MXPA98000446A - Sarcosinates as adjuvants and activators of fluazifop-but - Google Patents
Sarcosinates as adjuvants and activators of fluazifop-butInfo
- Publication number
- MXPA98000446A MXPA98000446A MXPA/A/1998/000446A MX9800446A MXPA98000446A MX PA98000446 A MXPA98000446 A MX PA98000446A MX 9800446 A MX9800446 A MX 9800446A MX PA98000446 A MXPA98000446 A MX PA98000446A
- Authority
- MX
- Mexico
- Prior art keywords
- sarcosinate
- activator
- butyl
- sodium
- herbicidal composition
- Prior art date
Links
- 239000012190 activator Substances 0.000 title claims description 15
- 239000002671 adjuvant Substances 0.000 title abstract description 19
- 230000000240 adjuvant Effects 0.000 title abstract description 18
- 229940071089 sarcosinate Drugs 0.000 claims abstract description 37
- FSYKKLYZXJSNPZ-UHFFFAOYSA-M sarcosinate Chemical compound CNCC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-M 0.000 claims abstract description 36
- ZUFONQSOSYEWCN-UHFFFAOYSA-M sodium;2-(methylamino)acetate Chemical compound [Na+].CNCC([O-])=O ZUFONQSOSYEWCN-UHFFFAOYSA-M 0.000 claims abstract description 11
- KSAVQLQVUXSOCR-UHFFFAOYSA-M Sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims abstract description 9
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims description 23
- 230000002363 herbicidal Effects 0.000 claims description 22
- 239000011734 sodium Substances 0.000 claims description 20
- 239000011780 sodium chloride Substances 0.000 claims description 13
- 240000000218 Cannabis sativa Species 0.000 claims description 12
- 229910052783 alkali metal Inorganic materials 0.000 claims description 10
- -1 alkali metal salts Chemical class 0.000 claims description 9
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims description 6
- BACYUWVYYTXETD-UHFFFAOYSA-N 2-[dodecanoyl(methyl)amino]acetic acid Chemical class CCCCCCCCCCCC(=O)N(C)CC(O)=O BACYUWVYYTXETD-UHFFFAOYSA-N 0.000 claims description 5
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 229940071145 lauroyl sarcosinate Drugs 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- FXALIOUHXMVTMJ-UHFFFAOYSA-N CCCCCCCCCCCC([Na])=O Chemical compound CCCCCCCCCCCC([Na])=O FXALIOUHXMVTMJ-UHFFFAOYSA-N 0.000 claims description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 3
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 2
- 150000001340 alkali metals Chemical group 0.000 claims 2
- 125000003342 alkenyl group Chemical group 0.000 claims 2
- 150000003973 alkyl amines Chemical class 0.000 claims 2
- 125000005466 alkylenyl group Chemical group 0.000 claims 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 claims 2
- AVXURJPOCDRRFD-UHFFFAOYSA-N hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims 2
- YUVKUEAFAVKILW-SECBINFHSA-M (2R)-2-[4-[5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoate Chemical group C1=CC(O[C@H](C)C([O-])=O)=CC=C1OC1=CC=C(C(F)(F)F)C=N1 YUVKUEAFAVKILW-SECBINFHSA-M 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 13
- VAIZTNZGPYBOGF-UHFFFAOYSA-N Fluazifop butyl Chemical group C1=CC(OC(C)C(=O)OCCCC)=CC=C1OC1=CC=C(C(F)(F)F)C=N1 VAIZTNZGPYBOGF-UHFFFAOYSA-N 0.000 abstract description 9
- 230000001988 toxicity Effects 0.000 abstract description 4
- 231100000419 toxicity Toxicity 0.000 abstract description 4
- 239000004009 herbicide Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 241000508725 Elymus repens Species 0.000 description 6
- 240000008893 Cynodon dactylon Species 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-N Palmitic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229940048098 Sodium Sarcosinate Drugs 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 230000000977 initiatory Effects 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000003359 percent control normalization Methods 0.000 description 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine zwitterion Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- ZMANZCXQSJIPKH-UHFFFAOYSA-N triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- XRIBIDPMFSLGFS-UHFFFAOYSA-N 2-(dimethylamino)-2-methylpropan-1-ol Chemical compound CN(C)C(C)(C)CO XRIBIDPMFSLGFS-UHFFFAOYSA-N 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N 2-amino-2-(hydroxymethyl)propane-1,3-diol Chemical group OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- 240000001498 Asparagus officinalis Species 0.000 description 1
- 235000005340 Asparagus officinalis Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 240000002860 Daucus carota Species 0.000 description 1
- 235000002767 Daucus carota Nutrition 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N Diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 240000007842 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 240000003613 Ipomoea batatas Species 0.000 description 1
- 235000002678 Ipomoea batatas Nutrition 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N Isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- JITOKQVGRJSHHA-UHFFFAOYSA-M Monosodium methyl arsenate Chemical compound [Na+].C[As](O)([O-])=O JITOKQVGRJSHHA-UHFFFAOYSA-M 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 241000209504 Poaceae Species 0.000 description 1
- 229940043230 Sarcosine Drugs 0.000 description 1
- 108010077895 Sarcosine Proteins 0.000 description 1
- 238000003436 Schotten-Baumann reaction Methods 0.000 description 1
- 240000003453 Spinacia oleracea Species 0.000 description 1
- 235000009337 Spinacia oleracea Nutrition 0.000 description 1
- 206010041662 Splinter Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000000711 cancerogenic Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- QUSNBJAOOMFDIB-UHFFFAOYSA-N ethyl amine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 244000080466 oignon Species 0.000 description 1
- 235000002732 oignon Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N oxane Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 238000009304 pastoral farming Methods 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N propane Chemical group CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Abstract
The present invention relates to a Fluazifop-butyl adjuvant, and preferably Fluaziforp-P-butyl, which has increased activity, lower irritation and lower toxicity than conventional adjuvants. The adjuvant is C8 to C22 sarcosinate or sarcosinate salt, such as sodium cocoyl sarcosinate, sodium lauroyl sarcosinate, or combinations thereof, which are combined with Fluazifop-P-butyl and provides more effective activity, control, but all experimental adjuvants gave superior control to that of X-
Description
SARCOSINATES AS ADJUVANTS AND FLUAZIPOP-BUTTER ACTIVATORS
BACKGROUND OF THE INVENTION
Fluazifop-butyl (butyl (RS) -2- U-L l-5- (trifluor
methyl) -2- pyridinium oxij eniloxij propionate), or its enantiomer fluazifop-P-butyl (butyl (R) -2-T4- [C 5- (trifluoromethyl) -2-pyrimidinyl] -oxij = phenoxy = propane) they are represented by the following formula:
Both the racemic mixture and the enantiomer are selective herbicides, with the enantiomer being especially effective grass selective herbicide. which exhibits perennial and annual herb grazing post control on top of cotton, soybeans and other broadleaf crops, including asparagus, carrots, dry bulb onions. spinach. sweet potatoes, and ornamental. The ST enantiomer sells comßrcialmßntß by
REF: 26496 Zeneca Ag Products under the trade name FUSILADE (R) 2000 or FUSILADE (R) DX. They are typically used in formulations to aid in the operation or improve the effectiveness of the pesticide, herbicide, etc. The term includes wetting agents, dispersants, emulsifiers, dispersing agents, foaming aids, suds suppressors, penetrants and correctors. Adjuvants such as Valent X-77 (R)
Spreadßr are commonly used to improve the performance of Fluazifop-P-butyl. However, the Valent X-77 (R)
Spreader and other ethoxylated nonionic surfactants contain free ethylene oxide which can form 1,4 dioxane, a known carcinogen. Therefore, an object of the present invention is to provide adjuvants and activators of
Fluazifop-P-butyl that do not suffer from the disadvantages of the prior art. A further object of the present invention is to provide herbicidal formulations with increased activity, lower irritation capacity and lower toxicity than conventional formulations.
BRIEF DESCRIPTION OF THE INVENTION The problems of the prior art have been overcome by the present invention, which provides an adjuvant for Fluazifop-butyl, and preferably Fluazifop-P-butyl. which has increased activity, lower irritation and lower toxicity than conventional adjuvants. The adjuvant is C8 sarcosinate a- or sarcosinate salt. such as cocoyl sodium sarcosinate, lauroyl sodium sacosinate, or combinations thereof, which is combined with Fluazifop-P-butyl and provides more effective activity.
DETAILED DESCRIPTION OF THE INVENTION Typically, the sacosinates are used in the form of their sodium, potassium or ammonium salt solution.
The N-acyl sarcosinates produced commercially by the Schotten-Baumann reaction of the sodium salt of sarcosine with the appropriate fatty acid chloride under carefully controlled conditions: R-C-Cl + HNCH2? OONa + NaOH R-C-NOCOCOA + NaCl + H20
J \ - I CH3 0 CH3
wherein R is typically a long chain fatty acid from Cio to Cie. made commonly from lauric, palmitic acid. irish or oleic After the reaction is complete, the crude sodium salt is acidified to release the free fatty acid sarcosinic acid that is separated from the aqueous by-products. Then it is neutralized to a salt form. Sarcosinates such as sodium lauroyl sarcosinate, sodium cocoyl sarcosinate and sodium iristoyl sarcosinate are commercially available under the trademark HAMPOSYL (R) from Hampshire Chemical Corp. as 30% active solutions in water. The present inventor has found that N-acyl sarcosinates from Ce to C22. and in particular, sodium cocoyl sarcosinate and sodium lauroyl sarcosinate, are excellent adjuvants for Fuazifop-P-butyl. (the most (P) enantiomer of Fuazifop-butyl has been found to contain the herbicidal activity of the racemic mixture, in this way it has been isolated and formulated at half the concentration of the racemic mixture. The present invention It should be understood by those skilled in the art, however, that even though the following description refers to the (P) enantiomer, the racemic mixture could also be used.) Sarcosinates are low in toxicity, irritation and when combined with Fuazifop-P-butyl. they cause them to exhibit increased activity. Suitable salts of these sarcosinates which are useful in the present invention include monoethylamine; Diethylamine: triethylamine; alkali metal salts, particularly sodium and potassium; isopropylamine;
and ammonia or amino alcohols such as tris amino or 2-dimethylamino-2-methyl-1-propanol. Preferably the salcorsinate solutions at 3036 are used so that the final concentration of sarcosinate in the formulation is from 0.1% to 3% (v / v), more preferably 0.5 to 1%. Higher concentrations of sarcosinate tend to be less effective, probably because the excess of surfactant tends to cause the herbicide to be washed away from the application area. The ST formulations are prepared by first mixing the sarcosinate with water, and then mixing the FUSILADE (R) herbicide with the resulting surfactant solution. The invention is further illustrated by the following non-limiting examples.
EXAMPLE 1 Fuazifop-P-butyl was added to solutions of sodium cocoyl sarcosinate and sodium lauroyl sarcosinate. Valent X-77 was used as control. The Valent X-77 is 90% active and the sarcosinate solutions are 30% active. ST tested four test systems and control for effectiveness in controlling Bermuda grass. The Bermuda grass used in this ST experiment was established in 1985 and has been fertilized and plowed under normal practices until the treatments were applied. Following the application d? the treatments, the unwanted grasses and pastures other than Bressmuda grass with Quadmec were controlled thirty-three days after the application; with MSMA 120 days after treatment, classifications (DAT) were collected. The area was fertilized with 68 units / A of nitrogen 3350 days after the application. The experimental area was irrigated on a base as needed. ST carried out seven and fourteen date classifications. The Fuazifop-P-butyl ST applied Bermuda grass to 56.70 grams of active ingredient per 0.404 hectares, the Valent X-77 ST added 0.25% v / v and the sarcosinates to an equivalent active concentration. 0.75% v-v and double the level. 1.50% The data is shown in Table 1 below. At 7 days after the application, only a yellowing effect was observed and control could not be classified in percent (Table 1). The control was achieved in DAT 14 and the data seem to show that the addition of sodium cocoyl sarcosinate at 1.5% v-v and sarcosinate d? sodium lauroyl at both 0.75% and 1.5% v-v increased the activity of the herbicide FUSILADE «on grass d? Bermuda common. At 31 days after application, the 0.75% v / v of sodium cocoyl sarcosinate and sodium lauroyl sarcosinate gave better control, but all experimental adjuvants gave superior control to that of X-77. TABLE 1 Herbicide: Fusilado 2000 Grass: Bermuda grass
Use regime 56.70 gr /, 404 hectare Growth stage: Post Volume d? Spraying: 86.53 liters / .404 hectare Type of Land: Lawn Control Adjuvant: X-77 Usage Regime% Adjuvant Control% V / V 7 DAT 14 DAT 31 DAT 121 DAT 362 DAT
X-77 (90% active 0.25 1. 5 4 0 1 -5 0 0
Na cocoyl sarcosinate (30% active) 0.75 2 5 5 0 7 0 0 0 Na cocoyl sarcosinate (30% active) 1.50 3 0 6 5 5 0 0 0
Lauroyl Sarcoxinate Na (30% active) 0.75 3.0 7 5 6 5 0 0 Lauroyl Na Sarcosinate (30% active) 1.50 2, 5 7 0 4 0 0 0 Verification 0 0 0 0 0
EXAMPLE 2 Fuazifop-P-butyl was added to solutions of sodium cocoyl sarcosinate and sodium lauroyl sarcosinate. Valent X-77 was used as control. The Valent X-77 is 90% active and the sarcosinate solutions are 30% active. Four test systems and control were tested for effectiveness in controlling Quack grass. The plots were 3,048 m x 18.29 m planted in a lawn of grass type Quack and the center of 1.83 of each plot was sprayed, leaving 61 cms. of checks on the outside of each plot. Quack-type grass classifications were visual calculations of% control based on a scale of 0-100, where 0 is equal to no control and 100 is equal to full control. Rankings of date seven were carried out, fourteen, thirty, fifty-three and two hundred and ninety of the effects. Fuazifop-P-butyl was applied to Quack grass at 56.70 grams of active ingredient per 0.404 hectares, Valent X-77 was added at 0.25% v / v and sarcosinates at an equivalent active concentration, 0.75 v / v and twice the level. 1.50% The data are shown below in Table 2. The sample containing sarcosinate d? Sodium cocoyl at 0.756. v / v resulted in slower initial activity than the sample used at a higher regimen, but at 14 days after the treatment (DAT) activity of the two regimens was the same and remained the same for the rest of the test. Conversely, the regime under d? Sodium lauroyl sarcosinate resulted in initial activity faster than the superior regimen. The activity for the two regimes was equal to 14 DAT. For 290 DAT, only the sample with the superior lauroyl sodium sarcosinate regime showed any continuous activity on the grass d? Quack. TABLE 2 CONTROL OF QUACK-TYPE PASTE WITH N-ACID FUSILADE AND SARCOSINATE Herbicide: Fusilated 2000 Grass: Quack type Grass Use Regime: 56.70 grams / .404 hectare Growth Stage: Post Spray Volume: 75.70 liters / .404 hectare Type of Land: Adjuvant Control Lawn: X-77 Regime d? Use% d? Adjuvant Control V / V 7 DAT 14 DAT 30 DAT 53 DAT 250 DAT
X-77 (90% active) 0 .25 1 0 4 0 3 0 Na cocoyl sarcosinate (30% active 0 .75 3 0 2 5 Na cocoyl sarcosinate (30% active) 1 .50 3 0 3 0 2 5 Sarcosinate d? Lauroyl d? Na (30% Active 0, .75 3 0 1 5 1 5 Na lauroyl sarcosinate (30% active 1. 50 1 0 2 0 1 5 40
EXAMPLE 3 ST added Fuazifop-P-butyl to solutions of sarcosinate d? sodium cocoyl and lauroyl sarcosinate d? sodium. S? he used Valent X-77 as control. The Valent X-77 is 90% active and the sarcosinate solutions are 30% active. Four systems were tested d? test and control for effectiveness when controlling Quack grass. The plots were 3.05 m x 18.29 m sown with Quack grass, which was spring-loaded, disc and cut. The center of 1.83 of each plot was sprayed leaving 61 cms. of test checks on the outside of each plot. Quack-type pasture classifications were visual calculations of% control based on a scale of 0-100. where 0 is equal to no control and 100 is equal to complete control. Classifications were carried out on the date seven, fourteen, thirty-two hundred and seventy-nine of the effects. Fuazifop-P-butyl was applied to Quack grass at 56.70 grams of active ingredient per .404 hectare, Valßnt X-77 was added at 0.25% v / v and sarcosinates at an equivalent active concentration, 0.75% v / v and double the level. 1.50% The data are shown below in Table 3. All the additives showed similar regime response with Fuazifop-P-butyl. ST display substantial control still as of 279 DAT.
TABLE 3 CONTROL OF QUACK TYPE PASTE WITH FUSILADE AND SARCOSINATE OF
N-ACIL Herbicide: Splinter 2000 Grass: Quack grass Use regime: 56.70 grams / .404 hectare Growth Stage: Post Spraying Volume: 75.70 liters / .404 hectare Type of Land: Labrada Adjuvant Control: X-77 Regimen of Use% of Adjuvant Control% V / V 7 DAT 14 DAT 30 DAT 279 DAT X-77 (90% Active) 0.25 1 0 6 0 8 5 7 0 Na Cocoyl Sarcosinate (30% active) 0.75 1 0 5 5 9 0 7 0 Sarcosinate de Cocoilo d? Na (30% active) 1.50 1 0 5 5 8 5 8 0 Sarcosinate de Lauroilo d? Na (30% active) 0.75 1 0 5 0 8 0 6 0
Lauroyl Na Sarcosinate (30% active) 1.50 10 5 5 9 0 7 5
Claims (16)
1. - A herbicidal composition characterized in that it comprises an effective herbicidally effective amount d? butyl-2- [4- [[5- (trifluoromethyl) -2-pyridinyl] oxy] phenoxy] propanoate and an activator comprising an N-acyl sarcosinate or a salt thereof having the formula:
RCON (CH3) CH2CCOX wherein R is alkyl or alkenyl of Ce to C22. and X is hydrogen, alkali metal, ammonium, Ci-Cβ alkylamine or an amino alcohol. 2. The herbicidal composition of claim 1, characterized in that butyl-2- [4- [[5- (trifluoromethyl) -2-pyridinyl] oxy] phenoxy] propanoate is (R) -2- [4- [[ 5- (Trifluoromethyl) -2-pyridinyl] oxy] phenoxy] propane butyl. 3- The herbicidal composition d? Claim 1, characterized in that the sarcosinate of
N-acyl is selected from the group consisting of alkali metal salts of lauroyl sarcosinate, alkali metal salts of cocoyl sarcosinate, and a mixture of an alkali metal salt of lauroyl sarcosinate and an alkali metal salt of cocoyl sarcosinate.
4. - The herbicidal composition of claim 2, characterized in that the N-acyl sarcosinate is selected from the group consisting of alkali metal salts of lauroyl sarcosinate, alkali metal salts d? cocoyl sarcosinate, and a mixture of an alkaline metal salt of sarcosinate d? lauroyl and an alkali metal salt of cocoyl sarcosinate.
5. The herbicidal composition of claim 1, characterized in that the activator is sodium lauroyl sarcosinate.
6. The herbicidal composition of claim 2. characterized in that the activator TS sarcosinate lauroyl sodium.
7. The herbicidal composition of claim 1. characterized in that the TS coco sarcosinate sodium activator.
8. The herbicidal composition of claim 2, characterized in that the TS coco sarcosinate sodium activator.
9. A method for controlling weeds in grass, characterized in that I understand to apply to the grass an effective amount of a herbicidal composition comprising butyl-2- [4- [[5-]. { trifluoromethyl) -2-pyridinyl] oxy] phenoxy] propanoate and an activator comprising an N-acyl sarcosinate or a salt thereof having the formula: RCON (CH3) CH2COOX wherein R is alkyl or alkenyl d? Ce to C22, and X is hydrogen, alkali metal, ammonium, alkylamine d? Ci-Cß or an amino alcohol. 10.- The method d? claim 9, characterized in that? l -butyl-2- [4- [[5- (trifluoromethyl) -2-pyridinyl] oxy] phenoxy] propanoate is (R) -2- [4- [[5- (trifluoromethyl) - 2-pyridinyl] oxy] phenoxy] -propanoate d? butyl. 11.- The method d? claim 9, characterized in that the TS sarcosinate activator d? sodium lauroyl. 12. The method of claim 10, characterized in that the activator is sodium lauroyl sarcosinate. 13. The method of claim 9, characterized in that the activator is sodium cocoyl sarcosinate. 14.- The method d? Claim 10, characterized in that the activator is sodium cocoyl sarcosinate. 15. The method of claim 9, characterized in that the activator is present in the herbicidal composition in a concentration d? 0.75% or less. 16. The method of claim 10, characterized in that the activator is present in the herbicidal composition in a concentration of 0.75% or less.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/504,273 US5686391A (en) | 1995-07-19 | 1995-07-19 | Sarcosinates as fluazifop-butyl adjuvants and activators |
| US08504273 | 1995-07-19 | ||
| PCT/US1996/010049 WO1997003560A1 (en) | 1995-07-19 | 1996-06-11 | Sarcosinates as fluazifop-butyl adjuvants and activators |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MXPA98000446A true MXPA98000446A (en) | 1998-04-01 |
| MX9800446A MX9800446A (en) | 1998-04-30 |
Family
ID=24005571
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX9800446A MX9800446A (en) | 1995-07-19 | 1996-06-11 | Sarcosinates as fluazifop-butyl adjuvants and activators. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5686391A (en) |
| JP (1) | JPH11509549A (en) |
| CN (1) | CN1126448C (en) |
| AU (1) | AU698125B2 (en) |
| BR (1) | BR9609690A (en) |
| CA (1) | CA2223619C (en) |
| DE (1) | DE29623549U1 (en) |
| MX (1) | MX9800446A (en) |
| TW (1) | TW328902B (en) |
| WO (1) | WO1997003560A1 (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6060431A (en) * | 1996-09-09 | 2000-05-09 | Ash; David | Formulation and process for the selective control of Bermuda and other grasses in Bentgrass, Kentucky Bluegrass, Dichondera, Fine Fescue, Tall Fescue, Annual and perennial Ryegrass and St. Augustinegrass turfs and Iceplant |
| US5981471A (en) | 1997-02-06 | 1999-11-09 | Entremed, Inc. | Compositions and methods for inhibiting cellular proliferation |
| IES970766A2 (en) * | 1997-10-24 | 1999-05-05 | Barclay Chemicals R & D Ltd | A herbicidal composition comprising glyphosate (N-phosphonomethyl glycine) and an N-acyl sarcosinate |
| US5985798A (en) * | 1998-06-04 | 1999-11-16 | Hampshire Chemical Corp. | N-acyl sarcosinates as glyphosate adjuvants |
| EP1115283B1 (en) | 1998-09-23 | 2003-09-03 | Hampshire Chemical Corporation | Sarcosinates as glufosinate adjuvants |
| US6908882B1 (en) * | 1999-09-09 | 2005-06-21 | Monsanto Company | Enhanced method of killing weeds with glyphosate herbicide |
| US8326011B2 (en) * | 2008-05-21 | 2012-12-04 | Varian Medical Systems, Inc. | Methods, systems, and computer-program products for estimating scattered radiation in radiographic projections |
| US9743663B2 (en) | 2010-06-24 | 2017-08-29 | Compo GmbH & Co., KG | Pelargonic acid formulation |
| CN105454246B (en) * | 2014-09-24 | 2017-12-05 | 南京华洲药业有限公司 | A kind of mixed herbicide containing sulfentrazone and the spirit of pyrrole fluorine first standing grain |
| CN104403674B (en) * | 2014-12-15 | 2017-11-14 | 成都新朝阳作物科学有限公司 | Soil conditioner for adjusting soil physical and chemical property and preparation method thereof |
| US10957445B2 (en) | 2017-10-05 | 2021-03-23 | Hill-Rom Services, Inc. | Caregiver and staff information system |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4325729A (en) * | 1977-12-13 | 1982-04-20 | Ciba-Geigy Corporation | Herbicidal and plant growth regulating pyridyloxy-phenoxy-propionic acid derivatives |
| US4552580A (en) * | 1982-03-11 | 1985-11-12 | Ciba Geigy Corporation | Use of N-acyl sarcosinate and its salts as compatibility agents for pesticide/liquid fertilizer formulations |
-
1995
- 1995-07-19 US US08/504,273 patent/US5686391A/en not_active Expired - Fee Related
-
1996
- 1996-06-11 BR BR9609690A patent/BR9609690A/en not_active IP Right Cessation
- 1996-06-11 WO PCT/US1996/010049 patent/WO1997003560A1/en active Application Filing
- 1996-06-11 MX MX9800446A patent/MX9800446A/en unknown
- 1996-06-11 CN CN96195617.8A patent/CN1126448C/en not_active Expired - Fee Related
- 1996-06-11 DE DE29623549U patent/DE29623549U1/en not_active Expired - Lifetime
- 1996-06-11 JP JP9506667A patent/JPH11509549A/en active Pending
- 1996-06-11 CA CA002223619A patent/CA2223619C/en not_active Expired - Lifetime
- 1996-06-11 AU AU61716/96A patent/AU698125B2/en not_active Ceased
- 1996-06-25 TW TW085107610A patent/TW328902B/en active
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