NL7212832A - Liquid butadiene-alkene copolymers - with high cis-1,4 -unsaturation,by copolymerising on nickel fluorocarboxylate halide ca - Google Patents
Liquid butadiene-alkene copolymers - with high cis-1,4 -unsaturation,by copolymerising on nickel fluorocarboxylate halide caInfo
- Publication number
- NL7212832A NL7212832A NL7212832A NL7212832A NL7212832A NL 7212832 A NL7212832 A NL 7212832A NL 7212832 A NL7212832 A NL 7212832A NL 7212832 A NL7212832 A NL 7212832A NL 7212832 A NL7212832 A NL 7212832A
- Authority
- NL
- Netherlands
- Prior art keywords
- fluorocarboxylate
- copolymerising
- unsaturation
- halide
- nickel
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Liquid polymers essentially of cis-1,4-butadiene are prepd. by reacting buta-1,3-diene with >=1 mono alk-l-ene (esp. but-1-ene) in the presence of a catalyst (RCO2) NiX (where X is halogen, and R is alkyl in which the C-atom adjacent the carboxylate gp. is substd. with >=1 F atom), pref. at reduced pressure and 30-120 degrees C. The prods. are used as softeners for thermoplastics, as hardening accelerators in coating compsns., as additives to adhesives, for lowering filtration and pour-point of liquid fuels and to improve the viscosity index of motor oils.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR168366 | 1968-10-01 | ||
FR7134350A FR2153787A5 (en) | 1971-09-23 | 1971-09-23 |
Publications (3)
Publication Number | Publication Date |
---|---|
NL7212832A true NL7212832A (en) | 1973-03-27 |
NL172553B NL172553B (en) | 1983-04-18 |
NL172553C NL172553C (en) | 1983-09-16 |
Family
ID=37913629
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NL7212832A NL172553C (en) | 1968-10-01 | 1972-09-22 | PROCESS FOR PREPARING POLYMERIC COMPOUNDS BY POLYMERIZATION OF BUTADIENE-1,3. |
Country Status (1)
Country | Link |
---|---|
NL (1) | NL172553C (en) |
-
1972
- 1972-09-22 NL NL7212832A patent/NL172553C/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
NL172553C (en) | 1983-09-16 |
NL172553B (en) | 1983-04-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
BB | A search report has been drawn up | ||
BC | A request for examination has been filed | ||
V1 | Lapsed because of non-payment of the annual fee |