NL7212832A - Liquid butadiene-alkene copolymers - with high cis-1,4 -unsaturation,by copolymerising on nickel fluorocarboxylate halide ca - Google Patents

Liquid butadiene-alkene copolymers - with high cis-1,4 -unsaturation,by copolymerising on nickel fluorocarboxylate halide ca

Info

Publication number
NL7212832A
NL7212832A NL7212832A NL7212832A NL7212832A NL 7212832 A NL7212832 A NL 7212832A NL 7212832 A NL7212832 A NL 7212832A NL 7212832 A NL7212832 A NL 7212832A NL 7212832 A NL7212832 A NL 7212832A
Authority
NL
Netherlands
Prior art keywords
fluorocarboxylate
copolymerising
unsaturation
halide
nickel
Prior art date
Application number
NL7212832A
Other versions
NL172553C (en
NL172553B (en
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR7134350A external-priority patent/FR2153787A5/fr
Application filed filed Critical
Publication of NL7212832A publication Critical patent/NL7212832A/en
Publication of NL172553B publication Critical patent/NL172553B/en
Application granted granted Critical
Publication of NL172553C publication Critical patent/NL172553C/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Liquid polymers essentially of cis-1,4-butadiene are prepd. by reacting buta-1,3-diene with >=1 mono alk-l-ene (esp. but-1-ene) in the presence of a catalyst (RCO2) NiX (where X is halogen, and R is alkyl in which the C-atom adjacent the carboxylate gp. is substd. with >=1 F atom), pref. at reduced pressure and 30-120 degrees C. The prods. are used as softeners for thermoplastics, as hardening accelerators in coating compsns., as additives to adhesives, for lowering filtration and pour-point of liquid fuels and to improve the viscosity index of motor oils.
NL7212832A 1968-10-01 1972-09-22 PROCESS FOR PREPARING POLYMERIC COMPOUNDS BY POLYMERIZATION OF BUTADIENE-1,3. NL172553C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR168366 1968-10-01
FR7134350A FR2153787A5 (en) 1971-09-23 1971-09-23

Publications (3)

Publication Number Publication Date
NL7212832A true NL7212832A (en) 1973-03-27
NL172553B NL172553B (en) 1983-04-18
NL172553C NL172553C (en) 1983-09-16

Family

ID=37913629

Family Applications (1)

Application Number Title Priority Date Filing Date
NL7212832A NL172553C (en) 1968-10-01 1972-09-22 PROCESS FOR PREPARING POLYMERIC COMPOUNDS BY POLYMERIZATION OF BUTADIENE-1,3.

Country Status (1)

Country Link
NL (1) NL172553C (en)

Also Published As

Publication number Publication date
NL172553C (en) 1983-09-16
NL172553B (en) 1983-04-18

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