NZ244994A - Radiant energy collecting apparatus with movable floating platform on fluid reservoir being submersible during bad weather - Google Patents

Radiant energy collecting apparatus with movable floating platform on fluid reservoir being submersible during bad weather

Info

Publication number
NZ244994A
NZ244994A NZ244994A NZ24499492A NZ244994A NZ 244994 A NZ244994 A NZ 244994A NZ 244994 A NZ244994 A NZ 244994A NZ 24499492 A NZ24499492 A NZ 24499492A NZ 244994 A NZ244994 A NZ 244994A
Authority
NZ
New Zealand
Prior art keywords
platform
fluid
impellers
reservoir
feed
Prior art date
Application number
NZ244994A
Inventor
Allan James Yeomans
Original Assignee
Allan James Yeomans
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Allan James Yeomans filed Critical Allan James Yeomans
Publication of NZ244994A publication Critical patent/NZ244994A/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24SSOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S23/00Arrangements for concentrating solar-rays for solar heat collectors
    • F24S23/70Arrangements for concentrating solar-rays for solar heat collectors with reflectors
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24SSOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S30/00Arrangements for moving or orienting solar heat collector modules
    • F24S30/40Arrangements for moving or orienting solar heat collector modules for rotary movement
    • F24S30/42Arrangements for moving or orienting solar heat collector modules for rotary movement with only one rotation axis
    • F24S30/422Vertical axis
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24SSOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S20/00Solar heat collectors specially adapted for particular uses or environments
    • F24S20/70Waterborne solar heat collector modules
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24SSOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S23/00Arrangements for concentrating solar-rays for solar heat collectors
    • F24S23/70Arrangements for concentrating solar-rays for solar heat collectors with reflectors
    • F24S23/79Arrangements for concentrating solar-rays for solar heat collectors with reflectors with spaced and opposed interacting reflective surfaces
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08Seawater, e.g. for desalination
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24SSOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S23/00Arrangements for concentrating solar-rays for solar heat collectors
    • F24S23/70Arrangements for concentrating solar-rays for solar heat collectors with reflectors
    • F24S2023/83Other shapes
    • F24S2023/832Other shapes curved
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24SSOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S23/00Arrangements for concentrating solar-rays for solar heat collectors
    • F24S23/70Arrangements for concentrating solar-rays for solar heat collectors with reflectors
    • F24S2023/87Reflectors layout
    • F24S2023/872Assemblies of spaced reflective elements on common support, e.g. Fresnel reflectors
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • Y02A20/138Water desalination using renewable energy
    • Y02A20/142Solar thermal; Photovoltaics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/40Solar thermal energy, e.g. solar towers
    • Y02E10/47Mountings or tracking
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37Wastewater or sewage treatment systems using renewable energies using solar energy

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Combustion & Propulsion (AREA)
  • Photovoltaic Devices (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Breeding Of Plants And Reproduction By Means Of Culturing (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Mounting And Adjusting Of Optical Elements (AREA)

Abstract

The invention relates to a radiant energy collecting installation, particularly to a solar energy collecting installation with a view to provide heating and to produce electricity. The radiant energy collecting installation (10) comprises a container (11) with liquid, a platform (13) floating on the liquid in the container (11), a device permitting the displacement of the platform (13) on the liquid in the container (11), a radiant energy collecting device mounted onto the platform (13) which comprises a collecting pipe (29) playing the role of transferring the collected energy to a source of energy, a reflecting device such as mirrors (28), mounted on the platform (13) in such manner that it reflects the radiant energy and concentrates the solar energy towards the radiant energy collecting pipe (29), and is characterized in that the reflecting device such as mirrors (28) is immersed selectively into the liquid in the container (11), the collecting pipe (29) remaining above the liquid to prevent energy loss in case of bad weather.

Description

<div class="application article clearfix" id="description"> <p class="printTableText" lang="en">Patei4^orm <br><br> No. 5 <br><br> Hal. 5 <br><br> NEW ZEALAND <br><br> 9 /. <br><br> ff,= Lt <br><br> &lt;*• A <br><br> A <br><br> Priority Datc(s): .,. .6. /_/■ 7/^ jj( y- ^ <br><br> ?£. <br><br> ' * 1 ' * ' • • • | <br><br> Ufnpiete Specification Filed: . <br><br> Publication Date: ...$/£ P.O. Journsl. No: ... .IStfj?.. <br><br> PATENTS ACT 1953 <br><br> COMPLETE SPECIFICATION <br><br> (To be furnished in Duplicate) <br><br> Where jmiority as provided by subsection (2) °r£j)/^r scciion II of the Patents Act 1953 is in rcspccl of one or more provisional ifications, quo}c number or numbers and date or dates ■ '\ <br><br> No. I <br><br> Date <br><br> (a) Insert title or Invention. <br><br> (a) <br><br> RADIANT ENERGY COLLECTING APPARATUS <br><br> (b) State (in full) name, address and nationality of annlicant or applicants as Application form <br><br> (c) Here begin full description of invention. The continuation of the spccifi- <br><br> cation should be upon paper of the same size as this form, on one side only with the lines well spaced and with a margin of 2.5cm on the left hand side of the paper. The completion oi the description should be followed by the words "What I (or wc) claim is" after which should be written the claim or claims numbered consecutively (see note below). The specification and the dup-Ikmu thereof mum be signed ui the end. <br><br> 'irtJIHj 1 &lt;iOOI3IB9MK <br><br> (b) <br><br> ALLAN JAMES YEOMANS / 60 Sunrise Boulevard, <br><br> SURFERS PARADISE QUEENSLAND AUSTRALIA an AUSTRALIAN citizen <br><br> HEREBY dcclarc the invention, for which l/wc pray that a patent may be granted to me/us and the method by which it is to be performed, to be particularly dcscribcd in and by the following statement: <br><br> NOTE. The claims must relate to a single invention, must be clcar and succinct, and must be fairly based on the matter disclosed in the specification. They should form in brief a clcar statement of that which constitutes the invention. Applicants should be careful that their claims include neither more nor less than they desire to protect by their patent. Any unnecessary multiplicity of claims or prolixity of language should be avoided. <br><br> Claims should not be made for the cfficicncy or advantages of the invention. <br><br> *&gt;■* 1 t <br><br> Technical Field <br><br> The present invention relates to radiant energy collecting apparatus and in particular aspects to solar energy collecting apparatus, means for facilitating alignment of such 5 apparatus with the sun, means for protecting said apparatus in inclement weather conditions and means of stabilizing said apparatus. <br><br> Background of the Invention <br><br> To utilize solar energy for heating or for electricity 10 generation it is generally necessary to concentrate the solar radiation to obtain higher temperatures in the energy storage and transport medium. <br><br> There are various methods used to concentrate the solar radiation. One method utilizes a circular mirror of parabolic 15 section with the centre line of the dish pointing at the sun. The parabolic mirror must be suitably mounted to permit constant movement to follow the arc of the sun through the sky. <br><br> Additionally, the alignment of the arc of the sun through the sky will change from day to day as the declination 20 of the sun changes from summer solstice to the winter solstice. Complex mechanisms are required to fulfill these requirements. <br><br> In the above method, the solar energy is concentrated into a small single focus point where a suitable heat absorber is mounted and it is difficult to transport this energy to a 25 utilization point. <br><br> In another system, long parallel mirrored troughs having a parabolic cross-section are aligned with the sun. In this system, the concentration occurs at a focus line parallel with the alignments of the collecting troughs. The mirrored 30 troughs are either formed by one piece parabolic mirrors or a series of mirrors. In either case it is important from the point of view c* focussing and efficiency to support the mirrors or series of mirrors so that they do not move out of alignment with the collectors which are arranged at the focus 35 line of the parabolic trough. Large and accurately formed structures are generally required for this purpose. <br><br> The collecting troughs may be aligned in a North/South <br><br> / r i <br><br> 3 <br><br> direction and the troughs are so mounted as to permit them to follow the movement of the sun through the course of the day. Complex mechanisms are also required to fulfill this requi rement. <br><br> containing a suitable heat absorbing liquid, the pipe being mounted at the focus line of the parabolic reflecting troughs. <br><br> In the trough collecting system, the troughs can also be mounted in an East-West alignment and it is then necessary 10 to align the troughs to the arc line of the sun once each day to allow for change in declination. Complex mechanisms are also required to control this alignment. <br><br> In mounting parabolic reflecting troughs in either the North-South or the East-West configuration, the troughs are 15 adjusted to maintain their focus on the sun by pivotally mounting on an axis parallel to the focus line of the mirrored troughs and generally requiring a multiplicity of rotating bearings and associated mounting structures. <br><br> It is also generally necessary to arrange the 20 reflecting surfaces of solar energy collecting apparatus so that they are not subject to the possibility of damage caused by such things as hail. This is often achieved by the use of high quality and consequently expensive toughened glass in the construction of the reflecting mirrors. Additionally as a 25 protection the mirrored surfaces often need to be turned away from the direction of on coming hail. <br><br> It is an object of the present invention to overcome or substantially ameliorate one or more of the above described di sadvantages. <br><br> 30 Summary of the Invention <br><br> In one aspect of the present invention, a radiant energy collecting apparatus is provided including a fluid reservoir, a platform floating on fluid in said fluid reservoir, a drive for pivoting the platform about a vertical 35 axis, radiant energy collectors supported on the platform, and concentrators for directing the radiant energy to the radiant energy collectors. Preferably the radiant energy collectors <br><br> 5 <br><br> The solar energy is then generally collected in a pipe <br><br> 0 y L •k- <br><br> n / / '' ^ / <br><br> 4 : V 4 <br><br> are of elongated form and extend transversely to the vertical pivot axis. <br><br> In one preferred form the fluid reservoir comprises a built reservoir such as a storage container, or dam containing 5 a liquid such as water. Alternatively the fluid may comprise water in a river or ocean. The term "fluid reservoir" as used throughout the specification thus includes any of the arrangements described above, the term "reservoir" including natural or purpose built liquid containers. 10 In another aspect of the present invention and when the platform floats on a liquid, at least the concentrators may be selectively submerged beneath the surface of the liquid for protection against inclement weather conditions, such as in high winds, hail or heavy rain. In one embodiment of this 15 invention, a low pressure is established beneath the platform to restrain the platform against the buoyant force on the platform of the liquid. In another embodiment the platform is provided with additional buoyant or flotation devices or means so that when submerged by flooding it will move to a 20 dynamically stable submerged position without excessive distortion or tipping. <br><br> In another aspect of the present invention, the flotation devices are secured to the platform for supporting the platform when the reflectors are submerged beneath fluid 25 from the reservoir, and wherein the buoyancy of the flotation devices per unit height increases from bottom to top of the flotation devices. <br><br> In still another aspect of the present invention, the apparatus collects solar energy and the drive or pivoting means 30 pivots the platform to track movement of the sun. <br><br> In yet another aspect of the present invention, the concentrators are a plurality of parallel and elongated reflectors supported on the platform, where each reflector is parabolic to concentrate solar energy on a horizontal focal 35 line, and the energy collectors are supported at the focal lines of the reflectors. Each parabolic reflector is preferably constructed of a plurality of parallel elongated <br><br> * 24450 <br><br> reflective elements, such as mirrors which may be arcuate or flat in cross section. Where used on a body of liquid, the platform is preferably constructed of a flexible buoyant material so that it will conform to the flat surface of the 5 liquid which forms a planar datum plane so that the reflectors will be maintained focussed on their associated collectors. <br><br> In another aspect of the present invention, fluid feed impellers are supported beneath the platform within the reservoir and communicate with ports through the platform for 10 pumping fluid onto the platform and reflectors. In still another aspect of the present invention, opposing fluid impellers are associated with each fluid feed impeller, the opposing impellers being operable with the feed impellers to force fluid in an opposing direction to the feed impellers, 15 with deflectors being disposed between the feed impellers and the opposing impellers. <br><br> In yet another aspect of the present invention, a duct is associated with one or both impellers and is configured so as to direct fluid adjacent one or both impellers in a vertical 20 direction and direct fluid at the other end at least partially in a horizontal direction. <br><br> It is an object of the present invention to provide a radiant energy collecting apparatus which may be easily and inexpensively constructed and operated. <br><br> 25 It is another preferred object of the invention to provide a radiant energy collecting apparatus in which the concentrators may be maintained in alignment with their associated collectors. <br><br> It is another preferred object of the present invention 30 to provide a radiant energy collecting apparatus in which the solar concentrators may be easily maintained in alignment with the sun. <br><br> It is still another preferred object of the present invention to provide a radiant energy collecting apparatus 35 which may be simply protected in adverse weather conditions or otherwi se. <br><br> It is yet another preferred object of the present <br><br> 2 4 4 <br><br> invention to provide a radiant energy collecting apparatus which may be simple and easily assembled for collecting radiant energy over large surface areas. <br><br> Still another preferred object of the present invention 5 is to provide an inexpensive radiant energy collecting apparatus which is protected against breaking or other degradation which can result from excessive distortion. <br><br> Brief Description of the Drawings <br><br> A preferred embodiment of the invention will now be 10 described with reference to the drawings in which:- <br><br> Fig. 1 is a plan view of one form of solar energy collecting apparatus according to the present invention; <br><br> Fig. 2 is a schematic plan view of the apparatus showing details of the floatation control system for the 15 apparatus; <br><br> Fig. 3 is a sectional elevation of the apparatus along 1ine A-A of Fig. 2; <br><br> Fig. 4 is a plan view of one concentrating mirror system for use in the apparatus; <br><br> 20 Fig. 5 is an end view of the system shown in Fig. 4; <br><br> Fig. 6 is a side elevational view of the system of Figs 4 and 5; <br><br> Fig. 7 is a plan view showing a buoyant support system for the platform; and 25 Fig. 8 is a sectional view along line B-B of Fig. 7. <br><br> showing the platform submerged. <br><br> Fig. 9 is a plan view of one large raft system of ten individual parallel parabolic mirror systems in which the individual mirrors and overhead superstructure have been 30 omitted for clarity; <br><br> Fig. 10 is a sectional elevational view of the raft system along lines C-C of Fig. 9 and Fig. 11; <br><br> Fig. 11 is a partial plan view of the raft and mirror system as depicted in Fig. 9 and in the general area of view 35 C-C of Fig. 9; <br><br> Fig. 12 is a side elevation of a water impeller assembly with the present invention; <br><br> 4 <br><br> Fig. 13 is a partial plan view of the raft and mirror systems including the impeller assembly of Fig. 12; and <br><br> Fig. 14a-c are end elevation, inverted plan, and side elevation views, respectively, of one of the flotation 5 blocks illustrated in Fig. 10. <br><br> Description of the Preferred Embodiment <br><br> Referring to the drawings and firstly to Figs. 1 to 3, there is illustrated solar energy collecting apparatus 10 according to one preferred form of the present invention, 10 including a circular water container or reservoir 11, which may for example comprise a pond or a dam or a purpose built container, including an outer wall 12 which encloses and contains water within the container 11. A platform 13 is located within the conJ:iiner 11 so as to float on water 14 15 contained therein which is at the level 15. The platform 13 may be constructed of a buoyant material such as a foam plastics material or be mounted on a layer of such material. Alternatively, the platform 13 may be formed with sealed air reservoirs or provided with other means to make it buoyant. 20 A hoop 16 is attached to or formed integrally with the platform 13 so as to form a generally water tight skirt around the outer diameter of the platform 13, the hoop 16 extending below the underside of the platform 13. <br><br> As shown in Figs. 2 and 3, a trench 17 is constructed 25 in the base 18 of the container 11 and is generally continuous around the container 11 so as to be of annular form. The outer diameter of trench 17 is less than the diameter of the hoop 16 thus forming a land 19 on which the hoop 16 will rest when water is withdrawn from the container 11. <br><br> 30 Guide rollers 20 are mounted around the inside diameter of the container walls 12 so as to maintain the relative position of the platform 13 by pressing against the hoop 16. One or more of the rollers 20 may be motor driven to conveniently rotate the platform 13 to control the alignment 35 of the solar energy collecting apparatus 10 with the sun. <br><br> One or more outlet pipes 21 are connected to suitable pump and valve units 22 to allow water to be pumped out from <br><br> ? 4 4 S 9 4 <br><br> 8 <br><br> under the platform 13 to above the platform 13 by flow through outlets 24 or to an auxiliary water storage pond (not shown), via pipes 23. The water flow rates and directions can be controlled by the pump valve units 22. The base 18 of the 5 container 11 is also provided with a trough 25, the trough 25 communicating with the pump valve units 22 via a pipe 26. <br><br> Supported on the platform 13 are a plurality of solar concentrators 27 arranged as shown in Fig. 1 in a side-by-side attitude and each comprising as shown more clearly in Figs. 4 10 and 5 a series of parallel mirrors 28 either of curved form or planar form and angled so as to act as and define one large elongated parabolic mirror. These mirrors 28 are arranged to focus the sunlight onto an overhead energy collector pipe 29, such as a black pipe, the collector pipe 29 being mounted on 15 a suitable frame 30 of triangular form above the mirrors 28. The collector pipes 29 are suitably coupled together to allow for the collection of the heat energy in a known manner and subsequent utilization in any manner common to the trade, such as an energy supply for a steam turbine driven electricity 20 generating plant. For this purpose, the collector pipes 29 may carry a heat or energy absorbing medium such as heat absorbing oil. The collector pipes 29 of the respective concentrators 27 may be coupled together for example through a manifold and the heated medium conveyed by the pipes 29 used for steam 25 generation purposes. Alternatively, the medium carried by the collection pipes may be circulated in a closed system and heat exchangers used to extract the heat from the medium. <br><br> To compensate for slight errors in the alignment of the concentrating mirrors 28, an arcuate reflector 31 is positioned 30 above the collecting pipe 29 and so formed so as to act as a non-imaging optical concentrator. <br><br> To improve heat collection from elements of the frame 30 and other components of the structure which may intercept the radiant energy which would otherwise directly impinge upon 35 the concentrating mirrors 28, mirrored or reflective surfaces 32 (see Fig. 6) are attached to or may form part of such components, the surfaces 32 being set substantially at 90 <br><br> ?4 4 £ $ 4 <br><br> &lt;1uv J * W <br><br> 9 <br><br> degrees to the focus line of the mirrors 28 to cause the radiant energy of the sun to reflect therefrom onto the mirrors 28 and thence to focus onto the collector pipe 29 or reflector 31 as indicated by the arrows in Fig. 6. <br><br> 5 The platform 13 in its preferred form is constructed of a flexible buoyant material such as a lightweight thin foamed plastics material. The platform 13 when floating will thus maintain a flat planar attitude due to its being flexible and conforming to the flat surface of the liquid upon which it 10 is floating. The concentrating mirrors 28 will thus maintain a correct focussed or substantially focussed attitude relative to their associated collector pipes 29. Any movement of the platform say due to wave motion will result in a corresponding movement of the collector pipes 29 so they remain at or 15 substantially at the focus of their associated mirrors 29. Use of a lightweight flexible buoyant material for the platform 13 significantly reduces the cost of the system whilst ensuring that the mirrors are maintained in alignment with their collectors. <br><br> 20 As stated above, to cause rotation of the platform, one or more of the rollers 20 may be motor driven. For this purpose, one of the rollers 20' may be coupled through a belt 33 to a drive roller 34 which is adapted to be driven by a servomotor or other actuating means 35. Actuation of the 25 servomotor 35 is controlled by a tracking apparatus 36 of any known type such as apparatus which employs phototransistors or other light sensitive means and a shading member which creates a shadow over the light sensitive means in accordance with their alignment with the sun. Of course, many different 30 alternative systems may be employed for controlling or causing movement of the platform 13 in accordance with movement of the sun such as a timing system. <br><br> In use, when the sun rises in the East, the tracking apparatus 36 will cause through the servomotor or other 35 actuating means 35, drive pulley 34, belt 33, and wheel 20' rotation of the floating platform 13 to move the concentrators 27 so that their longitudinal axes are directed towards the <br><br> 10 <br><br> sun's longitudinal meridian at the horizon. Thus the longitudinal axes of the concentrators 27 lie in vertical planes which intersect the sun. As the sun moves across its arc, its change in longitudinal meridian at the horizon will 5 be tracked by the concentrators 27 with the platform 13 floating on the liquid 14 in the container 11 and carrying the concentrators 27 being rotated by its drive system so that the longitudinal axes of the concentrators 27 remain aligned with the sun. Thus at all times when the sun is up, the collection 10 apparatus 10 is exposed to maximum radiant energy from the sun to thereby maximize energy collection. The use of the floating platform 13 allows for easy and convenient movement of the apparatus 10 to achieve and maintain alignment of the concentrators 27 with the sun. <br><br> 15 Should a risk of hail or similar damaging weather phenomena look imminent, then pump 22 is turned on and water is pumped at high volume from the water container 11 to the storage pond causing the platform 13 to lower. The bottom of the skirt or hoop 16 will then come in contact with the base 20 land 19 of the container 11 to produce a general sealing effect. A slight pressure reduction will then occur under the whole platform at which time water is then caused to flow out through pipe 24 to the area above the platform 13. The pressure reduction under the platform 13 is maintained 25 sufficiently to prevent the platform 13 from tending to float up above the water being pumped in at 24 so that the water covers the platform 13 and associated solar concentrators 27 to prevent damage thereto. <br><br> Alternatively, rather than rely on the pressure 30 reduction under the platform 13 to maintain it submerged, mechanical means may be employed for this purpose. For example, holding pins or members mounted to the outer wall 12 of the container 11 may be extended inwardly after platform submergence to maintain the solar concentrators 27 submerged 35 and the reflective surfaces or mirrors 28 of the concentrators 27 protected. To permit the platform 13 to again float, the pins or members may be withdrawn. As yet another alternative, <br><br> 11 <br><br> the platform may be provided with one or more air chambers or reservoirs which may be filled with water to sink the platform or filled with air to enable the platform to float. <br><br> Water may be directed back to the container 11 by 5 directing the water through pipe 26 into the trough 25. As a degree of flexibility will exist in platform 13, directing water to the trough 25 positioned centrally under the platform 13 will cause the central area of the platform to become slightly elevated and thus ensure efficient and rapid draining 10 of water when re-exposure of the concentrators 17 to the sur. is required. <br><br> Figs. 7 and 8 illustrate a buoyant support system for the platform 13 when the latter is arranged on a large body of water, such as on a lake, bay, river or the like, the 15 platform 13 including as before a plurality of side-by-side concentrators 27, only one of which is fully shown. The platform 13 in this embodiment is provided about its periphery with an upstanding rim 37 which terminates at its upper edge in a buoyant member, or alternatively a series of buoyant 20 members 38. In the embodiment illustrated the member 38 is of annular form and may comprise foam plastics material which extends fully about the rim 37. Further buoyant members 39 may be associated with each parabolic concentrator 27 and located at the central normally shaded portion of the concentrators 27. 25 Preferably the members 39 are mounted on stems 40 so as to be spaced from the concentrators mirrors 28. The members 39 preferably comprise elongated lengths of foam plastics material and the stems 40 rigidly support the members 39. Alternatively, the stems 40 may comprise short lengths of wire or other 30 flexible attachment means. <br><br> Where it is desired to sink the platform 13 as shown in Fig. 8 in say inclement weather conditions, water is simply pumped onto the top surface thereof by any suitable means, such as a conventional pump. Alternatively, the platform 13 may be 35 provided with one or more water supply and drainage assemblies 41 as shown in Fig. 8. Each assembly comprises an opening 42 through the platform 13 aligned with an annular skirt 43 which <br><br> 2 -v 4 9 4 <br><br> 12 <br><br> extends to the underside of the platform 13. Arranged within the skirt 43 ana submerged in the liquid within the skirt 43 is an impeller 44 coupled to a drive motor 45 supported in any suitably fashion such as by a gantry 46 on the top side of the 5 platform 13. When the motor 45 is driven in a first direction, water will be forced from the underside of the platform 13 to the topside thereof through the skirt 43 and opening 42. When it is desired to drain the platform 13, the motor 45 is driven in the opposite direction to cause reverse 10 rotation of the impeller 44 and water to be pumped out through the opening 42. <br><br> Water pumped onto the platform 13 will be contained thereon by the rim 37 so that the platform 13 will begin to sink. Should the sides of the platform 13 tend to sink first 15 they will be supported by the buoyant rim member 38. Water can be continued to be pumped over the platform 13 to submerge the concentrators 27 until a dynamically stable equilibrium is achieved with the regions of the platform 13 between the rim 37 being supported by the buoyant members 39. The platform 13 20 will again rise to the surface of the body of water so as to expose the concentrators 27 to the sun after the water contained by the rim 37 is drained. <br><br> Referring now to Fig. 9, there is illustrated an alternative form of the invention in plan view comprising a 25 typical raft in which the plurality of individual reflector mirrors and the overhead solar collecting systems and their mountings have been omitted. These elements are illustrated in Fig. 10 which shows the buoyant raft 52 in which grooves or flats 5 3 have been formed at varying angles and on which flat 30 strips of mirrors 54 are attached. These mirrors 54 and their allied grooves are set at such an angle as to concentrate the rays of radiant energy (typically sunlight) 55 onto a solar collecting pipe 56. Further, should the alignment of the mirrors 54 be slightly inaccurate, the sunlight rays 55 will 35 impinge on reflecting screen 57 and in turn onto the solar collecting pipe 56. <br><br> The solar collecting pipe 56 and reflecting screen 57 are mounted on a suitable frame 58 which is in turn mounted <br><br> directly to the raft 52. Alternatively, the frame 58 can be indirectly mounted to the raft, as for example by mounting the frame 58 to the flotation blocks 59 which themselves are mounted directly to the raft 52. <br><br> 5 In normal operation, the raft 52 would float in a reservoir with a relative water level as indicated by reference number 61. (Of course, the reservoir could be any suitable large body of water, whether an artificial pool, a natural bay, an estuary or a dam. <br><br> 10 If weather conditions indicate that the mirrors 54 <br><br> should be protected from possible damage by hail, then water from the reservoir is pumped by suitable means onto the top surface of the floating raft 52. <br><br> The outer diameter of the raft 52 (or the outer edge 15 should it not be a round configuration) has attached to it or forming part of the raft 52 a small wall defined by the flotation block 59 composed of a suitable flotation medium such as foamed polystyrene. Also mounted on and rigidly attached to the raft 52 along their length are additional longitudinal 20 flotation blocks 60. These flotation blocks 60, as best illustrated in Figs. 14a-c, have cut outs or slots 63 in their lower surface (see also Fig. 11). <br><br> Further, it should be understood that while the raft 52 may itself be unitary, it is also within the scope of the 25 present invention to form large rafts 52 by combining long parallel individual raft structures, which can be attached together in any suitable manner, as shown for example at reference numeral 64 in Fig. 10. <br><br> Located within the general area of the raft 52 and 30 attached thereto adjacent spaced shrouded ports 70 through the platform 52 are impellers 65 and 66 mounted on a drive shaft 67 which is driven by a suitable motor 68 itself suitably mounted, as by the bracket 69 shown, to the raft 52 (see Figs. 12 and 13). The upper impeller 65 and lower impellers 66 35 preferably have an opposite pitch to their blades for a purpose to be described hereafter. <br><br> The ports 70 are located in the base of the raft 52 so <br><br> 24 4 b <br><br> 14 <br><br> as to permit the flow of water from under the raft 52 through to above the raft 52, and vice versa. In the preferred embodiment as shown in Fig. 12, the raft 52 is itself made of a sufficiently buoyant material so that it will support the 5 entire apparatus with the mirrors 54 above the water level. Therefore, the ports 70 can be open as shown. <br><br> If, alternatively, the raft 52 requires additional buoyancy to maintain the mirrors 54 above the water level during normal operation, the raft 52 can be configured much 10 like a boat with an outer rim enclosing a volume which will displace sufficient fluid so that the water level around the raft will not rise above the top of the rim (and thus, the mirrors 54 will not necessarily be covered with fluid even though they may be disposed at a lower level than the fluid 15 level around the raft). In this alternative embodiment, the ports would preferably be closed during normal operation. This could be accomplished by providing suitably controlled valving to open or close the ports as required during operation. <br><br> Additional ducting or shrouding 71 may also be included 20 to assist the directional flow of the water, the ducting 71 being located intermediate the impellers 65 and 66. Another ducting system 72 is preferably provided adjacent one or more lower impellers 66, which ducting system 72 is suitably mounted so as to direct the vertical flow of water through impeller 66 25 into a horizontal flow so as to permit the movement of the raft 52 to be controlled. Control can be accomplished in this manner by providing a single ducting system 72 which can be selectively directed, or alternatively can be accomplished by providing the system with multiple impellers 66, each directed 30 differently, with movement then being controlled by operating only selected impellers. <br><br> Of course, it would be within the scope of at least one aspect of the present invention to provide an external drive for the raft 52. For example, if the raft 52 were located in 35 a pool where it could reliably be positioned adjacent a side of the pool, movement of the raft 52 to follow the movement of the sun could be accomplished by a suitable drive at the side <br><br> 15 <br><br> of the pool arid engaging the raft, as shown for example in the above described embodiment of Figs. 2 and 3. <br><br> Operation of the above described preferred embodiment of the apparatus is thus as follows. <br><br> 5 In normal operation, when the mirrors 54 are exposed to the sun, the relative water level between the raft 52 and the reservoir in which the raft 52 is floating would be as indicated at reference numeral 61. Orientation of the raft 52 can be suitably controlled in response to the condition of the 10 sun, as previously described, by the ducting 72. <br><br> Should weather conditions indicate the possibility of damage to the mirrors 54 caused by such things as hail, then the motors 68 would be activated so to force water in the reservoir up through ports 70 onto the top surface of the 15 raft 52. <br><br> The natural tendency is for water to concentrate in particular areas so that the raft 52 would be submerged to a greater extent at the location of the ports 70, with the mirrors 54 in other, higher, areas thereby still exposed to 20 danger from the weather. However, the construction of the flotation blocks 59, 60 are such that they generally taper from their base to a wider section at their top. This tapered configuration causes the concentration of water in any particular area to spread out over the surface of the raft and 25 ensure that an even depth of protective water will be provided over all of the mirrors 54. Thus, the mirrors 54 would all be reliably protected by water at a level such as indicated by reference numeral 62 in Fig. 10. In fact, the tapered configuration of the flotation blocks 59, 60 ensures that a 30 consistent and even depth of water is maintained throughout the flooding process. (Further, the even flooding of water over the raft 52 is assisted by the openings 63 cut into the bottom of the flotation blocks 59, 60, which openings 63 permit the water being pumped onto the raft 52 to circulate over the 35 entire raft 52). <br><br> It should also be understood, however, that the flotation blocks 59, 60 could alternatively provide the desired <br><br> 16 <br><br> graduated buoyancy by being stepped rather than continuously tapered or tapered on one side only. In such a configuration, however, it is highly preferred that the horizontal cross-sectional area of the flotation blocks be equal one with 5 another at any particular distance from the raft 52. <br><br> Throughout the period of risk to the mirrors 54, the motor 68 would be kept operating at sufficient speed so that the upper impellers 65 would maintain the level 62 of protective water over the mirrors 54. <br><br> 10 At the cessation of the risk to the mirrors 54, the motor 68 may be turned off. Due to the natural buoyancy of the raft 52, stopping the impeller 65 will permit a reverse flow back out through ports 70, so that the raft 52 will eventually refloat itself with the mirrors 54 uncovered and thus again be 15 operable to reflect solar energy to the collecting pipe 56. Further, in the preferred embodiment, the attachment of the individual sections forming the raft 52 (as shown at reference numeral 64) is generally such that leakage could occur therethrough as well (although such leakage should obviously 20 be minimized sufficiently that the impellers 65 will be able to maintain the water at the desired level 62 during the weather period when the mirrors 54 require protection). Of course, it should also be appreciated that the operation of the flotation blocks 59, 60 in maintaining a level surface over the 25 raft 52 will further assist in preventing pockets of water from being trapped on the raft 52 and thereby inhibiting the efficient operation of the apparatus. <br><br> Of course, to accelerate the flotation process, the motor 68 could be reversed causing the impeller 65 to force a 30 downward flow of water through port 70. Such an operation would also be used with the previously described alternative embodiment of the present invention (that is, where the raft is configured as a boat), where the impeller 65 would thus function as a sump pump to remove the water from the raft. 35 During the operation of the impellers 65, the flow of water up through the ports 70 can tend to locally submerge the raft in the area adjacent to the ports 70 and impellers 65. <br><br> 2 4 4 * 4 <br><br> 17 <br><br> The opposite pitch of the other impellers 66 rotating on the same drive shaft 17 prevents this operation however, by causing a counterbalancing upward force. By suitably selecting relative pitch and blade areas of t,he associated impellers 65, 5 66, the raft 52 can reliably be maintained in a level configuration despite the forces resulting from pumping fluid onto the raft during inclement weather. <br><br> Of course, if opposite rotation of the impellers 65, 66 is desired during removal of the water from the raft 52 10 following inclement weather, the vertical forces introduced by the two impellers 65, 66 reverse, with the bottom impellers 66 thereby providing counterbalancing forces which prevent the raft 52 from raising up at the location of the ports 70 (which configuration would undesirably tend to concentrate the fluid 15 on the raft 2 in low areas away from the ports 70). <br><br> Of course, because of the opposite action of the coaxial impellers 65, 66, the additional ducting 71 desirably operates to separate the opposing flow of fluid generated by their rotation. <br><br> 20 The present invention thus provides a solar energy collecting apparatus which is relatively inexpensive to construct and provides an efficient system for maximizing radiant energy received from the sun. The apparatus may be constructed of inexpensive and readily available materials and 25 of a large size to suit commercial power generation purposes. Alternatively, the apparatus of the invention may be adapted for single household use. Whilst the solar concentrators and collectors have been described to be normally substantially horizontal, they may in some circumstances be inclined to the 30 horizontal but still lie in use at right angles to vertical planes intersecting the sun. <br><br> Further, it should be understood that while the apparatus of the invention is particularly suited for collection of solar heat energy, the apparatus may also collect 35 other forms of radiant energy which may be concentrated. <br><br> The liquid upon which the platform is supported for floating movement is preferably arranged within a reservoir, <br><br> 9 /• L '' <br><br> L ■t 1 - <br><br> 18 <br><br> however, the liquid may comprise any other body of liquid such as water in a river, sea or other storage container. <br><br> Thus while the above has been given by way of illustrative embodiment of the invention, all such 5 modifications and variations thereto as would be apparent to persons skilled in the art are deemed to fall within the broad scope and ambit of the invention as herein set forth in the appended claims. <br><br> 15 <br><br> 20 <br><br> 25 <br><br> 30 <br><br> 35 <br><br></p> </div>

Claims (25)

<div class="application article clearfix printTableText" id="claims"> <p lang="en"> Ik 4 C<br><br> 19<br><br> WHAT I CLAIM IS;-<br><br>
1. A radiant energy collecting apparatus, comprising:<br><br>
a fluid reservoir;<br><br>
a platform floating on fluid in said fluid reservoir; 5 means for moving said platform within said reservoir;<br><br>
radiant energy collectors supported on said platform; means on said platform for concentrating radiant energy on said radiant energy collectors; and means for selectively submerging said concentrating 10 means beneath fluid from said reservoir for protection against inclement weather conditions.<br><br>
2. The apparatus of Claim 1, wherein the submerging means comprises:<br><br>
15 means for pumping fluid onto said platform; and means for maintaining said fluid on said platform and over said concentrating means.<br><br>
3. The apparatus of Claim 2, wherein said maintaining 20 means comprises means for establishing a low pressure beneath said platform to secure said platform beneath the level of fluid pumped into the reservoir.<br><br>
4. The apparatus of CI<br><br>
25 maintaining means comprise beneath said platform within impellers communicating with iim 2, wherein said pumping and fluid feed impellers supported said reservoir, said fluid feed ports through said platform.<br><br>
5. The apparatus of Claim 4, further comprising:<br><br>
30 opposing fluid impellers associated with each fluid feed impeller, said opposing impellers being operable with said feed impellers to force fluid in an opposing direction to said feed impellers; and deflectors between said feed impellers and said opposing 35 impellers.<br><br>
6.<br><br>
The apparatus of Claim 5, wherein said feed impellers<br><br>
20<br><br>
244994<br><br>
have an opposite pitch from said opposing impellers, and associated feed impellers and opposing impellers are secured to and axially spaced on common vertically oriented drive shafts.<br><br>
5
7. The apparatus of Claim 4 wherein said moving means comprises a duct associated with at least one impeller and connecting two duct openings, said duct directing fluid through an opening adjacent the at least one impeller in a vertical direction and directing fluid through the other opening at 10 least partially in a horizontal direction.<br><br>
8. The apparatus of Claim 1 wherein said platform is sufficiently buoyant to support the concentrating means above the fluid level in the reservoir.<br><br>
15<br><br>
9. The apparatus of Claim 8 wherein the submerging means comprises:<br><br>
means for pumping fluid onto said platform; and means for maintaining said fluid on said platform 20 and over said concentrating means.<br><br>
10. The apparatus of Claim 9 wherein said pumping and maintaining means comprise fluid feed impellers supported beneath said platform within said reservoir, said fluid feed<br><br>
25 impellers communicating with ports through said platform.<br><br>
11. The apparatus of Claim 10 further comprising:<br><br>
opposing fluid impellers, each associated with a respective fluid feed impeller, said opposing impellers being<br><br>
30 operable with said feed impellers to force fluid in an opposing direction to said feed impellers; and deflectors between said feed impellers and said opposing impellers.<br><br>
35
12. The apparatus of Claim 11 wherein said feed impellers have an opposite pitch from said opposing impellers, and<br><br>
•V<br><br>
10<br><br>
21<br><br>
244 9 9 4<br><br>
associated feed impellers and opposing impellers are secured to and axially spaced on common vertically oriented drive shafts.<br><br>
13. The apparatus of Claim 10 wherein said moving means comprises a duct associated with at least one impeller and connecting two duct openings, said duct directing fluid through an opening adjacent the at least one impeller in a vertical direction and directing fluid through the other opening at least partially in a horizontal direction.<br><br>
14. The apparatus of Claim 1 wherein:<br><br>
the platform includes a rim therearound for separating fluid in the reservoir from the concentrating means on the platform; and 15 the submerging means comprises a fluid impeller secured to said collecting apparatus and selectively operable to move fluid between the reservoir and the apparatus.<br><br>
15. The apparatus of Claim 1 further comprising<br><br>
20 flotation devices secured to said platform for supporting said platform when said concentrating means are submerged beneath fluid from said reservoir.<br><br>
16. The apparatus of Claim 15 wherein the buoyancy of<br><br>
25 the flotation devices per unit height increases from bottom to top of said flotation devices.<br><br>
17. The apparatus of Claim 16 wherein said flotation devices are elongate and secured to said platform along their<br><br>
30 length, said devices being tapered outwardly from a narrow bottom side adjacent said platform to a wide top side.<br><br>
18. The apparatus of Claim 1 wherein said concentrating means comprises reflectors positioned to reflect solar energy<br><br>
35 toward said collectors.<br><br>
. f ' •- ■<br><br>
»:!<br><br>
244994<br><br>
19. The apparatus of Claim 18, wherein each reflector is parabolic with a focal point and the collectors are supported substantially at the focal point of one of the reflectors.<br><br>
5 20. The apparatus of Claim 1 wherein said concentrating means comprises a plurality of side-by-side elongated reflector elements defining a substantially parabolic reflecting trough.<br><br>
21. The apparatus of Claim 20 wherein said collectors 10 comprise elongated pipes carrying an energy transfer medium.<br><br>
22. The apparatus of Claim 20 wherein said collectors are supported by a framework at a spaced position from said reflector elements substantially at the focus of the defined<br><br>
15 parabolic reflecting trough, said framework further including reflectors to direct radiant energy toward the collectors.<br><br>
23. A solar energy collecting apparatus comprising: a fluid reservoir;<br><br>
20 a platform floating on fluid in said fluid reservoir;<br><br>
means for moving said platform within said reservoir to track movement of the sun;<br><br>
a plurality of substantially parallel and 25 longitudinal reflectors supported on the platform, each reflector being substantially parabolic to concentrate solar energy on a substantially horizontal focal line;<br><br>
solar energy collectors supported at the focal lines of the reflectors; and 30 means for selectively submerging said reflectors beneath the fluid for protection against inclement weather conditions, including a pump for pumping fluid from the reservoir onto said platform, and means for maintaining the platform beneath the fluid level of the reservoir.<br><br>
35<br><br>
24. A radiant energy collecting apparatus comprising:<br><br>
a fluid reservoir;<br><br>
a platform floating on fluid in said fluid reservoir;/% ^<br><br>
V *<br><br>
"7 Mar<br><br>
1395<br><br>
2449<br><br>
23<br><br>
means for moving said platform within said reservoir;<br><br>
radiant energy collectors supported on said platform;<br><br>
5 means on said platform for concentrating radiant energy on said radiant energy collectors;<br><br>
means for pumping fluid onto said platform for selectively submerging said concentrating means beneath fluid from said reservoir for protection against inclement weather 10 conditions;<br><br>
fluid feed impellers supported beneath said platform within said reservoir, said fluid feed impellers communicating with ports through said platform;<br><br>
flotation devices secured to said platform for 15 supporting said platform when said concentrating means are submerged beneath fluid from said reservoir, the buoyancy of the flotation devices per unit height increasing from bottom to top of said flotation devices.<br><br>
20
25. The apparatus of Claim 24 further comprising:<br><br>
opposing fluid impellers each associated with a respective fluid feed impeller, said opposing impellers being operable with said feed impellers to force fluid in an opposing direction to said feed impellers; and 25 deflectors between said feed impellers and said opposing impellers.<br><br>
26. The apparatus of Claim 25 wherein said feed impellers have an opposite pitch from said opposing impellers,<br><br>
30 and associated feed impellers and opposing impellers are secured to and axially spaced on common vertically oriented drive shafts.<br><br>
27. The apparatus of Claim 24 wherein said moving means 35 comprises a duct associated with at least one impeller and connecting two duct openings, said duct directing fluid through an opening adjacent the at least one impeller in a vertical direction and directing fluid through the other<br><br>
• L. ''r C'rHjCc<br><br>
244944<br><br>
24<br><br>
opening at least partially in a horizontal direction.<br><br>
28. The apparatus of Claim 24 wherein said platform is sufficiently buoyant to support the concentrating means above<br><br>
5 the fluid level in the reservoir.<br><br>
29. The apparatus of Claim 24 wherein said flotation devices are elongate and secured to said platform along their length, said devices being tapered outwardly from a narrow<br><br>
10 bottom side adjacent said platform to a wide top side.<br><br>
30. A radiant energy collecting apparatus substantially as hereinbefore described with reference to Figs. 1 to 6, Figs. 7 &amp; 8, or Figs. 9 cto 14 of the<br><br>
15 accompanying drawings. (, \ |\<br><br>
• •••• • »••••••<br><br>
ALLAN JAMfeS1YBOMANS<br><br>
N.Z. PATENT OFFICE<br><br>
12 J UN 1995 .f L :r : '™^!VED "<br><br>
</p>
</div>
NZ244994A 1991-11-06 1992-11-02 Radiant energy collecting apparatus with movable floating platform on fluid reservoir being submersible during bad weather NZ244994A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AUPK931391 1991-11-06
AUPL253692 1992-05-21

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AT (1) ATE153750T1 (en)
AU (1) AU671423B2 (en)
BG (1) BG61823B1 (en)
DE (1) DE69220081D1 (en)
ES (1) ES2103971T3 (en)
NZ (1) NZ244994A (en)
OA (1) OA09936A (en)
RO (1) RO116981B1 (en)
RU (1) RU2109227C1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AUPO429396A0 (en) * 1996-12-20 1997-01-23 Solsearch Pty Ltd Solar energy collector system
NL1014175C2 (en) 2000-01-25 2001-07-26 Oldelft B V Ultrasound probe.
AU2003902656A0 (en) * 2003-05-29 2003-06-12 Connor, Philip Michael Collector for solar radiation
EP2233738A4 (en) 2008-12-29 2013-09-25 Kiknadze Gennady Iraklievich Converter and an energy conversion method, a torque flow pump and a turbine

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RU2109227C1 (en) 1998-04-20
RO116981B1 (en) 2001-08-30
AU2674592A (en) 1993-06-07
AU671423B2 (en) 1996-08-29
DE69220081D1 (en) 1997-07-03
OA09936A (en) 1994-11-15
BG98792A (en) 1995-05-31
JPH07500901A (en) 1995-01-26
BG61823B1 (en) 1998-06-30
ATE153750T1 (en) 1997-06-15
JP3131220B2 (en) 2001-01-31

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