA01004785A (en) | 2002-05-06 |
KR20010092734A (en) | 2001-10-26 |
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