NO833979L - INK PREPARATION - Google Patents
INK PREPARATIONInfo
- Publication number
- NO833979L NO833979L NO833979A NO833979A NO833979L NO 833979 L NO833979 L NO 833979L NO 833979 A NO833979 A NO 833979A NO 833979 A NO833979 A NO 833979A NO 833979 L NO833979 L NO 833979L
- Authority
- NO
- Norway
- Prior art keywords
- straight
- chain
- amine oxide
- thickened
- chain amine
- Prior art date
Links
- 238000002360 preparation method Methods 0.000 title claims description 23
- 150000001412 amines Chemical class 0.000 claims description 34
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Inorganic materials Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 18
- -1 alkali metal hypochlorite Chemical class 0.000 claims description 14
- 238000004061 bleaching Methods 0.000 claims description 14
- 239000002562 thickening agent Substances 0.000 claims description 14
- 229910052783 alkali metal Inorganic materials 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 3
- 239000003085 diluting agent Substances 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 5
- 239000007844 bleaching agent Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000008719 thickening Effects 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 239000005708 Sodium hypochlorite Substances 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 229940071089 sarcosinate Drugs 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- ZUFONQSOSYEWCN-UHFFFAOYSA-M sodium;2-(methylamino)acetate Chemical compound [Na+].CNCC([O-])=O ZUFONQSOSYEWCN-UHFFFAOYSA-M 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3953—Inorganic bleaching agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Medicinal Preparation (AREA)
Description
Oppfinnelsen vedrører bleke- og rensepreparater som inneholder hypokloritt, og spesielt fortykkede blekepreparater, The invention relates to bleaching and cleaning preparations containing hypochlorite, and in particular thickened bleaching preparations,
det vil si produkter som har øket viskositet sammenlignet med rent vandige løsninger av alkalimetallhypokloritt. that is, products that have increased viscosity compared to purely aqueous solutions of alkali metal hypochlorite.
Fortykkede blekepreparater har en rekke fordeler i forhold til ufortykkede blekepreparater ved det at de mer viskøse produkter fester seg lettere og for lengre tid til vertikale og skrånende flater enn de ufortykkede produkter gjør. Ydelsen til fortykkede blekepreparater er derfor meget bedre enn for ufortykkede blekepreparater for vertikale og skrånende flater slik de påtreffes i vaskeservanter, urinaler, utslagsvasker, avløpsrør og lignende. I de senere år er det fremsatt en rekke forslag som gir fortykkede blekepreparater, f.eks. produkter med viskositeter ved 25°C på mer enn 10 centistoke ved til-setning av egnede fortykningsmidler. Thickened bleaching preparations have a number of advantages compared to unthickened bleaching preparations in that the more viscous products stick more easily and for longer to vertical and sloping surfaces than the unthickened products do. The performance of thickened bleaching preparations is therefore much better than that of non-thickened bleaching preparations for vertical and sloping surfaces such as those found in wash basins, urinals, wash basins, drain pipes and the like. In recent years, a number of proposals have been put forward that provide thickened bleaching preparations, e.g. products with viscosities at 25°C of more than 10 centistokes when suitable thickeners are added.
Britisk patent nr. 1.329.086 beskriver fortykkede vandige alkalimetallhypokloritt-blandinger som inneholder, i tillegg til hypoklorittet, et alkalimetallsalt av en Cg - C^g- fullt mettet fettsyre og et hypokloritt-løselig overflateaktivt middel, idet sistnevnte er eksemplifisert ved et aminoksyd som inneholder en Cg - C^g-alkylgruppe. De aminoksyder som er beskrevet i patentskriftet er slike som er kommersielt tilgjenge-lige og som stammer fra naturlig forekommende Cg-C^g-fettsyrer, f.eks. kokosnøttsyrer, laurinsyre og myristinsyre. British Patent No. 1,329,086 discloses thickened aqueous alkali metal hypochlorite mixtures containing, in addition to the hypochlorite, an alkali metal salt of a Cg - C^g fully saturated fatty acid and a hypochlorite-soluble surfactant, the latter being exemplified by an amine oxide which contains a C 8 -C 8 alkyl group. The amine oxides described in the patent document are those which are commercially available and which originate from naturally occurring Cg-Cg fatty acids, e.g. coconut acids, lauric acid and myristic acid.
Britisk patent nr. 1.466.560 beskriver fortykkede vandige alkalimetallhypokloritt-blandinger hvor fortykningen oppnås ved å blande hypoklorittløsninger med kombinasjoner av visse sarkosinat- eller taurid-overflateaktive midler med ett eller flere andre overflateaktive midler som kan omfatte visse såper, kvaternære ammoniumforbindelser, aminoksyder, betainer og/eller alkanolamider. British Patent No. 1,466,560 describes thickened aqueous alkali metal hypochlorite mixtures where the thickening is achieved by mixing hypochlorite solutions with combinations of certain sarcosinate or tauride surfactants with one or more other surfactants which may include certain soaps, quaternary ammonium compounds, amine oxides, betaines and/or alkanolamides.
Britisk patent nr. 1.584.379 beskriver fortykkede blekepreparater som omfatter en vandig løsning av et alkalimetallhypokloritt som inneholder (a) et sukrose-overflateaktivt middel som består av en eller flere estere av en langkjedet fettsyre med sukrose og (b) et annet hypoklorittløselig overflateaktivt middel, f.eks. en kvaternær ammoniumforbindelse, British Patent No. 1,584,379 discloses thickened bleaching preparations comprising an aqueous solution of an alkali metal hypochlorite containing (a) a sucrose surfactant consisting of one or more esters of a long-chain fatty acid with sucrose and (b) another hypochlorite-soluble surfactant , e.g. a quaternary ammonium compound,
et aminoksyd, et betain eller alkanolamid.an amine oxide, a betaine or alkanolamide.
Britisk patent nr. 2.051.162A beskriver fortykkede vandige alkalimetallhypoklorittblandinger som inneholder, i tillegg til hypoklorittet, et aminoksyd og et alkalimetallalkylsulfat, British Patent No. 2,051,162A discloses thickened aqueous alkali metal hypochlorite mixtures containing, in addition to the hypochlorite, an amine oxide and an alkali metal alkyl sulfate,
britisk patent nr. 2.003.522A beskriver fortykkede vandige alkalimetallhypoklorittblandinger som inneholder et C0-C_ - aminoksyd med forgrenet kjede eller en blanding av slike aminoksyder eller en blanding av et slikt aminoksyd med forgrenet kjede og et aminoksyd med rett kjede. British Patent No. 2,003,522A discloses thickened aqueous alkali metal hypochlorite mixtures containing a C0-C_ - branched chain amine oxide or a mixture of such amine oxides or a mixture of such a branched chain amine oxide and a straight chain amine oxide.
Selv om fortykkede blekemidler som inneholder en enkelt forbindelse som fortykningsmiddel er beskrevet (se f.eks. britisk patent nr. 2.003.522A omtalt ovenfor), er det funnet å være økonomisk fordelaktig å anvende minst to, vanligvis organiske, forbindelser som fortykningsmidler for den vandige hypoklorittløsning. Et typisk og velkjent eksempel er det som er beskrevet i britisk patentskrift nr. 1.329.086 hvor fortykning oppnås ved en kombinasjon av en såpe og et aminoksyd i spesifiserte mengdeforhold. Although thickened bleaches containing a single compound as a thickener have been described (see, for example, British Patent No. 2,003,522A discussed above), it has been found to be economically advantageous to use at least two, usually organic, compounds as thickeners for the aqueous hypochlorite solution. A typical and well-known example is that described in British patent document no. 1,329,086, where thickening is achieved by a combination of a soap and an amine oxide in specified proportions.
Vi har nå overraskende funnet at det er mulig å fremstille fortykkede blekepreparater ved å anvende i det vesentlige en enkelt forbindelse av en spesiell type som fortykningsmiddel, idet den totale omkostning ved slike produkter er sammenlignbar med prisen på blandinger som inneholder to forbindelser som fortykningsmidler. We have now surprisingly found that it is possible to produce thickened bleach preparations by essentially using a single compound of a special type as a thickener, the total cost of such products being comparable to the price of mixtures containing two compounds as thickeners.
Følgelig tilveiebringer foreliggende oppfinnelse et fortykket blekepreparat som omfatter vann, et alkalimetallhypokloritt, og et organisk fortykningsmiddel som utelukkende består av et rettkjedet aminoksyd eller en blanding av rettkjedete aminoksyder hvor aminoksydet (eller minst det ene aminoksyd) Accordingly, the present invention provides a thickened bleach preparation comprising water, an alkali metal hypochlorite, and an organic thickener consisting exclusively of a straight-chain amine oxide or a mixture of straight-chain amine oxides where the amine oxide (or at least one amine oxide)
har minst 14 karbonatomer i den rette kjede. Ideelt må det organiske fortykningsmiddel bestå av et i alt vesentlig rent Cj^- eller,fortrinnsvis, C^-rettkjedet aminoksyd alene. Preparater i henhold til foreliggende oppfinnelse inneholder ingen betydelige mengder, av organisk f ortykningsmiddel bortsett fra rettkjedet aminoksyd. has at least 14 carbon atoms in the straight chain. Ideally, the organic thickening agent must consist of an essentially pure C 1 - or, preferably, C 1 -straight-chain amine oxide alone. Preparations according to the present invention do not contain significant amounts of organic thickening agent apart from straight-chain amine oxide.
Rettkjedete aminoksyder som inneholder mer enn 15 karbonatomer i den rette kjede har begrenset løselighet i alkalimetallhypokloritt-løsninger. Imidlertid kan de inkorporeres i fortykkede blekepreparater forutsatt at egnede solubiliserings-midler anvendes. Vi har funnet at rettkjedete aminoksyder som inneholder mindre enn 16 karbonatomer i den rette kjede kan Straight-chain amine oxides containing more than 15 carbon atoms in the straight chain have limited solubility in alkali metal hypochlorite solutions. However, they can be incorporated into thickened bleaching preparations provided that suitable solubilizers are used. We have found that straight chain amine oxides containing less than 16 carbon atoms in the straight chain can
anvendes for dette formål.are used for this purpose.
Eventuelt kan fortykkede blekemidler i henhold til foreliggende oppfinnelse inneholde ytterligere komponenter som hyppig inkorporeres i slike blandinger, inklusive kaustisk alkali, alkalimetallsalter, parfyme og farvemidler. Derfor kan produkter i henhold til foreliggende oppfinnelse inkludere kaustisk alkali, f.eks. natriumhydroksyd, og/eller et alkalimetallsalt, f.eks. natriumklorid, idet hvert er til stede fortrinnsvis i en mengde av 0,5 - 5vekt%. En parfyme og/eller et fargemiddel kan også være til stede i blandingen. Optionally, thickened bleaching agents according to the present invention may contain additional components that are frequently incorporated in such mixtures, including caustic alkali, alkali metal salts, perfume and coloring agents. Therefore, products according to the present invention may include caustic alkali, e.g. sodium hydroxide, and/or an alkali metal salt, e.g. sodium chloride, each being present preferably in an amount of 0.5 - 5% by weight. A perfume and/or a coloring agent may also be present in the mixture.
Blekepreparatene i henhold til oppfinnelsen inneholder fortrinnsvis en mengde av tilgjengelig klor i området 1 - 15, fortrinnsvis 5-10, vekt%. The bleaching preparations according to the invention preferably contain an amount of available chlorine in the range 1-15, preferably 5-10, wt%.
Preparatene i henhold til oppfinnelsen har fortrinnsvisThe preparations according to the invention preferably have
en viskositet på minst 10 centistoke ved 25°C, målt med et Ostwald-viskosimeter, og et tåkepunkt i overkant av 35°C. a viscosity of at least 10 centistokes at 25°C, measured with an Ostwald viscometer, and a cloud point in excess of 35°C.
De følgende eksempler, hvor alle deler og prosenter angir vekt, og alle viskositeter er målt ved 25°C med et Ostwald-viskosimeter, illustrerer videre fortykkede blekepreparater i henhold til oppfinnelsen. The following examples, where all parts and percentages indicate weight, and all viscosities are measured at 25°C with an Ostwald viscometer, further illustrate thickened bleach preparations according to the invention.
Eksempler 1 til 14Examples 1 to 14
Det ble fremstilt en rekke fortykkede blekepreparater vedA number of thickened bleaching preparations were made from
å blande natriumhypokloritt, slik at man fikk et tilgjengelig klornivå på 8%, natriumhydroksyd, natriumklorid og et enkelt2-Cig-rettkjedet aminoksyd i kaldt vann. En lignende blanding, identifisert som blanding A, som ikke inneholdt noe aminoksyd, ble også fremstilt, for sammenligningsformål. Detaljer angående blandingene, deres viskositeter og tåkepunkter er vist i tabell 1 . to mix sodium hypochlorite, so that an available chlorine level of 8% was obtained, sodium hydroxide, sodium chloride and a single 2-Cig straight chain amine oxide in cold water. A similar mixture, identified as mixture A, which contained no amine oxide, was also prepared, for comparison purposes. Details regarding the mixtures, their viscosities and cloud points are shown in Table 1.
Resultatene viser at fortykningsoppførselen til rettkjedete aminoksyder øker med økende kjedelengde. Løseligheten hos rettkjedete aminoksyder i natriumhypoklorittløsninger avtar med økende kjedelengde. The results show that the thickening behavior of straight-chain amine oxides increases with increasing chain length. The solubility of straight-chain amine oxides in sodium hypochlorite solutions decreases with increasing chain length.
Eksempler 15 til 26Examples 15 to 26
Det ble fremstilt en rekke fortykkede blekepreparater vedA number of thickened bleaching preparations were made from
å blande natriumhypokloritt, slik at man fikk et tilgjengelig klornivå på 8%, natriumhydroksyd, natriumklorid og blandinger to mix sodium hypochlorite, so that an available chlorine level of 8% was obtained, sodium hydroxide, sodium chloride and mixtures
av C-J2- ' C14~°^g-rettkjedete aminoksyder i kaldt vann. of C-J2- ' C14~°^g-straight-chain amine oxides in cold water.
Detaljer for blandingene og deres egenskaper er vist i tabell 2, og resultatene illustrerer den solubiliserende effekt hos lavere rettkjedete aminoksyder på blandinger som inneholder C^g-kjedete aminoksyder. Details of the mixtures and their properties are shown in Table 2, and the results illustrate the solubilizing effect of lower straight chain amine oxides on mixtures containing C₁₂ chained amine oxides.
Eksemplene viser at teknisk og økonomisk akseptable fortykkede blekemidler kan fremstilles ved anvendelse av et enkelt organisk fortykningsmiddel (hvor midlet omfatter et enkelt rettkjedet amin eller en blanding av rettkjedete aminoksyder uten noe annet organisk fortykningsmiddel til stede) i motsetning til den som for tiden er på markedet, som generelt inneholder minst to organiske fortykningsmidler. På samme tid illustrerer eksemplene at akseptabel fortykning kan oppnås ved anvendelse av aminoksyd hvor alkylgruppen helt ut er en rettkjedet gruppe. The examples show that technically and economically acceptable thickened bleaches can be prepared using a single organic thickener (where the agent comprises a single straight-chain amine or a mixture of straight-chain amine oxides without any other organic thickener present) as opposed to that currently on the market , which generally contain at least two organic thickeners. At the same time, the examples illustrate that acceptable thickening can be achieved by using amine oxide where the alkyl group is completely a straight chain group.
Claims (4)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8231264 | 1982-11-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO833979L true NO833979L (en) | 1984-05-03 |
Family
ID=10533985
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO833979A NO833979L (en) | 1982-11-02 | 1983-11-01 | INK PREPARATION |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0110544A1 (en) |
| JP (1) | JPS5998200A (en) |
| AU (1) | AU562925B2 (en) |
| DK (1) | DK500783A (en) |
| NO (1) | NO833979L (en) |
| NZ (1) | NZ206092A (en) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8325541D0 (en) * | 1983-09-23 | 1983-10-26 | Unilever Plc | Liquid thickened bleaching composition |
| FR2570713B1 (en) * | 1984-09-21 | 1987-08-21 | Lesieur Cotelle | THICK AQUEOUS CLEANING COMPOSITIONS |
| US4800036A (en) * | 1985-05-06 | 1989-01-24 | The Dow Chemical Company | Aqueous bleach compositions thickened with a viscoelastic surfactant |
| GB8630845D0 (en) * | 1986-12-24 | 1987-02-04 | Ici Plc | Bleaching compositions |
| GB8807752D0 (en) * | 1988-03-31 | 1988-05-05 | Unilever Plc | Bleaching composition |
| US4900467A (en) * | 1988-05-20 | 1990-02-13 | The Clorox Company | Viscoelastic cleaning compositions with long relaxation times |
| US4946619A (en) * | 1988-07-19 | 1990-08-07 | The Clorox Company | Solubilization of brighter in liquid hypochlorite |
| US5034150A (en) * | 1989-05-03 | 1991-07-23 | The Clorox Company | Thickened hypochlorite bleach solution and method of use |
| US5279758A (en) * | 1991-10-22 | 1994-01-18 | The Clorox Company | Thickened aqueous cleaning compositions |
| US5705467A (en) * | 1991-10-22 | 1998-01-06 | Choy; Clement K. | Thickened aqueous cleaning compositions and methods of use |
| ZA935882B (en) * | 1992-10-19 | 1994-03-11 | Clorox Co | Composition and method for developing extensional viscosity in cleaning compositions. |
| WO2001041571A1 (en) | 1999-12-10 | 2001-06-14 | Kao Corporation | Microbicide compositions |
| US9637708B2 (en) | 2014-02-14 | 2017-05-02 | Ecolab Usa Inc. | Reduced misting and clinging chlorine-based hard surface cleaner |
| US10519327B2 (en) | 2018-04-20 | 2019-12-31 | Redjak, L.L.C. | Methods and coatings for protecting surfaces from bio-fouling species |
| US10829649B2 (en) | 2018-04-20 | 2020-11-10 | Redjak, L.L.C. | Methods and coatings for protecting surfaces from bio-fouling species |
| US10689527B2 (en) | 2018-04-20 | 2020-06-23 | Redjak, L.L.C | Methods and coatings for protecting surfaces from bio-fouling species |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE755338A (en) * | 1969-08-29 | 1971-02-26 | Unilever Nv | BLEACHING COMPOSITIONS |
| GB1466560A (en) * | 1974-02-05 | 1977-03-09 | Jeyes Group Ltd | Bleach compositions |
| US4229313A (en) * | 1977-09-02 | 1980-10-21 | Imperial Chemical Industries Limited | Alkali metal hypochlorite bleaching and cleaning compositions thickened with branch chain amine oxides |
| GB2003522B (en) * | 1977-09-02 | 1982-02-24 | Ici Ltd | Bleaching and cleaning compositions |
| CH647543A5 (en) * | 1980-05-13 | 1985-01-31 | Sandoz Ag | HYPOCHLORITE-BASED CLEANER WITH THICKENING AGENTS. |
| EP0079697B2 (en) * | 1981-11-07 | 1990-03-14 | THE PROCTER & GAMBLE COMPANY | Cleaning compositions |
-
1983
- 1983-10-24 EP EP83306440A patent/EP0110544A1/en not_active Withdrawn
- 1983-10-28 AU AU20804/83A patent/AU562925B2/en not_active Ceased
- 1983-10-28 NZ NZ206092A patent/NZ206092A/en unknown
- 1983-11-01 NO NO833979A patent/NO833979L/en unknown
- 1983-11-01 DK DK500783A patent/DK500783A/en not_active Application Discontinuation
- 1983-11-02 JP JP58206823A patent/JPS5998200A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| NZ206092A (en) | 1986-03-14 |
| DK500783D0 (en) | 1983-11-01 |
| AU2080483A (en) | 1984-05-10 |
| JPS5998200A (en) | 1984-06-06 |
| AU562925B2 (en) | 1987-06-25 |
| JPH0425319B2 (en) | 1992-04-30 |
| EP0110544A1 (en) | 1984-06-13 |
| DK500783A (en) | 1984-05-03 |
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| Publication | Publication Date | Title |
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| NO833979L (en) | INK PREPARATION | |
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| US4680143A (en) | Detergent compositions | |
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| NO844779L (en) | INK PREPARATION | |
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| NO140678B (en) | FOAMY DISHWASHER MIXTURE. | |
| NO851850L (en) | SOLUTION MIXING. | |
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| GB938783A (en) | Liquid detergent compositions | |
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