NO323340B1

NO323340B1 - Product containing benztiazuron, metabenzthiazuron, tebutiuron, isoproturon and / or etiozine, processes for the preparation of such products and use of said product.

Info

Publication number: NO323340B1
Application number: NO19995492A
Authority: NO
Inventors: Martin Kugler; Peter Wachtler; Wilfried Paulus; Hermann Uhr; Lutz Heuer
Original assignee: Lanxess Deutschland Gmbh
Priority date: 1997-05-15
Filing date: 1999-11-10
Publication date: 2007-04-02
Also published as: AU736095B2; DK0982995T3; AU7761498A; DE59809348D1; CA2289724A1; BR9811464A; KR20010012078A; CN1283081A; EP0982995A1; DE19720342A1; WO1998051154A1; EP0982995B1; WO1998051154A8; NO995492L; ES2201500T3; JP2001524976A; NO995492D0; MXPA99010092A

Description

Foreliggende søknad vedrører den nye anvendelsen av de kjente virkestoffer benztiazuron, metabenztiazuron, tebutiuron, isoproturon og etiozin samt deres blandinger og blandinger av disse virkestoffene med ytterligere kjente virkestoffer for å bekjempe algeveksten på interiør- og eksteriørdispersjonsmalinger, trebeskyttelsesmalinger og -lasurer. Foreliggende søknad vedrører videre fremgangsmåte for fremstilling av interiør- og eksteriørdispersjonsmalinger, trebeskyttelsesmalinger og -lasurer inneholdende nevnte virkestoffer, samt interiør- og eksteriørdispersjonsmalinger, trebeskyttelsesmalinger og -lasurer inneholdende nevnte virkestoffer. The present application relates to the new use of the known active substances benzthiazuron, metabenzthiazuron, tebuthiuron, isoproturon and ethiosin as well as their mixtures and mixtures of these active substances with further known active substances to combat algae growth on interior and exterior dispersion paints, wood protection paints and glazes. The present application also relates to a method for the production of interior and exterior dispersion paints, wood protection paints and glazes containing said active ingredients, as well as interior and exterior dispersion paints, wood protection paints and glazes containing said active ingredients.

Benztiazuron Metabenztiazuron Benzthiazuron Metabenzthiazuron

Tebutiuron Isoproturon Tebutiuron Isoproturon

Etiozin Ethiozin

Det er kjent at man kan bekjempe ugress selektivt med benztiazuron og metabenztiazuron (se f. eks. BE-PS 687 019, US 2 756 135, GB 1 085 430). It is known that weeds can be selectively controlled with benzthiazuron and metabenzthiazuron (see e.g. BE-PS 687 019, US 2 756 135, GB 1 085 430).

Det er også kjent at man kan bekjempe ugress med tebutiuron (se DE 1 816 568) og etiozin (sammenlign US 3 671 523). It is also known that weeds can be controlled with tebutiuron (see DE 1 816 568) and ethiosin (compare US 3 671 523).

Likeledes blir isoproturon anvendt for å bekjempe uønsket ugressvekst (se f. eks. Likewise, isoproturon is used to combat unwanted weed growth (see e.g.

DE 2 039 041). DE 2 039 041).

Det er fra WO9706676 kjent å anvende dehydroabietylamin som formuleringshjelpemiddel i algicide sammensetninger for å beskytte tekniske materialer ovenfor bla. alger. It is known from WO9706676 to use dehydroabiethylamine as a formulation aid in algicidal compositions to protect technical materials above, among other things. algae.

Videre er det fra DE4433856 kjent å anvende isoproturon for beskyttelse av tekniske materialer mot vekst av akvatiske organismer. Furthermore, it is known from DE4433856 to use isoproturon for the protection of technical materials against the growth of aquatic organisms.

Ved analyse av miljøfordrageligheten til isoproturon kjenner man dessuten virkningen overfor enkelte ferskvannsalger (se M. Manthey et al., Sei. Total Environ. 1993, s. 453-459, F. A. Anton et al., Sei. Total Environ. 1993, s. 845-851, J. I. N. Kumar, J. Indian Bot. Soc. 70,277 (1991)). When analyzing the environmental tolerance of isoproturon, one also knows the effect on certain freshwater algae (see M. Manthey et al., Sei. Total Environ. 1993, pp. 453-459, F. A. Anton et al., Sei. Total Environ. 1993, pp. 845-851, J. I. N. Kumar, J. Indian Bot. Soc. 70, 277 (1991)).

Nå ble det uventet funnet ut at virkestoffene benztiazuron, metabenztiazuron, tebutiuron, isoproturon og etiozin også egner seg til å bekjempe algeveksten på interiør-og eksteriørdispersjonsmalinger, trebeskyttelsesmalinger og -lasurer. Fremfor alt er dette også uventet, fordi også de i malingssystemer relevante blågrønne algene lar seg bekjempe med de nevnte virkestoffene. Now it was unexpectedly found that the active substances benztiazuron, metabenztiazuron, tebuthiuron, isoproturon and ethiosin are also suitable for combating algae growth on interior and exterior dispersion paints, wood protection paints and varnishes. Above all, this is also unexpected, because the blue-green algae relevant in paint systems can also be combated with the aforementioned active substances.

Dessuten er det funnet at de nevnte virkestoffene ikke blir vannet ut fra mediene som skal beskyttes (dispersjonsmaling osv.) og følgelig fører slik til en god langtidsvirkning. Virkestoffene er langtidsstabile både i kommersielle malinger og også i den tørkede, påførte malingen. In addition, it has been found that the mentioned active substances are not washed out of the media to be protected (dispersion paint, etc.) and consequently lead to a good long-term effect. The active ingredients are long-term stable both in commercial paints and also in the dried, applied paint.

På grunn av den gode algicide virkningen virker forbindelse ifølge oppfinnelsen også mot lav. I kombinasjon med fungicider vises herved en synergistisk økning av effektiviteten. Due to the good algicidal effect, the compound according to the invention also works against lichens. In combination with fungicides, a synergistic increase in effectiveness is shown.

Dessuten ble det funnet ut at man kan forbedre virkningen av benztiazuron, metabenztiazuron, tebutiuron, isoproturon og etiozin betydelig, delvis til og med synergistisk, når man tilsetter ytterligere herbicider, algicider og/eller materialbeskyttelsesmidler som tilsetningspartner. Moreover, it was found that the effect of benzthiazuron, metabenzthiazuron, tebuthiuron, isoproturon and ethiosin can be significantly improved, partially even synergistically, when additional herbicides, algicides and/or material protection agents are added as addition partners.

Algene som skal bekjempes er fortrinnsvis prokaryotiske alger (cyanofytter/blågrønne alger) som f. eks. representanter for underklassen coccogoneae og underklassen hormogoneae. The algae to be combated are preferably prokaryotic algae (cyanophytes/blue-green algae), such as e.g. representatives of the subclass coccogoneae and the subclass hormogoneae.

Eksempelvis - men ikke innskrenkende - skal nevnes fra ordenen chroococcales arter av slektene synechococcus, chroococcus, gloeocapsa, aphanocapsa, aphanothece, microcystis og merismopedta, fra ordnene chamaesiphonales og pleurocapsales arter av slektene chamaesiphon og dermatocarpa, fra ordenen oscillatoriales arter av slektene phormidium, schizothrix, spirulina, ptectonema og lyngbya, fra ordenen nostocales arter av slektene nostoc, rivularia, tolypothrix, scytonema, anabaenopsis, catothrix og aulosira, fra ordenen stigonematatles arter av slektene stigonema, fischerella, hapalosiphon og mastigocladus. For example - but not limiting - must be mentioned from the order chroococcales species of the genera synechococcus, chroococcus, gloeocapsa, aphanocapsa, aphanothece, microcystis and merismopedta, from the orders chamaesiphonales and pleurocapsales species of the genera chamaesiphon and dermatocarpa, from the order oscillatoriales species of the genera phormidium, schizothrix, spirulina, ptectonema and lyngbya, from the order nostocales species of the genera nostoc, rivularia, tolypothrix, scytonema, anabaenopsis, catothrix and aulosira, from the order stigonematatles species of the genera stigonema, fischerella, hapalosiphon and mastigocladus.

Videre viser forbindelsene også en god virkning mot eukaryotiske representanter fra gruppen heterokontophyta, rhodophyta, chlorophyta, euglenophyta, cryptophyta, dinophyta og haptophyta. Eksempelvis - uten å være innskrenkende - skal nevnes fra klassen xanthophyceae arter av slektene tribonema og vaucheria, fra klassen chrysophyceae arter av slektene chrysocapsa, rhizochrysis, cfhrysosphaera, phaeothamnion og thallochrysis, fra klassen phaeophyceae (brunalger) arter av slektene ectocarpus, pylaiella, cutleria, zanardinia, dictyota, padina, dictyopteris, laminaria, macrocystis, lessonia, nerocystis, chorda, alaria, fucus, ascophyllum, himanthalia, sargassum, cystoseira, halidrys, pelvetia, coccophora og durvilla, fra klassen rhodophyceae (rødalger) arter av slektene porphyridum, bangia, porphyra, corallina, lithothamnia, lithophyllum, rhodymania, delesseria, grinnellia, platysiphonia, polysiphonia, ceramium, plumaria, fra klassen chlorophyceae (grønnalger) arter av slektene chlorococcum, chlorella, spongiochloris, monostroma, ulva, enteromorpha, ulothrix, trentepohlia, apatococcus, desmococcus, cladophora, siphonocladus, valorda, caulerpa, bryopsis, acetabularia, halimeda og tuna. Furthermore, the compounds also show a good effect against eukaryotic representatives from the group heterokontophyta, rhodophyta, chlorophyta, euglenophyta, cryptophyta, dinophyta and haptophyta. For example - without being limiting - must be mentioned from the class xanthophyceae species of the genera tribonema and vaucheria, from the class chrysophyceae species of the genera chrysocapsa, rhizochrysis, cfhrysosphaera, phaeothamnion and thallochrysis, from the class phaeophyceae (brown algae) species of the genera ectocarpus, pylaiella, cutleria, zanardinia, dictyota, padina, dictyopteris, laminaria, macrocystis, lessonia, nerocystis, chorda, alaria, fucus, ascophyllum, himanthalia, sargassum, cystoseira, halidrys, pelvetia, coccophora and durvilla, from the class rhodophyceae (red algae) species of the genera porphyridum, bangia , porphyra, corallina, lithothamnia, lithophyllum, rhodymania, delesseria, grinnellia, platysiphonia, polysiphonia, ceramium, plumaria, from the class chlorophyceae (green algae) species of the genera chlorococcum, chlorella, spongiochloris, monostroma, ulva, enteromorpha, ulothrix, trentepohlia, apatococcus, desmococcus, cladophora, siphonocladus, valorda, caulerpa, bryopsis, acetabularia, halime then and tuna.

Det som skal utstyres med algicide substanser er fortrinnsvis interiør- og eksteriørdispersjonsmalinger, trebeskyttelsesmalinger og -lasurer. What should be equipped with algicidal substances are preferably interior and exterior dispersion paints, wood protection paints and glazes.

Under betegnelsen dispersjonsmaling forstås vannholdige, alkalisk innstilte malinger på basis av polymerdispersjoner som anvendes som bindemiddel. Disse for fremstilling av dispersjonsmaling anvendte polymerdispersjonene inneholder som eksempel og fortrinnsvis polyakrylater, styrolakrylater, polyvinylacetat, polyvinylpropionat og andre polymerer. The term dispersion paint refers to aqueous, alkaline-set paints based on polymer dispersions that are used as binders. These polymer dispersions used for the production of dispersion paint contain, for example and preferably, polyacrylates, styrene acrylates, polyvinyl acetate, polyvinyl propionate and other polymers.

Benztiazuron, metabenztiazuron, tebutiuron, isoproturon og/eller etiozin blir blandet direkte eller i form av formuleringer henholdsvis blandinger inn i ovennevnte dispersjonsmalinger eller i deres utgangsprodukter. Benzthiazuron, metabenzthiazuron, tebuthiuron, isoproturon and/or ethiosin are mixed directly or in the form of formulations or mixtures into the above-mentioned dispersion paints or into their starting products.

For deres innarbeiding i interiør- og eksteriørdispersjonsmalinger, trebeskyttelsesmalinger eller -lasurer foreligger benztiazuron, metabenztiazuron, tebutiuron, isoproturon og etiozin fortrinnsvis i form av vanlige formuleringer, som løsninger, emulsjoner, suspensjoner, pulvere, skum, pastaer, granulater, aerosoler og finkapslinger i polymerer stoffer. For their incorporation into interior and exterior dispersion paints, wood protection paints or glazes, benzthiazuron, metabenzthiazuron, tebuthiuron, isoproturon and ethiosin are preferably available in the form of common formulations, such as solutions, emulsions, suspensions, powders, foams, pastes, granules, aerosols and fine encapsulations in polymers substances.

Disse formuleringene hhv. midlene blir fremstilt på kjent måte, f. eks. gjennom blanding av virkestoffene med drøyemidler, altså flytende løsningsmidler, kondenserte gasser som står under trykk og/eller faste bærere, eventuelt ved anvendelse av overflateaktive midler, altså emulgeringsmidler og/eller dispergeirngsmidler og/eller skumdannende midler. I tilfelle av anvendelse av vann som drøyemiddel kan for eksempel også organiske løsningsmidler anvendes som hjelpeløsningsmidler. Som flytende løsningsmidler anvendes stort sett: aromater, som xylol, toluol, alkylnaftalin, klorerte aromater eller klorerte alifatiske kullvannstoffer, som klorbenzol, kloretylen eller metylenklorid, alifatiske kullvannstoffer, som sykloheksan eller parafin, f. eks. jordoljefraksjoner, alkoholer som butanol eller glykol, samt deres etere og estere, ketoner, som aceton, metyletylketon, metylisobutylketon eller sykloheksanon, sterke polare løsningsmidler, som dimetylformamid eller dimetylsulfoksid, likesom vann; med betegnelsen kondenserte gassformige drøyemidler eller bærerstoffer betegnes slike væsker som er gassformige ved normaltemperatur og under normaltrykk, f. eks. aerosol-drivgasser som halogenhydrokarboner, slik som butan, propan, nitrogen og karbondioksid; som faste bærerstoffer nevnes f. eks. naturlig steinmel som kaolin, leirjord, talkum, kritt, kvarts, attapulgitt, montmorillonitt eller diatomeenjord og syntetisk steinmel, som høydispers kiselsyre, aluminiumoksid og silikater; som faste bærerstoffer for granulater nevnes f. eks. brutt og fraksjonert naturlig stein som kalsitt, marmor, bims, sepiolitt, dolomitt, likesom syntetiske granulater fra uorganiske og organiske melsorter, likesom granulater fra organisk materiale som sagmugg, kokosnøttskall, maiskolber og tabakstilk; som emulgerings- og/eller skumdanningsmiddel nevnes f. eks. ikke-ionogene og anioniske emulgatorer som polyoksyetylen-fettsyreester, polyoksyetylen-fettalkohol-eter, f. eks. alkylarylpolyglykoleter, alkylsulfonater, afkylsulfater, arylsulfonater, likesom proteinhydrolysater; som dispergeirngsmiddel nevnes som eksempel ligninsulfittavlut og metylcellulose. These formulations respectively the means are produced in a known manner, e.g. through mixing the active substances with emulsifiers, i.e. liquid solvents, condensed gases under pressure and/or solid carriers, possibly by using surface-active agents, i.e. emulsifiers and/or dispersants and/or foam-forming agents. In the case of using water as a suspending agent, for example, organic solvents can also be used as auxiliary solvents. As liquid solvents are generally used: aromatics, such as xylol, toluene, alkylnaphthalene, chlorinated aromatics or chlorinated aliphatic hydrocarbons, such as chlorobenzene, chloroethylene or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffin, e.g. petroleum fractions, alcohols such as butanol or glycol, as well as their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strong polar solvents, such as dimethylformamide or dimethyl sulfoxide, such as water; the term condensed gaseous retarding agents or carrier substances refers to such liquids which are gaseous at normal temperature and under normal pressure, e.g. aerosol propellants such as halogenated hydrocarbons such as butane, propane, nitrogen and carbon dioxide; as solid carrier substances are mentioned, e.g. natural rock flour such as kaolin, clay, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock flour, such as highly dispersed silica, alumina and silicates; as solid carriers for granules are mentioned, e.g. broken and fractionated natural stone such as calcite, marble, pumice, sepiolite, dolomite, as well as synthetic granules from inorganic and organic flours, as well as granules from organic material such as sawdust, coconut shells, corncobs and tobacco stalks; as an emulsifying and/or foaming agent are mentioned, e.g. non-ionic and anionic emulsifiers such as polyoxyethylene fatty acid ester, polyoxyethylene fatty alcohol ether, e.g. alkyl aryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates, as well as protein hydrolysates; Examples of lignin sulphite leachate and methyl cellulose are mentioned as dispersants.

I formuleringene kan det også anvendes vedheftningsmidler som karboksymetylcellulose, naturlige og syntetiske pulveraktige, kornede eller lateksformede polymerer som gummi arabicum, polyvinylalkohol, polyvinylacetat, videre naturlige fosfolipider, som kefaliner og lecitiner, og syntetiske fosfolipider. Ytterligere additiver kan være mineraliske og vegetabilske oljer. In the formulations, adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex-shaped polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate, further natural phospholipids, such as cephalins and lecithins, and synthetic phospholipids can also be used. Additional additives can be mineral and vegetable oils.

Det kan anvendes fargestoffer som uorganiske pigmenter, f. eks. jernoksid, titanoksid, ferrocyanblå, og organiske fargestoffer som alizarin-, azo- og Dyes such as inorganic pigments can be used, e.g. iron oxide, titanium oxide, ferrocyan blue, and organic dyes such as alizarin, azo and

metallftalocyaninfargestoffer og sporelementer som salter fra jern, mangan, bor, kobber, kobolt, molybden og sink. metal phthalocyanine dyes and trace elements such as salts from iron, manganese, boron, copper, cobalt, molybdenum and zinc.

En ytterligere gjenstand for foreliggende søknad er synergistisk virkende blandinger av benzthiazuron, metabenzthiazuron, tebuthiuron, isoproturon og/eller ethiozin med minst ett fungicid og eventuelt ytterligere virkestoffer. A further subject of the present application are synergistically acting mixtures of benzthiazuron, metabenzthiazuron, tebuthiuron, isoproturon and/or ethiozin with at least one fungicide and possibly further active substances.

Virksomheten mot alger samt aktivitetsspekteret for virkestoffene ifølge oppfinnelsen hhv. herav fremstilte formuleringer økes også når ytterligere algicid-virksomme forbindelser, baktericider, molluscicider, insekticider og/eller grohemmende midler tilsettes. Disse blandingene har et bredere aktivitetsspekter enn de enkelte virkestoffene alene. The activity against algae as well as the spectrum of activity for the active substances according to the invention or formulations produced from this are also increased when additional algicide-active compounds, bactericides, molluscicides, insecticides and/or anti-growth agents are added. These mixtures have a wider spectrum of activity than the individual active substances alone.

Dessuten oppnår man også i mange tilfeller synergistiske effekter, dette betyr at virksomheten av blandingen er større enn virksomheten av den individuelle komponenten. Spesielt fordelaktige tilsetningspartnere er f. eks. følgende forbindelser: Moreover, synergistic effects are also achieved in many cases, this means that the activity of the mixture is greater than the activity of the individual component. Particularly advantageous addition partners are e.g. the following compounds:

Triazoler som: Triazoles such as:

Azaconazol, azocyklotin, bitertanol, bromuconazol, cyproconazol, diclobutrazol, difenoconazol, diniconazol, epoksyconazol, etaconazol, fenbuconazol, fenklorazol, fenetanil, fluquinconazol, flusilazol, fiutriafol, furconazol, heksaconazol, imibenconazol, ipconazol, isozofos, myclobutanil, metconazol, paclobutrazol, penconazol, propioconazol, (+)-cis-1 -(4-klorfenyl)-2-(l H-l ,2,4-tirazol-l -yl)-cykloheptanol,2-(l-tert-butyl)-l-(2-klorfenyl)-3-(l,2,4-triazol-l-yl)-propan-2-ol, tebuconazol, tetraconazol, triadimefon, triadimenol, triapentenol, triflumizol, triticonazol, uniconazol, likesom deres metallsalter og syreaddukter. Azaconazole, azocyclotin, bitertanol, bromuconazole, cyproconazole, diclobutrazol, difenoconazole, diniconazole, epoxyconazole, etaconazole, fenbuconazole, fenchlorazole, fenetanil, fluquinconazole, flusilazole, fiutriafol, furconazole, hexaconazole, imibenconazole, ipconazole, isozofos, myclobutanil, metconazole, paclobutrazol, penconazole, propioconazole, (+)-cis-1-(4-chlorophenyl)-2-(1H-1,2,4-tyrazol-1-yl)-cycloheptanol, 2-(1-tert-butyl)-1-(2- chlorophenyl)-3-(l,2,4-triazol-l-yl)-propan-2-ol, tebuconazole, tetraconazole, triadimefon, triadimenol, triapentenol, triflumizole, triticonazole, uniconazole, as well as their metal salts and acid adducts.

Imidazoler som: Imidazoles such as:

Clotrimazol, bifonazol, climbazol, econazol, fenapamil, imazalil, isoconazol, ketoconazol, lombazol, miconazol, pefurazoat, prokloraz, triflumizol, tiazolcar, 1-imidazolyl-l-(4'-klorofenoksy)-3,3-dimetylbutan-2-on, likesom deres metallsalter og syreaddukter. Clotrimazole, bifonazole, climbazole, econazole, fenapamil, imazalil, isoconazole, ketoconazole, lombazole, miconazole, pefurazoate, prochloraz, triflumizole, thiazolcar, 1-imidazolyl-l-(4'-chlorophenoxy)-3,3-dimethylbutan-2-one , as well as their metal salts and acid adducts.

Pyridiner og pyrimidiner som: Pyridines and pyrimidines such as:

Ancymidol, butiobat, fenarimol, nuarimol, triamirol; Ancymidol, butiobate, fenarimol, nuarimol, triamirol;

Succinat-dehydrogenaseinhibitorer som: Succinate dehydrogenase inhibitors such as:

Benodanil, karboksim, karboksimsulfoksid, cyklafluramid, fenfuram, flutanil, furkarbanil, furmecykloks, mebenil, mepronil, metfuroksam, metsulfovaks, pyrokarbolid, oksykarboksin, shirlan, seedvax. Benodanil, carboxim, carboxim sulfoxide, cyclafluramide, fenfuram, flutanil, furcarbanil, furmecyclox, mebenil, mepronil, metfuroxam, metsulfovax, pyrocarbolide, oxycarboxin, shirlan, seedvax.

Naftalin-derivater som: Naphthalene derivatives such as:

Terbinafin, naftifin, butenafin, 3-kloro-7-(2-aza-2,7,7-trimetyl-okt-3-en-5-in). Terbinafine, naftifine, butenafine, 3-chloro-7-(2-aza-2,7,7-trimethyl-oct-3-en-5-yne).

Sulfenamider som: Sulphenamides such as:

Diklorfluanid, tolylfluanid, folpet, fluorfolpet, captan, captofol. Dichlorfluanid, tolylfluanid, folpet, fluorofolpet, captan, captofol.

Benzimidazoler som: Benzimidazoles such as:

Karbendazim, benomyl, fuberidazol, tiabendazol eller deres salter. Carbendazim, benomyl, fuberidazole, thiabendazole or their salts.

Morfolinderivater som: Morpholine derivatives such as:

Aldimorf, dimetomorf, dodemorf, falimorf, fenpropidin, fenpropimorf, tridemorf, trimorfamid og deres arylsulfonsyresalter, som f. eks. p-toluensulfonsyre og p-dødecylfenylsulfonsyre. Aldimorph, dimethomorph, dodemorph, palimorph, fenpropidine, fenpropimorph, tridemorph, trimorfamide and their aryl sulfonic acid salts, such as e.g. p-toluenesulfonic acid and p-dodecylphenylsulfonic acid.

Benztiazoler som: Benzthiazoles such as:

2-merkaptobenzotiazol. 2-Mercaptobenzothiazole.

Benztiofendioksider som: Benzthiophene dioxides such as:

Benzo[b]tiofen-S,S-dioksid-karbonsyrecykloheksylamid. Benzo[b]thiophene-S,S-dioxide-carbonic acid cyclohexylamide.

Benzamider som: Benzamides such as:

2,6-dikloro-N-(4-trifluorometylbenzyl)-benzamid, tecloftalam. 2,6-dichloro-N-(4-trifluoromethylbenzyl)-benzamide, tecloftalam.

Borforbindelser som: Boron compounds such as:

Borsyre, borsyreester, boraks. Boric acid, boric acid ester, borax.

Formaldehyd og formaldehydavspaltende forbindelser som: Benzylalkoholmono-(poly)-hemiformal, n-butanolhemiformal, dazomet, etylenglykol-hemiformal, heksahydro-S-triazin, heksametylentetramtn, N-hydroksyrnetyl-N'-metyltio-urinstoff, N-metylolkloracetamid, oksazolidin, paraformaldehyd, taurolin, tetrahydro-1,3-oksazin, N-(2-hydroksypropyl)amin-metanol. Formaldehyde and formaldehyde-releasing compounds such as: Benzyl alcohol mono-(poly)-hemiformal, n-butanol hemiformal, dazomet, ethylene glycol hemiformal, hexahydro-S-triazine, hexamethylenetetramine, N-hydroxymethyl-N'-methylthio-urea, N-methylolchloroacetamide, oxazolidine, paraformaldehyde , tauroline, tetrahydro-1,3-oxazine, N-(2-hydroxypropyl)amine-methanol.

Isotiazoliner som: Isothiazolines such as:

N-metylisotiazolin-3-on, 5-kIor-N-metylisotiazolin-3-on, 4,5-diklor-N-oktyI-isotiazoIin-3-on, 5-klor-_N-oktylisotiazollinon, N-oktyl-isotiazolin-3-on, 4,5-tri-metylen-isotiazolinon, 4,5-benzisotiazolinon. N-methylisothiazolin-3-one, 5-chloro-N-methylisothiazolin-3-one, 4,5-dichloro-N-octyl-isothiazolin-3-one, 5-chloro-_N-octylisothiazolinone, N-octyl-isothiazolin- 3-one, 4,5-tri-methylene-isothiazolinone, 4,5-benzisothiazolinone.

Aldehyder som: Aldehydes such as:

Kanelaldehyd, formaldehyd, glutardialdehyd, B-bromkanelaldehyd. Cinnamaldehyde, formaldehyde, glutardialdehyde, B-bromocinnamaldehyde.

Tiocyanater som: Thiocyanates such as:

Tiocyanatometyltiobenzotiazol, metylenbistiocyanat. Thiocyanatomethylthiobenzothiazole, methylene bisthiocyanate.

Kvartare ammoniumforbindelser som: Quaternary ammonium compounds such as:

Benzalkoniumklorid, benzyldimetyltetradecylammoniumklorid, benzyldimetyl-dodecylammoniumklorid, diklorberizyl-dimetyl-alkyl-ammoniumklorid, didecyl-dimetylammoniumklorid, dioktyl-dimetyl-ammoniumkloird,N-heksadecyl-tri-metyl-ammoniumklorid, 1 -heksadecyl-pyridiniumklorid. Benzalkonium chloride, benzyldimethyltetradecylammonium chloride, benzyldimethyl-dodecylammonium chloride, dichlorberysyl-dimethyl-alkyl-ammonium chloride, didecyl-dimethylammonium chloride, dioctyl-dimethyl-ammonium chloride, N-hexadecyl-tri-methyl-ammonium chloride, 1-hexadecyl-pyridinium chloride.

Jodderivater som: Iodine derivatives such as:

Dijodmetyl-p-tolyllsulfon, 3-jod-2-propinyl-alkohol, 4-klorfenyl-3-jodpropargylformal, 3-brom-2,3-dijod-2-propenyletylkarbamat, 2,3,3-trijodallylalkohol,3-brom-2,3-dijod-2-propenylalkohol, 3-jod-2-propinyl-n-butylkarbamat, 3-jod-2-propinyl-n-heksylkarkbamat, 3-jod-2-propinyl-cykloheksylkarbamat,3-jod-2-propinyl-fenylkakrbamat. Diiodomethyl-p-tolylsulfone, 3-iodo-2-propynyl alcohol, 4-chlorophenyl-3-iodopropargylformal, 3-bromo-2,3-diiodo-2-propenylethyl carbamate, 2,3,3-triiodallyl alcohol, 3-bromo- 2,3-diiodo-2-propenyl alcohol, 3-iodo-2-propynyl-n-butylcarbamate, 3-iodo-2-propynyl-n-hexylcarbamate, 3-iodo-2-propynyl-cyclohexylcarbamate, 3-iodo-2- propynyl-phenylcacrabamate.

Fenoler som: Phenols such as:

Tribromfenol, tetraklorfenol, 3-metyl-4-klorfenol, 3,5-dimetyl-4-klor-fenol, fenoksyetanol, diklorfen, 2-benzyl-4-klorfenol, 5-klor-2-(2,4-di-klorfenoksy)-fenol, heksaklorofen, p-hydroksybenzosyreester, o-fenylfenol, m-fenylfenol, p-fenylfenol og deres alkali- og jordalkalimetallsalter. Tribromophenol, tetrachlorophenol, 3-methyl-4-chlorophenol, 3,5-dimethyl-4-chlorophenol, phenoxyethanol, dichlorophen, 2-benzyl-4-chlorophenol, 5-chloro-2-(2,4-di-chlorophenoxy) )-phenol, hexachlorophene, p-hydroxybenzoic acid ester, o-phenylphenol, m-phenylphenol, p-phenylphenol and their alkali and alkaline earth metal salts.

Mikrobizider med aktivert halogengruppe som: Microbicides with activated halogen group such as:

Bronopol, bronidoks, 2-brom-2-nitro-l,3-propandiol, 2-brom-4'-hydroksy-acetofenon, 1 -brom-S-kloMAS.S-tetrametyl^-imidazoldinon, B-brom-8-nitrostyrol, kloracetamid, kloramin T, l,3-dibrom-4,4,5,5-tetrametyl-2-imidazoldinon, di-kloramin T, 3,4-diklor-(3H)-1,2-ditiol-3-on, 2,2-dibrom-3-nitirl-propionamid, 1 „2-dibrom-2,4-dicyanobutan, halan, halazon, mucoklorsyre, fenyl-(2-klor-cyan-vinyl)sulfon, fenyl-(l,2-diklor-2-cyanvinyl)sulfon, triklorisocyanursyre. Bronopol, bronidox, 2-bromo-2-nitro-1,3-propanediol, 2-bromo-4'-hydroxy-acetophenone, 1 -bromo-S-cloMAS.S-tetramethyl^-imidazoldinone, B-bromo-8- nitrostyrene, chloracetamide, chloramine T, 1,3-dibromo-4,4,5,5-tetramethyl-2-imidazoldinone, di-chloramine T, 3,4-dichloro-(3H)-1,2-dithiol-3- one, 2,2-dibromo-3-nitrile-propionamide, 1 „ 2-dibromo-2,4-dicyanobutane, halan, halazone, mucochloric acid, phenyl-(2-chloro-cyano-vinyl) sulfone, phenyl-(l, 2-dichloro-2-cyanovinyl) sulfone, trichloroisocyanuric acid.

Pyridiner som: Pyridines such as:

1- hydroksy-2-pyridintion (og deres Na-, Fe-, Mn-, Zn-salter), tetraklor-4-metylsulfonylpyridin, pyrimetanol, mepanipyrim, dipyrition, 1 -hydroksy-4-metyl-6-(2)4,4-trimetylfentyl)-2(lH)-pyridin. 1-hydroxy-2-pyridinethione (and their Na, Fe, Mn, Zn salts), tetrachloro-4-methylsulfonylpyridine, pyrimethanol, mepanipyrim, dipyrithion, 1-hydroxy-4-methyl-6-(2)4 ,4-trimethylphentyl)-2(1H)-pyridine.

Metoksyakrylater eller lignende som: Metyl-(£)-metoksimino[alfa-(o-tolyloksy)-o-tolyl]acetat, (E)-2-metoksyimino-N-metyl-2-(2-fenoksyfenyl)acetamid, (E)-2-{2-[6-(2-cyanofenoksy)pyrimidin-4-yloksy]fenyl}-3-metoksyakrylat, Methoxyacrylates or the like such as: Methyl-(£)-methoxyimino[alpha-(o-tolyloxy)-o-tolyl]acetate, (E)-2-methoxyimino-N-methyl-2-(2-phenoxyphenyl)acetamide, (E )-2-{2-[6-(2-cyanophenoxy)pyrimidin-4-yloxy]phenyl}-3-methoxyacrylate,

0-metyl-2-[([3-metoksimino-2-butyl)imino]oksy)o-tolyl]-2-metoksiminoacetimidat, O-methyl-2-[([3-methoxyimino-2-butyl)imino]oxy)o-tolyl]-2-methoxyiminoacetimidate,

2- [[[[l-(2,5-dimetyIfenyl)etyliden]amino]oksy]metyl]-alfa-(metoksimino)-N-metyl-benzenacetamid, 2- [[[[l-(2,5-dimethylphenyl)ethylidene]amino]oxy]methyl]-alpha-(methoxyimino)-N-methyl-benzeneacetamide,

alfa-(metoksyimino)-N-metyl-2-[[[[l-[3-(trifluorometyl)fenyl]etyliden]amino]oksy]metyl]-benzenacetamid, alfa-(metoksyimino)-2-[[t[l-[3-(trifluorometyl)fenyl]etyUden]amino]oksy]metyl]-benzeneddiksyre-metylester, alpha-(Methoxyimino)-N-methyl-2-[[[[l-[3-(trifluoromethyl)phenyl]ethylidene]amino]oxy]methyl]-benzeneacetamide, alpha-(methoxyimino)-2-[[t[l -[3-(trifluoromethyl)phenyl]ethylidene]amino]oxy]methyl]benzeneacetic acid methyl ester,

alfa-(metoksymetyIen)-2-[[[[l-[3-(trifluorometyl)fenyl]etyliden]amino]oksy]metyl]-benzeneddiksyre-metylester, alpha-(Methoxymethylene)-2-[[[[l-[3-(trifluoromethyl)phenyl]ethylidene]amino]oxy]methyl]benzeneacetic acid methyl ester,

2-[[[5-kloro-3-(trilfuonnetyl)-2-pyridm^^ benzenacetamid, 2-[[[5-chloro-3-(trifluoromethyl)-2-pyridin^^ benzeneacetamide,

2-[[[cyklopropyl[(4-etoksyfenyl)imino]metyl]tio]metyl]-alfa-(metoksyim benzeneddiksyre-metylester, 2-[[[cyclopropyl[(4-ethoxyphenyl)imino]methyl]thio]methyl]-alpha-(methoxy benzeneacetic acid methyl ester,

alfa-(metoksyimino)-N-metyl-2-(4-metyl-5-fenyl-2,7-dioksa-3,6-diazaokta-3,5 yl)-benzenacetamid(alpha-(Methoxyimino)-N-methyl-2-(4-methyl-5-phenyl-2,7-dioxa-3,6-diazaocta-3,5 yl)-benzeneacetamide (

alfa-(metoksymetylen)-2-(4-metyl-5-fenyl-2,7-dtø^ benzeneddiksyre-metylester, alpha-(Methoxymethylene)-2-(4-methyl-5-phenyl-2,7-dto^benzeneacetic acid methyl ester,

alfa-(metoksyimino)-N-metyl-2-[[[l-[3-(tirfluorometyl)fenyl]-etoksy]imino]metyl]-benzenacetamid, alpha-(Methoxyimino)-N-methyl-2-[[[l-[3-(trifluoromethyl)phenyl]-ethoxy]imino]methyl]-benzeneacetamide,

2-[[(3,5-dikloro-2-pyridinyl)oksy]metyl]-alfa-(metoksyimino)-N-metyl-benzenacetamid, 2-[[(3,5-dichloro-2-pyridinyl)oxy]methyl]-alpha-(methoxyimino)-N-methyl-benzeneacetamide,

2-[4,5-dimetyl-9-(4-morfolinyl)-2,7-dioksa-3,6-diazanona-3,5-dien-l-yl]-alfa-(metoksymetylen)-benzeneddiksyre-metylester. 2-[4,5-Dimethyl-9-(4-morpholinyl)-2,7-dioxa-3,6-diazanona-3,5-dien-1-yl]-alpha-(methoxymethylene)-benzeneacetic acid methyl ester.

Metallsåper som: Metal soaps such as:

Tinn-, kobber-, sinknaftenat, -oktoat, 2-etylheksanoat, -oleat, -fosfat, -benzoat. Tin, copper, zinc naphthenate, -octoate, 2-ethyl hexanoate, -oleate, -phosphate, -benzoate.

Metallsalter som: Metal salts such as:

Kobberhydroksykarbonat, natriumdikromat, kaliumdikromat, kaliumkromat, kobbersulfat, kobberklorid, kobberborat, sinkfluorsilikat, kobberfluorsilikat. Copper hydroxycarbonate, sodium dichromate, potassium dichromate, potassium chromate, copper sulfate, copper chloride, copper borate, zinc fluorosilicate, copper fluorosilicate.

Oksider som: Oxides such as:

Tributyltinnoksid, Cu20, CuO, ZnO. Tributyltin oxide, Cu20, CuO, ZnO.

Ditiokarbamater som: Dithiocarbamates such as:

Cufraneb, ferban, kalium-N-hydroksymetyl-N'-metyl-ditiobarbamat, Na- eller K-dimetylditiokarbamat, macozeb, maneb, metam, metiram, tiram, zineb, ziram. Cufraneb, ferban, potassium-N-hydroxymethyl-N'-methyl-dithiobarbamate, Na- or K-dimethyldithiocarbamate, macozeb, maneb, metam, metiram, tiram, zineb, ziram.

Nitriler som: Nitriles such as:

2,4,5,6-tetraklorisoftalodinitril, dinatrium-cyano-ditioimidokarbamat. 2,4,5,6-Tetrachloroisophthalodinitrile, disodium cyano-dithioimidocarbamate.

Kinoliner som: Quinolines such as:

8-hydroksykinolin og deres Cu-salter. 8-Hydroxyquinoline and their Cu salts.

Diverse fungicider og baktericider som: Various fungicides and bactericides such as:

5-hydroksy-2(5H)-furanon, 4,5-benzditiazolinon, 4,5-trimetylenditiazolinon, N-(2-p-klorbenzoyletyl)-heksaminiumklorid, 2-okso-2-(4-hydroksy-fenyl)acetydroksimsyre-klorid, tris-N-(cykloheksyldiazeniumdioksy)-aluminium, N-(cykloheksyl-diazeniumdioksy)-tributyltinn hhv. K-salter, bis-N-(cykloheksyldiazeniumdioksy)-kobber. 5-Hydroxy-2(5H)-furanone, 4,5-benzdithiazolinone, 4,5-trimethylenedithiazolinone, N-(2-p-chlorobenzoylethyl)hexaminium chloride, 2-oxo-2-(4-hydroxy-phenyl)acetydroximic acid- chloride, tris-N-(cyclohexyldiazeniumdioxy)-aluminium, N-(cyclohexyldiazeniumdioxy)-tributyltin or K salts, bis-N-(cyclohexyldiazeniumdioxy)-copper.

Ag, Zn eller Cu-holdig zeolitt alene eller innesluttet i polymere virkestoffer. Ag, Zn or Cu-containing zeolite alone or enclosed in polymeric active substances.

Insekticider/akartcider/nematicider som: Insecticides/aspecticides/nematicides such as:

Abamectin, acefat, acetamiprid, akrinatrin, alanycarb, aldicarb, aldoxycarb, aldrin, alletrin, alfa-cypermetrin, amitraz, avermectin, AZ 60541, azadirachtin, azinfos A, azinfos M, azocyklotin. Abamectin, acephate, acetamiprid, acrinathrin, alanycarb, aldicarb, aldoxycarb, aldrin, allethrin, alpha-cypermethrin, amitraz, avermectin, AZ 60541, azadirachtin, azinphos A, azinphos M, azocyclotin.

Bacillus thuringiensis, bartrin, 4-birom-2(4-klorfenyl)-l-(etoksymetyl)-5-(trifluormetyl)-lH-pyrrol-3-karbonitril, bendiocarb, benfuracarb, bensultap, beta-cyflutrin, bifentrin, bioresmetrin, bioalletrin, bromofos A, bromofos M, bufencarb, buprofezin, butatiofos, butokarboksin, butoksykarboxim. Bacillus thuringiensis, barthrin, 4-birom-2(4-chlorophenyl)-1-(ethoxymethyl)-5-(trifluoromethyl)-1H-pyrrole-3-carbonitrile, bendiocarb, benfuracarb, benzultap, beta-cyfluthrin, bifenthrin, bioresmethrin, bioallethrin, bromofos A, bromofos M, bufencarb, buprofezin, butathiophos, butocarboxin, butoxycarboxime.

Cadusafos, carbaryl, carbofuran, carbofenotion, carbosulfan, cartap, chinometionat, cloetocarb, klordan, kloretoksyfos, klorfenvinfos, klorfluazuron, klormefos, N-[(6-kloro-3-pyridinyl)-metyl3-N<*->cyano-N-metyl-etanimidamid, klorpicrin, klorpyrifos A, klorpyrifos M, Cis-resmetrin, clocytrin, cypofenotrin, clofentezin, coumafos, cyanofos, cykloprotrin, cyflutrin, cyhalotrin, cyheksatin, cypermetrin, cyromazin. Cadusafos, carbaryl, carbofuran, carbophenothion, carbosulfan, cartap, chinomethionate, cloetocarb, chlordane, chlorethoxyphos, chlorfenvinphos, chlorfluazuron, chlormephos, N-[(6-chloro-3-pyridinyl)-methyl3-N<*->cyano-N- methyl-ethanimidamide, chlorpicrin, chlorpyrifos A, chlorpyrifos M, Cis-resmethrin, clocythrin, cypophenothrin, clofentezine, coumafos, cyanophos, cycloprothrin, cyfluthrin, cyhalothrin, cyhexatin, cypermethrin, cyromazine.

Decametrin, deltametrin, demeton M, demeton S, demeton-S-metyl, diafentiuron, dialifos, diazinon, l,2-dibenzoyI-l-(l,l-dimetyl)-hydrazin, DNOC, dichlofention, diklorvos, diclifos, dicrotofos, diflubenzuron, dimetoat, dimetyl-(fenyl)-silyl-metyl-3-fenoksybenzyleter, dimetyl-(4-etoksyfenyl)-silylmetyl-3-fenoksybenzyleter, dimetylvinfos, dioksation, disulfoton. Decamethrin, deltamethrin, demeton M, demeton S, demeton-S-methyl, diafenthiuron, dialifos, diazinon, l,2-dibenzoyl-l-(l,l-dimethyl)-hydrazine, DNOC, dichlofenthion, dichlorvos, diclifos, dicrotophos, diflubenzuron, dimethoate, dimethyl-(phenyl)-silyl-methyl-3-phenoxybenzyl ether, dimethyl-(4-ethoxyphenyl)-silylmethyl-3-phenoxybenzyl ether, dimethylvinphos, dioxation, disulfoton.

Eflusilanat, emamectin, empentrin, endosulfan, EPN, esfenvalerat, etiofencarb, etion, etofenprox, etrimfos. Eflusilanat, emamectin, empenthrin, endosulfan, EPN, esfenvalerate, etiofencarb, ethion, etofenprox, etrimfos.

Fenamifos, fenazaquin, fenbutatinoksid, fenflutrin, fenitrotion, fenobucarb, fenotiocarb, fenoksycarb, fenpropatrin, fenpyrad, fenpyroksimat, fensulfotion, fention, fenvalerat, fipronil, fluazuron, flucykloxuron, flucytrinat, flufenoxuron, flumetrin flufenprox, fluvalinat, fonofos, formetanat, formotion, fosmetilan fostiazat, fubfenprox, furatiocarb. Fenamiphos, fenazaquin, fenbutatin oxide, fenfluthrin, fenitrothion, fenobucarb, phenothiocarb, fenoxycarb, fenpropathrin, fenpyrad, fenpyroximate, fensulfothion, fenthion, fenvalerate, fipronil, fluazuron, flucycloxuron, flucytrinate, flufenoxuron, flumethrin flufenprox, fluvalinate, fonofos, formetanate, formotion, fosmetilan fostiazate, fubfenprox, furatiocarb.

HCH, heptenofos, heksafiumuron, heksytiazox, hydrametylnon, hydropren. HCH, heptenophos, hexafiumuron, hexythiazox, hydramethylnon, hydroprene.

Imidacloprid, jodfenfos, iprobenfos, isazofos, isoamidofos, isofenfos, isoprocarb, isoprotiolan, isoxation, ivermectin, lama-cyhalotrin, lufenuron. Imidacloprid, iodfenphos, iprobenphos, isazofos, isoamidofos, isofenphos, isoprocarb, isoprothiolan, isoxation, ivermectin, llama-cyhalothrin, lufenuron.

Kadedrin. Cadedrin.

Lambda-cyhalotrin, lufenuron. Lambda-cyhalothrin, lufenuron.

Malation, mecarbam, mervinfos, mesulfenfos, metaldehyd, metacrifos, metamidofos, metidation, metiocarb, metomyl, metalcarb, milbemectin, monocrotofos, moxiectin. Malathion, mecarbam, mervinphos, mesulfenphos, metaldehyde, metacriphos, methamidophos, methidation, methiocarb, methomyl, metalcarb, milbemectin, monocrotophos, moxiectin.

Naled, NC 184, NI 125, nikotin, nitenpyram. Naled, NC 184, NI 125, nicotine, nitenpyram.

Ometat, oxamyl, oxydemeton M, oxydeprofos. Ometate, oxamyl, oxydemeton M, oxydeprophos.

Paration A, paration M, penfluron, permetrin, 2-(4-fenoksyfenoksy)-etyletylkarbamat, fentoat, foråt, fosalon, fosmet, fosfamidon, foxim, pirimicarb, pirimifos M, pirimifos A, pralletrin, profenofos, promecarb, proppafos, propoxur, protiofos, protoat, pymetrozin, pyrachlofos, pyridafention, pyresmetrin, pyretrum, pyridaben, pyrimidifen, pyriproxifen. Parathion A, parathion M, penfluron, permethrin, 2-(4-phenoxyphenoxy)-ethylethylcarbamate, phentoate, forat, fosalon, fosmet, phosphamidon, foxim, pirimicarb, pirimiphos M, pirimiphos A, prallethrin, profenofos, promecarb, proppafos, propoxur, protiofos, protoate, pymetrozine, pyrachlofos, pyridafenthion, pyresmethrin, pyrethrum, pyridaben, pyrimidifen, pyriproxyfen.

Quinalfos. Quinalfos.

Resmetrin, RH-7988, rotenon. Resmethrin, RH-7988, rotenone.

Salition, sebufos, silafluofen, sulfotep, sulprofos. Salition, sebufos, silafluofen, sulfotep, sulprofos.

Tau-fluvalinat, taroils, tebufenozid, tebufenpyrad, tebupirimfos, teflubenzuron, teflutrin, temefos, terbam, terbufos, tetraklorvinfos, tetrametrin, tetrametacarb, tiafenox, tiapronil, tiodicarb, tiofanox, tiazofos, tiocyklam, tiometon, tionazin, turingiensin, tralometrin, triaraten, triazofos, triazamat, triazuron, triklorfon, triflumuron, trimetacarb. Tau-fluvalinate, taroils, tebufenozide, tebufenpyrad, tebupirimfos, teflubenzuron, tefluthrin, temephos, terbam, terbufos, tetrachlorvinphos, tetramethrin, tetrametacarb, tiafenox, tiapronil, thiodicarb, tiofanox, tiazofos, thiocyclam, thiometone, thionazine, thuringiensin, tralometrine, triaraten, triazophos, triazamate, triazuron, trichlorfon, triflumuron, trimetacarb.

Vamidotion, XMC, xylylcarb, zetametrin. Vamidotion, XMC, xylylcarb, Zetamethrin.

Molluscicider som: Molluscicides such as:

Fentinacetat, metaldehyd, metiocarb, niclosamid. Fentin acetate, metaldehyde, methiocarb, niclosamide.

Herbicider og ytterligere algicider som: Herbicides and additional algicides such as:

Acetoklor, acifluorfen, aclonifen, acrolein, alaklor, alloksydim, ametryn, amidosulforon, amitrol, amrnoniumsulfamat, anilofos, asulam, atrazin, aziptrotryn, azimsulforon. Acetochlor, acifluorfen, aclonifen, acrolein, alachlor, alloxydim, ametryn, amidosulforon, amitrol, amrnonium sulfamate, anilophos, asulam, atrazine, aziptrothrin, azimsulforon.

Benazolin, benfluralin, benfuresat, bensulfuron, bensulfid, bentazon, benzofencap, benztiazuron, bifenox, borax, bromacil, bromobutid, bromofenoksim, bromoksynil, butaklor, butamifos, butralin, butylat, bialafos, benzoyl-prop, bromobutid. Benazolin, benfluralin, benfuresate, bensulfuron, benzulfide, bentazon, benzofencap, benztiazuron, bifenox, borax, bromacil, bromobutide, bromophenoxime, bromoxynil, butachlor, butamiphos, butraline, butylate, bialaphos, benzoyl-prop, bromobutide.

Carbetamid, chlometoksyfen, kloramben, klorbromuron, klorflurenol, kloridazon, klorimuron, klornitrofen, kloreddiksyre, klortoluron, kloroksuron, klorprofam, klorsulforon, klortal, klortiamid, cinmetylin, cinofulsuron, cletodim, clomazon, chlomeprop, clopyralid, cyanamid, cyanazin, cycloat, cykloksydim, kloroksynil, clodinafop-propargyl, cumyluron, CGA 248757, clometoksyfen, cyhalofop, clopyrasuluron, cyklosulfamuron. Carbetamide, chlomethoxyphene, chloramben, chlorbromuron, chlorflurenol, chloridazon, chlorimuron, chlornitrophen, chloroacetic acid, chlortoluron, chloroxuron, chlorpropham, chlorsulphoron, chlorthal, chlorthiamide, cinmethylin, cinofulsuron, clethodim, clomazon, chlomeprop, clopyralid, cyanamide, cyanazine, cycloate, cyclooxydim, chloroxynil, clodinafop-propargyl, cumyluron, CGA 248757, clomethoxyfen, cyhalofop, clopyrasuluron, cyclosulfamuron.

Diklorprop, diklorprop-P, diclofop, dietatyl, difenoksuron, difenzoquat, diflufenican, dimefuron, dimepiperat, dimetaklor, dimetipin, dinitramin, dinoseb, dinoseb acetat, dinoterb, difenamid, dipropetryn, diquat, ditiopyr, diduron, DNOC, DSMA, 2,4-D, daimuron, dalapon, dazomet, 2,4-DB, desmedifam, desmetryn, dicamba, dichlobenil, dimetamid, ditiopyr, dimetametryn. Dichlorprop, dichlorprop-P, diclofop, dietatyl, difenoxuron, difenzoquat, diflufenican, dimefuron, dimepiperate, dimetachlor, dimetipine, dinitramine, dinoseb, dinoseb acetate, dinoterb, diphenamide, dipropethryn, diquat, dithiopyr, diduron, DNOC, DSMA, 2,4 -D, daimuron, dalapon, dazomet, 2,4-DB, desmedifam, desmetryn, dicamba, dichlobenil, dimethamide, dithiopyr, dimetametryn.

Eglinazin, endotal, EPTC, esprocarb, etalfturalin, etidimuron, etofumesat, etobenzanid, etoksyfen, ET 751, etametsulfuron. Eglinazine, endotal, EPTC, esprocarb, etalfturalin, etidimuron, etofumesate, etobenzanid, ethoxyphene, ET 751, ethametsulfuron.

Fenoksaprop, fenoksaprop-P, fenuron, flamprop, flamprop-M, flazasulfuron, fluazifop, fluazifop-P, fuenaklor, flukloralin, flumeturon, flurocglycofen, fluoronitrofen, flupropanat, flurenol, fiurokloridon, fluroksypyr, fomesan, fosamin, flamprop-isopropyl, flamprop-isopropyl-L, flumiclorac-pentyl, flumipropyn, flumioxzim, flurtaton, flumioxzim. Fenoxaprop, fenoxaprop-P, fenuron, flamprop, flamprop-M, flazasulfuron, fluazifop, fluazifop-P, fuenachlor, fluchloralin, flumeturon, flurocglycofen, fluoronitrofen, flupropanate, flurenol, fiurochloridone, fluroxypyr, fomesan, fosamine, flamprop-isopropyl, flamprop- isopropyl-L, flumiclorac-pentyl, flumipropyn, flumioxzim, flurtaton, flumioxzim.

Glyfosat, glufosinat-ammonium. Glyphosate, glufosinate ammonium.

Haloksyfop, heksazinon. Haloxyfop, hexazinone.

Imazametabenz, isoproturon, isoksaben, isoksapyrifop, imazapyr, imazaquin, imazetapyr, ioksynil, isopropalin, imazosulfuron. Imazametabenz, isoproturon, isoxaben, isoxapyrifop, imazapyr, imazaquin, imazethapyr, ioxynil, isopropalin, imazosulfuron.

KUH911,KUH920. KUH911,KUH920.

Laktofen, lenacil, tinuron, LS830556. Lactofen, lenacil, tinuron, LS830556.

MCPA, MCPA-tioetyl, MCPB, mecoprop, mecoprop-P, mefenacet, mefluidid, metam, metamitron, metazaklor, metabenztiazuron, metazol, metoroptryn, metyldymron, metylisottocyanat, metobromuron, metoksuron, metribuzin, metsulfuron, molinat, monalid, monolinuron, MSMA, metotaklor, metosulam, metobenzuron. MCPA, MCPA-thioethyl, MCPB, mecoprop, mecoprop-P, mefenacet, mefluidid, metam, metamitron, metazachlor, metabenztiazuron, metazol, metoroptern, methyldymron, methylisocyanate, metobromuron, methoxuron, metribuzin, metsulfuron, molinate, monalid, monolinuron, MSMA, methochlor, metosulam, metobenzuron.

Naproanilid, napropamid, naptalam, neburon, nicosulforon, norflurazon, natriumklorat. Naproanilide, napropamide, napthalam, neburon, nicosulphoron, norflurazon, sodium chlorate.

Oksadiazon, oksyfluorfen, orbencarb, oryzalin, quinchlorac, quinmerac, Oxadiazon, oxyfluorfen, orbencarb, oryzalin, quinchlorac, quinmerac,

Propyzamid, prosulfocarb, pyrazolat, pyrazolsulforon, pyrazoksyfen, pyributicarb, pyridat, paraquat, pebulat, pendimetalin, pentaklorfenol, pentanoklor, petroleumsoljer, fenmedifam, picloram, piperofos, pretilaklor, primisulfuron, prodiamin, prometryn, propaklor, propanil, propaquizafob, propazin, profam, pyritiobac. Propyzamide, prosulfocarb, pyrazolate, pyrazolesulforon, pyrazoxyfen, pyributicarb, pyridate, paraquat, pebulat, pendimethalin, pentachlorophenol, pentanochlor, petroleum oils, fenmedipham, picloram, piperophos, pretilachlor, primisulfuron, prodiamine, promethrin, propachlor, propanil, propaquizafob, propazine, propam, pyrithiobac.

Quinmerac, quinocloamin, quizalofop, quizalofop-P. Quinmerac, quinocloamine, quizalofop, quizalofop-P.

Rimsulfuron. Rimsulfuron.

Setoxydim, sifuron, simazin, simetryn, sulfometuron, sulfentrazon, sulcotrion, sulfosat. Setoxydim, sifuron, simazine, symetryn, sulfometuron, sulfentrazon, sulcotrion, sulfosate.

Tjæreolje, TC A, tebutam, tebutiuron, terbacil, terbumeton, terbutylazin, terbutryn, tiazafiuoron, tifensulforon, tiobencarb, tiocarbazil, tralkoksydim, triallat, triasulfuron, tribenuron, triclopyr, tridifan, trietazin, trifiuralin, tycor, tdiazimin, tiazopyr, triflusulforon. Tar oil, TC A, tebutam, tebutiuron, terbacil, terbumeton, terbuthylazine, terbutryn, thiazafiuoron, thifensulforon, thiobencarb, thiocarbazil, tralkoxydim, triallate, triasulfuron, tribenuron, triclopyr, tridiphan, trietazine, trifiuralin, tycor, tdiazimin, thiazopyr, triflusulforon.

Vernolater. Vernolates.

Vektforholdet mellom virkestoffene i disse virkestoffkombinasjonene kan varieres innen et relativt stort område. The weight ratio between the active substances in these active substance combinations can be varied within a relatively large range.

Fortrinnsvis får virkestoffkombinasjoner benztiazuron, metabenztiazuron, tebutiuron, isoproturon og/eller etiozin på 0,1 til 99,9%, særlig på 1 til 75%, meget foretrukket 5 til 50%, hvorav resten til 100% dekkes gjennom en eller flere av ovennevnte tilsetningspartnere. Preferably, active ingredient combinations benzthiazuron, metabenzthiazuron, tebuthiuron, isoproturon and/or ethiozin are obtained from 0.1 to 99.9%, in particular from 1 to 75%, very preferably 5 to 50%, of which the remainder is 100% covered through one or more of the above addition partners.

Et til beskyttelse av interiør- og eksteriørdispersjonsmalinger, trebeskyttelsesmalinger og -lasurer mot alger anvendelig konsentrat inneholder virkestoffene ifølge oppfinnelsen hhv. virkestoffkombinasjonene i en konsentrasjon på 0,01 til 95 vekt-%, særlig 0,1 til 60 vekt-%. A concentrate suitable for the protection of interior and exterior dispersion paints, wood protection paints and varnishes against algae contains the active substances according to the invention or the active ingredient combinations in a concentration of 0.01 to 95% by weight, in particular 0.1 to 60% by weight.

Anvendelseskonsentrasjonen av virkestoffene hhv. virkestoffkombinasjonene er avhengig av arten og forekomsten av algene som skal bekjempes likesom av sammensetningen av malingen som skal beskyttes. Den optimale anvendelsesmengden blir bestemt ved hjelp av testserier. I alminnelighet ligger anvendelseskonsentrasjonen i området fra 0,001 til 5 vekt-%, fortrinnsvis fra 0,05 til 1,0 vekt-%, med henvisning til malingen som skal beskyttes. The application concentration of the active substances or the active ingredient combinations depend on the nature and occurrence of the algae to be combated as well as the composition of the paint to be protected. The optimal amount of application is determined by means of test series. In general, the application concentration is in the range from 0.001 to 5% by weight, preferably from 0.05 to 1.0% by weight, with reference to the paint to be protected.

Følgende eksempler skal tydeliggjøre anvendelsesmuligheten av virkestoffene som algicider: The following examples will clarify the possibility of using the active substances as algaecides:

Eksempler Examples

Eksempel 1 Example 1

0,5% benztiazuron, metabenztiazuron, tebutiuron, isoproturon og etiozin ble blandet hver for seg i en eksteriør-dispersjonsmaling på basis av styrolakrylat. Deretter ble malingen som inneholder virkestoffet malt på begge sider av kartong. 0.5% benzthiazuron, metabenzthiazuron, tebuthiuron, isoproturon and ethiosin were mixed separately in an exterior dispersion paint based on styrene acrylate. Then the paint containing the active ingredient was painted on both sides of the cardboard.

Prøveanordningen kontamineres ved hjelp av dypping i en algesuspensjon som består av phormidium-, oscillatoria, chlorella- og scenedesmus-arter og deretter overføres prøveanordningen til en Petriskål som er fylt med Allen's agar og som er inokulert med de nevnte alger. The sample device is contaminated by dipping in an algae suspension consisting of phormidium, oscillatoria, chlorella and scenedesmus species and then the sample device is transferred to a Petri dish filled with Allen's agar and inoculated with the aforementioned algae.

Etter fire ukers inkubasjon ved romtemperatur og 1200-1500 LUX viste platene som inneholder benztiazuron, metabenztiazuron, tebutiuron, isoproturon og etiozin en meget god algestabilitet, mens en virkestoff-fri kontrollprøve blir fullstendig tilgrodd av testorganismer. After four weeks of incubation at room temperature and 1200-1500 LUX, the plates containing benzthiazuron, metabenzthiazuron, tebuthiuron, isoproturon and ethiosin showed very good algal stability, while an active substance-free control sample is completely overgrown by test organisms.

Eksempel 2 Example 2

Deretter ble prøveanordningen utvasket 24 timer ved 12 l/t gjennomstrømshastighet og 20°C. The test device was then washed out for 24 hours at a flow rate of 12 l/h and 20°C.

Etter avslutning av vanningssyklusen ble prøvene tatt ut av vannet, skylt og tørket i 24 timer. After completion of the watering cycle, the samples were taken out of the water, rinsed and dried for 24 hours.

Prøveanordningen kontamineres ved hjelp av dypping i en algesuspensjon som består av phormidium-, oscillatoria, chlorella- og scenedesmus-arter og deretter overføres prøveanordningen til en Petriskål som er fylt med Allen's agar og som er inokulert med de ovennevnte algene. The sample device is contaminated by dipping in an algal suspension consisting of phormidium, oscillatoria, chlorella and scenedesmus species and then the sample device is transferred to a Petri dish filled with Allen's agar and inoculated with the above-mentioned algae.

Etter 4 ukers inkubasjon ved romtemperatur og 1200-1500 LUX viste platene som inneholder benztiazuron, metabenztiazuron, tebutiuron, isoproturon og etiozin en meget god algestabilitet, mens en virkestoff-fri kontrollprøve ble fullstendig tilgrodd av testorganismer. After 4 weeks of incubation at room temperature and 1200-1500 LUX, the plates containing benzthiazuron, metabenzthiazuron, tebuthiuron, isoproturon and ethiosin showed very good algal stability, while an active substance-free control sample was completely overgrown by test organisms.

Analogt til Eksempel 1 og 2 ble det gjennomført forsøk med eksteriør-dispersjonsmaling på basis av polyvinylacetat. Analogously to Examples 1 and 2, experiments were carried out with exterior dispersion paint based on polyvinyl acetate.

Med 0,5% benztiazuron, metabenztiazuron, tebutiuron, isoproturon og etiozin konstateres her med og uten vanning ingen tilgroing, mens de ubehandlede kontrollprøvene er fullstendig tilgrodd. With 0.5% benzthiazuron, metabenzthiazuron, tebuthiuron, isoproturon and ethiosin, with and without watering, no overgrowth is observed, while the untreated control samples are completely overgrown.

Claims

1. Application of benzthiazuron, metabenzthiazuron, tebuthiuron, isoproturon and/or ethiosin to combat algae growth on interior and exterior dispersion paints, wood protection paints and varnishes.

2. Method for combating algae growth on interior and exterior dispersion paints, wood protection paints and glazes, characterized in that the aforementioned materials are mixed or treated with benztiazuron, metabenztiazuron, tebutiuron, isoproturon and/or ethiosin.

3. Interior and exterior dispersion paints, wood protection paints and glazes, characterized in that they contain benzthiazuron, metabenzthiazuron, tebutiuron, isoproturon and/or ethiosin.

4. Interior and exterior dispersion paints, wood protection paints and glazes according to claim 3, characterized in that they additionally contain at least one fungicide, bactericide, molluscicide, insecticide, herbicide, algicide and/or an active anti-fouling substance.