NL7413678A - Hydrocarbons from carbonaceous fuels - by partial combustion and catalytic reaction of carbon monoxide and hydrogen - Google Patents

Hydrocarbons from carbonaceous fuels - by partial combustion and catalytic reaction of carbon monoxide and hydrogen

Info

Publication number
NL7413678A
NL7413678A NL7413678A NL7413678A NL7413678A NL 7413678 A NL7413678 A NL 7413678A NL 7413678 A NL7413678 A NL 7413678A NL 7413678 A NL7413678 A NL 7413678A NL 7413678 A NL7413678 A NL 7413678A
Authority
NL
Netherlands
Prior art keywords
gas
pref
hydrocarbons
degrees
atm
Prior art date
Application number
NL7413678A
Other languages
Dutch (nl)
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Priority to NL7413678A priority Critical patent/NL7413678A/en
Publication of NL7413678A publication Critical patent/NL7413678A/en

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K23/00—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids
    • F01K23/02—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled
    • F01K23/06—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle
    • F01K23/067—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle the combustion heat coming from a gasification or pyrolysis process, e.g. coal gasification
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0485—Set-up of reactors or accessories; Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Industrial Gases (AREA)

Abstract

Hydrocarbons are produced by (a) producing a gas contg. H2 and CO3 by partial combustion of a carbonaceous fuel; (b) cooling the gas; (c) removing solid particles from the gas by scrubbing with a liq; (d) removing S cpds. by scrubbing with a suitable solvent; and (e) subjecting the CO to catalytic reaction with the H2 in the gas to form hydrocarbons. The carbonaceous fuel is pref. coal to lignite. Step (a) is pref. effected at 900-1500 degrees C and 10-50 atm. using air or O2-enriched air. In step (b), the gas is pref. cooled by injection of water, steam and/or part of the gas from step (c), and/or by indirect that exchange with water to produce steam; the gas is pref. cooled to 120-200 degrees C. The gas is pref. scrubbed with water to remove solids and desulphurised by the ADIP or Sulphinol process. Step (e) is pref. effected at 200-300 degrees C and 10-30 atm. using a catalyst contg. Fe, Co, Ni or Ru. The product is pref. cooled to -30 to -70 degrees C to separate a liq. fraction(>=3 hydrocarbons) from a gaseous fraction contg. H2, CO, N2 and =2C hydrocarbons. The gaseous fraction is pref. expanded to 3-10 atm in a back-press. turbine, then used to cool the product from step (e), and then burnt and the hot combustion gases used in step (a) and for burning the gas.
NL7413678A 1974-10-18 1974-10-18 Hydrocarbons from carbonaceous fuels - by partial combustion and catalytic reaction of carbon monoxide and hydrogen NL7413678A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
NL7413678A NL7413678A (en) 1974-10-18 1974-10-18 Hydrocarbons from carbonaceous fuels - by partial combustion and catalytic reaction of carbon monoxide and hydrogen

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7413678A NL7413678A (en) 1974-10-18 1974-10-18 Hydrocarbons from carbonaceous fuels - by partial combustion and catalytic reaction of carbon monoxide and hydrogen

Publications (1)

Publication Number Publication Date
NL7413678A true NL7413678A (en) 1976-04-21

Family

ID=19822294

Family Applications (1)

Application Number Title Priority Date Filing Date
NL7413678A NL7413678A (en) 1974-10-18 1974-10-18 Hydrocarbons from carbonaceous fuels - by partial combustion and catalytic reaction of carbon monoxide and hydrogen

Country Status (1)

Country Link
NL (1) NL7413678A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2503696A1 (en) * 1981-04-14 1982-10-15 Comp Generale Electricite Hydrocarbon fuel made from carbon di:oxide in combustion gases - via conversion to carbon mon:oxide and hydrogen using electrical heating
EP0103914A2 (en) * 1982-08-26 1984-03-28 Shell Internationale Researchmaatschappij B.V. Process for the generation of power and the preparation of liquid hydrocarbons
EP0497425A1 (en) * 1991-01-30 1992-08-05 Shell Internationale Researchmaatschappij B.V. Process for the combined production of organic compounds and power
EP2258814A1 (en) 2009-06-04 2010-12-08 Shell Internationale Research Maatschappij B.V. Process for processing fischer-tropsch off-gas

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2503696A1 (en) * 1981-04-14 1982-10-15 Comp Generale Electricite Hydrocarbon fuel made from carbon di:oxide in combustion gases - via conversion to carbon mon:oxide and hydrogen using electrical heating
EP0103914A2 (en) * 1982-08-26 1984-03-28 Shell Internationale Researchmaatschappij B.V. Process for the generation of power and the preparation of liquid hydrocarbons
EP0103914A3 (en) * 1982-08-26 1985-07-31 Shell Internationale Research Maatschappij B.V. Process for the generation of power and the preparation of liquid hydrocarbons
EP0497425A1 (en) * 1991-01-30 1992-08-05 Shell Internationale Researchmaatschappij B.V. Process for the combined production of organic compounds and power
AU658600B2 (en) * 1991-01-30 1995-04-27 Shell Internationale Research Maatschappij B.V. Process for the combined production of organic compounds and power
EP0497425B1 (en) * 1991-01-30 1997-08-27 Shell Internationale Researchmaatschappij B.V. Process for the combined production of organic compounds and power
EP2258814A1 (en) 2009-06-04 2010-12-08 Shell Internationale Research Maatschappij B.V. Process for processing fischer-tropsch off-gas

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