NL1015112C1 - Adsorbent / desorbent heat exchanger. - Google Patents

Adsorbent / desorbent heat exchanger. Download PDF

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Publication number
NL1015112C1
NL1015112C1 NL1015112A NL1015112A NL1015112C1 NL 1015112 C1 NL1015112 C1 NL 1015112C1 NL 1015112 A NL1015112 A NL 1015112A NL 1015112 A NL1015112 A NL 1015112A NL 1015112 C1 NL1015112 C1 NL 1015112C1
Authority
NL
Netherlands
Prior art keywords
heat exchanger
ribs
adsorbent
desorbent
granulate
Prior art date
Application number
NL1015112A
Other languages
Dutch (nl)
Inventor
Rainer Dr Lang
Manfred Dr Roth
Marc Stricker
Original Assignee
Vaillant Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vaillant Bv filed Critical Vaillant Bv
Application granted granted Critical
Publication of NL1015112C1 publication Critical patent/NL1015112C1/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B35/00Boiler-absorbers, i.e. boilers usable for absorption or adsorption
    • F25B35/04Boiler-absorbers, i.e. boilers usable for absorption or adsorption using a solid as sorbent
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/003Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using thermochemical reactions
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/0056Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using solid heat storage material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/27Relating to heating, ventilation or air conditioning [HVAC] technologies
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14Thermal energy storage

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sorption Type Refrigeration Machines (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)

Description

- 1 -- 1 -

Adsorbeer-/desorbeerwanntewisselaarAdsorbent / desorbent heat exchanger

De uitvinding heeft betrekking op een adsorbeer/-desorbeerwarmtewisselaar volgens de kop van conclusie 1.The invention relates to an adsorbent / desorbent heat exchanger according to the preamble of claim 1.

5 Bij bekende dergelijke adsorbeer-/desorbeerwarmte- wisselaars is een buis ingebed in granulaat.In known such adsorber / desorber heat exchangers, a tube is embedded in granulate.

Bij dergelijke warmtewisselaars doet zich het nadeel voor, dat door het slechte geleidingsvermogen van het adsorbens en de hoge diffusieweerstand in de storting 10 het sorptieproces slechts heel langzaam en zeer oneffectief verloopt.The disadvantage of such heat exchangers is that the sorption process is very slow and very ineffective due to the poor conductivity of the adsorbent and the high diffusion resistance in the deposit 10.

Doel van de uitvinding is, dit nadeel te vermijden en een adsorbeer-/desorbeerwarmtewisselaar van de in de inleiding genoemde soort te verschaffen, waarbij een snel 15 verloop«van het sorptieproces wordt gegarandeerd.The object of the invention is to avoid this drawback and to provide an adsorber / desorber heat exchanger of the type mentioned in the introduction, whereby a rapid course of the sorption process is guaranteed.

Volgens de uitvinding wordt dit bereikt met een warmtewisselaar van de in de inleiding vermelde soort door de karakteristieke kenmerken van conclusie 1.According to the invention this is achieved with a heat exchanger of the type mentioned in the preamble due to the characteristic features of claim 1.

Door de voorgestelde maatregelen wordt bereikt, 20 dat enerzijds het warmtewisselende oppervlak van de buis wordt vergroot en tussen de afzonderlijke ribben slechts een storting in één laag mogelijk is. Daardoor kan het sorptieproces ondanks het slechte warmtegeleidingsvermogen en ondanks de grote diffusieweerstand van het adsorbens 25 snel en effectief verlopen. Daarbij is een groot stofuitwissel ingsoppervlak voor de adsorptie en desorptie van het adsorbaat, b.v. water, aanwezig en kan de warmte door het directe contact met de ribbe snel met de warmtedrager, die in de buis stroomt, worden uitgewisseld.It is achieved by the proposed measures that on the one hand the heat-exchanging surface of the tube is increased and only one layer is possible to deposit between the individual ribs. Therefore, the sorption process can proceed quickly and effectively despite the poor thermal conductivity and despite the great diffusion resistance of the adsorbent. In addition, a large dust exchange area for the adsorption and desorption of the adsorbate, e.g. water, and the heat can be quickly exchanged by the direct contact with the rib with the heat carrier flowing in the tube.

30 Door de voorgestelde maatregelen wordt ook een hoog warmtegetal van de sorptiewarmtepomp bij gelijktijdig goede vermogensdichtheid bereikt.The proposed measures also achieve a high heat number of the sorption heat pump while at the same time good power density.

In dat verband is het gunstig de kenmerken van conclusie 2 aan te houden.In that regard, it is advantageous to maintain the features of claim 2.

35 Door de kenmerken van conclusie 3 wordt een zeer eenvoudige vervaardiging van een adsorbeer-/desorbeerwarm-tewisselaar volgens de uitvinding mogelijk gemaakt.The features of claim 3 enable a very simple manufacture of an adsorbent / desorbent heat exchanger according to the invention.

De uitvinding wordt nu aan de hand van de teke- 1015112 .The invention is now described with reference to the drawings 1015112.

- 2 - ning, die schematisch een warmtewisselaar volgens de uitvinding toont, nader toegelicht.- 2, which schematically shows a heat exchanger according to the invention, further explained.

De weergegeven adsorbeer~/desorbeerwarmtewisselaar is voorzien van een door een warmteopnemend medium door-5 stroombare buis 1. Deze buis 1 is voorzien van ribben 2 en staat met deze in een goed geleidende verbinding.The shown adsorber / desorber heat exchanger is provided with a pipe 1 which can flow through a heat-absorbing medium. This pipe 1 is provided with ribs 2 and is in a well-conducting connection with it.

Tussen de afzonderlijke ribben 2 is granulaat 4 telkens in één laag aangebracht, waarbij de korrelgrootte van het granulaat iets kleiner is dan de vrije afstand 5 10 tussen twee ribben. Daardoor wordt gegarandeerd, dat er tussen elke twee ribben 2 maar één laag granulaat aanwezig is, waarbij het in het gunstige geval om een zeoliet gaat.Granulate 4 is arranged in one layer between the individual ribs 2, the grain size of the granulate being slightly smaller than the free distance between two ribs. This ensures that there is only one layer of granulate between every two ribs 2, which is advantageously a zeolite.

In het gebied van de ribben 2 is de warmtewisselaar omgeven door een net 3, dat het er uit vallen van het 15 granulaat 4 verhindert. Voor de borging van net 3 is dat omwikkeld met een band 6.In the region of the ribs 2, the heat exchanger is surrounded by a net 3, which prevents the granulate 4 from falling out. To secure net 3, this is wrapped with a band 6.

10151121015112

Claims (3)

1. Adsorbeer-/desorbeerwarmtewisselaar met een door 5 granulaat (4) omgeven, door een warmteopnemend medium doorstroombare buis (1), met het kenmerk, dat buis (1) is voorzien van ribben (2), die van elkaar staan op een afstand, die kleiner is dan de dubbele korrelgrootte van granulaat (4), b.v. een zeoliet, en de ruimte tussen de 10 ribben (2) is opgevuld met in één laag aangebracht granulaat (4), waarbij de ribben (2) zijn omgeven door een net (3).Adsorbent / desorbent heat exchanger with a pipe (1) surrounded by a granulate (4) and flowable through a heat-absorbing medium, characterized in that pipe (1) is provided with ribs (2) which are spaced apart , which is smaller than the double grain size of granulate (4), e.g. a zeolite, and the space between the 10 ribs (2) is filled with granulate (4) applied in one layer, the ribs (2) being surrounded by a net (3). 2. Warmtewisselaar volgens conclusie 1, met het kenmerk, dat de hoogte tussen de ribben (4) overeenkomt met 15 het drie- tot vijfvoudige van de afstand tussen de ribben.Heat exchanger according to claim 1, characterized in that the height between the ribs (4) corresponds to three to five times the distance between the ribs. 3. Warmtewisselaar volgens conclusie 1 of 2, met het kenmerk, dat de ribben (2) zijn uitgevoerd als spiraalrib-be. 1015 112Heat exchanger according to claim 1 or 2, characterized in that the ribs (2) are designed as a spiral rib. 1015 112
NL1015112A 1999-05-25 2000-05-04 Adsorbent / desorbent heat exchanger. NL1015112C1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AT91299 1999-05-25
AT0091299A AT407568B (en) 1999-05-25 1999-05-25 ADSORBER / DESORBER HEAT EXCHANGER

Publications (1)

Publication Number Publication Date
NL1015112C1 true NL1015112C1 (en) 2000-11-28

Family

ID=3502705

Family Applications (1)

Application Number Title Priority Date Filing Date
NL1015112A NL1015112C1 (en) 1999-05-25 2000-05-04 Adsorbent / desorbent heat exchanger.

Country Status (4)

Country Link
AT (1) AT407568B (en)
CH (1) CH690793A5 (en)
DE (1) DE10024793B4 (en)
NL (1) NL1015112C1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT411551B (en) * 2000-04-17 2004-02-25 Vaillant Gmbh Adsorber / desorber heat exchanger
AT409186B (en) * 2000-08-18 2002-06-25 Vaillant Gmbh Adsorber / desorber heat exchanger
AT410716B (en) * 2001-02-23 2003-07-25 Vaillant Gmbh ADSORBER / DESORBER FOR A ZEOLITH HEATER
AT412506B (en) * 2001-08-22 2005-03-25 Vaillant Gmbh Absorption or desorption module in form of container has screen element between heat exchanger and absorber/desorber; container consists of stainless steel or steam resistant ceramic
DE102005000022A1 (en) * 2005-03-16 2006-09-28 Füsting, Bernd Sorbent molding, method of manufacture and use
DE102008055699A1 (en) 2007-11-09 2009-10-15 Vaillant Gmbh Sorber heat exchanger of an adsorption heat pump
DE202007016166U1 (en) 2007-11-16 2008-07-10 Hellwig, Udo, Prof. Dr. composite body
DE102010004344A1 (en) 2010-01-11 2011-07-14 Viessmann Werke GmbH & Co KG, 35108 Coating process and adsorber element
DK178553B1 (en) 2014-04-25 2016-06-13 Teknologisk Inst Temperature fluctuation and temperature gradient resistant coating composition having also corrosion inhibiting properties, method for making the coating and use thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5441716A (en) * 1989-03-08 1995-08-15 Rocky Research Method and apparatus for achieving high reaction rates
DE4405669A1 (en) * 1994-02-23 1995-08-24 Zeolith Tech Adsorbent coating on metals and method of manufacture
DE19730697A1 (en) * 1997-07-17 1999-01-21 Buderus Heiztechnik Gmbh Adsorption heat pump using zeolite heat exchanger
DE19902695B4 (en) * 1998-01-21 2016-01-07 Vaillant Gmbh Sorption heat pump with an ad / desorber heat exchanger

Also Published As

Publication number Publication date
AT407568B (en) 2001-04-25
CH690793A5 (en) 2001-01-15
DE10024793B4 (en) 2007-05-16
ATA91299A (en) 2000-08-15
DE10024793A1 (en) 2001-02-01

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Effective date: 20060504