NO965501D0 - Supported catalyst system, process for its preparation and its use for polymerization of olefins - Google Patents

Supported catalyst system, process for its preparation and its use for polymerization of olefins

Info

Publication number
NO965501D0
NO965501D0 NO965501A NO965501A NO965501D0 NO 965501 D0 NO965501 D0 NO 965501D0 NO 965501 A NO965501 A NO 965501A NO 965501 A NO965501 A NO 965501A NO 965501 D0 NO965501 D0 NO 965501D0
Authority
NO
Norway
Prior art keywords
aryl
alkyl
alkenyl
solvent
component
Prior art date
Application number
NO965501A
Other languages
Norwegian (no)
Other versions
NO965501L (en
Inventor
Volker Fraaije
Bernd Bachmann
Andreas Winter
Original Assignee
Hoechst Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst Ag filed Critical Hoechst Ag
Publication of NO965501D0 publication Critical patent/NO965501D0/en
Publication of NO965501L publication Critical patent/NO965501L/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A supported catalyst system with high activity is obtained by: (a) bringing metallocene component(s) (I) into contact with cocatalyst component(s) (II) in solvent(s), (b) adding the soluble product to the support and (c) removing the solvent. Preferably component (I) is a compound of formula (I), in which M<1> = a Group IVb metal; R<1>, R<2> = H, 1-10C alkyl or alkoxy, 6-20C aryl, 6-10C aryloxy, 2-10C alkenyl, OH, NR<12>2 (with R<12> = 1-2C alkyl or 6-14C aryl) or halogen; R<3>-R<8>, R<3>'-R<8>' = H, 1-40C hydrocarbyl (linear, branched or cyclic, e.g. 1-10C alkyl, 2-10C alkenyl, 6-20C aryl, 7-40C aralkyl or alkaryl, or 8-40C aralkenyl; or adjacent groups R<4>-R<8> and/or R<4>'-R<8>' may form part of a ring system; R<9> = a bridging group, preferably -O-R-O-, -O-R'-O-, -O-R-, -R' -R-, -R-, -R-R-, -R'-R'-, -R-(R')x-R-, -R'-R'-R'- (with R = -M<2>R<10>R<11>- and R' = -CR<10>R<11>-), >BR<10>, >AlR<10>, Ge, O, S, SO, SO2, >NR<10>, CO, >PR<10> or >P(O)R<10>; R<10>, R<11> = H, halogen or a 1-40C hydrocarbon group such as 1-20C alkyl, 1-10C fluoroalkyl or alkoxy, 6-14C aryl, 6-10C fluoroaryl or aryloxy, 2-10C alkenyl, 7-40C aralkyl or alkaryl, or 8-40C aralkenyl; or R<10> + R<11> may form part of a ring system; x = 0-18; M<2> = Si, Ge or Sn; rings A and B may be the same or different, and saturated or unsaturated; R<9> may also link two units of formula (I) together. Preferably cocatalyst (II) comprises aluminoxane(s) or a Lewis acid or ionic compound which can react with (I) to form a cationic compound. The solvent is a hydrocarbon or mixture thereof
NO965501A 1995-12-22 1996-12-20 Supported catalyst system, process for its preparation and its use for polymerization of olefins NO965501L (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19548288A DE19548288A1 (en) 1995-12-22 1995-12-22 Supported catalyst system, process for its preparation and its use for the polymerization of olefins

Publications (2)

Publication Number Publication Date
NO965501D0 true NO965501D0 (en) 1996-12-20
NO965501L NO965501L (en) 1997-06-23

Family

ID=7781116

Family Applications (1)

Application Number Title Priority Date Filing Date
NO965501A NO965501L (en) 1995-12-22 1996-12-20 Supported catalyst system, process for its preparation and its use for polymerization of olefins

Country Status (10)

Country Link
EP (1) EP0780402B1 (en)
JP (1) JP4445044B2 (en)
AT (1) ATE238355T1 (en)
BR (1) BR9606095A (en)
CA (1) CA2193319A1 (en)
DE (2) DE19548288A1 (en)
ES (1) ES2197933T3 (en)
NO (1) NO965501L (en)
TW (1) TW374772B (en)
ZA (1) ZA9610688B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999007747A1 (en) * 1997-08-12 1999-02-18 Chisso Corporation Process for the preparation of olefin (co)polymers, olefin copolymers, and application thereof
MXPA05008841A (en) 2003-02-21 2005-10-18 Dow Global Technologies Inc Process for homo- or copolymerization of conjugated olefines.

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3726067A1 (en) 1987-08-06 1989-02-16 Hoechst Ag METHOD FOR PRODUCING 1-OLEFIN POLYMERS
DE4119343A1 (en) * 1991-06-12 1992-12-17 Basf Ag INSULATED, SUPPORTED CATALYST SYSTEM FOR THE POLYMERIZATION OF C (DOWN ARROW) 2 (DOWN ARROW) - TO C (DOWN ARROW) 1 (DOWN ARROW) (DOWN ARROW) 0 (DOWN ARROW) -ALK-1-END
FI112233B (en) * 1992-04-01 2003-11-14 Basell Polyolefine Gmbh Catalyst for olefin polymerization, process for its preparation and its use
US5240894A (en) * 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
US5238892A (en) * 1992-06-15 1993-08-24 Exxon Chemical Patents Inc. Supported catalyst for 1-olefin(s) (co)polymerization
ES2117279T3 (en) 1993-05-25 1998-08-01 Exxon Chemical Patents Inc CATALYTICAL METALOCHENE SYSTEMS SUPPORTED FOR THE POLYMERIZATION OF OLEPHINS, THEIR PREPARATION AND USE.
DE4333569A1 (en) * 1993-10-01 1995-04-06 Hoechst Ag Process for olefin polymerization
FI96866C (en) * 1993-11-05 1996-09-10 Borealis As Support olefin polymerization catalyst, its preparation and use
DE4344689A1 (en) * 1993-12-27 1995-06-29 Hoechst Ag Metallocene compound
DE4344688A1 (en) * 1993-12-27 1995-06-29 Hoechst Ag Metallocene compound

Also Published As

Publication number Publication date
NO965501L (en) 1997-06-23
EP0780402A1 (en) 1997-06-25
JPH09188712A (en) 1997-07-22
EP0780402B1 (en) 2003-04-23
ATE238355T1 (en) 2003-05-15
ES2197933T3 (en) 2004-01-16
DE19548288A1 (en) 1997-06-26
BR9606095A (en) 1998-11-03
DE59610373D1 (en) 2003-05-28
ZA9610688B (en) 1997-06-23
TW374772B (en) 1999-11-21
CA2193319A1 (en) 1997-06-23
JP4445044B2 (en) 2010-04-07

Similar Documents

Publication Publication Date Title
ES2169288T3 (en) CATALYSTS CONTAINING METALOCENES WITH ARILSUBSTITUID INDENILE DERIVATIVES AS LEGENDS, PROCEDURES AND INTERMEDIATE PRODUCTS FOR THE OBTAINING OF THESE METALOCENES, AND THEIR EMPLOYMENT.
ES2182336T3 (en) NEW CATALYZER SYSTEMS FOR REACTIONS OF (CO-) POLYMERIZATION, HALOGENUROS-AMIDAS OF METALOCENOS AND ITS USE.
KR940018401A (en) Catalyst composition for producing polyolefin and process for producing polyolefin
US3806500A (en) Polymerization with thermally aged catalyst
DE3867515D1 (en) METHOD FOR PRODUCING A SOLID CATALYST FOR OLEFIN POLYMERIZATION.
ZA932305B (en) Catalyst for the polymerization of olefins, process for its preparation and its use.
DE69224184D1 (en) Process for the preparation of bridged, chiral metallocene catalysts of the bisindenyl type
NO984568D0 (en) Metallocene Catalytic Carriers and Methods for Producing the Carrier, Catalyst System and Polymerization Process
ATE97670T1 (en) AVOIDING COLORED IMPURITIES IN THE PRODUCTION OF ULTRA HIGH MOLECULAR ETHYLENE POLYMERS USING A TITANIUM-CONTAINING CATALYST SYSTEM.
KR950703406A (en) Polymer carbonylation catalyst system
NO965501D0 (en) Supported catalyst system, process for its preparation and its use for polymerization of olefins
KR870007211A (en) Process for preparing di- and polymerizable ethylene consisting of contacting an inert solid catalyst and a promoter with ethylene
ATE130591T1 (en) METHOD FOR THE METATHESIS OF OLEFINS AND CATALYST TO BE USED.
EP0263525A3 (en) Process for preparing ethylene homo- and copolymers by means of a chromium trioxide catalyst
MY106053A (en) Process for preparing polyarylene thioether
BR9504330A (en) Process metallocene catalyst compound for the preparation of an application olefin polymer and olefin polymer
FI895464A0 (en) Catalyst component, catalyst and polymerization process
JPS6466214A (en) Production of alpha-olefin polymer
ATE21914T1 (en) PROCESS FOR THE CONTINUOUS PREPARATION OF PARTICULATE ETHYLENE-BUTENE-(1)COPOLYMERS.
KR960029350A (en) Metallocene supported catalyst and its manufacturing method
FI905430A (en) FOERFARANDE FOER FRAMSTAELLNING AV EN FAST PROKATALYSATORKOMPOSITION TILL ETT KATALYSATORSYSTEM AVSETT FOER POLYMERISATION AV OLEFINER OCH EN PROKATALYSATORKOMPOSITION FRAMSTAELLD MEDELST FOERFARANDET.
BR9000637A (en) CATALYST SYSTEM AND POLYMERIZATION PROCESS
TH9010B (en) Oxidizing Agility Additive Polymerization Catalyst

Legal Events

Date Code Title Description
FC2A Withdrawal, rejection or dismissal of laid open patent application