MXPA99005165A - Coating material - Google Patents
Coating materialInfo
- Publication number
- MXPA99005165A MXPA99005165A MXPA/A/1999/005165A MX9905165A MXPA99005165A MX PA99005165 A MXPA99005165 A MX PA99005165A MX 9905165 A MX9905165 A MX 9905165A MX PA99005165 A MXPA99005165 A MX PA99005165A
- Authority
- MX
- Mexico
- Prior art keywords
- coating material
- group
- particles
- acrylate
- range
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims abstract description 86
- 239000011248 coating agent Substances 0.000 title claims abstract description 46
- 238000000576 coating method Methods 0.000 title claims abstract description 46
- 239000002245 particle Substances 0.000 claims abstract description 67
- 239000000049 pigment Substances 0.000 claims abstract description 40
- 238000010521 absorption reaction Methods 0.000 claims abstract description 21
- 239000011230 binding agent Substances 0.000 claims abstract description 11
- 239000011796 hollow space material Substances 0.000 claims abstract description 6
- 239000006185 dispersion Substances 0.000 claims description 36
- 229920001577 copolymer Polymers 0.000 claims description 35
- -1 polyethylene Polymers 0.000 claims description 35
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 32
- TZCXTZWJZNENPQ-UHFFFAOYSA-L Barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 24
- WGPCGCOKHWGKJJ-UHFFFAOYSA-N sulfanylidenezinc Chemical compound [Zn]=S WGPCGCOKHWGKJJ-UHFFFAOYSA-N 0.000 claims description 24
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 23
- 239000004698 Polyethylene (PE) Substances 0.000 claims description 22
- 229920000573 polyethylene Polymers 0.000 claims description 21
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 20
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- FEIQOMCWGDNMHM-UHFFFAOYSA-M 5-phenylpenta-2,4-dienoate Chemical compound [O-]C(=O)C=CC=CC1=CC=CC=C1 FEIQOMCWGDNMHM-UHFFFAOYSA-M 0.000 claims description 17
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L Calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 16
- 239000005083 Zinc sulfide Substances 0.000 claims description 16
- 229910052759 nickel Inorganic materials 0.000 claims description 16
- 239000000839 emulsion Substances 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- 229920002635 polyurethane Polymers 0.000 claims description 14
- 239000004814 polyurethane Substances 0.000 claims description 14
- 239000002562 thickening agent Substances 0.000 claims description 13
- PQXKHYXIUOZZFA-UHFFFAOYSA-M Lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 claims description 12
- 239000002518 antifoaming agent Substances 0.000 claims description 12
- 230000005540 biological transmission Effects 0.000 claims description 12
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 12
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 12
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 12
- 229920005989 resin Polymers 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 12
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- 229960003563 Calcium Carbonate Drugs 0.000 claims description 11
- XOLBLPGZBRYERU-UHFFFAOYSA-N Tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 11
- 229910052782 aluminium Inorganic materials 0.000 claims description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 11
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 11
- 239000002270 dispersing agent Substances 0.000 claims description 11
- 229910001369 Brass Inorganic materials 0.000 claims description 10
- 239000004215 Carbon black (E152) Substances 0.000 claims description 10
- 239000010951 brass Substances 0.000 claims description 10
- 229920005549 butyl rubber Polymers 0.000 claims description 10
- 229920001971 elastomer Polymers 0.000 claims description 10
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 claims description 10
- 150000002430 hydrocarbons Chemical class 0.000 claims description 10
- 229910044991 metal oxide Inorganic materials 0.000 claims description 10
- 150000004706 metal oxides Chemical class 0.000 claims description 10
- CERQOIWHTDAKMF-UHFFFAOYSA-M methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 10
- 229920001888 polyacrylic acid Polymers 0.000 claims description 10
- 239000004584 polyacrylic acid Substances 0.000 claims description 10
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 10
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 10
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 10
- 239000005060 rubber Substances 0.000 claims description 10
- VHOQXEIFYTTXJU-UHFFFAOYSA-N 2-methylbuta-1,3-diene;2-methylprop-1-ene Chemical compound CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 claims description 9
- 229920002681 Hypalon Polymers 0.000 claims description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 9
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 9
- 229910052787 antimony Inorganic materials 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 9
- 239000000945 filler Substances 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 9
- 229920005587 polyester-imide Polymers 0.000 claims description 9
- WUKWITHWXAAZEY-UHFFFAOYSA-L Calcium fluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 8
- 229910001634 calcium fluoride Inorganic materials 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 239000006229 carbon black Substances 0.000 claims description 8
- 235000019241 carbon black Nutrition 0.000 claims description 8
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 8
- 229910052802 copper Inorganic materials 0.000 claims description 8
- 239000010949 copper Substances 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 8
- 239000004005 microsphere Substances 0.000 claims description 8
- BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 8
- 229910052709 silver Inorganic materials 0.000 claims description 8
- 239000004332 silver Substances 0.000 claims description 8
- 229910001887 tin oxide Inorganic materials 0.000 claims description 8
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims description 7
- 229910000906 Bronze Inorganic materials 0.000 claims description 7
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 7
- 239000010974 bronze Substances 0.000 claims description 7
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical class CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 7
- 230000001419 dependent Effects 0.000 claims description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 7
- 229910052749 magnesium Inorganic materials 0.000 claims description 7
- 239000011777 magnesium Substances 0.000 claims description 7
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 7
- 239000003973 paint Substances 0.000 claims description 7
- 229920000197 polyisopropyl acrylate Polymers 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 7
- 229910052725 zinc Inorganic materials 0.000 claims description 7
- 239000011701 zinc Substances 0.000 claims description 7
- OYLGJCQECKOTOL-UHFFFAOYSA-L Barium fluoride Chemical compound [F-].[F-].[Ba+2] OYLGJCQECKOTOL-UHFFFAOYSA-L 0.000 claims description 6
- JRPBQTZRNDNNOP-UHFFFAOYSA-N Barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 claims description 6
- 229910001006 Constantan Inorganic materials 0.000 claims description 6
- XCAUINMIESBTBL-UHFFFAOYSA-N Lead(II) sulfide Chemical compound [Pb]=S XCAUINMIESBTBL-UHFFFAOYSA-N 0.000 claims description 6
- 229910000831 Steel Inorganic materials 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 229910001632 barium fluoride Inorganic materials 0.000 claims description 6
- 229910002113 barium titanate Inorganic materials 0.000 claims description 6
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 6
- 229910052797 bismuth Inorganic materials 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 239000011651 chromium Substances 0.000 claims description 6
- 150000002222 fluorine compounds Chemical class 0.000 claims description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052737 gold Inorganic materials 0.000 claims description 6
- 239000010931 gold Substances 0.000 claims description 6
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052741 iridium Inorganic materials 0.000 claims description 6
- 239000000395 magnesium oxide Substances 0.000 claims description 6
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 6
- 229910052976 metal sulfide Inorganic materials 0.000 claims description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 239000011733 molybdenum Substances 0.000 claims description 6
- 239000010956 nickel silver Substances 0.000 claims description 6
- AJCDFVKYMIUXCR-UHFFFAOYSA-N oxobarium;oxo(oxoferriooxy)iron Chemical compound [Ba]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O AJCDFVKYMIUXCR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052763 palladium Inorganic materials 0.000 claims description 6
- 229910052697 platinum Inorganic materials 0.000 claims description 6
- 150000003346 selenoethers Chemical class 0.000 claims description 6
- 239000011775 sodium fluoride Substances 0.000 claims description 6
- 235000013024 sodium fluoride Nutrition 0.000 claims description 6
- 239000010959 steel Substances 0.000 claims description 6
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 6
- 229910052715 tantalum Inorganic materials 0.000 claims description 6
- 239000011135 tin Substances 0.000 claims description 6
- 229910052718 tin Inorganic materials 0.000 claims description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 6
- 229910052721 tungsten Inorganic materials 0.000 claims description 6
- 239000010937 tungsten Substances 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- GTLQJUQHDTWYJC-UHFFFAOYSA-N zinc;selenium(2-) Chemical compound [Zn+2].[Se-2] GTLQJUQHDTWYJC-UHFFFAOYSA-N 0.000 claims description 6
- ZLNQQNXFFQJAID-UHFFFAOYSA-L Magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000001095 magnesium carbonate Substances 0.000 claims description 5
- 239000011776 magnesium carbonate Substances 0.000 claims description 5
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052984 zinc sulfide Inorganic materials 0.000 claims description 5
- WPYVAWXEWQSOGY-UHFFFAOYSA-N Indium antimonide Chemical compound [Sb]#[In] WPYVAWXEWQSOGY-UHFFFAOYSA-N 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 4
- 239000000956 alloy Substances 0.000 claims description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 4
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 4
- 230000005684 electric field Effects 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims description 4
- 239000010445 mica Substances 0.000 claims description 4
- 229910052618 mica group Inorganic materials 0.000 claims description 4
- 239000011707 mineral Substances 0.000 claims description 4
- 235000010755 mineral Nutrition 0.000 claims description 4
- 238000010422 painting Methods 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- FYUWIEKAVLOHSE-UHFFFAOYSA-N ethenyl acetate;1-ethenylpyrrolidin-2-one Chemical compound CC(=O)OC=C.C=CN1CCCC1=O FYUWIEKAVLOHSE-UHFFFAOYSA-N 0.000 claims description 3
- VNNBZUFJRRODHO-UHFFFAOYSA-N prop-2-enenitrile;prop-1-en-2-ylbenzene Chemical compound C=CC#N.CC(=C)C1=CC=CC=C1 VNNBZUFJRRODHO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- PZZYQPZGQPZBDN-UHFFFAOYSA-N Aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N HF Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 2
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 239000004809 Teflon Substances 0.000 claims description 2
- ANOBYBYXJXCGBS-UHFFFAOYSA-L Tin(II) fluoride Chemical compound F[Sn]F ANOBYBYXJXCGBS-UHFFFAOYSA-L 0.000 claims description 2
- 239000007983 Tris buffer Substances 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 229910001618 alkaline earth metal fluoride Inorganic materials 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- 239000003849 aromatic solvent Substances 0.000 claims description 2
- 239000000969 carrier Substances 0.000 claims description 2
- UOUJSJZBMCDAEU-UHFFFAOYSA-N chromium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Cr+3].[Cr+3] UOUJSJZBMCDAEU-UHFFFAOYSA-N 0.000 claims description 2
- 239000003086 colorant Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 229920001940 conductive polymer Polymers 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000002019 doping agent Substances 0.000 claims description 2
- 238000004043 dyeing Methods 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 239000010433 feldspar Substances 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 2
- 239000006260 foam Substances 0.000 claims description 2
- 150000002334 glycols Chemical class 0.000 claims description 2
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims description 2
- 229910052738 indium Inorganic materials 0.000 claims description 2
- 239000011256 inorganic filler Substances 0.000 claims description 2
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 2
- 229910010272 inorganic material Inorganic materials 0.000 claims description 2
- 239000011147 inorganic material Substances 0.000 claims description 2
- 229910000460 iron oxide Inorganic materials 0.000 claims description 2
- 239000002923 metal particle Substances 0.000 claims description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N o-xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 2
- 239000011368 organic material Substances 0.000 claims description 2
- 150000002979 perylenes Chemical class 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 239000002798 polar solvent Substances 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 239000011528 polyamide (building material) Substances 0.000 claims description 2
- 229920000767 polyaniline Polymers 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920000128 polypyrrole Polymers 0.000 claims description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 2
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 claims description 2
- 150000004760 silicates Chemical class 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 238000001228 spectrum Methods 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 229920001169 thermoplastic Polymers 0.000 claims description 2
- 239000004416 thermosoftening plastic Substances 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 239000010456 wollastonite Substances 0.000 claims description 2
- 229910052882 wollastonite Inorganic materials 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- 239000004020 conductor Substances 0.000 claims 2
- 229910052981 lead sulfide Inorganic materials 0.000 claims 2
- 229940056932 lead sulfide Drugs 0.000 claims 2
- 125000004122 cyclic group Chemical group 0.000 claims 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000005259 measurement Methods 0.000 description 15
- 238000001035 drying Methods 0.000 description 13
- GVZNXUAPPLHUOM-UHFFFAOYSA-N 2-[1-(1-methoxypropan-2-yloxy)propan-2-yloxy]propan-1-ol Chemical compound COCC(C)OCC(C)OC(C)CO GVZNXUAPPLHUOM-UHFFFAOYSA-N 0.000 description 10
- WHJKCPTVEYZNOG-UHFFFAOYSA-N 6-(hydroxymethyl)-5-methoxy-2-[4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane-3,4-diol Chemical compound COCC1OC(OC)C(OC)C(OC)C1OC1C(O)C(O)C(OC)C(CO)O1 WHJKCPTVEYZNOG-UHFFFAOYSA-N 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 229920005789 ACRONAL® acrylic binder Polymers 0.000 description 6
- 239000012463 white pigment Substances 0.000 description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N Iron(III) oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 235000014647 Lens culinaris subsp culinaris Nutrition 0.000 description 3
- 244000043158 Lens esculenta Species 0.000 description 3
- MKALOVJHPRAZRE-UHFFFAOYSA-N 5-phenylpenta-2,4-dienoic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=CC=CC1=CC=CC=C1 MKALOVJHPRAZRE-UHFFFAOYSA-N 0.000 description 2
- 239000002313 adhesive film Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000565 sealant Substances 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- DNMNDNSFJMUUFM-UHFFFAOYSA-N Prussian blue Chemical compound [Fe+3].[Fe+3].[Fe+3].[Fe+3].N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N.N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N.N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N DNMNDNSFJMUUFM-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000000996 additive Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- YCEJLNKYYGDNTD-UHFFFAOYSA-L barium(2+);oxozinc;sulfanylidenezinc;sulfate Chemical compound [Ba+2].[Zn]=O.[Zn]=S.[O-]S([O-])(=O)=O YCEJLNKYYGDNTD-UHFFFAOYSA-L 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000003595 spectral Effects 0.000 description 1
Abstract
The invention relates to a coating material comprising a binding agent with high transparency in the thermal infrared range;first, plate-shaped particles, which reflect in the wavelength range of thermal infrared, and/or first spherical particles which backscatter in the wavelength range of thermal infrared;and/or second spherical particles which, in the dry state, have and/or form a hollow space, and consist of a material which is transparent in the thermal infrared range;second particles which reflect and/or backscatter in the wavelength range of visible light from 0.35-0.7&mgr;m, and are transparent in the wavelength range of thermal infrared, and/or polymer pigments which are transparent in the thermal infrared range and which, in the dry state, have and/or form a hollow space;third spherical particles which are electrically conductive and have a low absorption in the thermal infrared range;other admixtures known per se, that are usually used for coating.
Description
COATING MATERIAL
Description of the invention
It may be desirable to save energy in houses and buildings if the coating materials on the outside and / or inside could absorb solar energy without emitting it again directly into the thermal infrared wavelength range.
Normally, the white coating materials used as wall paints have the following spectral properties:
The reflection in the wavelength range of visible light from 0; 35 to 0.7 is greater than 80%. The absorption in the near infrared wavelength range of '0.7 to 2.5 μm increases by 10%' to 0.7 μm to approximately 50% to 2.5 μm. The emission in the thermal infrared wavelength range of 8 to 14 μm, typically falls on average by 90%.
REF .: 30449 However, since the solar radiation has its maximum energy approximately 1 μm, it might be desirable to achieve an absorption that is as high as possible with the coating material, starting from 0.7 μm, for example directly adjacent to the range of visible light. In this, the sun provides 7 times more energy in the short half wave of the near infrared as in the long half wave. In addition, it is desirable to not re-emit the energy absorbed in the thermal infrared wavelength range of 8 to 14 μm.
In the German patent DE-A 195 01 114, the coating materials which only partially re-emit the solar energy absorbed in e-1 long wavelength range of thermal radiation are described. However, the particles introduced here for the absorption of solar energy lead to a more or less strong darkening of the coating material in the visible range.
The absorbent coating materials, dark, which can capture most of the solar energy do not correspond to the aesthetic needs of the inhabitants of the house. Very clear, white or at least almost white coating materials are desired.
German Patent DE-A 195 01 114 discloses a coating material of this type, which can have a relatively bright or clear appearance but has a very low degree of effectiveness with respect to solar absorption.
In addition, it is desirable that the walls of the house in zones of temperate to cold climate have a degree of emission dependent on the angle, which allows less energy to be radiated "towards the cold sky, but which receives the thermal radiation of the predominantly hot floor. In contrast, in hot climatic zones it is desirable to select a degree of emission directed towards the sky, which is as large as possible, because the heat can be conducted towards the predominantly clear sky in desert regions, while the irradiation thermal of the hot surroundings is reflected.
and / or first spherical particles that are backscattered (backscattering of Wed) in the wavelength range of the thermal infrared from 5 to 100 μm, but at least from 5 to 25 μm, and have a degree of transmission in this length range of wave of at least 20%, and are present as single crystals, where the average diameter d of the first spherical particles is determined by the formula
d = 10 μm / 2.1 • '(nT? o - nB? o) / where
n-rio = index of refraction of the first spherical particle, at the wavelength of 10 μm and nB? o = index of refraction of the binding agent at the wavelength of 10 μm
and / or second spherical particles having and / or forming a hollow space in the dry state, which are comprised of a material having a degree of transmission in the thermal infrared range of 5 to 100 μm, but at least 5 to 25 μm, greater than 20%, preferably greater than 30% and backscattered and / or reflected in the thermal infrared wavelength range from 5 to 100 μm, but at least 5 to 25 μm, and whose average diameter is from 2 to 20 μm.
c) the second particles that reflect and / or backscatter in the wavelength range of visible light from 0.35 to 0.7 μm and have a degree of transmission in the thermal infrared wavelength range of 5 to 100 μm, but at least from 5 to 25 μm, greater than 20%, preferably greater than 40%, and which are present as single crystals, wherein the average diameter d of the second particle is determined by the formula:
d = 0.55 μm / 2.1 • (nt0.55 - nBo.5s), where
nto.55 = index of refraction of the second particle, at the wavelength of 0.55 μm and nBo.55 = index of refraction of the binding agent at the wavelength of 0.55 μm
and / or polymeric pigments having a degree of transmission in the thermal infrared range of 5 to 100 μm, but at least 8 to 14 μm, greater than 20%, preferably greater than 30%, and which have and / or they form a hollow space in the dry state, where the average diameter of the polymeric pigment particles is 0.2 to 2 μm, preferably 0.3 to 1 μm
d) the third spherical particles, which are electrically conductive and have an absorption ba a in the thermal infrared range of 5 to 25 μm less than 80%, preferably less than 60%, and whose average diameter is 0.1 to 2 μm , preferably 0.2 to μm
e) other known additives that are typically used in coatings, namely solvents such as water, aromatic solvents such as solvent naphtha, xylene, toluene, polar solvents such as alcohols and thickening agents, thixotropic agents, foam anti-foaming agents, dispersing agents for the given particles, additives for the reduction of the film-forming temperature such as glycols and benzene.
It should be understood that the average diameter or average particle size is the diameter for the particle size that reaches values in the respectively named ranges, and are present in a normal distribution around this value.
Advantageous embodiments of the subject matter of the invention are provided in the dependent claims.
An advantageous embodiment of the subject matter of the invention is characterized in that the binder agent is selected from:
a) the group of aqueous dispersions and emulsions comprising dispersions and emulsions based on acrylic, styrene acrylate, polyethylene, polyethylene oxide, copolymers of ethylene-acrylic acid, methacrylate, copolymers of vinylpyrrolidone-vinyl acetate, polyvinylpyrrolidone, isopropyl acrylate , polyurethane and / or
b) from the group of solvent-containing binding agents which comprise acrylic groups, cyclized rubber, butyl rubber, hydrocarbon resin, copolymers of α-methylstyrene-acrylonitrile, polyester imide, butyl esters of acrylic acid,
ethers of polyacrylic acid, polyurethanes, aliphatic polyurethanes, chlorosulfonated polyethylene and / or
c) from the group of thermoplastic materials such as polyolefins and polyvinyl compounds, especially polyethylene, polypropylene, Teflon and polyamide.
An advantageous embodiment of the subject matter of the invention is characterized in that the first plate-shaped particles consist of at least one material that is selected from:
a) metal and / or 'selected metal alloys of aluminum, aluminum-bronze, antimony, chromium, iron, gold, iridium, copper, magnesium, molybdenum, nickel palladium, platinum, silver, tantalum, bismuth, tungsten, zinc, tin, brass, brass, nickel-brass, nickel-chrome alloy, nickel, constantan (40% nickel alloy and 60% copper), manganine and steel.
b) and / or of materials, electrically non-conductive which are coated or covered with metal or
Selected metal alloys of aluminum, aluminum-bronze, antimony, chromium, iron, gold, iridium, copper, magnesium, molybdenum, nickel, palladium, platinum, silver, tantalum, bismuth, tungsten, zinc, tin, bronze, brass, nickel- brass, nickel / chrome alloy, nickel, constantan, manganine, steel or tin oxide electrically conductive
c) and / or the first plate-shaped particles are formed as laminated pigments which are constructed of at least three layers, wherein the layer
• intermediate has a refractive index smaller than the outer layers, and whose materials are selected from the group of materials that have a transmission greater than 20%, preferably greater than
40%, ~ eñ ~ "the thermal infrared wavelength range of 5 to 25 μm comprising:
(1) inorganic materials such as metal sulfides selected from zinc sulphide and lead sulphide, metal selenides such as zinc selenide, fluorides selected from calcium fluoride, lithium fluoride, barium fluoride and sodium fluoride,. antimonides such as indium antimonide, selected metal oxides 12
of zinc oxide, magnesium oxide, antimony oxide, barium titanate, barium ferrite, barium sulfate, calcium sulfate and mixed crystals of the aforementioned materials, and electrically conductive tin oxide
(2) and / or organic materials selected from acrylate, styrene acrylate, polyethylene, polyethylene oxide, chlorosulfonated polyethylene, ethylene-acrylic acid copolymers, methacrylate, vinylpyrrolidone-vinyl acetate copolymers, polyvinylpyrrolidone, polyisopropyl acrylate, polyurethanes, rubber cyclized, butyl rubber, hydrocarbon resin, copolymers of tyne-acrylonitrile α-methyl, polyester imide, acrylic acid butyl esters, polyacrylic acid esters whose refractive index can be selectively increased by the addition of colloidal metal particles.
An additional advantageous embodiment of the subject matter of the invention is characterized in that the first spherical particles consist of at least one material selected from
metal sulfides such as zinc sulphide and lead sulphide, metal selenides such as zinc selenide, fluorides such as calcium fluoride, lithium fluoride, barium fluoride and sodium fluoride, carbonates such as calcium carbonate or carbonate of magnesium, of antimonides such as anti-indium oniride, of metal oxides such as zinc oxide, magnesium oxide, antimony oxide, barium titanate, barium ferrite, calcium sulfate, barium sulfate and mixed crystals of the materials quoted, selected from mixed crystals of barium sulfate with zinc sulphide, such as Saptleben Chemie lithopones
A further advantageous embodiment of the subject matter of the invention is characterized in that the material of the second spherical particles consists of at least one material which is selected from
acrylate, styrene acrylate, acrylonitrile copolymer, polyethylene, polyethylene oxetate, chlorosulfonated polyethylene, 14
ethylene-acrylic acid copolymer, methacrylate, vinylpyrrolidone-vinyl acetate copolymer, vinylidene chloride copolymer, polyvinylpyrrolidone, polyisopropyl acrylate, polyurethane, cyclized rubber, butyl rubber, hydrocarbon resin, tireno-acrylonitrile a-methyl copolymer , polyester imide, acrylic acid butyl esters, polyacrylic acid esters.
A further advantageous embodiment of the subject matter of the invention is characterized in that the second particles consisting of at least one material that is selected from:
metal sulfides such as zinc sulphide, and lead sulphide, metal selenides such as zinc selenide, fluorides selected from calcium fluoride, lithium fluoride, barium fluoride and sodium fluoride, carbonates such as carbonate calcium or magnesium carbonate, of antimonides such as indium antimonide of metal oxides such as zinc oxide, magnesium oxide,
antimony oxide, barium titanate, barium ferrite, calcium sulfate, barium sulfate and mixed crystals of the aforementioned materials, such as mixed crystals of barium sulfate with zinc sulphide such as Saptleben Chemie lithopones.
A further advantageous embodiment of the subject matter of the invention is characterized in that the material of the second particles, which are present as the polymeric pigment, consist of at least one material that is selected from:
acrylate, styrene acrylate, acrylonitrile copolymer, polyethylene, polyethylene oxide, chlorosulfonated polyethylene, ethylene-acrylic acid copolymer, methacrylate, vinylpyrrolidone-vinyl acetate copolymer, vinylidene chloride copolymer, polyvinylpyrrolidone, polyisopropyl acrylate,. polyur-ethane, cyclized rubber, - butyl rubber, hydrocarbon resin, copolymer of tyne-acrylonitrile α-methyl, polyester imide, esters 16
acrylic acid butyl esters, polyacrylic acid esters.
A further advantageous embodiment of the subject matter of the invention is characterized in that the third spherical particles are electrically conductive particles that are clear or transparent in the visible range, which consist of at least one material that is selected from:
a) the group of metals such as aluminum, antimony, chromium, iron, gold, iridium, copper, magnesium, molybdenum, nickel, palladium, platinum, silver, tantalum, bismuth, tungsten, zinc and tin
b) and / or from the group of metal alloys such as brass, brass, nickel-brass, nickel / chrome, nickel, constantan, manganine and steel
and / or from the group of electrically conductive polymers such as polypyrrole or polyaniline, the diameter of which is 0.1 to 1.2 times the average wavelength of 0.55 μm of visible light, and is 17
preferably smaller than the average wavelength of visible light.
d) and / or the group of electrically conductive coated pigments such as from the group of silicates such as talc, kaolin, mica, feldspar, wollastonite, silicon dioxide from the group of metal oxides such as titanium dioxide or barium sulfate, which are coated with tin oxide doped with antimony or doped with fluorine
and / or from the group of pigments that are produced by doping with known doping agents such as alkali metal, ammonium or alkaline earth metal fluorides as well as tin (II) fluoride, hydrogen fluoride and antimonium oxide (I II) ) as well as electrically conductive tin oxide
f) and / or the group of conductive carbon blacks whose diameter '' falls by 0.1 '' to 1.2 'times the average wavelength of visible light of 0.55 μm, and 18
is preferably smaller than the average wavelength of visible light,
g) and / or group of mineral materials with natural electrical conductivity, such as zinc blende.
A further advantageous embodiment of the subject matter of the invention is characterized in that at least one additional filler is added which is transparent in the wavelength range of visible light and has a low refractive index, less than 2.5, preferably lower of 2.0, in the thermal infrared wavelength range of 5 to 10 μm, but at least in the wavelength range of 5 to 25 μm and has a low absorption of less than 80%, preferably less than 60%, in this wavelength range, and whose average particle size is from 0.3 to 30 μm, preferably from 0.5 to 20 μm.
A further advantageous embodiment of the subject matter of the invention is characterized in that at least one additional filler is selected from the group consisting of inorganic fillers such as a filler.
such as calcium carbonate, calcium sulfate, calcium fluoride, magnesium carbonate and / or the group of organic fillers such as acrylate, acrylonitrile copolymers, vinylidene chloride copolymers, styrene acrylate, polyethylene, polyethylene oxide, chlorosulfonated polyethylenes , copolymers of ethylene-acrylic acid, methacrylate, copolymers of vinylpyrrolidone-vinyl acetate, polyvinylpyrrolidone, polyisopropyl acrylate, polyurethanes, or cyclized rubber, butyl rubber, hydrocarbon resin, copolymers of a-methyl-urea-acrylonitrile, imide of polyester, butyl esters of acrylic acid, esters of polyacrylic acid.
A further advantageous embodiment of the subject matter of the invention is characterized in that at least one additional filler is present in the form of hollow microspheres and has an average diameter of 20 to 250 μm, preferably of 40 to 120 μm.
A further advantageous embodiment of the subject of interest of the invention is characterized in that
it uses at least one type of pigment for painting, for dyeing in the visible range, which has a high transmission, greater than 40%, preferably greater than 60%, in the thermal infrared wavelength range of 5 to 25 μm , and has a high absorption greater than 30%, preferably greater than 50%, in the complete solar spectrum of 0.4 to 2.5 μm, which is selected from the group of inorganic pigments for painting, especially metal oxides such as iron oxide, chromium oxides, but also tris (hexacyanoferrates (II)) of the formula Fe4 (Fe (CN) 6] 3 such as blue iron mannox from Degussa and the group of organic pigments for paints such as the Black S0084 from Paliogel (trademark commercial) of BASF from the group of perylenes.
A further advantageous embodiment of the subject matter of the invention is characterized in that the first plate-shaped particles are of the type which are alignable by an electric field or a magnetic field and cause a degree of emission dependent on the angle of the complete array .
twenty-one
A further advantageous embodiment of the subject matter of the invention is characterized in that metals and materials that react on the surface are protected by fatty acids, by chromization or phosphatization.
A further advantageous embodiment of the subject matter of the invention is characterized in that the first particles are in the form of a plate of material. electrically non-conductive, they are made of plastic or mineral mica.
A further advantageous embodiment of the subject matter of the invention is characterized in that a coating material with one of the previous characteristics is used, wherein the coating material must contain the first particles in the form of a plate and because the electric field and / or the magnetic field is applied during and / or after the application of the coating material to a carrier.
The subject matter of the invention is more closely described in the following by means of the Examples.
22
Example 1
280 g of water 4 g of thickening agent Tylose MH 2000 BASF 300 g of polymeric pigment emulsion Clothes OP-62 Rohm and Haas 180 g of dispersion of styrene-acrylate Mowilith DM
611 Hoechst 120 g of polyethylene oxidate Poligen E1 BASF 3 g of anti-foaming agent Byk 023 3 g of pigment dispersant N BASF 70 g of electrically conductive pigment Sacon P401
Sachtleben 650 g of Sachtolith L Sachtleben 40 g of water 70 g of aluminum flakes Reflexal
100 Eckart 5 g Dowanol TPM Dow Chemicals
After dispersion in a mixer, the materials were spread on a commercial card for color test with which the firmness and opacity of the color can also be tested, and esp-e'ctraímente-measured later, of the drying.
The results were as follows 23
The reflection in the light range from 0.35 to 0.7 μm was 78%. The absorption in the near infrared range from 0.7 to 2.5 μm was on average 40%. The emission in the thermal radiation range from 8 to 14 μm was on average 54%. The broadband measurement of the coating with a thermo-battery from 6 to more than 100 μm resulted in an emission degree of 51%. The visual impression was white. Despite the high degree of whiteness, the solar absorption in the near infrared interval was very good. Only 51% of the solar energy obtained in this way was lost by the emission.
Example 2
280 g of water 4 g of thickening agent Tylose MH 2000 BASF 300 g of polymeric pigment emulsion Clothing OP-62 Rohm and Haas 180 g of styrene-acrylate dispersion Mowilith DM
611 Hoechst 80 g acrylate dispersion Mowilith DM 771 Hoeschst 24
40 g of wax emulsion W-842 N Keim-Additec 3 g of anti-foaming agent Byk 023 3 g of pigment dispersant N BASF 50 g of stabilized, ultra-fine brass pigment, particle size 1 μm Eckart 300 g of Sachtolith L Sachtleben 40 g of water 350 g of resin sealant GR Heubach 110 g of stainless steel flakes SS Fine Water
Grade Novamet USA 5 g Dowanol TPM Dow Chemicals
After dispersion in a mixer, the materials were spread on a commercial card for color test, with which firmness and opacity can also be tested, and was spectrally measured after drying.
The results were as follows
The reflection in the light range from 0.35 to 0.7 μm was 75%. The absion in the near infrared range from 0.7 to 2.5 μm was on average 46%.
The emission in the range of thermal radiation from 8 to 14 μm was on average 52%. The broadband measurement of the coating with a thermo-battery from 6 to more than 100 μm resulted in an emission level of 49%.
3
320 g of water 6 g of thickening agent Tylose MH 2000 BASF 200 g of polymeric pigment emulsion Clothes OP-62 Rohm and Haas 160 g of styrene-acrylate dispersion Acronal
290D BASF 120 g acrylate dispersion Mowilith DM 771
Hoechst 3 g defoaming agent Byk 023 3 g pigment dispersant N BASF 60 g stabilized silver pigment, micronized, particle size less than 1 μm 3 g conductive carbon black, micronized, particle size less than 0.4 μm 300 g of coarse white pigment of zinc sulphide, particle size of 4 to 5 μm, Sachtleben 50 g of Sachtolith L Sachtleben 26
g of Dowanol TPM Dow Chemicals
After dispersion in a mixer, the materials were spread on a commercial card for color test, with which firmness and opacity can also be tested, and was spectrally measured after drying.
The results were as follows:
The reflection in the light range from 0.35 to 0.7 μm was 82%. The absion in the near infrared range from 0.7 to 2.5 μm was on average 38%. The emission in the thermal radiation range of 8 to 14 μm was on average 55%. The broadband measurement of the coating with a thermo-battery from 6 to more than 100 μm resulted in an emission degree of 59%.
Example 4
280 g of water. ' '' 4 g thickening agent Tylose MH 20Ó0'BASF 27
300 g of polymeric pigment emulsion Ropague 0P- 62 Rohm and Haas 120 g of acrylate styrene-acrylate dispersion
290D BASF 180 g acrylate dispersion HG-54K Rohm and Hass
3 g of anti-foaming agent by Byk 023 3 g of pigment dispersant N BASF 90 g of zinc blende, micronized, d50 = 1.5 μm
Metallgesell schaft 500 g of Sachtolith L 40 g of water 200 g of resin sealant GR Heubach 150 g of stainless steel flakes SS Fine Water
Grade Novamet USA 5 g Dowanol TPM Dow Chemicals
After dispersion in a mixer, the materials were spread on / a commercial card for color test, with which firmness and opacity can also be tested, and spectrally measured after drying. The results were as follows:
The reflection in the light range from 0.35 to 0.7 μm was 73%.
28
The absion in the near infrared range from 0.7 to 2.5 μm was on average 47%. The emission in the thermal radiation range from 8 to 14 μm was on average 55%. The broadband measurement of the coating with a thermo-battery from 6 to more than 100 μm resulted in an emission degree of 59%.
Example 5
320 g of Alpex Hoechst 64 g of Novares LA 300 Rütger VFT AG (35 g of solvent naphtha 180/210 65 g of Sachtolith HD-S Sachtleben 11 g of Tego Conduct UF Goldscmidt 50 g of zinc flakes Nova et USA
After dispersion in a mixer, the materials were spread on a commercial card for color test, with which firmness and opacity can also be tested, and spectrally measured after drying.
The results were like. follow 29
The reflection in the light range from 0.35 to 0.7 μm was 70%. The absorption in the near infrared range from 0.7 to 2.5 μm was on average 43%. The emission in the thermal radiation range from 8 to 14 μm was on average 49%. The broadband measurement of the coating with a thermo-battery from 6 to more than 100 μm resulted in an emission degree of 47%.
Example 6
320 g of water 6 g of thickening agent Tylose MH 2000 BASF 100 g of polymeric pigment emulsion Clothes OP-62 Rohm and Haas 160 g of styrene-acrylate dispersion Acronal
290D BASF 120 g acrylate dispersion Mowilith DM 771 Hoechst 3 g defoaming agent Byk 023 3 g dispersant. pigment N BASF 0.5 g conductive carbon black, micronized, particle size less than 0.4 μm 3 g Black Paliogen S0084 from BASF 30
300 g of coarse white pigment of zinc sulphide, particle size of 5-9 μm, Sac tleben 100 g of crystalline calcium carbonate, O and 5 g of Dowanol TPM Dow Chemicals
After dispersion in a mixer, the materials were spread on a commercial card for color test, with which firmness and opacity can also be tested, and was spectrally measured after drying.
The results were as follows:
The reflection in the light range from 0.35 to 0.7 μm was 70%. The absorption in the near infrared range from 0.7 to 2.5 μm was on average 42%. The emission in the thermal radiation range from 8 to 14 μm was on average 54%. The broadband measurement of the > coating with a thermo-battery from 6 to more than 100 μm, resulted in an emission rating of 57%.
31
Example 7
320 g of water 6 g of thickening agent Tylose MH 2000 BASF 100 g of polymeric pigment emulsion Clothes OP-62 Rohm and Haas 160 g of styrene-acrylate dispersion Acronal
290D BASF 120 g acrylate dispersion Mowilith DM 771 Hoechst 3 g defoaming agent Byk 023 3 g pigment dispersant N BASF 1.5 g conductive carbon black, micronized, particle size less than 0.4 μm 200 g thick white pigment of zinc sulphide, size. of particle 5-9 μm, Sachtleben 50 g of calcium carbonate, crystalline, Omya 4 g of hollow polyethylene microefers, bulk density 0.03-0.9 g / cm3 5 g of Dowanol TPM Dow Chemicals
After dispersion in a 'mixer,' the materials' were scattered over a card
- commercial for color test, with -which can 32
firmness and opacity were also tested, and it was measured spectrally after drying.
The results were as follows:
The reflection in the light range from 0.35 to 0.7 μm was 78%. The absorption in the near infrared range from 0.7 to 2.5 μm was on average 38%. The emission in the range of thermal radiation from 8 to 14 μm was on average 52%. The wideband measurement of the coating with a thermo-battery from 6 to more than 100 μm resulted in an emission degree of 57%.
The density of the paint could be reduced by 25% by the use of hollow microspheres.
Example 8
320 g of water 6 g of thickening agent Tylose MH 2000 BASF 100 ~~ g of "" emulsion, of polymeric pigment Clothes OP- 62 Roíi and Haas.
33
160 g of acrylate styrene-acrylate dispersion
290D BASF 120 g of "" dispersion of acrylate Mowilith DM 771
Hoechst 3 g of anti-foaming agent Byk 023 3 g of pigment dispersant N BASF 1 g of conductive carbon black, micronized, particle size less than 0.4 μm 3 g of Black Paliogen S0084 of BASF 2 g of blue iron Mannox, Degussa 200 g of coarse white pigment of zinc sulphide, particle size 5-9 μm, Sachtleben 50 g of calcium carbonate, crystalline, Omya 2 g of hollow microspheres Expancel, bulk density 0.3 - 0.8 g / cm3 5 g of Dowanol TPM Dow Chemicals
After dispersion in a mixer, the materials were spread on a commercial card for color test, with which firmness and opacity can also be tested, and was spectrally measured after drying.
The results were as follows 34
The reflection in the light range from 0.35 to 0.7 μm was 62%. The absorption in the near infrared range from 0.7 to 2.5 μm was on average 44%. The emission in the thermal radiation range from 8 to 14 μm was on average 58%. The broadband measurement of the coating with a thermo-battery from 6 to more than 100 μm resulted in an emission degree of 60%.
The density of the paint could be reduced by 25% by the use of hollow microspheres.
9
320 g of water 6 g of thickening agent Tylose MH 2000 BASF 100 g of polymeric pigment emulsion Clothes OP-62 Rohm and Haas 160 g of styrene-acrylate dispersion Acronal
290D BASF 120 g acrylate dispersion Mowilith DM 771 Hoechst 3 g defoaming agent Byk 023 3 g pigment dispersant N BASF 35
1. 5 g conductive carbon black, micronized, particle size less than 0.4 μm 1.5 g red iron oxide Bayferrox 720 N Bayer
200 g of coarse white pigment of zinc sulfide, particle size of 5-9 μm, Sachtleben 50 g of calcium carbonate, crystalline, Omya 3 g of hollow polyethylene microspheres, bulk density 0.05-1.3 g / cm3 5 g of Dowanol TPM Dow Chemicals
After dispersion in a mixer, the materials were spread on a commercial card for color test, with which firmness and opacity can also be tested, and was spectrally measured after drying.
The results were as follows
The reflection in the light range from 0.35 to 0.7 μm was 64%. The absorption in the near infrared range from 0.7 to 2.5 μm was on average 47%. The emission in the range of thermal radiation from 8 to 14 μm was on average 55%. The 'broadband measurement of the coating with a thermo-battery 37
Self-adhesive coated in this manner had an emission degree, dependent on the angle, in the thermal infrared range, as well as a darker or lighter shade depending on the direction of observation.
The reflection in the visible light range from 0.35 to 0.7 was 35% in the angular range from 0o to 45 °, and 78% from 45 ° to 180 °. The emission in the thermal radiation range from 8 to 14 μm was 90% in the angular range from 0 to 45 ° and 58% from 45 ° to 180 °. The broadband measurement of the coating with a thermo-battery from 6 to more than 100 μm, resulted in an emission degree of 90% in the angular range from 0 ° to 45 °, and an emission degree of 56% from 45 ° up to 180 °.
Example 11
280 g of water 4 g of thickening agent Tylose MH 2000 BASF 300 g of emulsion of. polymeric pigment Ropague. OP- 62 'Rohm and Haas- _ 120 g of styrene-acrylate dispersion Acronal 290D BASF 1.5 g of conductive carbon black, micronized, particle size less than 0.4 μm 1.5 g of red iron oxide Bayferrox 720 N Bayer
200 g of coarse white pigment of zinc sulfide, particle size of 5-9 μm, Sachtleben 50 g of calcium carbonate, crystalline, Omya 3 g of hollow polyethylene microspheres, bulk density 0.05-1.3 g / cm3 5 g of Dowanol TPM Dow Chemicals
After dispersion in a mixer, the materials were spread on a commercial card for color test, with which firmness and opacity can also be tested, and was spectrally measured after drying.
The results were as follows
The reflection in the light range from 0.35 to 0.7 μm was 64%. The absorption in the near infrared range from 0.7 to 2.5 μm was on average 47%. The emission in the range of thermal radiation from 8 to 14 μm was on average 55%. Broadband measurement of the coating with a texmo battery from 6 to more than 100 μm resulted in an emission degree of 58%.
The density of the paint could be reduced by 20% by the use of hollow polyethylene microspheres.
Example 10
500 g of Desmoderm A Bayer Finishing 50 g of Desmoderm Z Bayer additive 10 g of electrically conductive pigment Sacon P401
Sachtleben 50 g calcium carbonate, crystalline, Omya 50 g Sachtolith HD-S Sachtleben 150 g stainless steel flakes SS Novamet USA
After the dispersion in a mixer the materials were coated by knife on a self-adhesive film. In the wet state, the stainless steel flakes in the binder were aligned with a large-area electromagnet, in such a way that they took an angle of 45 degrees to the surface standards. After drying the coa, the self-adhesive film coated in this way had an emission degree, dependent on the angle, in the thermal infrared range, as well as a darker or lighter shade depending on the direction of observation.
The reflection in the visible light range from 0.35 to 0.7 was 35% in the angular range from 0o to 45 °, and 78% from 45 ° to 180 °. The emission in the thermal radiation range from 8 to 14 μm was 90% in the angular range from 0 ° to 45 ° and 58% from 45 ° to 180 °. The broadband measurement of the coa with a thermo-battery from 6 to more than 100 μm; resulted in an emission degree of 90% in the angular range from 0 ° to 45 °, and an emission degree of 56% from 45 ° to 180 °.
Example 11 - 280 g of water 4 g of thickening agent Tylose MH 2000 BASF 300 g of emulsion of. polymeric pigment Ropague. OP- 62 'Rohm and Ha s •' '"120 g dispersion-styrene-acrylate Acronal 290D BASF 180 g acrylate dispersion HG-54K Rohm and Haas 3 g antifoam agent Byk 023 3 g pigment dispersant N BASF 50 g of electrically conductive pigment, Sacon P401 Sachtleben 500 g of Sachtolith L 40 g of water 200 g of Harzsiegel GR Heubach 5 g of Dowanol TPM Dow Chemicals 100 g of aluminum lentils Dragon 20/90, treated superficially
The materials were mixed without the aluminum lentils and applied with a paint roller to a vertical wall. The Dragon aluminum lentils were introduced with an artificial velvet apparatus into the wet coa material, in such a way that it assumed an angle of 45 ° oriented downward to the standard surface of the vertical wall. After drying the coa, the wall coated in this way had an emission degree dependent on the angle, in the thermal infrared range. The wall covered in this way had a lower degree of emission towards the sky than towards the floor.
The emission in the thermal radiation range from 8 to 14 μm was 92% in the angular range of
0 '45 °, and 56% from 45 ° to 180 ° The broadband measurement of the coa with a thermo-battery from 6 to more than 100 μm, resulted in an emission degree of 92% in the angular range of 0 to 45 °, and an emission degree of 55% from 45 ° to 180 °.
Comparative Example
The following mixture was based on a formulation cited in the German patent DE-A 195 01 114:
200 g of polyethylene dispersion Poligen PE of
BASF 200 g dispersion polyethylene (oxidate) Poligen
BASF WE1 40 g acrylate dispersion Mowilith DM 771 Hoechst 2 g defoaming agent Byk 023 30 g Collacral VL as a thickener 240 g water "• •. '400 g sealer. silver lithopone from Sachtleben GmbH 80 g aluminum flakes Aquasil BP 2750 from Silberline
After dispersion in a mixer, the materials were spread on a commercial card for color test, with which firmness and opacity can also be tested, and was spectrally measured after drying.
The results were as follows:
The reflection in the light range from 0.35 to 0.7 μm was 67%. The absorption in the near infrared range from 0.7 to 2.5 μm was on average 29%. The emission in the range of thermal radiation from 8 to 14 μm was on average 71%. The broadband measurement of the coa with a thermo-battery from 6 to more than 100 μm resulted in an emission level of 68%.
The visual impression was too gray, corresponding to the low reflection in the visible range. The solar absorption in the near infrared range is 29% less than in the coating material according to the invention, and the emission in the thermal radiation range is smaller than the customary coating materials, but still too high.
Summary of Measurement Results
It is noted that in relation to this date, the best method known to the applicant to carry out the aforementioned invention, is that which is clear from the present description of the invention.
Claims (16)
1. A "coating material", characterized in that it comprises: a) a binder with high transparency of at least 30%, preferably greater than 50%, in the visible light range of 0.35 to 0.7 μm and with at least 20%, preferably greater than 40%, in the thermal infrared range from 5 to 100 μm, at least 5 to 15 μm, b) first plate-like particles reflecting in the thermal infrared wavelength range of 5 to 100 μm, but at least 5 to 25 μm, and whose dimensions are LXBXT, L = 5 -100 μm, B ' = 5 - 100 μm and T = 0.1 - 5 μm, preferably L = --- 30 - 60 μm, B = 30 - 60 μm and T = 0.5 - 1.5 μm, where 'L ~ length B = width. and T = thickness. and / or first spherical particles that are backscattered (backscattering of Wed) in the wavelength range of the thermal infrared from 5 to 100 μm, but at least from 5 to 25 μm, and have a degree of transmission in this length range wave of at least 20%, and are present as oncrystals, where the average diameter d of the first spherical particles is determined by the formula d = 10 μm / 2.1 • (nT? o - nB? 0), where nT? o_ = index of refraction of the first spherical particle, at the wavelength of 10 μm and nB? o = Index. de_ refraction of the binding agent at the wavelength of 10 μm and / or second spherical particles having and / or forming a hollow space in the dry state, which are comprised of a material having a degree of transmission in the thermal infrared range of 5 to 100 μm, but at least 5 to 10 μm. up to 25 μm, greater than 20%, preferably greater than 30% and retrodispe.rsan and / or reflect in the thermal infrared wavelength range from 5 to 100 μm, but at least 5 to 25 μm, and whose average diameter is 2 to 20 μm. c) second particles that reflect and / or backscatter in the wavelength range of visible light from 0.35 to 0.7 μm and have a degree of transmission in the thermal infrared wavelength range of 5 to 10 μm, but at less from 5 to 25 μm, greater than 20%, preferably greater than 40%, and which are present as monochromes, where the average diameter d of the second particle is determined by the formula: d = 0.55 μm / 2.1 • (nTo.55 - nB0.5s) f where nTo.55 = index of refraction of the second particle, at the wavelength of 0.55 μm and nBo.5s = refractive index of the binding agent at the wavelength of 0.55 μm and / or polymeric pigments having a degree of transmission in the thermal infrared range from 5 to 10.0 μm, but at least from 8 to 14 μm, greater than 20%, preferably greater than 30%, and which have and / or form a hollow space in the dry state, wherein the average diameter of the polymeric pigment particles is 0.2 to 2 μm, preferably 0.3 to 1 μm d) third spherical particles, which are electrically conductive and have a low absorption in the thermal infrared range of 5 to 25 μm less than 80%, preferably less than 60%, and whose average diameter is 0.1 to 2 μm, preferably 0.2 to μm e) other known additives which are typically used in coatings, namely solvents such as water, aromatic solvents such as solvent naphtha, xylene, toluene, polar solvents such as alcohols and thickening agents, ixotropic agents, foam anti-foaming agents, dispersing agents for the given particles, additives for the reduction of the film-forming temperature such as glycols and benzene.
2. The coating material. according to claim 1, characterized in that the binding agent is selected from: a) el. group of aqueous dispersions and emulsions comprising dispersions and emulsions based on acrylate, styrene acrylate, polyethylene, polyethylene oxide, copolymers of ethylene-acrylic acid, methacrylate, copolymers of vinylpyrrolidone-vinyl acetate, polyvinylpyrrolidone, isopropyl acrylate, polyurethane and /or b) of the group of solvent-containing binder agents which comprise acrylic groups, cyclized rubber, butyl rubber, hydrocarbon resin, copolymers of α-methylstyrene-acrylonitrile, polyester imide, acrylic acid butyl esters, polyacrylic acid ethers, polyurethanes, aliphatic polyurethanes, chlorosulfonated polyethylene and / or c) from the group of thermoplastic materials such as polyolefins and polyvinyl compounds, especially polyethylene, polypropylene, Teflon and polyamide.
3. The coating material according to claim 1, characterized in that the first plate-shaped particles consist of at least one material that is selected from a) metal and / or metal alloys selected from aluminum, aluminum-bronze, antimony, chromium, iron, gold, iridium, copper, magnesium, molybdenum, nickel palladium, platinum, silver, tantalum, bismuth, tungsten, zinc, tin, bronze , brass, nickel-brass, nickel-chrome alloy, nickel, constantan (40% nickel alloy and 60% copper), manganine and steel. b) and / or of electrically non-conductive materials which are coated or covered with selected metal or metal alloys of aluminum, aluminum-bronze, antimony, chromium, iron, gold, iridium, copper, magnesium, molybdenum, nickel, palladium, platinum , silver, tantalum, bismuth, tungsten, zinc, tin, bronze, brass, nickel-brass, nickel / chrome alloy, nickel, constantan, manganine, steel or electrically conductive tin oxide c) and / or the first particles in the form Plates are formed as laminated pigments which are constructed of at least three layers, wherein the intermediate layer has a refractive index smaller than the outer layers, and whose materials are selected from the group of materials having a transmission greater than 20. %, preferably greater than 40%, in the thermal infrared wavelength range of 5 to 25 μm comprising: (1) inorganic materials such as metal sulfides selected from zinc sulphide and lead sulfide, metal selenides such as zinc selenide, fluorides selected from calcium fluoride, lithium fluoride, barium fluoride and sodium fluoride, antimonides such as antimony of indium, metal oxides selected from zinc oxide, magnesium oxide, antimony oxide, barium titanate, barium ferrite, barium sulfate, calcium sulfate and mixed crystals of the aforementioned materials, and electrically conductive tin oxide (2) and / or organic materials selected from acrylate, styrene acrylate, polyethylene, polyethylene oxide, chlorosul phonated polyethylene, ethylene-acrylic acid copolymers, methacrylate, vinylpyrrolidone-vinyl acetate copolymers, polyvinylpyrrolidone, polyisopropyl acrylate, polyurethanes, cyclic rubber, butyl rubber, hydrocarbon resin, copolymers of α-methylstyrene-acrylonitrile, polyester imide, butyl esters of acrylic acid, polyacrylic acid esters whose refractive index can be selectively increased by the addition of colloidal metal particles.
J 4. The coating material according to claim 1, characterized in that the first spherical particles consist of at least one material that is selected from: metal sulphides such as zinc sulphide and lead sulphide, metal selenides such as zinc selenide, fluorides such as calcium fluoride, lithium fluoride, barium fluoride and sodium fluoride, carbonates such as calcium carbonate or magnesium carbonate, antimonides such as indium antimonide, metal oxides such as zinc oxide, magnesium oxide, antimony oxide, barium titanate, barium ferrite, calcium sulfate, barium sulfate and mixed crystals of the materials cited, selected from mixed crystals of barium sulphate with zinc sulphide, such as Saptleben Chemie lithopones
5. The coating material according to claim 1, characterized in that the material of the second spherical particles consists of at least one material that is selected from: acrylate, styrene acrylate, acrylonitrile copolymer, polyethylene, polyethylene oxide, chlorosulfonated polyethylene, ethylene-acrylic acid copolymer, methacrylate, vinylpyrrolidone-vinyl acetate copolymer, vinylidene chloride copolymer, polyvinylpyrrolidone, polyisopropyl acrylate, polyurethane, cyclized rubber, • butyl rubber, hydrocarbon resin, α-methylstyrene-acrylonitrile copolymer, polyester imide, acrylic acid butyl esters, polyacrylic acid esters.
6. The coating material according to claim 1, characterized in that the second particles consist of at least one material that is selected from: metal sulfides such as zinc sulphide, and lead sulfide, of metal selenides such as zinc selenide, of fluorides "selected from calcium fluoride, lithium fluoride, barium fluoride and sodium fluoride, carbonates such as calcium carbonate or magnesium carbonate, of antimonides such as indium antimonide of metal oxides such as zinc oxide, magnesium oxide, antimony oxide, barium titanate, barium ferrite, calcium sulfate, barium sulfate and mixed crystals of the materials mentioned, such as mixed crystals of barium sulfate with zinc sulphide such as the lithopones of 'S'achtleben Chemie ..
7. The coating material according to claim 1, characterized in that the material of the second particles, which are present as a polymeric pigment, consist of at least one material that is selected from: acrylate, styrene acrylate, acrylonitrile copolymer, polyethylene, polyethylene oxide, chlorosulfonated polyethylene, ethylene-acrylic acid copolymer, methacrylate, vinylpyrrolidone-vinyl acetate copolymer, vinylidene chloride copolymer, polyvinylpyrrolidone, polyisopropyl acrylate, polyurethane, cyclized rubber, butyl rubber, hydrocarbon resin, α-methylstyrene-acrylonitrile copolymer, polyester imide, acrylic acid butyl esters, polyacrylic acid esters.
8. The coating material according to claim 1, characterized in that the third spherical particles are electrically conductive particles that are clear or transparent in the visible range, consisting of at least one material that is selected from: a) the group of metals such as aluminum, antimony, chromium, iron, gold, iridium, copper, magnesium, molybdenum, nickel, palladium, platinum, silver, tantalum, bismuth, tungsten, zinc and tin b) and / or from the group of metal alloys such as brass, brass, nickel-brass, nickel / chrome, nickel, constantan, manganine and steel c) and / or of the group of electrically conductive polymers such as polypyrrole or polyaniline, whose diameter is 0.1 to 1.2 times the average wavelength of 0.55 μm of visible light, and is preferably smaller than the average wavelength of the visible light. d) and / or the group of electrically conductive coated pigments such as the group of silicates such as talc, kaolin, mica, feldspar, wollastonite, silicon dioxide from the group of metal oxides such as titanium dioxide or barium sulfate. , which are coated with tin oxide doped with antimony or doped with fluorine e) and / or of the group of pigments which are produced by doping with known doping agents such as alkali metal, ammonium or alkaline earth metal fluorides as well as tin (II) fluoride, hydrogen fluoride and antimony oxide (III) ) as well as electrically conductive tin oxide f) and / or the "group of conductive carbon blacks whose diameter falls by 0.1 to 1.2 times the average wavelength of visible light of 0.55 μm, and is preferably smaller than the average wavelength of visible light, g) and / or group of mineral materials with natural electrical conductivity, such as zinc blende.
9. The reclosing material according to claim 1, characterized in that at least one additional filler is added which is transparent in the wavelength range of visible light and has a low refractive index, less than 2.5, preferably less than 2.0, in the thermal infrared wavelength range of 5 to 100 μm, but at least in the wavelength range of 5 to 25 μm and has a low absorption of less than 80%, preferably less than 60%, in this wavelength range, and whose average particle size is from 0.3 to 30 μm, preferably 0.5 to 20 μm.
10. The coating material according to claim 9, characterized in that at least one additional filler is selected from the group consisting of inorganic fillers such as calcium carbonate, calcium sulfate, calcium fluoride, magnesium carbonate and / or group of organic fillers such as acrylate, acrylonitrile copolymers, vinylidene chloride copolymers, styrene acrylate, polyethylene, polyethylene oxide, chlorosulfonated polyethylenes, ethylene-acrylic acid copolymers, methacrylate, vinylpyrrolidone-vinyl acetate copolymers, polyvinylpyrrolidone, acrylate polyisopropyl, polyurethanes, or cyclized rubber, butyl rubber, hydrocarbon resin, α-methylstyrene-acrylonitrile copolymers, polyester imide, acrylic acid butyl esters, polyacrylic acid esters.
11. The coating material according to claim 9 or 10, characterized in that at least one additional filler is present in the form of hollow microspheres and has an average diameter of 20 to 250 μm, preferably 40 to 120 μm.
12. The coating material according to claim 1, characterized in that at least one type of pigment is used for painting, for dyeing in the visible range, which has a high transmission, greater than 40%, preferably greater than 60%, in the thermal infrared wavelength range of 5 to 25 μm, and has a high absorption greater than 30%, preferably greater than 50%, in the entire solar spectrum of 0.4 to 2.5 μm, which is selected from the group of pigments inorganic for painting, especially metal oxides such as iron oxide, chromium oxides, but also tris (hexacyanoferrates (II)) of the formula Fe (Fe (CN) 6] 3 such as blue iron mannox from Degussa and from the group of organic pigments for paints such as the Black S0084 of Paliogel (trade mark) of BASF of the group of the perylenes.
13. The coating material according to claim 1, characterized in that the first plate-shaped particles are of the type that are alignable by an electric field or a magnetic field and cause a degree of emission dependent on the angle of the complete array.
14. The coating material according to claim 1, 3 or 8, characterized in that the metals and materials that react superficially are protected by fatty acids, by chromization or phosphatization.
15. The coating material according to claim 1 or 3, characterized in that the first plate-shaped particles of electrically non-conductive material are plastic or mineral mica.
16. A method for applying a coating material, characterized in that a coating material is used according to any of the previous claims, wherein the coating material must contain the first particles in the form of a plate and because the electric field and / or the Magnetic field is applied during and / or after the application of the coating material to a carrier.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19650300.0 | 1996-12-04 | ||
| DE19650300A DE19650300A1 (en) | 1996-12-04 | 1996-12-04 | Paint |
| PCT/DE1997/002831 WO1998024852A1 (en) | 1996-12-04 | 1997-12-03 | Coating material |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| MX9905165A MX9905165A (en) | 2000-04-30 |
| MXPA99005165A true MXPA99005165A (en) | 2000-09-04 |
| MX206829B MX206829B (en) | 2002-02-21 |
Family
ID=7813630
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX9905165A MX206829B (en) | 1996-12-04 | 1997-12-03 | COATING MATERIAL |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US6194484B1 (en) |
| EP (1) | EP0942954B1 (en) |
| JP (1) | JP2001508091A (en) |
| KR (1) | KR100466788B1 (en) |
| CN (1) | CN1183207C (en) |
| AT (1) | ATE213760T1 (en) |
| AU (1) | AU716875B2 (en) |
| BR (1) | BR9713563A (en) |
| CA (1) | CA2273238C (en) |
| DE (2) | DE19650300A1 (en) |
| DK (1) | DK0942954T3 (en) |
| ES (1) | ES2169443T3 (en) |
| HK (1) | HK1020284A1 (en) |
| MX (1) | MX206829B (en) |
| NZ (1) | NZ336006A (en) |
| WO (1) | WO1998024852A1 (en) |
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| PT1137722E (en) * | 1998-10-26 | 2004-10-29 | Gerd Hugo | COATING WITH SPECTRAL SELECTIVITY |
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| DE10038381A1 (en) * | 2000-08-07 | 2002-02-28 | Gerd Hugo | Flat arrangement with dark surface and low solar absorption |
| DE10044216A1 (en) | 2000-09-07 | 2002-05-02 | Fraunhofer Ges Forschung | Coating material for multifunctional, superphobic layers |
| DE10102789A1 (en) * | 2001-01-22 | 2002-08-01 | Gerd Hugo | Coating with low solar absorption |
| GB2403724A (en) * | 2003-07-11 | 2005-01-12 | Qinetiq Ltd | Thermal infrared reflective coatings |
| US7601400B2 (en) * | 2005-03-10 | 2009-10-13 | General Electric Company | Liquid electrostatic coating composition comprising corrosion resistant metal particulates and method for using same |
| US7544396B2 (en) * | 2005-03-10 | 2009-06-09 | General Electric Company | Electrostatic coating composition comprising corrosion resistant metal particulates and method for using same |
| US7740682B2 (en) * | 2005-07-22 | 2010-06-22 | Ragan Randall C | High-density composite material containing tungsten powder |
| SE529327C2 (en) * | 2005-11-09 | 2007-07-03 | Totalfoersvarets Forskningsins | Ways of creating a low-missive surface and using a color to create a low-missive |
| GB0606604D0 (en) * | 2006-04-01 | 2006-05-10 | P W Circuts Ltd | Treatment apparatus |
| TWI374922B (en) * | 2006-12-29 | 2012-10-21 | Eternal Chemical Co Ltd | Anti-uv coating composition and the use thereof |
| US9056988B2 (en) * | 2007-02-05 | 2015-06-16 | Ppg Industries Ohio, Inc. | Solar reflective coatings and coating systems |
| US8822025B2 (en) * | 2007-02-05 | 2014-09-02 | Ppg Industries Ohio, Inc. | Coating system exhibiting cool dark color |
| JP2010000460A (en) * | 2008-06-20 | 2010-01-07 | Tohoku Univ | Radiation heat transfer control film |
| JP5430093B2 (en) * | 2008-07-24 | 2014-02-26 | デクセリアルズ株式会社 | Conductive particles, anisotropic conductive film, joined body, and connection method |
| CN101434494B (en) * | 2008-12-12 | 2012-01-04 | 广东万兴无机颜料股份有限公司 | Gold-bearing tin oxide ceramic pigment and preparation thereof |
| US8679617B2 (en) | 2010-11-02 | 2014-03-25 | Prc Desoto International, Inc. | Solar reflective coatings systems |
| CN102464932B (en) * | 2010-11-16 | 2016-03-30 | 罗门哈斯公司 | Infrared reflective coating composition |
| CN102477240A (en) * | 2010-11-24 | 2012-05-30 | 深圳市名雕装饰股份有限公司 | Floor protective paint |
| CN102477238B (en) * | 2010-11-24 | 2013-12-25 | 深圳市名雕丹迪设计有限公司 | Water-based varnish |
| US9057835B2 (en) | 2011-06-06 | 2015-06-16 | Ppg Industries Ohio, Inc. | Coating compositions that transmit infrared radiation and exhibit color stability and related coating systems |
| CN102295898B (en) * | 2011-06-08 | 2012-05-30 | 丁建民 | Configuration and coating method of aluminium foil precoat nano conductive carbon primary coat liquid |
| EP2753666B1 (en) * | 2011-09-06 | 2020-04-08 | Basf Se | Infrared-absorbing white and light-coloured paints |
| CN102383334B (en) * | 2011-10-24 | 2013-07-03 | 吴江市天源塑胶有限公司 | Dichloroethylene water-based paint |
| WO2013068363A1 (en) * | 2011-11-09 | 2013-05-16 | Basf Se | Use in paper coatings of a mixture of a secondary polymeric dispersion and of a primary dispersion of an emulsion polymer |
| CA2871737C (en) * | 2012-04-30 | 2020-08-25 | 3M Innovative Properties Company | High solar-reflectivity roofing granules utilizing low absorption components |
| DE112013002445T5 (en) * | 2012-05-11 | 2015-02-26 | Coatings Foreign Ip Co. Llc | Aqueous coating composition comprising stabilized color pigments |
| CN115595569A (en) * | 2013-03-16 | 2023-01-13 | Prc-迪索托国际公司（Us） | Azole compounds as corrosion inhibitors |
| JP2015078338A (en) * | 2013-09-11 | 2015-04-23 | ナガセケムテックス株式会社 | Composition for formation of functional film and functional film laminate |
| CN106062095A (en) * | 2014-10-23 | 2016-10-26 | 亮源产业（以色列）有限公司 | High-temperature solar-absorptive coatings with high thermal conductivity and low emissivity, and methods for use thereof |
| CN104403392B (en) * | 2014-11-07 | 2018-05-11 | 长安大学 | Road surface coating material and its application for reducing bituminous paving temperature |
| DE202016006686U1 (en) | 2016-07-21 | 2016-11-11 | Brillux Gmbh & Co. Kg | Aqueous coating agent |
| DE102016121807A1 (en) * | 2016-11-14 | 2018-05-17 | Joint Stock Company Railway Research Institute | Solar radiation-reflecting coating and its use |
| RU175366U1 (en) * | 2017-05-15 | 2017-12-01 | федеральное государственное бюджетное образовательное учреждение высшего образования "Национальный исследовательский университет "МЭИ" (ФГБОУ ВО "НИУ "МЭИ") | Heat insulating structure |
| CN111989375B (en) * | 2018-05-11 | 2022-03-01 | 富士胶片株式会社 | Coating agent, antifogging film, method for producing antifogging film, and laminate |
| CN112724753A (en) * | 2019-10-28 | 2021-04-30 | 罗惠民 | Solar coating composition, solar coating, preparation method of solar coating and electricity storage device |
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| ATE10642T1 (en) * | 1981-02-13 | 1984-12-15 | Guenter Dr.-Ing. Pusch | CAMOUFLAGE COATING WITH BROAD EFFECT. |
| DE3432998C3 (en) * | 1984-09-07 | 1993-12-02 | Gerd Hugo | Camouflage color |
| US4916014A (en) * | 1987-10-30 | 1990-04-10 | Paul Weber | I.R. reflecting paint |
| DE3903023A1 (en) * | 1989-02-02 | 1990-08-09 | Basf Ag | METAL OXIDE-COATED GLOSS PIGMENTS |
| JP2593968B2 (en) * | 1991-02-08 | 1997-03-26 | 新日鐵化学株式会社 | Solar heat shielding black paint composition and coated structure |
| DE59206491D1 (en) * | 1991-12-21 | 1996-07-11 | Roehm Gmbh | IR reflecting body |
| JP3375993B2 (en) * | 1992-10-19 | 2003-02-10 | サカイオーベックス株式会社 | Method for producing light-heat conversion sheet |
| DE4418214C2 (en) * | 1994-05-25 | 1999-02-04 | Gerd Hugo | Paint with low emissivity in the area of thermal radiation |
| DE19501114C2 (en) * | 1995-01-17 | 2001-01-18 | Gerd Hugo | Paint with reflective properties in two wavelength ranges and absorbent properties in a third wavelength range |
-
1996
- 1996-12-04 DE DE19650300A patent/DE19650300A1/en not_active Withdrawn
-
1997
- 1997-12-03 NZ NZ336006A patent/NZ336006A/en not_active IP Right Cessation
- 1997-12-03 WO PCT/DE1997/002831 patent/WO1998024852A1/en active IP Right Grant
- 1997-12-03 CA CA002273238A patent/CA2273238C/en not_active Expired - Lifetime
- 1997-12-03 KR KR19997004868A patent/KR100466788B1/en not_active IP Right Cessation
- 1997-12-03 ES ES97952704T patent/ES2169443T3/en not_active Expired - Lifetime
- 1997-12-03 AT AT97952704T patent/ATE213760T1/en active
- 1997-12-03 BR BR9713563-1A patent/BR9713563A/en not_active IP Right Cessation
- 1997-12-03 AU AU56503/98A patent/AU716875B2/en not_active Expired
- 1997-12-03 CN CNB97180253XA patent/CN1183207C/en not_active Expired - Lifetime
- 1997-12-03 JP JP52506498A patent/JP2001508091A/en active Pending
- 1997-12-03 MX MX9905165A patent/MX206829B/en unknown
- 1997-12-03 EP EP97952704A patent/EP0942954B1/en not_active Expired - Lifetime
- 1997-12-03 DE DE59706522T patent/DE59706522D1/en not_active Expired - Lifetime
- 1997-12-03 DK DK97952704T patent/DK0942954T3/en active
-
1999
- 1999-06-04 US US09/325,969 patent/US6194484B1/en not_active Expired - Lifetime
- 1999-11-19 HK HK99105362A patent/HK1020284A1/en not_active IP Right Cessation
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