NO760071L - - Google Patents
Info
- Publication number
- NO760071L NO760071L NO760071A NO760071A NO760071L NO 760071 L NO760071 L NO 760071L NO 760071 A NO760071 A NO 760071A NO 760071 A NO760071 A NO 760071A NO 760071 L NO760071 L NO 760071L
- Authority
- NO
- Norway
- Prior art keywords
- parts
- mixture
- water
- resin
- expanded polystyrene
- Prior art date
Links
- 239000004568 cement Substances 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims description 37
- 239000002245 particle Substances 0.000 claims description 14
- 229920005989 resin Polymers 0.000 claims description 13
- 239000011347 resin Substances 0.000 claims description 13
- 239000004794 expanded polystyrene Substances 0.000 claims description 11
- -1 poly(ethylene oxide) Polymers 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 159000000000 sodium salts Chemical class 0.000 claims description 8
- 229920001732 Lignosulfonate Polymers 0.000 claims description 7
- 239000002002 slurry Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 239000005909 Kieselgur Substances 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 125000000129 anionic group Chemical group 0.000 claims description 4
- 150000001735 carboxylic acids Chemical class 0.000 claims description 4
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 3
- 229920001169 thermoplastic Polymers 0.000 claims description 3
- 239000004416 thermosoftening plastic Substances 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims 1
- 239000003945 anionic surfactant Substances 0.000 claims 1
- 239000011396 hydraulic cement Substances 0.000 claims 1
- 239000000463 material Substances 0.000 description 14
- 239000000654 additive Substances 0.000 description 10
- 230000000996 additive effect Effects 0.000 description 8
- 239000004094 surface-active agent Substances 0.000 description 8
- 239000011269 tar Substances 0.000 description 8
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 5
- 239000010426 asphalt Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 235000019256 formaldehyde Nutrition 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- GKQHIYSTBXDYNQ-UHFFFAOYSA-M 1-dodecylpyridin-1-ium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+]1=CC=CC=C1 GKQHIYSTBXDYNQ-UHFFFAOYSA-M 0.000 description 1
- WHRZCXAVMTUTDD-UHFFFAOYSA-N 1h-furo[2,3-d]pyrimidin-2-one Chemical compound N1C(=O)N=C2OC=CC2=C1 WHRZCXAVMTUTDD-UHFFFAOYSA-N 0.000 description 1
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- FTBVOJZWVWWLFB-UHFFFAOYSA-N 2-(octan-2-ylamino)ethanol Chemical compound CCCCCCC(C)NCCO FTBVOJZWVWWLFB-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 235000006173 Larrea tridentata Nutrition 0.000 description 1
- 244000073231 Larrea tridentata Species 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 229960002126 creosote Drugs 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 229920006248 expandable polystyrene Polymers 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- GXSYESHGCYHSMD-UHFFFAOYSA-N n,n'-di(octan-2-yl)ethane-1,2-diamine Chemical compound CCCCCCC(C)NCCNC(C)CCCCCC GXSYESHGCYHSMD-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 229920005552 sodium lignosulfonate Polymers 0.000 description 1
- SRAWNDFHGTVUNZ-UHFFFAOYSA-M sodium;3,6-dibutylnaphthalene-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(CCCC)=CC2=CC(CCCC)=CC=C21 SRAWNDFHGTVUNZ-UHFFFAOYSA-M 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
- C08L101/02—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
- C08L101/06—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing oxygen atoms
- C08L101/08—Carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
Abstract
Sementsammensetning-tilsat ser•Cement composition-added looks •
Description
Foreliggende oppfinnelse vedrører tilsatser for inneslutning av luft i hydrauliske sementholdige sammensetnin- The present invention relates to additives for entrapping air in hydraulic cementitious compositions.
ger og for'bibeholdelse av slike sammensetninger ,i homogen til- »' stand når lette materialer anvendes som ballast. generation and preservation of such compositions in a homogeneous state when light materials are used as ballast.
US-patent nr.( 3-819-391 beskriver et frittflytende sponlignende fast stoff som dannes av 12,5 - 37,5 vekt-% av et bituminøst materiale og resten, nemlig 87,5 62,5 %, av et overflateaktivt middel, -ved dispersjon av det overflateaktive middel og de bituminøse materialer i vann og tørking av disper-sjonen for tilveiebringelse av faste spon. US Patent No. (3-819-391 describes a free-flowing chip-like solid which is formed from 12.5 - 37.5% by weight of a bituminous material and the remainder, namely 87.5-62.5%, of a surfactant , - by dispersing the surface-active agent and the bituminous materials in water and drying the dispersion to provide solid shavings.
Når mellom 0,1 og 2,0 vekt-$, basert på vekten av sementmengden, tilsettes til en sementholdig blanding inneholdende ekspanderte polystyrenpartikler' som ballast, blir det mulig for bindemiddelfasen i blandingen å inneslutte luft i en utstrekning av 1335- 60 volum-% og å bibeholde oppslemmingen, i When between 0.1 and 2.0 wt.-$, based on the weight of the amount of cement, is added to a cementitious mixture containing expanded polystyrene particles' as ballast, it becomes possible for the binder phase in the mixture to enclose air to an extent of 1335-60 vol. % and to retain the slurry, i
en homogen tilstand til og med selv "om partiklene av ekspandert polystyren kan ha en romvekt på 15>6 g/dm^-eller mindre og normalt oppviser stor tendens, til å.agglomerere og å stige til overflaten av blandingen. a homogeneous state even though the particles of expanded polystyrene may have a bulk density of 15>6 g/dm^ or less and normally exhibit a great tendency to agglomerate and to rise to the surface of the mixture.
Foreliggende oppfinnelse angår forbedrede sammensetninger i forhold-til dette patent.. Sammensetningene ifølge foreliggende oppfinnelse er enklere å blande og gir den sementholdige oppslemming andre fordeler foruten de som er angitt i ovennevnte patent. The present invention relates to improved compositions in relation to this patent. The compositions according to the present invention are easier to mix and give the cementitious slurry other advantages besides those indicated in the above-mentioned patent.
Det har nå vist seg at en vannoppløselig, vesentlig homogen, pulverformig tilsats kan fremstilles ved en enkel, mekanisk' blanding av bestanddeler og at blandingen ikke bare oppviser slike egenskaper.som luftinneslutning og bibeholdelse av homogenitet slik som sammensetningen i ovennevnte US-patent, It has now been shown that a water-soluble, substantially homogeneous, powdery additive can be produced by a simple, mechanical mixing of components and that the mixture not only exhibits such properties as air entrapment and maintaining homogeneity such as the composition in the above-mentioned US patent,
.men også oppviser de ytterligere fordeler ved at den.but they also exhibit further advantages in that it
(1) inhiberer den normale tendens som en sementoppslemming har (1) inhibits the normal tendency of a cement slurry
til å "hurtig-bindes",' (2) gir en bedre "våt kant" og (3) også forbedrer overflaten til det oppnådde betongprodukt. to "quick-set",' (2) provides a better "wet edge" and (3) also improves the surface of the resulting concrete product.
Sammensetningene ifølge foreliggende oppfinnelse The compositions according to the present invention
utgjøres av, beregnet på vekt, 40 - 60 % av de overflateaktive midler og bituminøse materialer som beskrevet i ovennevnte patent, og resten, nemlig 60 - 40 %, av ytterligere materiale som utgjøres av polyetylenoksydharpikser, lignosulfonater og diatoméjord. ' . is made up of, calculated by weight, 40 - 60% of the surfactants and bituminous materials as described in the above-mentioned patent, and the rest, namely 60 - 40%, of additional material which is made up of polyethylene oxide resins, lignosulfonates and diatomaceous earth. ' .
Ifølge foreliggende oppfinnelse tilføres en blander 4 med. overf lateaktive midler og polyetylenoksyd.. Blanderen som kan utgjøres av en konvensjonell båndblander får arbeide .til bestanddelene er godt blandet. According to the present invention, a mixer 4 is supplied with. Surface-active agents and polyethylene oxide. The mixer, which can be made up of a conventional belt mixer, is allowed to work until the components are well mixed.
Flere overf lateaktive midler, anioniske,, kationiske. og , ikke-ioniske overf lat ea,ktive midler kan benyttes ved utførelsen av foreliggende oppfinnelse. Spesie.lt anvendbare tilsatser kan på grunn av deres kjemiske struktur klassifiseres ifølge det Several surfactants, anionic, cationic. and non-ionic surfactants can be used in the implementation of the present invention. Especially useful additives can be classified according to their chemical structure
iin
nedenstående:below:
1.. Anioniske midler som omfatter alkylarylsulfonater, 1.. Anionic agents comprising alkylaryl sulfonates,
slik som alkylriaftalensulfonater, ("Alkanol B", "Nekal BX-78"); natriumsalter av formaldehyd-kondenserte naftalensulfonsyrer ("Darvan no. 1", "Darvahno. 2"'og "Tamol SN"); alkylsulfonater such as alkyl riathalenesulfonates, ("Alkanol B", "Nekal BX-78"); sodium salts of formaldehyde-condensed naphthalenesulfonic acids ("Darvan no. 1", "Darvahno. 2"' and "Tamol SN"); alkyl sulfonates
slik som natriumlaurylsulfonat ("Dupanol WA"); natriumsalter such as sodium lauryl sulfonate ("Dupanol WA"); sodium salts
av polymere karboksylsyrer ("Tamol 731").of polymeric carboxylic acids ("Tamol 731").
2. Kationiske midler omfattende kvat.ernære ammoniumsalter' 2. Cationic agents comprising quaternary ammonium salts'
slik som laurylpyridiniumklorid og trimetyloksadecylammonium-bromid; og sekundære aminer slik som N-(1-metylheptyl)etanolamin og N,N'-bis-(l-metylheptyl)etylendiamin. such as laurylpyridinium chloride and trimethyloxadecylammonium bromide; and secondary amines such as N-(1-methylheptyl)ethanolamine and N,N'-bis-(1-methylheptyl)ethylenediamine.
3. Ikke-ioniske midler omfattende produkter av metylen-.oksyd kondenserte med fettsyrer, alkoholer eller fenoler, slik • som alkylerte arylpolyestéralkoholer ("Triton X-120",). Spesielt gode ikke-ioniske midler som fortrinnsvis benyttes i blandinger er "Tween 65", som er et polyoksyetylensorbitah-tristearat og 3. Non-ionic agents comprising products of methylene oxide condensed with fatty acids, alcohols or phenols, such as alkylated aryl polyester alcohols ("Triton X-120"). Particularly good nonionic agents which are preferably used in mixtures are "Tween 65", which is a polyoxyethylene sorbitol tristearate and
"Span 60" som er et sorbitanmono-stearat."Span 60" which is a sorbitan mono-stearate.
Det har vist seg fordelaktig å benytte en blanding av forskjellige overflateaktive midler ved gjennomføringen av foreliggende oppfinnelse.. En ' f oretrukken blanding består av a) 12 vektdeler av natriumsaltene av formaldehyd kondensert med naftalensulfonsyrer ("Tamol SN"), b) 2 vektdeler av natrium saltene av polymere karboksylsyrer ("Tamol■731 SD", et sprøyte-tørket produkt), og c) .1 vektdel av en alkylfenoksypqly(etylen-oksy)-etanol som er reaksjonsproduktet av en alkylfenol med etylenoksyd med den generelle formel: It has proven advantageous to use a mixture of different surface-active agents in the implementation of the present invention. A preferred mixture consists of a) 12 parts by weight of the sodium salts of formaldehyde condensed with naphthalenesulfonic acids ("Tamol SN"), b) 2 parts by weight of the sodium salts of polymeric carboxylic acids ("Tamol■731 SD", a spray-dried product), and c) .1 part by weight of an alkylphenoxypqly(ethyleneoxy)ethanol which is the reaction product of an alkylphenol with ethylene oxide of the general formula:
(betegnelse "Igepal DM"). Begge de første to overflateaktive midler er anioniske og 'det tredje overf lateaktive mdddel er ikke-ionis.k....» (designation "Igepal DM"). Both the first two surfactants are anionic and the third surfactant is non-ionic.
Som ikke-ionisk klassifiseres også poly(etylenoksyd)-harpiksene som anvendes ifølge foreliggende oppfinnelse. (. The poly(ethylene oxide) resins used according to the present invention are also classified as non-ionic. (.
Polyetylenoksydharpiksene utgjøres av .homopolymere,r med den generelle formel' HO-CH2CH2-(0-CH2CH2)-0H. Polymerisa-sjonsgraden n varierer 'fra ca. 2000 til 100.000, hvorved tilsva-rende molekylvekter varierer fra lOOVOOO til 5•000.000. Ifølge foreliggende oppfinnelse anvendes fortrinnsvis en harpiks med en molekylvekt på ca. 400.000. ' Slike harpikser.'er oppløselige i vann og er blitt benyttet som ét pumpe-hjelpemiddel for betong. Disse harpikser oppviser ekstraordinær fortyknings-evne. Ettersom harpiksene er viskoelastiske har de evne til å absorbere mekanisk energi, fra turbulente hvirvler og å frigjøre slik lagret energi langsomt eller i en forsinket virknings- 1 rekkefølge. Denne effekt som betegnes slippreduksjon 'medfører som netto resultat at væsketransporten eller væskens bevegelse gjennom ledninger forbedres. Holdbarheten.av blandingen er ikke spesielt kritisk. Fagmannen kan lett .bestemme når denne blanding har blitt ensartet. The polyethylene oxide resins consist of homopolymers with the general formula HO-CH2CH2-(0-CH2CH2)-OH. The degree of polymerization n varies from approx. 2,000 to 100,000, whereby corresponding molecular weights vary from 1000,000 to 5,000,000. According to the present invention, a resin with a molecular weight of approx. 400,000. Such resins are soluble in water and have been used as a pumping aid for concrete. These resins exhibit extraordinary thickening ability. As the resins are viscoelastic, they have the ability to absorb mechanical energy from turbulent eddies and to release such stored energy slowly or in a delayed action sequence. This effect, which is termed slip reduction, has the net result that the liquid transport or the movement of the liquid through lines is improved. The shelf life of the mixture is not particularly critical. The person skilled in the art can easily determine when this mixture has become uniform.
Etter at blandingen har blitt ensartet, tilsettes det bituminøse materiale. Det bituminøse materiale som kan anvendes ifølge foreliggende oppfinnelse kan utgjøres av hviLket som After the mixture has become uniform, the bituminous material is added. The bituminous material which can be used according to the present invention can be made up of which
■helst materiale med lav viskositet og'med lavt mykningspunkt, som utgjøres av asfalt, steinkulltjære eller derivater derav. Det bituminøse materiale må være en væske ved romtemperatur. Derfor er de mindre viskøse asfalttyper aktuelle ved utførelse av foreliggende oppfinnelse. Asfalt med en Saybolt-viskositet på 10-4000 SFS ved 50°C er aktuell ifølge' foreliggende oppfinnelse. Alternativt kan asfalt oppløst i oppløsningsmidler . anvendes som oppnådd ved fortynning (gjenoppløsning) av et fast ■preferably material with low viscosity and with a low softening point, which consists of asphalt, coal tar or derivatives thereof. The bituminous material must be a liquid at room temperature. Therefore, the less viscous types of asphalt are relevant when carrying out the present invention. Asphalt with a Saybolt viscosity of 10-4000 SFS at 50°C is relevant according to the present invention. Alternatively, asphalt can be dissolved in solvents. is used as obtained by dilution (re-dissolution) of a solid
eller halvfast asfaltmateriale med en petroleumdestillat-fraksjon. Tjæretypene utgjøres av brune til svarte viskøse or semi-solid asphalt material with a petroleum distillate fraction. The tar types consist of brown to black viscous
væsker. oppnådd ved destruktiv destillasjon, av slike. organiske materialer som kull, petroleum og tre'. Spesielt egnede er. tjære oppnådd ved. destruktiv destillasjon av kull. Tjæren må også være en væske ved romtemperatur. Tjærens viskositet bør være liquids. obtained by destructive distillation, of such. organic materials such as coal, petroleum and wood'. Particularly suitable are. tar obtained by. destructive distillation of coal. The tar must also be a liquid at room temperature. The viscosity of the tar should be
10-4000 SFS ved 50°C. Tjære med høyere viskositet' kan fortynnes med oppløsningsmidler for oppnåelse av en ønsket viskositet. Foruten tjære kan destillater av tjære benyttes. Tjæredestil-later slik som kreosotolje som destillerer ved ca. •200-400°C og inneholder vesentlige mengder naftalen, antracen og.fenantren, 10-4000 SFS at 50°C. Higher viscosity tars can be diluted with solvents to achieve a desired viscosity. Besides tar, distillates of tar can be used. Tar distillates such as creosote oil which distills at approx. •200-400°C and contains significant amounts of naphthalene, anthracene and phenanthrene,
er også egnede ved utøvelse av foreliggende oppfinnelse. Egnede^bituminøse materialer er mørke, termoplastharpikser av polymere polynukleære hydrokarboner fremstilt ved krakking av petroleum under regulerte betingelser slik at umettede aromatiske forbindelser oppnås, hvoretter disse aromatiske forbindelser polyme-riseres til et produkt med lavt smeltepunkt.' En.vesentlig ikke-reaktiv, termoplastisk hydrokarbontype-harpiks oppnådd ved are also suitable for practicing the present invention. Suitable bituminous materials are dark, thermoplastic resins of polymeric polynuclear hydrocarbons prepared by cracking petroleum under controlled conditions so that unsaturated aromatic compounds are obtained, after which these aromatic compounds are polymerized into a low melting point product. A substantially non-reactive, thermoplastic hydrocarbon-type resin obtained by
polymerisering av materialer av hydrokarbontypen og med betegnelsen "Nebony'<:>er spesielt anvendbar ved utførelse av foreliggende oppfinnelse. Ved dette.stadium fortsettes blandingen til blandingens farge viser at en god blanding er oppnådd. polymerization of materials of the hydrocarbon type and with the designation "Nebony"<:>is particularly applicable in carrying out the present invention. At this stage the mixing is continued until the color of the mixture shows that a good mixture has been obtained.
Ved dette stadium tilsettes saltet av lignosulfonat. At this stage, the salt of lignosulfonate is added.
Lignosulfonater fremstilt ved sulfonering av ligninmaterialer slik som'kalsiumlignosulfonat, er kommersielt tilgjengelig under betegnelsen "Marasperse C" og natriumlignosulfonat er kommersielt tilgjengelig under betegnelsen "Polyfon F". Spesielt anbefales lignosulfonatet med betegnelsen "Maracon T". Lignosulfonates produced by sulfonation of lignin materials such as calcium lignosulfonate are commercially available under the name "Marasperse C" and sodium lignosulfonate is commercially available under the name "Polyfon F". In particular, the lignosulfonate with the designation "Maracon T" is recommended.
Til slutt tilsettes diatomé-jorden. Blandingen fortsettes til bestanddelene er godt blandet og dette er lett å observere. Som, resultat oppnås et. pulverformig vannoppløselig fast stoff med lysebrun farge., Finally, the diatomaceous earth is added. The mixing is continued until the ingredients are well mixed and this is easy to observe. As, result is obtained a. powdery water-soluble solid with a light brown color.,
I varmt vær og i hete og tørre klimaer har den del av In warm weather and in hot and dry climates, it has its share
.sementoppslemmingen som befinner seg i umiddelbar kontakt med de varme formene tendens til å herdes eller bindes meget hurti-gere enn øvrige deler av oppslemmingen, hvilket er et fenomen .the cement slurry which is in immediate contact with the hot forms tends to harden or bind much faster than other parts of the slurry, which is a phenomenon
som innen denne teknikk betegnes som "hurtig-binding". Dette medfører problemer på grunn av at den del som har blitt hurtig-bundet'er sprø og ikke godt forenet med resten av sement- which within this technique is referred to as "quick binding". This causes problems because the part that has been quick-set is brittle and not well united with the rest of the cement.
strukturen. Tilsatsen ifølge oppfinnelsen inhiberer denne "hurtig-binding" uten at den totale bindingstid for betong-', sammensetningen endres. the structure. The additive according to the invention inhibits this "quick setting" without changing the total setting time of the concrete composition.
Et annet fenomen som har tendens til å inntreffe, spesielt ved varmt og tørt vær, er at etter hverandre fylte seksjoner ikke bindes godt sammen slik at man kan få en fugeløs struktur, selv om bare en kort tidsperiode kan ha forløpt mellom påfyllingen av de to seksjonene. Evnen til å bibeholde egen-skapen av en seksjon so,m forenes med en deretter påfylt seksjon av betong, betegnes som oppvisning av en "våt kant". Tilsatsen ■ ifølge foreliggende oppfinnelse muliggjør at betongsammensetnin-gen i hvilken, den anvendes oppviser en funksjonsdyktig våt kant i lengre tidsperiode. ' Another phenomenon that tends to occur, especially in hot and dry weather, is that successive filled sections do not bond well together so that a jointless structure can be obtained, even though only a short period of time may have elapsed between the filling of the two the sections. The ability to retain the property of a section which is joined with a subsequently filled section of concrete is referred to as exhibiting a "wet edge". The additive ■ according to the present invention enables the concrete composition in which it is used to exhibit a functional wet edge for a longer period of time. '
Når ekspandert polystyren skal utgjøre ballasten, kan den pulverformige tilsa,ts tilsettes til de ekspanderte polystyrenpartikler ved et hvilket som helst tidspunkt etter at partiklene er forekspandert. Partiklene er deretter ferdige og anvendes som ballast for en sementholdig sammensetning med lav When expanded polystyrene is to form the ballast, the powdered additive can be added to the expanded polystyrene particles at any time after the particles have been pre-expanded. The particles are then finished and used as ballast for a cementitious composition with lichen
tetthet. Blandingen av ballasten,, d.v.s. de 'ekspanderte polystyrenpartikler og tilsatsen kan gjennomføres under nøye regulerte betingelser. Deretter behøver ballasten bare tilsettes, til sementen og- vannet på feltet under anvendelse av konvensjonell teknikk. density. The mixture of the ballast,, i.e. the 'expanded polystyrene particles and the additive can be carried out under carefully regulated conditions. The ballast then only needs to be added to the cement and water on the field using conventional techniques.
Fortrinnsvis anvendes tilsatssammensetningen- ifølge oppfinnelsen slik at 0,7 - 2,6 kg, men fortrinnsvis ca. 1,2 kg, av sammensetningen som ovenfor beskrevet, blandes med ca. 0,24 m^ ekspanderte polystyrenpartikler, hvilke' partikler er ekspandert slik at deres■sluttlige tetthet er ca. 15,6 - 156 g/dm , fortrinnsvis .i området 15,6 - 46,8 g/dm^.. Strukturelt sett oppviser■partiklene adskilte sluttede celler som gjør dem Preferably, the additive composition - according to the invention - is used so that 0.7 - 2.6 kg, but preferably approx. 1.2 kg, of the composition as described above, is mixed with approx. 0.24 m^ expanded polystyrene particles, which' particles are expanded so that their ■final density is approx. 15.6 - 156 g/dm , preferably in the range 15.6 - 46.8 g/dm^.. Structurally speaking, the particles exhibit separate closed cells which make them
'vesentlig ugjennomtrengelige for vann og derved unngås en økning av vannbehovet for den våte sementblanding. Slike ekspanderte polystyrenperler finnes kommersielt tilgjengelige fra flere produsenter. I de ekspanderbare polystyrenpartikler er det innesluttet. 3 - 15 vekt-% av et flyktig hydrokarbon-skummemiddel, slik som pentan. eller petroleumeter, som lett avdrives ved forhøyede temperaturer. Oppvarming av disse partikler i ikke-innestengt tilstand innebærer at polystyrenperlene ekspanderer til 10 - 60 ganger opprinnelig størrelse. Varmen kan oppnås på substantially impermeable to water and thus an increase in the water requirement for the wet cement mixture is avoided. Such expanded polystyrene beads are commercially available from several manufacturers. It is enclosed in the expandable polystyrene particles. 3 - 15% by weight of a volatile hydrocarbon foaming agent, such as pentane. or petroleum ether, which is easily driven off at elevated temperatures. Heating these particles in an unconfined state means that the polystyrene beads expand to 10 - 60 times their original size. The heat can be achieved on
konvensjonell•måte ved hjelp,av varmluft, damp, varmt vann, infrarød bestråling og lignende. conventional•way using hot air, steam, hot water, infrared radiation and the like.
I det foregående . har man beskrevet visse-utførelses- , former av foreliggende oppfinnelse. Det er dog åpenbart for fagmannen at modifikasjoner og variasjoner av oppfinnelsen er mulige innen oppfinnelsens ramme.' In the foregoing. certain embodiments of the present invention have been described. However, it is obvious to the person skilled in the art that modifications and variations of the invention are possible within the scope of the invention.'
Fremstillingen,av tilsatsen gjennomføres lett ved til-setning hvorved deler betegner vektdeler dersom intet annet er ' angitt, til en konvensjonell blander av båndtypen a.v 35 deler' av natriumsaltene av med formaldehyd kondenserte naftalensulfon-«syrer ("Tamol SN"), 6 deler av natriumsaltene av polymere karboksylsyrer ("Tamol 731" ,■ .sprøytetørket til et pulver), 3 deler av alkylfenoksypoly(oksyetylen)etanoler- ("Igepal DM") _og 3 deler av poly(etylenoksyd)harpiks ("Polyox WSRN 3000"). The preparation of the additive is easily carried out by adding parts by weight if nothing else is indicated to a conventional mixer of the ribbon type a.v 35 parts of the sodium salts of formaldehyde-condensed naphthalenesulfonic acids ("Tamol SN"), 6 parts of the sodium salts of polymeric carboxylic acids ("Tamol 731", spray-dried to a powder), 3 parts of alkylphenoxypoly(oxyethylene)ethanols- ("Igepal DM") _and 3 parts of poly(ethylene oxide) resin ("Polyox WSRN 3000") .
Blandingen fortsettes ttil bestanddelene synes å være godt blandet . The mixing is continued until the ingredients appear to be well mixed.
Deretter tilsettes 7 deler av det bituminøse materiale ("Nebony L-55", en væske) og blandingen_fortsettes til satsen Then 7 parts of the bituminous material ("Nebony L-55", a liquid) are added and the mixture_continues to the batch
synes å ha fått en jevn farge, hvilket viser at bestanddelene, er godt blandet. appears to have acquired a uniform colour, which shows that the ingredients are well mixed.
Deretter tilsettes 15 deler av alkalisaltene av lignosulfonat ("Maracon T") og blandingen fortsettes til produktets utseende viser at det er godt blandet. Then 15 parts of the alkali salts of lignosulfonate ("Maracon T") are added and mixing is continued until the appearance of the product shows that it is well mixed.
Ved dette tidspunkt tilsettes 31 deler diatcmejord ("Celite") og blandingen fortsettes igjen til blandingen syne§At this point, 31 parts of diatomaceous earth ("Celite") are added and the mixture is continued again until the mixture is syne§
å være ensartet.to be uniform.
Ved fremstillingen av lettbetong blandes''0,5 m^ ekspanderte polystyrenpartikler (normalt 2 sekker hver inneholdende 0,25 m ekspandert polystyren) som ballast, 2,7 kg av den pulverformige tilsats ifølge foreliggende oppfinnelse, 250 kg Portland-sement (vanligvis seks konvensjonelle sekker, som hver . In the production of lightweight concrete, 0.5 m^ expanded polystyrene particles (normally 2 bags each containing 0.25 m expanded polystyrene) are mixed as ballast, 2.7 kg of the powdered additive according to the present invention, 250 kg of Portland cement (usually six conventional sacks, which each .
veier 4l,5 kg) og 115-140 liter vann i en konvensjonell horison-talblander. 'Derved oppnås en oppslemming som gir 0,65 - 0,68 m^ av en betongstruktur med en sluttlig tetthet på ca. 45 g/dm^ og inneholdende ca. 50 % innesluttet luft i bindemiddelfasen. weighs 4l.5 kg) and 115-140 liters of water in a conventional horizontal mixer. Thereby, a slurry is obtained which gives 0.65 - 0.68 m^ of a concrete structure with a final density of approx. 45 g/dm^ and containing approx. 50% trapped air in the binder phase.
Claims (4)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US54351375A | 1975-01-23 | 1975-01-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO760071L true NO760071L (en) | 1976-07-26 |
Family
ID=24168383
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO760071A NO760071L (en) | 1975-01-23 | 1976-01-09 |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS5230529B2 (en) |
| BE (1) | BE837077A (en) |
| CA (1) | CA1078539A (en) |
| DE (1) | DE2601816A1 (en) |
| DK (1) | DK22476A (en) |
| FR (1) | FR2298520A2 (en) |
| GB (1) | GB1498383A (en) |
| IT (1) | IT1052522B (en) |
| NL (1) | NL7514985A (en) |
| NO (1) | NO760071L (en) |
| SE (1) | SE7600161L (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2814317B1 (en) * | 1978-04-03 | 1979-05-10 | Siegfried Maier | Additive for dehumidifying plaster |
| JPS58161953A (en) * | 1982-03-19 | 1983-09-26 | 株式会社間組 | Two-component cement composition |
| HU228967B1 (en) | 2008-11-19 | 2013-07-29 | Loeglen Kft | Lightweight building structure and a method making thereof |
| HU228968B1 (en) | 2010-02-17 | 2013-07-29 | Wyw Block Ag | Energy - and weight - saving building element, as well as making and application procedure thereof |
| JP6877392B2 (en) * | 2018-08-20 | 2021-05-26 | 日本製紙株式会社 | Granular composition and its production method, dispersant, and hydraulic composition |
| JP6877391B2 (en) * | 2018-08-09 | 2021-05-26 | 日本製紙株式会社 | Granular composition and dispersant |
| US11873443B2 (en) | 2018-08-09 | 2024-01-16 | Nippon Paper Industries Co., Ltd. | Composition and production method of same, and dispersing agent |
| JP6830083B2 (en) * | 2018-08-15 | 2021-02-17 | 日本製紙株式会社 | Dispersant and its manufacturing method |
-
1975
- 1975-12-05 IT IT52557/75A patent/IT1052522B/en active
- 1975-12-08 JP JP50146825A patent/JPS5230529B2/ja not_active Expired
- 1975-12-12 CA CA241,632A patent/CA1078539A/en not_active Expired
- 1975-12-23 NL NL7514985A patent/NL7514985A/en not_active Application Discontinuation
- 1975-12-24 BE BE163113A patent/BE837077A/en unknown
-
1976
- 1976-01-09 SE SE7600161A patent/SE7600161L/en unknown
- 1976-01-09 NO NO760071A patent/NO760071L/no unknown
- 1976-01-13 FR FR7600731A patent/FR2298520A2/en active Granted
- 1976-01-20 DE DE19762601816 patent/DE2601816A1/en not_active Withdrawn
- 1976-01-21 DK DK22476*#A patent/DK22476A/en not_active Application Discontinuation
- 1976-01-23 GB GB2753/76A patent/GB1498383A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2601816A1 (en) | 1976-07-29 |
| NL7514985A (en) | 1976-07-27 |
| DK22476A (en) | 1976-07-24 |
| JPS5187530A (en) | 1976-07-31 |
| JPS5230529B2 (en) | 1977-08-09 |
| FR2298520B2 (en) | 1980-11-07 |
| GB1498383A (en) | 1978-01-18 |
| FR2298520A2 (en) | 1976-08-20 |
| CA1078539A (en) | 1980-05-27 |
| SE7600161L (en) | 1976-07-26 |
| IT1052522B (en) | 1981-07-20 |
| BE837077A (en) | 1976-04-16 |
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