MY168427A - Method for producing oxo-vinyl-ionol and o-protected derivatives thereof - Google Patents

Method for producing oxo-vinyl-ionol and o-protected derivatives thereof

Info

Publication number
MY168427A
MY168427A MYPI2014001356A MYPI2014001356A MY168427A MY 168427 A MY168427 A MY 168427A MY PI2014001356 A MYPI2014001356 A MY PI2014001356A MY PI2014001356 A MYPI2014001356 A MY PI2014001356A MY 168427 A MY168427 A MY 168427A
Authority
MY
Malaysia
Prior art keywords
formula
ionol
vinyl
protected derivatives
hydrogen
Prior art date
Application number
MYPI2014001356A
Inventor
Wolfgang Siegel
Hansgeorg Ernst
Michael Puhl
Stefan Benson
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=47143125&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=MY168427(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Basf Se filed Critical Basf Se
Publication of MY168427A publication Critical patent/MY168427A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/06—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/06—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms
    • C07C403/08—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms by hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C07F9/5442—Aromatic phosphonium compounds (P-C aromatic linkage)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/55—Design of synthesis routes, e.g. reducing the use of auxiliary or protecting groups

Abstract

The present invention relates to the preparation of oxovinylionol and its O-protected derivatives of the formula I (I) in which R is hydrogen or an OH protecting group, for example a group Si(Ra)3 by reacting a compound of the formula II (II) in which R have the meanings given above for formula I, i.e. ?-vinyl ionol (formula II, R = hydrogen) or an O-protected derivative thereof (formula II, R = OH protecting group) with an oxidant in the presence of at least one transition metal, where the oxidant comprises at least one oxygen-containing compound which is selected from among hydrogen peroxide and organic hydroperoxides. (No suitable figure)
MYPI2014001356A 2011-11-09 2012-11-08 Method for producing oxo-vinyl-ionol and o-protected derivatives thereof MY168427A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP11188401 2011-11-09

Publications (1)

Publication Number Publication Date
MY168427A true MY168427A (en) 2018-11-09

Family

ID=47143125

Family Applications (1)

Application Number Title Priority Date Filing Date
MYPI2014001356A MY168427A (en) 2011-11-09 2012-11-08 Method for producing oxo-vinyl-ionol and o-protected derivatives thereof

Country Status (9)

Country Link
EP (1) EP2776447B2 (en)
JP (1) JP6154818B2 (en)
CN (1) CN103917549B (en)
CL (1) CL2014001226A1 (en)
DK (1) DK2776447T4 (en)
ES (1) ES2681706T5 (en)
MY (1) MY168427A (en)
TW (1) TWI576333B (en)
WO (1) WO2013068465A2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9221854B2 (en) 2012-08-17 2015-12-29 Basf Se Isomerization of olefinic compounds

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2212948A1 (en) † 1972-03-17 1973-09-20 Basf Ag Alpha,beta-unsatd aldehydes branched in alpha - position - by catalysed alkylation of unsatd alcohols
US3932485A (en) 1974-08-28 1976-01-13 Hoffmann-La Roche Inc. Improved preparation of Wittig salt of vinyl β-ionol
US4098827A (en) * 1977-01-17 1978-07-04 Hoffmann-La Roche Inc. 1-(2,6,6-Trimethyl-3-hydroxy-1-cyclohexen-1-yl)-3-methyl-penta-1,4-diene[or 1-yn-4-EN]-3-ols
DE2704406A1 (en) 1977-02-03 1978-08-10 Basf Ag METHOD OF INTRODUCING A CARBONYL GROUP INTO A CYCLOHEXEN RING
JPS5953463A (en) * 1982-08-20 1984-03-28 エフ・ホフマン―ラ　ロシユ　アーゲー Manufacture of cyclohexenone derivative
DE3377127D1 (en) * 1982-08-20 1988-07-28 Hoffmann La Roche Process for the preparation of astaxanthine and intermediates in the astaxanthine synthesis
DK173704B1 (en) 1985-04-17 2001-07-09 Hoffmann La Roche Process for catalytic oxidation of allylic groups
US5107010A (en) 1990-12-12 1992-04-21 Neurosearch A/S Astaxanthin intermediates
CN100506774C (en) 2005-12-09 2009-07-01 浙江医药股份有限公司新昌制药厂 Method for preparing astaxanthin intermediate
ITMI20052486A1 (en) * 2005-12-23 2007-06-24 Italiana Sint Spa INTERMEDIATE SYNTHESIS PROCEDURE FOR THE PREPARATION OF ASTAXANTIN
CN100361948C (en) 2005-12-30 2008-01-16 贵州黄果树烟草集团公司 Synthesis of ketone-substituted alpha-ionone, ketone-substituted beta-ionone, ether and ester derivative by one-step method
WO2008145627A1 (en) 2007-06-01 2008-12-04 Basf Se Electrochemical oxidation at allyl groups
US8163944B2 (en) * 2007-10-08 2012-04-24 University Of Maryland College Park Allylic oxidations catalyzed by dirhodium catalysts under aqueous conditions
CN101723769A (en) 2009-12-27 2010-06-09 贵州中烟工业有限责任公司 Method for synthesizing violet dienone with homogeneous phase reaction and heterogeneous phase separation

Also Published As

Publication number Publication date
WO2013068465A2 (en) 2013-05-16
TWI576333B (en) 2017-04-01
DK2776447T3 (en) 2018-09-10
CL2014001226A1 (en) 2014-09-26
ES2681706T3 (en) 2018-09-14
JP2014532745A (en) 2014-12-08
ES2681706T5 (en) 2022-05-09
EP2776447A2 (en) 2014-09-17
DK2776447T4 (en) 2022-03-28
WO2013068465A3 (en) 2013-07-18
CN103917549B (en) 2016-12-07
CN103917549A (en) 2014-07-09
EP2776447B1 (en) 2018-05-30
TW201326106A (en) 2013-07-01
JP6154818B2 (en) 2017-06-28
EP2776447B2 (en) 2022-01-05

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