NO20052576L - Fjerning av svovelforbindelser fra hydrokarbonstrommer ved a bruke adsorbenter og regenerering av de belastede absorbentene - Google Patents

Fjerning av svovelforbindelser fra hydrokarbonstrommer ved a bruke adsorbenter og regenerering av de belastede absorbentene

Info

Publication number
NO20052576L
NO20052576L NO20052576A NO20052576A NO20052576L NO 20052576 L NO20052576 L NO 20052576L NO 20052576 A NO20052576 A NO 20052576A NO 20052576 A NO20052576 A NO 20052576A NO 20052576 L NO20052576 L NO 20052576L
Authority
NO
Norway
Prior art keywords
regeneration
sulfur compounds
charged
adsorbent
absorbents
Prior art date
Application number
NO20052576A
Other languages
English (en)
Inventor
Thijme Last
Jolinde Machteld Van De Graaf
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of NO20052576L publication Critical patent/NO20052576L/no

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/102Removal of contaminants of acid contaminants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/12Recovery of used adsorbent
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • B01D2253/108Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30Physical properties of adsorbents
    • B01D2253/302Dimensions
    • B01D2253/308Pore size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/24Hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/304Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/306Organic sulfur compounds, e.g. mercaptans
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/06Polluted air
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40083Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40086Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by using a purge gas
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2

Abstract

Oppfinnelsen gjelder en prosess for fjerning av svovelforbindelser fra en hydrokarbon strøm, spesielt en gassfase hydrokarbonstrøm som omfatter nevnte svovelforbindelser, hvilken prosess omfatter å la nevnte gasstrøm komme i kontakt med en adsorbent som omfatter en zeolitt med en porediameter på minst 5 Å for å adsorbere svovelforbindelsene på denne, og adsorpsjonsprosessen blir fulgt av en regenereringsprosess av brukt, belastet adsorbent ved å la nevnte belastede adsorbent komme i kontakt med en regenererende gasstrøm med en relativ fuktighet av vann på mindre enn 100 %, spesielt mindre enn 80 %. Passende blir regenereringen fulgt av en tørr regenererende behandling. Oppfinnelsen gjelder videre en prosess for regenerering av adsorbent som omfatter en zeolitt med en porediameter på minst 5 Å belastet med svovelforbindelser, ved å la adsorbenten komme i kontakt med en regenererende gasstrøm med en relativ fuktighet av vann på mindre enn 100 %, spesielt mindre enn 80 %. Hensiktsmessig blir regenereringen fulgt av en tørr regenererende behandling.
NO20052576A 2002-10-29 2005-05-27 Fjerning av svovelforbindelser fra hydrokarbonstrommer ved a bruke adsorbenter og regenerering av de belastede absorbentene NO20052576L (no)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP02257483 2002-10-29
PCT/EP2003/050765 WO2004039926A1 (en) 2002-10-29 2003-10-29 Removal of sulphur compounds from hydrocarbon streams using adsorbents and regeneration of the loaded adsorbents

Publications (1)

Publication Number Publication Date
NO20052576L true NO20052576L (no) 2005-05-27

Family

ID=32187258

Family Applications (1)

Application Number Title Priority Date Filing Date
NO20052576A NO20052576L (no) 2002-10-29 2005-05-27 Fjerning av svovelforbindelser fra hydrokarbonstrommer ved a bruke adsorbenter og regenerering av de belastede absorbentene

Country Status (5)

Country Link
US (1) US7517389B2 (no)
EP (1) EP1590425A1 (no)
CA (1) CA2503701C (no)
NO (1) NO20052576L (no)
WO (1) WO2004039926A1 (no)

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EP2190558A1 (en) 2007-09-10 2010-06-02 Shell Internationale Research Maatschappij B.V. Process for producing purified synthesis gas from synthesis gas comprising trace amounts of sulphur contaminants with a metal-organic framework
US7682424B2 (en) * 2008-01-31 2010-03-23 Conocophillips Company Contaminant removal from a gas stream
CA2712939A1 (en) 2008-02-04 2009-08-13 Shell Internationale Research Maatschappij B.V. A process for regeneration of adsorbent beds
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Also Published As

Publication number Publication date
US20060107832A1 (en) 2006-05-25
CA2503701A1 (en) 2004-05-13
WO2004039926A1 (en) 2004-05-13
AU2003301679A1 (en) 2004-05-25
US7517389B2 (en) 2009-04-14
EP1590425A1 (en) 2005-11-02
CA2503701C (en) 2011-12-20

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