NZ237014A - Treating wool by oxidation, resin and softening treatments to improve shrink resistance - Google Patents
Treating wool by oxidation, resin and softening treatments to improve shrink resistanceInfo
- Publication number
- NZ237014A NZ237014A NZ237014A NZ23701491A NZ237014A NZ 237014 A NZ237014 A NZ 237014A NZ 237014 A NZ237014 A NZ 237014A NZ 23701491 A NZ23701491 A NZ 23701491A NZ 237014 A NZ237014 A NZ 237014A
- Authority
- NZ
- New Zealand
- Prior art keywords
- resin
- treatment
- process according
- wool
- silicone polymer
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Description
New Zealand Paient Spedficaiion for Paient Number £37014
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237 0 1
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Patents Form No. 5
TREATMENT OF WOOL
WE, BIP CHEMICALS LIMITED/ a British company of 20 St Mary's Parsonage, Manchester M3 2NL, ENGLAND
hereby declare the invention, for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following statement:
(followed by page la)
- I a —
237 0
TREATMENT OF WOOL
This invention relates to the treatment of wool, and is particularly concerned with a process for improving its resistance to shrinkage.
A process very widely used for this purpose entails W subjecting the wool to an oxidation treatment, usually a chlorination, as with free chlorine or a hypochlorite or dichloroisocyanurate salt; removing unreacted (and potentially very damaging) oxidising agent from the wool fibres, as by passage through a reducing medium such as sodium sulphite solution, followed by a water rinse; and then treating the wool with a synthetic resin to impart a resistance to shrinkage which supplements that given by the oxidation treatment. Usually thereafter, but sometimes simultaneously with the resin treatment, the wool is treated with a softening agent to soften the harsh handle which it would otherwise have as a result of the
237 0
2 -
resin treatment; and in due course the treated wool is dried evenly at a moderately raised temperature to ensure that adequate curing of the resin has taken place.
The process just outlined can be applied to the treatment of wool tops (ie wool fibre before it is spun) as well as to the treatment of yarn and of woollen piece goods and garments.
Probably the resins most used in the process are those obtained by reaction of epichlorhydrin (a compound having a reactive epoxy group attached to the radical -CH^Cl) with a poiyamide whose repeating unit contains basic -NH-or -NH2 groups, as distinct from the non-basic -NH- groups of the amide linkage -CO.NH-. Such a resin is for example that obtained by the reaction of epichlorhydrin with the condensation product of a polyalkylene amine eg triethylene diamine (H2NCH2CHxNHCH2CH2NHi) and adipic acid (HOiC.CHjjCH^CH^CH^COiH). Not all such resin is exhausted onto the wool from whatever medium the epichlorhydrin resin is applied, and there is now strong evidence that the resin-containing aqueous effluent from the process is harmful because of the presence in it of chlorine covalently bound to carbon, as in the -CH^Cl group.
23 7 0 1 .-
We have now found that effluent problems can be greatly reduced, and a treated wool product obtained with properties just as good as those that result when an epichlorhydrin resin is employed, by using a colloidal melamine resin as the resin to impart shrinkage. Colloidal melamine resins are used in the treatment of paper to improve its wet strength, and are obtained by dissolving a partially condensed melamine formaldehyde resin in an acid such as hydrochloric, formic, acetic or lactic acid under controlled conditions, and further diluting with water. The solution becomes infinitely miscible with water, and on aging develops a bluish haze. The solution contains positively charged colloidal particles of the melamine resin.
fw^ According to the invention, there is provided a process for the treatment of wool to improve its resistance to shrinkage, by subjecting it first to an oxidation treatment and then to a resin treatment to supplement the shrink resistance imparted by the oxidation treatment, the resin treatment being accompanied or followed by treatment with a softening agent to soften the harsh handle associated with use of the resin, in which process the resin employed is a colloidal melamine resin and the softening agent employed is a silicone polymer.
237 0 1
Preferably, the silicone polymer is dispersed in the colloidal melamine resin,ie in the aqueous phase which constitutes the dispersion medium of that system.
There is described in EP-A-80272 a process for the shrink-resist treatment of wool, by a chlorinating the wool with an acidified hypochlorite b removing excess chlorinating agent from the wool c applying to the acidified wool an acid colloid solution of a methylol melamine resin, which solution may contain a suitable softening agent, such as for example those of the polyethylene type.
EP-A-80272 is not, however, concerned to avoid effluent problems arising from the presence of -CH^Cl or like groups in the resin conventionally used for wool treatment; nor does it mention the use of a silicone polymer as softening agent, a use which we have found has the advantage over polyethylene softeners of producing in the wool better stabilisation against shrinkage and better non-felting properties during washing.
The silicone polymer employed as softening agent may be cationic, but is preferably non-ionic. In general the
237 0 1
0
silicone polymer used shows no chemical reactivity towards the colloidal melamine resin.
The melamine resin employed is preferably one which has at least two -CH^OR groups per melamine nucleus, where R = H or is an alkyl group containing from one to four carbon atoms.
The invention is further illustrated by the following Examples.
Example 1
An acidic melamine resin solution was produced by mixing the following ingredients in the following proportions by weight.
Aqueous solution (80% reactive solids;
pH at 1:1 HzO dilution=8.5) of partially condensed melamine formaldehyde resin available as BEETLE8 336
10kg
Concentrated hydrochloric acid
(specific gravity=l.16)
lkg
Water at 40° C
36kg
237 0
The mixture was allowed to stand for 2 hours to develop colloidal properties, and was then diluted with an equal volume of water to give a colloidal melamine resin having a shelf life of more than 6 months.
The diluted composition (1 part by weight) was further diluted with water (4 parts) and to this mixture was added an aqueous emulsion of a non-ionic polydimethylsiloxane (0.5 parts by weight; silicone content 35% by weight).(The silicone release agent sold by Basildon Chemicals under the designation BC330 is very suitable.)
The mixed melamine resin/silicone polymer composition was then applied, from a bath adjusted with acetic acid to pH 5-6, to knitted wool garments which had been 'w* conventionally chlorinated with a dichloroisocyanurate salt, treated with antichlor, and rinsed.The bath temperature was slowly raised from ambient to 40° C during 10 minutes, and held at that temperature for a further 10 minutes to exhaust the melamine resin and silicone polymer onto the wool. Weight gain was about 1.5% by dry weight of the wool.The material was then removed from the bath, hydroextracted and tumble-dried at 60-80° C.
t
2 3 7 0
Example 2
For the treatment of wool tops the procedure of Example 1 was modified as follows.
The mixed melamine resin/silicone polymer was applied in the 4th bowl of a conventional 5-bowl unit to deposit about 1.5% of solid mixture onto the tops. The treated tops were then passed to the 5th bowl, in which a cationic substituted stearamide had been included as additional softener. The tops were finally dried at 70-80° C.
Claims (5)
- WHAT WE CLAIM IS: c 3 7 G 1 4 1 A process for the treatment of wool to improve its resistance to shrinkage, by subjecting it first to an oxidation treatment and then to a resin treatment to supplement the shrink resistance imparted by the oxidation treatment, the resin treatment being accompanied or followed by treatment with a softening agent to soften the harsh handle associated with use of the resin, in which process the resin employed is a colloidal melamine resin and the softening agent employed is a silicone polymer.
- 2 A process according to claim 1, in which the silicone polymer is dispersed in the colloidal melamine resin.
- 3 A process according to claim 1 or 2, in which the silicone polymer is non-ionic.
- 4 A process according to claim 3, in which the silicone polymer is a polydimethylsiloxane.
- 5 A process according to any of claims 1 to 4, in which the melamine resin has at least two -CH^OR groups per melamine nucleus, where R = H or Ci-4 alkyl. f \y A \ ^ > J 237 C 1 9 8 A process according to any of claims 1 to 5, in which the oxidation treatment is a chlorination. 7 A process according to claim 6, in which the chlorination utilises a dichloroisocyanurate salt. 8 A process according to any of claims 1 to 7, applied to the treatment of wool tops. 9 A process according to any of claims 1 to 7, applied to the treatment of knitted wool garments. 10 A process according to claim 1, substantially as herein described with reference to the Examples. 11 Wool when treated according to the process as claimed in any one of claims 1 to 10 inclusive. BIP CHEMICALS LIMITED By Their Attorneys BALDWIN SON & CAREY
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB909002680A GB9002680D0 (en) | 1990-02-07 | 1990-02-07 | Treatment of wool |
Publications (1)
Publication Number | Publication Date |
---|---|
NZ237014A true NZ237014A (en) | 1992-09-25 |
Family
ID=10670536
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NZ237014A NZ237014A (en) | 1990-02-07 | 1991-02-05 | Treating wool by oxidation, resin and softening treatments to improve shrink resistance |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0441421B1 (en) |
AU (1) | AU630275B2 (en) |
DE (1) | DE69108588T2 (en) |
GB (2) | GB9002680D0 (en) |
NZ (1) | NZ237014A (en) |
ZA (1) | ZA91605B (en) |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0080272A3 (en) * | 1981-10-28 | 1984-08-22 | South African Inventions Development Corporation | Shrink-resist treatment of wool |
GB2217741B (en) * | 1988-04-21 | 1991-07-31 | Bip Chemicals Ltd | Treatment of silk fabrics |
-
1990
- 1990-02-07 GB GB909002680A patent/GB9002680D0/en active Pending
-
1991
- 1991-01-16 DE DE69108588T patent/DE69108588T2/en not_active Expired - Fee Related
- 1991-01-16 EP EP91200072A patent/EP0441421B1/en not_active Expired - Lifetime
- 1991-01-17 GB GB9101054A patent/GB2240790B/en not_active Expired - Fee Related
- 1991-01-28 ZA ZA91605A patent/ZA91605B/en unknown
- 1991-02-05 NZ NZ237014A patent/NZ237014A/en unknown
- 1991-02-07 AU AU70866/91A patent/AU630275B2/en not_active Ceased
Also Published As
Publication number | Publication date |
---|---|
AU7086691A (en) | 1991-08-08 |
EP0441421B1 (en) | 1995-04-05 |
AU630275B2 (en) | 1992-10-22 |
ZA91605B (en) | 1991-10-30 |
DE69108588T2 (en) | 1995-10-05 |
GB2240790B (en) | 1993-06-02 |
GB2240790A (en) | 1991-08-14 |
EP0441421A1 (en) | 1991-08-14 |
GB9101054D0 (en) | 1991-02-27 |
GB9002680D0 (en) | 1990-04-04 |
DE69108588D1 (en) | 1995-05-11 |
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