MXPA98009608A - Hair dye compositions and process - Google Patents

Abstract

A composition for oxidative dyeing of hair comprising, by weight of the total composition;0.0001-20%of at least one primary intermediate and at least one coupler for the formation of oxidation dyes, 0.01-10%of a 2-hydroxyphenyl benzotriazole compound which absorbs ultraviolet radiation in the wavelength range of 200 to 400 nanometers, 0.5-20%surfactant, and 10-65%water;a two component kit containing the hair dye composition and a developer, and a method for oxidative dyeing of hair with said kit.

Description

TECHNICAL FIELD The invention pertains to the field of hair dyeing methods and compositions. BACKGROUND OF THE INVENTION Oxidizing dye systems are employed for permanent dyeing of hair. However, hair dyed with Oxidizing dyes tend to break down when exposed to sunlight, and red tones are especially susceptible. Accordingly, there is a need for hair dye systems that exhibit improved resistance to fading when exposed to light or to the skin. ra.vio 1.eta »The object of the present invention is to provide a system of dyes for the hair that shows an improved resistance to color fading caused by light ravialet" Compendium of the invention The invention focuses on a composition for the oxidative dyeing of the hair »said composition comprises 3 by weight of the total composition of approximately e 0.0001 to 20"/» (combined weight) of at least one primary intermediate and at least one coupler for the formation of oxidation dyes "of about 0.01 to 10% of a 2-hydroxyphenylbenzotriazole compound that absorbs radiation ul raviolets within a range of wavelengths of 200 to 400 nm, from approximately 0.5 to 20% surfactant, from approximately 10 to 65% water »The invention also focuses on a set of two components for the oxidative dyeing of the hair, said assembly comprising a first container qu. e contains a composition containing, by weight of the total composition: from about 0.0001 to 20% (combined weight) of at least one primary intermediate and at least one coupler for the formation of the oxidation dyes, from about 0.01 to 10 % of a compound of 2-hydroxyphenylbenzotriazole that absorbs ultraviolet radiation within a range of wavelengths of 200 to 400 nanometers »of approximately 0.5 ~ 20% surfactant, approximately 10 to 65% water, and a second container containing a developer composition comprising, by weight of the total composition _ approximately 0.5 to 45% hydrogen peroxide, from about 0% to 10% of a silicon conditioning agent, from about 0.01 to 5% of an anionic polymer, and from about 99% of water. The invention also comprises a method for oxidant dyeing of the hair, said method comprises the steps of a) applying to the hair a composition obtained by Composition A and Composition B, wherein Composition A comprises, by weight of the total composition, from about 0.0001 to 20. % (combined weight) of at least one primary intermediate and at least one coupler for the formation of oxidation dyes, from about 0.01 to 10% of a 2-hydroxyphenylbenzotriazole compound that absorbs the ultraviolet radiation within the wavelength range from 200 to 400 nanometers, from approximately 0 to 5% to 20% surfactant, and from approximately 10 to 65% water? and Composition B comprises, by weight of the total composition 5 from about 0.5 to 4-5% hydrogen peroxide, from about 0.1 to 10% of a silicon conditioning agent, approximately 0.01 to 5% of a polymer. anionic, and approximately 99% water, b) leave said composition in the hair for a period of 2 a. 60 minutes, c) rinsing the hair with water »Detailed description All the percentages mentioned here are percentages by weight unless otherwise indicated» The compositions of the invention have a pH within a range of 7 to 11, and the Composition A preferably contains 65% or less of water. PRIMARY INTERMEDIATE PRODUCTS AND COUPLERS The composition comprises from 0.0001 to 20%, preferably from 0.001 to 15%, more preferably from 0.01 to 10% (combined weight) of at least one primary intermediate and at least one coupler. Preferably, the primary intermediate range will be from about 0.0001 to 5% by weight and the coupler range will be from about 0.0001 to 5% by weight. The primary intermediates and couplers are well-known ingredients for dyeing hair, and include substituted aminephenols in ortho position or para or biep phenylenediamines, such co or paraphenylenediamines of the formula: where R 1 and R 2 are each independently, hydrogen, alkylene (Cl-C 6), or alkyl (C 1 -C) substituted with one or more hydroxy, methaxy, methylsulfonyl, amino, aminocarbon, or furfuril, unsubstituted phenyl or phene substituted by amino? R3 and R6, each independently, are hydrogen, alkylaryl (Ci-Co) sa coxy (C1-C), halogen, or alkyI (Cl-C6) substituted with one or more hydraxylais groups and R4 and R5 san each xndependien emen, hydrogen, lower alkoxy (Cl-Co), lower alkylation (Cl-Co) to good halogen »Examples of suitable primary intermediates are para-aminophenol, para-diphenol, arta-aminaphenols, ortho-phenylenediamines, ortho -diphenols, and heterocyclic compounds. Examples of suitable primary intermediates include for phenylenediamine, 2-methyl-1,4-dinaminobenzene, 2,6-dimeti 1-1,4-diaminobenzene, 2,5-imethyl-1,4-diamidobenzene , 2,3-di.methyl-i, 4-diaminobenzene, 2-clars-1, 4-diaminobenzene, 2-methaxy-1, 4-diaminobenzene, 1-phenylamino-4-aminebenzene, 1-dimethylamino- 4-aminobenzene, 1- di-il-yl-4-aminebenzene, i-bis (beta-hydroxyethyl) amine-4- to inobenzene, l-methoxyethylamino-4-aminobenzene, 2-hydro ime i 1-1, 4-d iaminobenzene, 2-hydroxyethyl-i, 4-diaminobenzene »2-isapropyl-i, 4-diaminobenzene, 1-hydroxypropyl-4-aminobenzene, 2,6-dimethyl 1-3-axi-1, 4-diaminobenzene, -amino-4-hydraxybenzena, and derivatives thereof »Preferred primary intermediates are p-phenylenedia ina, p-amiphophenal, o-aminophenal, N, N-bis (2-hydroxyethyl) -p-phenylenediamine, 2, 5- diaminaluepo, and mixtures thereof »Suitable couplers include, for example, those that They have the general formula: where R1 is hydroxy to unsubstituted amine, or hydraxy to amine substituted with one to several hydraxyalkyl groups (Cl-C0), R3 and R5 are each independently, hydrogen, hydroxy, amino, or amino substituted with alkyl (Ci-). Co), alkoxy (Cl-Co), or hydroxyalkyl (Cl-Co); and R2, R4 and R6 each, independently, hydrogen, alkoxy (Cl-Co), alkoxy (Ci-Co), hydraxyalkyl (Cl-Co), or alkyl (Cl-Co), or R3 and R4 together they can form a methyl n-dioxy group. Examples of such compounds include meta-derivatives as for example phenols, meta-diphenols, meta-phenophenols, meta-phenylenediamines, and the like, which may be unsubstituted, or substituted on the amino group or on the the benzene ring with alkyl, hydroxyalkyl, alkylamino, and the like groups »Suitable couplers include 3,4-methyldiphenyl ifenol, 3,4-methylenedioxy-i- ((beta-hydroxyeti.1) amino) benzene» 1-methoxy-2 - mine-4- ((beta-hi ro iet.il) amine) benzene, i-hydro i-3- (dimethylamino) benzene, o-methyl-1-hydroxy-3 ((beta-hydra) yl) amine) benzene, 2,4-dicylaro-i-hydra i -3-aminobenzene, 1-hydroxy-3- (diethyl) lamino) benzene, 1-hydro? i-2-methyl 1-3-minobenzene, 2-chloro-o-eti 1-1-hydroxy-3-aminobenzene, 1,3-diaminobenzene, o-methoxy-1, 3- diaminobenzene, o-hid or ie i lo i-1 »3-diaminobenzene, 6-methaxy-5-eti 1-1, 3-diaminobenzene, o-eti loxi-1, 3-diaminebenzene, 1-bi (beta-) hydroxyeti 1) amino-3-aminobenzene, 2-methyl-1, 3-diaminobenzene, o-methoxy-1-amino- ((beta-hydroxyethyl) amine) -benzene, 6- (beta-aminoeti-loxi) -1, 3-diaminobenzene, 6- (beta-hidraxieti loxi) -1- mina-3- (methylamine) benzene, o-carbo imeti loxi-i, 3-diaminobenzene, 6-ethyloxy-l-bis (beta-hydroxyethyl) amipa ~ 3-aminobenzene, o-hydroxyeti 1-1, 3-diaminobenzene, l-hydroxy- 2-isopropyl 1-5-methylstanzene, 1,3-dihydroxybenzene, 2-chloro-l, 3-dihydroxybenzene, 2-methyl-1,3-dihydrobenzene, 4-pale-i, 3-dihyd a iben eno , 5, or ~ dicyar-2-methyl-l, 3-d ihydroxy e-ceno, l-hydroxy-3-amylobenzen, l-hydraxy-3- (carbamoymethyl) benzene, o-hydroxybenzomorphine, 4- et .il-o-dihydroxypyridine, 2,6-dihydroxypyridine, 2,6-diaminopyridine, o-minobenzomarfol iría, 1-phenyl-3- ei 1-5-pirazalone, 1-hydroxynaphthalene, 1,7-dihydraxinaphthalene, 1,5 -dihydroxynaphthalene, and mixtures thereof.

Preferred couplers include resorcinol, 1-naphthol, 5-amino-o-cresol, 2-ethylresorcinol, m-aminafensl, m-phenylenediamine, 1-ohenyl-methyl-iurazole-5-ana, their salts, or mixtures thereof. The COMPOSITE 2-HI.DR0XIFENILBENZ0TRI ZOL The compositions of the present invention contain from 0.01 to 10%, preferably from 0.01 to 8%, more preferably from 0.01 to 5% of a 2-hydroxy-nylbenzotriazole compound capable of absorbing ultraviolet radiation within a wavelength range of 200 to 400 nanometers, preferably of approximately 250 to 390 nanometers »It will be noted that many of the primary intermediate couplers found in hair dyes can absorb ultraviolet (UV) radiation in this range of wavelengths, and it is believed that this is one reason why hair dyes fade when exposed to ultraviolet light. "Without this explanation being a limitation, s It is believed that the benzotriazole compounds used in the compositions of the invention permeate at least partially the sharp size, besides forming complexes with the external surface of the hair fiber. It is believed that they can act as primary absorbers of ultraviolet radiation, thus avoiding , at least by reducing the tendency of the hair dye molecules themselves to absorb UV radiation and as a result of being degraded. Compounds of 2-hydroxyphenylbenzotriazal suitable for use in the compositions of the present invention can be distinguished from the molecules of dye for the hair because, preferably, na contain amino group substituents. The 2-hydrosyphenylbenzatriazales suitable for use in the compositions of the present invention correspond to one of the general formulas (a), (b) and (c), presented below: The compounds of the formula (a) have the general formula; R. where Ri, R2, R3, R4 and R5 each independently are H, hydroxylamino, carbaxyl, halogen, either branched or straight chain alkylated (Cl-C40), straight or branched chain alkoxy (C1-C40) » alkoxycarbonyl (C2-C20), fepilo substituted by a'iquila (Cl-C40), cycloalkyl (C5-Có), S03H, S03Na, or where Ei and E2 are each independent among them, H, to either alkyl ( C1-C4), and E3 is H, halogen, to either alkyl (Cl-C4); R3 is H, halogen, OH, straight or branched chain alkyl (Cl-C40), S03Na, cycloalkyla (C5-Có), phenyl, phenyl substituted by alkylofCl-CIO), a where E1 and E2 are each independently H, either alkyl (C1-C4), and E3 is H, halogen or alkylated (C1-C4) branched or straight chain. Examples of such compounds are presented in US Pat. Nos. 5,240,975. 4,904,712; 4, 921,960. 5,097,041; 5,095,062; 4,973,701; 4,587,346; and 4,675,352. The compounds of the formula (b) have the general formula: where Ti is hydrogen, halogen, alkyl (CÍ-C4), S03H, or S03Na, T2 is alkyl (Cl-CÍ2), S03H or SO-3Na is hydrogen, halogen, or -0E2 E2 is hydrogen or (C1-C18) alkyl, E3 is hydrogen, alky C4), halogen, S03H, or S03Na, E4 is hydrogen, halogen, or EES E5 is hydrogen or alkyl (Ci-C18), and E6 is hydrogen, hydroxyl or carbaxyl. Examples of compounds of this type are presented in U.S. Patent No. 5S7, O91, which is incorporated herein by reference. Esters of 2-hydroxyphenylbenzotriazole having the same formula (c) are also suitable; where R1, R2 and R3 independently of each other, are hydrogenated, halogen, or else an ester-containing radical provided that there is at least one ester-containing radical. Examples of such 2-hydroxyphenylbenzatriazole esters appear in U.S. Patent No. 4,996,326, which is incorporated herein by reference. Benzotriazole fluaripads compounds having the general formula (d) are also suitable as the 2-hydroxyphenyl benzatriazole compound for use in the compositions of the present invention: where Ri is hydrogen, halogen, (Ct-C4) alkyl, or (C10C4) alkoxy, R2 is alkyl (Cl-C18), cycloalkyl of 5 to 12 carbon atoms, or phenylalkylae of 7 to 15 carbon atoms, E is straight or branched chain alkylene of from 1 to 10 carbon atoms to said alkylene is interrupted with 1 to 3 groups selected from the group consisting of -O-, -S-, -S02-, -COO- , -OOC-, and Rf is perfluoroalkyl of straight chain to branched chain of 12 carbon atoms, perfluoroalkyl of 2 a or carbon atoms substituted by one or more perfluoroalkoxy groups of 2 a or carbon atoms, or an aligo terminal group (hexafluoropropene oxide). Examples of such compounds are presented in U.S. Patent No. 5,312,852, which is incorporated herein by reference. The preferred compounds of formula (a) are those compounds in which Ri and R2 are both H. A more preferred subset are the compounds where R1 and R2 are both H, and R3 is S03Na or S03H. A preferred sub-bond of this latter group are the compounds where R1, R2 and R4 are H, R3 is S03Na at either S03H, and R5 is an alkyla (C. 1-C10) of straight or branched chain. The most preferred compound is a compound wherein R1, R2 and R4 are H, R3 is S03Na, and R5 is a branched chain alkyl (Cl-CI). An example is the compound having the CTFA name of .isobutyl benzotriazole. sodium lfanata. This material can be purchased from Ciba-8eigy under the trade name Cibaf st W Liquid, which is an anionic material. THE SURFACTANT The compositions of the present invention comprise from 0.5 to 20%, preferably from 0.5 to 15%, with greater preference of »5 to 1.0% of a surfactant. Suitable surfactants can be anionic, nonionic, amphoteric, or zwitterionic. Anionic Surfact.ant.es anionic surfactants include alkyl sulfates and alkyl ether sulfates generally having the formula R0S03M and R0 (C2H40) xS03M where R is alkyl or alkenyl of about 10 to 20 carbon atoms, x is from 1 to about 10 and M is a water soluble cation such as ps cation ammonium salt, sodium, potassium to triethanolamine »Another type of anionic surfactant which can be employed in the compositions of the present invention are water soluble salts of the reaction of sulfuric acid, organic, of the general formula; Ri-S03-M where R1 is chosen within the rump consisting of a straight or branched chain saturated aliphatic hydrocarbon radical having from about S to about 24 carbon atoms, preferably from 12 to about 18 atoms of carbon; and M is a cation. Examples of such anionic surfactants are salts of the reaction products of organic sulfuric acid of hydrocarbons such as co-n-paraffins having from 8 to 24 carbon atoms, and a suffusing agent such as for example sulfur trioxide. The products of the reaction of fatty acids esterified with isethionic acid and neutralized with sodium hydroxide are also suitable anionic surfactants. Fatty acids can be derived from coconut oil, for example. In addition, succinates and succini atas are suitable anionic surfactants. This class includes compounds such as disodium N-octadecylsulfosuccinate; N- (1,2-dicarboxyethyl) -N-actadecylsulfosuccinate tetrasodium; and Sodiosul fasuccinic acid esters, for example sodium dihexyl ester of sodiosulfosuccinic acid, dioctyl ester of sodiosul fosuccinic acid, and the like. Other suitable anionic surfactants include olefin sulfopates having from about 12 to 24 carbon atoms. The term "olefin sulfonate" refers to a compound that can be produced by the sulfonation of an alpha olefin by means of sulfur trioxide. not complexed, followed by neutralization of the acid reaction mixture under conditions such that sulphonates formed in the reaction hydrolyzed to provide the corresponding hydroxy alkanesulfonates. The alpha-alefin from which the olefin sulfonate is derived is a mono-alefin having from about 12 to 24 carbon atoms, preferably of approximately 14 to 16 carbon atoms. Other suitable classes of organic anionic sulfactants are beta-alkaxyalkanesulphonates or water-soluble soaps such as the fatty acid salts (C10-C20), with or for example soaps based on coconut and tallow. Preferred salts are ammonium, potassium and sodium salts. Another class of anionic surfactants include N-acyl amino acid surfactants and salts thereof (alkali, alkaline earth, and ammonium salts) having the formula: OR R2 I! I R -C - N - (R3) n - COOM where Ri is an alkylaryl (C8-C24) or alkepyl, preferably C10-C18; R2 is H, alkyl (Ci-C4), fepila, a well CH2C00M; R3 is CX2- or (C1-C2) alkoxy, where each X independently is H or Ci-C alkylaryl) or alkyl ester, n is 4, and M is H or a salt that cation ca ca above described. Examples of such surfactants are N-acyl sarcosinates, including lauroyl sarcosinate, myristoyl sarcosinate, cocol sarcosinate, and aleoyl sarcosinate, preferably in sodium or potassium forms. Na ionic surfactants The composition may contain one or more surfactants nonionic instead of anionic surfactant to well in addition to the anionic surfactant. The nonionic surfactant.es are generally compounds produced by the condensation of alkylene oxide groups with? Hydrophobic compound »Classes of non-ionic surfactants are; (a) Long chain dialkyl sulphoxides containing a short chain or hydroxyalkyl alkyl radical of about 1 to 3 carbon atoms, and a long hydrophobic chain which may be an alkyl, alkenyl, hydroxyalkyl radical or either ketoalkyl containing from about 8 to 20 carbon atoms, from O to 10 portions of ethylene oxide, and O or glyceryl portion. (b) Polysorbates, such as fatty acid sucrose esters. Examples of such materials include sucrose cacoata, sucrose behenate, etc. (c) Acryl phenol polyethylene oxide condensates, for example, the condensation product of alkyl phenols having an alkyl group of 6 to 20 carbon atoms, with ethylene oxide present in amounts of about 10 to 60 moles of ethylene oxide per mole of alkyl phenol. (d) Condensation products of ethylene oxide with the reaction product of propylene oxide and ethylenediamine »(e) Condensation products of aliphatic alcohol of 8 to 18 carbon atoms with ethylene oxide, for example, a Condensate of coconut alcohol / ethylene oxide having from 10 to 30 moles of ethylene oxide per mole of coconut alcohol, the fraction of coca alcohol has from 10 to 14 carbon atoms »(f) Tertiary amine oxides long chain such as those corresponding to the general formula: R 1 R 2 R 3 N 0 wherein R 1 contains an alkyl, alkenyl or monahydroxyalkyl radical within a range of 8 to 18 carbon atoms in length, from 0 to about 10 portions of ethylene oxide, and from 0 to about i glyceryl moiety and R2 and R3 are each, alkyl or monohydroxyalkyl groups containing approximately approximately 3 carbon atoms »(g) Long chain tertiary phosphine oxides corresponding to the general formula: RR.1R2P0 where R contains an alkylaryl, alkenyl, or monohydroxyalkyl radical having from 8 to 18 carbon atoms, from 10 portions of etxlena oxide, and or 1 glyceryl portion, and R2 and R3 are each alkyl or monohydroxyalk groups containing from 1 to 3 carbon apices. fh) Alkyl polysuccesses having a hydroxyl group of 6 to 30, preferably 10 carbon atoms and a palxsaccase group with, for example, glucose, galactose, etc. »Suitable alkyl polysaccharides are achila, nonidecil, undecidadodo , tr-i dec la, tetratJecil a, pentadec la, hexadecxlo, heptacyl, and octadecyl, di-, tri-, tetra-, penta-, and hexaglucosides, ga lactosides, lactosides, glucose, fructose, fructose, etc » (x) Glxcerxlo fatty esters of pal letxleng 11 col.PET), of formula RC (0) 0CH2CH (OH) CH2 (0CH2CH) nOH where n is from 5 to 200 and RC (0) - is a group hxdraxxcarbanilo where R is preferably an aliphatic radical or txene of 7 to 19 carbon atoms. "(J) Other non-ionic surfactants that may be employed include fatty acid amides of polyhydroKi-Cl-Co) alkyl (CIO-C18 such as methyl Igluca x) da (C32-C18), fatty acid amides gives pal 3 hxdra? x N-lcox, q] ucam da-s (CÍ2-C18) N-pr opilo to N-he ? etc? S? rfacLan tes Anfot rich Su. fac tantes apfotépco. Which can be used in the »0 Compositions of the invention are generally described as bed derived from aliphatic tertiary secondary amines where an aliphatic radical is a straight or branched chain alkyl of 8 to 18 carbon atoms and the other aliphatic radical contains an anilic group co or per axle. carboxy, sulfonate, sulfate, phosphate or fasfanate. Suitable apothermal surfactants can be composed of imidazolium having the general formula: R3 RlCON (CH.) N -N * -CH2Z I I, R4 R2 where R1 is alkyloxy (C8-C22) or biep alkenyls, preferably (C12-C16); R2 is hydrogen at either CH2C02M, R3 is CH2CH20H or CH2CH20CH2CHC0QM; R4 is hydrogen, CH2CH2QH, or CH2CH20CH2CH2C00M, Z is C02M or CH2C02M, n is 2 or 3, preferably 2, M is hydrogen or a bed cation such as an alkali metal, alkaline earth metal cation, ammonium or alkanolammonium. Examples of such materials are marketed under the trademark MIRANOL, from the Miranol, Inc. company. Amphoteric surfactants are also suitable san manocarboxi cans or dicarbaxy lates such as cacanfacarboxipropionata, cacoanacarboxiprapionic acid, cacanfocarboxiglycinate, and cacaanfsacetate.

Other types of amphoteric surfactants include aminoalkanoates of the formula R-NH (CH2) nC00M to either inodialcanates of the formula R- ((CH2) mCOOM) 2 and mixtures thereof; where n and m are from i to 4, R is (C8-C22) alkyl or alkylene, and M is hydrogen, alkali metal, alkaline earth metal, ammonium or alkanolamine. Examples of such amphoteric surfactants include n-alkylaminopropionates and n-alkyliminodipropiopaths, sold under the trade name MIRATAINE from Mirapal, Inc. or DERIPHAT from Henkel, for example N-lauryl-beta-aminepropionic acid, N-acid -lau.ril-beta-imino-dipropionic, or mixtures thereof. Zwitterionic surfactants are also suitable for s? use in the compositions of the invention »The general formula for such surfactants is (R3) x I R2-Y - CH2-R4-Z- where R2 has u? alkyl, alkenyl or hydroxyalkyl radical of from about 8 to about 18 carbon atoms, from O to approximately 10 portions of ethylene oxide and or 1 portion of glycerals; And it is selected within the rump consisting of nitrogen atoms, phosphor, and sulfur; R3 is an alkyl or monohydroxyalkyl group containing about 1 to 3 carbon atoms; X is 1 when Y is an atom of sulfur, and 2 when Y is a nitrogen atom or phosphorus; R 4 is an alkylene or hydraxyalkylene of about 1 to about 4 carbon atoms, and Z is a radical selected from the group consisting of carboxylate, sulfonate, sulfate, phosphonate, and phosphate groups. Zwitterionic surfactants include betaines for example, higher alkyl betaines, eg, dimethylcarboxymethyl betaine of cocaine, dimethyl laoxymethyl betaine of lauryl, dimethyl lalphacaryoxyethi 1 betaine of lauryl, di ethylcarboxymethylbetaine of cetyl, bis- (2- hydroxyethyl) arboxymethi 1 betaine of lauryl, bis- (2-hydroxypropyl.].) carbox imeti I betaine of stearyl, dimethylgamma-carbaxieti 1 betaine of aleyl, and mixtures of them »Sulphobetaines and idobetaines, such as coconut dimethylsulfopropyl betaine, dimethyl Isul foprapi 1 stearyl betaine, and the like are also suitable. In addition, the compositions of the invention may contain various other ingredients. Preferably, the compositions of the invention comprise from O.01 to 15%, preferably from 0.05 to 10%, preferably from 0.10 to 8% of a conditioning agent. cationic which is a cationic polymer, a quaternary ammonium salt or a salt of a fatty amine. Quaternary ammonium salts have the formula; where Pi is hydrogen, an aliphatic group of i to 22 carbon atoms, or alternatively an aromatic, aryl to alcaryl group having from 12 to 22 carbon atoms; R2 is an aliphatic group that has 1-22 carbon atoms; R3 and R4 are each alkyl groups of l3 carbon atoms, and X is an anion selected from halogen, acetate, phosphate, nitrate and methyl sulfate radicals. The aliphatic groups may contain, in addition to the carbon and hydrogen atoms, ether linkages as well as amide groups. Suitable quaternary ammonium compounds may be long chain monoalkyl, long chain dialkyl, long chain trialkyl, and the like. Examples of such quaternary ammonium salts include behenalcania chloride, behentrimonium chloride, behentrimonium etasulfata, bezalconia chloride, benzethonium chloride, benzyl triethyl aniam chloride, cetalcania chloride, cetrimonium chloride, cetrimapium bromide, cetrimonium metasulfata. , cetrimania tosylate, cetylpyridinium chloride, dibeheni chloride 1 / Idrachidium idimania, dibenthiium chloride, dibennyldimania methosulfate, dicapril / dicapryldimonium chloride, dicetildimonium chloride, and mixtures thereof. Other quaternary ammonium salts useful as a cationic conditioning agent are compounds of the general formula; R. R4 I I R, - - (CH_) 3-N-R6 I I R3 R5 donds Rl is a. aliphatic group having 22 carbon atoms, R2, R3, R4, R5 and R6 are the same or different and are selected from H and alkyl having 1 to 4 carbon atoms and X is an anion according to the above defined »Likewise, salts of quaternary imidaza linio that have the following general formula san also suitable: where R5 is hydrogen or an alkyl (C1-C4); Ró is an alkyl (Cl-C4). R7 is a (C8-C22) alkylaryl; and R8 is hydrogen, to an alkyla (Cl-C22); and X is an anion in accordance with the above defined. Also suitable conditioning agent cationic cabella salt salts of primary, secondary, or tertiary fatty amines, where the substituted groups have 12 to 22 carbon atoms. Examples of such amines include dimethylstearamine, dimethylaminoamine, stearylamine, myristylamine, tridecylamine, ethylstearamine, etc. Cationic polymers also suitable for bedding the cationic conditioning agent are: (a) quaternary derivatives of cellulose ethers, for example, polymeric beds sold under the trademark JR-125, JR-400, JR-30M. Palyquaterniu 10, which is a polymeric quaternary ammonium salt of hydroxyethylcellulose reacted with an epoxide substituted with trimethylammonium, is preferred. (b) Vinylpyrrole idana copolymers having the monomer units of the formula: I. R3 I N-KR ^ RjX 'where R1 is hydrogen or methyl, and preferably methyl; and is either i, preferably 1 R 2 is O or NH, preferably NH; R3 is CxH2x where x is from 2 to 18, or -CH2-CH0H-CH2-, preferably CxH2x where x is 2; R 4 is ethyl, ethyl, phenyl, or phenyl substituted by (C 1 -C 4), preferably methyl; and F.5 is methyl or ethyl, preferably methyl. Compounds of the above formula are preferred where y is i, R2 is NH, R3 is CH2CH2, R4 is methyl and R5 is methyl. Such compounds are known by the CTFA designation. Pol quaterniu 28 »(c) Homopolymer of chloride and dimethyldiallylammonium, or co-polymer of di-ethyldiallylammonium chloride and acrylamide» These compounds are sold under the brand name MERQUAT (mr) of Merck »(d) copolymers derived from a.crylic or methacrylic acid wherein the monomer units are selected from the group consisting of acrylate, methylacrylamide, diacetone-acrylamide, acrylamide to methacrylamide substituted on the nitrogen by lower alkyl, alkyl esters of acrylic acid and methacrylic acid, vipylpyrrole. idon, and vinyl esters. Examples of cationic polymers that can be employed in the compositions of the invention are cationic polymers - "? - presented in U.S. Patents Nos. 5,240,450 and 5,573,709, which are incorporated herein by reference. Preferred compositions of the invention contain from 0.01 to 10%, preferably from 0.05 to 5%, and most preferably from 0.1 to 3%, of a fatty oil. The term "fatty oil" refers to an oil which is in the liquid or semi-liquid state at room temperature and which generally contains at least one fatty compound derived from fatty acids having alkyl, saturated or unsaturated, straight-chain or branched, groups of 6 to 25 carbon atoms »Preferred fatty acid glyceryl esters »Examples of such oils include saxifrage seed oil, apricot kernel oil, avocado oil, babassu oil, borage oil, castor oil, coconut oil, corn oil, oil hazelnut, olive oil, palm oil, flax oil, and all the fatty oils presented on pages 507-508 of the Cosmetic Ingredient Handbook, CTFA, Second Edition, 1992, which is incorporated herein by reference. of saxifrage seed »It may also be desirable to include from 0.001 to 5%, preferably from 0.005 to 4%, with a preference of. 05 to 5% by weight from one to several preservatives. The same percentage ranges of emulsifiers and humectants can also be included in the composition »_8? In general, the dye compositions of the present invention are in the form of creams, which means that they have a smooth creamy texture which does not run or drip when applied to the hair. The invention also focuses on a two-component assembly for . the oxidative hair dyeing, which comprises a first container containing the composition comprising, by weight of the total composition; from 0.0001 to 20% at least one primary intermediate product and at least one coupler for the formation of oxidation dyes, from 0.01 to 10% of a 2-hydroxyfenic compound Ibenzotriazole that absorbs ultraviolet radiation in the range of lengths of wave of 200 to 400 nanometers, of 0 to 5% of surfactant, and of 10 to 65% of water; and a second container containing a developer composition comprising, by weight of the total composition: from 0.5 to 45% hydrogen peroxide, from 0.1 to 10% of a sil.icone hair conditioning agent; from 0.01 to 5% of an anionic polymer, and from 1 to 99% of water. Silicone hair conditioning agents "? they are present in the developer composition in 0.1 to 10%, preferably 0.5 to 8%, more preferably 0.5 to 5% of the total revealing composition. Suitable conditioning and silicate conditioning agents include volatile volatile ionic silicone fluids, silicone resins, and silicone solids or semi-solids. Volatile silicones are linear or cyclic silicones having a measurable vapor pressure, which is defined as a vapor pressure of at least 2 mm of mercury at 20 ° C. Examples of volatile silicones are cyclic silicones having the general formula; where n = 3-7 »Likewise, linear, variable silicones can be used in the compositions of the invention, having the general formula: (CH3) 3Si-Q- (Si (CH3) 2-0) n-Si (CH3 ) 3 where n = 0-7, preferably 0-5. The silicone hair conditioning agent may comprise water-insoluble, non-volatile silicone fluids including polyalkyl loxanes, polyalkyl, polyalkylarylsiloxanes, palylethylsiloxane copalimers, silicones with amine functionality, and mixtures thereof. Such silicates have the following general formula: where R and R * are each independently, alkylate, aryla, or an alky substituted with one or more amine groups, and "?" and "and" are each independently 0-100,000, provided "x + y" is equal to at least one and A is a siloxi end unit. It is preferred if A is methyl, R1 is methyl, and R 'is a substituted alkyl with at least one amino group, more preferably a silicone with a ".mine functionality" of the formula: CHCH3 I CH2 I NH I CH2 I CH2 I NH2 which is known in CTFA as trimethylsilyllamodimethicone. The silicone hair conditioning agent can also be a silicone polymer having the following general formula: "(RR'R") 3SiOl / 21 FsiO! where R, R * and R "are each independently a straight or branched chain phenyla or alkyl (Ci-CIO), and" x "and" y "such as the ratio between the units of (RR'Ra) 3Si0i / 2 and the Si02 units is 0.5 to 1.5 to 1.

Preferably R, R 'and R "are an alkyl (Cl-Co), and more preferably are methyl and" x "and" and "san such that the ratio between the units of (CH3) 3Si01 / 2 and the units of Si02 is from 0.75 to 1. It is even more preferred that this dimethylaxy silicate cantenga of 2.4 to 2.9% by weight of hydraxyl groups, formed with the reaction of the sodium salt of silicic acid, chlorotri ethylsilapa, and isapropyl alcohol »The manufacture of trimethylsilaxy silicate is presented in U.S. Patent Nos. 2,67, 182, 3,54, 120, and 3,836,437, which are incorporated herein by reference. The described trimethylsilicate silicate is available from Dow Corning Corporation under the trade name 2-0749 and 2-0747, each of which is a mixture of about 4-60% volatile silicana and 40-60% trimethylsilicate laxy. Dow Corning 2-0749, particularly, it is a fluid containing approximately 50% trimethylsilaxy silicate and approximately 50% cyclomethicone. The fluid has a viscosity of 200 to 700 centipaise at a temperature of 25 ° C, a specific gravity of 1.00 to 1.10 at a temperature of 25 ° C, and a refractive index of 1.40-1.41 »Preferably, the developer composition it contains a mixture of 0.001 to 10%, preferably 0.005 to 5%, more preferably 0.01 to 4%, of each of cyclomethicone, trimethylsilaxysilicate and an insoluble non-volatile silicana. in water, particularly trimeti Isi 1 i 1amadi eticana »The developer composition also contains from 0.001 to 57%, preferably from 0.05 to 4%, more preferably from 0.05 to 3%, of one or more anionic polymers such a bed those described in U.S. Patent No. 4,240,450, which is incorporated herein by reference. Examples of such anionic polymers are vinyl acetate and crotonic acid copolymers, graft copolymers of vinyl esters to either acrylic or ethacrylic esters, cross-linked graft copolymers resulting from the polymerization of at least one monomer of the type ionic, at least one manomer of the non-ionic type, polyethylene glycol, and a crosslinking agent, and the like. Preferred are acrylate copolymers such as co-or capylamer of allyl ether of steareth and acrylate. The developer composition comprises of 99%, preferably 10 to 99%, more preferably 60 to 97% of water. The two containers that come together in the form of a set purchased by the consumer »Immediately before the hair coloring» the consumer the contents of the containers together and applies the mixture to the hair. Finally, the invention focuses on a method for oxidative hair dyeing, comprising the steps of; a) applying to the hair a composition obtained by mixing Composition A and Composition B, where Composition A is encapsulated, the weight of the total composition; from 0.0001 to 20% at least one primary intermediate and at least one coupler for the formation of oxidation dyes, from 0.01 to 10% of a 2-hydroxyphenylbenzotriazole compound that absorbs ultraviolet radiation in the range of wavelength from 200 to 400 nanometers, cié 0. 5 to 20% surfing, and. from 10 to 65% water; and Composition B comprises, the weight of the total composition: from 0.5 to 45% of hydrogen peroxide, from 0.1 to 10% of a silicone conditioning adjuster, from 0.01 to 5% of an anionic polymer, and of 1 to 99% water, b) said composition is left in the hair for a period of 2 to 60 minutes, c) the hair is rinsed with water. Compositions A and B are mixed and applied to the field for the time necessary to achieve the desired coloration, generally from 2 to 60 minutes, preferably from 5 to 45 minutes, and more preferably from 10 to 35 minutes »The preferred ratio between Composition A and Composition B to achieve optimum coloration is approximately 0-5 to 1.5: 1.0 to 2.0, preferably 1 to 1.5, respectively. After the appropriate time, the hair is rinsed with water to remove the dye mixture. The hair is allowed to dry »The invention will be further described in relation to the following examples which are only invented for the purpose of illustrating said invention. EXAMPLE 1 A composition for dyeing hair oxidant was made in the following manner; Pair in weight / weight Ammonium lauryl sulphide (anionic surfactant) 2 »0 Propilentjlical (humectant) 4.00 Etoxid igl icol (solvent) 2.00 Monoethanolamine (pH adjuster) 5.00 Seaweed extract (conditioner) 0.80 EDTA (agent of action) 0.80 Isoascorbic acid (antioxidant.) 0.20 Su.I sodium phytate (reducing agent) 0.50 Primary intermediates and couplers 5.00 (tin e 5 Oleic acid (soap) 12.50 Cetearyl alcohol (opacifying) 4.00 Emulsifying wax (emulsifier) 2.00 Ole -20 (surfactan e nonionic) 1.00 Estearet-21 (non-ionic surfactant) 0.70 Saxifrage seed oil (oil) 0.75 1 coho1 o1ei 1 ica (oil) 0.40 Polyquaternium 10 (conditioning agent 0.20 cat.) Pal quaternium 28 (conditioning agent 0.50 cationic) Mica / titanium dioxide (colorant) O »30 3 Hydrolyzed wheat protein (conditioner) 1.00 Cibafast liquid (UV absorber) 1.00 Fr 0.75 Ammonium hydroxide (pH adjuster) 5.00 Wheat amino acids (conditioner) 1.00 Water QS * isabutilbenzatriazalsulfonata sodium, Ciba Beigy The composition was first made by dissolving the first eight ingredients in water. The primary intermediates and couplers were then added with heat application until dissolution. The remaining ingredients, except ammonium hydroxide, wheat amino acids, and fragrance were mixed separately and added after the primary intermediates and couplers. The remaining water, ammonium hydroxide, hydrolyzed wheat protein, wheat amino acids and fragrance were finally added to the mixture. EXAMPLE 2 A developer based on hydrogen peroxide was prepared for use with the hair dye composition of the claim 1 as follows; Percentage weight / weight Methyl arabin (preservative) 0.05 EDTA (agent of qu? Iac: Ion) O »02 Mineral oil (oil) 0.60 AI cohe.1 cete rí 1 i c.a / ceteareth-20 (8; 2) 3.75 (emulsify ican e) Cyclomethicane / trimethylsiloxysilicate (50:50). 1 (1 i.cona conditioner) Cetearyl alcohol (opacifier) 0.40 Trimeti Isil i lamodimetican (conditioner of 2.00 if 1 icon) Disodium phosphate (pH adjuster) 0.03 Phosphoric acid (pH adjuster) 0.03 Hydrogen peroxide (35% solution in water) 25.70 Copalí was allyl ester of stearet 10 / acrylate 0.35 (anionic polymer) Water GS The preservatives were first dissolved in about half of the water. The solution was heated and the mineral oil, cetearyl alcohol / ceteareth and cetearyl alcohol were added with stirring. The mixture was cooled and the silicones were added »Phosphate was dissolved disodium and phosphoric acid in water and added to the mixture after the silicones, together with the remaining ingredients »EXAMPLE 3 Ninety women members of a panel participated in an eight-week double-blind trial designed to compare the hair dyed with the compositions of Examples i and 2 with hair styled using hair color Preference of L'Oréal. The hair color Prsference of L'Oréal contains the following ingredients reproduced from the label of ingredients of the packaging Water, DEA of cocamide, butoxyethanol, tallow amine PEO-, alcohol SD 40, oleyl ether of pol igliceril-4, oleyl alcohol, ammonium hydroxide, iglyceryl-2 polyolelether, prapi tongue, oleic acid, diethylamine prapylcocoaspartamide sodium, pentasodium pentetate, ammonium acetate, intermediate dyes, sodium metabisulfite, fragrance, erythorbic acid, fragrance. Color developer: Water, hydrogen peroxide, cetearyl alcohol, oleamide DEA, ceteareth-30, glycerin, phosphoric acid, pentasodium pentetate, sodium stannate, pyrophosphate tetr sodium »Each member of the panel was examined in two four-week cycles» During the first cycle, the hair of the panel member was dyed with the first hair dye system. Over a period of four weeks, the panel member was asked to answer several questions about color. Then, the hair of the same panel member was dyed using the second dyeing system for the color. Over a period of four weeks, the panel member was asked to answer several questions regarding color. The results of the test were as follows:; i »In comparison to your first day with the dye, the colottle your hair has decreased? SUMMARY Percentage of affirmative responses Color Week 1 Week 2 Week 3 Week 4 Rubio champagne 42 68 90 100 Rubio extra clear ash 45 64 73 7. "Light ash coffee 45 óó 83 92 Light coffee 83 66 75 66 Medium coffee 58 83 92 92 .1 Dark coffee 17 25 50 66 Light reddish chestnut 58 66 8_. 83 Average 49 63 79 83 PREFERENCE DE L'ORéAL 20 Percentage of affirmative responses Color Week i Week Week 3 Week 4 Rubio champagne 56 78 83 83 Rubio extra clear ash 20 40 SO 80 Light ash coffee 66 83 Bo 83 r-, c: Light coffee 50 66 66 75 Medium coffee 58 Tin: ^? 100 Dark brown 42 58 75 67 Light reddish chestnut 58? -í 92 92 Promise 50 68 82 83 2 »Compared to the first day of the application of the dye, the color of your hair remained? without changes? SUMMARY Percentage of affirmative answers Colar Week 1 Semaannaa 2 Yes = mana 3 Week 4 Blonde champagne 74 63 53 42 Rubio extra clear ash 82 64 45 5 Light ash coffee 83 58 5 42 Light coffee 75 50 66 50 Medium coffee 83 83 42 50 Dark coffee 100 92 75 75 Light reddish chestnut 75 5 42 42 Average 81 66 49 PREFERENCE DE L'ORéAL Percentage of affirmative responses Color Week 1 Week Se ana 3 Week 4 Blonde champagne 66 50 47 33 Rubio extra clear ash 90 80 66 60 Light ash coffee 58 50 42 TT Light coffee 83 66 83 50 Medium coffee 66 58 42 42 Dark coffee 92 92 67 67 Light reddish chestnut Average 66 65 50 41 3 »Do you feel that the amount of dye that remains on your hair is acceptable? PERCENTAGE OF AFFIRMATIVE RESPONSES AFTER 4 WEEKS INVENTION PREFERENCE OF L 'OREAL Rubio champagne 95 83 Blond ceni a extra clear 73 80 Coffee light ash 92 67 Light coffee 83 83 Medium coffee 83 83 Dark coffee 100 92 Light reddish chestnut 75 58 Average 87 78 4 »If the heat of your hair has decreased, the change (for all shades combined) is s WEEK i%%% Barely measurable Noteable Very pronounced I V PREF I V PREF I V PREF 63 64 33 34 5 2 WEEK 2%%% Fairly remarkable Notable Very remarkable INV PREF INV PREF INV PREF 49 52 47 43 4 5 WEEK 3%%% Fairly remarkable Remarkable Very remarkable INV PREF INV PREF INV PREF 47 47 50 40 3 18 WEEK 4%%% Barely remarkable Natable Very remarkable INV PREF INV PREF INV PREF 39 38 55 33 5 29 INV = Invention PREF = Preference of L'Oréal 5 »Bleeding media Was calculated if faded medium in relation to panel members who reported bleaching at intervals of one, three, four and four weeks, with the combination of seven shades» At panel members who reported fade after interval of one, three, four and four weeks were asked to rate the fade on a scale of 3, representing the best state and 3 the worst. The numerical results obtained were averaged to obtain the medium »Hair dye Media Standard error Invention (n = 74) i »66A 0» 07 Preference of L'Or? Al (n-72) 1.92 0.10 The above results illustrate that the hair dye composition of the present invention exhibited improved calender resistance. after three weeks in comparison with the tference for the hair Preference of L 'Oréal »While the invention has been described in relation to the preferred embodiment, the scope of the present invention is not limited to the particular shape presented, but rather, On the contrary, it covers the documents, modifications and equivalents that may be included within the spirit and scope of the invention as defined in the appended claims. ; 0

Claims (13)

1. CLAIMS 1. A composition for the dyeing of hair that comprises, by weight of the total composition: from 0.0001 to 207. of at least one primary intermediate and at least one coupler for the formation of oxidation dyes, from 0.01 to 107 of a 2-hydroxyphenylbenzatriazole compound that absorbs UV radiation in the wavelength range from 200 to 400 nanometers, from 0.5 to 20% surfactants, and from 10 to 65% water »2» composition of claim i, wherein the 2-hydroxyphenylbenzotriazole compound has the formula: (a) R3 wherein R1, R2, F; 3, R4 and R5 each independently, H, hydralaila, carboxyl, halogen, or straight-to-branched alkyl (C1-C40), alk (C1-C40) ) straight or branched chain, alkoxycarbonyl (C2-C20), carbaxy. phenyla substituted by alkyl (Cl-C40), cycloalkyl (C5-Co), S03H, S03Na, or where Ei and E2 are each independently, H, either alkyl (C1-C4), and E3 is H, halogen to either alkyl (C1-C4); R3 is H, halogen, OH, straight-to-branched chain (C1-C40) alkyl, S03Na, cycloalkyl (C5-C6), phenylalkyl, substituted phenylalkyl (Cl-CIO), or AND. where E1 and E2 are each independently H (C1-C4) and E3 is H, halogen or C1-C4; (b) where Ti is hydrogen. halogen, alkylation (C1-C4), S03H S03Na, T2 is alkylation (C1-C12), S03H or S03Na Ei is hydrogen, halogen at either 0E2 E2 is hydrogen or alkylation (Ci-C18), E3 is hydrogen, alkyl (Cl-C4), halogen, S03H S03Na, E4 is hydrogen, halogen to either OES E5 is hydrogenated or alkyl (Cl-C18), and Eó is hi íc) where R1, R2, and R3 are each independently hydrogen, halogen, or an ester-containing radical provided that there is at least one ester-retaining radical; (d) R1 is hydrogen, halogen, alkyl (Cl-C4), or (C1-C4) alkoxy, R2 is (C1-C18) alkyl, cycloalkyl of 5 to 12 carbon atoms or phenylalkyl of 7 to 15 carbon atoms E is an alkylene of 1 to 10 carbon atoms straight or branched chain to said alkylene interrupted for the 3 groups selected from the group consisting of -0-, -S-, -S02-, -COO-, - OOC-, and Rf is a straight or branched chain perfluoroalkyla of 1 to 12 carbon atoms, perf luroalkyla of 2 to or carbon atoms substituted by perfluoroal caxi of 2 to 6 carbon atoms, or an oligo terminal group ( Hexaf luoropropene oxide); (e) and mixtures thereof. 3. The composition of claim 3, wherein the 2-hydraxifenilbenzatriazal compound has the formula: (a) R3 wherein R1, R2, R3, R4 and R5 each independently H, hydroxylated, carbalaryl, halogenated, straight or branched chain alkylated (C1-C40) alkoxy (C1-C40) chain straight to branched, alkoxycarbonyl (C2-C20), carbaxy, phenyla substituted by alkyl (Ci-C40), cycloalkylamino (C5-) where El and E2 are each, independently, H, or alkyl (C1-C4), and E3 is H, halogen to either (C1-C4) alkyl; R3 is H, halogen, OH, straight or branched chain (C1-C40) alkyl, S03Na, (C5-C6) cycloalkyl, phenyl, phenyl substituted by alkyl (Cl-CIO), or where El and E2 are, each independently, H al alky (C1-C4) and E-3 is H, halo to well Ci-C4; 4. The composition of claim 3, wherein Ri and R2 are H. 5. The composition of claim 5, wherein R3 is S02Na to either S03H. or. The composition of claim 5, wherein R 5 is straight or branched chain alkyl (Cl-CIO). 7. The composition of claim 5, wherein Ri, R2 and R4 are H, R3 is S03Na, and R5 is a branched chain alkyl (CI). 8. The composition of claim 1, wherein the 2-hydroxy-n-benzotriazole is sodium isobutylbenzotriazal sulfonate. The composition of claim 1, further comprising a cationic conditioning agent of the hair selected from the group consisting of: (a) quaternary ammonium salts having the formula: dande Rl is hydrogen, an aliphatic group of 1 to 22 carbon atoms, or an aromatic, aryl or alkaryl group having 12 a. 22 carbon atoms; R2 is an aliphatic group having from i to 22 carbon atoms; R3 and R4 are each alkyl groups of 1 to 3 carbon atoms, and X is an anion selected from the halogen, acetate, phosphate, nitrate and methylamide radicals; and (b) (i) cationic derivatives of cellulose ethers, (ii) vinylpyrrolidone copalimers, (iii) haloalimers of di-ethyl diarylammonium chloride, (iv) dimethyl diallylammonium chloride acrylamide and acrylamide, (v) hamopalimers or copolymers of acrylic or methacrylic acid, and (vi) mixtures thereof. The composition of claim 9, wherein the cationic hair conditioning agent is a copolymer of suitable vinylpyrrole having the monomer units of the formula: 3 i dande Rl is hydrogen or methyl, -CH2 CHOH CHj--, and is 0 to either 1, R2 is O or NH, R3 is CxH2x donds "x" is 2 to 18, or R4 is methyl, ethyl , phenyl to phenyl substituted in Cl-C4, and R5 is methyl or ethyl. 11. The composition of claim 10 wherein Rl is mstyl »12. The composition of claim 11 wherein R2 is NH. 13. The composition of claim 12 wherein R3 is CH2C1-I2, R4 is methyl, and R5 is methyl »14» The composition of claim 1, wherein the surfactant is selected from the group consisting of an anionic surfactant, an ionic surfactant, an amphoteric surfactant, a zwitterionic surfing agent , and ezczlas of the same »15» The composition of the reividicación 14 »where the surfactant is selected within the group consisting of an anionic surfactant, a nonionic surfactant» and mixtures thereof. 16. The composition of claim 15, wherein the anionic surfactant is an alkyl sulfate having the. formula R0S03M, an alkyl ether sulfate having the formula R0S0 (C2H40) S03M, where R is alkyl to alkepyl of approximately 20 carbon atoms, x is from i to i and M ss a water-soluble cation such as, for example, ammonium, sodium, potassium or triethanolamine. 17. The composition of claim 5, wherein the non-ionic surfactant is the product of the condensation of ethylene oxide and an aliphatic alcohol having from 8 to 18 carbon atoms. 18 The composition of claim 1 which further comprises 0.01 to 10% of a fatty acid »19» The composition of claim 18, wherein the fatty oil is saxifrage seed oil. 20. A set of two components for the oxidative dyeing of the hair, comprising; a first container containing a composition comprising, by weight of the total composition: from 0.0001 to 207 »of at least one primary intermediate and at least one coupler for the formation of oxidation dyes, from 0.01 to 10% of a compound 2-hydroxyphenylbenzotriazal that absorbs ultraviolet radiation in the range of wave lengths from 200 to 400 nanometers, from 0 »5 to 20% of surfactant, and from 10 to 65% of water; and a second container containing a developer composition comprising, by weight of the total composition; from 0.5 to 45% of hydrogen peroxide, from 0.1 to 10% of a non-volatile silicone insoluble in water, from 0.01 to 5% of an anionic polymer, and from i to. 997. of water »21. A method for oxidative hair dyeing comprising the steps of; a) apply to the hair a composition obtained by mixing Composition A and Composition B, where the Composition A comprises, by weight of the total composition: from 0.0001 a. 20% of at least one primary intermediate and at least one coupler for the formation of oxidation dyes, from O.Ol to 10% of a 2-hydroxypheni Ibenzotriazole compound that absorbs ultraviolet radiation in the range of lengths wave of 200 a. 400 nanometers, from 0.5 to 2.0% surfactant, and from 10 to 65% water; and Composition B comprises, by weight of the total composition; from 5 to 45% of hydrogen peroxide, from 0.1 to 10% of a non-volatile silicana insoluble in water, from 0.01 to 5% of an anionic polymer, and from 1 to 99% of water, b) leaving said composition in the hair for 2 to 60 minutes, c) rinse the hair with water.