MY169081A - Method for producing butadiene by oxidative dehydrogenation of n-butenes by monitoring the peroxide-content during product processing - Google Patents

Method for producing butadiene by oxidative dehydrogenation of n-butenes by monitoring the peroxide-content during product processing

Info

Publication number
MY169081A
MY169081A MYPI2015001731A MYPI2015001731A MY169081A MY 169081 A MY169081 A MY 169081A MY PI2015001731 A MYPI2015001731 A MY PI2015001731A MY PI2015001731 A MYPI2015001731 A MY PI2015001731A MY 169081 A MY169081 A MY 169081A
Authority
MY
Malaysia
Prior art keywords
butadiene
butenes
flow
gas flow
oxygen
Prior art date
Application number
MYPI2015001731A
Inventor
Walsdorff Christian Dr
Rer Nat Grune Philipp Dr
-Ing Josch Jan Pablo Dr
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of MY169081A publication Critical patent/MY169081A/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/04Purification; Separation; Use of additives by distillation
    • C07C7/05Purification; Separation; Use of additives by distillation with the aid of auxiliary compounds
    • C07C7/08Purification; Separation; Use of additives by distillation with the aid of auxiliary compounds by extractive distillation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/11Purification; Separation; Use of additives by absorption, i.e. purification or separation of gaseous hydrocarbons with the aid of liquids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02Boron or aluminium; Oxides or hydroxides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04Alkali metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/26Chromium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32Manganese, technetium or rhenium
    • C07C2523/34Manganese
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/85Chromium, molybdenum or tungsten
    • C07C2523/88Molybdenum
    • C07C2523/887Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The invention relates to a method for producing butadiene from n-butenens, comprising the following steps: A) a feed gas flow (a) containing n-butenes is provided; B) the feed gas flow (a) containing n-butenes and an oxygen-containing 10 gas is fed to at least one dehydrogenation area and is oxidatively dehydrogenated from n-butenes to form butadiene; a product gas flow (b) containing butadiene, unreacted n-butenes, water vapour, oxygen, low-boiling point hydrocarbons, optionally carbon oxides and optionally inert gases is obtained; C) the product gas flow (b) is cooled and compressed in at least one 15 cooling step and at least one compression step, said product gas flow (b) being brought into contact with a coolant (4) supplied in the circuit; at least one condensate flow (c1) containing water and a gas flow (c2) containing butadiene, n-butenes, water vapour, oxygen, low-boiling point hydrocarbons, optionally carbon oxides and optionally inert gases is obtained; D) non-condensable and 20 low-boiling point gas component parts containing oxygen, low-boiling point hydrocarbons, optionally carbon oxides and optionally inert gases are separated from the gas flow (c2) by absorbing C4-hydrocarbons containing the butadiene and n-butenes in absorption means supplied in the circuit; an absorption agent flow charged with C4-hydrocarbons and the gas flow (d2) are obtained, and subsequently the C4-hydrocarbon is desorbed from the charged absorption agent flow; a C4-product gas flow is obtained; E) the C4-product flow (d1) is separated by extractive distillation using a selected solvent for butadiene in a butadiene and the material flow (e1) containing the selective solvent and a material flow (e2) containing n-butenes; F) the butadiene and the material flow (e1) containing the selective solvent is distilled in a material flow (f1) consisting essentially of the selective solvent and a material flow (f2) containing a butadiene; wherein the samples are taken in step C) from the coolant (4) supplied in the circuit and samples are taken in step D) from absorption means supplied in the circuit, the peroxide content being determined in the taken samples using iodometry, differential scanning calorimerty (DSC) or micro calorimerty. (Fig.1)
MYPI2015001731A 2013-01-16 2014-01-13 Method for producing butadiene by oxidative dehydrogenation of n-butenes by monitoring the peroxide-content during product processing MY169081A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP13151491 2013-01-16

Publications (1)

Publication Number Publication Date
MY169081A true MY169081A (en) 2019-02-14

Family

ID=47561412

Family Applications (1)

Application Number Title Priority Date Filing Date
MYPI2015001731A MY169081A (en) 2013-01-16 2014-01-13 Method for producing butadiene by oxidative dehydrogenation of n-butenes by monitoring the peroxide-content during product processing

Country Status (7)

Country Link
EP (1) EP2945921B1 (en)
JP (1) JP6231130B2 (en)
KR (1) KR20150105455A (en)
CN (1) CN104936930B (en)
EA (1) EA201591325A1 (en)
MY (1) MY169081A (en)
WO (1) WO2014111331A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016023892A1 (en) * 2014-08-12 2016-02-18 Basf Se Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
EA201790690A1 (en) * 2014-09-26 2017-09-29 Басф Се METHOD OF OBTAINING 1,3-BUTADIENE FROM N-BUTENES THROUGH OXIDATIVE DEGYDERATION
US10358399B2 (en) * 2014-11-03 2019-07-23 Basf Se Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
KR101785146B1 (en) * 2015-03-24 2017-10-12 주식회사 엘지화학 Method for producing conjugated diene and an apparatus
RU2603198C1 (en) * 2015-08-10 2016-11-27 Открытое акционерное общество Научно-исследовательский институт "Ярсинтез" (ОАО НИИ "Ярсинтез") Method of producing butadiene
EP3371145B1 (en) * 2015-11-06 2023-07-19 Uop Llc Use of c4 absorber for stripping aldehydes
WO2018095856A1 (en) * 2016-11-22 2018-05-31 Basf Se Method for preparing 1,3-butadiene from n-butenes through oxidative dehydrogenation comprising methacrolein removal during processing
EP3366660A1 (en) * 2017-02-24 2018-08-29 Linde Aktiengesellschaft Method and installation for the production of olefins
KR102030121B1 (en) * 2018-05-18 2019-10-08 금호석유화학 주식회사 A method for manufacturing 1,3-butadiene using a catalyst article coated with metal oxide

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PH12128A (en) 1973-09-04 1978-11-07 Standard Oil Co Chromium-containing catalysts useful for oxidation reactions
US3932551A (en) 1973-10-12 1976-01-13 The Standard Oil Company Process for the preparation of diolefins from olefins
US3911039A (en) 1974-01-23 1975-10-07 Standard Oil Co Ohio Process for the preparation of botadiene from N-butene
GB1523772A (en) 1974-07-22 1978-09-06 Standard Oil Co Oxidation catalysts
IN145044B (en) 1975-01-13 1978-08-19 Standard Oil Co Ohio
JPS56140931A (en) 1980-04-04 1981-11-04 Nippon Zeon Co Ltd Preparation of conjugated diolefin
JPS56150023A (en) 1980-04-22 1981-11-20 Nippon Zeon Co Ltd Preparation of conjugated diolefin
US4424141A (en) 1981-01-05 1984-01-03 The Standard Oil Co. Process for producing an oxide complex catalyst containing molybdenum and one of bismuth and tellurium
US4547615A (en) 1983-06-16 1985-10-15 Nippon Zeon Co. Ltd. Process for producing conjugated diolefins
JP5621305B2 (en) 2009-05-29 2014-11-12 三菱化学株式会社 Method for producing conjugated diene
KR20120026049A (en) 2009-05-29 2012-03-16 미쓰비시 가가꾸 가부시키가이샤 Method for producing conjugated diene
JP2016503073A (en) * 2013-01-15 2016-02-01 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se Process for producing 1,3-butadiene from n-butenes by oxidative dehydrogenation

Also Published As

Publication number Publication date
CN104936930A (en) 2015-09-23
EP2945921A1 (en) 2015-11-25
EP2945921B1 (en) 2017-03-22
KR20150105455A (en) 2015-09-16
CN104936930B (en) 2017-03-29
WO2014111331A1 (en) 2014-07-24
EA201591325A1 (en) 2016-01-29
JP2016503072A (en) 2016-02-01
JP6231130B2 (en) 2017-11-15

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