NL2030947B1 - Production method for ultrafine ceramic fiber cotton thermal insulation sleeve for heat transfer pipeline - Google Patents

Production method for ultrafine ceramic fiber cotton thermal insulation sleeve for heat transfer pipeline Download PDF

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Publication number
NL2030947B1
NL2030947B1 NL2030947A NL2030947A NL2030947B1 NL 2030947 B1 NL2030947 B1 NL 2030947B1 NL 2030947 A NL2030947 A NL 2030947A NL 2030947 A NL2030947 A NL 2030947A NL 2030947 B1 NL2030947 B1 NL 2030947B1
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Prior art keywords
water
thermal insulation
ceramic fiber
fiber cotton
industrial starch
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NL2030947A
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Dutch (nl)
Inventor
Shen Yi
Zeng Xiongfeng
Wang Baoxiang
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Tangshan Huaxian Tech Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/56Compositions suited for fabrication of pipes, e.g. by centrifugal casting, or for coating concrete pipes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Thermal Insulation (AREA)
  • Paper (AREA)
  • Devices For Post-Treatments, Processing, Supply, Discharge, And Other Processes (AREA)

Abstract

The invention discloses a production method for an ultrafine ceramic fiber cotton thermal insulation sleeve for a heat transfer pipeline. The production method for the ultrafine ceramic fiber cotton thermal insulation sleeve for the heat transfer pipeline includes: slurry curing, beating and deslagging, centrifuging for pipe molding, and microwave drying. By such a method, ultrafine ceramic fiber cotton, silica sol, industrial starch, and sodium methyl silicate which are used as raw materials do not contain asbestos, mineral wool and other substances that are harmful to human body, which ensures the safety during production and construction. The silica sol is used as a binder; the sodium methyl silicate is used as a water repellent, which ensures good moisture resistance and durability. According to the obtained ultrafine ceramic fiber cotton thermal insulation sleeve, an implementation process for thermal insulation of an outer layer of the heat transfer pipeline is simplified.

Description

P1154 /NLpd
PRCDUCTION METHOD FOR ULTRAFINE CERAMIC FIBER COTTON THERMAL
INSULATION SLEEVE FOR HEAT TRANSFER PIPELINE
TECHNICAL FIELD
The present invention relates to the technical field of heat transfer, more specifically to a production method for an ul- trafine ceramic fiber cotton thermal insulation sleeve for a heat transfer pipeline.
BACKGROUND ART
Most of thermal insulation materials of early heat transfer pipelines are natural minerals and natural resource raw materials, such as asbestos, diatomite, cork, straw ropes, and sawdust, etc.
In addition, glass wool, slag wool, perlite, vermiculite, etc. are used as thermal insulation materials. Most of thermal insulation structures of these thermal insulation materials are smeared, filled, bundled, and masonry. Procedures are complicated, and it is not easy to achieve automatic continuous production. At the same time, these thermal insulation materials used at the present have poor durability, especially poor hydrophobicity and high wa- ter absorption rate, easily causing corrosion of thermal insula- tion pipelines.
Therefore, how to solve the deficiencies in the performance and production of the thermal insulation material of the existing heat transfer pipeline has become an important key technical prob- lem to be solved by those skilled in the art.
SUMMARY
The present invention aims to provide a production method for an ultrafine ceramic fiber cotton thermal insulation sleeve for a heat transfer pipeline, which solves the deficiencies in perfor- mance of a thermal insulation material of an existing heat trans- fer pipeline and the problems of high production cost and failure of continuous production.
The objective of the present invention is achieved through the following technical solutions:
In a production method for an ultrafine ceramic fiber cotton thermal insulation sleeve for a heat transfer pipeline, ultrafine ceramic fiber cotton, industrial starch, silica sol, and sodium methyl silicate are used as main raw materials, and production steps include slurry curing, beating and deslagging, centrifuging for pipe molding, and microwave drying.
Preferably, the ultrafine ceramic fiber cotton raw material is a fiber with aluminum silicate serving as a main chemical com- ponent; the fiber has a diameter of 1.5-3 um and a length of 2-5 mm; the industrial starch is ordinary commonly used industrial starch with a starch content more than or equal to 90%; the purity of the silica sol is more than or equal to 90%; and the purity of the sodium methyl silicate is more than or equal to 95%.
Preferably, the slurry curing includes: mixing and stirring the industrial starch and water with a water temperature of 5-25°C according to a mass ratio of the industrial starch to the water of 1:2-1:3 at a stirring rate of 80-120 r/min for 5-10 min; after the industrial starch is uniformly dispersed, adding water with a tem- perature of 100°C according to a mass ratio of the industrial starch to the water of 1:10-1:12; and continuing to stir the mix- ture for 5-10 min to cure the industrial starch, thus obtaining cured slurry.
Preferably, the beating and deslagging includes: transferring the obtained cured slurry into a beating tank; supplementing water with a water temperature of 5-25°C according to a mass ratio of the industrial starch to water of 1:200-1:230; continuing to stir the mixture for 5-10 min; adding 75-85 parts of the ultrafine ceramic fiber cotton, 12-16 parts of the silica sol, and 1-2 parts of the sodium methyl silicate in sequence; after continuing to stir the mixture for 5 to 10 min, turning on a deslagging device to dis- charge slag balls, thus obtaining mixed slurry.
Preferably, the centrifuging for pipe melding includes: in- jJecting the obtained mixed slurry into a centrifuging drum, turn- ing on a transmission motor of the centrifuging drum to make a ro- tating speed of the centrifuging drum at 600-1000 r/min, perform-
ing centrifuging for 120-240 s, and then extruding a wet billet from the centrifuging drum.
Preferably, the drying for billet correction includes: trans- ferring the obtained wet billet into a microwave dryer for drying at a drying temperature of 105-110°C for 8-10 h to obtain a dried blank, and then grinding rough parts at the edge of the dried bil- let with sand paper to obtain an ultrafine ceramic fiber cotton thermal insulation sleeve finished product.
In the technical solution provided by the present invention, in the production method for the ultrafine ceramic fiber cotton thermal insulation sleeve for the heat transfer pipeline, ul- trafine ceramic fiber cotton, industrial starch, silica sol, and sodium methyl silicate are used as main raw materials, and produc- tion steps include slurry curing, beating and deslagging, centri- fuging for pipe molding, and microwave drying. In this way, con- tinuous full-automatic production is achieved. Referring to the detection standard Acid Cotton for Thermal Insulation and Product thereof GB/T16400-2015, the prepared ultrafine ceramic fiber cot- ton thermal insulation sleeve has a density of 165-186 kg/m’, a hydrophobicity of 99.2%-99.4%, a water absorption per volume of 2.1-2.3%, and a heat conduction coefficient (an average tempera- ture is 70°C or below) of 0.38-0.05 W/(m-K).
DETAILED DESCRIPTION OF THE EMBODIMENTS
In order to make the purposes, technical solutions and ad- vantages of the present invention clearer, the technical solutions of the present invention will be described in detail below. It is apparent that the described embodiments are a part of the embodi- ments of the present invention, not all the embodiments. Based on the embodiments in the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present in- vention.
This specific implementation mode aims to provide a produc- tion method for an ultrafine ceramic fiber cotton thermal insula- tion sleeve for a heat transfer pipeline, ultrafine ceramic fiber cotton, industrial starch, silica sol, and sodium methyl silicate are used as main raw materials, and production steps include slur- ry curing, beating and deslagging, centrifuging for pipe molding, and microwave drying. In this way, continuous full-automatic pro- duction is achieved. In this way, continuous full-automatic pro- duction is achieved. The embodiments are illustrated below. In ad- dition, the embodiments shown below do not limit the content of the invention described in the claims in any way. In addition, all the contents of the configuration shown in the following embodi- ments are not limited to necessarily serving as a solution to the invention described in the claims.
Embodiment 1
As an optional implementation mode, in a specific embodiment of the present invention, the ultrafine ceramic fiber cotton raw material is a fiber with aluminum silicate serving as a main chem- ical component; the fiber has a diameter of 1.5 um and a length of 2 mm; the industrial starch is ordinary commonly used industrial starch with a starch content of 90%; the purity of the silica sol is 90%; and the purity of the sodium methyl silicate is 95%.
As an optional implementation mode, in a specific embodiment of the present invention, the slurry curing includes: the indus- trial starch and water with a water temperature of 5°C are mixed and stirred according to a mass ratio of the industrial starch to water of 1:2 at a stirring rate of 120 r/min for 10 min; after the industrial starch is uniformly dispersed, water with a temperature of 100°C is added according to a mass ratio of the industrial starch to the water of 1:10; and the mixture is continued to be stirred for 10 min to cure the industrial starch, thus obtaining cured slurry.
As an optional implementation mode, in a specific embodiment of the present invention, the beating and deslagging includes: the obtained cured slurry is transferred into a beating tank; water with a water temperature of 5°C is added according to a mass ratio of the industrial starch to water of 1:200; the mixture is contin- ued to be stirred for 10 min; 75 parts of the ultrafine ceramic fiber cotton, 12 parts of the silica sol, and 1 part of the sodium methyl silicate are added in sequence; after the mixture is con-
tinued to be stirred for 10 min, a deslagging device is turned on to discharge slag balls, thus obtaining mixed slurry.
As an optional implementation mode, in a specific embodiment of the present invention, the centrifuging for pipe molding in- 5 cludes: the obtained mixed slurry is injected into a centrifuging drum; a forming mold is immersed into the mixed slurry; a vacuum valve is switched on for vacuum suction filtration at a vacuum de- gree of 0.2 MPa for 90 s; the forming mold is lifted out of the mixed slurry; the vacuum valve is then switched off; and a wet billet is taken out of the forming mold.
As an optional implementation mode, in a specific embodiment of the present invention, the drying for billet correction in- cludes: the obtained wet billet is firstly transferred into a mi- cro dryer for drying at a drying temperature of 105°C for 10 h to obtain a dried billet; rough parts at the edge of the dried billet are polished with sand paper to obtain an ultrafine ceramic fiber cotton thermal insulation sleeve finished product. Referring to the detection standard Acid Cotten for Thermal Insulation and
Product thereof GB/T16400-2015, the prepared ultrafine ceramic fi- ber cotton thermal insulation sleeve has a density of 165 kg/m’, a hydrophobicity of 99.4%, a water absorption per volume of 2.1%, and a heat conduction coefficient (an average temperature is 70°C or below) of 0.38 W/ (mK).
Embodiment 2
As an optional implementation mode, in a specific embodiment of the present invention, the ultrafine ceramic fiber cotton raw material is a fiber with aluminum silicate serving as a main chem- ical component; the fiber has a diameter of 2.0 um and a length of 3 mm; the industrial starch is commonly used industrial starch with a starch content of 95%; the purity of the silica sol is 95%; and the purity of the sodium methyl silicate is 95%.
As an optional implementation mode, in a specific embodiment of the present invention, the slurry curing includes: the indus- trial starch and water with a water temperature of 15°C are mixed and stirred according to a mass ratio of the industrial starch to water of 1:2.5 at a stirring rate of 100 r/min for 8 min; after the industrial starch is uniformly dispersed, water with a temper- ature of 100°C is added according to a mass ratio of the industrial starch to the water of 1:15; and the mixture is continued to be stirred for 8 min to cure the industrial starch, thus obtaining cured slurry.
As an optional implementation mode, in a specific embodiment of the present invention, the beating and deslagging includes: the obtained cured slurry is transferred into a beating tank; water with a water temperature of 15°C is added according to a mass ratio of the industrial starch to water of 1:220; the mixture is contin- ued to be stirred for 8 min; 80 parts of the ultrafine ceramic fi- ber cotton, 14 parts of the silica sol, and 1.5 parts of the sodi- um methyl silicate are added in sequence; after the mixture is continued to be stirred for 8 min, a deslagging device is turned on to discharge slag balls, thus obtaining mixed slurry.
As an optional implementation mode, in a specific embodiment of the present invention, the centrifuging for pipe molding in- cludes: the obtained mixed slurry is injected into a centrifuging drum; a forming mold is immersed into the mixed slurry; a vacuum valve is switched on for vacuum suction filtration at a vacuum de- gree of 0.1 MPa for 60 s; the forming mold is lifted out of the mixed slurry; the vacuum valve is then switched off; and a wet billet is taken out of the forming mold.
As an optional implementation mode, in a specific embodiment of the present invention, the drying for billet correction in- cludes: the obtained wet billet is firstly transferred into a mi- cro dryer for drying at a drying temperature of 110°C for 9 h to obtain a dried billet; rough parts at the edge of the dried billet are polished with sand paper to obtain an ultrafine ceramic fiber cotton thermal insulation sleeve finished product. Referring to the detection standard Acid Cotton for Thermal Insulation and
Product thereof GB/T16400-2015, the prepared ultrafine ceramic fi- ber cotton thermal insulation sleeve has a density of 175 kg/m’, a hydrophobicity of 99.3%, a water absorption per volume of 2.2%, and a heat conduction coefficient (an average temperature is 70°C or below) of 0.43 W/ (mK).
Embodiment 3
As an optional implementation mode, in a specific embodiment of the present invention, the ultrafine ceramic fiber cotton raw material is a fiber with aluminum silicate serving as a main chem- ical component; the fiber has a diameter of 3.0 um and a length of 5 mm; the industrial starch is ordinary industrial commonly used starch with a starch content of 98%; the purity of the silica sol is 98%; and the purity of the sodium methyl silicate is 98%.
As an optional implementation mode, in a specific embodiment of the present invention, the slurry curing includes: the indus- trial starch and water with a water temperature of 25°C are mixed and stirred according to a mass ratio of the industrial starch to water of 1:3 at a stirring rate of 80 r/min for 5 min; after the industrial starch is uniformly dispersed, water with a temperature of 100°C is added according to a mass ratio of the industrial starch to the water of 1:12; and the mixture is continued to be stirred for 5 min to cure the industrial starch, thus obtaining cured slurry.
As an optional implementation mode, in a specific embodiment of the present invention, the beating and deslagging includes: the obtained cured slurry is transferred into a beating tank; water with a water temperature of 25°C is added according to a mass ratio of the industrial starch to water of 1:230; the mixture is contin- ued to be stirred for 5 min; 85 parts of the ultrafine ceramic fi- ber cotton, 16 parts of the silica sol, and 2 parts of the sodium methyl silicate are added in sequence; after the mixture is con- tinued to be stirred for 5 min, a deslagging device is turned on to discharge slag balls, thus obtaining mixed slurry.
As an optional implementation mode, in a specific embodiment of the present invention, the centrifuging for pipe molding in- cludes: the obtained mixed slurry is injected into a centrifuging drum; a forming mold is immersed into the mixed slurry; a vacuum valve is switched on for vacuum suction filtration at a vacuum de- gree of 0 MPa for 30 s; the forming mold is lifted out of the mixed slurry; the vacuum valve is then switched off; and a wet billet is taken out of the forming mold.
As an optional implementation mode, in a specific embodiment of the present invention, the drying for billet correction in- cludes: the obtained wet billet is firstly transferred into a mi- cro dryer for drying at a drying temperature of 110°C for 8 h to obtain a dried billet; rough parts at the edge of the dried billet are polished with sand paper to obtain an ultrafine ceramic fiber cotton thermal insulation sleeve finished product. Referring to the detection standard Acid Cotton for Thermal Insulation and
Product thereof GB/T16400-2015, the prepared ultrafine ceramic fi- ber cotton thermal insulation sleeve has a density of 186 kg/m’, a hydrophobicity of 99.2%, a water absorption per volume of 2.3%, and a heat conduction coefficient (an average temperature is 70°C or below) of 0.05 W/ (mK).
The above descriptions are only specific implementation modes of the present invention, but the protection scope of the present invention is not limited to this. Any changes or replacements that can be easily conceived by those skilled in the art within the technical scope of the present invention shall all fall within the protection scope of the present invention. Therefore, the protec- tion scope of the present invention should be subject to the pro- tection scope of the claims.

Claims (5)

CONCLUSIESCONCLUSIONS 1. Werkwijze voor het produceren van een thermische isolatiehuls van ultrafijn keramisch vezelkatoen voor een pijpleiding voor warmteoverdracht, gekenmerkt door de volgende stappen te omvatten: uitharden van suspensie, kloppen en ontslakken, centrifugeren voor het vormen van pijpen en drogen met microgolven.1. A method of producing an ultra-fine ceramic fiber cotton thermal insulation sleeve for a heat transfer pipeline, characterized by including the following steps: curing of suspension, beating and deslagging, centrifugation for pipe forming and microwave drying. 2. Werkwijze voor het produceren volgens conclusie 1, met het ken- merk, dat het uitharden van de suspensie omvat: het mengen en roe- ren van industrieel zetmeel en water met een watertemperatuur van 5 tot 25 °C volgens een massaverhouding van het industriële zet- meel tot het water van 1:2 tot 1:3 bij een roersnelheid van 80 tot 120 omw/min gedurende 5 tot 10 min; nadat het industriële zet- meel uniform is gedispergeerd, wordt water toegevoegd met een tem- peratuur van 100 °C volgens een massaverhouding van het industri- ele zetmeel tot het water van 1:10 tot 1:12; en het mengsel 5 tot 10 minuten blijven roeren om het industriële zetmeel uit te har- den, waardoor uitgeharde suspensie wordt verkregen.A production method according to claim 1, characterized in that the hardening of the suspension comprises: mixing and stirring industrial starch and water with a water temperature of 5 to 25 °C according to a mass ratio of the industrial starch to water from 1:2 to 1:3 at a stirring speed of 80 to 120 rpm for 5 to 10 minutes; after the industrial starch is uniformly dispersed, water is added at a temperature of 100°C according to a mass ratio of the industrial starch to the water of 1:10 to 1:12; and continue stirring the mixture for 5 to 10 minutes to harden the industrial starch, thereby obtaining hardened suspension. 3. Werkwijze voor het produceren volgens conclusie 1, met het ken- merk, dat het kloppen en ontslakken omvat: het overbrengen van de uitgeharde suspensie die is verkregen volgens conclusie 2 in een kloptank; het aanvullen van water met een watertemperatuur van 5 tot 25 °C volgens een massaverhouding van het industriële zetmeel tot water van 1:200 tot 1:230; blijf het mengsel 5 tot 10 minuten roeren; het toevoegen van 75 tot 85 delen van de ultrafijne kera- mische katoenvezels, 12 tot 16 delen van de silicasol en 1 tot 2 delen van het natriummethylsilicaat in volgorde; nadat het mengsel 5 tot 10 minuten is blijven roeren, wordt een ontslakkingsapparaat ingeschakeld om de slakkenballen te lossen, waardoor een gemengde suspensie wordt verkregen.A production method according to claim 1, characterized in that the beating and deslagging comprises: transferring the hardened suspension obtained according to claim 2 into a beating tank; supplementing water with a water temperature of 5 to 25 °C according to a mass ratio of the industrial starch to water of 1:200 to 1:230; continue stirring the mixture for 5 to 10 minutes; adding 75 to 85 parts of the ultrafine ceramic cotton fibers, 12 to 16 parts of the silica sol and 1 to 2 parts of the sodium methyl silicate in order; After stirring the mixture for 5 to 10 minutes, a deslagging device is turned on to release the slag balls, producing a mixed suspension. 4. Werkwijze voor het produceren volgens conclusie 1, met het ken- merk, dat het centrifugeren voor het vormen van pijpen omvat: het injecteren van de volgens conclusie 3 verkregen gemengde suspensie in een centrifugeertrommel, het aanzetten van een transmissiemotor van de centrifugeertrommel om een rotatiesnelheid van de centrifu- geertrommel op 600-1000 omw/min, centrifugeren gedurende 120-240 s en vervolgens het extruderen van een natte staaf uit de centrifu- getrommel.A production method according to claim 1, characterized in that the centrifugation to form pipes comprises: injecting the mixed suspension obtained according to claim 3 into a centrifuging drum, turning on a transmission motor of the centrifuging drum to produce a rotation speed of the centrifugal drum at 600-1000 rpm, centrifuging for 120-240 s and then extruding a wet rod from the centrifugal drum. 5. Werkwijze voor het produceren volgens conclusie 1, met het ken- merk, dat het drogen voor het corrigeren van de staaf omvat: het overbrengen van de in conclusie 4 verkregen natte staaf in een mi- crogolfdroger om te drogen bij een droogtemperatuur van 105 tot 110 °C gedurende 8 tot 10 uur om een gedroogde blanco te verkrij- gen en vervolgens ruwe delen aan de rand van de gedroogde staaf slijpen met schuurpapier om een thermische isolatiehuls van ultra- fijne keramische vezelkatoen als eindproduct te verkrijgen.A method of production according to claim 1, characterized in that the drying for correcting the rod comprises: transferring the wet rod obtained in claim 4 into a microwave dryer for drying at a drying temperature of 105 to 110°C for 8 to 10 hours to obtain a dried blank, and then grind rough areas on the edge of the dried rod with sandpaper to obtain an ultra-fine ceramic fiber cotton thermal insulation sleeve as a final product.
NL2030947A 2022-02-15 2022-02-15 Production method for ultrafine ceramic fiber cotton thermal insulation sleeve for heat transfer pipeline NL2030947B1 (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111533582A (en) * 2020-04-26 2020-08-14 上海伊索热能技术股份有限公司 Preparation method for removing slag of ceramic fiber
CN111578043A (en) * 2020-05-14 2020-08-25 唐山顺浩环保科技有限公司 Open-close type heat insulation pipeline and preparation method thereof
CN111704397A (en) * 2020-05-18 2020-09-25 唐山顺浩环保科技有限公司 Fireproof material, fireproof door, preparation method and application
CN111546485B (en) * 2020-05-14 2021-08-24 唐山顺浩环保科技有限公司 Conical heat-insulating pipeline and preparation method thereof
CN113800801A (en) * 2020-06-15 2021-12-17 唐山顺浩环保科技有限公司 Ceramic fiber particle and preparation method and application thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111533582A (en) * 2020-04-26 2020-08-14 上海伊索热能技术股份有限公司 Preparation method for removing slag of ceramic fiber
CN111578043A (en) * 2020-05-14 2020-08-25 唐山顺浩环保科技有限公司 Open-close type heat insulation pipeline and preparation method thereof
CN111546485B (en) * 2020-05-14 2021-08-24 唐山顺浩环保科技有限公司 Conical heat-insulating pipeline and preparation method thereof
CN111704397A (en) * 2020-05-18 2020-09-25 唐山顺浩环保科技有限公司 Fireproof material, fireproof door, preparation method and application
CN113800801A (en) * 2020-06-15 2021-12-17 唐山顺浩环保科技有限公司 Ceramic fiber particle and preparation method and application thereof

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