NO762571L - - Google Patents
Info
- Publication number
- NO762571L NO762571L NO762571A NO762571A NO762571L NO 762571 L NO762571 L NO 762571L NO 762571 A NO762571 A NO 762571A NO 762571 A NO762571 A NO 762571A NO 762571 L NO762571 L NO 762571L
- Authority
- NO
- Norway
- Prior art keywords
- ethylene oxide
- mol
- detergent
- approx
- mixture
- Prior art date
Links
- 239000003599 detergent Substances 0.000 claims abstract description 31
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 28
- -1 ester salt Chemical class 0.000 claims description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- 210000002268 wool Anatomy 0.000 claims description 11
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 10
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 9
- 229910052708 sodium Inorganic materials 0.000 claims description 9
- 239000003513 alkali Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 239000001226 triphosphate Substances 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 7
- 239000013543 active substance Substances 0.000 claims description 7
- 150000005690 diesters Chemical class 0.000 claims description 6
- 239000001177 diphosphate Substances 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 150000002191 fatty alcohols Chemical class 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 239000003760 tallow Substances 0.000 claims description 5
- 150000001447 alkali salts Chemical class 0.000 claims description 4
- 150000003863 ammonium salts Chemical class 0.000 claims description 4
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 claims description 3
- 125000000129 anionic group Chemical group 0.000 claims description 3
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 claims description 3
- 229940055577 oleyl alcohol Drugs 0.000 claims description 3
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 claims description 3
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 claims description 3
- 230000001476 alcoholic effect Effects 0.000 claims description 2
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical class [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims description 2
- 235000011180 diphosphates Nutrition 0.000 claims description 2
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical group CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 claims description 2
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 235000011178 triphosphate Nutrition 0.000 claims description 2
- 125000002264 triphosphate group Chemical class [H]OP(=O)(O[H])OP(=O)(O[H])OP(=O)(O[H])O* 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 5
- 238000005406 washing Methods 0.000 description 40
- 235000019832 sodium triphosphate Nutrition 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 6
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 6
- 238000009950 felting Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- FKKAGFLIPSSCHT-UHFFFAOYSA-N 1-dodecoxydodecane;sulfuric acid Chemical compound OS(O)(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC FKKAGFLIPSSCHT-UHFFFAOYSA-N 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 3
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000126 substance Chemical class 0.000 description 2
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical class OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 2
- QFMZQPDHXULLKC-UHFFFAOYSA-N 1,2-bis(diphenylphosphino)ethane Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)CCP(C=1C=CC=CC=1)C1=CC=CC=C1 QFMZQPDHXULLKC-UHFFFAOYSA-N 0.000 description 1
- YUGDYIWBYHTUFR-UHFFFAOYSA-N 10-methylundecyl benzenesulfonate Chemical compound CC(C)CCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YUGDYIWBYHTUFR-UHFFFAOYSA-N 0.000 description 1
- LIFHMKCDDVTICL-UHFFFAOYSA-N 6-(chloromethyl)phenanthridine Chemical compound C1=CC=C2C(CCl)=NC3=CC=CC=C3C2=C1 LIFHMKCDDVTICL-UHFFFAOYSA-N 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004435 Oxo alcohol Substances 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- ZUBJEHHGZYTRPH-KTKRTIGZSA-N [(z)-octadec-9-enyl] hydrogen sulfate Chemical compound CCCCCCCC\C=C/CCCCCCCCOS(O)(=O)=O ZUBJEHHGZYTRPH-KTKRTIGZSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical class OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Chemical class 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920001444 polymaleic acid Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 239000011347 resin Chemical class 0.000 description 1
- 229920005989 resin Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- IWMMSZLFZZPTJY-UHFFFAOYSA-M sodium;3-(dodecylamino)propane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCNCCCS([O-])(=O)=O IWMMSZLFZZPTJY-UHFFFAOYSA-M 0.000 description 1
- HWCHICTXVOMIIF-UHFFFAOYSA-M sodium;3-(dodecylamino)propanoate Chemical compound [Na+].CCCCCCCCCCCCNCCC([O-])=O HWCHICTXVOMIIF-UHFFFAOYSA-M 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 235000019817 tetrapotassium diphosphate Nutrition 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 230000000451 tissue damage Effects 0.000 description 1
- 231100000827 tissue damage Toxicity 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/34—Derivatives of acids of phosphorus
- C11D1/345—Phosphates or phosphites
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
U.llvaskmiddel.Detergent.
Description
Oppfinnelsen vedrører en vaskemiddelformuleringThe invention relates to a detergent formulation
til vasking av tekstiler-av ull, som ved siden av en god vaskekraft utmerker seg ved en liten filtskrumpning av ullen. for washing textiles made of wool, which, in addition to a good washing power, is characterized by a slight felt shrinkage of the wool.
Rensning av tekstiler av ull ved hjelp av våtvask er spesielt vanskelig ved at slike tekstiler på grunn av struk-turtrekk av ullfibrene i vaskeprosessen ved anvendelse av van-lig vaskemiddel tenderer til filting, idet de skjellformede ull-fibre haker seg i hverandre. Til grunn for oppfinnelsen lå der-for den oppgave å utvikle en.vaskemiddelformulering som ved anvendelse av ull i våtvask ikke frembringer overnevnte vevnadsbe-skadigelse. Cleaning woolen textiles by means of wet washing is particularly difficult in that, due to the structural features of the wool fibers in the washing process when using ordinary detergents, such textiles tend to felt, as the shell-shaped wool fibers catch on each other. The invention was based on the task of developing a detergent formulation which does not cause the aforementioned tissue damage when wool is used in wet washing.
Oppfinnelsens gjenstand er således et fullvaskemiddel, inneholdende i det vesentlige ca. 10 til 20 vekt% av minst et syntetisk vaskeaktivt stoff samt ca. 10 til 80 vekt% av en blanding av alkalidifosfater, alkalitrifosfater og minst et estersalt av en partialester av orto-, pyro- eller tripolyfosforsyre, idet blandingsforholdet av blandingskomponentene utgjør 10 til ca. 2-40 til ca. 0,25-2 og de alkoholiske komponenter av partialesteren er definert ved radikalet med den generelle' formel The object of the invention is thus a full detergent, essentially containing approx. 10 to 20% by weight of at least one synthetic detergent active substance as well as approx. 10 to 80% by weight of a mixture of alkali diphosphates, alkali triphosphates and at least one ester salt of a partial ester of ortho-, pyro- or tripolyphosphoric acid, the mixing ratio of the mixture components being 10 to approx. 2-40 to approx. 0.25-2 and the alcoholic components of the partial ester are defined by the radical with the general' formula
R-(OC2Hi4)-nR-(OC 2 Hi 4 )-n
hvori R betyr en mettet eller umettet, rettlinjet eller forgrenet alkylrest med 10 til 18 C-atomer og n betyr et tall fra 2 til 10. in which R means a saturated or unsaturated, linear or branched alkyl residue with 10 to 18 carbon atoms and n means a number from 2 to 10.
Vaskemidlet kan som vaskeaktivt stoff inneholde et anionisk, ikke-ionisk, zwitterionisk eller amfotært syntetisk tensid. The detergent may contain an anionic, non-ionic, zwitterionic or amphoteric synthetic surfactant as a detergent active substance.
Med anioniske tensider er det å forstå de vannopp-løselige salter av høyere fettsyrer eller harpikssyrer, som natrium- eller kaliumsåper av herdet og uherdet kokospalmekjerne eller roeolje samt av talg og tilsvarende blandinger herav. Videre er det med anionaktive stoffer innen oppfinnelsens ramme å forstå høyere alkylsubstituerte, enkjernede, aromatiske sulfo-nater, som alkylbenzensulfonater med 9 til lk C-atomer i alkyl-'resten, alkylnaftalinsulfonater, alkyltoluensulfonater, alkyl-xylensulfonater eller alkylfenolsulfonater samt sulfaterte alifatiske alkoholer eller alkoholetere, som natrium- eller kaliumlauryl- resp. -heksadecylsulfat, trietanolaminlaurylsul-fat, natrium- eller kaliumoleylsulfat samt natrium- eller kalium-salter av med ca. 2 til 6 mol etylenoksyd etoksylert laurylsul-fat. Videre egnede anioniske tensider er sekundære lineære alkansulfonater samt a-olefinsulfonater med en kjedelengde på 12-20 C-atomer. By anionic surfactants is meant the water-soluble salts of higher fatty acids or resin acids, such as sodium or potassium soaps of hardened and unhardened coconut palm kernel or beet oil as well as of tallow and similar mixtures thereof. Furthermore, anionic active substances within the scope of the invention are understood to mean higher alkyl-substituted, mononuclear, aromatic sulphonates, such as alkylbenzene sulphonates with 9 to 10 C atoms in the alkyl residue, alkyl naphthalene sulphonates, alkyl toluene sulphonates, alkyl xylene sulphonates or alkylphenol sulphonates as well as sulphated aliphatic alcohols or alcohol ethers, such as sodium or potassium lauryl resp. -hexadecyl sulfate, triethanolamine lauryl sulfate, sodium or potassium oleyl sulfate as well as sodium or potassium salts of approx. 2 to 6 moles of ethylene oxide ethoxylated lauryl sulfate. Further suitable anionic surfactants are secondary linear alkanesulfonates and α-olefinsulfonates with a chain length of 12-20 C atoms.
Med ikke-ioniske tensider er det innen oppfinnelsens ramme å forstå slike forbindelser som har en organisk hydrofob gruppe samt en hydrofil rest. Eksempler på ikke-ionogene tensider er kondensasjonsproduktene av alkylfenoler med etylenoksyd resp. av høyere fettalkoholer med etylenoksyd, videre kondensasjonsprodukter av p.olypropylenglykol med etylenoksyd eller propylenoksyd samt kondensasjonsprodukter av etylenoksyd med reak-sjonsproduktet av etylendiamin og propylenoksyd. Også langkjed-ede tertiære aminoksyder hører innen gruppen av overnevnte forbindelser. By non-ionic surfactants, it is within the scope of the invention to understand such compounds which have an organic hydrophobic group as well as a hydrophilic residue. Examples of non-ionic surfactants are the condensation products of alkylphenols with ethylene oxide or of higher fatty alcohols with ethylene oxide, further condensation products of polypropylene glycol with ethylene oxide or propylene oxide as well as condensation products of ethylene oxide with the reaction product of ethylenediamine and propylene oxide. Long-chain tertiary amine oxides also belong to the group of above-mentioned compounds.
Endelig er det innen rekken av de som tensidbestand-deler av de ifølge oppfinnelsen vaske- og rensemiddelegnede produkter med amfolytiske eller zwitterionisk karakter å regne følgende forbindelser: Derivater av alifatiske, sekundære og tertiære aminer eller kvaternære ammoniumforbindelser med 8 til 18 C-atomer og en hydrofil gruppe i den alifatiske rest, som f.eks. natrium-3-dodecylaminopropionat, natrium-3-dodecylamino-propansulf onat, J>- (N,N-d ime ty 1-N-heksadecy 1 amino)- propan-1-sulfonat eller fettsyreaminoalkyl-N,N-dimetylacetobetain, idet fettsyrene inneholder 8 til 18 C-atomer og alkylresten 3 C-atomer. Finally, the following compounds can be counted as surfactant components of the products suitable for washing and cleaning agents according to the invention with an ampholytic or zwitterionic character: Derivatives of aliphatic, secondary and tertiary amines or quaternary ammonium compounds with 8 to 18 C atoms and a hydrophilic group in the aliphatic residue, such as e.g. sodium 3-dodecylaminopropionate, sodium 3-dodecylamino-propanesulfonate, J>-(N,N-dimethyl 1-N-hexadecy 1 amino)- propane-1-sulfonate or fatty acid aminoalkyl-N,N-dimethylacetobetaine, the fatty acids containing 8 to 18 C atoms and the alkyl residue 3 C atoms.
Eksempelvis anvendes ifølge oppfinnelsen sekundært For example, according to the invention, it is used secondarily
natriumalkylsulfonat, dodecylbenzensulfonat med 11-15 mol etylenoksyd .. etoksylert talgfettalkohol med 2-6 mol etylenoksyd etoksylert lauryletersulfat, oleylfettaminoksetylat, inneholdende 8-15 mol etylenoksyd og en med 10-15 mol etylenoksyd etoksylert oksoalkohol med 10-15 C-atomer som vaskeaktivt stoff. sodium alkylsulfonate, dodecylbenzenesulfonate with 11-15 mol ethylene oxide .. ethoxylated tallow fatty alcohol with 2-6 mol ethylene oxide ethoxylated lauryl ether sulfate, oleyl fatty amino oxyethylate, containing 8-15 mol ethylene oxide and an ethoxylated oxoalcohol with 10-15 mol ethylene oxide with 10-15 C atoms as detergent active substance .
Etter en ytterligere foretrukket utførelsesform av oppfinnelsen utgjør blandingsforholdet av blandingskomponentene 10 til 5-10 til 1-2. According to a further preferred embodiment of the invention, the mixing ratio of the mixing components is 10 to 5-10 to 1-2.
Av de i blandingen inneholdte estersalter anvendes fortrinnsvis alkali- eller ammoniumsaltet av mono- eller dilauryletoksylatfosforsyreestér med 4 mol etylenoksyd pr. mol laurylalkohol eller av mono- resp. dioleyletoksylatfos forsyreestér med 6 mol etylenoksyd pr. mol oleylalkohol eller blandinger av mono- og diestere. Of the ester salts contained in the mixture, the alkali or ammonium salt of mono- or dilauryl ethoxylate phosphoric acid esters with 4 mol of ethylene oxide per moles of lauryl alcohol or of mono- or Dioleyl ethoxylatphos foracid esters with 6 mol of ethylene oxide per moles of oleyl alcohol or mixtures of mono- and diesters.
De ifølge oppfinnelsen egnede fos forsyrepartial-estere kan fremstilles etter kjente fremgangsmåter, f.eks. ved direkte forestring av den tilsvarende syre. av fosforet, som orto-, pyro- eller tripolyfosforsyre med fettalkoholetoksylater eller ved omsetning av halogenderivater av fosfor resp. av fos-forsyreanhydrider med fettalkoholetoksylater. The phosphoric acid partial esters suitable according to the invention can be prepared according to known methods, e.g. by direct esterification of the corresponding acid. of the phosphorus, as ortho-, pyro- or tripolyphosphoric acid with fatty alcohol ethoxylates or by reacting halogen derivatives of phosphorus resp. of phosphoric acid anhydrides with fatty alcohol ethoxylates.
Ytterligere bestanddeler av vaskemiddelformuleringen ifølge oppfinnelsen kan eventuelt være vanlige vaskehjelpe- og tilsetningsstoffer som alkali- eller ammoniumsalter av svovel-og/eller borsyre samt stoffer som øker vannbadets smussbæreevne. Sistnevnte stoffgruppe omfatter cellulose- og stivelsesderivater som karboksymetylcellulose. eller karboksymetylstivelse samt polyelektrolytter i form av homopolymerisater av polyvinylalko-hol, av polymaleinsyre eller av polyakrylsyre resp. av kopoly-merisater av disse forbindelser med olefiner eller kortkjedede, umettede alifatiske etere eller alkoholer. Endelig kan også optiske lysgjørere, desinfeksjonsmidler og/eller proteolytiske enzymer være bestanddel av vaskemidlet. Additional components of the detergent formulation according to the invention may possibly be common washing aids and additives such as alkali or ammonium salts of sulfuric and/or boric acid as well as substances that increase the dirt carrying capacity of the water bath. The latter substance group includes cellulose and starch derivatives such as carboxymethyl cellulose. or carboxymethyl starch as well as polyelectrolytes in the form of homopolymers of polyvinyl alcohol, of polymaleic acid or of polyacrylic acid resp. of copolymers of these compounds with olefins or short-chain, unsaturated aliphatic ethers or alcohols. Finally, optical brighteners, disinfectants and/or proteolytic enzymes can also be part of the detergent.
Et karakteristisk trekk ved fullvaskemidlet ifølge oppfinnelsen er dets pH-verdi i vandig oppløsning som utgjør ca. 7,8 til 9,2. A characteristic feature of the detergent according to the invention is its pH value in aqueous solution, which amounts to approx. 7.8 to 9.2.
Et til oppfinnelsen med hensyn til sammensetning lignende vaskemiddel omtales i DAS 1.617-160 og er bestemt til vasking av syntetiske vevnader. Det kjente vaskemiddel fremstilles ved forstøvningstørkning av vandige oppslemninger som inneholder overflateaktige etylenoksydaddukter, organiske og uorganiske tilsetningsstoffer samt alkali- eller ammoniumsalter av fos fatestere. Med uorganiske tilsetningsstoffer er det eksempelvis å forstå natriumtripolyfosfat, natriumkarbonat, natrium-silikat eller-natriumperborat. Det er klart at det kjente vaskemiddel på grunn av nærvær av overnevnte sterkt alkaliskreagerende uorganiske tilsetningsstoffer ikke er egnet til vasking av ull, da ull derved ville filtdanne betraktelig. A detergent similar in composition to the invention is mentioned in DAS 1.617-160 and is intended for washing synthetic fabrics. The known detergent is produced by spray-drying aqueous slurries containing surface-like ethylene oxide adducts, organic and inorganic additives as well as alkali or ammonium salts of phosphate esters. By inorganic additives is meant, for example, sodium tripolyphosphate, sodium carbonate, sodium silicate or sodium perborate. It is clear that the known detergent is not suitable for washing wool due to the presence of the above-mentioned strongly alkali-reactive inorganic additives, as wool would thereby form felt considerably.
Å unngå fUtdannelsen av tekstiler som består av ull ved vasking er imidlertid nettopp oppgave ved vaskemiddelformuleringen ifølge oppfinnelsen, som dessuten garanterer en god renseeffekt. Avoiding the formation of wool in textiles during washing is, however, precisely the task of the detergent formulation according to the invention, which also guarantees a good cleaning effect.
Virkningen av vaskemidlet ifølge oppfinnelsen forklares nærmere ved hjelp av følgende eksempler. The effect of the detergent according to the invention is explained in more detail with the help of the following examples.
Eksempel 1. ( Sammenligningseksempel).Example 1. ( Comparison example).
Det ble i en forsøksrekke a) - e) fastslått vaskekraften. av' vaskebad samt innvirkning av de i vaskebadene inneholdte vaskemiddel på filtdannelse av vaskegodset som besto av ull. Som vaskegods ble det ved hvert vaskeforsøk anvendt 1,2 kg ikke tilsmusset ullvirke nr. 221 samt en prøvestrimmel av 11x11 cm av tilsmusset ullvevnad nr. 102 fra Eidgenossischen Material-und Priifungsanstalt (EMPA) , St. Gallen, Sveits. The washing power was determined in a series of experiments a) - e). of' washing baths as well as the effect of the detergents contained in the washing baths on felting of the laundry which consisted of wool. As laundry, 1.2 kg of unsoiled wool fabric No. 221 and a test strip of 11x11 cm of soiled woolen fabric No. 102 from Eidgenossischen Material-und Priifungsanstalt (EMPA), St. Gallen, Switzerland, were used for each washing test.
Vaskeforsøkene ble gjennomført i en husholdnings-vaskemaskin av typen Miele Automatic 4l6 S, under anvendelse av finvaskeprosessen ved en vaskebadtemperatur på 30°C. Vaskevannet hadde 18 tyske hårdhetsgrader og en pH-verdi på 8,8. Vasketiden utgjorde 25 minutter og badforholdetkarakterisert vedforhold mellom (kg) vaskegods til (liter vaskebad 1:25- The washing tests were carried out in a household washing machine of the type Miele Automatic 4l6 S, using the fine wash process at a washing bath temperature of 30°C. The washing water had 18 German degrees of hardness and a pH value of 8.8. The washing time was 25 minutes and the bath ratio was characterized by the ratio of (kg) laundry to (liter wash bath 1:25-
Etter utløp av den foreskrevne vasketid ble stand-ardullvirket spylt klart og deretter i remisjonsfotometer Elrepho fra Firma Zeiss fastslått remisjonsdifferensen mellom vasket og uvasket vaskegods som grad for vaskekraften. Filtskrumpingen ble bestemt tilsvarende forskrift nr. 106 i Internasjonal .V/ool Se-kreteriat, Jekley, Yorkshire, England. After expiry of the prescribed washing time, the standard woolen fabric was rinsed clean and then in a remission photometer Elrepho from the company Zeiss the remission difference between washed and unwashed laundry was determined as a measure of the washing power. The felt shrinkage was determined in accordance with regulation no. 106 of the International .V/ool Se-kreteriat, Jekley, Yorkshire, England.
For gjennomføring av vaske fors økene ble det pr. vaskegang i første rekke hatt 100 g av en grunndanning av følg-ende sammensetning i vaskevannet: 7 vekt% sekundært natriumalkylsulfonat med 1^-17 For the implementation of washing for the increases, per wash cycle primarily had 100 g of a basic formation of the following composition in the wash water: 7% by weight secondary sodium alkyl sulphonate with 1^-17
C-atomer,C atoms,
2 vekt/S talgfettalkohol med 11 mol etylenoksyd pr. mol alkohol etoksylert, 3 vekt% lauryletersulfat med 2 mol etylenoksyd pr. mol laurylalkohol, 2 weight/S of tallow fatty alcohol with 11 mol of ethylene oxide per mol alcohol ethoxylated, 3 wt% lauryl ether sulfate with 2 mol ethylene oxide per moles of lauryl alcohol,
3 vekt% p-toluensulfonsyre,3% by weight p-toluenesulfonic acid,
85 vekt% vann.85% by weight water.
Overnevnte grunnblanding ble ved gjennomføring av forsøksrekkene a) - e) komplettert med følgende tilsetninger: The above-mentioned basic mixture was supplemented with the following additions when carrying out the test series a) - e).
a) ingen tilsetning.a) no addition.
b) 2 g av en blanding av mono- og dilauryletoksylatfosforsyreestér med 4 mol etylenoksyd pr. mol laurylalkohol. Blandingsforholdet mellom mono- og diestere utgjorde 1:4. b) 2 g of a mixture of mono- and dilauryl ethoxylate phosphoric acid esters with 4 mol of ethylene oxide per moles of lauryl alcohol. The mixing ratio between mono- and diesters was 1:4.
c) 20 g tetranatriumdifos fat.c) 20 g tetrasodium diphos barrel.
d) 20 g pentanatriumtrifosfat.d) 20 g pentasodium triphosphate.
e) 2 g av en blanding av mono- og dilauryletoksylatfosforsyreestér med 4 mol etylenoksyd pr. mol laurylalkohol. e) 2 g of a mixture of mono- and dilauryl ethoxylate phosphoric acid esters with 4 mol of ethylene oxide per moles of lauryl alcohol.
Blandingsforholdet mellom mono- og diestere utgjorde 1:4. The mixing ratio between mono- and diesters was 1:4.
20 g tetranatriumdifosfat.20 g tetrasodium diphosphate.
De ved vaskeforsøkene a) - e) oppnådde vaskeresul-tater er oppstillet i tabellen. The washing results obtained in the washing tests a) - e) are listed in the table.
Eksempel 2. (Vaskemiddel ifølge oppfinnelsen).Example 2. (Detergent according to the invention).
Det ble gått frem analogt eksempel 1, idet det imidlertid som tilsetning til grunnblandingen ble tilsatt følg-ende produkter f) og g): f) 2 g av en blanding av mono- og dilauryletoksylatfosforsyreestér med 4 mol etylenoksyd pr. mol laurylalkohol. The procedure was analogous to example 1, but the following products f) and g) were added as an addition to the base mixture: f) 2 g of a mixture of mono- and dilauryl ethoxylate phosphoric acid esters with 4 mol of ethylene oxide per moles of lauryl alcohol.
Blandingsforholdet mellom mono- og diestere utgjorde 1:.4. The mixing ratio between mono- and diesters was 1:4.
20 g tetranatriumdifosfat.20 g tetrasodium diphosphate.
20 g pentanatriumtrifosfat.20 g pentasodium triphosphate.
g) 2 g av en blanding av mono- og dilauryletoksylatfosforsyreestér med 4 mol etylenoksyd pr. mol laurylalkohol. Blandingsforholdet mellom mono- og diestere utgjorde 1:4. g) 2 g of a mixture of mono- and dilauryl ethoxylate phosphoric acid esters with 4 mol of ethylene oxide per moles of lauryl alcohol. The mixing ratio between mono- and diesters was 1:4.
10 g tetranatriumdifosfat.10 g tetrasodium diphosphate.
5 g pentanatriumtrifosfat.5 g pentasodium triphosphate.
De ved vaskeforsøkene f) og g) oppnådde vaskeresul-tater fremgår av tabellen. The washing results obtained in the washing tests f) and g) appear in the table.
Eksempel 5- (Vaskemiddel ifølge oppfinnelsen). Example 5- (Detergent according to the invention).
I et vaskeforsøk ble det under de i eksempel 1 angitte vaskebetingelser undersøkt det flytende vaskemiddel av følgende sammensetning: In a washing test, under the washing conditions specified in example 1, the liquid detergent of the following composition was examined:
12 vekti tetrakaliumdifosfat,12 wt in tetrapotassium diphosphate,
4 vekt% pentanatriumtrifosfat,4 wt% pentasodium triphosphate,
1,5 vekti av en blanding av mono- og dilauryl-etoksylatf osf orsyreestér med 4 mol etylenoksyd pr. mol laurylalkohol, 1.5 weight of a mixture of mono- and dilauryl ethoxylate phosphoric acid esters with 4 mol of ethylene oxide per moles of lauryl alcohol,
7 vekti sekundært natriumalkansulfonat med7 by weight of secondary sodium alkanesulfonate with
14-17 C-atomer,14-17 C atoms,
2,5 vekti lauryletersulfat med 2 mol etylenoksyd pr. mol laurylalkohol, 2.5 by weight of lauryl ether sulfate with 2 mol of ethylene oxide per moles of lauryl alcohol,
3 vekt/? p-toluensulfonsyre,3 weight/? p-toluenesulfonic acid,
70 vekti vann.70 by weight of water.
Det flytende vaskemiddel hadde en pH-verdi på 8,1. Flateskrumpningen etter filting utgjorde etter 3 vaskeprosesser 3,0% og vaskekraften målt som remisjonsdifferens etter envaske-prosess, 17,3$. The liquid detergent had a pH value of 8.1. The surface shrinkage after felting amounted to 3.0% after 3 washing processes and the washing power measured as a remission difference after a single washing process, 17.3$.
Eksempel 4. (Vaskemiddel ifølge oppfinnelsen).Example 4. (Detergent according to the invention).
I et vaskeforsøk ble det under de i eksempel 1 angitte vaskebetingelser undersøkt det flytende vaskemiddel med følgende sammensetning: In a washing test, under the washing conditions specified in example 1, the liquid detergent with the following composition was examined:
12 vekt/S tetrakaliumdif osf at,12 wt/S tetrapotassium diff osf at,
8 vekti pentanatriumtrifosfat,8 wt in pentasodium triphosphate,
2 vekti av en blanding av mono- og dioleyletylat-fosforsyreestér med 4 mol etylenoksyd pr. mol oleylalkohol, 2 by weight of a mixture of mono- and diolley ethylate phosphoric acid esters with 4 mol of ethylene oxide per moles of oleyl alcohol,
8 vekti dodecylbenzensulfonat,8 wt.i dodecylbenzenesulfonate,
2 vekti oksoalkohol med 12-15 C-atomer, etoksylert med 10 mol etylenoksyd pr. mol alkohol, 2 vekt% oleylfettaminoksetylat med 8 mol etylenoksyd pr. mol fettamin, 2 by weight of oxo alcohol with 12-15 C atoms, ethoxylated with 10 mol of ethylene oxide per mol alcohol, 2 wt% oleyl fatty amino acetylate with 8 mol ethylene oxide per moles of fatty amine,
7 vekti p-toluensulfonsyre,7 by weight of p-toluenesulfonic acid,
3 vekti KOH,3 wt in KOH,
56 vekti vann.56 by weight of water.
Det flytende vaskemiddel hadde en pH-verdi på 8,5. Plateskrumpingen ved filting utgjorde etter 3 vaskeprosesser 2,8% og vaskekraften etter en vaskegang 17,0%. The liquid detergent had a pH value of 8.5. The sheet shrinkage during felting was 2.8% after 3 washing processes and the washing power after one wash was 17.0%.
Eksempel 5* (Vaskemiddel ifølge oppfinnelsen).Example 5* (Detergent according to the invention).
I et vaskeforsøk ble det under de i eksempel 1 angitte vaskebetingelser undersøkte pulverformede vaskemiddel av følgende sammensetning: In a washing test, powdered detergent of the following composition was examined under the washing conditions specified in example 1:
14 vekt% tetranatriumdifosfatj14% by weight tetrasodium diphosphatej
4 vekt% dinatriumdihydrogendifosfatj4% by weight disodium dihydrogen diphosphatej
57 vekt% pentanatriumtrifosfat,57 wt% pentasodium triphosphate,
2 vekt% av en blanding av mono- og dilauryletoksy- latf osf orsyreestér med 4 mol etylenoksyd pr. mol laurylalkohol, 3 vekt% lauryletersulfat med 2 mol etylenoksyd pr. mol , 2 vekt% talgfettalkoholetoksylat med 11 mol etylenoksyd pr. mol alkohol, 10 vekt% sekundært natriumalkansulfonat med en kar-bonkjede på 14-17 C-atomer, 2% by weight of a mixture of mono- and dilaurylethoxy- latf phosphoric acid esters with 4 mol ethylene oxide per mol lauryl alcohol, 3 wt% lauryl ether sulfate with 2 mol ethylene oxide per mol , 2 wt% tallow fat alcohol ethoxylate with 11 mol ethylene oxide per moles of alcohol, 10% by weight of secondary sodium alkanesulfonate with a carbon chain of 14-17 C atoms,
1 vekt% karboksymetylcellulose,1% by weight carboxymethyl cellulose,
7 vekt% vann.7% water by weight.
Den ved vaskemidlet forårsakede flateskrumpning ved filting utgjorde etter 3 vaskeprosesser 3,4% ved en vaskekraft på 17,4%. The surface shrinkage caused by the detergent during felting amounted to 3.4% after 3 washing processes at a washing power of 17.4%.
Av eksemplene 1-5 fremgår at vaskemidlet ifølge oppfinnelsen ifølge eksemplene 2 - 5, på tross av deres egen vaskekraft bare forårsaker en liten filting av vaskegodset. From examples 1-5 it appears that the detergent according to the invention according to examples 2-5, despite their own washing power, only causes a slight felting of the laundry.
Claims (6)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2532802A DE2532802C2 (en) | 1975-07-23 | 1975-07-23 | Wool detergent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO762571L true NO762571L (en) | 1977-01-25 |
Family
ID=5952166
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO762571A NO762571L (en) | 1975-07-23 | 1976-07-22 |
Country Status (11)
| Country | Link |
|---|---|
| AT (1) | AT351132B (en) |
| BE (1) | BE844443A (en) |
| CH (1) | CH598349A5 (en) |
| DE (1) | DE2532802C2 (en) |
| DK (1) | DK148039C (en) |
| FR (1) | FR2318923A1 (en) |
| GB (1) | GB1515792A (en) |
| IT (1) | IT1062651B (en) |
| NL (1) | NL7607786A (en) |
| NO (1) | NO762571L (en) |
| SE (1) | SE427756B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2841445A1 (en) * | 1977-09-28 | 1979-04-05 | Ciba Geigy Ag | DETERGENTS AND DETERGENTS |
| FR2564853B1 (en) * | 1984-05-28 | 1987-08-21 | Lesieur Cotelle | LIQUID COMPOSITION FOR CLEANING HARD SURFACES. |
| FR2584736B1 (en) * | 1985-07-15 | 1987-10-23 | Rhone Poulenc Chimie | SUPPORT FOR LIQUID CONSTITUENTS, ANTI-FOAM SUBSTANCES AND DETERGENT FORMULAS CONTAINING THEM |
| US8993506B2 (en) | 2006-06-12 | 2015-03-31 | Rhodia Operations | Hydrophilized substrate and method for hydrophilizing a hydrophobic surface of a substrate |
| WO2008157197A1 (en) | 2007-06-12 | 2008-12-24 | Rhodia Inc. | Mono-, di- and polyol alkoxylate phosphate esters in oral care formulations and methods for using same |
| US7524800B2 (en) | 2007-06-12 | 2009-04-28 | Rhodia Inc. | Mono-, di- and polyol phosphate esters in personal care formulations |
| CA2690602C (en) | 2007-06-12 | 2017-02-28 | Rhodia Inc. | Hard surface cleaning composition with hydrophilizing agent and method for cleaning hard surfaces |
| US7557072B2 (en) | 2007-06-12 | 2009-07-07 | Rhodia Inc. | Detergent composition with hydrophilizing soil-release agent and methods for using same |
| CN102333853A (en) * | 2009-02-25 | 2012-01-25 | 法瑞波兹·德乌迪安 | Compositions for laundering and subsequently drying delicate garments without incurring any damage and methods to use them |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE498264A (en) * | 1949-03-30 | |||
| NO121968C (en) * | 1966-06-23 | 1977-06-13 | Mo Och Domsjoe Ab | |
| US3956198A (en) * | 1972-12-15 | 1976-05-11 | Days-Ease Home Products Corporation | Liquid laundry washing-aid |
-
1975
- 1975-07-23 DE DE2532802A patent/DE2532802C2/en not_active Expired
-
1976
- 1976-06-28 CH CH825576A patent/CH598349A5/xx not_active IP Right Cessation
- 1976-07-13 SE SE7607986A patent/SE427756B/en unknown
- 1976-07-14 NL NL7607786A patent/NL7607786A/en not_active Application Discontinuation
- 1976-07-20 GB GB30166/76A patent/GB1515792A/en not_active Expired
- 1976-07-21 AT AT536476A patent/AT351132B/en not_active IP Right Cessation
- 1976-07-21 IT IT50526/76A patent/IT1062651B/en active
- 1976-07-22 DK DK330476A patent/DK148039C/en not_active IP Right Cessation
- 1976-07-22 NO NO762571A patent/NO762571L/no unknown
- 1976-07-23 BE BE169167A patent/BE844443A/en not_active IP Right Cessation
- 1976-07-23 FR FR7622551A patent/FR2318923A1/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| GB1515792A (en) | 1978-06-28 |
| SE7607986L (en) | 1977-01-24 |
| DE2532802A1 (en) | 1977-01-27 |
| DE2532802C2 (en) | 1983-03-10 |
| NL7607786A (en) | 1977-01-25 |
| CH598349A5 (en) | 1978-04-28 |
| DK330476A (en) | 1977-01-24 |
| AT351132B (en) | 1979-07-10 |
| DK148039C (en) | 1985-07-08 |
| DK148039B (en) | 1985-02-11 |
| IT1062651B (en) | 1984-10-20 |
| BE844443A (en) | 1977-01-24 |
| SE427756B (en) | 1983-05-02 |
| FR2318923A1 (en) | 1977-02-18 |
| FR2318923B1 (en) | 1980-07-25 |
| ATA536476A (en) | 1978-12-15 |
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