NL2007304C2 - Use of perfume composition as fuel for internal combustion engines. - Google Patents
Use of perfume composition as fuel for internal combustion engines. Download PDFInfo
- Publication number
- NL2007304C2 NL2007304C2 NL2007304A NL2007304A NL2007304C2 NL 2007304 C2 NL2007304 C2 NL 2007304C2 NL 2007304 A NL2007304 A NL 2007304A NL 2007304 A NL2007304 A NL 2007304A NL 2007304 C2 NL2007304 C2 NL 2007304C2
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- NL
- Netherlands
- Prior art keywords
- perfume composition
- group
- agents
- fuel
- perfume
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
- C10L1/023—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/305—Octane number, e.g. motor octane number [MON], research octane number [RON]
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Fats And Perfumes (AREA)
Abstract
The present invention relates to fuel compositions containing perfume fractions, that is to say compositions of fragrance materials, and to the use of such perfume fractions containing fuel compositions to provide a fuel for internal combustion engines and burners. According to the present fuel composition for internal combustion engines and burners on basis of ethanol, wherein said fuel composition contains 1 -40 vol. % of a perfume fraction, based on the total fuel composition, said perfume fraction is constituted of one or more additives selected from a group consisting of essential oils, aroma compounds and aromatic oxygenates, the Volumetric Higher Heating Value (HHV), measured according to ASTM D240, of said perfume fraction is higher than or equal to 33,0 MJ/litre.
Description
Title: Use of perfume composition as fuel for internal combustion engines.
The present invention relates to perfume compositions, that is to say compositions of fragrance materials, and to the use of such perfume compositions to 5 provide a fuel for internal combustion engines and burners.
EP-B-3172, US-A-4304679, US-A-4322308, US-A-4278658, US-A-4134838, US-A-4288341, US-A-4289641 and US-A-4663068 all describe perfume compositions. A difficulty with the perfume compositions disclosed in these documents is that they include components which limit their use in combustion 10 processes. One aspect is that these perfume compositions posses a very low caloric value due to the presence of water and ethanol as solvents. In addition to that, the water component in the perfume composition shows a corrosion inducing behaviour, which makes the perfume composition unsuitable for use in engines. Furthermore, the perfume compositions are of polar nature which is also not favourable for use as 15 a fuel in internal combustion engines and burners.
One object of the present invention is to provide a perfume composition which can be used as a fuel for internal combustion engines and burners.
One object of the present invention is provide a perfume 20 composition in which the portion of water as a co solvent is reduced to such a level that the perfume composition is suitable for use as a fuel in internal combustion engines and burners.
One object of the present invention is provide a perfume composition that still has its own characteristic odour but can be used as a fuel for 25 internal combustion engines and burners.
Another object of the present invention is provide a perfume composition that can be used as a fuel for internal combustion engines and burners, wherein the safety, stability and durability of the internal combustion engines and burners, in which these perfume compositions are to be used, are guaranteed.
30 The present invention is characterized by the use of a perfume composition as a fuel for internal combustion engines and burners, in which 1,5-30 wt. % of the perfume composition is constituted of one or more substances which are selected from group consisting of essential oils and aroma compounds and 2 the remainder is selected from the group of gasoline, kerosene, heating oil, jet fuel, diesel, bio diesel and E85 (ethanol/gasoline blend).
One or more of the aforementioned objects are achieved by such a perfume composition. Especially, the presence of one or more fuels selected from 5 the group of gasoline, kerosene, heating oil, jet fuel, diesel, bio diesel and E85 (ethanol/gasoline blend) is essential for obtaining the required caloric value and combustion properties. And the presence of essential oils and aroma compounds will have the effect of maintaining the characteristic odour of the perfume itself.
Examples of fuels to be used in the present perfume compositions 10 are motor fuels, in particular gasoline to DIN EN 228, kerosene and in particular aviation gasoline to ASTM D910 grade 100 LL or jet fuel such as Jet A-1 or Jet B, and diesel, in particular to DIN EN 590, formerly DIN 51 60, and heating oil. The so called bio diesel, i.e. diesel originating from organic resources, is also preferred. The "middle distillates" which, at standard pressure (1013 mbar), have a boiling range of 15 180 to 360[deg.j C., can be used as well.
In a preferred embodiment of the invention the perfume composition comprises a proportion of 15 - 30 wt. %, relative to the perfume composition, of one or more substances which are selected from group consisting of essential oils and aroma compounds. Such a perfume composition can be classified as eau de parfum.
20 In another embodiment of the present invention the perfume composition comprises a proportion of 8 - 15 wt. %, relative to the perfume composition, of one or more substances which are selected from group consisting of essential oils and aroma compounds. Such a perfume composition can be classified as eau de toilette.
25 According to another embodiment the perfume composition comprises a proportion of 4 - 8 wt. %, relative to the perfume composition, of one or more substances which are selected from group consisting of essential oils and aroma compounds. Such a perfume composition can be classified as eau de cologne.
30 Furthermore, in a preferred embodiment of the present invention the perfume composition comprises a proportion of 1,5 - 4 wt. %, relative to the perfume composition, of one or more substances which are selected from group consisting of essential oils and aroma compounds. Such a perfume composition can be classified 3 as splash cologne.
Additives are admixtures, active ingredients or active ingredient mixtures which, in motor or combustion fuels and lubricants, enhance desired properties, suppress unwanted properties or exert novel effects. For example, in the 5 case of motor fuels, the engine intake system may be kept clean and deposits prevented in the engine or the ageing resistance of lubricant oils may be extended. Reducing exhaust gas pollutant emissions and preventing the corrosion of metal parts in the fuel system are further desired actions of additives.
In a preferred embodiment the perfume compositions according to 10 the present invention further comprise a proportion of 0,1 - 10 wt. %, relative to the perfume composition, of one or more substances which are selected from group consisting of pigments, dyes, colorants, cetane improvers, soot particle emission reducing agents, flow promoters, filterability improvers, antioxidants, corrosion inhibitors, antifoam agents, ignition accelerators, stabilizers, antiknock agents, 15 carburettor antiicing additives, antideposition agents, antismoke agents, biocides, lubricity improvers, antiwear agents, fixatives and viscosity improvers.
Specific examples of the aforementioned additives are: flow promoters (flow improvers, antisettling agents, for example in diesel fuel, Wax AntiSettling Additives (WASA), for example polyolefins, chlorinated polyethylenes, 20 ethylene/propylene copolymers, low molecular weight copolymers such as ethylene/vinyl acetate copolymers), filterability improvers (for example relatively high molecular weight chlorinated hydrocarbons such as for example condensation products of naphthalene and chlorinated paraffins, copolymers based on ethylene with in each case acrylic and methacrylic acid esters, maleic acid diesters, alcohols 25 or vinyl acetate), metal deactivators (usually chelating agents, for example 1,3-bis-(2-hydroxybenzylideneamino)propane=N,N'-disalicylidene-1,2-diaminopropan e), antioxidants (oxidation inhibitors, for example phenol derivatives such as p-aminophenol, 2,6-di-tert.-butyl-4-methylphenol (BHT), phenylenediamine, naphthalene derivatives such as naphthylamine, 1,3-bis-(2-hydroxy-30 benzylideneamino)propane), corrosion inhibitors (for example naphthenoic acid sodium salt, mixtures of (2-ethylhexyl)-(3-methylbutyl) phosphate and C14-C16 amines, 2-(2-(2-ethylhexyl)-phenoxyl)-1,1,2,2-tetraethoxyethanol, ethylenediamine dinonylnaphthalenesulfonate, mixtures of polymerized linoleic acid, polymerized 4 methyllinoleic acid and organic phosphorus compounds, hydrazine, oleamides), ignition accelerators (cetane number improvers, for example amyl nitrate, cyclohexyl nitrate, 2-ethylhexyl nitrate, nitrobenzene), detergents (for example benzenesulfonic acid sodium salt, alkyl substituted succinimides such as for example polyisobutenyl 5 succinic acid derivatives, alkyl substituted carbamides, polyisobuteneamines/ polyisobutenepolyamines, amines), particulate-reducing substances, stabilizers (in particular for diesel) (for example long-chain or cyclic amines such as N,N-dimethylcyclohexylamine), antiknock agents (for example tert.-butyl alcohol, isobutyl alcohol, MTBE, ETBE, TAME, N-methylaniline, methanol), carburetor 10 antiicing additives (icing inhibitors, for example ethanol, isopropanol, dimethylformamide, dimethylacetamide, dipropylene glycol, diethylene glycol monomethyl ether, organic phosphorus compounds, glycerol esters of fatty acids, formamides, imidazolines), antideposition agents (antipreignition agents, for example 1,2-dibromoethane, cresyl diphenyl phosphate, tricresyl phosphate, tricresyl 15 phosphate, trimethyl phosphite, trichloroethyl phosphate, boric acid esters), antismoke agents (combustion aids, smoke-reducing agents, for example barium naphthalenesulfonate, barium carbonate, lead naphthenate, tetraethyl lead, calcium sulfonate, manganese naphthenate, nickel carbonyl, methylcyclopentadienyl manganese tricarbonyl, ferrocene, butyl hydroperoxide, nitropropane, ethyl nitrate), 20 biocides, lubricity improvers, antiwear agents, dyes, color stabilizers, and viscosity improvers.
Preferred examples of essential oils are selected from group (i) consisting of Basil, Bay, Balsam Peru, Bergamot, Black Pepper, Cassia, Cajuput, Cardamom, Cedarwood, Cinnamon, Chamomile, Cinnamon, Clary Sage, Cypress, 25 Clove, Coriander, Fennel, Frankincense, Eucalyptus, Geranium, Ginger, Grapefruit, Ho Leaf, Jasmine, Hyssop, Ho Wood, Myrrh, Lemon, Hyssop, Neroli, Lemongrass, Juniper, Oakmoss, Lime, Lavender, Patchouli, Mandarin/Tangerine, Marjoram, Rose, Neroli, Melissa, Rosewood, Verbena, Myrtle, Sandalwood, Niaouli, Nutmeg, Valerian, Orange,, Palma, Rosa, Vanilla, Peppermint, Pine, Vetiver, Petitgrain, Rosemary, 30 Ylang Ylang, Ravensara, Spikenard, Sage, Yarrow, Spearmint, Tagetes, Tangerine, Tea Tree, Thyme.
Preferred examples of aroma compounds are selected from group (ii) consisting of Methyl formate, Methyl acetate, Methyl butyrate, Methyl butanoate, 5
Ethyl acetate, Ethyl butyrate, Ethyl butanoate, Isoamyl acetate, Pentyl butyrate, Pentyl butanoate, Pentyl pentanoate, Octyl acetate, Myrcene, Geraniol Rose, Nerol Sweet rose, Citral, Citronellal, Citronellol, Linalool, Nerolidol, Limonene, Camphor, Terpineol, alphalonone, Thujone, Benzaldehyde, Eugenol, Cinnamaldehyde, Ethyl 5 maltol, Phenyl Ethanol, Vanillin, Anisole, Anethole, Estragole, Thymol, gamma-Decalactone, gamma-Nonalactone, delta-Octalactone, Jasmine lactone, Massoia lactone, Wine lactone, Sotolon, Dihydrojasmone.
Preferred examples of fixatives are selected from the group consisting of Ambergris, sandalwood, musk, vetiver, orris root, and bergamot orange. 10 These fixatives will reduce the evaporation rate and improve the stability. So the final perfume composition will last longer while keeping its original fragrance.
The present invention will now be explained by Examples according to the invention and comparative examples. The invention is by no means restricted to the values and components used in the Examples.
15 Comparative Example 1
The caloric value of perfume composition qualified as an Eau de Toilette with a fruity apple - pineapple scent was measured before testing the perfume composition in an internal combustion engine. The caloric value measured was far below the lower limit of a fuel to be qualified as a fuel suitable for internal 20 combustion engine. The solvent used was a mixture of 30/70 water/ethanol on volume% basis.
Comparative Example 2
The caloric value of perfume composition qualified as an Eau de Toilette with a fruity apple - pineapple scent was measured before testing the 25 perfume composition in an internal combustion engine. The caloric value measured was far below the lower limit of a fuel to be qualified as a fuel suitable for internal combustion engine. The solvent used was a mixture of 30/70 water/ethanol on volume% basis.
Example 1 30 A fuel mixture for gasoline engine that qualifies as an Eau de
Toilette with a fruity apple - pineapple scent comprising 92 vol-% of combustible solvent = E85 (i.e. commercial ethanol/gasoline blend) and 8 vol-% of aroma compound = Methyl butyrate was tested as a fuel in an internal combustion engine.
6
The performance of the engine was comparable with the performance of the same engine running without the fragrance.
Example 2: A fuel mixture for diesel engine that qualifies as an Eau de Parfum 5 with a rosy scent 80 vol-% combustible solvent = RME (i.e. Rapeseed Methyl Ester, a commercial biodiesel) and 20 vol-% essential oil = rose oil was tested as a fuel in a diesel engine. The performance of the engine was comparable with the performance of the same engine running without the fragrance.
Altough the Examples disclosed herein only comprise one essential 10 oil or aromatic compound, it is clear that combinations of several essential oils and aromatic compounds can be used in th present perfume composition.
15
Claims (9)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL2007304A NL2007304C2 (en) | 2011-08-26 | 2011-08-26 | Use of perfume composition as fuel for internal combustion engines. |
PCT/NL2012/050584 WO2013032321A1 (en) | 2011-08-26 | 2012-08-24 | Use of a perfume composition as a fuel for internal combustion engines |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL2007304 | 2011-08-26 | ||
NL2007304A NL2007304C2 (en) | 2011-08-26 | 2011-08-26 | Use of perfume composition as fuel for internal combustion engines. |
Publications (1)
Publication Number | Publication Date |
---|---|
NL2007304C2 true NL2007304C2 (en) | 2013-02-27 |
Family
ID=46881139
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NL2007304A NL2007304C2 (en) | 2011-08-26 | 2011-08-26 | Use of perfume composition as fuel for internal combustion engines. |
Country Status (2)
Country | Link |
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NL (1) | NL2007304C2 (en) |
WO (1) | WO2013032321A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20190067461A (en) * | 2017-12-07 | 2019-06-17 | 주식회사 한빛에너지 | A method of fueling waste oil using a combustion promoting additive |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105249390B (en) * | 2015-09-07 | 2018-10-16 | 江南大学 | A kind of Chinese prickly ash cooking wine and preparation method thereof |
CN106266685B (en) * | 2016-08-27 | 2019-11-12 | 广东罗浮山国药股份有限公司 | A kind of compound essential oil and preparation method thereof |
CN111607440A (en) * | 2020-05-27 | 2020-09-01 | 四川中融雷科汽车科技有限公司 | Nano-material diesel combustion improver and preparation method thereof |
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-
2011
- 2011-08-26 NL NL2007304A patent/NL2007304C2/en not_active IP Right Cessation
-
2012
- 2012-08-24 WO PCT/NL2012/050584 patent/WO2013032321A1/en active Application Filing
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20190067461A (en) * | 2017-12-07 | 2019-06-17 | 주식회사 한빛에너지 | A method of fueling waste oil using a combustion promoting additive |
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WO2013032321A1 (en) | 2013-03-07 |
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