NO823145L - ALKALIC AND CHLORABLE STABLE CLEANER. - Google Patents
ALKALIC AND CHLORABLE STABLE CLEANER.Info
- Publication number
- NO823145L NO823145L NO823145A NO823145A NO823145L NO 823145 L NO823145 L NO 823145L NO 823145 A NO823145 A NO 823145A NO 823145 A NO823145 A NO 823145A NO 823145 L NO823145 L NO 823145L
- Authority
- NO
- Norway
- Prior art keywords
- weight
- sodium
- product
- approx
- cleaning agent
- Prior art date
Links
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 48
- 239000000203 mixture Substances 0.000 claims abstract description 43
- 239000008187 granular material Substances 0.000 claims abstract description 39
- 239000012459 cleaning agent Substances 0.000 claims abstract description 30
- 239000000047 product Substances 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 20
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 20
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 18
- 239000000460 chlorine Substances 0.000 claims abstract description 18
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 18
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 18
- 235000019795 sodium metasilicate Nutrition 0.000 claims abstract description 17
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 17
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- 239000004094 surface-active agent Substances 0.000 claims abstract description 12
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 11
- 229910000318 alkali metal phosphate Inorganic materials 0.000 claims abstract description 6
- 238000005187 foaming Methods 0.000 claims abstract description 3
- 239000010453 quartz Substances 0.000 claims abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 3
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims description 7
- 239000003513 alkali Substances 0.000 claims description 6
- CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 claims description 5
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 3
- 239000013078 crystal Substances 0.000 claims description 3
- 239000006260 foam Substances 0.000 claims description 3
- 239000000080 wetting agent Substances 0.000 claims description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 235000013312 flour Nutrition 0.000 claims description 2
- 239000001488 sodium phosphate Substances 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 2
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 2
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 2
- 239000012084 conversion product Substances 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 abstract description 4
- 235000019353 potassium silicate Nutrition 0.000 abstract description 4
- 239000000843 powder Substances 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 description 16
- 235000011121 sodium hydroxide Nutrition 0.000 description 12
- 230000000694 effects Effects 0.000 description 9
- 238000003860 storage Methods 0.000 description 8
- 230000015556 catabolic process Effects 0.000 description 6
- 235000017550 sodium carbonate Nutrition 0.000 description 6
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 5
- 239000003599 detergent Substances 0.000 description 5
- 239000002736 nonionic surfactant Substances 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000004851 dishwashing Methods 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- 235000012241 calcium silicate Nutrition 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 235000019737 Animal fat Nutrition 0.000 description 1
- 240000004178 Anthoxanthum odoratum Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical class [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- -1 cutlery Inorganic materials 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 235000012243 magnesium silicates Nutrition 0.000 description 1
- 238000009896 oxidative bleaching Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3958—Bleaching agents combined with phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Oppfinnelsen vedrører et alkalisk og klorstabilt rengjørings-middel som fortrinnsvis er egnet til anvendelse i oppvask-maskiner og som vesentlig bestanddel inneholder et blandingsgranulat som overveiende består av fosfater, silikater og hjelpestoffer. The invention relates to an alkaline and chlorine-stable cleaning agent which is preferably suitable for use in dishwashers and which contains as an essential component a mixed granulate which predominantly consists of phosphates, silicates and auxiliaries.
Oppvask- eller rengjøringsmidler for apparatrensning i næringsmiddelindustrien inneholder vanligvis alkalifosfater, fortrinnsvis natriumtrifosfat, alkalisilikater- karbonater, bikarbonater, -hydroksyder, skumfattige ikke-ionogene tensider, oksydative blekemidler, spesielt aktivkloravspaltende forbindelser, samt korrosjonsinhibitorer og klorstabilisatorer. Dishwashing or cleaning agents for appliance cleaning in the food industry usually contain alkali phosphates, preferably sodium triphosphate, alkali silicates-carbonates, bicarbonates, -hydroxides, low-foaming non-ionic surfactants, oxidative bleaches, especially active chlorine-releasing compounds, as well as corrosion inhibitors and chlorine stabilizers.
Funksjonen av de enkelte rengjøringsmiddelkomponenter bestårThe function of the individual cleaning agent components consists
i at natriumtrifosfat komplekst binder vannets hårdhetsdannere, mens alkalisilikater sterkt hindrer korrosjoner av oppvaskgjenstander som f.eks. glass, porselen, bestikk, edelstålmaterialer og lignende. Alkalikairbonater, -bikaron-ater og -hydroksyder øker rengjøringsvirkningen av rengjørings-midlene og befrir oppvaskgjenstandene spesielt for plante- og dyrisk fett. Ved hjelp av oksydative blekemidler fjernes farvetilsmussinger, som f.eks. te, kaffe, frukt- og grønnsak-safter fra oppvaskgjenstanden, mens tensidene øker oppvask-gjenstandenes fuktbarhet. in that sodium triphosphate complexly binds the water's hardness generators, while alkali silicates strongly prevent corrosion of washing-up items such as e.g. glass, porcelain, cutlery, stainless steel materials and the like. Alkali carbonates, bicarbonates and hydroxides increase the cleaning effect of the cleaning agents and free the dishes, especially from vegetable and animal fat. With the help of oxidative bleaching agents, color stains are removed, such as e.g. tea, coffee, fruit and vegetable juices from the dishes, while the surfactants increase the wettability of the dishes.
Moderne oppvarskmidler må være ikke-støvende, god risle-dyktige og hurtig oppløselige i vann. De må dessuten danne et fra oppvaskmaskinens doseringsinnretninger godt og fullstendig utspylbart produkt og i oppbevaring av en høy lagringsstabilitet med hensyn til aktivkloravspaltende forbindelser.. Modern cleaning agents must be non-dusty, have good trickle-ability and quickly dissolve in water. They must also form a product that can be easily and completely rinsed from the dishwasher's dosing devices and, in storage, have a high storage stability with regard to active chlorine-releasing compounds.
For å bedre utspylbarheten av oppvaskmiddelet fra doserings-innretningene og å hindre en sammenbakning av produktet inneholder handelsvanlige rengjøringsmidler fortrinnsvis del-hydratiserte råstoffer eller de granuleres ved hjelp av vann. Det til granuleringen nødvendige vann og/eller råstoffenes krystallvann bevirker imidlertid en hurtig nedbrytning av de i rengjøringsmidlene inneholdt aktivkloravspaltende forbindelser som f.eks. diklorisocyanurater. Denne uønskede effekt som fører til en vesentlig dårligere rengjørings-virkning av rengjøringsmiddelet forsøkte man som omtalt i DE-AS 23 50 295 mest mulig å hindre ved anvendelse av stabilisator for den aktivkloravspaltende forbindelse. In order to improve the washability of the washing-up liquid from the dosing devices and to prevent caking of the product, commercial cleaning agents preferably contain partially hydrated raw materials or they are granulated using water. The water required for the granulation and/or the crystal water of the raw materials, however, causes a rapid breakdown of the active chlorine-releasing compounds contained in the cleaning agents, such as e.g. dichloroisocyanurates. As mentioned in DE-AS 23 50 295, an attempt was made to prevent this unwanted effect, which leads to a significantly worse cleaning effect of the cleaning agent, as much as possible by using a stabilizer for the active chlorine-releasing compound.
En begunstigelse av den for tidlige spaltning av de aktiv-klorspaltende forbindelser med vann i fravær av spesielle stabilisatorer inntrer også når gjengjøringsmiddelet inneholder hydroskopiske komponenter som f.eks. alkalisilikater. En granulering av alkalisilikatene med natriumtripolyfosfat i henhold til fremgangsmåten ifølge DE-AS 24 54 448 er ikke tilstrekkelig til å fjerne overnevnte ulempe med alkalisilikatene da det i granulatet, dvs. også på granulatpartiklenes overflate er granulatbestanddelene homogent fordelt og derved hindres ikke et vannopptak av silikater. Granulatet tenderer også i dette tilfelle til sammenbakning. A favoring of the premature splitting of the active chlorine-splitting compounds with water in the absence of special stabilizers also occurs when the restoring agent contains hydroscopic components such as e.g. alkali silicates. A granulation of the alkali silicates with sodium tripolyphosphate according to the method according to DE-AS 24 54 448 is not sufficient to remove the above-mentioned disadvantage of the alkali silicates, as the granulate components are homogeneously distributed in the granulate, i.e. also on the surface of the granulate particles, and thereby water absorption by silicates is not prevented . In this case, the granules also tend to stick together.
En delløsning av det i et foregående påviste problem erA partial solution to the previously proven problem is
det i DE-AS 28 22 765 åpenbarte granulat. Det dreier seg herved om et granulert råmateriale for vask-, fettfjerning- the granules disclosed in DE-AS 28 22 765. This concerns a granulated raw material for washing, degreasing
og rengjøringsmiddel-tilberedninger som i det vesentlige består av natrium- eller kaliumsilikat eller -tripolyfosfat og hvor silikatet er beskyttet mot kontakt med fuktighet, and cleaning agent preparations which essentially consist of sodium or potassium silicate or -tripolyphosphate and where the silicate is protected against contact with moisture,
C02, tensider, klorholdige blekemidler og andre bestand-C02, surfactants, chlorine-containing bleaches and other ingredients
deler av den endelige tilberedning som videre ved oppløsning i hårdt vann ikke fører til en utfelling av slørdannende svakt oppløselig kalsiumsilikater, hvilket erkarakterisertved at det består av en indre silikatkjerne og et ytre sjikt, idet minste av delvis hydratisert tripolyfosfat, parts of the final preparation which, when further dissolved in hard water, do not lead to a precipitation of veil-forming, slightly soluble calcium silicates, which is characterized by the fact that it consists of an inner silicate core and an outer layer, the smallest of partially hydrated tripolyphosphate,
idet hydratiseringsgraden bestemmes av vannmengden som kreves til belegg av silikatkornene med tripolyfosfat. the degree of hydration being determined by the amount of water required to coat the silicate grains with tripolyphosphate.
Det kjente granulat anses derfor som fordelaktig som be standdel av rengjøringsformuleringer fordi f.eks. ved anvendelse av hårdt vann i oppvaskmaskinen binder det primært oppløste tripolyfosfat vannets hårdhetsdannere komplekst på forhånd og således hindres den etterfølgende dannelse av tungtoppløselige kalsium- og magnesiumsilikater fra granu-latkjernens stoff. The known granules are therefore considered advantageous as part of cleaning formulations because e.g. when using hard water in the dishwasher, the primarily dissolved tripolyphosphate binds the water's hardness formers complexly in advance and thus prevents the subsequent formation of poorly soluble calcium and magnesium silicates from the substance of the granulate core.
Granulatet ifølge DE-AS 28 22 765 er imidlertid beheftet med den ulempe at det bare består av to komponenter, nemlig alkalisilikat og tripolyfosfat. Til fremstilling av oppvaskmidler eller rengjøringsmidler til rengjøring av bruks-gjenstander og maskiner, f.eks. for næringsmiddelindustrien er imidlertid det kjente granulat ikke alene tilstrekkelig. Eksempelvis må det i en industriell oppvaskmaskin på grunn However, the granulate according to DE-AS 28 22 765 suffers from the disadvantage that it only consists of two components, namely alkali silicate and tripolyphosphate. For the production of washing-up agents or cleaning agents for cleaning utility objects and machines, e.g. for the food industry, however, the known granules alone are not sufficient. For example, it must be in an industrial dishwasher
av de korte rengjøringstider som utgjør delvis bare 40 sekunder anvendes oppvaskmidler med en høyere alkalitet. of the short cleaning times, which amount to only 40 seconds in some cases, detergents with a higher alkalinity are used.
For å oppnå den nødvendige alkalitetsgrad er det nødvendigIn order to achieve the required degree of alkalinity, it is necessary
i rengjøringsmidlene å innføre høyalkaliske komponenter fortrinnsvis alkalihydroksyder og- karbonater ved siden av det foran nevnte blandingsgranulat samt ikke-ionogene skumfattige tensider og aktivkloravspaltende stoffer. in the cleaning agents to introduce high-alkaline components, preferably alkali hydroxides and carbonates, alongside the above-mentioned mixed granules as well as non-ionic low-foam surfactants and active chlorine-releasing substances.
Anvendelsen av terke alkaliske forbindelser, spesieltThe use of strong alkaline compounds, in particular
natrium- eller kaliumhydroksyder i rengjøringsformuleringene er imidlertid meget problematisk da de ødelegger de i opp-vaskrengjøringsmidler hyppig anvendte ikke-ionogene tensider eller ved deres hydroskopiske egenskaper opptar vann fra omgivelsene og således sterkt akselererer nedbrytningen av aktivklorholdige forbindelser som diklorisocyanurater. sodium or potassium hydroxides in the cleaning formulations is, however, very problematic as they destroy the non-ionic surfactants frequently used in dishwashing detergents or, due to their hydroscopic properties, absorb water from the surroundings and thus strongly accelerate the breakdown of active chlorine-containing compounds such as dichloroisocyanurates.
Oppfinnelsens gjenstand er nu en alkalisk og klorstabilt rengjøringsmiddelblanding som ikke har de overnevnte ulemper og minst inneholder et Co-granulat på basis av et alkalimetasilikat. Rengjøringsmiddelet ifølge oppfinnelsen erkarakterisert vedat i det vesentlige består av : The object of the invention is now an alkaline and chlorine-stable cleaning agent mixture which does not have the above-mentioned disadvantages and at least contains a Co granulate based on an alkali metasilicate. The cleaning agent according to the invention is characterized by essentially consisting of:
ca. 0,5 til 20 vekt-% av et skumfattig tensid,about. 0.5 to 20% by weight of a low-foam surfactant,
ca. 0,5 til 10 vekt-% av en aktivkloravspaltende forbindelse about. 0.5 to 10% by weight of an active chlorine-releasing compound
samt as well
ca. 70 til 99 vekt-% av minst et Co-granulatabout. 70 to 99% by weight of at least one Co granule
som er blitt dannet ved granulering av produktene A, B eller C med pulverformet alkalimetallfosfat, fortrinnsvis, natriumtripolyfosfat og vann, idet which has been formed by granulating the products A, B or C with powdered alkali metal phosphate, preferably sodium tripolyphosphate and water,
A. er en blanding av ca. 99,5 til 80 vekt-% natriummetasilikat og ca. 0,5 til 20 vekt-% natriumhydroksyd, dannet ved omsetning av kvartsmel med natriumhydroksyd i overskudd, A. is a mixture of approx. 99.5 to 80% by weight sodium metasilicate and approx. 0.5 to 20% by weight sodium hydroxide, formed by reaction of quartz flour with sodium hydroxide in excess,
B. er omsetningproduktet av produktet A med en sur forbindelse, spesielt natriumbikarbonat og C. er omsetningsproduktet av produktet A med vannglass under lufttilførsel, således at ved siden av det derved dannede natriummetasilikat foreligger en natriumkarbonat-del inntil 10 vekt-%, samt et vanninnhold inntil 10 vekt-%, B. is the reaction product of product A with an acidic compound, especially sodium bicarbonate and C. is the reaction product of product A with water glass under air supply, so that next to the sodium metasilicate formed there is a sodium carbonate part of up to 10% by weight, as well as a water content up to 10% by weight,
og idet Co-granulatet inneholder ca. 20 til 85 vekt-% alkali-metallf osf at . and as the Co granules contain approx. 20 to 85% by weight of alkali metal phosphates.
Ifølge en foretrukken utførelsesform av blandingen ifølge oppfinnelsen er det -skumfattige tensid et ikke-ionisk fuktemiddel, som eksempelvis kan være fremstilt av etylendiamin, etylenoksyd og propylenoksyd og en kioravspaltende forbindelse natriumdi-klorisocyaorat med to krystallvann. According to a preferred embodiment of the mixture according to the invention, the foam-poor surfactant is a non-ionic wetting agent, which can for example be prepared from ethylenediamine, ethylene oxide and propylene oxide and a chiro-releasing compound sodium dichloroisocyanate with two crystal waters.
Videre er det til fremstilling av Co-granulatet egnedeFurthermore, they are suitable for the production of Co granules
produkt B en blanding av fortrinns/is ca. 70 vekt-% natriummetasilikat, ca. 10 vekt-% natriumhydroksyd og ca. 20 vekt-% natriumkarbonat og produktet C er en blanding av ca. 90 vekt-% natriummetasilikat og ca. 5 vekt-% vann' og ca. 5 vekt-% natriumkarbonat. Co-granulatet og/eller produktene ifølge product B a mixture of preference/ice approx. 70% by weight sodium metasilicate, approx. 10% by weight sodium hydroxide and approx. 20% by weight sodium carbonate and the product C is a mixture of approx. 90% by weight sodium metasilicate and approx. 5% by weight of water' and approx. 5% by weight sodium carbonate. The co-granulate and/or the products according to
B og/eller C kan eksempelvis fremstilles etter hvirvelsjiktfremgangsmåten. Produktene A, B eller C anvendes til behandl-ing med natriumtripolyfosfat og vann, fortrinnsvis i granulat-f orm. B and/or C can, for example, be produced using the fluidized bed method. Products A, B or C are used for treatment with sodium tripolyphosphate and water, preferably in granule form.
Eventuelt kan rengjøringsmiddelblandingen ifølge oppfinnelsen også inneholde tilsetninger av trinatriumfosfat eller natriumsulfat i en mengde inntil 50 vekt-%. Optionally, the cleaning agent mixture according to the invention may also contain additions of trisodium phosphate or sodium sulfate in an amount of up to 50% by weight.
Rengjøringsmiddelblandingen ifølge oppfinnelsen betyr overfor de vanlige kjente produkter forsåvidt teknisk fremskritt at. det på grunn av oppbygningen og sammensetningen av Co-granulatet sikrer en optimal rengjøringsvirkning og alkali-følsomme tensider som aktivkloravspaltende stoffer i blandingen spaltes ikke for tidlig på tross av nærvær av sterkt alkaliske forbindelser som natriumhydroksyd og/eller natriumkarbonat. Compared to the usual known products, the cleaning agent mixture according to the invention certainly means technical progress that. due to the structure and composition of the Co granulate, it ensures an optimal cleaning effect and alkali-sensitive surfactants such as active chlorine decomposing substances in the mixture do not decompose prematurely despite the presence of strongly alkaline compounds such as sodium hydroxide and/or sodium carbonate.
Oppfinnelsen skal forklares nærmere ved hjelp av noen eks-empler : The invention will be explained in more detail with the help of some examples:
Eksempel 1Example 1
1. Fremstilling av Co-granulatet:1. Production of the Co-granules:
På hullbunnen" av en hvirvelsjikt-forstøvningsgranulator ble det hatt 20 kg natriummetaasilikatpulver med et innhold av 20%-fri etsnatron. Nedenfra ble det gjennom hullbunnen innført 500 m3/time luft med en temperatur av 130°C. Etter at produktet var bragt til en temperatur på 85°C ble det gjennom en to-stoff dyse ved et forstøvningslufttrykk på On the hole bottom" of a fluidized bed atomization granulator was 20 kg of sodium metasilicate powder with a content of 20% free caustic soda. 500 m3/hour of air with a temperature of 130°C was introduced from below through the hole bottom. After the product had been brought to a temperature of 85°C, it was passed through a two-material nozzle at an atomizing air pressure of
1,6 bar innsprøytet 4 kg av en 50 %-ig vannglassoppløsning med et Si02til Na20-forhold på 3,3 nedenfra i hvirvelsjiktet. Det danner seg et granulat som har følgende sammensetning: 1.6 bar injected 4 kg of a 50% water glass solution with a SiO 2 to Na 2 O ratio of 3.3 from below in the fluidized bed. A granule is formed which has the following composition:
78,0 vekt-% natriummetasilikat78.0% by weight sodium metasilicate
12,9 vekt-% soda og resterende fritt etsnatron12.9% by weight soda ash and remaining free caustic soda
9,1 vekt-% vann.9.1% by weight water.
14,7 kg av dette granulat ble viderebehandlet i samme apparat ved tilsetning av 11,5 kg tørt, finmalt natriumtripolyfosfat samt 7,5 kg av en 20 vekt-%ig natriumtripolyfosfatsuspensjon. Til anvendelse kom 25 0 m3/time virveluft av en temperatur på 150°C. Det fremkom et hårdt slitasjegast Co-granulat av følgende sammensetning: 14.7 kg of this granulate was further processed in the same apparatus by adding 11.5 kg of dry, finely ground sodium tripolyphosphate and 7.5 kg of a 20% by weight sodium tripolyphosphate suspension. 250 m3/hour of swirling air at a temperature of 150°C was used. A hard wear gas Co granule of the following composition emerged:
42,5 vekt-% natriummetasilikat42.5% by weight sodium metasilicate
6,9 vekt-% soda og resterende fritt etsnatron6.9% by weight soda ash and remaining free caustic soda
45,9 vekt-% fosfat45.9% by weight phosphate
4,7 vekt-% bundet vann.4.7% by weight bound water.
2. Lagring- og rengjøringsprøve av rengjøringsmiddel-blandingen: 95 vektdeler av det ifølge punkt 1 fremstilte Co-granulat ble i en frittfall-blander blandet med 2,5 vektdeler av et ikke-ionisk fuktemiddel som var fremstilt av etylediamin, etylenoksyd og propylenoksyd samt 2,5 vektdeler natriumdiklorisocyanurat . 2H20 og blandingen underkastet i fast tillukkede glassflasker en 6 mndr. lagringsprøve. Deretter ble det undersøkt stabiliteten av aktivklorbæreren i ren-gjøringsmiddelblandingen samt rengjøringsvirkningen av blandingen i en husholdningsoppvaskmaskin under anvendelse av et normalt program på vaskegods med forskjellig definert tilsmutsingstyper. Tilsmutsingene ble tilberedt og aldret etter norm-utkastet DIN 44990, del 2. Vaskegodset besto av glass, porselenoppvask og edelstålbestikk. Renseprøven ble gjennomført under medanvendelse av en handelsvanlig klarspyler. Den anvendte mengde av rengjøringsmiddelblanding utgjorde 3 g rengjøringsmiddel pr. liter vaskebad samt 3 ml klarspyler. 2. Storage and cleaning test of the cleaning agent mixture: 95 parts by weight of the Co granulate produced according to point 1 was mixed in a free-fall mixer with 2.5 parts by weight of a non-ionic wetting agent which was made from ethylenediamine, ethylene oxide and propylene oxide as well as 2.5 parts by weight of sodium dichloroisocyanurate. 2H20 and the mixture subjected to 6 months in tightly closed glass bottles. storage test. The stability of the active chlorine carrier in the cleaning agent mixture was then investigated as well as the cleaning effect of the mixture in a household dishwasher using a normal program on laundry with different defined soiling types. The soiling was prepared and aged according to the draft standard DIN 44990, part 2. The laundry consisted of glassware, porcelain dishes and stainless steel cutlery. The cleaning test was carried out with the combined use of a commercially available rinse aid. The amount of cleaning agent mixture used was 3 g of cleaning agent per liter washing bath and 3 ml rinse aid.
Det ble oppnådd følgende resultater:The following results were obtained:
Etter 6 mndr. lagringstid utgjorde aktivkloravbygningenAfter 6 months storage time accounted for the active chlorine degradation
2% og rengjøringsvirkningen av det lagrede middel 98,5%. 2% and the cleaning effect of the stored agent 98.5%.
Eksempel 2 (Sammenligningseksempel)Example 2 (Comparison example)
Det ble gått frem analogt eksempel 1, idet det imidlertid ble anvendt et oppvaskrengjøringsmiddel av følgende sammensetning: The procedure was analogous to example 1, although a dishwashing detergent of the following composition was used:
90 vektdeler av et blandingsgranulat90 parts by weight of a mixed granulate
5 vektdeler Na2C03vannfritt5 parts by weight Na2C03 anhydrous
2,5 vektdeler natriumdiklorisocyanurat . 2H2O2.5 parts by weight of sodium dichloroisocyanurate. 2H2O
2,5 vektdeler ikke-ionisk tensid2.5 parts by weight non-ionic surfactant
Blandingsgranulatet besto av natriummetasilikat og natrium-tripolyf osf at i vektforhold 1:1 og var fremstilt ved fremgangsmåten ifølge DE-AS 24 54 448. The mixture granulate consisted of sodium metasilicate and sodium tripolyphosphate in a weight ratio of 1:1 and was produced by the method according to DE-AS 24 54 448.
Etter 6 mndr. lagringstid utgjorde aktivkloravbygningen 35% og rengjøringsvirkningen av det lagrede middel 86%. After 6 months storage time, the active chlorine degradation was 35% and the cleaning effect of the stored agent 86%.
Eksempel 3 (Sammenligningseksempel)Example 3 (Comparison example)
Det ble gått frem analogt eksempel 1, idet det imidlertid ble anvendt en oppvaskrengjører av følgende sammensetning: The procedure was analogous to example 1, but a dishwashing detergent with the following composition was used:
90 vektdeler av et blandingsgranulat90 parts by weight of a mixed granulate
5 vektdeler Na2C03vannfritt5 parts by weight Na2C03 anhydrous
2,5 vektdeler natriumdiklorisocyanurat . 2H2O2.5 parts by weight of sodium dichloroisocyanurate. 2H2O
2,5 vektdeler ikke-ionisk tensid.2.5 parts by weight non-ionic surfactant.
Blandingsgranulatet besto av natriummetasilikat og natrium-tripolyf osf at i vektforhold 1:1 og var fremstilt ved fremgangsmåten ifølge DE-AS 28 22 765. The mixture granulate consisted of sodium metasilicate and sodium tripolyphosphate in a weight ratio of 1:1 and was produced by the method according to DE-AS 28 22 765.
Etter 6 mndr. lagringstid utgjorde aktivkloravbygningen 15% og det lagrede middels rengjøringsvirkning 93%. After 6 months storage time, the active chlorine degradation amounted to 15% and the stored average cleaning effect 93%.
Eksempel 4Example 4
1. Fremstilling av Co-granulatet:1. Production of the Co-granules:
I hvirvelsjiktgranulatoren ifølge eksempel 1 ble det fyltIn the fluidized bed granulator according to example 1, it was filled
14 kg natriummetasilikatpulver som inneholdt 20 vekt-%14 kg of sodium metasilicate powder containing 20% by weight
fritt etsnatron og ved en tilluftstemperatur på 135°C bragt til en produkttemperatur på 9 0°C. Ved denne temperatur ble det gjennom en to-stoff dyse ved et forstøvningslufttrykk på 1,5 bar innsprøytet 16 kg av en 15 vekt-%ig natrium-hydrogenkarbonatoppløsning av 60°C nedenfra i hvirvelsjiktet. Det dannede granulat ble videre behandlet med 5 kg tørt, finmalt natriumtripolyfosfat samt 2,5 kg av en 20%ig natriumtripolyfosfatsuspensjon. Det ble igjen anvendt 250 m 3/time hvirvelluft av en temperatur på 150°C. Det resulterende Co-granulat hadde følgende sammensetning: free caustic soda and at a supply air temperature of 135°C brought to a product temperature of 90°C. At this temperature, 16 kg of a 15% by weight sodium hydrogen carbonate solution of 60°C was injected from below in the fluidized bed through a two-material nozzle at an atomizing air pressure of 1.5 bar. The formed granules were further treated with 5 kg of dry, finely ground sodium tripolyphosphate and 2.5 kg of a 20% sodium tripolyphosphate suspension. Again, 250 m 3 /hour of swirling air at a temperature of 150°C was used. The resulting Co granulate had the following composition:
46.7 vekt-% natriummetasilikat46.7% by weight sodium metasilicate
6,5 vekt-% etsnatron6.5% by weight caustic soda
16.8 vekt-% soda16.8 weight-% soda ash
25,0 vekt-% fosfat25.0% by weight phosphate
5,0 vekt-% vann.5.0 wt% water.
2. Fremstilling av rengjøringsmiddelblandingeh under anvendelse av Co-granulatet ifølge avsnitt 1: 95 vektdeler av det ifølge punkt 1 fremstilte Co-granulat ble i en frittfallblander blandet med 2m5 vektdeler av et ikke-ionisk tensid samt 2,5 vektdeler natriumdiklorisocyanurat x 2H2O. Tensidet var kondensasjonsproduktet av en langskjedet lineær alkohol med etylen- og propylenoksyd. Blandingen ble oppbevart over et tidsrom på 3 måneder i godt lukkede glassflasker og deretter tre måneder i åpne glass. En misfargning av rengjøringsmiddelblandingen ved spaltning av tensidét på grunn av nærvær av NaOH i blandingen inntrådte ikke under lagringstiden, hvilket er et bevis for blandingens stabilitet. 2. Preparation of cleaning agent mixture using the Co granulate according to section 1: 95 parts by weight of the Co granulate produced according to point 1 was mixed in a free-fall mixer with 2 m5 parts by weight of a non-ionic surfactant and 2.5 parts by weight sodium dichloroisocyanurate x 2H2O. The surfactant was the condensation product of a long-chain linear alcohol with ethylene and propylene oxide. The mixture was stored over a period of 3 months in tightly closed glass bottles and then three months in open jars. Discoloration of the detergent mixture by cleavage of the surfactant due to the presence of NaOH in the mixture did not occur during the storage period, which is a proof of the stability of the mixture.
Sammenligningsmessig skal det bemerkes at tilsvarende handelsvanlig rengjøringsformuleringer i nærvær av NaOH som bestanddel av formuleringen i kort tid misfarger seg under spaltning av tensidet, hvilket er forbundet en nedsettelse av rengjør-ingsmiddelets rengjøringsvirkning. In terms of comparison, it should be noted that corresponding commercially available cleaning formulations in the presence of NaOH as a component of the formulation discolour for a short time during the breakdown of the surfactant, which is associated with a reduction in the cleaning effect of the cleaning agent.
Claims (8)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19813136985 DE3136985A1 (en) | 1981-09-17 | 1981-09-17 | ALKALINE AND CHLORINE-STABLE CLEANER |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO823145L true NO823145L (en) | 1983-03-18 |
Family
ID=6141949
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO823145A NO823145L (en) | 1981-09-17 | 1982-09-16 | ALKALIC AND CHLORABLE STABLE CLEANER. |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0075125B1 (en) |
| AT (1) | ATE28756T1 (en) |
| DE (2) | DE3136985A1 (en) |
| DK (1) | DK414782A (en) |
| ES (1) | ES8306387A1 (en) |
| GR (1) | GR77336B (en) |
| NO (1) | NO823145L (en) |
| PT (1) | PT75563B (en) |
| TR (1) | TR22085A (en) |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3682829A (en) * | 1970-09-10 | 1972-08-08 | Desoto Inc | Production of low silica content dry,granular automatic dish washing detergent |
| US4228025A (en) * | 1979-06-29 | 1980-10-14 | The Procter & Gamble Company | Agglomeration process for making granular detergents |
-
1981
- 1981-09-17 DE DE19813136985 patent/DE3136985A1/en not_active Withdrawn
-
1982
- 1982-08-25 DE DE8282107785T patent/DE3276908D1/en not_active Expired
- 1982-08-25 AT AT82107785T patent/ATE28756T1/en not_active IP Right Cessation
- 1982-08-25 EP EP82107785A patent/EP0075125B1/en not_active Expired
- 1982-09-15 PT PT75563A patent/PT75563B/en unknown
- 1982-09-15 TR TR22085A patent/TR22085A/en unknown
- 1982-09-15 GR GR69278A patent/GR77336B/el unknown
- 1982-09-16 NO NO823145A patent/NO823145L/en unknown
- 1982-09-16 DK DK414782A patent/DK414782A/en not_active Application Discontinuation
- 1982-09-17 ES ES515799A patent/ES8306387A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| PT75563A (en) | 1982-10-01 |
| EP0075125A2 (en) | 1983-03-30 |
| DK414782A (en) | 1983-03-18 |
| EP0075125B1 (en) | 1987-08-05 |
| PT75563B (en) | 1985-05-31 |
| ES515799A0 (en) | 1983-06-01 |
| EP0075125A3 (en) | 1986-01-08 |
| ATE28756T1 (en) | 1987-08-15 |
| GR77336B (en) | 1984-09-11 |
| TR22085A (en) | 1986-03-21 |
| DE3136985A1 (en) | 1983-03-31 |
| ES8306387A1 (en) | 1983-06-01 |
| DE3276908D1 (en) | 1987-09-10 |
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