NO983541L - Catalyst for the dehydrogenation of ethylbenzene to styrene - Google Patents

Catalyst for the dehydrogenation of ethylbenzene to styrene

Info

Publication number
NO983541L
NO983541L NO983541A NO983541A NO983541L NO 983541 L NO983541 L NO 983541L NO 983541 A NO983541 A NO 983541A NO 983541 A NO983541 A NO 983541A NO 983541 L NO983541 L NO 983541L
Authority
NO
Norway
Prior art keywords
catalyst
oxides
ethylbenzene
dehydrogenation
styrene
Prior art date
Application number
NO983541A
Other languages
Norwegian (no)
Other versions
NO983541D0 (en
Inventor
Carlo Rubini
Luigi Cavalli
Esterino Conca
Original Assignee
Sued Chemie Mt Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sued Chemie Mt Srl filed Critical Sued Chemie Mt Srl
Publication of NO983541D0 publication Critical patent/NO983541D0/en
Publication of NO983541L publication Critical patent/NO983541L/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8871—Rare earth metals or actinides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Katalysator for dehydrogenering av etylbenzen til styren, omfattende jernoksid, oksider av alkali- og jordalkalimetaller, oksider fra lantanrekken og oksider av metallene i gruppe seks i det periodiske system. Katalysatoren fremstilles fra en pasta av jernoksid impregnert med en vandig løsning av et ceriumsalt, hvilken behandles med vandig KOH og kalsineres, etter tørking, for å danne preformet kaliumferrat, hvortil de andre bestanddelene eller forløperne i katalysatoren deretter tilføres.Catalyst for dehydrogenation of ethylbenzene to styrene, comprising iron oxide, oxides of alkali and alkaline earth metals, oxides of the lanthanum series and oxides of the metals of group six of the Periodic Table. The catalyst is prepared from a paste of iron oxide impregnated with an aqueous solution of a cerium salt, which is treated with aqueous KOH and calcined, after drying, to form preformed potassium ferrate, to which the other constituents or precursors of the catalyst are then added.

NO983541A 1997-08-01 1998-07-31 Catalyst for the dehydrogenation of ethylbenzene to styrene NO983541L (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT97MI001860A IT1293531B1 (en) 1997-08-01 1997-08-01 CATALYSTS FOR DEHYDROGENATION OF ETHYLBENZENE TO STYRENE
US09/314,704 US6184174B1 (en) 1997-08-01 1999-05-19 Catalysts for dehydrogenating ethylbenzene to styrene

Publications (2)

Publication Number Publication Date
NO983541D0 NO983541D0 (en) 1998-07-31
NO983541L true NO983541L (en) 1999-02-02

Family

ID=26331532

Family Applications (1)

Application Number Title Priority Date Filing Date
NO983541A NO983541L (en) 1997-08-01 1998-07-31 Catalyst for the dehydrogenation of ethylbenzene to styrene

Country Status (19)

Country Link
US (1) US6184174B1 (en)
EP (1) EP0894528B1 (en)
JP (1) JPH11104494A (en)
CN (1) CN1207330A (en)
AU (1) AU736855B2 (en)
BR (1) BR9802810A (en)
CA (1) CA2244188A1 (en)
CZ (1) CZ237798A3 (en)
DE (1) DE69812789T2 (en)
DK (1) DK0894528T3 (en)
ES (1) ES2193445T3 (en)
HR (1) HRP980418A2 (en)
HU (1) HUP9801740A3 (en)
ID (1) ID19866A (en)
IT (1) IT1293531B1 (en)
NO (1) NO983541L (en)
PL (1) PL327785A1 (en)
PT (1) PT894528E (en)
SK (1) SK102598A3 (en)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19814080A1 (en) 1998-03-30 1999-10-07 Basf Ag Catalyst for the dehydrogenation of hydrocarbons, in particular for the dehydrogenation of ethylbenzene to styrene, and process for its preparation
DE50012271D1 (en) * 1999-02-10 2006-04-27 Basf Ag Catalyst for the dehydrogenation of ethylbenzene to styrene
KR100383221B1 (en) * 2001-01-17 2003-05-12 한국화학연구원 Catalyst for dehydrogenation of alkylaromatic hydrocarbons and preparation method thereof
TWI267401B (en) * 2002-01-30 2006-12-01 Shell Int Research A catalyst, its preparation and its use in a dehydrogenation process
US7271126B2 (en) * 2002-05-15 2007-09-18 Sud-Chemie Inc. Catalyst for the dehydrogenation of ethyl benzene to STYRENE prepared with a high purity iron precursor
US6936743B2 (en) * 2002-09-05 2005-08-30 Fina Technology, Inc. Method for extending catalyst life in processes for preparing vinyl aromatic hydrocarbons
CN1299822C (en) * 2004-07-13 2007-02-14 华东理工大学 Nano carbon fiber catalyst for preparing styrene by ethyl benzene oxidation and dehydrogenation and its forming method
DE102004039603A1 (en) * 2004-08-13 2006-02-23 Basf Ag Catalyst containing iron oxide (s), alkali metal compound (s) and cerium oxide (s)
CN100381362C (en) * 2004-10-29 2008-04-16 中国石油化工股份有限公司 Potassium ferrate preparation method
CN100368083C (en) * 2004-10-29 2008-02-13 中国石油化工股份有限公司 Catalyst for preparing cinnamene by dehydrogenation of ethylbenzene
JP2008520685A (en) 2004-11-18 2008-06-19 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー An improved method for producing alkenyl aromatics under low steam-to-oil process conditions
US20060224029A1 (en) * 2005-03-29 2006-10-05 Fina Technology, Inc. Method of extending catalyst life in vinyl aromatic hydrocarbon formation
CN100443171C (en) * 2005-06-22 2008-12-17 中国石油化工股份有限公司 Oxide catalysts for ethyl benzene dehydrogenation preparation of styrene
CN1307108C (en) * 2005-07-29 2007-03-28 大庆石油学院 Method for improving oxidation activity of potassium ferrate
CN100408175C (en) * 2005-08-15 2008-08-06 中国石油化工股份有限公司 Dehydrogenation catalyst for preparing alkyl alkenyl arene
CN100408174C (en) * 2005-08-15 2008-08-06 中国石油化工股份有限公司 Catalyst for ethyl benzene dehydrogenation
CN101279267B (en) * 2007-04-04 2011-07-13 中国石油化工股份有限公司 Energy-saving catalyst for phenylethylene dehydrogenation
CN101279263B (en) * 2007-04-04 2010-07-21 中国石油化工股份有限公司 Catalyst for preparation of styrene by ethylbenzene dehydrogenation
JP5313233B2 (en) * 2007-05-03 2013-10-09 バスフ・コーポレイション Catalyst, its preparation and use
US8648007B2 (en) * 2008-04-22 2014-02-11 Fina Technology, Inc. Vaporization and transportation of alkali metal salts
US9138706B2 (en) * 2008-04-22 2015-09-22 Fina Technology, Inc. Method and apparatus for addition of an alkali metal promoter to a dehydrogenation catalyst
EP2329878A4 (en) * 2008-09-22 2013-08-21 Univ Waseda Dehydrogenation catalyst for alkyl aromatic compounds having high redox catalysis, process for preparation of the catalyst and process of dehydrogenation with the same
US20110105316A1 (en) * 2009-10-31 2011-05-05 Fina Technology, Inc. Mixed Metal Oxide Ingredients for Bulk Metal Oxide Catalysts
CN103372452B (en) * 2012-04-24 2015-08-19 中国石油天然气股份有限公司 The Catalysts and its preparation method of ethyl benzene dehydrogenation preparation of styrene
CN103537296B (en) * 2012-07-12 2015-06-10 中国石油化工股份有限公司 Ethylbenzene dehydrogenation catalyst in low water ratio
CN106413884B (en) 2014-05-09 2019-12-10 巴斯夫欧洲公司 Improved catalyst for dehydrogenation of hydrocarbons
WO2015169825A1 (en) 2014-05-09 2015-11-12 Basf Se Catalyst for dehydrogenating hydrocarbons
CN105562024A (en) * 2014-10-13 2016-05-11 中国石油化工股份有限公司 Catalyst for preparation of p-methyl styrene, and preparation method and application thereof
CN105562023A (en) * 2014-10-13 2016-05-11 中国石油化工股份有限公司 Catalyst for preparation of p-methyl styrene, and preparation method and application thereof
CN105562025B (en) * 2014-10-13 2018-05-11 中国石油化工股份有限公司 Low temperature ethylbenzene dehydrogenation catalyst with low water ratio and its preparation method and application
CN106423239B (en) * 2015-08-12 2019-01-25 中国石油化工股份有限公司 High stable phenylethylene catalyst
CN106423238B (en) * 2015-08-12 2019-01-25 中国石油化工股份有限公司 Phenylethylene catalyst and preparation method thereof
CN106423187B (en) * 2015-08-12 2019-02-19 中国石油化工股份有限公司 Phenylethylene catalyst
CN105056966B (en) * 2015-08-25 2018-09-25 营口风光新材料股份有限公司 Catalyst for ethyl benzene dehydrogenation preparation of styrene
RU2626238C1 (en) * 2016-06-08 2017-07-25 Федеральное государственное бюджетное образовательное учреждение высшего образования "Ярославский государственный технический университет" (ФГБОУВО "ЯГТУ") Catalyst for dehydrogenating of alkylaromatic hydrocarbons
CN108722430A (en) * 2018-04-19 2018-11-02 天津理工大学 Using nano-sized iron oxide as catalyst for phenylethylene dehydrogenation of source of iron and preparation method thereof
CN111420673A (en) * 2020-03-19 2020-07-17 湖南城市学院 Preparation method of catalyst for alkyl aromatic dehydrogenation

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GB8510197D0 (en) * 1985-04-22 1985-05-30 Ici Plc Catalysts
US4758543A (en) * 1987-07-01 1988-07-19 The Dow Chemical Company Dehydrogenation catalyst
JPH04277030A (en) * 1991-03-05 1992-10-02 Nissan Gaadoraa Shokubai Kk Ethylbenzene dehydrogenation catalyst
KR100373572B1 (en) * 1994-12-14 2003-04-21 쉘 인터내셔널 리써치 마챠피즈 비 브이 Dehydrogenation catalyst and process

Also Published As

Publication number Publication date
ITMI971860A1 (en) 1999-02-01
BR9802810A (en) 1999-12-21
CZ237798A3 (en) 1999-02-17
HUP9801740A3 (en) 2000-02-28
HRP980418A2 (en) 1999-06-30
AU736855B2 (en) 2001-08-02
SK102598A3 (en) 1999-04-13
JPH11104494A (en) 1999-04-20
EP0894528A2 (en) 1999-02-03
US6184174B1 (en) 2001-02-06
EP0894528A3 (en) 1999-11-03
PL327785A1 (en) 1999-02-15
ID19866A (en) 1998-08-13
IT1293531B1 (en) 1999-03-01
CA2244188A1 (en) 1999-02-01
HUP9801740A2 (en) 1999-05-28
DE69812789D1 (en) 2003-05-08
EP0894528B1 (en) 2003-04-02
NO983541D0 (en) 1998-07-31
PT894528E (en) 2003-06-30
ES2193445T3 (en) 2003-11-01
DE69812789T2 (en) 2004-02-12
CN1207330A (en) 1999-02-10
HU9801740D0 (en) 1998-09-28
DK0894528T3 (en) 2003-07-28
AU7859198A (en) 1999-02-11

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