NL7807562A - Prepn. of co:polyether glycol! with terminal ester gps. - by copolymerising THF with alkylene oxide or cyclic acetal using (co)polymer of unsatd. monomer(s) as catalyst - Google Patents

Prepn. of co:polyether glycol! with terminal ester gps. - by copolymerising THF with alkylene oxide or cyclic acetal using (co)polymer of unsatd. monomer(s) as catalyst Download PDF

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Publication number
NL7807562A
NL7807562A NL7807562A NL7807562A NL7807562A NL 7807562 A NL7807562 A NL 7807562A NL 7807562 A NL7807562 A NL 7807562A NL 7807562 A NL7807562 A NL 7807562A NL 7807562 A NL7807562 A NL 7807562A
Authority
NL
Netherlands
Prior art keywords
polymer
gps
catalyst
monomer
terminal ester
Prior art date
Application number
NL7807562A
Other languages
Dutch (nl)
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Priority to NL7807562A priority Critical patent/NL7807562A/en
Publication of NL7807562A publication Critical patent/NL7807562A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/16—Cyclic ethers having four or more ring atoms
    • C08G65/20—Tetrahydrofuran
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2669—Non-metals or compounds thereof
    • C08G65/2678—Sulfur or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2669—Non-metals or compounds thereof
    • C08G65/2684—Halogens or compounds thereof

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyethers (AREA)

Abstract

A copolyether glycol with terminal ester gps. is prepd. by reacting (A) THF with (B) an alkylene oxide contg. a 2-3C ring, or with a cyclic acetal of formula: (where n is 2-4; X and X1 are H, or 1-4C alkyl) in the presence of (C) a catalyst, and (D) a cpd. which can give an acylium ion R'-C +=O (where R' is H or hydrocarbon radical), esp. acetic anhydride. The catalyst is (a) a homopolymer of an ethylenically unsatd. monomer contg. gps. such that the final polymer contains the gps. (where represents the polymer chain or a chain segment; Z is H, 1-10C aliphatic or aromatic hydrocarbon radical, or halogen; D is as Z or a polymer chain segment; X and Y are H, halogen, 1-10C aliphatic or aromatic hydrocarbon radical, >=1 being F; R is a linear or branched gp. with a =40C principal chain); or (b) a copolymer of (a) with >=1 other ethylenically unsatd. monomer. The (co)polymer has an equiv. wt. of 950-1500 pref. 1000-1300 and dissolves at = about 5 wt.% in the reaction mass at the temp. of reaction. The copolyether glycol with terminal ester gps. can be converted to copolyether glycol which is used in the prepn. of polyurethanes.
NL7807562A 1978-07-13 1978-07-13 Prepn. of co:polyether glycol! with terminal ester gps. - by copolymerising THF with alkylene oxide or cyclic acetal using (co)polymer of unsatd. monomer(s) as catalyst NL7807562A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
NL7807562A NL7807562A (en) 1978-07-13 1978-07-13 Prepn. of co:polyether glycol! with terminal ester gps. - by copolymerising THF with alkylene oxide or cyclic acetal using (co)polymer of unsatd. monomer(s) as catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7807562A NL7807562A (en) 1978-07-13 1978-07-13 Prepn. of co:polyether glycol! with terminal ester gps. - by copolymerising THF with alkylene oxide or cyclic acetal using (co)polymer of unsatd. monomer(s) as catalyst

Publications (1)

Publication Number Publication Date
NL7807562A true NL7807562A (en) 1980-01-15

Family

ID=19831252

Family Applications (1)

Application Number Title Priority Date Filing Date
NL7807562A NL7807562A (en) 1978-07-13 1978-07-13 Prepn. of co:polyether glycol! with terminal ester gps. - by copolymerising THF with alkylene oxide or cyclic acetal using (co)polymer of unsatd. monomer(s) as catalyst

Country Status (1)

Country Link
NL (1) NL7807562A (en)

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Legal Events

Date Code Title Description
A85 Still pending on 85-01-01
BA A request for search or an international-type search has been filed
BB A search report has been drawn up
BC A request for examination has been filed
BV The patent application has lapsed