NZ508556A - Carbon dioxide atmosphere modifiers for packaging - Google Patents

Abstract

A sachet for maintaining or modifying the atmosphere in a package, the sachet including: (A) a moisture vapor activated chemical substance contained by two containing layers bonded together, and (B) at least one moisture absorbent layer immediately adjacent to, and bonded to at least one of the containing layers wherein each said absorbent layer is external, relative to the said containing layers and wherein each containing layer positioned adjacent to an absorbent layer is formed from microporous film. Fig 1. is a preferred example of the sachet. Package 1 indicates a container 2, a sachet 3. The sachet 3 includes containing layers 4 and 5 which hold a chemical 6. Layer 5 is micro-porous, allowing vapour to pass through it, but not allowing any liquid or solid material to pass through the layer. The chemicals may contain a CO2 releasing substance, or a combination of CO2 generating/oxygen absorbing substances which needs to be effectively separated from the package meat. The product 8 within the package is meat. The container 2 is sealed by two separate film layer 9 and 10. The sachet 3 also includes absorbing layer 7 which soaks up moisture. The moisture is then transferred from the absorbing layer 7 to permeate through the micro-porous layer 5 as water vapour activates chemical 6. The gas produced by the chemical 6 passes through the sachet 3 and into the package's atmosphere. This modifies the atmosphere allowing desired storage conditions for the meat.

Description

New Zealand Paient Spedficaiion for Paient Number 508556 508556 wo 99/62790 pct/nz99/00068 CARBON DIOXIDE ATOMSPHERE MODIFIERS FOR PACKAGING Technical Field This invention relates to methods and apparatus used in packaging.

More particularly, the principles of the present invention relate to the packaging of food products such as meat using atmosphere modifiers.

Reference to the packaging of meat should not be seen to be limited as the principles of the present invention may be equally applied to the packaging of other food products.

Background art The export and domestic consumption of meat, such as beef, lamb, chicken and other meats, provides a significant source of revenue for many countries. It is therefore important that this product arrives at its destination having the highest possible quality. It therefore follows that packaging methods used to contain the meat in 15 transit must be of high quality in order to keep the meat in a desired state.

There are however problems with the current methods and apparatus used to package meat.

A natural process that must be mitigated or avoided, is oxidation. This occurs by oxygen coming in contact with the meat during storage and transit, causing oxidation.

In general, consumers perceive that meat coloured red is fresh, and therefore preferable to discoloured meat. However, storage under conditions where oxygen is present results in gradual browning of the meat. While in many cases the product is still acceptable for consumption, consumers are deterred by the brownish appearance of the meat which they associate with a spoiled product.

Printed from Mimosa 12/05/2000 10:29:14 page -3- WO 99/62790 PCT/NZ99/00068 In cases where long-term storage of meat is necessary, the presence of oxygen can result in spoilage of the meat in addition to the browning of the meat.

One method of avoiding oxygen spoilage, is vacuum packaging the 5 meat in an oxygen impermeable barrier film. The problems associated with this are that the meat, under a low or nil oxygen modified atmosphere or a vacuum atmosphere, tends to develop a purple colouration which consumers find unacceptable.

High oxygen/C02 modified atmosphere systems are successfully used for retail cuts 10 of red meat, but the storage life is relatively low due to loss of colour.

A well known packaging system known as low oxygen/C02 packaging is in current use however has been mainly directed to non-retail ready markets.

The shelf life of C02 packaged meat is longer than for vacuum packed meat. The meat stored under C02 will rebloom on exposure to oxygen, giving the red 15 colouration which consumers associate with freshness.

The display life of C02 packaged meat, in the oxygenated state appears to be longer than that of vacuum packed meat. This may be attributed to the low oxygen concentration throughout the product lifetime.

The use of low oxygen/high C02 packaging is well known, as is the use of oxygen 20 absorbing compositions with meat products.

C02 will be absorbed in significant quantities by the meat within the first 48 hours of exposure. This absorption causes the internal pressure of the package to be reduced, unless there is a sufficient excess of C02 to saturate the meat, and a suitable mechanism by which the volume of the package may contract.

Therefore if the meat is placed on a conventional sized tray, evacuated, gas flushed 2 Printed from Mimosa 12/05/2000 10:29:14 page -4- WO 99/62790 PCT/NZ99/00068 with CO, and then sealed under a barrier film, severe distortion will occur as the C02 is absorbed and the internal pressure of the system is reduced. This is because the volume of the rigid tray cannot contract in a controlled manner like that of a bag, and 5 because insufficient C02 is present to compensate for that which is absorbed by the meat.

This effect may be reduced if a high package volume in relation to the volume of the product is achieved. However this is undesirable to consumers and results in excessive packaging and waste.

One solution to the above problems has been to provide a sachet of a substance that absorbs oxygen and releases C02 in response to humidity. The sachet may be placed between one gas permeable layer immediately surrounding the meat, and a second gas impermeable layer.

In some embodiments, the sachet is placed over a hole in the permeable layer. This 15 allows activation by in-pack humidity. The holes also allows rapid equilibration of gases. This embodiment thus produces a modified atmosphere package whereby distortion, excess oxygen and their associated negative effects is reduced.

Although this process has been successful, there have been problems associated with it.

Due to a number of steps that must be undertaken to implement the system for packaging the meat, the packaging process is complicated and expensive. For example, the process must be made accurate enough so that the sachet containing the regulating chemicals is placed over the hole in the permeable layer. An absorbing layer must also be placed in the package between the meat and the bottom of the 25 package in order to absorb the fluids that may exude from the meat. The supermarkets place a pricing or use by date label over the hole once the sachet is removed, to avoid leakage and prevent contamination.

Printed from Mimosa 12/05/2000 10:29:14 page -5- Other methods of atmosphere modification are desiccant sachets, sulfur dioxide emitters and devices for liberating chlorine dioxide.

These, combined with oxygen absorbers, and combined oxygen absorber/ C02 generators form part of the technology known as active packaging.

Sachets that contain a C02 liberating chemical substance may be used in active packaging. This sachet may be made from a micro-porous, non-permeable membrane that allows transfer of humidity, but does not allow the transfer of liquid through the 10 membrane.

There is also a need to transfer humidity from the pack to the sachet in order to initiate the atmosphere regulating chemicals.

European Patent EP0128795 describes oxygen or C02 generators housed in sub-compartments of packages. The chemicals react on contacting the drip from the meat. 15 No microporous films are used.

French Patent 2 621 015, describes C02 releasing chemicals, which are distributed in a fibrous structure. The hydro-phobicity of the fibres prevents the chemicals from leaching into the food.

European Patent EP 0 468 880 Al, describes oxygen absorbers and/or C02 generators 20 housed in liquid impermeable vapour permeable packets. The packets have two compartments housing the reactive components linked by a weak seal. Rupture of the weak seal causes the two components to react, thus modifying the package atmosphere.

All of the above documents describe devices that suffer the problem of requiring 25 moisture vapour to activate the compounds, wherein the vapour is not drawn around 4 Printed from Mimosa 12/05/2000 10:29:14 page -6- or local to the sachet to sufficiently activate the compounds in the sachet.

What is needed then is a system of modifying the atmosphere of a closed package, by a process that is uncomplicated and does not necessitate the steps previously used.

It is an object of the present invention to address the foregoing problems or at least to provide the public with a useful choice.

Further aspects and advantages of the present invention will become apparent from the ensuing description which is given by way of example only.

Disclosure of Invention According to one aspect of the present invention there is provided a sachet for maintaining or modifying the atmosphere in a package, the sachet including: a moisture vapor activated chemical substance contained by two containing 15 layers bonded together, and at least one liquid absorbent layer immediately adjacent to, and bonded to at least one of the containing layers wherein each said absorbent layer is external, relative to the said containing layers and wherein each containing layer positioned adjacent to an absorbent layer is formed from microporous film. 2q The present invention also relates to a method of packaging characterised by the step of placing into a package a device as described immediately above.

Described is a device for maintaining or modifying the atmosphere in a package, the device including: at least two containing layers, a moisture activated chemical substance contained by the containing layers, and at least one absorbent layer attached to at least one of the containing layers.

The absorbent layer may be any device capable of retaining and/or absorbing and/or transferring liquid or humidity.

The absorbent layer may be any suitable material, but preferably of food-grade quality.

The absorbent layer may contain a cellulosic absorbent such as paper or wood pulp or viscose fibers, superabsorbent polymers and the like and is preferably heat sealed to intellectual property office of n.z. - 9 JUL 2003 _Received the adjoining layer.

Preferably the absorbent layer is of a thickness and type to absorb all of the fluid released by the product.

A preferred feature of the present invention is to have the absorbent layer of sufficient type and thickness to absorb excess fluid from the product or pooling in the tray packaging.

The absorbent layer may be attached to the containing layers by many means and in one embodiment may be heat sealed to the containing layer.

Reference to packaging will now be made with reference to the packaging of meat in a plastic container. This should not be seen to be limiting, as the principles of the present invention may be applied to the packaging of other substances and containers of other types.

Preferably the plastic container will include a substantially rigid base with plastic 15 films at the top. The base may also include ribbed portions.

Reference to a rigid base and plastic top should not be seen to be limiting the scope of the present invention's, manufacture or use, as other container configurations may be used without departing from the scope of the present invention.

These atmosphere modifying absorbent pads may be used in non-retail packs such as 20 in vacuum packed meat primal cuts or alternatively in bulk gas flushed packages.

Preferably, one of die containing layers positioned next to the absorbing layer is formed from a micro-porous film. Micro-porous films have high moisture vapour transmission rates (MVTR'S) and are not permeable to liquid water. These high MVTR materials allow 25 water vapour to rapidly activate the chemical contained between the layers, but do not intellectual property office 0fn.z. - 9 JUL 2003 received WO 99/62790 PCT/NZ99/00068 allow the chemicals to leach out and contaminate the foodstuff.

Because of the nature of these films, it is preferable that the product does not come into contact with the micro-porous film as local dessication can occur. Therefore it is 5 envisioned that in use the device is placed in the packaging with the product on top of the containing layer (external) which is not micro-porous.

Reference to the present invention may now be made by reference to a sachet. Reference to a sachet should not be seen to be limiting the scope of the present inventions manufacture or use.

In one example, one side of the sachet may be constructed from a PET laminate or similar heat resistance material, and the other side from the micro-porous film.

Thus, it can be seen that the preferred structure of the present invention has an absorbent layer positioned on the bottom of the package which is next to a micro-porous layer that transfers moisture vapor from the absorbent layer or the humid 15 atmosphere of the package to chemicals contained by the micro-porous layer and the other containing layer. The non-micro-porous containing layer ensures that there is no local desiccation of the product on top of it and both the containing layers ensure that the chemicals do not come into contact with the product.

Preferably the absorbing layer is peripherally bonded to the other containing layer. In 20 some embodiments the peripheral bonds are heat laminated bonds or formed by heat lamination.

In one embodiment one or more containing layers may have oxygen absorbing capabilities.

In one preferred embodiment, the chemicals in the present invention may be one or a 25 combination of moisture activated chemicals that modify the atmosphere to the desired configuration. 7 Printed from Mimosa 12/05/2000 10:29:14 page -9- WO 99/62790 PCT/NZ99/00068 Preferably, the quantity and configuration of the chemical will be chosen for the appropriate expected shelf life and storage length of the product packaged.

The chemical may be a system capable of evolving or removing C02 over a period of 5 time. This should not be seen to be limiting however. For example, in other preferred embodiments the chemical may remove oxygen from or release oxygen to the environment of the package. Anti-microbial gases may also be released from the chemical.

The present invention has a number of advantages.

A number of humidity triggered atmosphere modifying devices are known and are used in food packaging. These include sachets which absorb oxygen, absorb oxygen and generate C02 and those which generate carbon-dioxide only. These chemicals must be kept separate from the food using a functional barrier. The present invention achieves this by the use of the micro-porous film which only allows transmission of 15 all gases. For example, these may be water vapour, C02 gas, oxygen and so forth. This list should not be seen to be limiting.

The presence of the absorbing device in the present invention ensures that sufficient moisture vapor is transferred to activate the chemicals that control the modified atmosphere. This combination of absorbent layer and containing layers, one of 20 which is micro-porous, addresses the problems associated with the prior art.

In many cases where the absorbing layer is not present, and the meat or foodstuff does not contain sufficient moisture, the moisture activated atmosphere modifying chemicals are not activated sufficiently to modify the atmosphere to the required specification. The present invention avoids this possibility by providing the 25 absorbing layer that contains moisture that may be transmitted over a period of time thus activating the desired chemicals allowing the gases evolved to pass through the micro-porous film into the package. 8 Printed from Mimosa 12/05/2000 10:29:14 page -10- It is preferable to have the chemicals activated slowly over a period of time to prevent over-inflation of the package and possible rupture of the seal.

The present invention also has the advantage of acting as a drip absorbent in the final 5 package. Thus, there is not the problem of liquid forming on the bottom of a package and spilling on an undesired location when the package is opened. Thus, the present invention has the advantage that it may be used as a drip absorber as well as an atmosphere modifier.

Thus, one device can absorb excess fluid, modify the package atmosphere, and 10 eliminate problems associated with prior art atmosphere modifiers.

In preferred embodiments, these atmosphere modifying devices may be used in a sheet form between layers of modified atmosphere packaged foodstuffs to ensure there is no concentration gradient of gas through the sample.

The present invention describes an absorbent pad which contains a fluid impermeable 15 gas permeable section containing atmosphere modifying chemicals. These chemicals are formulated to either generate C02 or to generate C02 and absorb oxygen.

The structure may also be used to house other atmosphere modifying chemicals when the product produces liquids. The chemicals need to be physically separated from the product. The reaction of these chemicals is triggered by the humidity of the product. 20 The present invention has the advantage of keeping the chemicals separate from the food thus preventing them from leaching out of the sachet.

The present invention may be particularly useful in modified atmosphere packages and in conjunction with evacuation/gas flushing. 9 Printed from Mimosa 12/05/2000 10:29:14 page -11- Some examples of the present invention are described below.

Example 1.

An absorbent pad capable of generating carbon dioxide and absorbing oxygen was 5 prepared with the following materials: Layer 1 PET film adhesively laminated to high opacity filled PE film.

Layer 2 Microporous polypropylene film with Gurley Air permeability of lOOsec/lOOcc.

Layer 3 Non woven fabric consisting of a mixture of viscose fibres and 10 polypropylene fibres with a weight of 120g/m2.

A fine particle size well mixed powder of the following composition by weight was prepared: Sodium bicarbonate 472.28 Fumaric acid 280.2 Sodium erythorbate 67.33 Ferrous sulphate 39.6 Calcium chloride 130.7 Fumed silica 9.9 1.75g of the formulation was placed in between layers 1 and 2 as described above to 20 form a cell of dimensions 58x56mm. A high speed filling machine of proprietary design was used.

The absorbent pads were sealed in a barrier pouch and held at chill temperatures where they were stable to premature reaction for many months.

The pads were used to prepare long shelf life packages of beef, lamb and pork.

Printed from Mimosa 12/05/2000 10:29:14 page -12- WO 99/62790 PCT/NZ99/00068 In barrier trays of volume 800cc was placed two attached cells as described above. The cells were placed so that the PET layer contacted the meat, and the absorbent layer contacted the bottom of the trays. 500g of beef, pork or lamb was then placed in 5 the trays, which were then gas flushed with a mixture of 80% carbon dioxide and 20% nitrogen. The initial oxygen concentration was less than lOOOppm. The barrier lidding film used was a proprietary film produced by Cryovac Sealed Air Corporation, which can be delaminated at the point of sale to leave a highly oxygen permeable film attached to the tray, and is described in U.S.S.N 08/764,405 filed 11 10 December as a CP application of US 5,6861,126 which is incorporated by reference herein.

After 10 weeks storage at -1°C the film was delaminated leaving the oxygen permeable film adhered to the tray. The products still have an acceptable retail display life in the oxygenated state. The bacteria levels were very low. For beef the 15 initial counts were 2.7 log cfu/cm2 which decreased to 2 log cfu/cm2 after ten weeks at -1°C. After retail display the total counts were 3.9 log cfu/cm2 for samples stored for 1 day before display, while samples stored for 10 weeks before display had a total count of 6.4 log cfu/cm2 after retail display.

The packs showed no deformation due to carbon dioxide absorption, nor excess 20 pressure caused by the presence of excess gas. No drip was visible in any of the packages at any point in the experiment.

There was no leaching of the chemicals from within the pad.

In further tests the pads could be suspended in water at 40°C for many days without leaching. Eventually the bond between the PET laminate and the microporous film 25 would break due to the pressure of water which had entered the area containing the chemicals. 11 Printed from Mimosa 12/05/2000 10:29:14 page -13- This experiment demonstrates the following: These atmosphere modifying chemicals may be successfully used as part of a drip absorbent system.

The chemicals are retained within the pouch after extended storage periods.

The chemicals contribute to the drip absorbing function of the non woven fabric by means of vapour transfer.

Example 2.

An absorbent pad capable of generating carbon dioxide, but not of absorbing oxygen 10 was constructed as follows: Sodium bicarbonate 550 Fumaric acid 320 Calcium chloride 130 Fumed silica 10 The mixture was used to formulate a pad for packaging chicken portions.

Example 3.

A powder of the following formulation was prepared: Iron powder 100 Sodium chloride 5 20 Precipitated silica 5 lg of the powder was placed in between layers 1 and 2 in a structure identical to that described in example 1.

The absorbent pad was placed in the bottom of the tray as in example 1 and 12 Printed from Mimosa 12/05/2000 10:29:14 page -14- WO 99/62790 PCT/NZ99/00068 used to pack 500g of beef. The tray was gas flushed with 100% nitrogen.

The scavenging sachet maintained an oxygen concentration of less than lOOppm throughout the lifetime of the package.

Example 4.

An absorbent pad was prepared as in example 1 except that Layer 3 was substituted with a material containing the following components: Super absorbent fibres Viscose fibres 10 Polyethylene fibres The composite had a weight of 150g/m2.

In a standard test using a 0.9% saline solution to compare the absorption capacities the composite fabric absorbed 3500g/m2 of fluid versus 1500g/m2 for the fabric described in Example 1. This material could therefore be used in applications where 15 much higher levels of drip are produced. The activity in terms of gas absorption and release were very similar to that obtained in example 1.

Example 5.

Sulphur dioxide releasing absorbent pads may be prepared using the structure described in example 1.

PCT/AU93/00562 describes a range of applications and materials which may be used to release sulfur dioxide in a controlled and sustained manner. These sulfur dioxide emitting materials may be utilised in the present invention.

The pad has the dual function of absorbing fluids and releasing an antimicrobial gas, whilst effectively separating the chemicals from the product. 13 Printed from Mimosa 12/05/2000 10:29:14 page -15- wo 99/62790 pct/nz99/00068 Example 7.

Oxygen releasing pads may be prepared by utilising sodium perborate or percarbonate and the like compounds and mixtures in the cavity between Layers 1 and 2 of the 5 structure as described in Example 1.

Brief Description of Drawings Further aspects of the present invention will become apparent from the following description which is given by way of example only and with reference to the accompanying drawings in which: Figure 1 shows a representation of one preferred embodiment, and Detailed Description Of The Drawings According to Figure 1 there is shown a package, shown by arrow 1.

Package 1 includes a container 2, a sachet 3.

The sachet 3 includes containing layers 4 and 5 which hold a chemical 6. Layer 5 is 15 micro-porous in nature, allowing vapour to pass through it, but not allowing any liquid or solid material to pass through the layer.

The chemicals modify the atmosphere in the container. These may be a C02 emitting substance, or a combination of a C02 generating/oxygen absorber or absorber or any atmosphere modifier which needs to be effectively separated from the packaged 20 product.

The sachet 3 also includes absorbing layer 7 which faces the base of the tray. The product 8 within the package is meat.

The container 2, is sealed by two separate film layers 9 and 10. However, in Printed from Mimosa 12/05/2000 10:29:14 page -16-

Claims (7)

WO 99/62790 PCT/NZ99/00068 alternative embodiments, a single plastic film may be used or a peelable laminate. In use, the sachet 3, may be placed in the container 2 with the absorbing layer placed downwards, and the meat added. 5 The moisture within the package is soaked up by the absorbing layer 7. The moisture is then transferred from the absorbing layer 7 to permeate through the micro-porous layer 5 as water vapour and activate the chemicals 6. The gas produced by the chemicals 6 may then pass through the sachet 3 and into the package's atmosphere. This modifies the atmosphere to the desired requirements. 10 Thus, the required atmosphere is maintained, and the chemical mixture is activated without the chemicals contacting the product. Aspects of the present invention have been described by way of example and it should be appreciated that modifications and additions may be made thereto without departing from the scope of the appended claims. 15 Printed from Mimosa 12/05/2000 10:29:14 page -17- WE CLAIM:

1. A sachet for maintaining or modifying the atmosphere in a package, the sachet including: a moisture vapor activated chemical substance contained by two containing layers bonded together, and at least one liquid absorbent layer immediately adjacent to, and bonded to at least one of the containing layers wherein each said absorbent layer is external, relative to the said containing layers and wherein each containing layer positioned adjacent to an absorbent layer is formed from microporous film.

2. A sachet as claimed in claim 1 wherein one containing layefc is not microporous.

3. A sachet as claimed in either claim 1 or claim 2 wherein one or more of the containing layers have oxygen absorbing capabilities.

4. A sachet as claimed in any one of claims 1 to 3 wherein the device is capable of being used as a drip absorber.

5. A sachet according to any one of claims 1 to 4 in which the moisture vapor activated chemical substance, when activated, modifies the gaseous atmosphere of the package.

6. A sachet according to any of claims 1 to 5 wherein the moisture vapor activated chemical substance, when activated, releases oxygen or carbon dioxide to, or removes oxygen or carbon dioxide from, the atmosphere within the package.

7. A sachet as claimed in any one of claims 1 to 6 wherein the absorbing layer is Ifi intellectual property office of n.z. " 9 JUL 2003 received peripherally bonded to the other containing layer. A sachet as claimed in claim 7 wherein the peripheral bonds are heat laminated bonds or formed by heat lamination. A method of packaging characterised by the step of including within a package a sachet as claimed in any one of claims 1 to 8. A method of packaging as claimed in claim 9 characterised in that the absorbent layer of the sachet is placed downwards within the package such that it does not contact the product contained within the package. A device substantially described herein with reference to and as illustrated by the accompanying drawings. A method substantially as herein described with reference to and as illustrated by the accompanying drawings. 17 PCT/NZ99/00068 Received 5 April 2000 0 lL