NO792000L - STABLE Aqueous SOLUTION OF VINYL COPY POLYMERIZATES CONTAINING CATIONIC GROUPS AND ANION ANTICIDES OR ANIONIC POLYELECTOLYLTS - Google Patents
STABLE Aqueous SOLUTION OF VINYL COPY POLYMERIZATES CONTAINING CATIONIC GROUPS AND ANION ANTICIDES OR ANIONIC POLYELECTOLYLTSInfo
- Publication number
- NO792000L NO792000L NO792000A NO792000A NO792000L NO 792000 L NO792000 L NO 792000L NO 792000 A NO792000 A NO 792000A NO 792000 A NO792000 A NO 792000A NO 792000 L NO792000 L NO 792000L
- Authority
- NO
- Norway
- Prior art keywords
- aqueous solution
- ionic
- units
- anionic
- vinyl
- Prior art date
Links
- 239000007864 aqueous solution Substances 0.000 title claims description 24
- 229920002554 vinyl polymer Polymers 0.000 title description 7
- 150000001450 anions Chemical class 0.000 title description 4
- ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical class C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 title 1
- 125000002091 cationic group Chemical group 0.000 claims description 23
- 229920006163 vinyl copolymer Polymers 0.000 claims description 20
- 239000000178 monomer Substances 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 16
- -1 poly(methacryloxyethyl-trimethylammonium chloride) Polymers 0.000 claims description 15
- 239000003945 anionic surfactant Substances 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
- 230000001376 precipitating effect Effects 0.000 claims description 5
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 229920001448 anionic polyelectrolyte Polymers 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 150000008040 ionic compounds Chemical class 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 230000003750 conditioning effect Effects 0.000 claims 1
- 150000003242 quaternary ammonium salts Chemical group 0.000 claims 1
- 239000000243 solution Substances 0.000 description 12
- 125000000129 anionic group Chemical group 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 7
- 229920000867 polyelectrolyte Polymers 0.000 description 7
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- 229920002125 Sokalan® Polymers 0.000 description 4
- 150000001793 charged compounds Chemical class 0.000 description 4
- 239000004584 polyacrylic acid Substances 0.000 description 4
- 125000001453 quaternary ammonium group Chemical group 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 125000001302 tertiary amino group Chemical group 0.000 description 4
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 3
- TURPNXCLLLFJAP-UHFFFAOYSA-N 2-[2-(2-hydroxyethoxy)ethoxy]ethyl hydrogen sulfate Chemical compound OCCOCCOCCOS(O)(=O)=O TURPNXCLLLFJAP-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 150000001447 alkali salts Chemical class 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 150000007942 carboxylates Chemical group 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 description 3
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 125000004103 aminoalkyl group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- DBNWKFDFDWDROA-UHFFFAOYSA-N 1-ethenylimidazolidine Chemical compound C=CN1CCNC1 DBNWKFDFDWDROA-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- GSQIVVSEVORPJF-UHFFFAOYSA-N 2-(butylamino)ethyl prop-2-enoate Chemical compound CCCCNCCOC(=O)C=C GSQIVVSEVORPJF-UHFFFAOYSA-N 0.000 description 1
- QHVBLSNVXDSMEB-UHFFFAOYSA-N 2-(diethylamino)ethyl prop-2-enoate Chemical compound CCN(CC)CCOC(=O)C=C QHVBLSNVXDSMEB-UHFFFAOYSA-N 0.000 description 1
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 150000001449 anionic compounds Chemical class 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 125000003118 aryl group Chemical class 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- 229940073608 benzyl chloride Drugs 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 229940106681 chloroacetic acid Drugs 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 125000005678 ethenylene group Chemical group [H]C([*:1])=C([H])[*:2] 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000003676 hair preparation Substances 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 125000006203 morpholinoethyl group Chemical group [H]C([H])(*)C([H])([H])N1C([H])([H])C([H])([H])OC([H])([H])C1([H])[H] 0.000 description 1
- OOUWNHAYYDNAOD-UHFFFAOYSA-N n-[(dimethylamino)methyl]prop-2-enamide Chemical compound CN(C)CNC(=O)C=C OOUWNHAYYDNAOD-UHFFFAOYSA-N 0.000 description 1
- ADTJPOBHAXXXFS-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]prop-2-enamide Chemical compound CN(C)CCCNC(=O)C=C ADTJPOBHAXXXFS-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- 239000013558 reference substance Substances 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/24—Homopolymers or copolymers of amides or imides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Cosmetics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Description
Foreliggende oppfinnelse angår vandige oppløsninger av vinylkopolymerisater med kationisk karakter som inneholder anioniske tensider eller anioniske polyelektrolytter. Vanlig- The present invention relates to aqueous solutions of cationic vinyl copolymers containing anionic surfactants or anionic polyelectrolytes. Usual-
vis er slike oppløsninger ustabile fordi det danner seg uopp-løselige salter eller komplekser av de nevnte kationiske og anioniske komponenter. Således felles vannoppløselige polymerisater av kvaternerte aminoalkylestere av akryl- eller metakrylsyre ut på grunn av aniontensider eller på grunn av polyakryl- such solutions are unstable because insoluble salts or complexes of the aforementioned cationic and anionic components are formed. Thus, water-soluble polymers of quaternized aminoalkyl esters of acrylic or methacrylic acid precipitate due to anionic surfactants or due to polyacrylic
syre eller dennes alkalisalter. På tross av dette består det hyppig et behov for å fremstille vandige oppløsninger, med forenelige komponenter med motsatt ladning fordi begge komponenter trenges samtidig på grunn av de spesifikke funksjoner, eller fordi den ene komponent allerede foreligger i vandig opp-løsning og kun vanskelig eller sågar slett ikke kan fjernes før den andre komponent tilsettes. acid or its alkali salts. Despite this, there is often a need to produce aqueous solutions, with compatible components with the opposite charge because both components are needed at the same time due to the specific functions, or because one component is already present in aqueous solution and only difficult or even cannot be removed at all until the second component is added.
Et eksempel på det samtidige behov for uforenelige mot-ioniske bestanddeler er hårkosmetiske midler. Disse bør inneholde såvel anioniske tensider som hårvaskemiddel som også kationiske vinylpolymerisater som hårfestemidler og hårkondi-sjoneringsmidler. An example of the simultaneous need for incompatible counter-ionic ingredients is hair cosmetics. These should contain both anionic surfactants as hair washing agent and also cationic vinyl polymers as hair fixing agents and hair conditioners.
For å fremstille vandige oppløsninger av denne type,To prepare aqueous solutions of this type,
blir ifølge NL-AS 7 607 314 en blanding av anioniske, ikke-ioniske og amfotere tensider kombinert med en nitrogenholdig amfoter polyelektrolytt som inneholder aminoalkylgrupper og små mengder karboksylgrupper. Anvendelsen av anioniske tensider i stedet for den av tre forskjellige typer samsatte tensidbland- becomes, according to NL-AS 7 607 314, a mixture of anionic, non-ionic and amphoteric surfactants combined with a nitrogen-containing amphoteric polyelectrolyte containing aminoalkyl groups and small amounts of carboxyl groups. The use of anionic surfactants instead of that of three different types of composite surfactant mix-
ing foretrekkes dog generelt.However, ing is generally preferred.
Bestandige vandige oppløsninger av anioniske polyelektrolytter og vinylkopolymerisater med enheter av umettede karboksylsyrer på den ene side og enheter med primære, sekundære eller Stable aqueous solutions of anionic polyelectrolytes and vinyl copolymers with units of unsaturated carboxylic acids on one side and units with primary, secondary or
tertiære aminogrupper på den annen side, kan ifølge US-PBtertiary amino groups on the other hand, according to US-PB
3.950.296 fremstilles ved spesielle pH-verdier. Når man nærmer seg det isoelektriske punkt, oppstår det uoppløselige utfellinger. 3,950,296 is produced at special pH values. When approaching the isoelectric point, insoluble precipitates occur.
Det var oppgave for foreliggende oppfinnelse å muliggjøre fremstilling av bestandige vandige oppløsninger som ved siden av hverandre inneholder oppløste vinylkopolymerisater med kationisk karakter, og slike ioniske eller ioniserbare oppløste forbindelser som har en utfellende virkning overfor en vandig oppløsning av poly(metakryloksyetyl-trimetylammoniumklorid), uten at stabili- It was the task of the present invention to enable the production of stable aqueous solutions which contain dissolved vinyl copolymers of a cationic character next to each other, and such ionic or ionizable dissolved compounds which have a precipitating effect on an aqueous solution of poly(methacryloxyethyl-trimethylammonium chloride), without to stabilize
teten og bestandigheten avhenger av valget av helt spesielle komponenter eller overholdelse av et trangt pH-område. Poly(metakryloksyetyl-trimetylammoniumklorid) med en midlere molekylvekt på 100.000. ble utvalgt på grunn av den lette tekniske tilgjenge-lighet som referansesubstans for bestemmelse av ufbreneligheten. the strength and durability depend on the choice of very special components or compliance with a narrow pH range. Poly(methacryloxyethyl-trimethylammonium chloride) with an average molecular weight of 100,000. was selected because of the easy technical availability as a reference substance for determining the inflammability.
De dermed uforenelige ioniske hhv. ioniserbare stoffer er også uforenelige med andre kationiske polyelektrolytter. Med vinylkopolymerisater med kationisk karakter forstås slike der den støkiometriske andel av kationiske grupper, dvs. amino- eller ammoniumgrupper, tydelig dominerer overfor anioniske grupper, The thus incompatible ionic resp. ionizable substances are also incompatible with other cationic polyelectrolytes. Vinyl copolymers with a cationic character are understood to mean those where the stoichiometric proportion of cationic groups, i.e. amino or ammonium groups, clearly dominates over anionic groups,
dvs. karboksyl- eller karboksylatgrupper.i.e. carboxyl or carboxylate groups.
En løsning av den gitte oppgave finnes i de vandige oppløs-ninger ifølge kravene. Avgjørende for bestandigheten er innholdet av kvaternære ammoniumgrupper i vinylkopolymerisat (2). A solution to the given task can be found in the aqueous solutions according to the requirements. Decisive for durability is the content of quaternary ammonium groups in vinyl copolymer (2).
Det består ikke i alle tilfeller en ubegrenset forenelig-There is not in all cases an unlimited compatible
het mellom de ellers uforenelige ioniske forbindelser, dog opp-heat between the otherwise incompatible ionic compounds, however,
nås i ethvert tilfelle en forbedret forenelighet sammenlignetin any case an improved compatibility is reached compared
med rent kationiske polyelektrolytter. Forbedret forenelighetwith purely cationic polyelectrolytes. Improved compatibility
kan f.eks. vise seg ved spesielle temperaturer, konsentrasjoner eller pH-verdier. Det foreligger andre tilfeller der det opp- can e.g. appear at particular temperatures, concentrations or pH values. There are other cases where the
trer forenelighetsproblemer for kationiske polyelektrolytter med motioniské forbindelser kun under bestemte ugunstige betingelser. Også i disse tilfeller kan området for uforeneligheten innsnevres ifølge oppfinnelsen. compatibility problems for cationic polyelectrolytes with counterionic compounds occur only under certain unfavorable conditions. In these cases too, the area of incompatibility can be narrowed according to the invention.
Oppløsningene ifølge oppfinnelsen inneholder de i hoved-kravet under punktene (2) og (3) nevnte bestanddeler i oppløst form. Ved siden av disse kan de alt etter behov og ønsket anvendelse inneholde andre oppløste eller ikke-oppløste bestanddeler. The solutions according to the invention contain the components mentioned in the main claim under points (2) and (3) in dissolved form. Alongside these, depending on the need and desired application, they may contain other dissolved or non-dissolved components.
Vinylkopolymerisåtet ( 2)Vinyl copolymer seed ( 2)
Vinylkopolymerisåtet som utgjør komponenten (2) er bygget opp av vinylmonomerer, dvs. monomerer med en radikalisk poly-meriserbar eller i det minste blandingspolymeriserbar karbon-dobbeltbinding i form av en vinylgruppe, en vinylidengruppe eller en vinylengruppe. Vinylkopolymerisatene ifølge oppfinnelsen kan være bygget opp utelukkende av monomerenhetene (A) og (B) og inneholder i ethvert tilfelle mer enn 10 grunnmol-% av disse enheter. The vinyl copolymer that makes up component (2) is built up of vinyl monomers, i.e. monomers with a radically polymerizable or at least mixture polymerizable carbon double bond in the form of a vinyl group, a vinylidene group or a vinylene group. The vinyl copolymers according to the invention can be built up exclusively from the monomer units (A) and (B) and in any case contain more than 10 basic mol% of these units.
De kationiske grupper behøver ikke å foreligge fullstendig i form av kvaternære ammoniumgrupper. De kan sågar foreligge overveiende i form av primære, sekundære eller tertiære aminogrupper eller av ved saltdannelse med en syre derav avledede primære, sekundære eller tertiære ammoniumgrupper såsannt kun den kvaternære ammoniumgruppe utgjør minst 5 grunnmol-% av monomerenhetene i vinylkopolymerisåtet (2). Fortrinnsvis utgjør The cationic groups do not have to be present entirely in the form of quaternary ammonium groups. They can even be present predominantly in the form of primary, secondary or tertiary amino groups or primary, secondary or tertiary ammonium groups derived from them by salt formation with an acid, so that only the quaternary ammonium group makes up at least 5 basic mol% of the monomer units in the vinyl copolymer mixture (2). Preferably make up
denne andel 5-25 grunnmol-%. Den kationiske karakter i vinyl-kopolymerisatet opprettholdes sålenge de anioniske enheter (B) this proportion 5-25 basis mol%. The cationic character of the vinyl copolymer is maintained as long as the anionic units (B)
med karboksyl- eller karboksylatgrupper støkiometrisk er under-legne de kationiske enheter (A) og (C). with carboxyl or carboxylate groups are stoichiometrically inferior to the cationic units (A) and (C).
I foretrukne tilfeller utgjør det støkiometriske over-skudd av kationiske i forhold til anioniske grupper 5-20 grunnmol-%. Andelen av ikke-ioniske monomerenheter (D) ligger fortrinnsvis under 50 grunnmol-%. In preferred cases, the stoichiometric excess of cationic groups in relation to anionic groups amounts to 5-20 basic mol%. The proportion of non-ionic monomer units (D) is preferably below 50 basic mol%.
Enhetene av typen (C) avledes fra vinylmonomerer med en primær, sekundær eller tertiær aminogruppe, hvorved de sistnevnte The units of type (C) are derived from vinyl monomers with a primary, secondary or tertiary amino group, whereby the latter
er foretrukket på grunn av den gode polymeriserbarhet. En foretrukket gruppe er amirioalkylestrene og aminoalkylamidene is preferred because of the good polymerizability. A preferred group is the amirioalkylesters and the aminoalkylamides
av akryl- og metakrylsyre, slik som f.eks., dimety laminoetylakry^ lat og -metakrylat, dietylaminoetylakrylat og -metakrylat, butylaminoetylakrylat og -metakrylat, piperidinoetyl-, morfo-linoetyl- og piperazinoetylestre av akryl- og metakrylsyre, N-dimetylaminometylakrylamid og -metakrylamid og N-dimetyl-aminopropylakrylamid og -metakrylamid. Andre anvendbare monomerer med aminogrupper er vinylpyridin, vinylimidazol og vinylimidazolidin. De tilsvarende ammoniumsalter oppnås fra disse monomerer ved omsetning med en organisk eller en uorganisk syre slik som saltsyre, svovelsyre, eddiksyre eller kloreddik-syre. of acrylic and methacrylic acid, such as, for example, dimethylaminoethyl acrylate and methacrylate, diethylaminoethyl acrylate and methacrylate, butylaminoethyl acrylate and methacrylate, piperidinoethyl, morpholinoethyl and piperazinoethyl esters of acrylic and methacrylic acid, N-dimethylaminomethylacrylamide and -methacrylamide and N-dimethylaminopropylacrylamide and -methacrylamide. Other useful monomers with amino groups are vinylpyridine, vinylimidazole and vinylimidazolidine. The corresponding ammonium salts are obtained from these monomers by reaction with an organic or an inorganic acid such as hydrochloric acid, sulfuric acid, acetic acid or chloroacetic acid.
Enhetene (A) med kvaternære ammoniumgrupper stammer fra monomerer som igjen stammer fra de ovenfor nevnte tertiære aminogruppeholdige monomerer ved kvaternisering, fortrinnsvis med metylklorid, benzylklorid eller dimetylsulfat. The units (A) with quaternary ammonium groups originate from monomers which in turn originate from the above-mentioned tertiary amino group-containing monomers by quaternization, preferably with methyl chloride, benzyl chloride or dimethyl sulfate.
De anioniske enheter (B) stammer fra maleinsyre, fumar-syre, itakonsyre, krotonsyre og fortrinnsvis fra akryl- eller metakrylsyre. Likeså egnet er de vannoppløselige salter av disse syrer, spesielt alkali- og. ammonium-saltene.. The anionic units (B) originate from maleic acid, fumaric acid, itaconic acid, crotonic acid and preferably from acrylic or methacrylic acid. Equally suitable are the water-soluble salts of these acids, especially alkali and. the ammonium salts..
De i.. kopolymerisatet likeledes foreliggende monomerenheter (D) er ikke-ioniske eller ioniserbare. Disse kan stamme fra vannoppløselige monomerer, f.eks. fra akryl- og metakrylamid, vinylpyrrolidon, hydroksyalkylestere av a,g-umettedede poly-meriserbare mono- eller dikarboksyIsyrer, spesielt da. slike med 2-4 karbonatomer i hydroksyalkylresten, såvel som fra den hypotet-isk monomere vinylalkohol. Monomerenhetene (D) kan også stamme fra vannuoppløselige komonomerer i et slikt omfang at vannopp-løseligheten for polymerisatet opprettholdes. Til slike forbindelser hører alkylestere (spesielt av C^_^-alkoholer) og nitriler av a,B-umettede karboksylsyrer, vinylestere a<y>fett-syrer, vinylhalogenider, vinylaromater, a-olefiner og/eller diener. The monomer units (D) also present in the copolymer are non-ionic or ionizable. These can originate from water-soluble monomers, e.g. from acrylic and methacrylamide, vinyl pyrrolidone, hydroxyalkyl esters of α,γ-unsaturated polymerizable mono- or dicarboxylic acids, especially da. those with 2-4 carbon atoms in the hydroxyalkyl residue, as well as from the hypothetical monomeric vinyl alcohol. The monomer units (D) can also originate from water-insoluble comonomers to such an extent that the water solubility of the polymer is maintained. Such compounds include alkyl esters (especially of C^_^-alcohols) and nitriles of a,B-unsaturated carboxylic acids, vinyl esters of a<y>fatty acids, vinyl halides, vinyl aromatics, a-olefins and/or dienes.
For hårkosmetiske preparater er spesielt egnet slike vinylkopolymerisater der det støkiometriske forhold mellom de kationiske grupper (A) og (C) og de anioniske grupper (B) ligger nær 1:1, spesielt i området mellom 1:1 pg 1,5:1. Typiske sammen-setninger inneholder omtrent like store andeler av enhetene (B) og (C) og en forholdsmessig liten andel av enhetene (A). Such vinyl copolymers are particularly suitable for hair cosmetic preparations where the stoichiometric ratio between the cationic groups (A) and (C) and the anionic groups (B) is close to 1:1, especially in the range between 1:1 and 1.5:1. Typical compositions contain roughly equal proportions of the units (B) and (C) and a relatively small proportion of the units (A).
For fremstilling av de vannoppløselige polymerisater finnes det et stort antall fremgangsmåter i henhold til hvilke også de ifølge oppfinnelsen anvendte vinylkpolymerisater (2) kan fremstilles. Ved siden av polymeriseringen av forholdsmessig fortynnede vandige monomeroppløsninger under innvirkning av vann-oppløselige radikaldannere, har fremfor alt slike fremgangsmåter vunnet betydning der høyt konsentrerte vandige monomeroppløsninger polymeriseres ved hjelp av vannoppløselige radikaldannere eller ultrafiolett lys. Derved oppstår det hårde polymerisater som kan behandles som faststoffer, og som, før anvendelse, oppløses i vann i deønskede konsentrasjoner. Polymeriseringen gjennom-føres i henhold til BE-PS 695 342 i folieposer, i henhold til DE-PS 1 770 588 i åpne beholdere, ifølge DE-OS 2 545 290 på et endeløst bånd, ifølge DE-OS 2 009 218 som perlepolymerisasjon i en ikke-vandig fase, og ifølge DE-OS 2 322 883 som suspensjonspoly-merisasjon i olje under dannelse av en bestandig og i vann oppløs-bar organosol. Molekylvekten for vinylkopolymerisåtet (2) kan ligge mellom 10.00 og en million. Fortrinnsvis fremstilles de i nærvær av regulatorer og har molekylvekter mellom 1000 og 50.000. For the production of the water-soluble polymers, there are a large number of methods according to which the vinyl copolymers (2) used according to the invention can also be produced. Next to the polymerization of relatively diluted aqueous monomer solutions under the influence of water-soluble radical generators, above all such methods have gained importance in which highly concentrated aqueous monomer solutions are polymerized by means of water-soluble radical generators or ultraviolet light. This results in hard polymers which can be treated as solids and which, before use, are dissolved in water in the desired concentrations. The polymerization is carried out according to BE-PS 695 342 in foil bags, according to DE-PS 1 770 588 in open containers, according to DE-OS 2 545 290 on an endless belt, according to DE-OS 2 009 218 as bead polymerization in a non-aqueous phase, and according to DE-OS 2 322 883 as suspension polymerization in oil to form a resistant and water-soluble organosol. The molecular weight of the vinyl copolymer seed (2) can lie between 10.00 and one million. Preferably, they are produced in the presence of regulators and have molecular weights between 1,000 and 50,000.
Den ioniske hhv, ioniserbare forbindelse ( 3)The ionic or ionizable compound ( 3)
Forbindelsene ifølge denne gruppe danner med rent kationiske polyelektrolytter slik som poly(metakryloksyetyl-trimetylammoniumklorid) .vannuoppløselige salter eller komplekser som faller ut av vandige oppløsninger. Den utfellende virkning kan vise seg i form av en blakking, en utflokking eller dannelse av større og uoppløselige aggregater, f.eks. som et bunnavsatt pro-. dukt. Av og til opptrer denne felling først ved bestemte temperaturer, konsentrasjoner eller pH-verd.iér. Den utfellende virkning går ut fra den anioniske komponent i forbindelsen (3). Forbindelsen (3) er enten en av anioner eller kationer oppbygget og i vandig oppløsning delvis eller helt dissosierende forbindelse, eller den går i vandig oppløsning over i en dissosiert forbindelse slik som f.eks. polykarboksylsyrer som ved dissosia-sjon danner protoner og polykarboksylatanioner. De i den vandige oppløsning foreliggende anioner har så en utfellende virkning overfor rent kationiske polyelektrolytter når dé The compounds according to this group form, with purely cationic polyelectrolytes such as poly(methacryloxyethyl-trimethylammonium chloride), water-insoluble salts or complexes which precipitate out of aqueous solutions. The precipitating effect can appear in the form of a flaking, a flocculation or the formation of larger and insoluble aggregates, e.g. as a bottom-deposited pro-. skill. Sometimes this precipitation only occurs at certain temperatures, concentrations or pH values. The precipitating effect is based on the anionic component in the compound (3). The compound (3) is either one of anions or cations built up and in aqueous solution a partially or completely dissociating compound, or it turns into a dissociated compound in aqueous solution such as e.g. polycarboxylic acids which on dissociation form protons and polycarboxylate anions. The anions present in the aqueous solution then have a precipitating effect on purely cationic polyelectrolytes when
enten inneholder flere ladninger eller er bundet til en stor hydrofob rest, altså utgjør aniontensider. Som aniontensider, kan oppløsningen inneholde vanlige seper såvel som alle vanlige tensider av sulfat- og sulfonattypen. Eksempler på slike er alkalisaltene av aromatiske sulfonsyrer, sulferte oljer, sulfater av fettalkoholer og sulferte oksyalkyleringsprodukter av fenoler, alkylerte fenoler, fettalkoholer og fettsyreamider. either contain more charges or are bound to a large hydrophobic residue, i.e. constitute anionic surfactants. As anionic surfactants, the solution can contain common soaps as well as all common surfactants of the sulfate and sulfonate type. Examples of such are the alkali salts of aromatic sulphonic acids, sulphated oils, sulphates of fatty alcohols and sulphated oxyalkylation products of phenols, alkylated phenols, fatty alcohols and fatty acid amides.
Vannoppløselige høymolekylare forbindelser med karboksyl-eller karboksylatgrupper som er forenelige med rent kationiske polymerisater, men imidlertid ikke med vinylpolymerisatene (2) ifølge oppfinnelsen av kationisk type, er spesielt polyakrylsyre, delvis forsået polyakrylnitril eller polyakrylamid, polymet-akrylsyre, blandingspolymerisater av maleinsyre med etylen eller styren og karboksymetylcellulose, fremfor alt slike forbindelser med molekylvekter over 1000. Det tilsvarende gjelder for de vannoppløselige salter, spesielt alkalisaltene og ammonium-saltene av disse forbindelser. Water-soluble high molecular weight compounds with carboxyl or carboxylate groups which are compatible with purely cationic polymers, but not with the cationic type vinyl polymers (2) according to the invention, are in particular polyacrylic acid, partially seeded polyacrylonitrile or polyacrylamide, polymethacrylic acid, mixed polymers of maleic acid with ethylene or styrene and carboxymethylcellulose, above all such compounds with molecular weights above 1000. The same applies to the water-soluble salts, especially the alkali salts and ammonium salts of these compounds.
For eksempel er polyakrylsyre og poly(dimetylaminoety1-metåkrylat) uforenelige i vandig oppløsning. I motsetning til dette kan man fremstille konsentrerte vandige oppløsninger (30<y>ekt-% faststoffer) av polyakrylsyre og et. blandingspolymerisat med kationisk karakter som består av For example, polyacrylic acid and poly(dimethylaminoethyl methacrylate) are incompatible in aqueous solution. In contrast to this, concentrated aqueous solutions (30<y>ect-% solids) of polyacrylic acid and et. mixed polymer with a cationic character consisting of
37 mol-% dimetylaminoety1-metakrylat37 mol% dimethylaminoethyl methacrylate
6 mol-% metakryloksyetyl-trimetylammoniumklorid6 mol% methacryloxyethyl trimethylammonium chloride
27 mol-% metakrylsyre og27 mol-% methacrylic acid and
20 mol-% hydroksypropylakrylat.20 mol% hydroxypropyl acrylate.
Disse oppløsninger er helt forenelige og klare ved et støkio-metrisk forhold mellom de kationiske grupper i blandingspoly-merisatet og karboksylgruppene i polyakrylsyren innen området 2:1 til over 7:1. Fortynnede oppløsninger (1 vekt-% faststoff) er i det minste ved verdier over 4:1 forenelige og klare for det nevnte ioneforhold. These solutions are completely compatible and clear at a stoichiometric ratio between the cationic groups in the mixed polymer and the carboxyl groups in the polyacrylic acid within the range of 2:1 to over 7:1. Dilute solutions (1% by weight solids) are at least compatible and clear for the aforementioned ionic ratio at values above 4:1.
Konsentrasjonen for de oppfinnelsesmessige oppløsninger av motsatt ladede forbindelser (2) og (3) kan gå. helt til metningsgrensen. Over et faststoffinnhold på 80 vekt-% foreligger det generelt ikke et flytende system mer. I området for høye konsentrasjoner for vinylkopolymerisåtet (2) er opp-løsningene sterkt viskøse. Av spesielt teknisk interesse er konsentrasjonsområdet på 0,5-15 vekt-% for hver av forbindelse (2) og (3), fordi forenelighetsproblemene her spiller den største rolle. Ved underskridelse av en totalkonsentrasjon på 1 vekt-% forsvinner forenelighetsfenomenene langsomt slik at det ikke består noe behov for anvendelsen av oppfinnelsen i dette område. The concentration for the inventive solutions of oppositely charged compounds (2) and (3) can go. right up to the saturation limit. Above a solids content of 80% by weight, there is generally no longer a liquid system. In the area of high concentrations for the vinyl copolymer seed (2), the solutions are highly viscous. Of particular technical interest is the concentration range of 0.5-15% by weight for each of compounds (2) and (3), because compatibility problems here play the greatest role. If the total concentration falls below 1% by weight, the compatibility phenomena slowly disappear so that there is no need for the application of the invention in this area.
Forsterkede forenelighetsproblemer pleier å opptrå når en kationisk polyelektrolytt står overfor anioniske forbindelser (3) i overstøkiometrisk mengde. Oppfinnelsen har derfor enøket betydning for vandige oppløsninger der de ioniske hhv. ioniserbare forbindelser (3), regnet i ioniske ladningsekvivalenter, foreligger støkiometrisk i større mengde enn amino- Enhanced compatibility problems tend to occur when a cationic polyelectrolyte is confronted with anionic compounds (3) in excess of stoichiometric amounts. The invention therefore has increased significance for aqueous solutions where the ionic or ionizable compounds (3), calculated in ionic charge equivalents, exist stoichiometrically in greater quantity than amino-
og ammoniumgruppene i vinylkopolymerisåtet (2) .and the ammonium groups in the vinyl copolymer (2).
Eksempel 1 Example 1
Lagringsbestandige hårsjampoer er sammensatt av:-.Storage-resistant hair shampoos are composed of:-.
a) 10 vektdeler (ci2~C14)-n-alkylpolyetylen-glykoleter-sulfat-natriumsalt b) 5 vektdeler vinylkopolymerisat A til F med kationisk karakter. a) 10 parts by weight (ci2~C14)-n-alkylpolyethylene glycol ether sulfate sodium salt b) 5 parts by weight vinyl copolymer A to F with a cationic character.
Til sammenligning ble det i stedet for vinylkopolymerisåtet anvendt den samme mengde av det kationiske poly(metakry1-oksyetyl-trimetylammoniumklorid) (M = 100.000).;Det oppstår spontant en fnokkdannelse som langsomt avsettes. For comparison, instead of the vinyl copolymer seed, the same amount of the cationic poly(methacry1-oxyethyl-trimethylammonium chloride) (M = 100,000) was used.
Polymerisatene A til FThe polymers A to F
Sammensetning i molandelér:Composition in molande:
Eksempel 2 Example 2
Det ble fremstilt en vandig oppløsning av følgende bestanddeler: An aqueous solution of the following components was prepared:
5 vektdeler av et blandingspolymerisat av5 parts by weight of a mixed polymer of
45 vekt-% metakryloksyety1-trimetylammoniumklorid 45% by weight of methacryloxyethyl-trimethylammonium chloride
5 vekt-% metakrylsyre5% by weight methacrylic acid
5 vekt-% dimetylaminoetyImetakrylat5% by weight of dimethylaminoethyl methacrylate
45 vekt-% 2-hydroksypropylakrylat45% by weight 2-hydroxypropyl acrylate
10 vektdeler (ci2~C14)-n-alkylpolyetylenglykol-etersulfat-natriumsalt 10 parts by weight of (ci2~C14)-n-alkyl polyethylene glycol ether sulfate sodium salt
85 vektdeler, vann.85 parts by weight, water.
Oppløsningen er klar og bestandig.The solution is clear and permanent.
Eksempel 3Example 3
Det ble fremstilt en vandig oppløsning av følgende bestanddeler: 5 vektdeler av et blandingspolymerisat av 10 vekt-% metakryloksyetyl-trimetylammoniumklorid An aqueous solution of the following components was prepared: 5 parts by weight of a mixed polymer of 10% by weight methacryloxyethyltrimethylammonium chloride
10 vekt-% metakrylsyre10% by weight methacrylic acid
10 vekt-% dimetylaminoetylmetakrylat10% by weight dimethylaminoethyl methacrylate
70 vekt-% 2-hydroksypropylakrylat70% by weight 2-hydroxypropyl acrylate
10 vektdeler (C12-C14)-n-alkylpolyetylenglykol-etersulfat-natriumsalt 10 parts by weight of (C12-C14)-n-alkyl polyethylene glycol ether sulfate sodium salt
85 vektdeler vann.85 parts by weight of water.
Oppløsningen er klar og bestandig. The solution is clear and permanent.
Claims (5)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19782832944 DE2832944A1 (en) | 1978-07-27 | 1978-07-27 | STABLE AQUEOUS SOLUTION OF VINYLCOPOLYMERISATS CONTAINING CATIONIC GROUPS AND ANIONSIDE OR ANIONIC POLYELECTROLYTES |
Publications (1)
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NO792000L true NO792000L (en) | 1980-01-29 |
Family
ID=6045513
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO792000A NO792000L (en) | 1978-07-27 | 1979-06-15 | STABLE Aqueous SOLUTION OF VINYL COPY POLYMERIZATES CONTAINING CATIONIC GROUPS AND ANION ANTICIDES OR ANIONIC POLYELECTOLYLTS |
Country Status (3)
Country | Link |
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DE (1) | DE2832944A1 (en) |
GB (1) | GB2027045B (en) |
NO (1) | NO792000L (en) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4393886A (en) | 1980-09-05 | 1983-07-19 | Ciba-Geigy Corporation | Mixtures of quaternary, polymeric, high molecular weight ammonium salts, which are based on acrylic compounds, and surfactants, their preparation, and their use in cosmetics |
EP0080976B1 (en) * | 1981-11-30 | 1986-09-24 | Ciba-Geigy Ag | Mixtures of quaternary polymeric acrylic ammonium salts, quaternary mono- or oligomeric ammonium salts and surfactants, their preparation and their use in cosmetic compositions |
DE3210752A1 (en) * | 1982-03-24 | 1983-10-06 | Roehm Gmbh | POLYMERISATE SUSPENSION CONTAINING A WATER-SOLUBLE POLYMERISATE SUSPENDED IN AN OIL PHASE |
US4948576A (en) * | 1983-02-18 | 1990-08-14 | Johnson & Johnson Consumer Products, Inc. | Detergent compositions |
GB8313232D0 (en) * | 1983-05-13 | 1983-06-22 | Causton B E | Prevention of undesired adsorption on surfaces |
US4454060A (en) * | 1983-06-09 | 1984-06-12 | Colgate-Palmolive Company | Liquid detergent composition with a cationic foam stabilizing copolymer containing pendant quaternary nitrogen groups and pendant hydrophobic groups |
KR920000131B1 (en) * | 1985-03-11 | 1992-01-09 | 가오오 가부시끼가이샤 | Detergent composition used in printing |
JPH0786122B2 (en) * | 1986-05-30 | 1995-09-20 | 日本ペイント株式会社 | Three-dimensionally crosslinked fine resin particles and method for producing the same |
DE3788696T2 (en) * | 1986-10-01 | 1994-04-28 | Allied Colloids Ltd | Water soluble polymer composition. |
FR2752584A1 (en) * | 1996-08-26 | 1998-02-27 | Coatex Sa | AGENT COMPATIBLE WITH SURFACTANTS USED IN DETERGENCE OR COSMETICS |
US7939601B1 (en) | 1999-05-26 | 2011-05-10 | Rhodia Inc. | Polymers, compositions and methods of use for foams, laundry detergents, shower rinses, and coagulants |
AU781532B2 (en) | 1999-05-26 | 2005-05-26 | Rhodia Inc. | Block polymers, compositions and methods of use for foams, laundry detergents, shower rinses and coagulants |
US6514918B1 (en) | 2000-08-18 | 2003-02-04 | Johnson & Johnson Consumer Companies, Inc. | Viscous, mild, and effective cleansing compositions |
-
1978
- 1978-07-27 DE DE19782832944 patent/DE2832944A1/en not_active Withdrawn
-
1979
- 1979-06-15 NO NO792000A patent/NO792000L/en unknown
- 1979-07-27 GB GB7926312A patent/GB2027045B/en not_active Expired
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DE2832944A1 (en) | 1980-02-14 |
GB2027045A (en) | 1980-02-13 |
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