NL179047C - PROCESS FOR THE PREPARATION OF S-TRIMETHOXY-BENZENE. - Google Patents

PROCESS FOR THE PREPARATION OF S-TRIMETHOXY-BENZENE.

Info

Publication number
NL179047C
NL179047C NLAANVRAGE7415674,A NL7415674A NL179047C NL 179047 C NL179047 C NL 179047C NL 7415674 A NL7415674 A NL 7415674A NL 179047 C NL179047 C NL 179047C
Authority
NL
Netherlands
Prior art keywords
benzene
carbon atoms
trimethoxy
preparation
5trihalo
Prior art date
Application number
NLAANVRAGE7415674,A
Other languages
Dutch (nl)
Other versions
NL179047B (en
NL7415674A (en
Original Assignee
Oce Andeno Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oce Andeno Bv filed Critical Oce Andeno Bv
Publication of NL7415674A publication Critical patent/NL7415674A/en
Publication of NL179047B publication Critical patent/NL179047B/en
Application granted granted Critical
Publication of NL179047C publication Critical patent/NL179047C/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/16—Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A 1,3,5-trialkoxy benzene having 1-3 carbon atoms in each of the alkoxy-groups is prepared at high overall yields, with minimal formation of hazardous or polluting by-products by reacting a 1,3,5trihalo benzene, for example 1,3,5-tribromo benzene with an alkalimetal alcoholate having 1-3 carbon atoms in the molecule in the presence of a copper salt, e.g. cuprous iodide or cupric chloride, and an aprotic solvent such as e.g. dimethylformamide. The product is readily recovered from the reaction mixture in an overall yield as high as 90%.
NLAANVRAGE7415674,A 1973-12-11 1974-12-02 PROCESS FOR THE PREPARATION OF S-TRIMETHOXY-BENZENE. NL179047C (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB5742873 1973-12-11

Publications (3)

Publication Number Publication Date
NL7415674A NL7415674A (en) 1975-06-13
NL179047B NL179047B (en) 1986-02-03
NL179047C true NL179047C (en) 1986-07-01

Family

ID=10479169

Family Applications (1)

Application Number Title Priority Date Filing Date
NLAANVRAGE7415674,A NL179047C (en) 1973-12-11 1974-12-02 PROCESS FOR THE PREPARATION OF S-TRIMETHOXY-BENZENE.

Country Status (5)

Country Link
JP (1) JPS5749526B2 (en)
CA (1) CA1041554A (en)
DE (1) DE2458191C3 (en)
FR (1) FR2253729A1 (en)
NL (1) NL179047C (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL49803A (en) * 1975-06-28 1979-11-30 Fisons Ltd Preparation of pyrogallol
JPS5553229A (en) * 1978-10-13 1980-04-18 Otsuka Chem Co Ltd Preparation of alkoxyphenol compound

Also Published As

Publication number Publication date
NL179047B (en) 1986-02-03
CA1041554A (en) 1978-10-31
FR2253729B1 (en) 1978-05-05
DE2458191C3 (en) 1978-06-01
JPS5749526B2 (en) 1982-10-22
FR2253729A1 (en) 1975-07-04
JPS50100032A (en) 1975-08-08
DE2458191B2 (en) 1977-10-06
NL7415674A (en) 1975-06-13
DE2458191A1 (en) 1975-06-19

Similar Documents

Publication Publication Date Title
EP0307934B1 (en) Process for the preparation of tricyclo 8.2.2.2. hexadeca 4,6,10,12,13,15 hexaene chlorinated in the benzenic rings
Félix et al. Regiospecific Synthesis of Mono‐and Polyiodo Derivatives of Benzene
KR840002405A (en) Method for preparing cephalosporin
Jun-ichi et al. Quarternary ammonium fluoride. A reagent for proton abstraction
Commercon et al. Substitution of vinylic iodides by various copper (I) and copper (II) derivatives
Bailey et al. Pyrolysis of Esters. I. Selectivity in the Direction of Elimination by Pyrolysis1
Oae et al. Direct Conversion of Arylamines to the Corresponding Halides, Biphenyls and Sulfides with t-butyl Thionitrate
US4102933B1 (en)
NL179047C (en) PROCESS FOR THE PREPARATION OF S-TRIMETHOXY-BENZENE.
VAITIEKUNAS et al. STUDIES ON THE CHEMISTRY OF HETEROCYCLICS. XXIV. 1 PREPARATION OF THIENYLACETYLENES
Wang et al. Novel reductive coupling cyclization of 1, 1-dicyanoalkenes promoted by metallic samarium in aqueous media
Bender et al. Preparation and Crystal Structure of Pd2Mo2 (η5‐C5H5) 2 (μ3‐CO) 2 (μ2‐CO) 4 (PEt3) 2. A Planar, Triangulated, Palladium‐Molybdenum‐Carbonyl Cluster
US3397214A (en) Process of reacting tetraalkylallene with palladous halide
Larson et al. A facile synthesis of symmetrical 1, 1-disubstituted ethylenes
Woods et al. Reactions of Several 4-Pyrones Catalyzed by Potassium Acetate and Trifluoroacetic Acid
US3689573A (en) Process for the preparation of cyclopent-2-enyl phenols
GB1414111A (en) Chlorination of butadiene
EP0110177A2 (en) Substituted cyclopentadienyl cobalt complexes and synthesis of pyridine homologues by means of the complexes
Keyaniyan et al. Convenient syntheses of dichloroethenylidenecyclopropanes: precursors to difunctional cyclopropane derivatives
US4140695A (en) Process for producing copper phthalocyanines
US3338960A (en) Preparation of halogenated unsaturated acids
GB1071309A (en) Production of 2-silamorpholine derivatives
Uemura et al. Preparation of some alkylthallium (III) dichlorides and their reactions with potassium and copper halides.
Zhu et al. PREPARATION OF 2-SUBSTITUTED ETHYL PERFLUOROALKYLSULFONES
Tsutsui et al. Proximity Effect in Arene Pi-Complex Formation

Legal Events

Date Code Title Description
BA A request for search or an international-type search has been filed
BA A request for search or an international-type search has been filed
BB A search report has been drawn up
BC A request for examination has been filed
A85 Still pending on 85-01-01
SNR Assignments of patents or rights arising from examined patent applications

Owner name: STAMICARBON B.V.

V1 Lapsed because of non-payment of the annual fee