NO147405B - Means for the preservation of wood and wood materials. - Google Patents
Means for the preservation of wood and wood materials. Download PDFInfo
- Publication number
- NO147405B NO147405B NO773254A NO773254A NO147405B NO 147405 B NO147405 B NO 147405B NO 773254 A NO773254 A NO 773254A NO 773254 A NO773254 A NO 773254A NO 147405 B NO147405 B NO 147405B
- Authority
- NO
- Norway
- Prior art keywords
- mixture
- weight
- wood
- solvent
- organic
- Prior art date
Links
- 239000002023 wood Substances 0.000 title claims description 30
- 239000000463 material Substances 0.000 title claims description 10
- 238000004321 preservation Methods 0.000 title claims description 4
- 239000000203 mixture Substances 0.000 claims description 36
- 239000000417 fungicide Substances 0.000 claims description 33
- 239000002917 insecticide Substances 0.000 claims description 33
- 230000000855 fungicidal effect Effects 0.000 claims description 31
- 239000002904 solvent Substances 0.000 claims description 29
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- 239000000126 substance Substances 0.000 claims description 20
- 150000002148 esters Chemical class 0.000 claims description 18
- 230000008020 evaporation Effects 0.000 claims description 17
- 238000001704 evaporation Methods 0.000 claims description 17
- 239000002253 acid Substances 0.000 claims description 15
- 239000003755 preservative agent Substances 0.000 claims description 15
- -1 (diethoxy-thiophosphoryloxyamino)-2-chloro-phenyl-acetonitrile Chemical compound 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 230000002335 preservative effect Effects 0.000 claims description 7
- 239000011230 binding agent Substances 0.000 claims description 5
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims description 4
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical group 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 239000011877 solvent mixture Substances 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 125000005843 halogen group Chemical group 0.000 claims description 3
- GQKRUMZWUHSLJF-UHFFFAOYSA-N 2-chloro-n-diethoxyphosphinothioyloxybenzenecarboximidoyl cyanide Chemical compound CCOP(=S)(OCC)ON=C(C#N)C1=CC=CC=C1Cl GQKRUMZWUHSLJF-UHFFFAOYSA-N 0.000 claims description 2
- ISRUGXGCCGIOQO-UHFFFAOYSA-N Rhoden Chemical compound CNC(=O)OC1=CC=CC=C1OC(C)C ISRUGXGCCGIOQO-UHFFFAOYSA-N 0.000 claims description 2
- ATROHALUCMTWTB-UHFFFAOYSA-N phoxim Chemical compound CCOP(=S)(OCC)ON=C(C#N)C1=CC=CC=C1 ATROHALUCMTWTB-UHFFFAOYSA-N 0.000 claims description 2
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 claims 2
- OTYZDIRNFDVXFG-UHFFFAOYSA-N (2-butylphenyl) n-methylcarbamate Chemical compound CCCCC1=CC=CC=C1OC(=O)NC OTYZDIRNFDVXFG-UHFFFAOYSA-N 0.000 claims 1
- ATROHALUCMTWTB-WYMLVPIESA-N (z)-n-diethoxyphosphinothioyloxybenzenecarboximidoyl cyanide Chemical compound CCOP(=S)(OCC)O\N=C(/C#N)C1=CC=CC=C1 ATROHALUCMTWTB-WYMLVPIESA-N 0.000 claims 1
- VEQOALNAAJBPNY-UHFFFAOYSA-N antipyrine Chemical compound CN1C(C)=CC(=O)N1C1=CC=CC=C1 VEQOALNAAJBPNY-UHFFFAOYSA-N 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 239000003171 wood protecting agent Substances 0.000 description 16
- 230000000694 effects Effects 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 11
- 241000196324 Embryophyta Species 0.000 description 10
- 239000013543 active substance Substances 0.000 description 8
- 241000238631 Hexapoda Species 0.000 description 7
- 230000000749 insecticidal effect Effects 0.000 description 7
- 241000233866 Fungi Species 0.000 description 6
- 241000256602 Isoptera Species 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- 230000006378 damage Effects 0.000 description 6
- 239000012141 concentrate Substances 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 239000011814 protection agent Substances 0.000 description 5
- JTPNRXUCIXHOKM-UHFFFAOYSA-N 1-chloronaphthalene Chemical compound C1=CC=C2C(Cl)=CC=CC2=C1 JTPNRXUCIXHOKM-UHFFFAOYSA-N 0.000 description 4
- 241000607479 Yersinia pestis Species 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- LXCJGJYAOVCKLO-UHFFFAOYSA-N n-cyclohexyl-n-hydroxynitrous amide Chemical class O=NN(O)C1CCCCC1 LXCJGJYAOVCKLO-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- RULKYXXCCZZKDZ-UHFFFAOYSA-N 2,3,4,5-tetrachlorophenol Chemical compound OC1=CC(Cl)=C(Cl)C(Cl)=C1Cl RULKYXXCCZZKDZ-UHFFFAOYSA-N 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 150000003580 thiophosphoric acid esters Chemical class 0.000 description 3
- AMCBMCWLCDERHY-UHFFFAOYSA-N 1,3-dichloronaphthalene Chemical compound C1=CC=CC2=CC(Cl)=CC(Cl)=C21 AMCBMCWLCDERHY-UHFFFAOYSA-N 0.000 description 2
- HAGYXNVNFOULKK-UHFFFAOYSA-N 1-trityl-1,2,4-triazole Chemical class N1=CN=CN1C(C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 HAGYXNVNFOULKK-UHFFFAOYSA-N 0.000 description 2
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 2
- QQQTUXWFODRVOO-UHFFFAOYSA-N 4-(trifluoromethyl)-5-trityl-2h-triazole Chemical compound FC(F)(F)C1=NNN=C1C(C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 QQQTUXWFODRVOO-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 125000004093 cyano group Chemical group *C#N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 125000005609 naphthenate group Chemical group 0.000 description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000002641 tar oil Substances 0.000 description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 2
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- OJFZCPMENWLPRI-UHFFFAOYSA-N (2-ethylphenyl)-phenylmethanone Chemical compound CCC1=CC=CC=C1C(=O)C1=CC=CC=C1 OJFZCPMENWLPRI-UHFFFAOYSA-N 0.000 description 1
- QBYIENPQHBMVBV-HFEGYEGKSA-N (2R)-2-hydroxy-2-phenylacetic acid Chemical compound O[C@@H](C(O)=O)c1ccccc1.O[C@@H](C(O)=O)c1ccccc1 QBYIENPQHBMVBV-HFEGYEGKSA-N 0.000 description 1
- XDIPOBQVBXLETD-UHFFFAOYSA-N 1,2,3,4-tetrachloro-5,6-dinitrobenzene Chemical compound [O-][N+](=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1[N+]([O-])=O XDIPOBQVBXLETD-UHFFFAOYSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- DREPONDJUKIQLX-UHFFFAOYSA-N 1-[ethenyl(ethoxy)phosphoryl]oxyethane Chemical compound CCOP(=O)(C=C)OCC DREPONDJUKIQLX-UHFFFAOYSA-N 0.000 description 1
- KPAPHODVWOVUJL-UHFFFAOYSA-N 1-benzofuran;1h-indene Chemical compound C1=CC=C2CC=CC2=C1.C1=CC=C2OC=CC2=C1 KPAPHODVWOVUJL-UHFFFAOYSA-N 0.000 description 1
- BFCFYVKQTRLZHA-UHFFFAOYSA-N 1-chloro-2-nitrobenzene Chemical class [O-][N+](=O)C1=CC=CC=C1Cl BFCFYVKQTRLZHA-UHFFFAOYSA-N 0.000 description 1
- AGSMIWJKNRFJRL-UHFFFAOYSA-M 2,3,4,5,6-pentachlorophenolate;tributylstannanylium Chemical compound CCCC[Sn](CCCC)(CCCC)OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl AGSMIWJKNRFJRL-UHFFFAOYSA-M 0.000 description 1
- VGVRPFIJEJYOFN-UHFFFAOYSA-N 2,3,4,6-tetrachlorophenol Chemical class OC1=C(Cl)C=C(Cl)C(Cl)=C1Cl VGVRPFIJEJYOFN-UHFFFAOYSA-N 0.000 description 1
- NQIJOUOHCIVSMY-UHFFFAOYSA-N 2-(5-phenylpentoxycarbonyl)benzoic acid Chemical class OC(=O)C1=CC=CC=C1C(=O)OCCCCCC1=CC=CC=C1 NQIJOUOHCIVSMY-UHFFFAOYSA-N 0.000 description 1
- KASUMNUEJWLOFW-UHFFFAOYSA-N 2-(diethoxyphosphinothioyloxyamino)-2-phenylacetonitrile Chemical compound C1(=CC=CC=C1)C(NOP(=S)(OCC)OCC)C#N KASUMNUEJWLOFW-UHFFFAOYSA-N 0.000 description 1
- UPTVJAJPBGIRLZ-UHFFFAOYSA-N 2-(trichloromethylsulfanyl)-3a,4,5,7a-tetrahydroisoindole-1,3-dione Chemical compound C1CC=CC2C(=O)N(SC(Cl)(Cl)Cl)C(=O)C21 UPTVJAJPBGIRLZ-UHFFFAOYSA-N 0.000 description 1
- QBGLHYQUZJDZOO-UHFFFAOYSA-N 2-chloro-3-nitrophenol Chemical class OC1=CC=CC([N+]([O-])=O)=C1Cl QBGLHYQUZJDZOO-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 241000257303 Hymenoptera Species 0.000 description 1
- 241000792765 Minous Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- IWYDHOAUDWTVEP-UHFFFAOYSA-N R-2-phenyl-2-hydroxyacetic acid Natural products OC(=O)C(O)C1=CC=CC=C1 IWYDHOAUDWTVEP-UHFFFAOYSA-N 0.000 description 1
- 241000590379 Reticulitermes santonensis Species 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- APQHKWPGGHMYKJ-UHFFFAOYSA-N Tributyltin oxide Chemical compound CCCC[Sn](CCCC)(CCCC)O[Sn](CCCC)(CCCC)CCCC APQHKWPGGHMYKJ-UHFFFAOYSA-N 0.000 description 1
- 241000261594 Tyrophagus longior Species 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- SAOKZLXYCUGLFA-UHFFFAOYSA-N bis(2-ethylhexyl) adipate Chemical compound CCCCC(CC)COC(=O)CCCCC(=O)OCC(CC)CCCC SAOKZLXYCUGLFA-UHFFFAOYSA-N 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- VRZVPALEJCLXPR-UHFFFAOYSA-N ethyl 4-methylbenzenesulfonate Chemical compound CCOS(=O)(=O)C1=CC=C(C)C=C1 VRZVPALEJCLXPR-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 229960002510 mandelic acid Drugs 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical compound [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 description 1
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 description 1
- RBXVOQPAMPBADW-UHFFFAOYSA-N nitrous acid;phenol Chemical class ON=O.OC1=CC=CC=C1 RBXVOQPAMPBADW-UHFFFAOYSA-N 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical class CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 230000007903 penetration ability Effects 0.000 description 1
- MOQRZWSWPNIGMP-UHFFFAOYSA-N pentyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCC MOQRZWSWPNIGMP-UHFFFAOYSA-N 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- PNNIWFKUEAZSPW-UHFFFAOYSA-M tributylstannyl 2,2,2-trichloroacetate Chemical compound CCCC[Sn](CCCC)(CCCC)OC(=O)C(Cl)(Cl)Cl PNNIWFKUEAZSPW-UHFFFAOYSA-M 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing aromatic radicals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/16—Inorganic impregnating agents
- B27K3/166—Compounds of phosphorus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/38—Aromatic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/50—Mixtures of different organic impregnating agents
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Description
Foreliggende oppfinnelse angår et middel for konservering av tre og trematerialer, bestående av bestemte vektmengder av en insektisidblanding, et alkoksy-fenyl-N-alkylkarbamat og/eller alkylfenyl-N-alkylkarbamater og minst en halogenert eller halogengruppefri insektisid thionofosforsyreester, og/eller thionofosfonsyreester og et fungisid, samt mer enn 60 vekt-% av et lite flyktig oljeligrnende eller oljeaktig organisk, kjemisk oppløsningsmiddel med et fordampningstall på over 35 og et flammepunkt over 30°C. The present invention relates to an agent for preserving wood and wood materials, consisting of specific weight amounts of an insecticide mixture, an alkoxy-phenyl-N-alkyl carbamate and/or alkylphenyl-N-alkyl carbamates and at least one halogenated or halogen group-free insecticide thiophosphoric acid ester, and/or thionophosphonic acid ester and a fungicide, as well as more than 60% by weight of a low-volatile oily or oily organic chemical solvent with an evaporation number above 35 and a flash point above 30°C.
Det er allerede kjent at tallrike karbamater og thiofosforsyreestere oppviser god insektisid virkning. Disse forbindelser blir derfor fremfor alt anvendt som bekjempnings-middel mot skadedyr, som plantebeskyttelsesmiddel (se f.eks. DE-PS 1.137.895), som sprøytemiddel og lignende for direkte eller indirekte bekjemping av skadeinsekter. Som plantebeskyttelsesmiddel består for disse insiktisider hyppig den nødvendighet og det krav at de skal være nedbrutt etter en viss tid, slik at det ikke skjer noen skade på mennesker eller dyr ved næringsopptak., Ønskelig er det videre at disse insektisider kan spyles ned fra plantene med vann slik at grønn-saker og frukt som har vært behandlet med disse insektisider kan behandles med vann før de spises. It is already known that numerous carbamates and thiophosphoric acid esters exhibit good insecticidal activity. These compounds are therefore above all used as pesticides, as plant protection agents (see e.g. DE-PS 1,137,895), as sprays and the like for direct or indirect control of pests. As a plant protection agent, for these insecticides there is often the necessity and the requirement that they must be broken down after a certain time, so that no harm occurs to humans or animals when nutrients are absorbed., It is also desirable that these insecticides can be washed down from the plants with water so that vegetables and fruit that have been treated with these insecticides can be treated with water before they are eaten.
Tallrike, meget virksomme og i plantevernøyemed anvendte insektisider oppviser derfor selv ved korrekt bruk på planter ikke lenger den nødvendige virkning etter en viss tid, slik at det i de enkelte tilfeller alt etter behov kan være nødvendig med etterbehandling. Så vidt mulig skal heller ikke insektisidene, f.eks. i form av oppløsninger, emulsjoner, spraykonsentrater og lignende, ikke trenge inn i de indre plantedeler, men kun utfolde sin virksomhet på overflaten, Numerous, highly effective insecticides used for plant protection therefore no longer have the required effect after a certain period of time, even when used correctly on plants, so that in individual cases, as needed, post-treatment may be necessary. As far as possible, the insecticides, e.g. in the form of solutions, emulsions, spray concentrates and the like, do not penetrate the internal plant parts, but only unfold their activity on the surface,
der de etter en viss tid vaskes av eller brytes ned. Derimot trenger svært ofte de systemiske insektisider inn i det indre av planten, men bygges dog ned der etter en viss tid, f.eks. i løpet av. 3 uker. Videre oppviser de pulverformige insektisider i form av støvmidler hyppig en for dårlig ved-heftingsevne, slik at de lett spyles av. where after a certain time they are washed off or broken down. In contrast, the systemic insecticides very often penetrate into the interior of the plant, but are built up there after a certain time, e.g. during. 3 weeks. Furthermore, the powdery insecticides in the form of dusting agents often exhibit too poor adhesion, so that they are easily washed off.
I tillegg skal de fleste insektisider-hyppig ha et selektivt virkningskrav, således skal f.eks. nyttedyr som bier, fugler og lignende ikke settes i fare. Dette har ført til at mange insektisider med hell kun kan anvendes mot bestemte skadedyr, f.eks. midd og lignende, mens de ved andre insekter hyppig ikke viser noen virkning. In addition, most insecticides must often have a selective effect requirement, so e.g. beneficial animals such as bees, birds and the like are not put at risk. This has led to the fact that many insecticides can only be used successfully against certain pests, e.g. mites and the like, while with other insects they often show no effect.
Innenfor rammen av foreliggende oppfinnelse ble det derfor prøvet tallrike insektisider med henblikk på deres brukbarhet som tre konserver ingsmidleir , hvorved det ble fastslått at til og med tallrike meget virksomme insektisider med et bredt insektisid virkningsspektrum, f.eks. insektiside fos-for syreestere og lignende, ikke er egnet som trekonserveringsmidler. Within the framework of the present invention, numerous insecticides were therefore tested with a view to their usability as three preservatives, whereby it was determined that even numerous highly effective insecticides with a broad insecticidal spectrum of action, e.g. insecticide phos-for acid esters and the like, are not suitable as wood preservatives.
Det stilles nemlig krav til trekonserveringsmidler som til dels avviker sterkt fra de krav som stilles til insektisider i disses vanlige anvendelsesområder, f.eks. når det gjelder plantebeskyttelsesmiddel,eller skadedyrbekjemp-ningsmidler. Mens insektisidene, f.eks. ved plantebeskyttelse, nedbygges etter en viss tid, vaskes bort eller lignende, stilles det krav til lang virkning når det gjelder trekonser-ver ingsmidler . Trekonserveringsmidlet skal derved ikke bare holde seg til overflaten og drepe de dyr som kommer i "kontakt med denne, tvert imot skal de trenge 'lengst mulig inn i treverket og beskytte dette mot et senere angrep. Selv ved klimatiske påkjenninger skal det ikke opptre noen særlig virknings-reduksjon og heller ikke noen vesentlig reduksjon av den konserverende virkning. Da treverket videre ikke bare angripes av tallrike skadedyr, insekter og disses larver, men også angripes av planter, slik som sopp og:lignende, må det virksomme trekonserveringsmiddel også oppvise en tilsvarende fungisid virkning, hvorved det er viktig at den fungiside og den insektiside virkning ikke påvirkes av ' hverandre på ugunstig måte. Namely, there are requirements for wood preservatives which in some cases differ greatly from the requirements for insecticides in their usual areas of application, e.g. when it comes to plant protection agents or pest control agents. While the insecticides, e.g. in the case of plant protection, degrades after a certain time, is washed away or the like, long-term effects are required when it comes to wood preservatives. The wood preservative must therefore not only stick to the surface and kill the animals that come into contact with it, on the contrary, they must penetrate as far as possible into the wood and protect it against later attack. Even in the case of climatic stresses, there must be no particular reduction in effectiveness, nor any significant reduction in the preservative effect. Furthermore, as the wood is not only attacked by numerous pests, insects and their larvae, but also by plants, such as fungi and the like, the effective wood preservative must also show a corresponding fungicidal action, whereby it is important that the fungicidal and the insecticidal action are not adversely affected by each other.
Mål og oppgave for foreliggende oppfinnelse er således å finne et trekonserveringsmiddel med god virkning som også etter lang tid oppviser en tilstrekkelig insektisid og fungisid trebeskyttelsesvirkning, og som beskytter treet, hhv. trematerialene i lang tid uten å forringe deres kvalitet. Tre-konserver ingsmidlet må også etter klimautsettelse og lignende, dvs. etter påvirkning av regn. snø, frost og sol, oppvise en tilstrekkelig konserverende virkning. Midlet bør samtidig med konserveringsvirkningen for treet med god fungisid og insektisid langtidsvirkning også kunne være brukbart som trebeskyttende grunningsmiddel eller farge- eller lasurmiddel og kunne trenge langt inn i treverket eller trematerialet. The aim and task of the present invention is thus to find a wood preservative with good effect which, even after a long time, exhibits a sufficient insecticidal and fungicidal wood protection effect, and which protects the tree, or the wooden materials for a long time without degrading their quality. The wood preservative must also be used after exposure to climate and the like, i.e. after exposure to rain. snow, frost and sun, exhibit a sufficient preservative effect. The agent should, at the same time as preserving the wood with a good fungicidal and insecticidal long-term effect, also be usable as a wood protective primer or coloring or glazing agent and be able to penetrate far into the wood or the wood material.
Ifølge oppfinnelsen er det fastslått at disse mål According to the invention, it has been established that these targets
og oppgaver finnes i et middel for konservering av tre og trematerialer, bestående av oljeoppløslige eller i oljeaktige oppløsningsmidler oppløselige organisk-kjemiske insektisider og fungisider, tungtflyktige oppløsningsmidler og eventuelt vandige tilsetningsstoffer, og disse midler for konservering karakteriseres ved at konserveringsmidlet utgjøres av 0,5 til 7 vekt-%, fortrinnsvis 2 til 5 vekt-%, beregnet på basis av den ferdige blanding, av en blanding bestående av minst ett i et organisk-kjemisk tungtflyktig eller oljeaktig oppløsnings-middel med et fordampningstall over 35 og et flammepunkt over 30°C oppløselig insektisid alkoksy-fenyl-N-alkylkarbarnat og/ eller alkylfenyl-N-alkylkarbarnat og minst en i et organisk-kjemisk tungtflyktig eller oljeaktig oppløsningsmiddel med et fordampningstall over 35 og et flammepunkt over 30°C oppløselig insektisid halogenert eller halogengruppefr i thionofosforsyreester og/eller thionofosfonsyreester med den generelle formel: and tasks are found in an agent for the preservation of wood and wood materials, consisting of oil-soluble or in oily solvents soluble organic chemical insecticides and fungicides, highly volatile solvents and possibly aqueous additives, and these agents for preservation are characterized by the fact that the preservative consists of 0.5 to 7% by weight, preferably 2 to 5% by weight, calculated on the basis of the finished mixture, of a mixture consisting of at least one in an organic-chemical heavy-volatile or oily solvent with an evaporation number above 35 and a flash point above 30° C soluble insecticide alkoxy-phenyl-N-alkyl carbarnate and/or alkylphenyl-N-alkyl carbarnate and at least one in an organic-chemical heavy-volatile or oily solvent with an evaporation number above 35 and a flash point above 30°C soluble insecticide halogenated or without halogen group in thionophosphoric acid ester and /or thionophosphonic acid ester with the general formula:
hvor R1 angir en alkylrest med 1 til 4 C-atomer, R2 en alkylrest eller en alkoksygruppe med 1 til 4 C-atomer eller en fenylrest, og angir en fenylrest eller en med 1 til 3 halo-genatomer eller med lavere alkyl- eller alkoksygrupper substi-tuert fenylrest, hvorved karbamatet hhv. karbamatblandingen i insektisidblandingen forholder seg til thiofosforsyreesteren hhv. thionofosfonsyreesteren eller blandingen av disse som 3:1 til 1:3, fortrinnsvis 1:0,75 til 1:2 (på vektbasis), og fra 0,3 til 10 vekt-%, beregnet på basis av den ferdige bland- where R1 denotes an alkyl residue with 1 to 4 C atoms, R2 an alkyl residue or an alkoxy group with 1 to 4 C atoms or a phenyl residue, and denotes a phenyl residue or one with 1 to 3 halogen atoms or with lower alkyl or alkoxy groups substituted phenyl residue, whereby the carbamate or the carbamate mixture in the insecticide mixture relates to the thiophosphoric acid ester or the thionophosphonic acid ester or the mixture thereof as 3:1 to 1:3, preferably 1:0.75 to 1:2 (by weight), and from 0.3 to 10% by weight, calculated on the basis of the finished mixture
ing, av et i et organisk-kjemisk tungtflyktig oljeaktig eller oljelignende oppløsningsmiddel med et fordampningstall på over 35 og et flammepunkt over 30°C oppløselig fungisid hhv. fungisidblanding samt mer enn 64 vekt-%, fortrinnsvis mer enn 72 vekt-%, beregnet på basis av den ferdige blanding, av et tungtflyktig oljelignende eller oljeaktig organisk-kjemisk oppløsningsmiddel med et fordampningtall' over 35 og et flammepunkt over 30°C. ing, of a fungicide soluble in an organic-chemical heavy-volatile oily or oil-like solvent with an evaporation rate of over 35 and a flash point over 30°C or fungicide mixture as well as more than 64% by weight, preferably more than 72% by weight, calculated on the basis of the finished mixture, of a highly volatile oil-like or oily organic chemical solvent with an evaporation number above 35 and a flash point above 30°C.
Insektisidblandingen anvendes derved i vektmengder på 0,5 til 7 vekt-%, og fortrinnsvis 2 til 5 vekt-%. The insecticide mixture is thereby used in amounts by weight of 0.5 to 7% by weight, and preferably 2 to 5% by weight.
Ifølge en foretrukket utførelsesform inneholder insektisidblandingen et alkoksy-fenyl-N-alkylk.arbarnat med den generelle formel According to a preferred embodiment, the insecticide mixture contains an alkoxy-phenyl-N-alkyl carbonate with the general formula
og/eller et alkylfenyl-N-alkylkarbamat med den generelle formel 1 ' and/or an alkylphenyl-N-alkylcarbamate of the general formula 1 '
hvori i begge tilfeller R-^ betyr en alkylrest med 1 til 4 C-atomer, fortrinnsvis em metylrest, og R2 betyr en alkylrest med 1 til 5 C-atomer, fortrinnsvis en alkylrest med 3 eller 4 C-atomer. in which in both cases R-1 means an alkyl radical with 1 to 4 C atoms, preferably a methyl radical, and R 2 means an alkyl radical with 1 to 5 C atoms, preferably an alkyl radical with 3 or 4 C atoms.
Videre anvendes fortrinnsvis som halogenert eller halogengruppefr i thionofosforsyreester'en ester med' formelen Furthermore, the ester with the formula is preferably used as a halogenated or halogen group-free in the thionophosphoric acid ester
fortr innsvis (dietoksy-thiofosforyloksyamino)-fenylacetonitril eller ifølge nyere terminologi: 0,0-dietyl-O-(alfa-cyanbenzyliden-amino)thionofosfat og/eller (dietoksy-thio-fosf or ylok sy imono) -2-klorfenylacetonitril. Som fungisid anvendes i de angitte vektmengder i og for seg kjente og i de angitte oppløsningsmidler oppløselige fungisider. Fortrinnsvis anvendes som fungisid et fungisid klorfenol, fortrinnsvis penta- og/eller tetraklorfenol eller en fungisid tetravalent tinnorganisk forbindelse eller et 1-trityl-l,2-4-triasol med den generelle formel hvori R angir et fluor-, klor- eller bromatom, en trifluormetyl-, nitro- eller cyanogruppe eller en alkylgruppe med opp til 4 karbonatomer, og n angir en eller to, samt salter derav med organiske eller uorganiske syrer, fortrinnsvis trifluormetyl-trifenylmetyltriasol eller en blanding av en eller flere av de ovenfor angitte fungisider. I henhold til en spesiell foretrukket utførelses-form anvender man en blanding bestående av 2-isopropoxy-fenyl-N-metylkarbarnat og/eller butylfenyl-N-metylkarbarnat og en insektisid> halogenert eller halogengruppefr i thionofosforsyreester med formelen preferably (diethoxy-thiophosphoryloxyamino)-phenylacetonitrile or according to newer terminology: 0,0-diethyl-O-(alpha-cyanobenzylidene-amino)thionophosphate and/or (diethoxy-thio-phosphoryloxymono)-2-chlorophenylacetonitrile. Fungicides that are known per se and soluble in the specified solvents are used as fungicides in the specified weight quantities. The fungicide used is preferably a fungicide chlorophenol, preferably penta- and/or tetrachlorophenol or a fungicide tetravalent organotin compound or a 1-trityl-1,2-4-triazole with the general formula in which R denotes a fluorine, chlorine or bromine atom, a trifluoromethyl, nitro or cyano group or an alkyl group with up to 4 carbon atoms, and n denotes one or two, as well as salts thereof with organic or inorganic acids, preferably trifluoromethyl-triphenylmethyltriazole or a mixture of one or more of the above-mentioned fungicides. According to a particularly preferred embodiment, a mixture is used consisting of 2-isopropoxy-phenyl-N-methyl carbarnate and/or butylphenyl-N-methyl carbarnate and an insecticide> halogenated or halogen-free in thionophosphoric acid ester with the formula
fortrinnsvis (d ietoksy-thiofosforyloksyimino)-fenylacetoni tr il hhv. 0,0 -dietyl-0-(alfa-cyanbensyliden-amino)thionofosfat preferably (diethoxy-thiophosphoryloxyimino)-phenylacetoni tr il or 0,0-diethyl-0-(alpha-cyanobenzylidene-amino)thionophosphate
og/eller (dietoksy-thiofosforyloksyimino)-2-klorfenylacetoni-tril. and/or (diethoxy-thiophosphoryloxyimino)-2-chlorophenylacetonitrile.
Selv om tallrike insektisider med et bredt virkningsspektrum, f.eks. 0,0-dietyl-O-[(2-isopropyl-4-metyl)-6-pyrimidyl]-thionofosfat, 0,0-dimetyl-0-2,2-diklorvinyl-fosfat, dietylvinylfosfat og bis(dimetylamino)-fosforylfluo-rid osv., ikke ér egnet som trekonserveringsmiddel i forfor-søk, da virkningen etter en viss forsøksvarighet synker i betydelig utstrekning, ble det innenfor rammen av oppfinnelsen fastslått at ved anvendelse av( en kombinasjon av insektisid alkoksy-fenyl-N-alkylkarbamat og/eller alkylfenyl-N-alkylkarbamat og minst en insektisid halogenert eller halogengruppefri thionofosforsyreester hhv. insektisid thionofosfonsyreester oppnås en langtidsvirkning for trekonserveringsmidlet med en stigning av virkningen, hvorved det ved tilsetning av fungiside virksomme stoffer ikke kunne fastslås en virknings-reduksjon av den insektiside virkning. Trekonserveringsmidlet trenger inn i treet og i trematerialene slik at det også oppnås en viss dybdekonservering og -impregnering. Ved frilufts-forsøk ble det videre fastslått at konserveringsmidlet forble virksomt også ved lang klimapåkjenning og bibeholdt både sin trebeskyttende fungiside og insektiside virkning uten at man kunne fastslå treskadende påvirkninger. Although numerous insecticides with a broad spectrum of action, e.g. 0,0-diethyl-O-[(2-isopropyl-4-methyl)-6-pyrimidyl]-thionophosphate, 0,0-dimethyl-0-2,2-dichlorovinyl phosphate, diethyl vinyl phosphate and bis(dimethylamino)-phosphoryl fluoro -rid, etc., is not suitable as a wood preservative in preliminary trials, as the effect decreases to a considerable extent after a certain duration of the trial, it was established within the scope of the invention that when using /or alkylphenyl-N-alkylcarbamate and at least one insecticide halogenated or halogen group-free thionophosphoric acid ester or insecticide thionophosphonic acid ester, a long-term effect is achieved for the wood preservative with an increase in the effect, whereby a reduction in the effect of the insecticidal effect could not be determined by the addition of fungicidal active substances. The wood preservative penetrates into the wood and into the wood materials so that a certain depth of conservation and impregnation is also achieved. active even in the case of long climatic stress and retained both its wood-protecting fungicide and insecticidal effect without any tree-damaging effects being identified.
I henhold til en spesiell1 foretrukket utførelsesform av oppfinnelsen erstattes 0,5 til 20 vekt-%, fortrinnsvis 2 til 15 vekt-%, av det organiske tungtflyktige, oljelignende eller oljeaktige oppløsningsmiddel hhv. blanding av oppløsnings-midler med et fordampingstall på over 35 og et flammepunkt på over 30°C med den samme mengde av en eller flere organiske kjemiske bindemidler og/eller fikseringsmidler, hvorved det som organisk kjemiske bindemidler og/eller fikseringsmidler anvendes slike som kan fordeles hhv. emulgeres og fortrinnsvis oppløses i det nevnte oppløsningsmiddel. According to a particularly preferred embodiment of the invention, 0.5 to 20% by weight, preferably 2 to 15% by weight, of the organic highly volatile, oil-like or oily solvent is replaced or mixture of solvents with an evaporation rate of more than 35 and a flash point of more than 30°C with the same amount of one or more organic chemical binders and/or fixing agents, whereby the organic chemical binding agents and/or fixing agents used are those that can be distributed respectively emulsified and preferably dissolved in the said solvent.
Som bindemiddel anvendes ifølge en spesielt hensiktsmessig utførelsesform kunstharpiks i'form av en emulsjon, dis-persjon eller oppløsning, fortrinnsvis alkydharpiks hhv. modifisert alkydharpikser eller fenolharpikser og/eller inden-kumaronharpikser. Som bindemiddel kan også bitumen eller bitu- According to a particularly suitable embodiment, synthetic resin in the form of an emulsion, dispersion or solution, preferably alkyd resin or modified alkyd resins or phenolic resins and/or indene-coumarone resins. Bitumen or bitumen can also be used as a binder
minøse stoffer anvendes i en mengde på opp til 10 vekt-%. minous substances are used in an amount of up to 10% by weight.
I tillegg kan det tilsettes i og for seg kjente fargestoffer, pigmenter, vannavvisende middel, lukttilsetninger og inhibi-torer hhv..korrosjonsbeskyttelsesmidler og lignende. Som vannavstøtende middel anvendes parafiner, voks. ullfett og lignende i vektmengder på 0,2 til 5 vekt-% og fortrinnsvis 0,5 til 2 vekt-%, beregnet på trebeskyttelsesmidlet. In addition, per se known dyes, pigments, water repellents, odor additives and inhibitors or corrosion protection agents and the like can be added. Paraffins and wax are used as water repellants. wool grease and the like in amounts by weight of 0.2 to 5% by weight and preferably 0.5 to 2% by weight, calculated for the wood preservative.
Som fikseringsmiddel hhv. mykner anvendes fremfor alt slike forbindelser som i tillegg skal forhindre en for-dampning av de virksomme stoffer og/eller en krystallisering hhv. utfelling av disse. Fortrinnsvis anvendes As a fixing agent or plasticizers are used above all such compounds which are also intended to prevent evaporation of the active substances and/or crystallization or precipitation of these. Preferably used
a) myknere, f.eks. alkyl-, aryl- eller aralkylftala-ter, fortrinnsvis dibutyl-, dioktyi- og benzylbutylftalater, alkylfosfater hhv. fosforsyreester, fortrinnsvis tributylfosfat/ adipater, fortrinnsvis di-2-étyl-heksyl-adipat, steara-ter og oleater, f.eks. alkylstearater og alkyloleater, fortrinnsvis butyloleat, butylstearat eller amylstéarat, bis-dimetylbenzyletér, p-tolueiisulfonsyreetylester, glycerinester, glycerineter eller høyere molekylære glykoletere, og/eller b) oljer, f.eks. linolje, risinusolje, tallolje og estere derav og/eller c) fikseringsmidler på basis av ketoner og/eller polyvinylalkyleter, f.eks. ketoner med alkyl-, aryl- eller a) plasticizers, e.g. alkyl, aryl or aralkyl phthalates, preferably dibutyl, dioctyl and benzylbutyl phthalates, alkyl phosphates or phosphoric acid ester, preferably tributyl phosphate/ adipates, preferably di-2-ethylhexyl adipate, stearates and oleates, e.g. alkyl stearates and alkyl oleates, preferably butyl oleate, butyl stearate or amyl stearate, bis-dimethyl benzyl ether, p-toluene sulfonic acid ethyl ester, glycerin esters, glycerin ethers or higher molecular glycol ethers, and/or b) oils, e.g. linseed oil, castor oil, tallow oil and esters thereof and/or c) fixing agents based on ketones and/or polyvinyl alkyl ethers, e.g. ketones with alkyl, aryl or
aralkylgrupper, fortrinnsvis benzofenon. etylbenzofenonj polyvinylalkyleter, fortrinnsvis polyvinylmetyleter. aralkyl groups, preferably benzophenone. ethyl benzophenone polyvinyl alkyl ether, preferably polyvinyl methyl ether.
Som organisk tungtflyktige oljeaktige eller oljelignende oppløsningsmiddel med et fordampningstall over 35 og et flammepunkt over 30°C, fortrinnsvis over 45°C, anvendes fortrinnsvis, vannuoppløselige eller lite vannoppløselige oppløsningsmidler. Som den slags oppløsningsmiddel anvendes tilsvarende mineraloljer eller disses aromatfraksjoner eller mineraloljeholdige oppløsningsmiddelblandinger, fortrinnvis testbensin, petroleum, gassolje og/eller alkylbenzol. Water-insoluble or slightly water-soluble solvents are preferably used as organically volatile oily or oil-like solvents with an evaporation number above 35 and a flash point above 30°C, preferably above 45°C. Corresponding mineral oils or their aromatic fractions or mineral oil-containing solvent mixtures, preferably test petrol, petroleum, gas oil and/or alkylbenzene, are used as the type of solvent.
Fortrinnsvis anvendes mineralolje med et kokeområde fra 170 til 220°C, testbensin med et kokeområde fra 170 til 220°C, spindelolje med et kokeområde fra 250 til 350°C, petroleum med henholdsvis aromater med et kokeområde fra 160 Preferably, mineral oil with a boiling range of 170 to 220°C, test gasoline with a boiling range of 170 to 220°C, spindle oil with a boiling range of 250 to 350°C, petroleum with respectively aromatics with a boiling range of 160
til 280°C eller terpentinolje og lignende. to 280°C or turpentine oil and the like.
I en utførelsesform anvendes også høytkokende blandinger av aromatiske og alifatiske hydrokarboner med et kokeområde fra 180 til 220°C og/eller spindelolje og/eller monoklornaftalin, fortrinnsvis a-monoklornaftalin. In one embodiment, high-boiling mixtures of aromatic and aliphatic hydrocarbons with a boiling range of 180 to 220°C and/or spindle oil and/or monochloronaphthalene, preferably α-monochloronaphthalene, are also used.
Det organiske tungtflyktige oljelignende eller oljeaktige oppløsningsmiddel med et fordampingstall over 35 og et flammepunkt over 30°C, fortrinnsvis over 45°C, kan delvis erstattes av lett- eller middelsflyktige organisk kjemiske oppløsningsmidler, forutsatt at oppløsningsmiddelblandingen beholder et fordampingstall over 35 og et flammepunkt over 30°C, fortrinnsvis over 45°C, og at ,'blandingen insektisid-fungisid er oppløselig i denne oppløsningsmiddelblanding. Derved bør insektisid-fungisid blandingen i det minste være like godt oppløselig som i de tidligere nevnte oppløsningsmidler. Det er fastslått at man alt etter fordampningstall og flammepunkt for de anvendte oljelignende eller oljeaktige oppløs-ningsmidler kan erstatte disse med opp til 20 vekt-%, fortrinnsvis opp til 5 vekt-%, av et oppløsningsmiddel med et lavere fordampingstall. The organic heavy-volatile oil-like or oily solvent with an evaporation number above 35 and a flash point above 30°C, preferably above 45°C, can be partially replaced by light or medium-volatile organic chemical solvents, provided that the solvent mixture retains an evaporation number above 35 and a flash point above 30°C, preferably above 45°C, and that the insecticide-fungicide mixture is soluble in this solvent mixture. Thereby, the insecticide-fungicide mixture should at least be as soluble as in the previously mentioned solvents. It has been established that, depending on the evaporation rate and flash point of the oil-like or oily solvents used, these can be replaced with up to 20% by weight, preferably up to 5% by weight, of a solvent with a lower evaporation rate.
Hva angår de fungiside virksomme stoffer, har det vist seg at det må anvendes i forskjellige konsentrasjoner alt etter arten av fungisid. Som spesielt fordelaktig med henblikk på den fungiside virkning har det vist seg å anvende 3 til 8 vekt-% klorfenol, fortrinnsvis penta- og/eller tetraklorfenol. Overraskende har det vist seg at de tetravalente fungiside tinnorganiske forbindelser og de fungiside 1-trityl-1,2,4-triasoler gir trekonserveringsmidlet en meget god fungisid virkning allerede i konsentrasjoner på 0,2 til 2 vekt-%. Fortrinnsvis blir det derfor i trekonserveringsmidlet som fungisid anvendt 0,3 til 2 vekt-% av en fungisid tetravalent tinnorganisk forbindelse og/eller 1-trityl-1,2,4-triasol med den generelle formel I hvori R er et fluor-, klor- eller bromatom, en trifluormetyl-, nitro- eller cyanogruppe eller en alkylgruppe med opp til 4 karbonatomer, og n er 1 eller 2, samt alter derav med organiske eller uorganiske syrer, fortrinnsvis trifluormetyl-tri-fenylmetyltriasol eller en blanding av ett eller flere av de ovenfor nevnte fungisider. As regards the fungicidally active substances, it has been shown that it must be used in different concentrations depending on the type of fungicide. Using 3 to 8% by weight of chlorophenol, preferably penta- and/or tetrachlorophenol, has proven to be particularly advantageous with regard to the fungicidal effect. Surprisingly, it has been shown that the tetravalent fungicide organotin compounds and the fungicide 1-trityl-1,2,4-triazoles give the wood preservative a very good fungicidal effect already in concentrations of 0.2 to 2% by weight. Preferably, 0.3 to 2% by weight of a fungicide tetravalent organotin compound and/or 1-trityl-1,2,4-triazole of the general formula I in which R is a fluorine, chlorine - or bromine atom, a trifluoromethyl, nitro or cyano group or an alkyl group with up to 4 carbon atoms, and n is 1 or 2, as well as alters thereof with organic or inorganic acids, preferably trifluoromethyl-tri-phenylmethyltriazole or a mixture of one or more of the above-mentioned fungicides.
Som tetravalente tinnorganiske forbindelser kan man anvende de i og for seg kjente fungiside tetravalente tinnorganiske forbindelser. Som spesielt egnet i trekonserverings-midlene ifølge oppfinnelsen har man funnet følgende tetravalente tinnorganiske fungiside forbindelser: Bis-(tri-butyl-tinn) oksyd, tlri-n-butyltinntrikloracetat, tri-n-butyltinn-8-oksychinolin, tri-n-butyltinnpentaklorfenolat, tri-n-tubyl-tinnbisetylendithiokarbamat, tri-n-butyltinnbenzoylcyanoeddik-syre, tri-n-butyltinndimetylarsensyre, tri-n-butyltinnfluorid., tri-n-butyltinnrhodanid, tributyltinndiklorfenolat såvel som aduktet tri-n-butyltinnakrylat/heksaklorcyklopentadien. I stedet for disse som nevnt tidligere foretrukne fungisider kan man dog anvende andre som er oppløselige i de angitte oppløsningsmidler, eller også blandinger av slike andre fungisider, f.eks. fungiside oljeoppløslige naftenater, fortrinnsvis sink- og/eller kobbernaftenater; 8-oksykinolin hhv. disses fungiside oljeoppløslige salter eller derivater, fortrinnsvis fenylkvikksølv-8-oksykinolat; fungiside forbindelser hhv. derivater eller blandinger av klorfenoler, fortrinnsvis forbindelser eller blandinger av penta- og/eller tetraklorfenol med tungtflyktige aminer, f.eks. kolofoniumamin; nitrofenoler hhv. nitroklorfenoler og/eller nitroklorbenzoler, fortrinnsvis 1,2-dinitrotetraklorbenzol; oijeoppløselige fungiside metallorganisie forbindelser, f.eks. av kobber, sink, mangan, kobolt, krom eller kvikksølv, f.eks. i form av kaprilater, naftenater, oleater og lignende; fungiside salter av N-nitroso-N-cykloheksylydroksylamin, fortrinnsvis aluminiumsaltet av N-nitroso-N-cykloheksylhydroksylamin og/eller N-triklor-metylthiotetrahydroftalimid. Ved anvendelse av N-nitroso-N-cykloheksylhydroksylamin og/eller aluminiumsaltet av N-nitroso-N-cykloheksylhydroksylamin må man dog ta hensyn til at disse fungiside forbindelser tilsynelatende kun er egnet for bestemte tretyper, hhv. mot spesielle tresopper. I fungisid-blandingene kan det også innarbeides tjæreoljedestillater og/ eller tjæreolje. As tetravalent organotin compounds, the tetravalent organotin compounds known per se as fungicides can be used. The following tetravalent organotin fungicide compounds have been found to be particularly suitable in the wood preservatives according to the invention: Bis-(tri-butyl-tin) oxide, tri-n-butyltin trichloroacetate, tri-n-butyltin-8-oxyquinoline, tri-n-butyltin pentachlorophenolate . Instead of these, as previously mentioned, preferred fungicides, however, one can use others which are soluble in the stated solvents, or also mixtures of such other fungicides, e.g. fungicide oil-soluble naphthenates, preferably zinc and/or copper naphthenates; 8-oxyquinoline or these fungicide oil-soluble salts or derivatives, preferably phenylmercuric-8-oxyquinolate; fungicide compounds or derivatives or mixtures of chlorophenols, preferably compounds or mixtures of penta- and/or tetrachlorophenol with highly volatile amines, e.g. rosin amine; nitrophenols or nitrochlorophenols and/or nitrochlorobenzenes, preferably 1,2-dinitrotetrachlorobenzene; oil-soluble fungicide metal-organic compounds, e.g. of copper, zinc, manganese, cobalt, chromium or mercury, e.g. in the form of caprylates, naphthenates, oleates and the like; fungicidal salts of N-nitroso-N-cyclohexylhydroxylamine, preferably the aluminum salt of N-nitroso-N-cyclohexylhydroxylamine and/or N-trichloromethylthiotetrahydrophthalimide. When using N-nitroso-N-cyclohexylhydroxylamine and/or the aluminum salt of N-nitroso-N-cyclohexylhydroxylamine, however, one must take into account that these fungicidal compounds are apparently only suitable for certain types of wood, resp. against special wood fungi. Tar oil distillates and/or tar oil can also be incorporated into the fungicide mixtures.
I henhold til en annen utførelsesform er det organisk kjemiske tungtflyktige eller oljeaktige oppløsningsmiddel samtidig et fungisid virksomt stoff- f.eks. kiornaftalin, fortrinnsvis monoklornaftalin og/eller,diklornaftalin. Derved blir konsentrasjonen av fungisid i dette unntakstilfelle over-skredet. Fortrinnsvis anvendes dog ikke monoklornaftalin og/ eller diklornfatalin som eneste fungisid virksomt stoff, men anvendes sammen med andre oppløsningsmidler og/eller fungisider innenfor rammen av oppfinnelsen.; According to another embodiment, the organic chemical heavy-volatile or oily solvent is at the same time a fungicidally active substance - e.g. chironaphthalene, preferably monochloronaphthalene and/or dichloronaphthalene. Thereby, the concentration of fungicide in this exceptional case is exceeded. Preferably, however, monochloronaphthalene and/or dichloronaphthalene are not used as the only fungicidal active substance, but are used together with other solvents and/or fungicides within the scope of the invention.;
Alt etter de anvendte virksomme stoffer og lignende, kan det være hensiktsmessig å anvende ytterligere emulgatorer og/eller fornettningsmidler. Depending on the active substances and the like used, it may be appropriate to use additional emulsifiers and/or crosslinking agents.
Med henblikk på virkningen av konserveringsmidlet With regard to the action of the preservative
og for å redusere korrosjonen, anvendes konserveringsmidler sammen med mandelsyre og/eller benzotriazol. I denne kombinasjon forhindres misfarging av trebeskyLtelsesmidlet i blikkbe-holdere hhv. ved innvirkning av trekonserveringsmidlet på and to reduce corrosion, preservatives are used together with mandelic acid and/or benzotriazole. In this combination, discolouration of the wood preservative in tin containers or by impact of the wood preservative on
1 1
metall eller metalldeler på grunn av en eventuell opptredende korrosjon. Disse korrosjonsbeskyttelsesmidler anvendes fortrinnsvis i vektmengder på 0,05 til 0,2 vekt-%. metal or metal parts due to possible corrosion. These corrosion protection agents are preferably used in amounts by weight of 0.05 to 0.2% by weight.
Hyppig fremstilles konserveringsmidlene i form av konsentrater som etter transport til det sted de skal benyttes, fortynnes med de ^angitte oppløsningsmidler til de vanlige konsentrasjoner. Derved er det mulig å fremstille meget virksomme trebeskyttelseskonsentrater som kan fraktes meget rime-lig. The preservatives are often produced in the form of concentrates which, after transport to the place where they are to be used, are diluted with the specified solvents to the usual concentrations. Thereby, it is possible to produce highly effective wood protection concentrates that can be transported very reasonably.
Ved konserveringsmidlene ifølge oppfinnelsen er When the preservatives according to the invention are
det meget fordelaktig å fremstille et konsentrat. Ved frem-stillingen av konsentratene, forskyver selvfølgelig de angitte konsentrasjoner seg på en slik måte at vektmengdene av insektisidblandingene og fungisidene forhøyes, slik at det etter transporten er mulig å oppnå de tidligere nevnte konsentrasjoner ved tilsetning av oppløsningsmiddel. it is very advantageous to prepare a concentrate. During the production of the concentrates, of course the specified concentrations shift in such a way that the weight amounts of the insecticide mixtures and fungicides are increased, so that after transport it is possible to achieve the previously mentioned concentrations by adding solvent.
Påføringsmengden av konserveringsmidler ifølge oppfinnelsen er forskjellig alt etter anvendelsesområde, kon-sentrasjon av virksomt stoff og lignende. Generelt utgjør mengdene 100 til 350 g/m 2 , fortrinnsvis 150 til 200 g/m 2. Midlet kan anvendes på alle typer tre hhv. trematerialer, og fortrinnsvis på tørre sådanne. The application quantity of preservatives according to the invention differs depending on the area of application, concentration of active substance and the like. In general, the quantities amount to 100 to 350 g/m 2 , preferably 150 to 200 g/m 2 . The agent can be used on all types of wood or wooden materials, and preferably on dry ones.
Sammenligningsforsøk. Comparison experiment.
Prøvede konserveringsmidler og prøvemetoder. Tested preservatives and test methods.
Det ble fremstilt 1%-ig impregneringsmiddeloppløs-ninger av dietoksy-thiofosforyloksyimino-fenylacetonitril hhv. 0,0-dietyl-O-a-cyanbenzyliden-amino tionofosfat; dietoksy-thiof osf oryloksy-imino-2-klorf enylacetonitril og 2-isopro-poksyfenyl-N-metylkarbamat i et organisk oppløsningsmiddel med et fordampingstall over 35 og et flammepunkt over 30°C, og med et sideområde mellom 180 og 210°C. Som fikseringsmiddel inne-holdt impregneringsmidlet i tillegg tributylfosfat. Man prøvde de virksomme stoffer alene og en kombinasjon av disse i spesielle vektforhold. 1% impregnating agent solutions of diethoxy-thiophosphoryloxyimino-phenylacetonitrile or 0,0-diethyl-O-α-cyanobenzylidene-amino thionophosphate; diethoxy-thiophosph oryloxy-imino-2-chlorophenylacetonitrile and 2-isopropoxyphenyl-N-methylcarbamate in an organic solvent with an evaporation number above 35 and a flash point above 30°C, and with a side range between 180 and 210°C. As a fixing agent, the impregnating agent also contained tributyl phosphate. They tried the active substances alone and a combination of these in special weight ratios.
For utprøvingen ble rundfiltre dynket med det for-tynnede impregneringsmiddel og tørket åpent i 8 dager. Der-etter ble små glassrør (diam. 2 cm, høyde 5 cm) som var fylt med 2 fuktige kunststoffskiver (polyuretanskum) satt på filtret. I hvert rør innførte man 50 mg tre og 30 arbeidere av termitt-stammen Reticulitermes santonensis. Forsøkets varighet var 21 dager. For the test, round filters were soaked with the diluted impregnating agent and dried in the open for 8 days. After that, small glass tubes (diam. 2 cm, height 5 cm) which were filled with 2 moist plastic disks (polyurethane foam) were placed on the filter. 50 mg of wood and 30 workers of the termite strain Reticulitermes santonensis were introduced into each tube. The duration of the experiment was 21 days.
Ved forsøkene ble det arbeidet slik at denne påførte virksomme mengde stoff var 20 g/m 2 ved en forsøksserie og 25 During the experiments, the work was done so that this applied effective amount of substance was 20 g/m 2 in a series of experiments and 25
2 2
g/m ved den andre. g/m at the second.
Av disse sammenligningsforsøk fremgår det at under overholdelse av bestemte mengdeforhold oppnås en virknings-stigning for beskyttel sesmidlet som sogar ligger over den additive virkning av enkeltstoffene. From these comparison tests, it appears that, subject to compliance with certain quantity ratios, an increase in effectiveness is achieved for the protective agent which is even above the additive effect of the individual substances.
Med uttrykket "% døde" angis middelverdien av de drepte termitter fra tre sammenligningsforsøk. Med skade angis en større materialødeleggelse mens angrep kun angir en delødeleggelse hhv. en liten beskadigelse, f.eks. på grunn av begynnende angrep uten vidtgående skade. Under disse forsøk bie det videre meget overraskende fastslått at tiden som gikk med til termittene var døde ble forkortet for kombinasjonene i forhold til enkeltstoffene. The expression "% dead" indicates the mean value of the termites killed from three comparison trials. Damage indicates greater material destruction, while attack only indicates partial destruction or a small damage, e.g. due to incipient attacks without widespread damage. During these experiments, it was further very surprisingly determined that the time it took for the termites to die was shortened for the combinations compared to the individual substances.
i in
Dette konserveringsmiddel egnet seg som trebeskyttende grunningsmiddel med god virkning mot sopp og insekter inkludert te rini tier. This preservative is suitable as a wood protective primer with a good effect against fungi and insects including te rini tie.
Dette trekonserveringsmiddel egner seg til bekjemp-ning av insekter og termitter med samtidig forebyggende virkning med samtidig god fungisid virkning. This wood preservative is suitable for combating insects and termites with simultaneous preventive action and good fungicidal action at the same time.
Denne blanding egner seg som forebyggende trekonserveringsmiddel . This mixture is suitable as a preventive wood preservative.
Dette trekonserveringsmiddel har en god forebyggende virkning mot insekter, spesielt mot termitter. Det har en ut-merket inntrengningsevne og en lang virkningsvarighet også ved klimatiske påkjenninger. This wood preservative has a good preventive effect against insects, especially against termites. It has an excellent penetration ability and a long duration of action, even in the case of climatic stresses.
Motstanden mot sopp er også meget god for denne blanding . The resistance to fungi is also very good for this mixture.
Trekonserveringsmidlet bevirker en lasierende farging av treverket og beskytter dette mot 'sopp og insekter. The wood preservative causes a lacy coloring of the wood and protects it against fungi and insects.
Dette konserveringsmiddel egner seg som trebeskyttende gruiuiingsmiddel med god virkning mot sopp og insekter inkludert termitter og blåsopp. This preservative is suitable as a wood-protecting agent with a good effect against fungi and insects, including termites and powdery mildew.
Claims (5)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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DE2644077A DE2644077C2 (en) | 1976-09-30 | 1976-09-30 | Preparations for the preservation of wood and wood-based materials |
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NO773254L NO773254L (en) | 1978-03-31 |
NO147405B true NO147405B (en) | 1982-12-27 |
NO147405C NO147405C (en) | 1983-04-13 |
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ID=5989275
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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NO773254A NO147405C (en) | 1976-09-30 | 1977-09-22 | Means for the preservation of wood and wood materials. |
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JP (1) | JPS5344604A (en) |
AR (1) | AR221831A1 (en) |
AT (1) | AT379541B (en) |
BE (1) | BE859030A (en) |
BR (1) | BR7706505A (en) |
CA (1) | CA1078104A (en) |
CH (1) | CH634343A5 (en) |
DE (1) | DE2644077C2 (en) |
DK (1) | DK147038C (en) |
ES (1) | ES462725A1 (en) |
FI (1) | FI60807C (en) |
FR (1) | FR2366110A1 (en) |
GB (1) | GB1590069A (en) |
IT (1) | IT1086098B (en) |
MY (1) | MY8500091A (en) |
NL (1) | NL7710148A (en) |
NO (1) | NO147405C (en) |
SE (1) | SE425470B (en) |
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DE3004248A1 (en) * | 1980-02-06 | 1981-08-13 | Desowag-Bayer Holzschutz GmbH, 4000 Düsseldorf | WOOD PROTECTIVE CONCENTRATE AND PRODUCTS MADE THEREOF FOR PRESERVATION OR. PROTECTING WOOD AND WOOD MATERIALS AGAINST WOOD-DESTROYING AND WOOD-MAKING ANIMALS AND VEGETABLE PLANTS |
DE3004319A1 (en) * | 1980-02-06 | 1981-08-13 | Desowag-Bayer Holzschutz GmbH, 4000 Düsseldorf | WOOD PROTECTIVE CONCENTRATE AND PRODUCT MADE THEREOF FOR THE PRESERVATION OF WOOD AND WOOD MATERIALS |
DE3024467A1 (en) * | 1980-06-28 | 1982-01-28 | Desowag-Bayer Holzschutz GmbH, 4000 Düsseldorf | AGENTS FOR THE PRESERVATION OF WOOD AND WOOD MATERIALS |
DE3130675A1 (en) * | 1981-08-03 | 1983-02-17 | Desowag-Bayer Holzschutz GmbH, 4000 Düsseldorf | Wood preservative concentrate and agent prepared therefrom for preserving wood and wooden materials |
JPS5916703A (en) * | 1982-07-20 | 1984-01-27 | ア−ス製薬株式会社 | Wood degradation preventive agent composition and method of preventing degradation of wood |
JPS59115805A (en) * | 1982-12-24 | 1984-07-04 | 日本農薬株式会社 | Protective agent for wood |
DE3617250A1 (en) * | 1986-05-22 | 1987-11-26 | Desowag Materialschutz Gmbh | MEDIUM OR CONCENTRATE FOR PRESERVATING WOOD AND WOOD MATERIALS |
DE3641554C2 (en) * | 1986-12-05 | 1995-04-06 | Solvay Werke Gmbh | Wood preservatives |
DE3708893A1 (en) * | 1987-03-19 | 1988-09-29 | Desowag Materialschutz Gmbh | MEDIUM OR CONCENTRATE FOR PRESERVATING WOOD AND WOOD MATERIALS |
AUPR211400A0 (en) | 2000-12-15 | 2001-01-25 | Koppers-Hickson Timber Protection Pty Limited | Material and method for treatment of timber |
WO2023163800A1 (en) * | 2022-02-25 | 2023-08-31 | Swimc Llc | Wood treatment comprising phosphates |
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DE2555984C3 (en) * | 1975-12-12 | 1979-12-13 | Desowag-Bayer Holzschutz Gmbh, 4000 Duesseldorf | Means for preserving wood and wood-based materials and process for their manufacture |
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1976
- 1976-09-30 DE DE2644077A patent/DE2644077C2/en not_active Expired
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1977
- 1977-09-15 NL NL7710148A patent/NL7710148A/en not_active Application Discontinuation
- 1977-09-19 AR AR269258A patent/AR221831A1/en active
- 1977-09-22 NO NO773254A patent/NO147405C/en unknown
- 1977-09-26 FR FR7729108A patent/FR2366110A1/en active Granted
- 1977-09-26 BE BE1008397A patent/BE859030A/en not_active IP Right Cessation
- 1977-09-28 ES ES462725A patent/ES462725A1/en not_active Expired
- 1977-09-28 IT IT28013/77A patent/IT1086098B/en active
- 1977-09-29 AT AT0696577A patent/AT379541B/en not_active IP Right Cessation
- 1977-09-29 DK DK431177A patent/DK147038C/en not_active IP Right Cessation
- 1977-09-29 SE SE7710901A patent/SE425470B/en unknown
- 1977-09-29 BR BR7706505A patent/BR7706505A/en unknown
- 1977-09-29 CA CA287,919A patent/CA1078104A/en not_active Expired
- 1977-09-30 JP JP11779377A patent/JPS5344604A/en active Granted
- 1977-09-30 CH CH1198977A patent/CH634343A5/en not_active IP Right Cessation
- 1977-09-30 GB GB40820/77A patent/GB1590069A/en not_active Expired
- 1977-09-30 FI FI772895A patent/FI60807C/en not_active IP Right Cessation
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1985
- 1985-12-30 MY MY91/85A patent/MY8500091A/en unknown
Also Published As
Publication number | Publication date |
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DE2644077B1 (en) | 1977-11-03 |
GB1590069A (en) | 1981-05-28 |
FI772895A (en) | 1978-03-31 |
DE2644077C2 (en) | 1979-06-28 |
NO147405C (en) | 1983-04-13 |
JPS6224241B2 (en) | 1987-05-27 |
IT1086098B (en) | 1985-05-28 |
NL7710148A (en) | 1978-04-03 |
FR2366110A1 (en) | 1978-04-28 |
SE425470B (en) | 1982-10-04 |
JPS5344604A (en) | 1978-04-21 |
AR221831A1 (en) | 1981-03-31 |
DK147038C (en) | 1984-10-01 |
BE859030A (en) | 1978-03-28 |
FI60807C (en) | 1982-04-13 |
FR2366110B1 (en) | 1980-08-01 |
BR7706505A (en) | 1978-08-08 |
AT379541B (en) | 1986-01-27 |
ATA696577A (en) | 1985-06-15 |
DK431177A (en) | 1978-03-31 |
ES462725A1 (en) | 1978-06-01 |
FI60807B (en) | 1981-12-31 |
CA1078104A (en) | 1980-05-27 |
CH634343A5 (en) | 1983-01-31 |
MY8500091A (en) | 1985-12-31 |
NO773254L (en) | 1978-03-31 |
DK147038B (en) | 1984-03-26 |
SE7710901L (en) | 1978-03-31 |
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PRESERVATION | UN DERSTAN DING TIMBER PRESERVATION |