NO743873L - - Google Patents
Info
- Publication number
- NO743873L NO743873L NO743873A NO743873A NO743873L NO 743873 L NO743873 L NO 743873L NO 743873 A NO743873 A NO 743873A NO 743873 A NO743873 A NO 743873A NO 743873 L NO743873 L NO 743873L
- Authority
- NO
- Norway
- Prior art keywords
- weight
- masonry
- water
- parts
- additive
- Prior art date
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000000654 additive Substances 0.000 claims description 15
- 230000000996 additive effect Effects 0.000 claims description 14
- 239000000945 filler Substances 0.000 claims description 13
- 239000002904 solvent Substances 0.000 claims description 10
- 239000011253 protective coating Substances 0.000 claims description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 7
- 239000004576 sand Substances 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 239000004568 cement Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 238000004945 emulsification Methods 0.000 claims description 5
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 claims description 4
- 229940044172 calcium formate Drugs 0.000 claims description 4
- 235000019255 calcium formate Nutrition 0.000 claims description 4
- 239000004281 calcium formate Substances 0.000 claims description 4
- 230000001804 emulsifying effect Effects 0.000 claims description 4
- 230000007062 hydrolysis Effects 0.000 claims description 4
- 238000006460 hydrolysis reaction Methods 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000004570 mortar (masonry) Substances 0.000 claims description 4
- 239000003945 anionic surfactant Substances 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 2
- 239000000843 powder Substances 0.000 description 10
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- -1 kaolin Chemical class 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000004438 BET method Methods 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000011398 Portland cement Substances 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- 229920003319 Araldite® Polymers 0.000 description 1
- OYPRJOBELJOOCE-IGMARMGPSA-N Calcium-40 Chemical group [40Ca] OYPRJOBELJOOCE-IGMARMGPSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- HHSPVTKDOHQBKF-UHFFFAOYSA-J calcium;magnesium;dicarbonate Chemical compound [Mg+2].[Ca+2].[O-]C([O-])=O.[O-]C([O-])=O HHSPVTKDOHQBKF-UHFFFAOYSA-J 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical class NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
- 229960002415 trichloroethylene Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/1018—Coating or impregnating with organic materials
- C04B20/1022—Non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/40—Surface-active agents, dispersants
- C04B2103/402—Surface-active agents, dispersants anionic
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/40—Surface-active agents, dispersants
- C04B2103/406—Surface-active agents, dispersants non-ionic
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/46—Water-loss or fluid-loss reducers, hygroscopic or hydrophilic agents, water retention agents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
- Adhesives Or Adhesive Processes (AREA)
Description
Tilsetningsraiddel for selvj e.vnende murverk. Additive part for self-leveling masonry.
Foreliggende oppfinnelse angår et tilsetningsmiddel for fremstilling av selvjevnende murverk. The present invention relates to an additive for the production of self-leveling masonry.
Med selvjevnende murverk menes et flytende murverk som By self-leveling masonry is meant a floating masonry that
etter påføring på et underlag gir en kledning eller et beskyttelsesbelegg som er fritt for uregelmessigheter i flaten uten at man be-høver å gjennomføre noen polering. Denslags murverk anvendes meget i bygningsindustrien for å eliminere ujevnheter i ikke-bearbeidede konstruksjonsblokker eller i horisontale flater av en hvilken som helst type, på hvilke man har til hensikt å påføre endelige belegg, slik som limede gulv, plastflater eller heldekkende gulvbelegnings-sjikt. after application to a substrate provides a coating or a protective coating that is free of irregularities in the surface without having to carry out any polishing. This type of masonry is widely used in the construction industry to eliminate unevenness in unprocessed construction blocks or in horizontal surfaces of any type, on which it is intended to apply final coverings, such as glued floors, plastic surfaces or full-covering floor covering layers.
Hvis flaten skal være helt plan, foretrekker man selfølgelig et selvjevnende murverk på grunn.av lettheten ved anvendelsen av dette. If the surface is to be completely flat, a self-levelling brickwork is naturally preferred due to the ease with which it is used.
Når de selvjevnende murverk benyttes i tynne sjikt hvis tykkelse er en funksjon av feilene i platene og som kan variere mellom ca. 1 og 2 cm, bør de hefte kraftig ved de underlag på hvilke de er anbragt, -og de bør hellerJikke oppvise noen sprekkdannelse eller noen kontraksjon. De mekaniske egenskaper, spesielt bøyestrekk-fastheten og trykkfastheten bør være gode. When the self-levelling masonry is used in thin layers whose thickness is a function of the defects in the slabs and which can vary between approx. 1 and 2 cm, they should adhere strongly to the substrates on which they are placed, and they should also not show any cracking or contraction. The mechanical properties, especially the bending tensile strength and compressive strength, should be good.
Murverk med selvjevnende virkning fremstilles for tiden ved at man tilsetter kaseinpulver til en blanding av sand, sement og vann, hvilken -blanding har et høyt sement innhold.. Denslags murverk oppviser imidlertid ikke alle de ønskede egenskaper, spesielt fravær av sprekkdannelse i flaten og fravær av dekantering av selve murverket. Masonry with a self-leveling effect is currently produced by adding casein powder to a mixture of sand, cement and water, which mixture has a high cement content. However, this type of masonry does not exhibit all the desired properties, in particular the absence of cracks in the surface and the absence of decanting the masonry itself.
Man har nå'funnet et pulverformig tilsetningsmiddel for selvjevnende murverk, hvilket middel karakteriseres ved at det består av 30-80 vekt-%, fortrinnsvis 33-55 vekt-%, av et fyllstoff med en.spesi-<1>fik flate større enn 10 m /g, 10-40 vekt-%, og fortrinnsvis 15~30 vekt-% av et emulgeringssystem og 5~60 vekt-%, fortrinnsvis 20-40 vekt-% av et middel som holder tilbake vannet. A powdered additive for self-levelling masonry has now been found, which agent is characterized by the fact that it consists of 30-80% by weight, preferably 33-55% by weight, of a filler with a specific surface area greater than 10 m /g, 10-40% by weight, and preferably 15~30% by weight of an emulsifying system and 5~60% by weight, preferably 20-40% by weight of an agent that retains water.
Dette tilsetningsmiddel anvendes i en mengde av 2-8 vektdeler pr. 100 vektdeler sement, 50-150 vektdeler sand og eventuelt 2-4 vektdeler av en akselerator. This additive is used in an amount of 2-8 parts by weight per 100 parts by weight of cement, 50-150 parts by weight of sand and possibly 2-4 parts by weight of an accelerator.
Man kan anvende et hvilket :som helst fyllstoff som har en . You can use any filler that has a .
spesifik flate på større enn 10 m 2/g. specific surface of greater than 10 m 2/g.
Blant de oftest anvendte fyllstoffer skal nevnes silikater slik som kaolm, oksyder slik som aluminiumoksyd, kalsiumkarbonat, kalsiummagnesiumkarbonat, bariumsulfat og kalsiumsulfat. Among the most commonly used fillers are silicates such as kaolin, oxides such as aluminum oxide, calcium carbonate, calcium magnesium carbonate, barium sulfate and calcium sulfate.
Dette fyllstoff tjener som bærer for emulgeringssystemet hvis tørrstoff består av 0-40 vekt-% av et ikke-ionisk overflateaktivt stoff og 60-100 vekt-% av et anionisk overflateaktivt stoff. De ikke-ioniske overflateaktive stoffer kan velges blant alkylfenolderivater, fenylderivater og fettalkoholderivater. This filler serves as a carrier for the emulsification system whose dry matter consists of 0-40% by weight of a non-ionic surfactant and 60-100% by weight of an anionic surfactant. The non-ionic surfactants can be selected from among alkylphenol derivatives, phenyl derivatives and fatty alcohol derivatives.
Man foretrekker å anvende oksyetylenderivater inneholdende 6-30 mol etylenoksyd bundet til oktylfenoler eller nonylfenoler. It is preferred to use oxyethylene derivatives containing 6-30 mol of ethylene oxide bound to octylphenols or nonylphenols.
De anioniske overflateaktive stoffer kan velges blant følg-ende forbindelser : sulfaterte derivater, av amider av aminoalkohol, aminer stammende fra aminosulfonsyrer eller aminosyrer, derivater av .alkalimetallalkyisulfater, sulfonerte derivater av monoestere eller diestere, derivater av alkylbenzensulfonater. The anionic surfactants can be chosen from the following compounds: sulfated derivatives of amino alcohol amides, amines derived from aminosulfonic acids or amino acids, derivatives of alkali metal alkyl sulfates, sulfonated derivatives of monoesters or diesters, derivatives of alkylbenzenesulfonates.
Dette emulgeringssystem avsettes på det inerte fyllstoff, hvilket tjener som bærer, hvorved man oppnår et pulver som er egnet til industriell anvendelse. This emulsification system is deposited on the inert filler, which serves as a carrier, whereby a powder suitable for industrial use is obtained.
Man kan imidlertid tenke seg at dette emulgeringssystemet foreligger i form av en vasske, hvilken skulle kunne føres inn i det vann som anvendes for beredning av murverket. One can imagine, however, that this emulsification system exists in the form of a sink, which could be introduced into the water used for preparing the masonry.
For å avsette emulgeringssystemet på fyllstoffet på homogen måte oppløser man eller suspenderer man de overflateaktive stoffer i .. oppløsningsrniddel. Mengden oppløsningsmiddel velges på en slik måte at man ved påføring på fyllstoffet oppnår en fast pasta. Man anvender vanligvis mellom 20 og 150 vektdeler, fortrinnsvis mellom 30 og 120' vektdeler oppløsningsmiddel pr.. 100 vektdeler fyllstoff. In order to deposit the emulsification system on the filler in a homogeneous manner, the surface-active substances are dissolved or suspended in a solvent. The amount of solvent is chosen in such a way that a solid paste is obtained when applied to the filler. Usually between 20 and 150 parts by weight, preferably between 30 and 120 parts by weight, of solvent are used per 100 parts by weight of filler.
Fortrinnsvis anvender man oppløsningsmidler med et kokepunkt på under 100°C, f.eks. alkoholer slik som metanol, etanol.eller iso-propylalkohol, estere slik som etylacetat, ketoner slik som aceton eller metyletylketon, klorerte oppløsningsmidler slik som metylenklorid, dikloretan, trikloretan eller trikloreten. ' Solvents with a boiling point below 100°C are preferably used, e.g. alcohols such as methanol, ethanol or isopropyl alcohol, esters such as ethyl acetate, ketones such as acetone or methyl ethyl ketone, chlorinated solvents such as methylene chloride, dichloroethane, trichloroethane or trichloroethene. '
Man fremstiller en oppløsning eller en suspensjon av de overflateaktive stoffer og innfører denne oppløsning sammen med fyllstoffet i en blander. Man oppnår en pasta som homogeniseres. Etter at pastaen er omrørt, fjernes oppløsningsmidlet og eventuelt vannet i de overflateaktive stoffer, énten ved oppvarming hvorved blanderen eventuelt settes under vakuum, eller ved at apparatet gjennomblåses med' en gass slik som luft eller nitrogen som kan være oppvarmet til en temperatur på mellom 50 og 70°C og som fører med seg oppløsningsmidlet. A solution or a suspension of the surfactants is prepared and this solution is introduced together with the filler into a mixer. A paste is obtained which is homogenized. After the paste has been stirred, the solvent and possibly the water in the surfactants are removed, either by heating whereby the mixer is optionally placed under vacuum, or by blowing the apparatus through with a gas such as air or nitrogen which can be heated to a temperature of between 50 and 70°C and which carries the solvent with it.
For å begrense risikoen for at overflateaktive stoffer skal føres bort sammen med■oppløsningsmidlet 'må man unngå at temperaturen blir altfor høy.- Etter fullstendig avdampning av oppløsningsmidlet oppnår man et løst pulver som har en meget varierende partikkelstør-relse og som har et tørt utseende. Man tilsetter deretter det vanntilbakeholdende stoff og omrører for å homogenisere de to pulvere. In order to limit the risk of surface-active substances being carried away together with the solvent, the temperature must be avoided. . The water-retaining substance is then added and stirred to homogenize the two powders.
Den oppnådde pulverblanding males deretter på en egnet måte slik at man oppnår et pulver med en partikkelstørrelse på mindre enn 500^um. Som vanntilbakeholdende stoff anvender man naturlige pro-dukter slik som alginater, cellulosederivater, f.eks. hydroksyalkyl-cellulose eller karboksymetylcellulose, polyakrylsyrederivater, f.eks. The obtained powder mixture is then ground in a suitable manner so that a powder with a particle size of less than 500 µm is obtained. Natural products such as alginates, cellulose derivatives, e.g. hydroxyalkyl cellulose or carboxymethyl cellulose, polyacrylic acid derivatives, e.g.
■natriumpolyakrylat eller polyvinylalkohol. ■sodium polyacrylate or polyvinyl alcohol.
Man foretrekkee polyvinylalkoholer med en molekylær hydrolysegrad på mellom 94 og 82% og med en viskositet på mellom 10 og 20 cP, målt ved 20°C i en vannoppløsning inneholdende 4 vekt-% polyvinylalkohol. Polyvinyl alcohols with a molecular degree of hydrolysis of between 94 and 82% and with a viscosity of between 10 and 20 cP, measured at 20°C in a water solution containing 4% by weight of polyvinyl alcohol, were preferred.
Det vanntilbakeholdende stoff anvendes i en mengde på mellom og 60 vekt-%, fortrinnsvis mellom 20 og 40 vekt-%, beregnet på det ferdige pulverets vekt. The water-retaining substance is used in an amount of between and 60% by weight, preferably between 20 and 40% by weight, calculated on the weight of the finished powder.
Det oppnådde tørre, pulverformige tilsetningsmiddel kan opp-bevares i lang tid hvis det isoleres fra fuktighet. Det anvendes som The dry, powdery additive obtained can be stored for a long time if isolated from moisture. It is used as
sådant ved tidspunktet for fremstilling av murverket. Murverket fremstilles ved at man blander 100 vektdeler sement, 50-150 vektdeler tørr sand og 2-8 vektdeler tilsetningsstoff. Når man på manuell måte eller ved anvendelse av en betongblander har oppnådd en blanding, tilsetter man det nødvendige vann, dvs. ca. 15-22 vekt-%, beregnet på murverkets totale vekt. such at the time of manufacture of the masonry. The masonry is produced by mixing 100 parts by weight of cement, 50-150 parts by weight of dry sand and 2-8 parts by weight of additives. When a mixture has been achieved manually or by using a concrete mixer, the necessary water is added, i.e. approx. 15-22% by weight, calculated on the total weight of the masonry.
Man kan fastslå at anvendelsen av tilsetningsstoffet ifølge foreliggende oppfinnelse gjør det mulig i betydelig' grad å redusere den nødvendige mengde vann fordi tilsetningsstoffet' gjør murverket flytende. It can be established that the use of the additive according to the present invention makes it possible to significantly reduce the required amount of water because the additive makes the masonry liquefiable.
Man kan til murverket sette'forskjellige vanligvis benyttede-stoffer, f.eks. en akselerator på basis av kalsiumformiat, ettersom tilsetningsstoffet ifølge oppfinnelsen har en tendens til å forlenge murverkets avbindingsfid. Various commonly used materials can be added to the masonry, e.g. an accelerator based on calcium formate, as the additive according to the invention tends to extend the setting life of the masonry.
Ved å plassere murverket i en beholder kan man kontrollere at det ikke skjer noen dekantering og ikke noen utsvetting av vann. Det ferske murverkets selvjevnende evne prøves ved at man måler murverkets utflytningsevne. For dette formål anvender man et Matthis-viskosimeter som vanligvis anvendes innenfor maleindustrien og som består av en i cm gradert plate som ved den ene ende er utstyr med en skål med et volum- på ca. '2 cm^.. Man fyller skålen med murverk, plas-serer fluidimeteret vertikalt og.måler lengden av den utflytning som skjer på 10 sekunder. Murbruket sies å være selvjevnende når den tid som går mellom fremstilling av murverket og det tidspunkt når utflyt-ningen kun er 5 cm på 10 sekunder. By placing the masonry in a container, it can be checked that no decanting occurs and no sweating of water. The self-levelling ability of the fresh masonry is tested by measuring the masonry's ability to float. For this purpose, a Matthis viscometer is used which is usually used in the painting industry and which consists of a plate graduated in cm which is equipped at one end with a bowl with a volume of approx. '2 cm^.. One fills the bowl with masonry, places the fluidimeter vertically and measures the length of the outflow which takes place in 10 seconds. The masonry is said to be self-levelling when the time that elapses between the manufacture of the masonry and the time when the displacement is only 5 cm in 10 seconds.
Ved anvendelse av .det nyfrémstilte murverk fremstiller'man også prøvestykker med dimensjoner 4 cm x 4 cm x 16 cm. På disse prøve-stykker måler man bøyningsfastheten og trykkfastheten ifølge normen NF P 15-451 (juli 1963). When using the newly framed masonry, test pieces with dimensions 4 cm x 4 cm x 16 cm are also produced. The bending strength and compressive strength are measured on these test pieces according to the standard NF P 15-451 (July 1963).
Man måler.dessuten murverkets vedheftningsegenskaper ved å støpe et beskyttelsesbelegg med en tykkelse på. 5 mm på den flate side-flate av en ubearbeidet betongblokk fremstilt ved å gå ut fra et murverk inneholdende 25 kg sement CPA 325 og 96 kg sand med en partikkel-størrelse på mellom 0 og 5 mm. In addition, the adhesion properties of the masonry are measured by casting a protective coating with a thickness of 5 mm on the flat side surface of an unworked concrete block produced by starting from a masonry containing 25 kg of cement CPA 325 and 96 kg of sand with a particle size of between 0 and 5 mm.
Ved hjelp av en valsefrese skjærer man ut stykker med en diameter på 5 cm (snittet går kun til den bærende blokk). Ved- hjelp av et Aralditlim limer man fast disse stykker på aluminiumstykker på hvilke det er mulig å skru fast spennbakkene på et dynamometer som arbeider med konstant hastighet og som muliggjør måling av kraften som er nødvendig for å trekke stykkene fra hverandre. Using a roller cutter, pieces with a diameter of 5 cm are cut out (the cut only goes to the supporting block). Using an Araldite glue, these pieces are glued onto aluminum pieces, on which it is possible to screw the clamping jaws of a dynamometer that works at a constant speed and which enables the measurement of the force required to pull the pieces apart.
Denne bestemmelse skjer enten etter 28 døgns lagring ved 23°C'og 501 relativ fuktighet (vedhefting i tørr tilstand) eller etter 28 døgns lagring under de samme- betingelser og etterfølgende nedsenk-ning i vann i 7 døgn (vedhefting i fuktig tilstand).'De oppnådde resultater uttrykkes i kp/cm p . This determination takes place either after 28 days of storage at 23°C and 501 relative humidity (adhesion in a dry state) or after 28 days of storage under the same conditions and subsequent immersion in water for 7 days (adhesion in a moist state). The results obtained are expressed in kp/cm p .
Man undersøker murbrukets bindingsegenskaper ved på samme betongblokk som ovenfor å støpe et beskyttelsesbelegg med en tykkelse''på 1-2 mm. Ved skraping med fingeren etter 24 timer kontrollerer man om det skjer noen stoffdannelse på flaten. The bonding properties of the mortar are examined by casting a protective coating with a thickness of 1-2 mm on the same concrete block as above. By scraping with your finger after 24 hours, you check whether any substance formation occurs on the surface.
Oppfinnelsen skal illustreres ved følgende, ikke-begrensende eksempler. The invention shall be illustrated by the following non-limiting examples.
Eksempel 1. Example 1.
Til en 15.0 liters blander utstyrt med Z-formede røreblad settes 45- kg av et kalsinert kaolin med en spesifik overflate på 26 m 2/ g (målt ifølge BET-metoden) og en partikkelstørrelse på mindre enn 40 yum. Deretter tilsettes 12,5 kg natriumdioktylsulfonsuccinat, 5 kg oksyetylennonylfenol (kondensat av nonylfenol og 30 mol etylenoksyd) og 46 kg metylenklorid. 45 kg of a calcined kaolin with a specific surface area of 26 m 2 / g (measured according to the BET method) and a particle size of less than 40 yum is added to a 15.0 liter mixer equipped with Z-shaped stirring blades. Then 12.5 kg of sodium dioctylsulfonsuccinate, 5 kg of oxyethylene nonylphenol (condensate of nonylphenol and 30 mol of ethylene oxide) and 46 kg of methylene chloride are added.
Det blandes i 10 minutter ved romtemperatur, slik at man oppnår en homogen pas.ta. Under fortsatt omrøring oppvarmes blandingen til 70-80°C helt til full eliminering av den flyktige fase. Dette tar 13 timer."" Deretter avkjøles til romtemperatur. It is mixed for 10 minutes at room temperature, so that a homogeneous paste is obtained. With continued stirring, the mixture is heated to 70-80°C until complete elimination of the volatile phase. This takes 13 hours."" Then cool to room temperature.
Man tilsetter deretter 25 kg av et polyvinylalkohol med en .molekylær hydrolysegrad på 88,2% og en viskositet på 14 cP. Det blan-dea i 10 minutter. 25 kg of a polyvinyl alcohol with a molecular hydrolysis degree of 88.2% and a viscosity of 14 cP are then added. It mixed for 10 minutes.
Deretter overføres, det hele til en.med knivblad utstyrt måle-apparatur hvori man oppnår et pulver med en partikkelstørrelse mindre enn 500^urn. The whole is then transferred to a measuring apparatus equipped with a knife blade, in which a powder with a particle size of less than 500 µm is obtained.
Man fremstiller et selvjevnende murbruk ved å blande 100 vektdeler kunstig Portland-sement 400,.75 vektdeler Fontainebleau-sand, 40 vektdeler av det ovenfor fremstilte pulver, 3 vektdeler kalsiumformiat og 40 vektdeler vann. A self-levelling mortar is prepared by mixing 100 parts by weight of artificial Portland cement, 400.75 parts by weight of Fontainebleau sand, 40 parts by weight of the powder prepared above, 3 parts by weight of calcium formate and 40 parts by weight of water.
Det oppnådde murverk er selvjevnende i løpet av 1 time og The achieved masonry is self-leveling within 1 hour and
15 minutter, målt ifølge den ovenfor angitte metode. Murverket oppviser ingen dekantering. Det fremstilles prøvelegemer med dimensjon-ene 4,cm x 16 cm x 4 cm. Ved måling ifølge normen NF P 15-451 bestem-mes prøvelegemene.s bøymngsfasthet til 55 kp/cirr 2 og trykkfastheten til 400 kp/cm<2>. 15 minutes, measured according to the above method. The masonry shows no decantation. Test specimens with dimensions 4.cm x 16 cm x 4 cm are produced. When measuring according to the standard NF P 15-451, the flexural strength of the test bodies is determined to be 55 kp/cir 2 and the compressive strength to 400 kp/cm<2>.
Man støper et 5 mm tykt beskyttelsesbelegg på den.glatte sideflaten av en betongblokk og måler beskyttelsesbeleggets vedhefting på den ovenfor beskrevne måte. Man finner en vedhefting i tørr tilstand på 19 kp/cm . A 5 mm thick protective coating is cast on the smooth side surface of a concrete block and the adhesion of the protective coating is measured in the manner described above. An adhesion in the dry state of 19 kp/cm is found.
Det fremstilles et beskyttelsesbelegg med tykkelsen 1-2 mm, A protective coating with a thickness of 1-2 mm is produced,
og man fastslår etter. 24 timer at det ikke skjer noen stoff dannelse på flaten. Heller ikke skjer det noen sprekkdannelse. and one determines after. 24 hours that no substance formation occurs on the surface. Nor does any cracking occur.
Eksempel 2. Example 2.
Til en 50 liters blander med Z-formede røreblad og videre utstyrt med et system for oppvarming ved hjelp av høytrykksdamp og utstyrt med anordninger for vakuum, settes 15 kg av et kalsinert kaolin med en spesifik overflate på 26 m 2/g.(målt ifølge BET-metoden) og en-partikkelstørrelse på mindre enn 40 ^um. Man tilsetter 735kg dodecy.l-benzensulfonat av trietanolamin i form av en 80%-ig oppløsning i vann, 1,5 kg av et kondensat av 6 molekyler etylenoksyd med et molekyl noriylfenoi, og 6 kg metanol. 15 kg of a calcined kaolin with a specific surface of 26 m 2 /g is added to a 50 liter mixer with Z-shaped stirring blades and further equipped with a system for heating by means of high-pressure steam and equipped with devices for vacuum BET method) and a particle size of less than 40 µm. 735 kg of dodecylbenzenesulfonate of triethanolamine in the form of an 80% solution in water, 1.5 kg of a condensate of 6 molecules of ethylene oxide with one molecule of noriylphenol, and 6 kg of methanol are added.
Det hele blandes i 10 minutter ved romtemperatur slik at man oppnår en homogen pasta. Deretter evakueres apparaturen til en gjen-værende trykk på ca. 65 mm Hg. Deretter gjennomføres en progressiv oppvarming opptil 65°C under fortsatt blanding. Den flyktige fase elimineres helt i løper av 4 timer. Deretter avkjøles det hele, og det tilsettes 11,25 kg av en polyvinylalkohol som har en molekylær hydrolysegrad på 88,2% og en viskositet på 14 cP. Det hele homogeniseres i 10 minutter. Man overfører deretter det hele til en med knivblad utstyrt oppmalingsapparatur, hvori det oppnås et pulver med en partikkelstørrelse på mindre enn 500^urn. The whole thing is mixed for 10 minutes at room temperature so that a homogeneous paste is obtained. The apparatus is then evacuated to a residual pressure of approx. 65 mm Hg. A progressive heating up to 65°C is then carried out with continued mixing. The volatile phase is completely eliminated within 4 hours. The whole is then cooled, and 11.25 kg of a polyvinyl alcohol which has a molecular degree of hydrolysis of 88.2% and a viscosity of 14 cP is added. The whole is homogenized for 10 minutes. The whole is then transferred to a grinding apparatus equipped with a knife blade, in which a powder with a particle size of less than 500 µm is obtained.
Man fremstiller et selvjevnende murverk ved å blande 100 vektdeler kunstig Portland-sement 400, 75 vektdeler Fontainebleau-sand, 4,5 vektdeler av det ovenfor fremstilte pulver, 3 vektdeler kalsiumformiat og 47,5 vektdeler vann. A self-leveling brickwork is produced by mixing 100 parts by weight of artificial Portland cement 400, 75 parts by weight of Fontainebleau sand, 4.5 parts by weight of the powder prepared above, 3 parts by weight of calcium formate and 47.5 parts by weight of water.
Det fremstilte murverk dekanterer ikke, og det er selvjevnende i et tidsrom på 45 minutter, bestemt på den ovenfor angitte måte. The manufactured masonry does not decant, and it is self-levelling in a period of 45 minutes, determined in the manner indicated above.
Fra murverket fremstilte prøvestykker oppviser en bøyefast-het på 100 kp/c■ m 2 og en trykkfasthet på 360 kp/cm 2. Test pieces made from the masonry exhibit a flexural strength of 100 kp/c■ m 2 and a compressive strength of 360 kp/cm 2.
Man måler murbrukets vedheftingsevne på den ovenfor angitte måte. Herved finnes en vedhefting i- tørr tilstand og 9 kp/cm 2 og en vedhefting i fuktig tilstand på .11 -kp/cm 2. The adhesiveness of the mortar is measured in the manner indicated above. This results in an adhesion in the dry state of 9 kp/cm 2 and an adhesion in a moist state of .11 -kp/cm 2.
Man fremstiller et beskyttelsesbelegg med en tykkelse på 1-2 mm, og man konstaterer etter 24 timer at det ikke skjer noen stoffdannelse på overflaten. Videre fastslår man at det ikke foreligger noen sprekkdannelse.'A protective coating is produced with a thickness of 1-2 mm, and it is established after 24 hours that no substance formation occurs on the surface. Furthermore, it is determined that there is no crack formation.'
Claims (7)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7338494A FR2249046B1 (en) | 1973-10-29 | 1973-10-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO743873L true NO743873L (en) | 1975-05-26 |
Family
ID=9127061
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO743873A NO743873L (en) | 1973-10-29 | 1974-10-28 |
Country Status (14)
| Country | Link |
|---|---|
| BE (1) | BE821558A (en) |
| BR (1) | BR7408941D0 (en) |
| CH (1) | CH592588A5 (en) |
| DE (1) | DE2450681B2 (en) |
| DK (1) | DK561774A (en) |
| ES (1) | ES431465A1 (en) |
| FR (1) | FR2249046B1 (en) |
| GB (1) | GB1484057A (en) |
| IE (1) | IE40711B1 (en) |
| IT (1) | IT1025294B (en) |
| LU (1) | LU71193A1 (en) |
| NL (1) | NL7413764A (en) |
| NO (1) | NO743873L (en) |
| SE (1) | SE417502B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2835423A1 (en) | 1978-08-12 | 1980-03-06 | Hoechst Ag | CONCRETE AND MORTAR ADDITIVES AND THEIR USE |
| US5565027A (en) * | 1996-04-02 | 1996-10-15 | Arco Chemical Technology, L.P. | Cement composition |
| AU5523000A (en) * | 1999-07-02 | 2001-01-22 | Densit A/S | Water-entrained cement-based materials |
| JP4884848B2 (en) * | 2006-06-01 | 2012-02-29 | 花王株式会社 | Rheology modifier |
| FR2928915B1 (en) * | 2008-03-21 | 2011-09-09 | Lafarge Platres | FATTY ALCOHOL ADJUVANT FOR CHAPELS |
| US8529693B2 (en) * | 2010-12-10 | 2013-09-10 | Troy Corporation | Adhesive strength enhancers for cementitious compositions |
| CN103635441A (en) * | 2011-06-30 | 2014-03-12 | 陶氏环球技术有限公司 | Hydraulic setting adhesive with improved open time |
| CN104837788B (en) * | 2012-12-14 | 2017-10-17 | 陶氏环球技术有限责任公司 | The additive of hydraulic pressure congealed mixt |
| US10487257B2 (en) * | 2016-07-20 | 2019-11-26 | Hexion Inc. | Materials and methods of use as additives for oilwell cementing |
| US11643588B2 (en) | 2017-12-04 | 2023-05-09 | Hexion Inc. | Multiple functional wellbore fluid additive |
-
1973
- 1973-10-29 FR FR7338494A patent/FR2249046B1/fr not_active Expired
-
1974
- 1974-10-21 NL NL7413764A patent/NL7413764A/en not_active Application Discontinuation
- 1974-10-25 IE IE2199/74A patent/IE40711B1/en unknown
- 1974-10-25 BR BR8941/74A patent/BR7408941D0/en unknown
- 1974-10-25 DE DE2450681A patent/DE2450681B2/en not_active Withdrawn
- 1974-10-28 GB GB46437/74A patent/GB1484057A/en not_active Expired
- 1974-10-28 NO NO743873A patent/NO743873L/no unknown
- 1974-10-28 CH CH1441674A patent/CH592588A5/xx not_active IP Right Cessation
- 1974-10-28 LU LU71193A patent/LU71193A1/xx unknown
- 1974-10-28 DK DK561774A patent/DK561774A/da unknown
- 1974-10-28 BE BE149947A patent/BE821558A/en unknown
- 1974-10-28 SE SE7413553A patent/SE417502B/en unknown
- 1974-10-29 IT IT28922/74A patent/IT1025294B/en active
- 1974-10-29 ES ES431465A patent/ES431465A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ES431465A1 (en) | 1976-11-01 |
| DK561774A (en) | 1975-06-23 |
| FR2249046B1 (en) | 1976-06-18 |
| SE7413553L (en) | 1975-04-30 |
| IE40711B1 (en) | 1979-08-01 |
| IE40711L (en) | 1975-04-29 |
| LU71193A1 (en) | 1975-06-24 |
| BE821558A (en) | 1975-04-28 |
| DE2450681B2 (en) | 1980-08-07 |
| IT1025294B (en) | 1978-08-10 |
| CH592588A5 (en) | 1977-10-31 |
| FR2249046A1 (en) | 1975-05-23 |
| GB1484057A (en) | 1977-08-24 |
| SE417502B (en) | 1981-03-23 |
| NL7413764A (en) | 1975-05-02 |
| BR7408941D0 (en) | 1975-08-26 |
| DE2450681A1 (en) | 1975-04-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2584830B2 (en) | Water-soluble cellulose ether derivatives and their use in architectural compositions | |
| FI104559B (en) | Dispersiojauhekoostumus | |
| AU571473B2 (en) | Lightweight joint compound | |
| EP2970007B1 (en) | Dry cement mortar with prolonged open time | |
| NO743873L (en) | ||
| JP4725742B2 (en) | Hydraulic composition | |
| KR102005252B1 (en) | Building composition comprising cellulose ether | |
| EP2297257B1 (en) | Coated building panels and articles containing calcium sulfate hemihydrate | |
| FR2943339A1 (en) | CEMENTITIOUS BINDER AND CEMENTITIOUS COMPOSITION FOR AUTONIVELANTE FLUID CAP, AND SELF-LEVELING FLUID CAP AS MADE | |
| CN101348348A (en) | High moisture retention concrete curing agent | |
| JPS5869758A (en) | Method and composition for preventing volume change of rapid curing flowable impermeable cement specific tissue | |
| CN102358693A (en) | Levelling mortar and ground construction process based on the same | |
| CN108473375A (en) | Cement-based binders composition | |
| JP2022504244A (en) | Formulations containing cellulose ethers and / or polysaccharides and fatty alcohols | |
| CN104016645A (en) | Preparation method of autoclaved aerated concrete block | |
| CN116997536A (en) | Silicon-containing emulsion powder for preparing cement-based tile adhesive dry-mix compositions | |
| US4444925A (en) | Floor composition | |
| JP3281548B2 (en) | Powder composition for waterproof adhesive used for concrete structures | |
| NO132833B (en) | ||
| JP2003020263A (en) | Self-levelling plaster | |
| JPH0312595B2 (en) | ||
| JPS643833B2 (en) | ||
| KR20060036865A (en) | Synthetic resin emulsion putty for freezing resistance | |
| JPH01160886A (en) | Deterioration-preventing and mending method for concrete structure or other cement material | |
| TWI814777B (en) | Long chain acrylic ester modified vinyl ester polymers |