NO862316L - STABILIZED Aqueous SOLUTIONS AND / OR DISPERSIONS OF POLYMERS, AND THE PREPARATION AND USE THEREOF. - Google Patents
STABILIZED Aqueous SOLUTIONS AND / OR DISPERSIONS OF POLYMERS, AND THE PREPARATION AND USE THEREOF.Info
- Publication number
- NO862316L NO862316L NO862316A NO862316A NO862316L NO 862316 L NO862316 L NO 862316L NO 862316 A NO862316 A NO 862316A NO 862316 A NO862316 A NO 862316A NO 862316 L NO862316 L NO 862316L
- Authority
- NO
- Norway
- Prior art keywords
- dispersions
- aqueous polymer
- polymer solutions
- weight
- stabilized aqueous
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims description 32
- 239000006185 dispersion Substances 0.000 title claims description 31
- 239000007864 aqueous solution Substances 0.000 title description 3
- 238000002360 preparation method Methods 0.000 title description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 28
- 150000004985 diamines Chemical class 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000000654 additive Substances 0.000 claims description 16
- 229910021529 ammonia Inorganic materials 0.000 claims description 14
- 239000012530 fluid Substances 0.000 claims description 14
- 239000001257 hydrogen Substances 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 11
- 239000003054 catalyst Substances 0.000 claims description 11
- 239000011541 reaction mixture Substances 0.000 claims description 10
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 8
- 239000007858 starting material Substances 0.000 claims description 8
- 238000011010 flushing procedure Methods 0.000 claims description 7
- 238000005553 drilling Methods 0.000 claims description 6
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 5
- 229940102253 isopropanolamine Drugs 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004927 clay Substances 0.000 claims description 4
- 238000000605 extraction Methods 0.000 claims description 4
- 150000004676 glycans Chemical class 0.000 claims description 4
- 239000003208 petroleum Substances 0.000 claims description 4
- 229920001282 polysaccharide Polymers 0.000 claims description 4
- 239000005017 polysaccharide Substances 0.000 claims description 4
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 claims description 4
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 3
- 229920002907 Guar gum Polymers 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 239000000665 guar gum Substances 0.000 claims description 3
- 235000010417 guar gum Nutrition 0.000 claims description 3
- 229960002154 guar gum Drugs 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000005576 amination reaction Methods 0.000 claims description 2
- 230000000844 anti-bacterial effect Effects 0.000 claims description 2
- 239000003899 bactericide agent Substances 0.000 claims description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 2
- 239000010428 baryte Substances 0.000 claims description 2
- 229910052601 baryte Inorganic materials 0.000 claims description 2
- 230000003197 catalytic effect Effects 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 claims description 2
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000004576 sand Substances 0.000 claims description 2
- 230000000087 stabilizing effect Effects 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 description 28
- 238000004821 distillation Methods 0.000 description 14
- 239000000203 mixture Substances 0.000 description 10
- 229910000831 Steel Inorganic materials 0.000 description 6
- 239000013535 sea water Substances 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- 229920001285 xanthan gum Polymers 0.000 description 5
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 3
- 239000000395 magnesium oxide Substances 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 239000003784 tall oil Substances 0.000 description 2
- SUTWPJHCRAITLU-UHFFFAOYSA-N 6-aminohexan-1-ol Chemical compound NCCCCCCO SUTWPJHCRAITLU-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000007868 Raney catalyst Substances 0.000 description 1
- 229910000564 Raney nickel Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 150000002483 hydrogen compounds Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- -1 triethanolamine ethers Chemical class 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/84—Compositions based on water or polar solvents
- C09K8/86—Compositions based on water or polar solvents containing organic compounds
- C09K8/88—Compositions based on water or polar solvents containing organic compounds macromolecular compounds
- C09K8/90—Compositions based on water or polar solvents containing organic compounds macromolecular compounds of natural origin, e.g. polysaccharides, cellulose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K11/00—Use of ingredients of unknown constitution, e.g. undefined reaction products
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/04—Aqueous well-drilling compositions
- C09K8/06—Clay-free compositions
- C09K8/12—Clay-free compositions containing synthetic organic macromolecular compounds or their precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/10—Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
Foreliggende oppfinnelse vedrører vandige oppløsninger og/eller dispersjoner av polymerer som er stabilisert med spesielle produkter, fremstilling derav ved blanding av polymerer, vann og eventuelt ytterligere tilsatsstoffer som f.eks. beskrevet i G.R. Gray, "Composition of Drilling Fluids", fjerde utgave 1980, side 526-586, med det spesielle produktet, samt anvendelse derav ved utvinning av jordolje. The present invention relates to aqueous solutions and/or dispersions of polymers that have been stabilized with special products, production thereof by mixing polymers, water and possibly further additives such as e.g. described in G.R. Gray, "Composition of Drilling Fluids", fourth edition 1980, pages 526-586, with the particular product, as well as its application in the extraction of petroleum.
Et anvendelsesområde for vandige oppløsninger og/eller dispersjoner av polymerer ved utvinningen av jordolje er tilveiebringelse og behandling av borehull. Eventuelt kan man tilføre slike oppløsninger og/eller dispersjoner bestemte egenskaper ved tilsats av additiver, f.eks. når det gjelder deres rheologiske oppførsel, deres viskositet, gelstyrke, suspen-sjonsevne for faste tilsatser og reduksjon av vanntapet ved filtrering i porøse formasjoner. Tilsvarende innstilte oppløsninger og/eller dispersjoner kan eksempelvis anvendes som spylevæske, spesielt som vannbasisk dypborespylevæske, "Frac"-væske eller overhalingsvæske. An area of application for aqueous solutions and/or dispersions of polymers in the extraction of petroleum is the provision and treatment of boreholes. Optionally, such solutions and/or dispersions can be given specific properties by adding additives, e.g. in terms of their rheological behaviour, their viscosity, gel strength, suspension capacity for solid additives and reduction of water loss by filtration in porous formations. Correspondingly adjusted solutions and/or dispersions can, for example, be used as flushing fluid, especially as water-based deep drilling flushing fluid, "Frac" fluid or overhaul fluid.
Som polymerer anvendes generelt cellulosederivater, polysakkarider og/eller guargummi. Disse utsettes imidlertid ved de anvendelses-betingelsene som finnes i borehullene lett for en termisk nedbrytning som påvirker egenskapene for oppløsningene og/eller dispersjonene i negativ retning. Slike egenskapsendringer, f.eks. viskositetsreduksjoner, opptrer ved spylevæsker som inneholder hydroksyetylcellulose allerede ved temperaturer fra ca. 80 "C, ved spylevæsker som inneholder karboksymetylcellulose eller xanthan ved temperaturer fra ca. 100 °C. Ved slike væsker er det derfor påkrevet løpende å etterdosere polymerer for å opprettholde egenskapsbildet for oppløsningen og/eller dispersjonen over lengere tid. As polymers, cellulose derivatives, polysaccharides and/or guar gum are generally used. However, under the conditions of use found in the boreholes, these are easily exposed to a thermal breakdown which affects the properties of the solutions and/or dispersions in a negative direction. Such property changes, e.g. viscosity reductions, occur with flushing fluids containing hydroxyethyl cellulose already at temperatures from approx. 80 "C, for flushing liquids containing carboxymethyl cellulose or xanthan at temperatures from about 100 °C. With such liquids, it is therefore required to continually add polymers to maintain the properties of the solution and/or dispersion over a longer period of time.
Det har allerede vært foreslått å forbedre temperaturbestandigheten for vandige polysakkarid-oppløsninger ved hjelp av bestemte tilsatser. It has already been proposed to improve the temperature resistance of aqueous polysaccharide solutions by means of certain additives.
Ifølge DE-OS 2 715 026 skal en tilsats bestående av en kombinasjon av en svovelholdig anti-oksydant og en lett oksyderbar alkohol være virksom. Forsøkene ble gjennomført ved 97° C. For høyere temepraturer og alkaliske omgivelser, slik de forekommer ved dypboring, er slike stabili satorer imidlertid ikke brukbare idet svovelforbindelsene nedbrytes og alkoholene langsomt frigjøres. According to DE-OS 2 715 026, an additive consisting of a combination of a sulfur-containing antioxidant and an easily oxidizable alcohol should be effective. The experiments were carried out at 97° C. However, for higher temperatures and alkaline environments, such as occur in deep drilling, such stabilizers are not usable as the sulfur compounds break down and the alcohols are slowly released.
I US-PS 3 953 335 foreslås magnesiumoksyd som tilsats til borevæsker som ikke inneholder leire. Ved siden av denne begrensede anvende-ligheten for magnesiumoksyd-tilsatsen oppnås også her bare en begrenset temepraturstabilitet. In US-PS 3,953,335, magnesium oxide is proposed as an additive to drilling fluids that do not contain clay. In addition to this limited applicability of the magnesium oxide additive, only a limited temperature stability is achieved here as well.
I SU-PS'ene 402 633, 730 786 og 1 039 949 foreslås mono-, di- og trietanolamin, samt komplekse blandinger som enten inneholder etanol, amin og urinstoff, eller fenol, urinstoff og leire, eller boraks, etanolamin, urinstoff og etanol, eller talloljedestillater og komplekse trietanolamin-etere som stabilisatorer. Den stabiliserende virkningen av disse addi-tivene er imidlertid liten (se eksempel 8). I tillegg er de anvendte tilsatsene relativt dyre og, når det gjelder komplekse blandinger, omstendelige og uøkonomiske på grunn av kompliserte og tallrike doseringer. In the SU-PSs 402 633, 730 786 and 1 039 949, mono-, di- and triethanolamine are proposed, as well as complex mixtures that either contain ethanol, amine and urea, or phenol, urea and clay, or borax, ethanolamine, urea and ethanol, or tall oil distillates and complex triethanolamine ethers as stabilizers. However, the stabilizing effect of these additives is small (see example 8). In addition, the additives used are relatively expensive and, in the case of complex mixtures, cumbersome and uneconomical due to complicated and numerous dosages.
Det består følgelig fremdeles et behov for en enkel, billig og likevel godt virksom stabilisator for vandige polymeroppløsninger og/eller-dispe r sjoner. Consequently, there is still a need for a simple, cheap and yet effective stabilizer for aqueous polymer solutions and/or dispersions.
Det er nå funnet stabiliserte vandige polymeroppløsninger og/eller-dispersjoner som er kjennetegnet ved at de inneholder et produkt som kan oppnås ved at man på i og for seg kjent måte omsetter alkanolaminer med ammoniakk i nærvær av hydrogen og katalysatorer til diaminer, og deretter fra reaksjonsblandingen fradestillerer ikke omsatte utgangsmaterialer, vann og det dannede diaminet. Stabilized aqueous polymer solutions and/or dispersions have now been found which are characterized by the fact that they contain a product which can be obtained by reacting alkanolamines with ammonia in the presence of hydrogen and catalysts to diamines in a manner known per se, and then from the reaction mixture does not distill off reacted starting materials, water and the diamine formed.
Fremstillingen av diaminer fra alkanolaminer med ammoniakk i nærvær av hydrogen og katalysatorer er kjent (se f.eks. Ullmann's "Enzyklopådie der technischen Chemie", 4. opplag, bind VII, side 380-383 (1974), DE-AS 1 172 268 og US-PS 2 861 995). The preparation of diamines from alkanolamines with ammonia in the presence of hydrogen and catalysts is known (see e.g. Ullmann's "Enzyklopådie der technischen Chemie", 4th edition, volume VII, pages 380-383 (1974), DE-AS 1 172 268 and US-PS 2,861,995).
Herved kan alkanolaminer med eksempelvis 2-10 C-atomer, som etanolamin, isopropanolamin, 1,4-butanolamin, 1,6-heksanolamin eller 1,8-oktanolamin omsettes med overskudd av ammoniakk, eksempelvis 3 til 150 mol ammoniakk/mol alkanolamin, i nærvær av hydrogen, eksempelvis 5 til 100 liter hydrogen/mol alkanolamin i nærvær av katalysatorer, eksempelvis hydreringskatalysatorer som inneholder kobolt, nikkel, kobber, sølv, mangan, jern, platina og/eller palladium i elementær form, eller i form av hydrogenforbindelser eller " kromitt, ved forhøyet temperatur, eksempelvis ved 150 til 300°C og forhøyet trykk, eksempelvis ved 10 til 500 bar. Fra de slik oppnådde reaksjonsblandingene fraskilles uomsatt ammoniakk generelt ved trykkavlastning, dannet diamin og vann ved destillasjon ved normaltrykk eller svakt redusert trykk, eksempelvis ved 1 til 0,1 bar, og uomsatt alkanolamin ved destillasjon ved svakt eller sterkt redusert trykk, eksempelvis ved 500 til 10 mbar. Herved forblir en destillasjonsrest som man idag ikke kjenner noen teknisk anvendelsesmulighet for. Denne samles derfor i depoter og forbrennes ved høye temperaturer. In this way, alkanolamines with, for example, 2-10 C atoms, such as ethanolamine, isopropanolamine, 1,4-butanolamine, 1,6-hexanolamine or 1,8-octanolamine can be reacted with an excess of ammonia, for example 3 to 150 mol ammonia/mol alkanolamine, in the presence of hydrogen, for example 5 to 100 liters of hydrogen/mol of alkanolamine in the presence of catalysts, for example hydrogenation catalysts containing cobalt, nickel, copper, silver, manganese, iron, platinum and/or palladium in elemental form, or in the form of hydrogen compounds or " chromite, at elevated temperature, for example at 150 to 300°C and elevated pressure, for example at 10 to 500 bar. From the reaction mixtures thus obtained, unreacted ammonia is generally separated by pressure relief, formed diamine and water by distillation at normal pressure or slightly reduced pressure, for example at 1 to 0.1 bar, and unreacted alkanolamine by distillation at slightly or strongly reduced pressure, for example at 500 to 10 mbar. This leaves a distillation residue for which no technical application possibility is currently known. This is therefore collected in depots and incinerated at high temperatures.
Idet en rekke diaminer fremstilles i stor teknisk skala ved den ovenfor omtalte fremgangsmåten, f.eks. etylendiamin, 1,2-propylendiamin og 1,6-heksametylendiamin, oppstår det store mengder av slike destillasjonsrester, som nå innenfor rammen av foreliggende oppfinnelse kan finne en teknisk anvendelse. Since a number of diamines are produced on a large technical scale by the above-mentioned method, e.g. ethylenediamine, 1,2-propylenediamine and 1,6-hexamethylenediamine, large quantities of such distillation residues occur, which can now find a technical application within the scope of the present invention.
De stabiliserte vandige polymeroppløsningene og/eller -dispersjonene ifølge oppfinnelsen kan inneholde destillasjonsrester av den ovenfor omtalte art, eksempelvis i mengder fra 0,001 til 3,0 vekt-%. Fortrinnsvis utgjør dette innholdet 0,1 till,0 vekt-%. The stabilized aqueous polymer solutions and/or dispersions according to the invention may contain distillation residues of the type mentioned above, for example in amounts from 0.001 to 3.0% by weight. Preferably, this content amounts to 0.1 to 0.0% by weight.
Fortrinnsvis inneholder de stabiliserte vandige polymeroppløsningene og/eller -dispersjonene ifølge oppfinnelsen destillasjonsrester fra fremstillingen av etylendiamin eller 1,2-propylendiamin ved katalyttisk aminering av etanolamin eller isopropanolamin. Preferably, the stabilized aqueous polymer solutions and/or dispersions according to the invention contain distillation residues from the production of ethylenediamine or 1,2-propylenediamine by catalytic amination of ethanolamine or isopropanolamine.
De øvrige bestanddelene i de stabiliserte vandige polymeroppløsningene og/eller -dispersjonene ifølge oppfinnelsen kan tilsvare teknikkens stand. Eksempelvis kan de som polymerer inneholde cellulosederivater, som hydroksyetylcellulose og karboksymetylcellulose, polysakkarider som xanthan og stivelser, eller guargummi, eksempelvis i mengder fr a0,01 til 5,0 vekt-%. The other components in the stabilized aqueous polymer solutions and/or dispersions according to the invention may correspond to the state of the art. For example, the polymers may contain cellulose derivatives, such as hydroxyethyl cellulose and carboxymethyl cellulose, polysaccharides such as xanthan and starches, or guar gum, for example in amounts from 0.01 to 5.0% by weight.
Ved de stabiliserte vandige polymeroppløsningene og/eller -dispersjonene ifølge oppfinnelsen kan det inneholdte vannet være av en hvilken som helst type. Eksempelvis kan det dreie seg om drikkevann, spillvann, overflatevann, og/eller sjøvann og/eller innsjøvann. In the case of the stabilized aqueous polymer solutions and/or dispersions according to the invention, the contained water can be of any type. For example, it could be drinking water, waste water, surface water, and/or sea water and/or lake water.
Videre kan også ytterligere tilsatser være tilstede, eksempelvis 0-10 vekt-% leire som bentonitt eller attapulgitt; 0-10 vekt-% borepartikler eller utborede leirer; 0-30 vekt-% baritt, ilmenitt eller jernoksyd; 0-30 vekt-% sand eller såkalte "proppants" som boksitt; salter som kaliumklorid, natriumklorid, kalsiumklorid osv. i en mengde på 0-40 vekt-%; videre glidemiddel, korrosjonsbeskyttelsesadditiver og baktericider, f.eks. sulfitter eller kvarternære ammoniumforbindelser og videre additiver som vanligvis anvendes i borehull-spylevæsker, overhalingsvæsker og "frac"-væsker. Furthermore, further additives can also be present, for example 0-10% by weight of clay such as bentonite or attapulgite; 0-10% by weight drilling particles or drilled clays; 0-30% by weight of barite, ilmenite or iron oxide; 0-30% by weight sand or so-called "proppants" such as bauxite; salts such as potassium chloride, sodium chloride, calcium chloride, etc. in an amount of 0-40% by weight; further lubricants, corrosion protection additives and bactericides, e.g. sulphites or quaternary ammonium compounds and further additives which are usually used in borehole flushing fluids, overhaul fluids and "frac" fluids.
Foreliggende oppfinnelse vedrører videre en fremgangsmåte til fremstilling av stabiliserte vandige polymeroppløsninger og/eller -dispersjoner som er kjennetegnet ved at man blander vandige polymeroppløsninger og/eller-dispersjoner som eventuelt inneholder vanlige tilsatser, med 0,001 til 3,0 vekt-% av et produkt som kan oppnås ved at man på i og for seg kjent måte omsetter alkanolaminer med ammoniakk i nærvær av hydrogen og katalysatorer til diaminer, og deretter fra reaksjonsblandingen avdestillerer uomsatte utgangsmaterialer, vann og det dannede diaminet. The present invention further relates to a method for the production of stabilized aqueous polymer solutions and/or dispersions which are characterized by mixing aqueous polymer solutions and/or dispersions which possibly contain common additives, with 0.001 to 3.0% by weight of a product which can be achieved by reacting alkanolamines with ammonia in the presence of hydrogen and catalysts to diamines in a known manner, and then unreacted starting materials, water and the formed diamine are distilled off from the reaction mixture.
Foreliggende oppfinnelse vedrører videre anvendelsen av produktet som kan oppnås ved at man på i og for seg kjent måte omsetter alkanolaminer med ammoniakk i nærvær av hydrogen og katalysatorer til diaminer, og deretter fra reaksjonsblandingen avdestillerer uomsatte utgangsmaterialer, vann og det dannede diaminet, til stabilisering av vandige polymer-oppløsninger og/eller -dispersjoner. The present invention further relates to the use of the product which can be obtained by reacting alkanolamines with ammonia in the presence of hydrogen and catalysts to diamines in a manner known per se, and then distilling off from the reaction mixture unreacted starting materials, water and the formed diamine, to stabilize aqueous polymer solutions and/or dispersions.
Endelig vedrører foreliggende oppfinnelse anvendelsen av stabiliserte vandige polymeroppløsninger og/eller -dispersjoner, som inneholder et produkt som kan oppnmås ved at man på i og for kjent måte omsetter alkanolaminer med ammoniakk i nærvær av hydrogen og katalysatorer til diaminer og deretter fra reaksjonsblandingen avdestillerer uomsatte utgangsmaterialer, vann og det dannede diaminet, ved utvinning av jordolje, spesielt ved anbringelse og behandling av borehull. Finally, the present invention relates to the use of stabilized aqueous polymer solutions and/or dispersions, which contain a product that can be obtained by reacting alkanolamines with ammonia in the presence of hydrogen and catalysts to diamines in a well-known manner and then distilling unreacted starting materials from the reaction mixture , water and the formed diamine, during the extraction of petroleum, especially during the placement and treatment of boreholes.
Ved fremgangsmåten til fremstilling av stabiliserte vandie polymer-oppløsninger og/eller -dispersjoner ifølge oppfinnelsen og ved anvendelsen av slike polymeroppløsninger og/eller -dispersjoner ifølge oppfinnelsen, kan de samme produktene anvendes og de samme forholdsreglene er foretrukket som ovenfor er beskrevet . for de stabiliserte vandige polymeroppløsningene og/eller -dispersjonene ifølge oppfinnelsen. In the method for producing stabilized aqueous polymer solutions and/or dispersions according to the invention and in the use of such polymer solutions and/or dispersions according to the invention, the same products can be used and the same precautions are preferred as described above. for the stabilized aqueous polymer solutions and/or dispersions according to the invention.
Foreliggende oppfinnelse utmerker seg ved at produkter som hittil ikke har hatt noen teknisk anvendelse kan anvendes teknisk. De stabiliserte vandige polymeroppløsningene og/eller -dispersjonene ifølge oppfinnelsen er som regel stabile til ca. 160"C og høyere. De er derfor overlegne de hittil kjente stabiliserte vandige polymeroppløsningene og/eller -dispersjonene i teknisk og/eller økonomisk henseende. The present invention is distinguished by the fact that products which have hitherto had no technical application can be used technically. The stabilized aqueous polymer solutions and/or dispersions according to the invention are generally stable to approx. 160"C and higher. They are therefore superior to the previously known stabilized aqueous polymer solutions and/or dispersions in technical and/or economic terms.
De følgende eksemplene beskriver oppfinnelsen uten å begrense dens omfang. The following examples describe the invention without limiting its scope.
Eksempel 1Example 1
700 isopropanolamin, 40 g ammoniakk og 10 1 hydrogen ble ved 190"C og ved et trykk på 160 bar pr. time pumpet gjennom en kontaktovn som var fylt med 1600 g Raney-nikkel. Deretter ble overskytende ammoniakk fradestillert fra reaksjonsblandingen under trykk, 1,2-propylendiamin og reaksjonsvannet ved normaltrykk, samt ved 100 mbar det uomsatte isopropanolaminet. Det oppsto pr. time 100 g destillasjonsrest. 700 isopropanolamine, 40 g ammonia and 10 1 hydrogen were pumped at 190"C and at a pressure of 160 bar per hour through a contact furnace which was filled with 1600 g Raney nickel. Then excess ammonia was distilled off from the reaction mixture under pressure, 1 ,2-propylenediamine and the reaction water at normal pressure, as well as at 100 mbar the unreacted isopropanolamine.There was formed per hour 100 g of distillation residue.
Eksempel 2Example 2
12,5 g handelsvanlig xanthan ble fordelt i 1000 g sjøvann (ifølge DIN 50900) under omrøring. Detter en svelletid på 16 timer ved romtemperatur ble viskositeten for oppløsningen målt i et Brookfield viskosimeter av type "LVTD" ved 60 opm. 12.5 g of commercial xanthan was distributed in 1000 g of seawater (according to DIN 50900) while stirring. After a swelling time of 16 hours at room temperature, the viscosity of the solution was measured in a Brookfield viscometer of the "LVTD" type at 60 rpm.
Deretter ble oppløsningen delt i fire like deler. Til tre deler ble det tilsatt 1,0 vekt-% av den ifølge eksempel 1 oppnådde destillasjonsresten, til den fjerde delen ble det tilsatt 1,0 vekt-% vann. The solution was then divided into four equal parts. To three parts was added 1.0% by weight of the distillation residue obtained according to example 1, to the fourth part was added 1.0% by weight of water.
De fremstilte oppløsningene ble fylt i stålbomber og omrullet i forskjellig tidspunkt ved 120 °C. The prepared solutions were filled into steel bombs and re-rolled at different times at 120 °C.
Etter avkjøling ble oppløsningene omrørt i kort tid og Brookfield viskositeten ble igjen målt. Resultatene fremgår av tabell 1. After cooling, the solutions were stirred for a short time and the Brookfield viscosity was again measured. The results appear in table 1.
Eksempel 3Example 3
Eksempel 2 ble gjentatt, men stålbombene ble omrullet ved 140 °C. Resultatene fremgår av tabell 1. Example 2 was repeated, but the steel bombs were rerolled at 140 °C. The results appear in table 1.
Eksempel 4Example 4
Eksempel 3 ble gjentatt, men i dette tilfellet ble bare 0,5 vekt-% av den ifølge eksempel 1 oppnådde destillasjonsresten tilsatt. Resultatene fremgår av tabell 1. Example 3 was repeated, but in this case only 0.5% by weight of the distillation residue obtained according to Example 1 was added. The results appear in table 1.
Eksempel 5Example 5
Eksempel 2 ble gjentatt, men stålbombene ble omrullet ved 160 "C. Resultatene fremgår av tabell 1. Example 2 was repeated, but the steel bombs were rerolled at 160 "C. The results appear in Table 1.
Eksemmpel 6 Example 6
5 g handelsvanlig hydroksyetylcellulose ble oppløst i 1 1 syntetisk sjøvann (ifølge DIN 50900). Den opnådde oppløsningen ble delt i seks like deler. To av disse delene ble blandet med 1 vekt-% av den ifølge eksempel 1 oppnådde destillasjonsresten, to andre deler ble blandet med 2 vekt-% magnesiumoksyd og de to gjenværende delene med lekt-% vann. Deretter ble av de tilstedeværende to identiske blandingene én lagret i 168 timer (= 7 dager) ved 100"C i en lukket glassflaske og den andre i 16 timer ved 150° C i en stålbombe. Brookfield-viskositeten ble målt før og etter varmebehandlingen. Resultatene fremgår fra tabell 2. 5 g of commercially available hydroxyethyl cellulose was dissolved in 1 1 of synthetic seawater (according to DIN 50900). The solution obtained was divided into six equal parts. Two of these parts were mixed with 1% by weight of the distillation residue obtained according to example 1, two other parts were mixed with 2% by weight of magnesium oxide and the two remaining parts with 1% water. Then, of the two identical mixtures present, one was stored for 168 hours (= 7 days) at 100°C in a closed glass bottle and the other for 16 hours at 150°C in a steel bomb. The Brookfield viscosity was measured before and after the heat treatment. The results appear from table 2.
Eksempel 7 Example 7
Det ble fremstilt fire blandinger med følgende sammensetning: Four mixtures were prepared with the following composition:
160 g syntetisk sjøvann,160 g synthetic seawater,
160 g 12 vekt-% vandig KC1-oppløsning,160 g 12% by weight aqueous KC1 solution,
80 g 20 vekt-% bentonitt-gel i ferskvann,80 g 20% by weight bentonite gel in fresh water,
4 g borestivelse ("Foragel S2"),4 g boron starch ("Foragel S2"),
4 g xanthan,4 g xanthan,
0,8 g karboksymetylcellulose ("Antisol FL 100").0.8 g of carboxymethyl cellulose ("Antisol FL 100").
Til tre av disse blandingene ble det tilsatt 1,0 vekt-% av den ifølge eksempel 1 oppnådde destillasjonsresten. Deretter ble alle blandingene fylt i stålbomber og eldet ved 150"C under omrulling. 1.0% by weight of the distillation residue obtained according to example 1 was added to three of these mixtures. Then all the mixtures were filled into steel bombs and aged at 150°C while rolling.
Før og etter elding ble det registrert data som er av betydning for spylevæsker for borehull. Resultatene fremgår av tabell 3. Before and after aging, data was recorded which is important for flushing fluids for boreholes. The results appear in table 3.
Eksempel 8Example 8
Til påvisning av den overlegne stabilisatorvirkningen som oppnås ved destillasjonsrestene som anvendes ifølge oppfinnelsen sammenlignet med de i SU 1039 949 A omtalte stabilisatorblandingene ble følgende forsøk gjennomført: 18,75 g handelsvanlig xanthan ble fordelt i 1500 g syntetisk sjøvann (ifølge DIN 50900) under omrøring. Etter en svelletid på 16 timer ved romtemperatur ble oppløsningen delt i seks like deler. To demonstrate the superior stabilizer effect achieved by the distillation residues used according to the invention compared to the stabilizer mixtures mentioned in SU 1039 949 A, the following experiment was carried out: 18.75 g of commercial xanthan was distributed in 1500 g of synthetic seawater (according to DIN 50900) while stirring. After a swelling time of 16 hours at room temperature, the solution was divided into six equal parts.
Til to prøver ble det tilsatt 1 vekt-% sjøvann. To andre prøver ble blandet med 1,0 vekt-% av den ifølge eksempel 1 oppnådde destillasjonsresten. 1% by weight of seawater was added to two samples. Two other samples were mixed with 1.0% by weight of the distillation residue obtained according to example 1.
De siste to prøvene ble blandet med 1,0 vekt-% av en blanding av 50 vekt-% talloljedestillat og 50 vekt-% trietanolamin-tris-glykoleter. The last two samples were mixed with 1.0% by weight of a mixture of 50% by weight tall oil distillate and 50% by weight triethanolamine-tris-glycol ether.
Deretter ble viskositeten for oppløsningene målt og de seks prøvene ble eldet i stålbomber ved 140 °C. Etter 48 timer og etter 75 timer ble det tatt ut tre bomber, disse ble avkjølt og viskositeten for innholdet ble målt. Then the viscosity of the solutions was measured and the six samples were aged in steel bombs at 140 °C. After 48 hours and after 75 hours, three bombs were taken out, these were cooled and the viscosity of the contents was measured.
Resultatene i tabell 4 viser at det virkelig oppnås en stabilisering ved tilsatsen av destillasjonsresten ifølge eksempel 1. The results in table 4 show that a stabilization is indeed achieved by the addition of the distillation residue according to example 1.
Claims (9)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19853522628 DE3522628A1 (en) | 1985-06-25 | 1985-06-25 | STABILIZED AQUEOUS SOLUTIONS AND / OR DISPERSIONS OF POLYMERS, THEIR PRODUCTION AND USE |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NO862316D0 NO862316D0 (en) | 1986-06-10 |
| NO862316L true NO862316L (en) | 1986-12-29 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO862316A NO862316L (en) | 1985-06-25 | 1986-06-10 | STABILIZED Aqueous SOLUTIONS AND / OR DISPERSIONS OF POLYMERS, AND THE PREPARATION AND USE THEREOF. |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0206168A3 (en) |
| DE (1) | DE3522628A1 (en) |
| DK (1) | DK296286A (en) |
| NO (1) | NO862316L (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19619079A1 (en) * | 1996-05-13 | 1997-11-20 | Thueringisches Inst Textil | Stabilising cellulose ether or ether-ester in the melt |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2873251A (en) * | 1956-09-19 | 1959-02-10 | Pan American Petroleum Corp | Non-clay-reactive drilling fluid |
| US3271307A (en) * | 1960-08-04 | 1966-09-06 | Petrolite Corp | Oil well treatment |
| NO812667L (en) * | 1980-08-08 | 1982-02-09 | Union Carbide Corp | TREATMENT OF PRINTED Aqueous Systems. |
| EP0130732B1 (en) * | 1983-06-22 | 1987-01-14 | Halliburton Company | Anionic polymer composition and its use for stimulating a subterranean formation |
-
1985
- 1985-06-25 DE DE19853522628 patent/DE3522628A1/en not_active Withdrawn
-
1986
- 1986-06-10 NO NO862316A patent/NO862316L/en unknown
- 1986-06-13 EP EP86108097A patent/EP0206168A3/en not_active Withdrawn
- 1986-06-24 DK DK296286A patent/DK296286A/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| DK296286D0 (en) | 1986-06-24 |
| DE3522628A1 (en) | 1987-01-08 |
| NO862316D0 (en) | 1986-06-10 |
| EP0206168A2 (en) | 1986-12-30 |
| DK296286A (en) | 1986-12-26 |
| EP0206168A3 (en) | 1988-10-05 |
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