MXPA99008189A - Aqueous composition that comprises a mixture of sulphone polyesters - Google Patents

Abstract

The subject of the invention is a cosmetic or dermatological composition comprising, in an aqueous phase: i) a water-soluble or water-dispersible terephthalic copolyester oligomer comprising essentially repeating dicarboxylate units of formula (I): CO-A-CO-O- (CH2-CH2O) ) n-] in which A represents a 1,4-phenylene, 1,3-sulfophenylene group, n ranges from 1 to 4, with at least 35% by mole of the said units of formula (I) units of formula (I) for which A represents a 1,4-phenylene group and n is equal to 1, with at least 7% by mole of the said units of formula (I) units of formula (I) for which A represents a 1,3-sulfophenylene group, the molecular weight by weight of said copolyester oligomer being below 20,000, ii) at least one copolyester sulfo-isophthalic dispersing it in the aqueous phase. This composition is destined for the makeup of keratin materials

Description

AQUEOUS COMPOSITION COMPRISING A MIXTURE OF SULPHONATED POLYESTERS Field of the Invention The present invention relates to a new smokeless, non-transferring and resistant composition. to topical application water, which comprises a mixture of sulfonated polyesters intended in particular for the cosmetic and / or dermatological fields. The invention also relates to the use of this composition for the make-up or cosmetic treatment of keratin materials of the human being such as the skin, nails, eyelashes, eyebrows, hair, or mucous membranes such as the lips. This composition may be in the form of a gel, a paste or a molten product, in particular a bar.

BACKGROUND OF THE INVENTION Make-up or treatment products of the skin or of the lips, such as foundation or red lipsticks, generally contain fatty phases such as waxes and oils, pigments and / or fillers and, optionally, Ref .: 31105 co-additives or cosmetic or dermatological active agents. They may contain gelling agents which make it possible to obtain the desired consistency for the composition according to the application.

Brief Description of the Invention These compositions, when applied to the skin or the lips, have the drawback of transferring, that is to say deposited at least in part, leaving marks, on some supports with which they can be put in contact, and particularly a glass, a cup, a cigarette, a garment or the skin. There is a lackluster persistence of the applied film, which needs to regularly renew the application of the composition of background or lipstick makeup. In addition, the appearance of these unacceptable marks, particularly in blouse collars, can divert some women from the use of this type of makeup. It is known from patent application EP-A-602905"to associate volatile oils with waxes to obtain products having improved non-transfer properties." However, these products slip in their application onto keratin materials, such as, for example, the lips, In addition, these products leave an impression of tightness during and after their application on the lips.On the other hand, the compositions after application on the skin or lips can be eliminated on contact with water, particularly during the bath or with the contact of rain or tears It is therefore desirable to have compositions that have good properties of remanence to water.

Description of the Invention The purpose of the present invention is to propose a new smoke composition that does not have the aforementioned drawbacks and that have particularly properties of no total transfer, of remanence to water, of absence of tightness during and after the application on - the keratin materials and easy to apply. The inventors have discovered that a composition of this type could be obtained using a mixture of sulfonated polyesters. A composition is then obtained which leaves after the application a film which exhibits a good performance, does not transfer anything, and which is resistant to water. The film is particularly bright, non-adhesive and comfortable (without tightness) during and after application of the composition on keratin materials. The film also produces a feeling of freshness and is easy to remove make-up with the makeup removers usually used. In addition, the composition is less slippery than non-transfer products containing volatile oils, thus facilitating its application to keratin materials. The subject of the present invention is therefore a new topically applied smoke composition which comprises, in an aqueous phase, a sulfonated polyester-type hydrophilic gelling agent, characterized in that the hydrophilic gelling agent is a water-soluble or water-dispersible terephthalic copolyester oligomer and because the composition also comprises a sulfonated isophthalic copolyester dispersible in the aqueous phase.

The particular gelling agents used according to the invention are water-soluble or water-dispersible terephthalic copolyester terephthalic oligomers comprising essentially repeating dicarboxylate units of formula (I): [-CO-A-CO-0- (CH2-CH20) "-] (I) wherein - A represents a 1,4-phenylene, 1,3-sulfophenylene and optionally 1,3-phenylene group, n ranges from 1 to 4, with at least 35% by mole of the said units of formula (I) ) units of formula (I) _ for which ~A represents a 1,4-phenylene group and n is equal to 1, with at least 7% by mole of the said units of formula (I) units of formula (I) for which A represents a 1,3-sulfofenyl group, the molecular mass by weight of the said oligomers being less than 20,000, preferably less than 15,000. Preferably, at least 40% by moles, and more preferably between 40 and 90 mole% of the units of formula (I) are units of formula (I) for which A represents a 1,4-phenylene group and n is equal to 1. Preferably, at least one 10% by mole, more preferably between 10% and 25% by mole of the units of formula (I) are units of formula (I) for which A represents a group 1 , 3-phenylene. The ends of the chains of the indicated oligomers may be similar or different and essentially represented by the groups of formula (I '): -CO-A-CO-O- (CH2-CH 0) "-H (I ') where A and n are as defined above. The indicated oligomers can also have, at the ends of the chain, and in a smaller amount, groups of formulas -A-CO-OH -A-CO-OR formulas in which A is as defined above and R represents an alkyl group of C? -C. When A represents a 1,3-phenylene group, it is more particularly an alkali metal sulphonate, in particular sodium or potassium sulfonate, or an ammonium sulfonate or mono-, di-, tri- or tetra-alkylammonium sulfonate. lower. By lower alkylammonium is meant preferably an ammonium of which the alkyl radical (s) are lower alkyl, preferably Ci-Cß- Preferably, it is a sodium sulfonate. The copolyester oligomer can optionally comprise up to 20 mol%, preferably from 0.5 to 5 mol% of units of formula (I) for which A represents a 1,3-phenylene group. According to a preferred embodiment of the invention, the copolyester oligomer indicated above has a molecular weight by weight ranging between 5,000 and 14,000, and more preferably between 8,000 and 10,000. Molecular masses by weight are measured by chromatography. by gel-permeation in dimethylacetamide containing 10 ~ 2 N LiBr, a 100 ° C. The results are expressed in polystyrene equivalents. The indicated copolyester oligomers can be obtained by the usual processes for the preparation of the polyesters by molten route, via or interfacial solvent, processes that produce esterification reactions of diacids and diols and polycondensation. of transesterification of diesters and diols and polycondensation. of self-condensation of hydroxy acids. of Schotten-Baumann- or use of diols and acid chlorides and polycondensation. of polymerization of lactones controlling the minimum content of units of formula (I) for which A represents a group 1,4-phenylene and n equals 1, similar to the initial stoichiometric ratios of the various monomers and to the control of side reactions. A particularly interesting preparation method is that of transesterification / polycondensation and / or esterification / polycondensation via melting with the aid of a transesterification and / or esterification catalyst. The domain of the structure is obtained by controlling the minimum content of units of formula (I) for which A represents a 1,4-phenylene group and n is equal to 1, similar by the initial stoichiometric ratios of the different diacid and / or diester monomers and diol and by the use of an etherification agent, limiting agent which may be a basic compound such as aliphatic or aromatic amines or a metal hydroxide or acetate alkaline or alkaline earth. The control of the molecular mass is obtained in a manner known to the person skilled in the art, by means of the appropriate compromise between pressure, temperature and time. The terephthalic copolymer oligomers used according to the invention can be prepared by esterification and / or transesterification / polycondensation of a monomeric base composition: - anhydride or diester terephthalic acid (Tp) - of anhydride or diester sulfoisophthalic acid (SIp) optionally of acid, anhydride or isophthalic diester (I?) - and of ethylene glycol (EG) according to relative amounts corresponding to * a molar ratio- (SIp) / [(Tp) + ( SIp) + (Ip)] of at least 7/100, preferably of at least 10/100, very particularly of 10/100 to 25/100 * a molar ratio (Ip) / [(Tp) + (SIp) + (Ip)] of 20/100 maximum, preferably of 5/100 maximum. * a molar ratio (EG) / [(Tp) + (SIp) + (Ip)] from 2/1 to 3/1. in the presence of an esterification and / or transesterification catalyst and an etherification limiter. The terephthalic monomer (Tp) is preferably used in the form of a lower diester (dialkyl dialkyl diester), preferably dimethyl. The sulphoisophthalic monomer (SIp) is preferably used in the form of an alkali metal (mainly sodium) sulfonate of lower diester (C? -C alkyl), preferably methyl. Particular mention may be made of dimethyl sodium-5-oxysulfonyl isophthalate. The optional isophthalic monomer (lp) is preferably used in the form of isophthalic acid. When all the "diacid" monomers are used in the form of a diester, the transesterifi cation (exchange) operation between these "diacid" monomers and the ethylene glycol is carried out at a temperature greater than or equal to 130 ° C, preferably of the order from 140 to 220 ° C and very particularly from 180 to 220 ° C; at this temperature the methanol (preferred case of methyl disterate) formed is removed from the reaction medium preferably by distillation. This exchange operation is carried out in the presence of a metal transesterification catalyst and an etherification limiter. The said catalyst is preferably a metal carboxylate, such as manganese acetate, zinc acetate, cobalt acetate or calcium acetate, or an organic or mineral titanate, such as butyl titanate, titanate 2, 2 ', 2"- triethyl nitrile (or rietanolat or titanium arninot which also plays the role of etherification limiter) or calcium titanate The preferred catalysts are organic titanates, used in amounts of the order of at least 0.001% by weight, expressed as titanium, preferably of the order of 0.002% to 0.02% by weight of titanium, based on the weight of reagents present The etherification limiting agent can be a basic compound such as aliphatic or aromatic amines (triethanolamine, guanidine carbonate, dimethylamine, naphthylamine ...) or an alkali metal or alkaline earth metal hydroxide or acetate (sodium acetate, potassium, sodium benzoate ...). an amount in the order of 0.001% to 0.05% in relation to the weight of reagents present. The duration of the exchange operation is from 1 to 4 hours; it is generally of the order of 2 to 3 hours. When more than 90% of the theoretical amount of methanol has been distilled, the remaining polyol is removed by bringing the temperature of the reaction medium to 230 ° C.

The polycondensation operation is preferably carried out at a temperature of the order of 230 to 280 ° C, preferably of the order of 240 to 260 ° C, in another reactor previously brought to this temperature and progressively placed under vacuum to a pressure that can reach up to lOPa; a pressure reduction of up to approximately 10 millibars lasts in the order of 40 minutes. The polycondensation operation is carried out with elimination of polyol molecules, this operation is stopped when the torque of the agitation shaft indicates a value equivalent to approximately 0.5 to 5 meters. Newton for a temperature of 250 ° C of the reaction mass and a stirring speed of 80 revolutions / minute of an anchor mobile in a 7.5 liter reactor. The vacuum is then broken with nitrogen, and the polymer is poured into an ingot mold; after cooling, the polymer is crushed. When one of the "diacid" monomers is present in the form of a diacid or anhydride and the one or more is in the form of a diester (s), the indicated copolymer oligomers are obtained by first performing a transesterification operation of the monomer diesters with ethylene glycol under the conditions described above, followed by an operation of esterification in a medium of the diacid monomer or anhydride with the ethylene glycol, then polycondensation under the conditions described previously, dividing the total amount of ethylene glycol between the two operations (transesterification and esterification). If necessary, the esterification operation is carried out by adding to the reaction medium resulting from the transesterification operation, the monomer in diacid or anhydride form and ethylene glycol previously suspended, at a temperature corresponding to that of the end of the temperature exchange; the introduction time is of the order of 1 hour. This esterification operation is carried out at a temperature of the order of 230 to 280 ° C, preferably of the order of 250 to 260 ° C, in the presence of a catalyst of the same type as that of transesterification and of a limiting agent of Eteri icació. The operation is carried out in the presence of the same types of catalyst and etherification limiter as those used during the transesterification operation, and this in the same proportions. The reaction is carried out with the elimination of water that is transferred from the reactor at the same time as the excess polyol. This type of preparation process is particularly described in patent application WO 95/32997. The terephthalic copolyester oligomer may be present in the composition according to the invention in a content ranging from 0.5% to 40% by weight, based on the total weight of the composition. Depending on the shape sought, gelled, pasty or solid, different amounts of particular gellant will be used. For a solid composition, preferably from 10 to 40% by weight of particular gelling agent, more preferably from 15 to 30% by weight For a gelled or pasty composition, preferably 0 will be used, 5 to 10% by weight of particular gelling agent, more preferably 2 to 5% by weight.

By "sulfo-isophthalic copolyester" is meant in the present application a copolyester consisting essentially of repeated units of isophthalic acid, of diol and of sulfo-isophthalic acid. By isophthalic acid, it is understood according to the present application also the esters and the acid chloride of isophthalic acid. The diol present in the sulfo-isophthalic copolyester can be a cycloaliphatic diol preferably having from 6 to 20 carbon atoms or an aliphatic diol preferably having from 3 to 20 carbon atoms. As a diol, ethylene glycol, diethylene glycol, triethylene glycol, 1,4-cyclohexanedimethanol, 1,3-propane diol, 1,4-butane diol, 1,5-pentane diol, 1,6-hexane diol, 3-methylpentanediol- (2,), 2-methylpentanol- (1, 4), 2, 2, 4 - 1 rimet ilpentanediol- (1,3), 2-ethylhexanediol- (1, 3), 2,2-diethylpropane-diol- (1, 3), (1, 3) -hexanediol, 1, -di - (hydroxyethoxy) benzene, 2,2-bis- (4-hydroxycyclohexyl) -propane, 2-dihydroxy-1,1,3,3-tetramethylcyclobutane, 2,2-bis- (3-hydroxy-ethoxyphenyl) ) -propane, 2,2-bis- (4-hydroxypropoxyphenyl) -propane. The isophthalic copolyester can comprise one or several diols such as those mentioned above and preferably a mixture of ethylene glycol or 1,4-cyclohexanedimethanol and diethylene glycol. Advantageously, the sulfo-isophthalic copolyester can comprise a diol mixture consisting of at least 45 mol% of diethylene glycol and a 100 mol% complement of ethylene glycol glycol or 1,4-cyclohexane dimethanol. The sulfo-isophthalic acid unit comprises a -S03M group with M representing a hydrogen atom, an ammonium ion NH4 + or a metal ion, such as for example Na +, Li +, K +, M being preferably Na +. Particularly preferred sulfoisophthalic acid is the sodium salt of 5-sulfoisophthalic acid. The sulfo-isophthalic acid unit is preferably present in the sulfo-isophthalic copolyester in a content ranging from 4 to 25% in moles per 100 moles of acids and 100 moles of diols. Advantageously, the sulfo-isophthalic copolyester can comprise, per 100 mol of acids, from 75% to 90% by mol of isophthalic acid and from 10% to 25% by mol of sulpho-isophthalic acid, particularly salt of sodium of 5-sulfoisophthalic acid, and, per 100 moles of diols, from 45% to 85% by moles of diethylene glycol and from 15% to 55% by moles of 1,4-cyclohexanedimethanol or of ethylene glycol or its mixture. The sulfo-isophthalic copolyester has preferably a glass transition temperature ranging from 20 ° C to 60 ° C, and better between 20 ° C and 40 ° C. Advantageously, the sulfo-isophthalic copolyester can have an inherent viscosity ranging between 0.01 and 0.1 liters / gram (0.1 to 1 deciliter / gram) and better between 0.02 and 0.05 liters / gram (0). , 2 to 0.5 deciliters / gram), measured in a mixture by weight of phenol and tetrachloroethane (60/40) at 25 ° C and at a concentration of 0.5 g of polymer per 100 ml of solvent, according to the standard ASTM D2857-70. The method of measuring the inherent viscosity is described in US-A-5260052, the content of which is incorporated by reference in the present application. Such sulfo-isophthalic copolyes are particularly described in US-A-377999J and US-A-5260052 and are sold for example under the names "EASTMAN AQ 35S", "EASTMAN AQ 38S", "EASTMAN AQ 55S", EASTMAN AQ 29D "," EASTMAN AQ 38D "by the EASTMAN CHEMICAL Company The composition according to the invention may comprise one or more sulfo-isophthalic copolyester According to the invention, the sulfo-isophthalic copolyester may be present in the composition in a number of materials dry, ranging from 1% to 40% by weight relative to the total weight of the composition, and preferably between 5% and 20% by weight Advantageously, the copolyester terephthalic oligomer and the sulfoisophthalic copolyester can be present in the composition according to the invention in a weight ratio of oligomer / copolies ter sulfoisophthalic ranging from 0, 5 and 20, and preferably between 1 and 5. On the other hand, the composition according to the invention may contain adjuvants commonly used in cosmetic compositions, particularly topical ones. Examples of colorants, pigments, pearlescents, anti-UV agents, preservatives, thickening agents, plasticizers, surfactants, waxes, oils, perfumes, modifying agents can be mentioned as examples of adjuvants. of pH, moisturizing agents. Of course, the person skilled in the art will try to choose this or these possible adjuvants, and / or their quantity, in such a way that the advantageous properties of the composition according to the invention are not, or substantially, altered by the considered addition. The composition according to the invention can be used for the makeup, care or non-therapeutic cosmetic treatment of keratin and / or mucosal materials. The composition of make-up can be a product of make-up of the lips, particularly in the form of paste or bar, a foundation in the background, an eye or cheek makeup, a mask for the eyelashes or the hair, a profiler, an anti-aging - Dark circles, or else a makeup composition of the body. The cosmetic treatment or care composition can be a composition for the treatment of the face, neck, hands, body, nails or lips, a deodorant composition or also sun protection. The invention also relates to a non-therapeutic process for the cosmetic treatment or make-up of keratin and / or mucosal materials consisting of applying a composition on the keratin and / or mucosal surfaces as described above. The subject of the invention is also the use of a copolyester terephthalic oligomer and a sulfoisophthalic copolyester such as defined above, in a cosmetic or dermatological composition to reduce or even suppress the transfer of the film of this deposited composition onto the keratin materials. and / or the mucous membranes and / or to suppress the deposit of marks "on another support other than the indicated keratin materials and / or the indicated mucous membranes." The invention also has the object of using a terephthalic copolyester and a sulfur copolyester. isophthalic as defined above in a cosmetic or dermatological composition for obtaining a film of this water-resistant and / or fresh and / or comfortable composition The subject of the invention is also the use of a composition as defined above for obtaining a film of this compos water resistant and / or having non-transferring and / or fresh and / or comfortable properties. Some examples illustrating the present invention without limiting it, however, will be given below.

EXAMPLE 1 Preparation of a terephical copolyester ether oligomer. In a 7.5 liter stainless steel reactor, equipped with an anchor stirrer that rotates at 80 rev / min connected with a KYOWA torque meter, with a double cover for the circulation of a heat transfer fluid and a distillation column regulated by a solenoid valve were: 11.47 moles of dimethyl terephthalate 2.53 moles of sodium 5-dimethoxysophthalate sulfonate 39.16 moles of ethylene glycol 54 ppm by weight of titanium, in the form of aminot rietanolate of titanium as a catalyst and etherification limiting agent. The mixture was preheated to 180 ° C.

It was then brought to the temperature of 220 ° C in approximately 130 minutes, to distill more than 90% of the theoretical amount of methanol. The reaction mixture was then brought to 230 ° C in 30 minutes. When the reaction mass has reached this temperature, a suspension is introduced in 60 minutes, always at 230 ° C, whose composition is as follows: -0.5 moles of isophthalic acid -2.36 moles of terephthalic acid -8 moles of ethylene glycol The reaction mass was then brought to a temperature of 250 ° C in 60 minutes. During the time of introduction of the mixture and during the heating time up to 250 ° C, a mixture of water and ethylene glycol is distilled without degradation.

The reaction mixture is then transferred to an autoclave preheated to 250 ° C then placed under reduced pressure of 100 mbar in 22 minutes. After 2 minutes under these conditions of temperature and pressure, the reaction mass is poured and allowed to cool. The copolyester obtained has the structural characteristics described in table 1 given below, in which: * "% molar of the diacid units" corresponds to the content, in%, of each diacid or diester used in relation to the set of diacids or diesters used. "Tp" means: telephthalmic unit "Ip" means: isophthalic unit "SIp" means: sulfoisophthal unit The characteristics of the "glycol" part of the copolyesters are obtained by methanolysis of the products at 190 ° C for 16 hours followed by a analysis by the vapor phase chromatography technique and dosed by internal contrast.

"Molar% of the diols units" corresponds to the content in% of the oxyethylene units "G", of the units di (oxyethylene) "2G", of the units t ri (oxyethylene) "3G" and of the units tetra ( oxyethylene) "4G", in relation to the set of diol units. * "% GT / S units" corresponds to the mole% of the units of formula (I) [-CO-A-CO-O- (CH2-CH2O) "-] (I) where A is 1,4 phenyl and n = l in relation to the group of units of formula (I) where A is 1, 4-phenylene, 1,3-sulfo phenylene and optionally 1,3-phenylene and n equals 1 to 4"% GT / S units" is calculated by the following formula: "% GT / S units = (% molar of units Tp) x (% molar of units G) / 100 * The molar mass of the polyesters (Mw) was determined by gel permeation chromatography (GPC) in the DMac / 100% LiBr, the results are given in polystyrene equivalents.

Molar% of diacid units Tp 82 Ip 3 SIp 15% GT / S units 46, 5% molar of the diols units G 56.8 2G 30.7 3G 10 4G 2.5 Mw 8,000 Axis 2: A red was prepared of bar-shaped lips with the following composition: - terephthalic copolyester ether oligomer of example 1 20% - copolyester sulfo-isof tálico (EASTMAN AQ 55S of EASTMAN CHEMICAL) 10% MA - pigments 5% - propylene glycol 2.5% - water csp 100% A red lip was obtained that allows obtaining a film "without transfer" total and that resists perfectly well to water. Example 3: A lipstick in the form of a stick was prepared with the following composition: terephthalic copolyester ether of example 1 20% copolyester sulfo-isophthalic (EASTMAN AQ 38S of EASTMAN CHEMICAL) 10% MA pigments 5% propylene glycol 2.5% - water csp 100% A red lip was obtained that allows obtaining a film "without transfer" total and that resists perfectly well to water. Example: A mask in the form of a gel was prepared with the following composition: - terephthalic copolyester ether oligomer of example 1 10% - copolyester sulf or isofiyl (EASTMAN AQ 55S of EASTMAN CHEMICAL) 8% MA - pigments 8% - propylene glycol 4% - water csp 100% A red lip was obtained that allows obtaining a film "without transfer" total and that resists perfectly well to water.

EXAMPLE 5 A body product with a body composition was prepared with the following composition: - terephthalic copolyester ether oligomer of example 5% - Copolyester Sodium O-Isof (EASTMAN AQ 38S from EASTMAN CHEMICAL) 5% MA - pigments 5% - propylene glycol 2, 5% - water csp 100% It is noted that in relation to this date, the best method known to the applicant to carry out the aforementioned invention, is that which is clear from the present description of the invention. Having described the invention as above, property is claimed as contained in the following:

Claims (29)

1. R E I V I N D I C A C I O N S 1. Topically applied smoke composition comprising, in an aqueous phase, a sulfonated polyester-type hydrophilic gelling agent, characterized in that: i) the sulfonated polyester-type hydrophilic gelling agent is a water-soluble or water-dispersible terephthalic copolyester ether oligomer comprising essentially repeating dicarboxylate units of the formula (I) ): [-CO-A-CO-0- (CH2-CH20) n-J (I) wherein A represents a group 1, 4-phenylene, 1,3-sulfophenylene and optionally 1,3-phenylene, n ranges from 1 to 4, with at least 35% by mole of the said units of formula (I) ) units for which A represents a 1,4-phenylene group and n is equal to 1, at least 7% by mole of the said units of formula (I) being units of formula (I) for which A represents a 1,3-sulphenylene group, and optionally up to 20% by mole, preferably up to 0.5% to 5% by mole of units of formula (I) for which A represents a 1,3-phenylene group, and the molecular weight by weight of said copolyester oligomer being less than 20,000, ii) and in that the composition also comprises at least one sulfoisophthalic copolyester dispersed in the aqueous phase. Composition according to Claim 1, characterized in that the copolyester oligomer has a molecular mass by weight of less than 15 000. 3. Composition according to claim 1 or 2, characterized in that the copolyester terephthalic oligomer has a molecular mass by weight ranging between 5,000 and 14,000, and better still between 8,000 and 10,000. 4. Composition according to any one of the preceding claims, characterized in that the terephthalic copolyester ether comprises at least 40 mol% said units of formula (I) for which A represents a 1,4-phenylene group and n is equal to 1. Composition according to any one of the preceding claims, characterized in that the copolyester terephthalic oligomer comprises a 40 to 90% by mole of the indicated units of formula (I) for which A represents a 1,4-phenylene group and n is equal to 1. 6. Composition according to any was of the preceding claims, characterized in that the terephthalic copolyester ether comprises at least 10 mol% of the units of formula (I) for which A represents a 1,3-sulfo phenylene group. Composition according to any one of the preceding claims, characterized in that the copolyester terephthalic oligomer comprises from 10% to 25% by mole of the said units of formula (I) for which A represents a group 1, 3-phenylene sulphide. Composition according to any one of the preceding claims, characterized in that the copolyester terephthalic oligomer comprises up to 20% by mole, and preferably between 0.5% and 5% by mole, of units of formula ( I) for which A represents a 1,3-phenylene group. Composition according to any one of the preceding claims, characterized in that the copolyester terephthalic oligomer is present in a content ranging between 0.5% and 40% by weight, based on the total weight of the composition. 10. Composition according to any one of the foregoing claims in solid form, characterized in that the copolyester terephthalic oligomer is present in a content ranging from 10% to 40% by weight, based on the total weight of the composition , and better between 15% and 30% in weight. Composition according to any one of Claims 1 to 9, gel form, characterized in that the copolyester terephthalic oligomer is present in a content ranging from 0.5% to 10% by weight, based on the weight total composition, and better between 2% and 5% by weight. 12. Composition according to any one of the preceding claims, characterized in that the sulfo-isophthalic copolyester consists essentially of repeated units of isophthalic acid, diol and sulfoisophthalic acid. 13. The composition according to claim 12, characterized in that the diol is chosen from the group consisting of ethylene glycol, diethylene glycol, triethylene glycol, 1,4-cyclohexanedimethanol. Composition according to any one of the preceding claims, characterized in that the sulpho-isophthalic copolyester comprises a diol mixture consisting of at least 45% by mol of diethylene glycol and in a 100% by weight complement of ethylene glycol or of 1,4-cyclohexane dimethanol. Composition according to any one of the preceding claims, characterized in that the sulfo-isophthalic acid unit is the sodium salt of 5-sulfo-isophthalic acid. 16. Composition according to any one of claims 12 to 15, characterized in that the sulfo-isophthalic acid unit is present in the sulfo-isophthalic copolyester in a content ranging between 4% and 25% in moles per 100 moles of acids and 100 moles of diols. Composition according to any one of the preceding claims, characterized in that the sulfo-iso-thalic copolyester comprises, per 100 mol of acids, from 75% to 90% by mol of isophthalic acid and of 10% at 25 mol% sulfo-isophthalic acid and, per 100 mol of diols, from 45% to 85 mol% of diethylene glycol and from 15% to 55 mol% of 1,4-cyclohexanedimethanol or of ethylene glycol or its mixture. 18. Composition according to any one of the preceding claims, characterized in that the copolyester sulfo-isophthalic has a glass transition temperature ranging from 28 ° C to 60 ° C. 19. Composition according to any one of the preceding claims, characterized in that the copolyester sulfo-isophthalic has an inherent viscosity ranging between 0.01 and 0.1 liters / grams, and better between 0.2 and 0.5 liters / gram, measured in a mixture by weight of phenol and tetrachloroethane (60/40) at 25 ° C and at a concentration of 0.5 g of polymer per 100 ml of solvent. Composition according to any one of the preceding claims, characterized in that the sulfo-isophthalic copolyester is present in an amount of dry matter ranging from 3% to 50% by weight relative to the total weight of the composition . Composition according to any one of the preceding claims, characterized in that the terephthelic copolyester ether and the sulfoisophthalic copolyester are present according to an oligomer / copolyester sulphoisophthalic weight ratio ranging from 0.5 to 20, and better between 1 and The composition according to any one of the preceding claims, characterized in that the composition is a cosmetic or dermatological composition. 23. Composition according to any one of the preceding claims, characterized in that it comprises at least one adjuvant selected from the group consisting of the dyes, the pigments, the pearlescents, the anti-UV agents, the preservatives, the thickening agents, the agents plasticizers, surfactants, waxes, oils, perfumes, pH modifying agents, moisturizing agents. Composition according to any one of the preceding claims, characterized in that it is presented in the form of a make-up composition or a cosmetic treatment of the keratin and / or mucosal materials. Composition according to any one of the preceding claims, characterized by the he-Cho that the composition is presented in the form of a lip makeup product, a foundation makeup, an eye or cheek makeup, a mask, of a profiler, of an anti-dark circles, of a composition of body make-up, of a composition for the treatment of the face, of the neck, of the hands, of the body, of the nails or of the lips, of a deodorant composition, of a sunscreen composition. 26. Non-therapeutic method of make-up or treatment of keratin and / or mucosal materials, characterized in that a composition according to one of claims 1 to 24 is applied to the keratin and / or mucous materials. Use of a water-soluble or water-dispersible terephthalic copolyester terephthalic oligomer comprising essentially repeating dicarboxylate units of formula (I): | CO-A-CO-0- (CH2-CH20) n-] (I) wherein - A represents a group 1, -phenylene, 1,3-sulfophenylene and optionally 1,3-phenylene, n ranges from 1 to 4, with at least 35% by mole of the said units of formula (I) units of formula (I) for which A represents a group 1, 4- phenylene and n is equal to 1, with at least 7% by mole of the said units of formula (I) units of formula (I) for which A represents a 1,3-sulfo phenylene group, and optionally up to 20% by mole, preferably up to 0.5% by 5% by mole of formula units (I) for which A represents a 1,3-phenylene group, and the molecular weight by weight being that indicated oligomer less than 20,000, and by a water-dispersible sulfo-isophthalic copolyester, in a cosmetic or dermatological composition for reducing, or even suppressing, the transfer of the film of this deposited composition onto keratin and / or mucosal materials, and / or to suppress the deposit of marks on another support other than those indicated keratin materials and / or those indicated mucous. 28. Use of a water-soluble or water-dispersible terephthalic terephthalic ccpoliester oligomer comprising essentially repeating dicarboxylate units of formula (I): [-CO-A-CO-O- (CH2-CH20) "-] (I) in which - A represents a group 1, 4-phenylene, 1,3-sulfophenylene and optionally 1,3-phenylene, - n ranges from 1 to 4, with at least 35 mole% of the indicated units of formula (I) being units of formula (I) for which A represents a 1,4-phenylene group and n is equal to 1, - being minus 7 mol% of the indicated units of formula (I) units for which A represents a 1,3-sulfo phenylene group, and optionally up to 20 mol%, preferably up to 0.5% to 5 mol % in moles of formula units (I) for which A represents a 1,3-phenylene group, and the molecular weight by weight of said copolyester oligomer is below 20,000, and by a water-dispersible sulfo-isophthalic copolyester in a cosmetic or dermatological composition for obtaining a film of this composition resistant to water and / or fresh and / or comfortable. 29. Use of a composition according to any one of claims 1 to 25, for obtaining a water-resistant film and / or having non-transfer and / or fresh and / or comfortable properties. SUMMARY OF THE INVENTION The subject of the invention is a cosmetic or dermatological composition comprising, in an aqueous phase: i) a water-soluble or water-dispersible terephthalic copolyester terephthalic oligomer comprising essentially repeating dicarboxylate units of formula (I): [-CO-A-CO-0- (CH2-CH20) n-] (I) wherein - A represents a group 1, 4-phenylene, 1,3-sulfophenylene, n ranges from 1 to 4, with at least 35% by mole of the said units of formula (I) units of formula (I) for which A represents a 1,4-phenylene group and n is equal to 1, with at least 7% by mole of the said units of formula (I) units of formula (I) for which A represents a group 1, 3-phenylene sulphide, the molecular weight by weight of said copolyester oligomer being below 20,000, ii) at least one sulfo-isophthalic copolyester dispersible in the aqueous phase. This composition is intended for the makeup of keratin materials.