NO961389L - Herbicidal aza-bisphosphonic acid mixtures - Google Patents

Herbicidal aza-bisphosphonic acid mixtures

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Publication number
NO961389L
NO961389L NO961389A NO961389A NO961389L NO 961389 L NO961389 L NO 961389L NO 961389 A NO961389 A NO 961389A NO 961389 A NO961389 A NO 961389A NO 961389 L NO961389 L NO 961389L
Authority
NO
Norway
Prior art keywords
alkyl
substituted
halogen
hydrocarbyl
thiomorpholine
Prior art date
Application number
NO961389A
Other languages
Norwegian (no)
Other versions
NO961389D0 (en
Inventor
Karl Joseph Fisher
Frank Xavier Woolard
John Montgomery Gerdes
Original Assignee
Zeneca Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zeneca Ltd filed Critical Zeneca Ltd
Publication of NO961389D0 publication Critical patent/NO961389D0/en
Publication of NO961389L publication Critical patent/NO961389L/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4025—Esters of poly(thio)phosphonic acids
    • C07F9/405—Esters of poly(thio)phosphonic acids containing nitrogen substituent, e.g. N.....H or N-hydrocarbon group which can be substituted by halogen or nitro(so), N.....O, N.....S, N.....C(=X)- (X =O, S), N.....N, N...C(=X)...N (X =O, S)
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/3804—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se) not used, see subgroups
    • C07F9/3839—Polyphosphonic acids
    • C07F9/3873—Polyphosphonic acids containing nitrogen substituent, e.g. N.....H or N-hydrocarbon group which can be substituted by halogen or nitro(so), N.....O, N.....S, N.....C(=X)- (X =O, S), N.....N, N...C(=X)...N (X =O, S)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/5532—Seven-(or more) membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/568—Four-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/572—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/576—Six-membered rings
    • C07F9/58—Pyridine rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/576—Six-membered rings
    • C07F9/59—Hydrogenated pyridine rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/576—Six-membered rings
    • C07F9/60—Quinoline or hydrogenated quinoline ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
    • C07F9/6503—Five-membered rings
    • C07F9/65031—Five-membered rings having the nitrogen atoms in the positions 1 and 2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
    • C07F9/6503—Five-membered rings
    • C07F9/6506—Five-membered rings having the nitrogen atoms in positions 1 and 3
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
    • C07F9/6509—Six-membered rings
    • C07F9/6512—Six-membered rings having the nitrogen atoms in positions 1 and 3
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having three nitrogen atoms as the only ring hetero atoms
    • C07F9/6518—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6527—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07F9/6533—Six-membered rings

Abstract

Herbicid blanding som omfatter: (A) en forbindelse med formel (I): N ¿ R l C (D hvor R1 er hydrogen, hydroksy, C1-C4-alkoksy, halogen, Cl-C4-alkyl, Ci-Ct- halogenalkyl, hydroksy-C1-C4-alkyl, hydroksy-Cl-C4-alkoksy eller N(R')(R7), hvor R* og R7 uavhengig av hverandre, er hydrogen eller Ci-C^-alkyl; R2 og R3 er uavhengig av hverandre, hydrogen; hydrokarbyl; substituert hydrokarbyl; hydrokarbyloksy; substituert hydrokarbyloksy; hydrokarbyl-S(O)B-; eller substituert hydrokarbyl-S(O)B-; eller R2 og R3 sammen danner en 3-6-leddet karbocyklisk ring, eventuelt substituert med halogen, hydroksy, C^-Cj-alkyl, Ci-Cj-alkoksy, C^-Cj-alkyltio eller N(R8)(R'), hvor R8 og Rs uavhengig av hverandre, er hydrogen eller Cl-ClJ-alkyl; og R4 og R5 uavhengig av hver- andre, er hydrogen; hydrokarbyl; substituert hydrokarbyl; hydrokarbyloksy; substituert hydrokarbyloksy; hydrokarbyltio; substituert hydrokarbyltio; pyridyl; substituert pyridyl; eller har formelen N(R10)(R11), hvor R10 og R" uavhengig av hverandre, er hydrogen, hydrokarbyl eller substituert hydro- karbyl; eller R4 og R* sammen med det nitrogenatom som de er bundet til, danner en aziridin-, piperazin-, morfolin-, tiomorfolin-, tiomorfolin- sulfinyl-, tiomorfolinsulfonyl-, heksametylenimin-, piperidin-, tetrahydro- pyridin-, pyrazol-, imidazol-, pyrrol-, triazol-, tetrahydropyrimidin-, dihydroimidazol-, pyrrolin-, azetidin-, perhydroindol-, perhydrokinolin-, perhydroisokinolin- eller pyrrolidinring, som hver eventuelt kan være substituert med Ci-C^-alkyl, halogen, C6-Clo-ar'yl, C6-C10-aryl substituert med halogen eller Cj-Cj-alkyl, C7-Cu-aralkyl, C7-C16-aralkyl substituert med halogen eller C^-Cj-alkyl, nitro, halogen-C^-Cio-alkyl, Ci-Cu-alkoksy, C!-GIO- alkyltio, Ci-Cm-alkylsulfonyl, fenoksy, fenoksy substituert med halogen eller Cl-C6-alkyl, C^C^-alkenyl eller cyano; eller R2 og R4 sammen med nitrogen- og karbonatomene som de er bundet til, danner en aziridin-, piperazin-, morfolin-, tiomorfolin-, tiomorfolinsulfinyl-, tiomorfolin- sulfonyl-, heksametylenimin-, piperidin-, tetrahydropyridin-, pyrazol-, imidazol-, pyrrol-, triazol-, tetrahydropyrimidin-, dihydroimidazol-, pyrrolin-, azetidin-, perhydroindol-, perhydrokinolin-, perhydroisokinolin- eller pyrrolidinring, som hver eventuelt kan være substituert med GJ-CU- alkyl, halogen, c,-Clo-aryl, C,-Ci10-aryl substituert med halogen eller c^Cj- alkyl, C7-Cls-aralkyl, C7-C16-aralkyl substituert med halogen eller C^-Cj- alkyl, nitro, halogen-Ci-C^-alkyl, C^C^-alkoksy, (^-C^-alkyltio, C^-C^- alkylsulfonyl, fenoksy, fenoksy substituert med halogen eller Cl-Cs-alkyl, C^Cto-alkenyl eller cyano; og m er O, l eller 2; og landbrukskjemisk akseptable salter derav; og (B) en landbrukskjemisk akseptabel bærer for denne. I henhold til andre aspekter er foreliggende oppfinnelse rettet mot en fremgangsmåte for å kontrollere plantevekst som omfatter at det på det område hvor kontroll ønskes, påføres en herbicid effektiv mengde av en forbindelse med formel (I); så vel som enkelte nye forbindelser som har en struktur innenfor rammen av den ovenfor angitte formel (I).Herbicidal composition comprising: (A) a compound of formula (I): N ¿R 1 C (D wherein R 1 is hydrogen, hydroxy, C 1 -C 4 alkoxy, halogen, C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, hydroxy-C1-C4-alkyl, hydroxy-C1-C4-alkoxy or N (R ') (R7), where R * and R7 are independently hydrogen or C1-C4 alkyl; R2 and R3 are independently each other, hydrogen; hydrocarbyl; substituted hydrocarbyl; hydrocarbylloxy; substituted hydrocarbylloxy; hydrocarbyl-S (O) B-; or substituted hydrocarbyl-S (O) B-; or R2 and R3 together form a 3-6 membered carbocyclic ring, optionally substituted by halogen, hydroxy, C 1 -C 2 alkyl, C 1 -C 2 alkoxy, C 1 -C 2 alkylthio or N (R 8) (R '), where R 8 and R 5 are independently hydrogen or C alkyl; and R 4 and R 5 independently of each other are hydrogen; hydrocarbyl; substituted hydrocarbyl; hydrocarbyloxy; substituted hydrocarbylloxy; hydrocarbylthio; substituted hydrocarbylthio; pyridyl; substituted pyridyl; or have the formula N (R10) (R11) "regardless of each other others are hydrogen, hydrocarbyl or substituted hydrocarbyl; or R 4 and R * together with the nitrogen atom to which they are attached form an aziridine, piperazine, morpholine, thiomorpholine, thiomorpholine sulfinyl, thiomorpholine sulfonyl, hexamethyleneimine, piperidine, tetrahydropyridine, pyrazole , imidazole, pyrrole, triazole, tetrahydropyrimidine, dihydroimidazole, pyrroline, azetidine, perhydroindole, perhydroquinoline, perhydroisoquinoline or pyrrolidine ring, each of which may be substituted with C1-C6 alkyl, C -Clo-ar'yl, C6-C10-aryl substituted with halogen or C1-C3 alkyl, C7-C20 aralkyl, C7-C16 aralkyl substituted with halogen or C1-C3 alkyl, nitro, halogen-C1 -C 10 -alkyl, C 1 -C 8 alkoxy, C 1 -G 10 alkylthio, C 1 -C 6 alkylsulfonyl, phenoxy, phenoxy substituted with halogen or C 1 -C 6 alkyl, C 1 -C 6 alkenyl or cyano; or R 2 and R 4 together with the nitrogen and carbon atoms to which they are attached form an aziridine, piperazine, morpholine, thiomorpholine, thiomorpholine sulfinyl, thiomorpholine sulfonyl, hexamethyleneimine, piperidine, tetrahydropyridine, pyrazole, imidazole, pyrrole, triazole, tetrahydropyrimidine, dihydroimidazole, pyrroline, azetidine, perhydroindole, perhydroquinoline, perhydroisoquinoline or pyrrolidine ring, each of which may be optionally substituted with GJ-CU alkyl, halogen, c C 10 -alkyl, C 1 -C 10 aryl substituted with halogen or C 1 -C 3 alkyl, C 7 -C 18 aralkyl, C 7 -C 16 aralkyl substituted with halogen or C 1 -C 2 alkyl, nitro, halogen-C 1 -C 3 -alkyl, C ^-C ^-alkoxy, (CC-C ^-alkylthio, C ^-C ^-alkylsulfonyl, phenoxy, phenoxy substituted with halogen or C Cl-Cs-alkyl, C ^-Cto alkenyl or cyano; and m is O, 1 or 2, and pharmaceutically acceptable salts thereof, and (B) an agriculturally acceptable carrier thereof, in accordance with other aspects, the present invention is directed to a method of controlling plant growth which includes applying a herbicide effective amount of a compound of formula (I) in the area where control is desired; as well as some new compounds having a structure within the scope of the above formula (I).

NO961389A 1993-10-07 1996-04-03 Herbicidal aza-bisphosphonic acid mixtures NO961389L (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13372293A 1993-10-07 1993-10-07
PCT/GB1994/002183 WO1995010188A2 (en) 1993-10-07 1994-10-07 Herbicidal aza bisphosphonic acid compositions

Publications (2)

Publication Number Publication Date
NO961389D0 NO961389D0 (en) 1996-04-03
NO961389L true NO961389L (en) 1996-06-03

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Family Applications (1)

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NO961389A NO961389L (en) 1993-10-07 1996-04-03 Herbicidal aza-bisphosphonic acid mixtures

Country Status (17)

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EP (1) EP0722268A1 (en)
JP (1) JPH09506075A (en)
CN (1) CN1134657A (en)
AU (1) AU690581B2 (en)
BR (1) BR9407762A (en)
CA (1) CA2173607A1 (en)
CZ (1) CZ101596A3 (en)
FI (1) FI961520A (en)
HU (1) HUT74893A (en)
IL (2) IL111180A (en)
NO (1) NO961389L (en)
NZ (1) NZ274000A (en)
PL (1) PL313820A1 (en)
SK (1) SK45296A3 (en)
TW (1) TW401276B (en)
WO (1) WO1995010188A2 (en)
ZA (1) ZA947814B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5728650A (en) * 1993-10-07 1998-03-17 Zeneca Limited Herbicidal aza bisphosphonic acids and compositions containing the same
WO1995034207A1 (en) * 1994-06-13 1995-12-21 Zeneca Limited Method of controlling plants by inhibition of farnesyl pyrophosphate synthase
IL115041A0 (en) * 1995-08-23 1995-12-08 Yissum Res Dev Co Novel bisphosphonates process for their preparation and pharmaceutical compositions containing them
CN101282730A (en) * 2005-10-06 2008-10-08 依奈特制药公司 Phosphoantigen salts of organic bases and methods for their crystallization
CA2646334A1 (en) * 2006-03-17 2007-09-27 The Board Of Trustees Of The University Of Illinois Bisphosphonate compounds and methods
PT103600B (en) * 2006-11-06 2009-01-30 Hovione Farmaciencia Sa PROCESS FOR THE PREPARATION OF BIOSPHONIC ACIDS AND THEIR PHARMACEUTICALLY ACCEPTABLE SALTS

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU739076A1 (en) * 1976-05-19 1980-06-05 Институт Химической Кинетики И Горения Со Ан Ссср Method of preparing beta-aminoethylidenediphosphonic acids
DE3623397A1 (en) * 1986-07-11 1988-01-14 Boehringer Mannheim Gmbh NEW DIPHOSPHONIC ACID DERIVATIVES, METHOD FOR THE PRODUCTION THEREOF AND MEDICINAL PRODUCTS CONTAINING THESE COMPOUNDS
IL84731A0 (en) * 1986-12-19 1988-05-31 Norwich Eaton Pharma Heterocycle-substituted diphosphonic acids and salts and esters and pharmaceutical compositions containing them
PL175475B1 (en) * 1992-05-29 1999-01-29 Procter & Gamble Pharma Novel sulphur containing phosphonate compounds

Also Published As

Publication number Publication date
CN1134657A (en) 1996-10-30
NZ274000A (en) 1998-03-25
BR9407762A (en) 1997-03-04
TW401276B (en) 2000-08-11
AU7790194A (en) 1995-05-04
CA2173607A1 (en) 1995-04-20
HUT74893A (en) 1997-02-28
JPH09506075A (en) 1997-06-17
HU9600839D0 (en) 1996-05-28
ZA947814B (en) 1995-08-14
WO1995010188A3 (en) 1995-05-04
IL111180A0 (en) 1994-12-29
NO961389D0 (en) 1996-04-03
WO1995010188A2 (en) 1995-04-20
IL111180A (en) 1999-09-22
FI961520A (en) 1996-05-27
PL313820A1 (en) 1996-07-22
SK45296A3 (en) 1996-09-04
AU690581B2 (en) 1998-04-30
CZ101596A3 (en) 1996-07-17
EP0722268A1 (en) 1996-07-24
FI961520A0 (en) 1996-04-04
IL114381A0 (en) 1995-10-31

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