NL2029586B1 - Method for recovery of co2 from chemical solvents and integration with subsequent processes - Google Patents
Method for recovery of co2 from chemical solvents and integration with subsequent processes Download PDFInfo
- Publication number
- NL2029586B1 NL2029586B1 NL2029586A NL2029586A NL2029586B1 NL 2029586 B1 NL2029586 B1 NL 2029586B1 NL 2029586 A NL2029586 A NL 2029586A NL 2029586 A NL2029586 A NL 2029586A NL 2029586 B1 NL2029586 B1 NL 2029586B1
- Authority
- NL
- Netherlands
- Prior art keywords
- gas
- stripping
- hydrogen
- stripping gas
- stripper
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 63
- 239000002904 solvent Substances 0.000 title claims abstract description 38
- 239000000126 substance Substances 0.000 title claims abstract description 27
- 238000011084 recovery Methods 0.000 title description 12
- 230000010354 integration Effects 0.000 title description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 236
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 125
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 110
- 239000007789 gas Substances 0.000 claims abstract description 80
- 239000002594 sorbent Substances 0.000 claims abstract description 37
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 33
- 238000006243 chemical reaction Methods 0.000 claims abstract description 33
- 239000001257 hydrogen Substances 0.000 claims abstract description 33
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 33
- 239000007788 liquid Substances 0.000 claims abstract description 30
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000012528 membrane Substances 0.000 claims abstract description 19
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 16
- 239000000446 fuel Substances 0.000 claims abstract description 11
- 238000000926 separation method Methods 0.000 claims abstract description 6
- 150000001412 amines Chemical class 0.000 claims abstract description 4
- 229910001868 water Inorganic materials 0.000 claims description 23
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 238000005868 electrolysis reaction Methods 0.000 claims description 9
- 150000002431 hydrogen Chemical class 0.000 claims description 7
- 230000005611 electricity Effects 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000004064 recycling Methods 0.000 claims description 3
- 238000003786 synthesis reaction Methods 0.000 claims description 3
- OEERIBPGRSLGEK-UHFFFAOYSA-N carbon dioxide;methanol Chemical compound OC.O=C=O OEERIBPGRSLGEK-UHFFFAOYSA-N 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 13
- 239000000203 mixture Substances 0.000 description 13
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 238000003795 desorption Methods 0.000 description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 5
- 239000008246 gaseous mixture Substances 0.000 description 5
- 238000005984 hydrogenation reaction Methods 0.000 description 5
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 4
- 239000006096 absorbing agent Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000005265 energy consumption Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000003546 flue gas Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 208000018459 dissociative disease Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 238000007210 heterogeneous catalysis Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/12—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1425—Regeneration of liquid absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1475—Removing carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/50—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon dioxide with hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/026—Increasing the carbon monoxide content, e.g. reverse water-gas shift [RWGS]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/204—Amines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/204—Amines
- B01D2252/20405—Monoamines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/204—Amines
- B01D2252/20421—Primary amines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/204—Amines
- B01D2252/20478—Alkanolamines
- B01D2252/20484—Alkanolamines with one hydroxyl group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/10—Nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/22—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/45—Gas separation or purification devices adapted for specific applications
- B01D2259/4525—Gas separation or purification devices adapted for specific applications for storage and dispensing systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/45—Gas separation or purification devices adapted for specific applications
- B01D2259/455—Gas separation or purification devices adapted for specific applications for transportable use
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Analytical Chemistry (AREA)
- Gas Separation By Absorption (AREA)
Claims (8)
- CONCLUSIESL. Werkwijze voor het strippen van koolstofdioxide (CO2) uit een sorbentvloeistof, de werkwijze omvattende: a) hetin een transporteerbaar opslagvat verschaffen van een verrijkte sorbentvloeistof, zoals een amine oplosmiddel waarin CO2 werd geabsorbeerd; b) het verschaffen van een stripgas, omvattende waterstof of stikstof, voor het verwijderen van het geabsorbeerde CO2 uit de verrijkte sorbentvloeistof; «¢) het met het stripgas strippen van het geabsorbeerde CO2 uit de verrijkte sorbentvloeistof teneinde een geregenereerde arme sorbentvloeistof en een CO2 bevattend gas te verkrijgen; d) gebruik maken van het CO2 bevattende gas en het stripgas als voeding voor opvolgende chemische conversie of brandstof producerende stappen: of €) het terugvoeren van het stripgas via een gasmembraanscheidingsstap teneinde een hoogzuivere CO2 stroom te verkrijgen.
- 2. Werkwijze volgens conclusie 1, waarin het stripgas waterstof is en het CO2 bevattende gas. samen met het waterstof, wordt toegevoerd aan een chemisch conversieproces omvattende ten minste één van - CO2 conversie tot methanol CO2 + 3 H2 -> CH30H + 2 H20; - CO2 conversie tot methaan door een Sabatier proces CO2 + 4 H2 => CH4 + 2 H20; - CO2 conversie tot CO door een omgekeerde water gas shift reactie CO2 + H2 -> CO + H20; en - CO2 gebaseerde Fischer-Tropsch synthese teneinde C2+ producten te produceren zoals (iso)paraffines: nCO2 + (3n+1)H2 -> CnH2n+2 + 2nH20.
- 3. Werkwijze volgens conclusie 1 en conclusie 2, waarin het waterstofstripgas is verkregen door elektrolyse van water.
- 4. Werkwijze volgens conclusie 3, waarin de elektrolyse van water elektriciteit gebruikt die afkomstig is van hernieuwbare bronnen, zoals wind en zonne-energie.
- 5. Werkwijze volgens conclusie 1, waarin het CO2 bevattende gas verder wordt gescheiden van het stripgas door een membraansysteem, en een in hoofdzaak zuivere CO2 stroom en in hoofdzaak zuiver stripgas uit genoemde membraansysteem worden afgescheiden, en het terugvoeren van genoemde in hoofdzaak zuiver stripgas aan de stripper.
- 6. Werkwijze volgens één der voorgaande conclusies, waarm de stripstap ¢) wordt uitgevoerd bij een temperatuur lager dan 100°C, met meer voorkeur lager dan 70°C, met nog meer voorkeur lager dan 40°C, en met de meeste voorkeur bij omgevingstemperatuur.
- 7. Werkwijze volgens één der voorgaande conclusies, waarin de stripstap ¢) wordt uitgevoerd bij omgevingsdruk.
- 8. Werkwijze volgens één der voorgaande conclusies, waarm de stripstap ¢) wordt uitgevoerd met een strippereenheid, bij voorkeur zonder een reboiler en/of condensereenheid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL2029586A NL2029586B1 (en) | 2021-11-02 | 2021-11-02 | Method for recovery of co2 from chemical solvents and integration with subsequent processes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL2029586A NL2029586B1 (en) | 2021-11-02 | 2021-11-02 | Method for recovery of co2 from chemical solvents and integration with subsequent processes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL2029586B1 true NL2029586B1 (en) | 2023-06-01 |
Family
ID=79831430
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL2029586A NL2029586B1 (en) | 2021-11-02 | 2021-11-02 | Method for recovery of co2 from chemical solvents and integration with subsequent processes |
Country Status (1)
| Country | Link |
|---|---|
| NL (1) | NL2029586B1 (nl) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000069774A1 (en) * | 1999-05-14 | 2000-11-23 | Texaco Development Corporation | Hydrogen recycle and acid gas removal using a membrane |
| WO2016094036A1 (en) * | 2014-12-10 | 2016-06-16 | Exxonmobil Research And Engineering Company | Gas-assisted stripping of liquid solvents for carbon capture |
| WO2017205044A1 (en) * | 2016-05-26 | 2017-11-30 | X Development Llc | Method for efficient co2 degasification |
| US20180243685A1 (en) * | 2017-02-27 | 2018-08-30 | Honeywell International Inc. | Dual stripper with water sweep gas |
| DE102019000803A1 (de) * | 2019-02-05 | 2020-08-06 | Hans-Jürgen Maaß | Verfahren zur Erzeugung von Synthesegas |
| JP2021130633A (ja) * | 2020-02-20 | 2021-09-09 | 株式会社タクマ | メタン製造方法、メタノール製造方法、メタン製造設備、及びメタノール製造設備 |
-
2021
- 2021-11-02 NL NL2029586A patent/NL2029586B1/en active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000069774A1 (en) * | 1999-05-14 | 2000-11-23 | Texaco Development Corporation | Hydrogen recycle and acid gas removal using a membrane |
| WO2016094036A1 (en) * | 2014-12-10 | 2016-06-16 | Exxonmobil Research And Engineering Company | Gas-assisted stripping of liquid solvents for carbon capture |
| WO2017205044A1 (en) * | 2016-05-26 | 2017-11-30 | X Development Llc | Method for efficient co2 degasification |
| US20180243685A1 (en) * | 2017-02-27 | 2018-08-30 | Honeywell International Inc. | Dual stripper with water sweep gas |
| DE102019000803A1 (de) * | 2019-02-05 | 2020-08-06 | Hans-Jürgen Maaß | Verfahren zur Erzeugung von Synthesegas |
| JP2021130633A (ja) * | 2020-02-20 | 2021-09-09 | 株式会社タクマ | メタン製造方法、メタノール製造方法、メタン製造設備、及びメタノール製造設備 |
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| HC | Change of name(s) of proprietor(s) |
Owner name: VALUE GROUP B.V.; NL Free format text: DETAILS ASSIGNMENT: CHANGE OF OWNER(S), CHANGE OF OWNER(S) NAME; FORMER OWNER NAME: WFU B.V. Effective date: 20240322 |