MY197243A - Synthesis of two-dimensional supramolecular compounds based on 1,3,5-tri (4-carbonylphenoxybenzene) benzene and its method and application - Google Patents
Synthesis of two-dimensional supramolecular compounds based on 1,3,5-tri (4-carbonylphenoxybenzene) benzene and its method and applicationInfo
- Publication number
- MY197243A MY197243A MYPI2022001790A MYPI2022001790A MY197243A MY 197243 A MY197243 A MY 197243A MY PI2022001790 A MYPI2022001790 A MY PI2022001790A MY PI2022001790 A MYPI2022001790 A MY PI2022001790A MY 197243 A MY197243 A MY 197243A
- Authority
- MY
- Malaysia
- Prior art keywords
- dimensional supramolecular
- tri
- benzene
- synthesis
- application
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 5
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- -1 (4-carbonylphenoxybenzene) benzene Chemical compound 0.000 title 1
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 abstract 3
- OIXWTBRGVYBTBN-UHFFFAOYSA-N C(=O)=C1CC=C(C=C1)OC1=CC(=CC(=C1)OC1=CCC(C=C1)=C=O)OC1=CCC(C=C1)=C=O Chemical compound C(=O)=C1CC=C(C=C1)OC1=CC(=CC(=C1)OC1=CCC(C=C1)=C=O)OC1=CCC(C=C1)=C=O OIXWTBRGVYBTBN-UHFFFAOYSA-N 0.000 abstract 2
- 239000000975 dye Substances 0.000 abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 230000015556 catabolic process Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 239000011941 photocatalyst Substances 0.000 abstract 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 230000002194 synthesizing effect Effects 0.000 abstract 1
- 239000002351 wastewater Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1691—Coordination polymers, e.g. metal-organic frameworks [MOF]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
- B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2239—Bridging ligands, e.g. OAc in Cr2(OAc)4, Pt4(OAc)8 or dicarboxylate ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/008—Supramolecular polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
- B01J2531/16—Copper
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/308—Dyes; Colorants; Fluorescent agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Toxicology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Catalysts (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
The invention relates to the treatment of dye-containing wastewater, in particular to a two-dimensional supramolecular compound based on the synthesis of 1,3, 5-tri (4-carbonyl phenyloxy) benzene and its method and application. The method consists of adding 1,3,5-tri(4-carbonyl phenyloxy)benzene, phenol and Cu(NO?)?. 3H?O to acetonitrile aqueous solution, stirring and mixing evenly, turning into the reaction kettle with ptfe lining, heating to 110-130?C and holding for 60-84 hours, then cooling to 20-30?C at the speed of 3-8?C/h and obtaining the two-dimensional supramolecular compound. Compared with the prior art, the invention provides a relatively simple method for synthesizing two-dimensional supramolecular compounds, and the two-dimensional supramolecular compounds synthesized by this method have better degradation efficiency for dyes in water. In addition, the test shows that the two-dimensional supramolecular compound synthesized by the invention is a stable and recoverable photocatalyst.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110875214.3A CN113583029B (en) | 2021-07-30 | 2021-07-30 | Two-dimensional supramolecular compound synthesized based on 1,3, 5-tri (4-carboxyphenyloxy) benzene and method and application thereof |
PCT/CN2021/142808 WO2023005143A1 (en) | 2021-07-30 | 2021-12-30 | Two-dimensional supramolecular compound synthesized on the basis of 1,3,5-tri(4-carbonylphenyloxy)benzene, method therefor, and application thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
MY197243A true MY197243A (en) | 2023-06-07 |
Family
ID=78253073
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MYPI2022001790A MY197243A (en) | 2021-07-30 | 2021-12-30 | Synthesis of two-dimensional supramolecular compounds based on 1,3,5-tri (4-carbonylphenoxybenzene) benzene and its method and application |
Country Status (3)
Country | Link |
---|---|
CN (1) | CN113583029B (en) |
MY (1) | MY197243A (en) |
WO (1) | WO2023005143A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113583029B (en) * | 2021-07-30 | 2022-07-12 | 皖西学院 | Two-dimensional supramolecular compound synthesized based on 1,3, 5-tri (4-carboxyphenyloxy) benzene and method and application thereof |
CN117585647B (en) * | 2023-11-24 | 2024-05-31 | 天津大学 | Application of molecular eutectic material in photocatalytic synthesis of hydrogen peroxide |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103739632A (en) * | 2013-10-23 | 2014-04-23 | 江苏大学 | Preparation method of cobalt metal organic complex having photocatalytic activity |
CN103990493B (en) * | 2014-05-16 | 2016-02-10 | 南开大学 | A kind of visible light catalyst for rhodamine B in degradation water and application thereof |
KR101737390B1 (en) * | 2015-01-26 | 2017-05-19 | 한림대학교 산학협력단 | cobalt clusters-based supremolecular triple-stranded helicates and one-dimensional coordination polymer using thereof and producing methods thereof |
CN104815691B (en) * | 2015-04-17 | 2017-03-22 | 郑州大学 | Super-molecular polymer for degrading organic pollutants in wastewater by photocatalysis, preparation method of super-molecular polymer and application of super-molecular polymer |
CN104926860A (en) * | 2015-06-12 | 2015-09-23 | 新乡学院 | Supramolecular polymer of lead iodide as well as preparation method and application of supramolecular polymer |
CN106749349A (en) * | 2016-11-24 | 2017-05-31 | 吉林师范大学 | Based on mixing N, the preparation method of the transient metal complex of O parts, crystal structure and its application |
CN108424524A (en) * | 2018-03-19 | 2018-08-21 | 陕西理工大学 | A kind of copper(II)Coordination polymer and the preparation method and application thereof |
CN110628037B (en) * | 2019-09-12 | 2021-10-26 | 重庆师范大学 | Yellow fluorescent mixed manganese supramolecular polymer and preparation method and application thereof |
CN112500579A (en) * | 2020-11-27 | 2021-03-16 | 山西大学 | Magnetically-recyclable cerium complex/GO/Fe3O4Ternary complex, preparation method and application |
CN113583029B (en) * | 2021-07-30 | 2022-07-12 | 皖西学院 | Two-dimensional supramolecular compound synthesized based on 1,3, 5-tri (4-carboxyphenyloxy) benzene and method and application thereof |
-
2021
- 2021-07-30 CN CN202110875214.3A patent/CN113583029B/en active Active
- 2021-12-30 WO PCT/CN2021/142808 patent/WO2023005143A1/en active Application Filing
- 2021-12-30 MY MYPI2022001790A patent/MY197243A/en unknown
Also Published As
Publication number | Publication date |
---|---|
WO2023005143A1 (en) | 2023-02-02 |
CN113583029A (en) | 2021-11-02 |
CN113583029B (en) | 2022-07-12 |
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