NO169729B - TOEYMYKNINGSMIDDELBLANDING - Google Patents
TOEYMYKNINGSMIDDELBLANDING Download PDFInfo
- Publication number
- NO169729B NO169729B NO831630A NO831630A NO169729B NO 169729 B NO169729 B NO 169729B NO 831630 A NO831630 A NO 831630A NO 831630 A NO831630 A NO 831630A NO 169729 B NO169729 B NO 169729B
- Authority
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- Norway
- Prior art keywords
- cationic
- softener
- active
- sulfonate
- aqueous
- Prior art date
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- 239000002979 fabric softener Substances 0.000 claims description 21
- 239000012188 paraffin wax Substances 0.000 claims description 13
- 125000002091 cationic group Chemical group 0.000 claims description 11
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000002752 cationic softener Substances 0.000 claims description 6
- -1 aliphatic quaternary ammonium salts Chemical class 0.000 claims description 4
- 239000004014 plasticizer Substances 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 claims 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 claims 1
- 239000004480 active ingredient Substances 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 238000010923 batch production Methods 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 239000004280 Sodium formate Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 235000011148 calcium chloride Nutrition 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- 239000004665 cationic fabric softener Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- AQUCOCCZWYJKFZ-UHFFFAOYSA-M diethyl(dioctadecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](CC)(CC)CCCCCCCCCCCCCCCCCC AQUCOCCZWYJKFZ-UHFFFAOYSA-M 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000002001 electrolyte material Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
- 235000019254 sodium formate Nutrition 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
- Stringed Musical Instruments (AREA)
- Adornments (AREA)
- Golf Clubs (AREA)
Description
Oppfinnelsen angår forbedrede, sterkt effektive tøy-mykningsmidler hvor en kationaktiv tøymykningsforbindelse og et høyere alkylsulfonat anvendes som selv ikke tilveie-bringer mykningsvirkning overfor tøyvasken. Den særpregede og synergistiske virkning av kombinasjonen av den kationaktive forbindelse og paraffinsulfonatet gjør det mulig å oppnå mykningsmidler med et lavere innhold av aktiv bestanddel enn ved ganske enkel anvendelse av et kationaktivt materiale for å oppnå en sammenlignbar mykningsvirkning. Dette gjør det mulig med et større spillerom ved fremstilling av tøy-mykningsmidler og dessuten å oppnå betydelige økonomiske be-sparelser. The invention relates to improved, highly effective fabric softeners where a cationically active fabric softener compound and a higher alkyl sulphonate are used which themselves do not provide a softening effect to the laundry. The distinctive and synergistic effect of the combination of the cation-active compound and the paraffin sulphonate makes it possible to obtain softeners with a lower content of active ingredient than by simply using a cation-active material to achieve a comparable softening effect. This makes it possible to have greater leeway in the production of fabric softeners and also to achieve significant financial savings.
Oppfinnelsens bakgrunn The background of the invention
Det er empirisk blitt fastslått at for en normal tøy-mengde som skal vaskes (f.eks. 3,6-4,5 kg) i en vanlig vaske-maskin hvori ca. 35 liter vann oa 30-60 g av et 6%-ig aktivt kationisk kondisjoneringsmiddel anvendes, fås en meget aksepterbar mykning. Bedømt efter en mykhetsskala fra 1 It has been empirically determined that for a normal amount of laundry to be washed (e.g. 3.6-4.5 kg) in a normal washing machine in which approx. 35 liters of water and 30-60 g of a 6% active cationic conditioning agent are used, a very acceptable softening is obtained. Judged according to a softness scale from 1
til 10 innebærer dette et poengtall av 9-10. to 10, this means a score of 9-10.
Ved et poengtall av 6 og derover oppfatter brukeren en merkbar forskjell mellom poengtall på 6, 7, 8, 9 og 10. With a score of 6 and above, the user perceives a noticeable difference between scores of 6, 7, 8, 9 and 10.
Fra 1 til 5 er vasken fullstendig utilfredsstillende From 1 to 5, the wash is completely unsatisfactory
og har et meget grovt og "platelignende" grep. På disse nivåer kan brukeren i alminnelighet ikke oppdage noen forskjeller. Selvfølgelig vil en ekspert med mer erfaring og bedre vurderingsevne kunne oppdage forskjeller blant alle disse poengtall. and has a very rough and "plate-like" grip. At these levels, the user generally cannot detect any differences. Of course, an expert with more experience and better judgment will be able to detect differences among all these scores.
Konsentrasjonen av 6% aktivt kationisk materiale har vært den generelle industrielle standard da høyere konsentrasjoner i vandige systemer ofte er vanskelig å fremstille, stabiliteten kan være dårlig, hellbarheten kan være dårlig, geldannelsen kan utgjøre et alvorlig problem, og disperger-barheten i vaskevannet kan være dårlig og føre til dårlig mykning og/eller flekkdannelse. The concentration of 6% active cationic material has been the general industrial standard as higher concentrations in aqueous systems are often difficult to produce, stability can be poor, pourability can be poor, gel formation can pose a serious problem, and dispersibility in the wash water can be poorly and lead to poor softening and/or spotting.
I US patentskrift 4000077 er forbedrede tøymyknings- midler beskrevet som omfatter en kombinasjon av et kationaktivt mykningsmiddel og et langkjedet alifatisk alkohol-sulfat (omfattende ethoxylerte alkoholsulfater). Det er klart ifølge dette patentskrift at det empirisk er blitt fastslått at lavere konsentrasjoner av samlede aktive bestanddeler (dvs. under 6%) kan føre til en mykning som svarer til den mykning som oppnås med 6% kationaktiv be- . standdel alene. In US patent 4000077, improved fabric softeners are described which comprise a combination of a cationically active softener and a long-chain aliphatic alcohol sulfate (including ethoxylated alcohol sulfates). It is clear according to this patent document that it has been empirically determined that lower concentrations of total active ingredients (ie below 6%) can lead to a softening that corresponds to the softening achieved with 6% cationic active be- . stand part alone.
I US patentskrift 3997453 er tøymykningsmidler med forbedret dispergerbarhet i kaldt vann beskrevet, og disse oppnås ved samtidig anvendelse av mindre mengder av nærmere spesifiserte anionaktive sulfonater. Forhold mellom kationaktiv bestanddel og anionaktiv bestanddel av fra 80:1 til 3:1, 50:1 til 4:1 og 40:1 til 5:1 er beskrevet. Blant de beskrevne sulfonater er Cq-C2q paraffinsulfonatene. In US patent 3997453, fabric softeners with improved dispersibility in cold water are described, and these are achieved by the simultaneous use of smaller quantities of more specifically specified anionic sulphonates. Ratios between cationic active ingredient and anionic active ingredient of from 80:1 to 3:1, 50:1 to 4:1 and 40:1 to 5:1 are described. Among the sulfonates described are the Cq-C2q paraffin sulfonates.
Formål med oppfinnelsen Purpose of the invention
Det tas derfor ved oppfinnelsen sikte på å tilveiebringe et tøymykningsmiddel med utmerkede bruksegenskaper og som dessuten er rimelig. The invention therefore aims to provide a fabric softener with excellent usage properties and which is also affordable.
Det tas ved oppfinnelsen dessuten sikte på å tilveiebringe kationiske tøymykningsmidler under anvendelse av lavere konsentrasjoner av aktiv, bestanddel, men som likevel gir mykningsvirkninger som kan sammenlignes med de mykningsvirkninger som erholdes med midler av kationaktiv bestanddel alene i høyere konsentrasjon av aktiv bestanddel . The invention also aims to provide cationic fabric softeners using lower concentrations of active ingredient, but which nevertheless provide softening effects that can be compared to the softening effects obtained with agents of cationic active ingredient alone in higher concentration of active ingredient.
Det tas ved oppfinnelsen nærmere bestemt sikte på The invention is specifically aimed at
å tilveiebringe et" synergistisk tøymykningsmiddel som inneholder et kationaktivt kvartært ammoniummyknings-middel sammen med et langkjedet paraffinsulfonat. to provide a "synergistic fabric softener" containing a cationic quaternary ammonium softener together with a long chain paraffin sulfonate.
Beskrivelse av oppfinnelsen Description of the invention
Det tilveiebringes ifølge oppfinelsen en vandig tøymyknings-middelblanding omfattende en kationisk mykner og 0,2-1% av et parafinsulfonat i et vektforhold av 5:1-12:1, idet den kationiske mykner er valgt fra gruppen bestående av vanndispergerbare di-langkjedede alifatiske, di-kortkjedede alifatiske kvartære ammoniumsalter, og den vandige tøy- mykningsmiddelblanding er særpreget ved at den kationiske mykner er tilstede i en mengde av 2-5 vekt% og er di-stearyldimethylammoniumklorid, og at parafinsulfonatet er et C14~<C>17<-p>arafinsulfonat. The invention provides an aqueous fabric softener mixture comprising a cationic softener and 0.2-1% of a paraffin sulfonate in a weight ratio of 5:1-12:1, the cationic softener being selected from the group consisting of water-dispersible di-long-chain aliphatic , di-short-chain aliphatic quaternary ammonium salts, and the aqueous fabric softener mixture is characterized in that the cationic softener is present in an amount of 2-5% by weight and is dis-stearyldimethylammonium chloride, and that the paraffin sulfonate is a C14~<C>17< -p>paraffin sulfonate.
Foruten den kationaktive myknende bestanddel i mykningsmidlet ifølge oppfinnelsen kan det i de vandige blandinger også innføres en lang rekke vanlige supplerende materialer eller valgfrie bestanddeler som ikke uheldig på-virker stabiliteten og/eller de funksjonelle egenskaper for tøymykningsmidlet ifølge oppfinnelsen. Således kan f.eks. mindre mengder av forskjellige overflateaktive materialer være tilstede, og spesielt visse overflateaktive fosfat-estere som kan være ønskelige for å bevirke at det vaskede tøy får antistatiske egenskaper. Slike vanlige ytterligere bestanddeler omfatter også parfymer, farvestoffer, pigmenter, kimdrepende midler, optiske hvitemidler eller antikorrosjons-midler (natriumsilikat) etc. Dersom disse anvendes, kan hver av disse utgjøre f.eks. 1 vekt% av de foreliggende tøymyk-ningsmidler . In addition to the cationic softening component in the fabric softener according to the invention, a wide range of common supplementary materials or optional components can also be introduced into the aqueous mixtures which do not adversely affect the stability and/or the functional properties of the fabric softener according to the invention. Thus, e.g. smaller amounts of various surface-active materials be present, and in particular certain surface-active phosphate esters which may be desirable to cause the washed laundry to acquire antistatic properties. Such common additional components also include perfumes, dyes, pigments, germicides, optical whitening agents or anti-corrosion agents (sodium silicate) etc. If these are used, each of these can constitute e.g. 1% by weight of the available fabric softeners.
Det kan også være ønskelig å supplere og/eller forandre det foreliggende tøymykningsmiddels viskositet ved å tilsette et elektrolyttmateriale, som kalsiumklorid, natriumnitrat eller natriumf ormiat etc, i en mengde av 0,05-5 vekt%. Mindre andeler av andre bestanddeler kan også innarbeides, som de lavere alkanoler, f.eks. ethylalkohol eller isopropyl-alkohol, og dessuten de vanlige blakningsmidler, spesielt av de velkjente harpiksemulsjonstyper. It may also be desirable to supplement and/or change the viscosity of the present fabric softener by adding an electrolyte material, such as calcium chloride, sodium nitrate or sodium formate etc, in an amount of 0.05-5% by weight. Smaller proportions of other components can also be incorporated, such as the lower alkanols, e.g. ethyl alcohol or isopropyl alcohol, and also the usual bleaching agents, especially of the well-known resin emulsion types.
De vandige tøymykningsmidler ifølge oppfinnelsen inneholder 2-5% av den kationaktive forbindelse og 0,2-1% av paraffinsulfonatet, idet forholdet mellom kationaktiv forbindelse og sulfonat varierer fra 5:1 til 12:1. De foretrukne tøymykningsmidler har et samlet innhold av aktive bestanddeler (dvs. kationaktiv forbindelse pluss sulfonat) av 4-6%, helst 4-4,5%, og et mest foretrukket forhold mellom kationaktiv forbindelse og sulfonat av ca. 10:1. The aqueous fabric softeners according to the invention contain 2-5% of the cationically active compound and 0.2-1% of the paraffin sulphonate, the ratio between cationically active compound and sulphonate varying from 5:1 to 12:1. The preferred fabric softeners have a total content of active ingredients (i.e. cationic active compound plus sulfonate) of 4-6%, preferably 4-4.5%, and a most preferred ratio between cationic active compound and sulfonate of approx. 10:1.
Den foretrukne generelle fremgangsmåte for fremstilling av tøymykningsmidlene ifølge oppfinnelsen er avhengig av hvorvidt en satsvis eller kontinuerlig prosess anvendes. The preferred general method for producing the fabric softeners according to the invention depends on whether a batch or continuous process is used.
Ved en satsvis prosess blir ca. 2/3 av oppskriftsmengden In a batch process, approx. 2/3 of the recipe amount
av vann oppvarmet til 35-50°C. Den kationaktive forbindelse og paraffinsulfonatet blir separat ført sammen under dannelse av en flytende blanding (i alminnelighet med oppvarming til 50-55°C). Blandingen blir derefter tilsatt det på forhånd oppvarmede vann og blandet med dette inntil en homogen masse fås. Derefter blir resten av vannet tilsatt under blanding. of water heated to 35-50°C. The cationic compound and the paraffin sulphonate are separately brought together to form a liquid mixture (generally with heating to 50-55°C). The mixture is then added to the pre-heated water and mixed with this until a homogeneous mass is obtained. Then the rest of the water is added while mixing.
Ved en kontinuerlig prosess blir forhåndsblandingen av kationaktiv forbindelse og paraffinsulfonat (ved 50-55°C) tilsatt den samlede oppskriftsmengde av vann som er blitt oppvarmet til ca. 70°C. In a continuous process, the premix of cation active compound and paraffin sulphonate (at 50-55°C) is added to the total recipe amount of water that has been heated to approx. 70°C.
Alle angitte deler er basert på All parts listed are based on
vekt dersom intet annet er angitt. weight if nothing else is stated.
Eksempel 1 Example 1
Et 40 x 40 cm bomullshåndkle som er blitt forvasket seks ganger for å fjerne alt materiale som kan finnes i håndkleet , skylles i ledningsvann ved værelsetemperatur og oppdeles i 5 stykker efter tørking i luft. Hvert stykke behandles med 1,5 g av en vandig blanding (A) inneholdende 4% distearyldiiæthylamrroniumklorid (DSDMAK). De myknede håndklestykker bedømmes ved hjelp av en parvis sammenlignings-metode mot håndklær som beskrevet ovenfor som er blitt be-handlet med de følgende blandinger: A 40 x 40 cm cotton towel that has been pre-washed six times to remove any material that may be found in the towel, is rinsed in tap water at room temperature and divided into 5 pieces after drying in air. Each piece is treated with 1.5 g of an aqueous mixture (A) containing 4% distearyldiethylammonium chloride (DSDMAK). The softened towel pieces are judged using a pairwise comparison method against towels as described above which have been treated with the following mixtures:
(B) 1,5 g vandig mykningsmiddel inneholdende 3,75% DSDMAK (B) 1.5 g aqueous plasticizer containing 3.75% DSDMAK
og 0,14% C^4_^y-natriumparaffinsulfonat (NAS). and 0.14% C^4_^y sodium paraffin sulfonate (NAS).
(C) 1,5 g vandig mykningsmiddel inneholdende 3,50% DSDMAK (C) 1.5 g aqueous plasticizer containing 3.50% DSDMAK
og 0,28 % NAS. and 0.28% NAS.
(D) 1,5 g vandig mykningsmiddel inneholdende 3,25% DSDMAK (D) 1.5 g aqueous plasticizer containing 3.25% DSDMAK
og 0,43% NAS. and 0.43% NAS.
Resultatene av bedømmelsen viser at (C) virker best, og derefter følger (D), dernest (A) og til sist (B). The results of the evaluation show that (C) works best, followed by (D), then (A) and finally (B).
Det bør bemerkes at (C) og (D) inneholder en vesentlig It should be noted that (C) and (D) contain an essential
mindre andel av kationaktiv forbindelse og endog en mindre samlet mengde av aktive bestanddeler enn (A) (kationaktiv forbindelse alene), men likevel gir bedre mykning. For smaller proportion of cationic active compound and even a smaller total amount of active ingredients than (A) (cationic active compound alone), but still gives better softening. For
(B) er mengden av NAS for lav til å gi de synergistiske virkninger som oppvises av (C) og (D) som er eksempler ifølge (B) the amount of NAS is too low to produce the synergistic effects exhibited by (C) and (D) which are examples according to
oppfinnelsen. the invention.
Ytterligere eksempler på vandige tøymykningsmidler ifølge oppfinnelsen er som følger: Further examples of aqueous fabric softeners according to the invention are as follows:
Det i de ovenstående eksempler anvendte DSDMAK har en molekylvekt av ca. 575 og omfatter foruten C^g-alkyl også en del C-^-alkyl. The DSDMAK used in the above examples has a molecular weight of approx. 575 and, in addition to C₁₋ alkyl, also includes some C₋₋ alkyl.
Paraf f insulf onate.t har en molekylvekt av ca. 328 bestemt ved metoden ifølge Epton. Paraf f insulf onate.t has a molecular weight of approx. 328 determined by the method according to Epton.
De vandige mykningsmidler ifølge oppfinnelsen er generelt anvendbare i likhet med andre slike midler, og de er spesielt anvendbare under skyllesyklusen i en automatisk klesvaskemaskin. Ved slike operasjoner og dessuten ved en hvilken som helst annet ønsket metode for å vaske tøy anvendes tøymykningsmidlene i alminnelighet slik ab c^e.t fås en konsentrasjon av aktive bestanddeler av 0,005-0,3, fortrinnsvis 0,007-0,2, og helst 0,01-0,15, % basert på vekten av skittentøyet. The aqueous fabric softeners according to the invention are generally usable like other such agents, and they are particularly usable during the rinse cycle in an automatic clothes washing machine. In such operations and also in any other desired method of washing clothes, the fabric softeners are generally used so that a concentration of active ingredients of 0.005-0.3, preferably 0.007-0.2, and most preferably 0, 01-0.15, % based on the weight of the dirty laundry.
Claims (2)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US37633782A | 1982-05-10 | 1982-05-10 |
Publications (3)
Publication Number | Publication Date |
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NO831630L NO831630L (en) | 1983-11-11 |
NO169729B true NO169729B (en) | 1992-04-21 |
NO169729C NO169729C (en) | 1992-07-29 |
Family
ID=23484616
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO831630A NO169729C (en) | 1982-05-10 | 1983-05-09 | TOEYMYKNINGSMIDDELBLANDING |
Country Status (22)
Country | Link |
---|---|
AT (1) | ATA164083A (en) |
AU (1) | AU556171B2 (en) |
BE (1) | BE896706A (en) |
BR (1) | BR8302399A (en) |
CA (1) | CA1192354A (en) |
CH (1) | CH655146A5 (en) |
DE (1) | DE3316313A1 (en) |
DK (1) | DK207683A (en) |
ES (1) | ES522202A0 (en) |
FR (1) | FR2526441B1 (en) |
GB (1) | GB2123043B (en) |
GR (1) | GR78260B (en) |
HK (1) | HK16991A (en) |
IT (1) | IT1173710B (en) |
MX (1) | MX158719A (en) |
NL (1) | NL8301673A (en) |
NO (1) | NO169729C (en) |
NZ (1) | NZ204067A (en) |
PH (1) | PH25256A (en) |
PT (1) | PT76663B (en) |
SE (1) | SE8302633L (en) |
ZA (1) | ZA833016B (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0121949A1 (en) * | 1983-02-15 | 1984-10-17 | THE PROCTER & GAMBLE COMPANY | Anionic/cationic detergent mixture with irregular structure |
US4888119A (en) * | 1986-10-06 | 1989-12-19 | Colgate-Palmolive Co. | Cationic/anionic surfactant complex antistatic and fabric softening emulsion for wash cycle laundry applications |
US4756850A (en) * | 1987-06-10 | 1988-07-12 | The Procter & Gamble Company | Articles and methods for treating fabrics |
DE3883296T2 (en) * | 1987-06-10 | 1993-12-16 | Procter & Gamble | Conditioning agents and compositions containing them. |
US5298195A (en) | 1992-03-09 | 1994-03-29 | Amway Corporation | Liquid dishwashing detergent |
US6022845A (en) * | 1995-11-03 | 2000-02-08 | The Procter & Gamble Co. | Stable high perfume, low active fabric softener compositions |
EP0832964A1 (en) * | 1996-09-19 | 1998-04-01 | The Procter & Gamble Company | Liquid stable thickened cleaning compositions |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4000077A (en) * | 1972-05-04 | 1976-12-28 | Colgate-Palmolive Company | Enhancement of cationic softener |
US3997453A (en) * | 1974-02-11 | 1976-12-14 | Colgate-Palmolive Company | Softener dispersion |
DE2648304A1 (en) * | 1975-10-31 | 1977-05-05 | Procter & Gamble Europ | LIQUID DETERGENT |
US4178255A (en) * | 1978-05-15 | 1979-12-11 | Colgate-Palmolive Company | Detergent compositions |
ATE10646T1 (en) * | 1979-09-29 | 1984-12-15 | The Procter & Gamble Company | DETERGENT COMPOSITIONS. |
DE3150178A1 (en) * | 1981-12-18 | 1983-06-30 | Hoechst Ag, 6230 Frankfurt | "CONCENTRATED SOFT SOFT DETERGENT" |
-
1983
- 1983-04-28 GR GR71261A patent/GR78260B/el unknown
- 1983-04-28 ZA ZA833016A patent/ZA833016B/en unknown
- 1983-05-02 NZ NZ204067A patent/NZ204067A/en unknown
- 1983-05-04 AT AT0164083A patent/ATA164083A/en not_active Application Discontinuation
- 1983-05-04 DE DE3316313A patent/DE3316313A1/en not_active Withdrawn
- 1983-05-05 PH PH28860A patent/PH25256A/en unknown
- 1983-05-05 GB GB08312350A patent/GB2123043B/en not_active Expired
- 1983-05-09 FR FR8307717A patent/FR2526441B1/en not_active Expired
- 1983-05-09 SE SE8302633A patent/SE8302633L/en unknown
- 1983-05-09 ES ES522202A patent/ES522202A0/en active Granted
- 1983-05-09 NO NO831630A patent/NO169729C/en unknown
- 1983-05-09 CA CA000427724A patent/CA1192354A/en not_active Expired
- 1983-05-09 PT PT76663A patent/PT76663B/en not_active IP Right Cessation
- 1983-05-09 IT IT48250/83A patent/IT1173710B/en active
- 1983-05-09 BR BR8302399A patent/BR8302399A/en not_active IP Right Cessation
- 1983-05-10 NL NL8301673A patent/NL8301673A/en not_active Application Discontinuation
- 1983-05-10 AU AU14400/83A patent/AU556171B2/en not_active Ceased
- 1983-05-10 DK DK207683A patent/DK207683A/en not_active Application Discontinuation
- 1983-05-10 CH CH2565/83A patent/CH655146A5/en not_active IP Right Cessation
- 1983-05-10 BE BE0/210735A patent/BE896706A/en not_active IP Right Cessation
- 1983-05-26 MX MX197071A patent/MX158719A/en unknown
-
1991
- 1991-03-07 HK HK169/91A patent/HK16991A/en unknown
Also Published As
Publication number | Publication date |
---|---|
CA1192354A (en) | 1985-08-27 |
SE8302633L (en) | 1983-11-11 |
FR2526441B1 (en) | 1987-05-15 |
HK16991A (en) | 1991-03-15 |
AU1440083A (en) | 1983-11-17 |
BE896706A (en) | 1983-11-10 |
IT1173710B (en) | 1987-06-24 |
NO169729C (en) | 1992-07-29 |
DE3316313A1 (en) | 1983-11-10 |
ZA833016B (en) | 1984-12-24 |
GB8312350D0 (en) | 1983-06-08 |
PT76663B (en) | 1986-01-27 |
ATA164083A (en) | 1994-03-15 |
BR8302399A (en) | 1984-01-10 |
SE8302633D0 (en) | 1983-05-09 |
AU556171B2 (en) | 1986-10-23 |
NL8301673A (en) | 1983-12-01 |
GR78260B (en) | 1984-09-26 |
IT8348250A0 (en) | 1983-05-09 |
NZ204067A (en) | 1986-09-10 |
CH655146A5 (en) | 1986-03-27 |
FR2526441A1 (en) | 1983-11-10 |
GB2123043A (en) | 1984-01-25 |
DK207683A (en) | 1983-11-11 |
ES8407093A1 (en) | 1984-08-16 |
ES522202A0 (en) | 1984-08-16 |
MX158719A (en) | 1989-03-03 |
PH25256A (en) | 1991-03-27 |
PT76663A (en) | 1983-06-01 |
NO831630L (en) | 1983-11-11 |
DK207683D0 (en) | 1983-05-10 |
GB2123043B (en) | 1986-02-26 |
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