MXPA06006123A - Active substance combinations having insecticidal properties - Google Patents

Abstract

The invention relates to novel insecticide combinations comprising anthranilic acid amides (group 1) and other insecticides selected among the group of (thio)phosphates (group 2) and/or the group of carbamates (group 3). Said insecticide combinations are very suitable for controlling animal pests such as insects.

Description

COMBINATIONS OF ACTIVE PRODUCTS WITH INSECTICIDE PROPERTIES Field of the invention The present invention refers to new-combinations of active products, which are constituted by anthranilic acid amides, known, on the one hand and, on the other, by known insecticidal active compounds. and -which are suitable, in a very good way, for the fight against animal pests such as insects. BACKGROUND OF THE INVENTION It is already known that certain anthranilic acid diamides have insecticidal properties (WO 01 / 70-671, WO 02/094791, WO 03/015519, WO 03/016284, WO 03/01551-8, WO 03/024222, WO 03/016282, WO 03/016283, WO 03/062226, WO 03/027099). Hereby, express reference is made to the formulas and generic definitions as well as to the individual compounds described therein. In addition, it is already known that a large number of heterocycles, organic compounds of tin, benzylureas and pyrethroids have insecticidal and acaricidal properties (see publications WO 93/2-2297, WO 93/10083, DE-A 26 41 343,? P-A 347 488, EP-A 210 487, US 3,364,177 and EP-A 234 • 045). Of course, the activity of these products is not always satisfactory either.

REF.:172914 DETAILED DESCRIPTION OF THE INVENTION It has now been found that mixtures formed by anthranilic acid amides of the formula (I) (group 1) wherein A1 and A2 signify, independently of each other, oxygen or sulfur, X1 signifies N or CR10, R1 signifies hydrogen or means alkyl having 1 to 6 carbon atoms, alkenyl having 2 to 6 carbon atoms, alkynyl having 2 to 6 carbon atoms or • cycloalkyl with 3 to 6 carbon atoms substituted, if appropriate, one or several times, the substituents being independently selected from R6, halogen, cyano, nitro, hydroxy, alkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 4 carbon atoms, alkoxycarbonyl with 2 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, dialkylamino with 2 to 8 carbon atoms, cycloalkylamino with 3 to 6 carbon atoms, (alkyl with 1 to 4 carbon atoms) cycloalkylamino with 3 to 6 carbon atoms or R11, R means hydrogen, alkyl with 1 to 6 carbon atoms, alkenyl with 2 to 6 carbon atoms, alkynyl with 2 to 6 carbon atoms, cycloalkyl with 3 to 6 carbon atoms alkoxy with 1 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, dialkylamino with 2 to 8 carbon atoms, cycloalkylamino with 3 to 6 carbon atoms, alkoxycarbonyl with 2 to 6 carbon atoms or alkylcarbonyl with 2 to 6 carbon atoms, R3 signifies hydrogen, R11 or means alkyl with 1 to 6 carbon atoms, alkenyl with 2 to -6 carbon atoms, alkynyl with 2 to 6 carbon atoms, -cycloalkyl having 3 to 6 carbon atoms substituted, if appropriate, one or several times, the substituents being independently selected from R6, halogen, cyano, nitro, hydroxy, alkoxy with 14 atoms carbon, .alpha.-haloalkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, alkoxycarbonyl with 2 to 6 carbon atoms, alkylcarbonyl with 2 to 6 carbon atoms, trialkylsilyl with 3 to 6 carbon atoms, R11, phenyl, phenoxy or a heteroaromatic ring with 5 or 6 members , where appropriate, each phenyl, phenoxy or heteroaromatic ring with 5 or 6 members can be substituted and the substituents can be chosen, independently from each other, between one to three residues W or one or "several residues R12, or R2 and R3 they can be linked together and form the ring M, R 4 means hydrogen, alkyl having 1 to 6 carbon atoms, alkenyl with 2 to 6 carbon atoms, alkynyl with 2 'to 6 carbon atoms, cycloalkyl with 3 to 6 carbon atoms carbon, halogenalkyl with 1 to 6 carbon atoms, halogenalkenyl with 2 to 6 carbon atoms, halogenalkynyl with 2 to 6 atoms -carbon, halogenalkyl with 3 to 6 carbon atoms, halogen, cyano, nitro, hydroxy, alkoxy with 1 to 4 carbon atoms, halogenalkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, halogenalkylthio with 1 to 4 atoms «carbon, halogenoalkylsulfinyl with the 4 atoms of carbon, halogenoalkylsulfonyl with 1 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, dialkylamino with 2 to S carbon atoms, cycloalkylane with 3 to 6 carbon atoms, trialkylsilyl with 3 to 6 carbon atoms or means phenyl, benzyl or phenoxy substituted, if appropriate, once or several times, it being possible to choose the substituents, independently of each other, between alkyl having 1 to 4 carbon atoms, alkenyl having 2 to 4 carbon atoms, alkynyl with 2 to 4 carbon atoms, cycloalkyl with 3 to 6 carbon atoms, haloalkyl with 1 to 4 carbon atoms, haloalkenyl with 2 to 4 carbon atoms. carbon, halogenalkynyl with 2 to 4 carbon atoms, halogencycloalkyl with 3 to 6 carbon atoms, halogen, cyano, nitro, alkoxy with 1 to 4 carbon atoms, halogenalkoxy with 1 to 4 carbon atoms, alkylthio- 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, - alkylsulfonyl with 1 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, "dialkylamino with 2 to 8 carbon atoms, • Cycloalkylamino with 3 to 6 carbon atoms, (alkyl) cycloalkylamino-with 3 to 6 a-carbon atoms, alkylcarbonyl with 2 to 4 carbon atoms, alkoxycarbonyl with 2 to 6 carbon atoms, alkylaminocarbonyl with 2 to 6 carbon atoms, dialkylaminocarbonyl with 3 to 8 atoms < of carbon or trialkylsilyl having 3 to 6 carbon atoms R5 and R8 respectively mean, - independently of one another, hydrogen, halogen or mean alkyl having 1 to 4 carbon atoms, halogenoalkyl having 1 to 4 carbon atoms, R12, < G, J, -OJ, -OG, -S (0) pJ, -_3 * (0) p-G, - 'S (O) p-phenyl substituted respectively, in given case, substituents being selectable, independently from each other, from one to three residues W or between R 12, alkyl having 1 to 10 carbon atoms, alkenyl having 2 to 6 carbon atoms, alkynyl with 2 to 6 carbon atoms, alkoxy with 1 to 4 carbon atoms or alkylthio having 1 to 4 carbon atoms, each substituent, independently of each other, may be substituted by one or more substituents chosen from G, J, R6, halogen, cyano, nitro, amino, hydroxy, alkoxy with 1 to 4 atoms carbon, • halogenalkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonium with 1 to 4 carbon atoms, halogenalkylthio with 1 to 4 carbon atoms, haloalkyl sulfinyl with 1 to 4 carbon atoms, halogenalkylsulfonyl with 1 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms arbono, dialkylamino with 2 to S atoms carbon, trialkylsilyl with 3 to 6 carbon atoms, phenyl or phenoxy, where appropriate each phenyl or phenoxy ring may be substituted and the substituents may be chosen, independently from each other, from one to three residues W or one or more residues R12 , G mean respectively, independently of-yes, a carbocyclic or heterocyclic, non-aromatic ring with 5 or 6 members, containing, if appropriate, one or two ring members selected from -group C (= 0), SO or S (= 0) 2 / and which may be -substituted, if appropriate, by one to four substituents chosen, independently from each other, between alkyl having 1 to 2 carbon atoms, halogen, cyano, nitro or alkoxy with 1 to 2 carbon atoms, or independently, meaning alkenyl with 2 to 6 carbon atoms, alkynyl with 2 to 6 carbon atoms, cycloalkyl with 3 to 7 carbon atoms, (cyano) cycloalkyl with 3 to 7 carbon atoms carbon, (alkyl with 1 to 4 carbon atoms) cycloalkyl or with 3 to 6 carbon atoms, (cycloalkyl with 3 to 6 carbon atoms) alkyl with 1 to 4 carbon atoms, each cycloalkyl, (alkyl) cycloalkyl and (cycloalkyl) -alkyl being substituted, if appropriate, -for one or more halogen atoms, J mean respectively, independently of each other, a heteroaromatic ring with 5 or 6 members, if necessary substituted, it being possible to choose the substituents, independently of each other, between one to three residues -W or one or more residues R12, R6 mean, independently of each other, -C (= E1) R19, LC (=? 1) R19, -'C (= E1) LR19, -LC (= E1) LR19, -0P (= 0) (OR19) 2, - "SO.LR18 or - LS02LR19, meaning each E1, independently of each other, O, S , N-R15, N-OR15, NN (R15) 2, N-S = 0, N-CN or N-N02, R7 means hydrogen, alkyl with 1 to 4 carbon atoms, haloalkyl with 1 to 4 carbon atoms carbon, halogen, alkoxy with 1 to 4 carbon atoms, halogenalkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, halogen alkylthio with 1 to 4 carbon atoms, halogenoalkylsulfinyl with 1 to 4 carbon atoms, halogenoalkylsulfonyl with 1 to 4 carbon atoms, R9 means haloalkyl with 1 to 4 carbon atoms, haloalkoxy with 1 to 4 carbon atoms or, halogenoalkylsulfinyl having 1 to 4 carbon atoms or halogen, R10 means hydrogen, alkyl having 1 to 4 carbon atoms, haloalkyl-1 to 4 carbon atoms, halogen, cyano or halogenoalkoxy having 1 to 4 carbon atoms, R 11 each independently means alkylthio having 1 to 6 carbon atoms, alkylsulfenyl having 1 to 6 carbon atoms, halogenalkylthio having 1 to 6 carbon atoms, halogenoalkylsulfenyl with 1 to 6 carbon atoms. to 6 carbon atoms, phenylthio or phenylsulfenyl respectively substituted, if appropriate, from one to three times, the substituents being independently selectable from the list formed by W, -S- (0) nN (R16) 2 , -'C (= 0) R13, -L (C = 0) R14, -S (C = 0) LR-14, -C (= 0) LR13, S (0) nNR13C (= 0) R13, - S (0) nNR13C (= 0) LR14 or -S- (0) nNR13S (0) 2LR14, L mean respectively, independently of each other, O, NR18 or S, R12 respectively mean, independently of each other, -B (OR17) 2, amino, SH, thiocyanate, trialkylsilyloxy with 3 to 8 carbon atoms, alkyl disulfide with 4 carbon atoms, -SF5, -C (= E) R19, -LC (= E) R19, C (= E) ) LR19, -LC = E) LR19, -OP (= Q) | OR19) 2, -S02LR19 or -LS02LR19, «signifi ca -O or "S, R13 respectively mean, independently of each other, hydrogen or mean alkyl having 1 to 6 carbon atoms, alkenyl having 2 to 6 carbon atoms, alkynyl with 2 to 6 carbon atoms or cycloalkyl with 3 to 6 carbon atoms substituted, if appropriate, one or more times, the substituents being independently selected from R6, halogen, cyano, nitro, hydroxy, alkoxy with 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, dialkylamino with 2 to 8 carbon atoms, cycloalkylamino with 3 to 6 carbon atoms carbon or - (alkyl with 1 to 4 carbon atoms) cycloalkylamino with 3 to 6 carbon atoms, mean respectively, independently of each other, alkyl having 1 to 20 carbon atoms, alkenyl oon 2 to carbon atoms, alkynyl with 2 to 2-0 carbon atoms or cycloalkyl with 3 to 6 carbon atoms substituted, if appropriate, one or more times, the substituents being independently selectable from Re, halogen, cyano, nitro, hydroxy, alkoxy with 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, dialkylamino 'with 2 to -8 carbon atoms, cycloalkylamino with 3 to -6 carbon atoms or (alkyl with 1 to 4 carbon atoms) cycloalkylamino with 3 to 6 carbon atoms or means substituted phenyl, optionally substituents, independently of one another, from one to three radicals W or one or more radicals R12, R1S, respectively, independently of each other, meaning hydrogen or halogenalkyl having 1 to 6 carbon atoms or alkyl with 1 to 6 carbon atoms substituted, if appropriate, one or more times, the substituents being independently selected from -cyano, nitro, hydroxy, akoxy with 1 to 4 carbon atoms, haloalkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, halogenalkylthio with 1 to 4 carbon atoms, haloalkisulfinyl with 1 to 4 carbon atoms, haloalkylsulfonyl with 1 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, dialkylamino with 2 to 8 carbon atoms, alkoxycarbonyl with 2 to 6 carbon atoms bond, alkylcarbonyl with 2 to 6 carbon atoms, trialkylsilyl with 3 to 6 carbon atoms or phenyl, optionally substituted, the substituents being independently selectable from one to three residues W or one or more residues R12, or N (R1S) 2 means a ring, which forms the ring M, RlG means alkyl with 1 to 12 carbon atoms or halogenalkyl with 1 to 12 carbon atoms, or N (R16) 2 / means a ring, which forms the ring M, R17 respectively mean, independently of each other, hydrogen or alkyl having 1 to 4 carbon atoms, or 5B (OR17 2 means a ring, in which both oxygen atoms are linked through a chain with two to three carbon atoms, which may be substituted, if appropriate, by one or two substituents chosen, independently from each other, from methyl or 1. 0 alkoxycarbonyl having 2 to 6 carbon atoms, R18 respectively meaning independently, hydrogen, alkyl having 1 to 6 carbon atoms or halogenalkyl having 1 to 6 carbon atoms, or N (R13) (R18) means a cycle, which forms the M ring, R19 respectively means, independently of one another, hydrogen or means alkyl with 1 to 6 carbon atoms substituted respectively, if desired, once or several times, the substituents being independently selectable from cyano, nitro, hydroxy, alkoxy with 1 to 4 carbon atoms, halogenoalkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, haloalkylthio with 1 to 4 carbon atoms, haloalkyl sulfinyl with 1 to 4 carbon atoms, halogenalkylsulfonyl with 1 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, dialkylamino with 2 to 8 carbon atoms, C02H, alkoxycarbonyl with 2 to 6 carbon atoms, alkylcarbonyl with 2 to 6 carbon atoms, trialkylsilyl with 3 to 6 carbon atoms or f-enyl, optionally substituted, it being possible to choose substituents, independently of one another, from one to three residues W, halogenalkyl with 1 to 6 carbon atoms, cycloalkyl with 3 to 6 carbon atoms or phenyl or pyridyl substituted respectively, if appropriate, one to three times by W, means a substituted ring. respectively, if appropriate, from one to four times, containing, in addition to the nitrogen atom, with which the pair of substituents R13 and R18, (R15) 2 or (R? e) 2, from two to six is linked. carbon atoms and, if necessary, furthermore, another nitrogen, sulfur or oxygen atom and the substituents may be chosen, independently of each other, from alkyl "with 1 to -2 carbon atoms, halogen, cyano, nitro or C 1 -C 2 -alkoxy means, independently of each other, alkyl with 1 to 4 carbon atoms, alkenyl with 2 to 4 carbon atoms, alkynyl with 2 to 4 carbon atoms, cycloalkyl with 3 to 6 carbon atoms carbon, halogen alkyl with 1 to 4 carbon atoms, halogen, non-alkenyl with 2 to 4 carbon atoms, halogenalkynyl with 2 to 4 carbon atoms, halogencycloalkyl with 3 to 6 carbon atoms, halogen, cyano, nitro, alkoxy with 1 to 4 carbon atoms, halogenoaloxy with 1 to 4 carbon atoms carbon, alkylthio with 1"to 4 atoms -carbon, alkylsulfinyl -with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, dialkylamino with 2 to 8 carbon atoms, cycloalkylamino with 3 to 6 carbon atoms,. { alkyl with 1 to 4 carbon atoms) cycloalkylamino with 3 to 6 carbon atoms, alkylcarbonyl with 2 to 4 carbon atoms, alkoxycarbonyl with 2 to 6 carbon atoms, C02H, alkylaminocarbonyl with 2 to 6 carbon atoms, dialkylaminocarbonyl with 3 to 8 carbon atoms or trialkylsilyl having 3 to 6 carbon atoms, n mean respectively, independently of each other, 0 or 1, p mean respectively, independently of each other, • 0, 1 or 2, being present, in the case where (a) R5 means hydrogen, alkyl with 1 to 6 carbon atoms, -halogenoalkyl with 1 to 6 carbon atoms, halogenal to ilo with 2 to 6 atoms of car-bono, halogenoalkynyl with 2 to -6 carbon atoms, halogenoalkoxy with 1 to 4 carbon atoms, haloalkylthio with 1 to 4 carbon or halogen atoms and (b) R8 means hydrogen, alkyl having 1 to 6 carbon atoms, halogenalkyl with 1 to 6 carbon atoms, halogenalkenyl with 2 to 6 carbon atoms, halogenalkynyl with 2 to 6 carbon atoms, halogenalkoxy with 1 to 4 carbon atoms, halogenalkylthio with 1 to 4 carbon atoms, halogen, alkylcarbonyl with 2 to 4 carbon atoms, alkoxycarbonyl with 2 3 6 carbon atoms, alkylaminocarbonyl with 2 to 6 carbon atoms or -dialkylaminocarbonyl with 3 to 6 carbon atoms. to 8 carbon atoms, (c) at least one substituent, chosen from R ^, Ru and R12 and (d), when R12 is not present, at least one R6 or R11 is different from alkylcarbonyl with 2 to 6 carbon atoms, alkoxycarbonyl with 2 a 6 carbon atoms, alkylaminocarbonyl with 2 to 6 carbon atoms and dialkylaminocarbonyl with 3 to 8 carbon atoms and the compounds of the general formula (I), also include the N-oxides and the salts, and, at least, an active insecticide product of groups 2 and3 below, chosen from A) (thio) phosphates (group 2), preferably (2-1) Azinphos-methyl (known from the US publication 2, 758, 115) and / or (2-2) Chlorpyrifos (known from US 3,244,586) and / or - (• 2-3) Diazinon (known from US 2,754,243) and / or (2-4) Dimethoat (known from US 2,494.2 3) and / or (2-5) Disulfoton (known from the publication DE-A 91 76 68) and / or (2-6) Ethion (known from US publication 2, 873, 223) and / or (2-7) Fenitrothion (known by the publication BE-A • 0 594 669) and / or (2-S) Fenthion (known from the publication DE-A 11 16656) and / or (2-9) Isoxathion (known by the publication DE-A 15 67 137) I (2-10) Malathion (known from US 2,578,562) and / or (2-11) Methidathion (known by the publication DE-A 16 45 982) and / or (2-12) Oxydemeton-methyl (known by the publication DE-A 94 73 68) and / or (2-13) Parathion (known by the publication DE-A -81 41 52) and / or (2-14) Parathlon-methyl (known by the publication DE-A 81 41 42) and / or (2-15) Phenthoat (known as GB-A 834 814) and / or (2-16) Phorat (known by the US publication 2,586,655) and / or (2-17) Phosalon (known by the publication DE-A 24 31 192) and / or • (2-1.8) Pho-s et (known by the publication ÜS and / or (2-19) Phoxim (known by the publication DE-A 12 38 -902) and / or (2-2O) -P i rimiphos-.n i lo (known by the publication DE-A 14 45 949) and / or (2-21) Pr-o'fenoph-os (known by the publication DE-A 22 4'9 462) and / or (2-22) P-rothiophos (known by the publication D? -A 21 11 41-4) and / or (2-23) Tebupirimphos (known from the publication DE-A 3 17 824) and / or (2-2-4) Triazophos (known from publication DE-A 1-2 9 924) and / or (-2-25) Chlorfe vinphos (known from the US publication, 956.073) and / or (2-2-6) DichlOrpho-s (known by the publication -GB-A 75 065) and / or (2-27) Dicrotophos (known by the publication BE-A 55 22 84) and / or (2-28) Mevinphos. { known from the US publication, 6-85,552) and / or (2-29) Monocrotophos (known from the publication DE-A 19 64 535) and / or (2-3-0) -Phosphamidon (known from the US publication 2, -908,605) and / or (2-31) Acephat (known from the publication DE-A 20 14 027) and / or (2-32) Methamidophos (known by the US publication) 3,309,266) and / or (2-33) Trichlorfon (known from the US publication 2,701,225) and / or B) carbamates - (group 3), preferably (3-1) Carbaryl (known from the US publication 2,903.47-8) and / or (3-2) Fenoxycarb (known by the publication EP-A 0 -004 334) and / or (3-3) -Formetanat (known by the publication DE-A 11 69 194) and / or (3-4) For etanat hydrochloride (known by the publication DE-A 11 € 9 194) and / or (3-5) Methiocarb. { known from the publication DE-A 11 62 352) and / or (3-6) Methomyl (known by the US publication) 3,639,620) and / or (3-7) Oxamyl (known from the publication DE-A 17 58 623) and / or (3-8) Pirimicarb. { = Pirimor) (known by the Dublication GB-A 1 181 657) and o (3-9) Propoxur (known by the publication DE-A 11 D8 202) and / or (3-10) Thiodicarb (known from the publication -DE-A 25 439) They have synergistic activity and are suitable for the fight against animal pests. • Surprisingly, the insecticidal and acaricidal activity of the combination of active products, according to the invention, is essentially greater than the sum of the activities of the individual active products. There is an authentic synergistic effect, not foreseeable, and not just a complement of the activities. The active compound combinations, according to the invention, contain, in addition to, at least one active product of the formula (I), at least one active product of group 2 [chosen between compounds (2-1) to (2-33)] and / or group 3 [chosen among compounds (3-1) to (3-10)] . The compounds of the formula (I) can also be present, depending on the type of the substituents, as isomers or mixtures of geometric and / or optical isomers, with a variable composition, which can be separated, if appropriate, in a manner and manner usual Both the pure isomers, as well as the -me-zclas of the isomers, their obtaining and use, as well as the agents that the. contain, constitute the object of the present invention. However, the compounds of the formula (I) will be discussed below, even if the pure compounds as well as the mixtures with variable proportions of the isomeric compounds are to be indicated. Preference is given to combinations of active compounds, which contain compounds of the formula (1-1) wherein R2 means hydrogen or alkyl having 1 to 6 carbon atoms, R3 means alkyl having 1 to 6 carbon atoms, which is, if appropriate, substituted by R6, R4 means alkyl having 1 to 4 carbon atoms, haloalkyl with 1 to 2 carbon atoms, halogenalkoxy with 1 to 2 carbon atoms or halogen, R5 means hydrogen, alkyl with 1 to 4 carbon atoms, halogenalkyl with 1 to 2 carbon atoms, halogenalkoxy with 1 to 2 carbon atoms or halogen, R6 means -C (= E2) R19, -LC (= E2) R19, -C (= E2) LR19 or -LC (= E2) LR19, meaning each E2, independently of each other O, S, N-R15, N-OR15, NN (R15) 2, and meaning each L, independently of each other, O or NR18, R7 means haloalkyl with 1 to 4 carbon atoms or halogen, R9 means halogenalkyl with 1 to 2 carbon atoms, halogenalkoxy with 1 to 2 carbon atoms, S (0)? -haloalkyl with 1 to 2 carbon atoms or halogen, R15 mean, independently hydrogen or halogenalkyl with 1 to 6 carbon atoms or alkyl with 1 to 6 carbon atoms substituted, respectively, optionally, the substituents being independently selected from -cyano, alkoxy with 1 to 4. carbon atoms, halogenalkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms , halogenalkylsulfinyl with 1 to 4 carbon atoms or halogenoalkylsulfonyl with 1 to 4 carbon atoms, R 18 respectively denote hydrogen or alkyl with 1 to 4 carbon atoms, R 19 signifies, respectively, independently of each other, hydrogen or C 16 alkyl, p mean, independently of each other, O, 1, 2, and, at least, an active product of group 2 [chosen between compounds (2-1) through (2-33)] and / or of group 3 [chosen from among the compounds (3-1) to (3-10)]. In the definitions cited as preferred, halogen means fluorine, chlorine, bromine and iodine, especially means fluorine, chlorine and bromine. Particularly preferred are the active compound combinations, which contain compounds of the formula (I-1), in which R 2 is hydrogen or methyl, R 3 is alkyl with 1 to 4 carbon atoms (especially ethyl, ethyl, n-, iso -propyl, n-, iso-, sec-, tere.-butyl), R4 means methyl, trifluoromethyl, trifluoromethoxy, fluorine, chlorine, bromine or iodine, Rs means hydrogen, fluorine, chlorine, bromine, iodine, trifluoromethyl or trifluoromethoxy R7 is chlorine or bromine, R9 is trifluoromethyl, chlorine, bromine, difluoromethoxy or trifluoroethoxy, and at least one active ingredient of group 2 [selected from compounds (2-1) to (2-33)] and / or of group 3"[selected from compounds (3-1) to (3-10)]. active products, which contain the following compounds of the formula (1-1): Example R¿R R4 • R * R7 Ry Pf. (° C) Nr. 1-1-1 H Me Me -Cl Cl • CF3 1-85-186 1-1-2 H Me -Me Cl Cl CH2CF3 207-206 1-1-3 H Me Me Cl • Cl Cl 225-226 1- 1-4 H Me Me Cl Cl B 162-164 1-1-5 H Cl Cl Cl Cl3 155-157 1-1-6 H Cl Cl Cl OCH2CF3 192-195 1-1-7 H Cl Cl Cl Cl • CI Cl 205-2-06 1-1-8 H Cl Cl Cl Cl 245-246 1-1-9 H i- Me Cl • Cl CF3 195-196 -Pr 1-1-10 H i- Me Cl Ol OCH2CF3 217-218 Pr 1-1-11 • H i- Me -Cl Ol Cl 173-175 -Pr 1-1-12 «i- Me Cl Cl Br 159-161 Pr Example R2 R3 R4 R5 R7 R5 Pf. (° C) Nr. 1-1-13 H? ^ C? Cl C? CF_ 200-201 Pr 1-1-14 H i Cl Cl Cl OCH2CF3 232-235 Pr 1-1-15 H i Cl Cl Cl 197-199 Pr 1-1-16 H i- Ol 01 Ol Br 18 '8-190 Pr 1-1-17 H Et Me Cl • Cl CF3 163-164 1-1-18 H Et Me Cl Cl OCH2CF3 205-207 1-1-19 H Et -Me Cl Cl Cl 199-200 1-1-2-0 H Et Me Cl 01 Br 194-195 1-1-21 H Et Cl 01 IÍ CF3 201-202 1-1-22 H Et Cl 01 Ol Ol 206-208 1-1-23 -H Et Cl OÍ Cl Br 214-215 1-1-24 H t- e Ol Cl CF3 223-225 -B- 1-1-25 H t-e Cl 'Ol Cl 163-165 Bu 1-1-26 H t- e Cl Ol -Br 159- 161 _3u Example R2 R3 R4 R5 R7 R9 Pf. (° C) Nr. 1-1-27 H ~ C? C? C? CF_ ^ 170-172 Bu 1-1-28 H t Cl Cl CL 172-173 Bu 1-1-29 H t- 01 Cl 01 • Br 179-180 Bu? -r-30 H Me Me Br Cl CF3 222-223 1-1-31 H Et Me • Br Cl OF3 192-193 1-1-32 H i- Me Br Ol CF3 197-198 Pr 1-1-33 H t- Me Br Cl CF3 247-248 Bu 1-1-34 H Me Me Br Cl Cl 140-141 1-1-35 H Et -Me Br Cl Cl 192-194 1-1-36 H i- • Me • Br Cl Cl 152-153 Pr 1-1-37 fí t- Me Br Cl Ol 224-225 Bu 1-1-38 H Me -Me Sr Cl .Br 147-149 1-1-39 H Et -Me Br 01 Br 194-196 1-1-40 H i- e Mr. Ol Br 185-187 Pr Example R2 R3 2 R5 R7 R5 Pf. (° C) Nr. 1-1-41 H ~ Me "Br C? Br 215-221 Your 1-1-42 H Me Me I Cl CF3 199-200 1-1-43 H Et Me 1 Ol CF3 199-2.00 1-1-44 H i- .Me I Cl OF3 1-88-189 Pr 1-1-45 H t- Me I Cl CF3 242-243 Bu 1-1-46 H Me Me Cl Cl 233-234 1-1-47 H Et Me I Cl Cl 196-197 1-1-48 H i- Me I Cl Cl 189-190 Pr 1-1-49 H t- Me Cl Cl 228-229 Bu 1-1-50 H Me Me I Cl Br 229-230 1-1-51 H iPr Me I Cl Br 191-192 1-1-52 H Me Sr Br Ol OF3 162-163 1-1-53 H Et Br Br Cl CF3 188-189 1-1-54 -H i- Sr Br Cl CF3 192-193 Pr 1-1-55? t- Br Mr Cl OF3 246-247 Bu Example Rz R3 R4 R5 R7 R9 Pf. (° C) Nr. 1-1-56 H Me Br Br Cl Cl 188-190 1-1-57 H Et Br Br 01 Cl 192-194 1-1-58 H i- Br Br Cl Cl 197-199 Pr 1-1-59 H t- Br Br Cl Cl 210-212 Bu 1-1- 60 H Me Br Br Cl Br 166-168 1-1-61 H Et Br Br Cl Br 196-197 1-1-62 H i- Br Br 01 Br 162-163 Pr 1-1-63 H t- Br Br Cl Br 194-196 Bu 1-1-64 H t- Cl Br Cl CF3 143-145 Bu 1- 1-65 Me Me Br Br Cl Cl 153-155 1-1-66 Me Me Me Br Cl CF3 207-208 1-1-67 Me Me Ol Cl Cl Cl 231-232 1-1-68 Me Me Br Br Cl Br 189-190 1-1-69 Me Me Cl Cl Cl Br 216-218 1-1-70 Me Me Ol Ol Cl CF3 225-227 1-1-71 Me Me Br Br 01 CF3 22 «-229 Example R2 R3 I3 R5 R R5"f. (° C) Nr. 1-1-72 H Me H Cl CF3 237-239 Pr and, at least, an active product of group 2 [chosen between the compounds (2-1) to (2-33)] and / or of the group 3 [chosen between the compounds (3-1) to (3-10) ] Combinations of active products are especially preferred. containing a compound of the following formulas (1-1-24) (1-1-26) (1-1-27) (1-1-43); 1-1-44) (1-1-5-0) (1-1-57) (1-1-58) (1-1-60) (1-1-71) (1-1-72) and, at least, one active product of group 2 [chosen among the compounds (2-1) -up to (2-33)] and / or the group 3 . { chosen among the compounds (3-1) - up (3-10)]. Preference will be given to combinations of active compounds according to the invention, preferably containing the following group 2 active substances: (2 ^ -2). Chlorpyri os, (2-31) Acephat, (2-32) Methamidophos. "Preferred combinations of active ingredients, according to the invention, which preferably contain the following active group 3 products: (3-1) Oarbaryl, (3-5) Methiooarb, (3-) 10) Thiodicarb.

The active compound combinations, cited below individually (binary mixtures), which contain a compound of the formula (1-1) and the indicated active product of group 2 or group 3 must be listed: Product combination Product combination Nr. Nr. • active, containing active, containing 5a) -2) Chlorpyrifos 32a) (1-1-44 and (2-2) Chlorpyrifos 5b) -31) Acephat 32b) (1-1-44 y ( 2-31) Acephat 5c) -32) Methamidophos 32c). { 1-1-44 and (2-32) Met amidophos 5d) -1) Carbaryl 32d) (1-1-44 and (3-1) Carbaryl 5e) -5) Methiocarb 32e) (1-1-44 y ( 3-5) Methiocarb 5f) -10) Thiodicarb 32f) (1-1-44 and (3-10) Thiodicarb 6a) -2) Chlorpyrifos 33a) (1-1-50 and (2-2) Chlorpyrifos 6b) - 31) Acephat 33b) (1-1-50 and (2-31) Acephat € c) -32) Methamidophos 33c) (1-1-50 y { 2-32) Metharaidophos 6d) -1) Carbaryl 33d) (1-1-50 and (3-1) Carbaryl - € e) - 5) Methiocarb 33e) (1-1-50 and (3-5) Methiocarb • 6f) -10) Thiodicarb 33f) (1-1-50 and (3-1) Thiodicarb 7a) -2) Chlorpyrifos 34a) (1 -1-51 and (2-2) Chlorpyrifos 7b) -31) Acephat 34b) (1-1-51 and (2-31) Acephat 7c) -32) Methamidophos 34c) (1-1-51 and (2- 32) Methamidophos 7d) -1) Carbaryl 34-d) (1-1-51 and (3-1) Carbaryl 7e) -5) Methiocarb 34e) (1-1-51 y {3.5) Methiocarb 7f ) 3-10) Thiodicarb 34f) (1-1-51 and (3-10) Thiodicarb 8a) 2-2) Chlorpyrifos 35a) (1-1-52 and (2-2) Chlorpyrifos 8b) -31) Acephat 35b ) (1-1-52 and (2-31) Acephat 8c) -32) Methamidophos 35c) (1-1-52 y { 2-32) Methamidophos 8d) -1) Carbaryl 35d) (1-1- 52 and (3-1) -Carbaryl 8e) 3-5) Methiocarb 35e) (1-1-52 and <; 3-'5) Methiocarb 8f) -10) Thiodicarb 35f). { 1-1-52 and (3-10) Thiodicarb 9a) 2-2) Chlorpyrifos 3-6a) (1-1-53 and (2-2) Chlorpyrifos 9b) 2-31) Acephat 36b) (1-1- 53 and (2-31) Acephat 9c) 2-32). Methamidophos 36c) (1-1-53 y { 2-32) Methamidophos 9d) 3-1) -Carbaryl 3 «d) (1-1- 53 and (3-1) Car-baryl 9e) 3-5) Methiocarb 36e) (1-1-53 and (3-5) Methiocarb 9f) 3-10) Thiodicarb 3íf) (1-1-53 and (3- 0) Thiodicarb 0 '5 0 5 Product combination Product combination Nr. Active Nr., Containing active, which -have 15a) -2) Chlorpyrifos 42a) (1-1-60 and -2) Chlorpyrifos 15b) -31) Acephat 42b) (1-1-60 and -31) Accephat 15c) -32) Methamidophos 42c) (1-1-60 and -32) Methamidophos 15d) -1) Carbaryl 42d) (1-1-60 and -1) Carbaryl 15e) -5) Methiocarb 42e) (1- 1-60 and -5) Methiocarb 15f) -10) Thiodicarb 42f) (1-1-60 and -10) Thiodicarb 16a) -2) Chlorpyrafos 43a) (1-1-61 and -2) -Chlorpyrifos 16b) - 31) Acephat 43b) (1-1-61 and -31) Acephat 16c) -32) Methamidophos 43c) (1-1-61 and -32) Methamidophos 16d) -1) Carbaryl 43d) (1-1-61 y -1) Carbaryl 16e) -5) Methiocarb 43e) (? -1-61 and -5) Methiocarb 16f) -10) Thiodicarb 43f) (1-1-61 and -10) Thiodicarb 17a) -2) Chlorpyrifos 44a) (1-1-62 and -2) Chlorpyrifos 17b) -31) Acephat 44b) (1-1-62 and -31) Acephat 17c) -32) Methamidophos 44c) (1-1-62 and -32) Methamidophos 17d ) -1) Carbaryl 44d) (1-1-62 and -1) Carbaryl 17e) -5) Methiocarb 44e) (1-1-62 and -5) Methiocarb 17f) -10) Thiodicarb 44f) (1-1- 62 and -10) Thiodicarb 18a) -2) Chlorpy ifos 45a ) (1-1-64 and -2) Chlorpyrifos 18b) -31) Acephat 45b) (1-1-64 and • 31) Acephat ISO -32) Methamidophos 45c) (1-1-64 and -32) Methamidophos 18d ) -1) Carbaryl 45d) (1-1-64 and 1) Carbaryl ISe) -5) Methiocarb 45e) (1-1-64 and • 5) Methiocarb "18f) -10) Thiodicarb 45f) (1-1- 64 and 10) Thiodicarb 19a) -2) Chlorpypfos 46a) (1-1-65 and 2) Chlorpyrifos 19b) -31) Acephat 46b) (1-1-65 and 31) Acephat 19c) 2-32) Methamidophos 46c) (1-1-65 and 32) Methamidophos lSd) 3-1) Carbaryl 46d). { 1-1-65 and 1) Ca-rbaryl 19e) 3-5). Methiocarb 46e) (1-1-65 and 5) Methiocarb 19f) 3-10) Thiodicarb 46f) (1-1-65 and 10) Thiodicarb Product combination Combination and product Nr. Active Nr., Qu. > contain active • iae contain 20a) (1-1-26) and 2-2) Chlorpyrifos 47a). { 1-1-66) and (2-2) Chlorpyrifos 20b) (1-1-26) and 2-31) Acephat 47b) (1-1-66) and (2-31) Acephat 2-Gc) (1-1-26) and -i 2-32) -Methamidophos 47c) (1-1-66) and (2-32) Methamidophos 20d) (1-1-26) and 3-1) Carbaryl 47d) (1-1-66) and (3-1) Carbaryl 20e) (1-1-26) and 3-5) Methiocarb 47e) (1-1-66) and (3-5) Methiocarb 20f) - (1-1-26) and 3-10) Thiodicarb 47f). { 1-1-66) and. { 3-10) Thiodicarb 21a)? -1-27) and -i 2-2) Chlorpyrifos 48a) (1-1-67) and •. { 2-2) • Ghlorpyri-fos 21b) (1-1-27) and 2-31) Acephat 48b) (1-1-67 and (2-31) Acephat 21c) (1-1-27 and 2-32) Methamidophos 48c). { 1-1-67 and (2-32) Methamidophos 21d) (1-1-27 and 3-1) Carbaryl 48d) (1-1-67) and. { 3-1) -Carbaryl 21e) (1-1-27 and 3-5) Methiocarb 48e) (1-1-67 and (3-5) Methiocarb 21f) (1-1-27 and 3-10) Thiodicarb 4-8f) (1-1-67 and. {3-10) Thiodicarb 22a) (1-1-29 and 2-2) Chlorpyrifos 49a) (1-1-68 and [2-2) Chlorpyrifos 22b) (1-1-29 and 2-31) Acephat 49b) (1-1-68 and (2-31) Acephat 22c) (1-1-29, and 2-32) Methamidophos 49c) (1-1-68 and (2-32) Methamidophoe 22d) (1-1-29 and 3-1) Carbaryl 49d). { 1-1-68 and (3-1) Carbaryl 22e) (1-1-29 and 3-5) Methiocarb 49e) (1-1-68 and (3-5) Methiocarb 22f) (1-1-29 and (3-10) Thiodicarb 49f) (1-1-68 and (3-10) Thiodicarb 23a) (1-1-30 and (2-2) Chlorpyrifos 50a) (1-1-69 and (2-2) Chlorpyrifos 23b) (1-1-30 and (2-31) Acephat 50b) (1-1-69) and • (2-31) Acephat 23c) (1-1-30 and (2-32) Methamidophos' 50c) . { 1-1-69) and. { 2-32) Methamidophos 23d) (1-1-30 and (3-1) -Carbaryl \ 50d) (1-1-69) and (3-1) Carbaryl 23e) (1-1-30 and (3-5) Methiocarb 50e) (1-1-69) and (3-5) Methiocarb 23f) (1-1-30 and (3-10) Thiodicarb 50f) (1-1-69) and (3-10) Thiodicarb 24a) (1-1-31 and (2-2) Chlorpyrifos] 51a) (1-1-70) and (2-2) Chlorpyrifos 24i) -. { 1-1-31 and (2-31) Acephat 51b) (1-1-70) and (2-31) Acephat 24c) (1-1-31 and (2-32) Methamidophos i 51c) (1- 1-70) and (2-32) Methamidophos 24d) (1-1-31 and (3-1) Carbaryl; 51d) (1-1-70) and. { 3-1) -Carbaryl 24e). { 1-1-31 and (3-5) Methiocarb 1 51e) (1-1-70) and (3-5) Methiocarb 24f) (1-1-31 and (3-10) Thiodi-carb j 51f) (1-1-70) and (3-10) Thiodicarb Product combination Product combination Nr. Active Nr., Containing active, containing 25a) '(1-1-32) and (2-2) Chlorpyrifos 52a)' (1-1-71) and (2-2) Chlorpyrifos -25b) (1-1-32) and (2-31) Acephat 52b) (1-1-71) and (2-31) Acephat 25c) • (1-1-32) and (2-32) Methamidophos 52c) (1-1-71) and (2-32) Methamido hos 25d) (1-1-32) and (3-1) Carbaryl 52d) (1-1-71) and (3-1) Carbaryl 25e). (1-1-32) and (3-5) Methiocarb 52e) (1-1-71) and (3-5) Methiocarb 2'5f) '(1-1-32) and (3-10) Thiodicarb 52f). { 1-1-71) and (3-10) Thiodicarb 26a). { 1-1-33) and (2-2) -Chlorpyrifos S3a) (1-1-72) and (2-2) -Chlorpyri.fos 26b) (1-1-33) and (2-31) Acephat 53b) (1-1-72) and (2-31) Acephat 26c) (1-1-33) and (2-32) Methamidophos 53c) (1-1-72) and (2-32) Methamidophos • 26d) '(1-1-33) and (3-1) Ca-rbaryl 53d) (1-1-72) and (3-1) -Carbaryl 26e): (1-1-33) and (3) -5) -Methiocarb 53e) (1-1-72) and. { 3-5) Methiocarb 26f) (1-1-33) and (3-1O) Thiodicarb 53f) (1-1-72) and (3-10) Thiodicarb 27a) (1-1-38) and (2-2) Chlorpyrifos 27b) (1-1-38) and (2-31) Acephat 27c) (1-1-38) and (2-32) Methamidophos 27d) (1-1-38) and (3-1) Carbaryl 27e) (1-1-38) and (3-5) Methiocarb • 27f) (1-1-38) and (3-10) Thiodicarb However, the definitions of the remains or the explanations given above in a genemanner or indicated in the preferred ranges may be combined arbitrarily with each other, ie between the respective preferred ranges and intervals. These are valid, of Tianera corresponding, for the final products as well as for the products of departure and for the intermediate products. In accordance with the invention, the combinations of the active compounds containing the compounds of the formula (I) and the active compounds of the formulas (2-1) to (2-23), in which the individual residues have a combination of the meanings indicated above as preferential (preferably).

According to the invention, combinations of the active compounds containing the compounds of the formula (I) and the active compounds of the formulas (2-1) to (2-23), in which the individual residues have a combination of the meanings indicated above as being especially preferred. According to the invention, combinations of the active compounds containing the compounds of the formula (I) and the active compounds of the formulas (2-1) to (2-23), in which the individual residues are particularly preferred, will be particularly preferred. have a combination of the meanings indicated above as being very particularly preferred. The saturated or unsaturated hydrocarbon radicals, such as alkyl or alkenyl, can be, even in combination with heteroatoms, such as, for example, alkoxy, as far as possible, respectively straight-chain or branched chain. The substituted radicals, if any, may be monosubstituted or polysubstituted, the substituents being the same or different in the case of a polisubstitution. The active compound combinations may also contain other mixing components with fungicidal, acaricidal or insecticidal action. When the active compounds are present in the active compound combinations, in accordance with the invention, in certain proportions by weight, the synergistic effect will be particularly evident. The • proportions of the mixture, which are required to achieve synergism, do not necessarily represent the preferred mixing proportions, which are relevant for a 100% effect. However, the proportions by weight of the active products may vary in the combinations of active products within a relatively broad range. In gene the combinations, according to the invention, have the active compound of the formula (I) and the mixture components of the group (2) or of the group (3) in the preferred and especially preferred mixing proportions indicated: The proportions of the mixture are based on the proportions n weight. The proportion must be understood as the product-active of the formula (I): component of the mixture Component of the mixture Preferential proportion of the Especially preferred mixture proportion of the mixture (2-1) Azinphos-methyl 10: 1 to 1:10 5: 1 to 1: 5. { • 2-2) • Chlorpyrifos 10: 1 to 1:10 5: 1 to 1: 5 (2-3) Diazinon 10: 1 to 1:10 5: 1 to 1: 5 (2-4) Dimethoat 10: 1 up to 1:10 5: 1 to 1: 5 (2-5) • Disulfoton 10: 1 to 1:10 5: 1 to 1: 5 (2-6) Ethion 1-0: 1 to 1:10 5: 1 up to 1: 5 (2-7) Fenitrothion 10: 1 to 1:10 5: 1 to 1: 5 (2-8) Fenthion 20: 1 to 1:10 5: 1 to 1: 5 (2-9) Isoxathion 10: 1 to 1:10 5: 1 to 1: 5 (2-10 Malathion 10: 1 to 1:10 5: 1 to 1: 5 { 2-11 Methidathion 10: 1 to 1:10 5: 1 up to 1: 5 (2-12 Oxydemeton-methyl 10: 1 to 1:10 5: 1 to 1: 5 (2-13 Parathion 10: 1 to 1:10 5: 1 to 1: 5. • Parathion-methyl 10: 1 to 1:10 5: 1 to 1: 5 { • 2-15 Phenthoat 10: 1 to 1:10 5: 1 - up to 1: 5 (2-16 Phorat 10: 1 up 1:10 5: 1 to 1: 5 (2-17 Phosalon 10: 1 to 1:10 5: 1 to 1: 5 (2-18 Phosmet 10: 1 to 1:10 5: 1 to 1: 5 (2 -19 Phoxim 10: 1 to 1:10 5: 1 to 1: 5 (2-20 Pirimiphos-methyl 10: 1 horn 1:10 5: 1 to 1: 5 (2-21 Profenophos 10: 1 to 1:10 5: 1 to 1: 5 (2-22 P rothiophos 10: 1 to 1:10 5: 1 - up to 1: 5. { 2-23 Tebupyrimphos 10: 1 to 1:10 5: 1 to 1: 5 (2-24 Triazophos 5: 1 to 1:20 1: 1 to 1:10 { 2-25 Chlorfenvinphos 10: 1 to 1: 10 5: 1 to 1: 5 {2-26 Dichlorphos 10: 1 to 1: 1-0 5: 1 to 1: 5 { 2-27 • Dicrotophos 10: 1 • to 1:10 5: 1 up to 1: 5 (2-28 .Mevinphos 10: 1 • up to 1:10 5: 1 to 1: 5 (2-29 onocrotophos 10: 1 to 1:10 5: 1 to 1: 5 Component of the mixture Preferred proportion of the Mixture mixture. Especially preferred of the mixture (2-30) Phosphamidon 10: 1 to 1:10 5: 1 to 1: 5 (2-31) Acephat 10: 1 to 1:10 5: 1 - up to 1: 5 (2-32) Methamidophos 10: 1 up to 1:10 5: 1 to 1: 5 (2-33) Trichlorfon 10: 1 to 1:10 5: 1 to 1: 5 (3-1) Carbaryl 10: 1 to 1: 1-0 5: 1 to fifteen . { 3-2) -Fenoxycarb 10: 1 to 1:10 5: 1 to 1: 5 (3-3) Formetanat 10: 1 to 1:10 5: 1 to 1: 5. { 3-4) Formetanat 10: 1 to 1:10 5: 1 to 1: 5 hydrochloride 43-5) Methiocarb 10: 1 to 1:10 5: 1 to 1: 5 (3-6) Methomyl 10: 1 to 1 : 10 5: 1 to 1: 5. { 3-7) Oxamyl 5: 1 to 1: 100 1: 1 to 1:20. { 3-8) Pirimicarb 10: 1 to 1:10 5: 1 to 1: 5 (3-9) Propoxur 10: 1 to 1:10 5: 1 to 1: 5 (3-10) Thiodicarb 5: 1 to 1 : 20 1: 1 to 1:10 The combinations of the active products are suitable for the control of animal pests, preferably against arthropods and nematodes, especially against insects and arachnids, which occur in agriculture, in animal health, in forestry, for the protection of stored products. and of the materials as well as in the hygiene sector. These are active against normally sensitive and resistant species as well as against all or against the stages of individual development. To the pests previously cited belong: from the order of the Isopoda for example, Oniscus asellus, Armadillidium vulgare, Porcellio sc ber. From the order of the Diplopoda, for example, Blaniulus guttulatus. From the order of the C lopoda, eg, Geophilus carpsphagus, Scutigera spp. . From the order of the 'Symphyla, -for example, -Scutigerella ipmaculata.

From the order of the Ihysanura, for example, lepisma saccharina. From the order of the Collembola, for example, Onychiurus armatus. From the order of Orthoptera, for example, Acheta domesticus, Oryllotalpa spp. , Locusta -migratory migration, Melanoplus spp. , Schistocerca gregaria. From the order of the Blattaria, for example Blatta orientalis, Periplaneta americana, L ucophaea maderae, Blatella gei ianica, From the order of the Dermaptera, for example, Forfícula auricularia.

From the order of the Isoptera, for example, Reticulitermes epp. . From the order of Phthiraptera, for example Pediculus humanus corparis, Haematopinus spp. , Linognathus spp. , Trichodectes spp. , Damalinia spp. . From the order of the Thysanoptera, for example, Hercinothrips femoralis, Thrips tabaci, T rips palmi, Fankliniella accidentalis. . From the order of the Heteroptera, for example,? Urygaster spp. , Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius -prolixus, Triatoma -spp. . 33 From the order of the homoptera, for example, Aleurodes brassicae, Bemrsia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicas, Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Phylloxera vastatrix, Pemphigus spp., Macrosiphum avenae, Myzus spp., Phorodon humuli, Rhopalosiphum -padi, Empoasca spp., "Euscelis -bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodephax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp. and Psylla spp. From the order of the Lepidoptera, for example, Pectinophora gossypiella, Bupalus piniarius, Cheimatobia bru ata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp., Feltia epp., Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, 'Gallería mellonella, Tineola bisselliella, Tinea pellionella, Hofmannophila pseudospretella, Cacoecia podana, Capua reticulana, Ohoristoneura fumiferana, Olysia ambiguella, Homona magnanimous, Tortrix viridana, Cnaphalocerus spp. , Oulema oryzae. From the order of the Coleoptera, for example, Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes-bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varivestis, Atomaria spp., Oryzaephilus surinamensis, Anthonomus spp., Sitophilus spp., O iorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma - spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis , Osstelytra zealandica, Lissorhcptrus orysophilus .. Dsl order of Hymenoptera, for example, Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp. From the order of the Diptera, for example, Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Oalliphora erythrocephala, Lucilia spp., Chrysomya spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp., Oestrus spp. , Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Typula paludosa, Hylemyia spp., Liriomyza spp. From the order of the Siphonaptera, for example, Xenopsylla sheopis, Ceratophyllus spp. From the class of the Arachnida, for example, "Scorpio maurus, Latrodectus actans, Acarus siró, Argas spp., Ornithodoros spp., Dermanyssus gallinae,? riophys-rib s, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hylamma spp., Ixodes spp., Psoroptes spp., Chorioptes spp. , Sarcoptes spp. , Tarsonemus spp. , Bryobia praetiosa, Panonychus spp., Tet-ranychus spp., Hemitarsonemus spp. , Brevipalpus spp. Plant parasitic nematodes include, for example, Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp. , Olobodera spp. , Meloidogyne spp. , Aphelenchoides spp. , Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp. The active compound combinations according to the invention can be transformed into the customary formulations, such as solutions, emulsions, injectable powders, suspensions, powders, dusts. , pastes, soluble powders, granules, suspension-emulsion concentrates, natural and synthetic materials impregnated with the active product, as well as microencapsulated in polymer materials. These formulations are prepared in known manner, for example by mixing the active ingredients with extenders, ie with liquid solvents and / or solid excipients, optionally with the use of surfactants, ie emulsifiers and / or dispersants and / or foam generating means.

When water is used as an extender, organic solvents may be used, for example, as auxiliary solvents. Preferred liquid solvents are: a-romatic hydrocarbons, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatic hydrocarbons and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, for example petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol, as well as their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, or the solvents • strongly polar, such as dimethylformamide and dimethyl sulfoxide as well as water. Suitable solid excipients are, for example, ammonium salts and natural mineral flours, such as kaolins, clays, talc, chalk, quartz, attapulgi, montmorillonite-or diatomaceous earth and the "synthetic molten minerals, such as highly silicic acid". dispersed, aluminum oxide and silicates, as excipients - solids for granulates come into consideration: for example broken and fractionated natural minerals, such as - calcite, marble, pumice, sepiolite, dolomite, as well as synthetic granulates of flours inorganic and organic as well as granulates of organic material, such as sawdust, coconut husk, corn ears and tobacco stems; Suitable emulsifiers and / or foam generators are, for example, non-ionogenic and anionic emulsifiers, such as polyoxyethylenated esters of fatty acids, polyoxyethylenated ethers of fatty alcohols, for example, alkylaryl polyglycol ether, sulfonates of alkyl, the alkyl sulphates, the aryl sulfonates, as well as the albumin hydrolysates; Dispersants are considered as: for example, sulphite lignin bleach and methylcellulose. In the formulations, adhesives such as carboxymethylcellulose, natural and synthetic polymers powdery, granulated or in the form of latex, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, as well as natural phospholipids such as lecithin and phospholipids, and synthetic phospholipids can be used. Other additives can be mineral and vegetable oils . Dyes, such as inorganic pigments, for example, iron oxide, titanium oxide, Prussian blue and organic dyes, such as • alizarin, azo and phthalocyanine dyes, as well as trace nutrients, such as iron salts, can be employed. , of manganese, boron, copper, cobalt, molybdenum and zinc. The formulations contain, in general, between 0.1 and 95% by weight of active compound, preferably between 0.5 and 90%.

The active compound combinations, according to the invention, can be presented in their commercially available formulations as well as in the forms of application prepared from these formulations, in mixture with other active products, such as insecticides, baits, sterilants, bactericides, acaricides, nematicides, fungicides, growth regulators or herbicides. Insecticides include, for example, esters of phosphoric acid, carbamates, esters of carbonic acid, chlorinated hydrocarbons, phenylureas, products prepared by means of microorganisms and the like. A mixture with other known active ingredients, such as herbicides or with fertilizers and growth regulators is also possible. The active compound combinations, according to the invention, can also be used, when used as insecticides, in their customary formulations in commerce as well as in the forms of application prepared from these formulations in a mixture with synergists. The synergists are the compounds by which the effect of the active products is increased, without the added synergist having to be active in itself.

The active product content of the application forms, prepared from the usual commercial formulations, can vary within wide limits. The "active product concentration of the application forms can be between 0.0000001 to 95% by weight of active compound, preferably between 0.0001 and 1% by weight. The application is carried out in a manner adapted to the forms of application. In the use against hygiene pests and stored products, combinations of active products are characterized by an excellent residual effect on wood and clay as well as good stability to alkalis on whitewashed supports. The active compound combinations according to the invention are not only active against plant pests, hygiene and stored products, but also in the field of veterinary medicine against animal parasites (ectoparasites) such as hard ticks, soft ticks, scabies mites, migratory mites, flies. { suckers and mincers), fly parasitic larvae, lice, hair nits, feathered nits and fleas. To these parasites belong: From the order of the Anoplurida, for example Haematopinus spp. , Linognathus spp. , Pediculus spp. , Phtirus spp. , Solenopotes spp ..

On the order of . the Mallophagidae "and of the suborders Amblycerina as well as Ischnocerina, for example Tri-menopon spp., Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepik ntron spp., Da alina spp., Trichodectes spp., Felicola spp. From the order of the Diptera and the suborders Nematocerina as well as Branchycerina, for example Aedes spp., Anopheles spp., Oulex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp., Atylotus spp., Tabanus spp.,? Aematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp. Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp. Glossina spp., Oalliphora spp., Lucilia spp., Chrysomya spp. Ohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., • Melophagus spp. ' From the order of Siphonapterida, for example Pulex spp., Gtenocephalides spp., Xenopsylla spp., Oeratophyllus spp. From the order of Heteropteridae, for example Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp. order of the Blattarida, for example Blatta orientalis, Periplaneta americana, Blattella germanica, Supella spp .. From the subclass of the Acaria. {Acarida) and the "order of the eta- as well as those stigmatites, for example Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp., Haemaphysalis spp., Hyalomma spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., Pneumonyssus spp., Sternostoma spp. ., Varroa spp. From the order of Actinedida (Prostigmata) and acarididae (Astigmata), for example Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp., -Psorergates spp., Demodex spp., Trombicula spp. , Listrophorus spp., Acarus spp., Tyrophagus spp. , Caloglyphus spp. , Hypodectes spp. , Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp. The combinations of active compounds according to the invention are also suitable for the fight against arthropods, which attack useful animals in agriculture such as, for example, cows, lambs, goats, horses, pigs, donkeys, camels, buffalo, rabbits, chickens, turkeys, ducks, geese, bees , other domestic animals such as, for example, dogs, cats, game birds, aquarium fish as well as so-called test animals, such as, for example, hamsters, guinea pigs, rabbits and mice. Through the fight against these arthropods will avoid cases of death and reductions in productivity (in milk, meat, wool, skins, eggs, honey, etc.), so that, by using the products active in accordance with the invention, it is possible a more economical and simpler maintenance of the animals. The application of the combinations of active products, according to the invention, is carried out in the veterinary sector in a known manner by enteral administration in the form of, for example, tablets, capsules, beverages, dragees, granules, pastes, bolis, by means of the procedure through the feed-through feed, of suppositories, by parenteral administration, such as, for example, by injection (intramuscular, subcutaneous, intravenous, intraperitoneal and the like), implants, by nasal application, by application through the skin in the form of, for example, immersion or bathing (Dippen), spray (Spray), surface watering (Pour-on and Spot-on), washing, dusting as well as using bodies molds containing the active product such as collars, ear tags, tail tags, limb bands, halters, marking devices, etc. When used for domestic livestock, poultry, pets, etc. the active ingredients can be used as formulations (for example powders, emulsions, agents capable of spreading), containing the active compounds in amounts of 1 to 80% by weight, directly or after dilution of 100 to 10,000 times or can be used in a manner of chemical bath. Furthermore, it has been found that the combinations of the active compounds according to the invention show a high insecticidal effect against insects, which destroy industrial materials. By way of example and preference - however without limitation - the following insects may be mentioned: Beetles, such as Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis; Xyleborus spec., Tryptodendron spec. , Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec., Dinoderus minutus. Hymenoptera, such as "Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur, Termites, such as Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicala, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastoter is to give iniensis, Zootermopsis nevadensis, Coptotermes formosanus. Thysanides, such as Lepisma saccharina. Industrial materials will be understood in the present context - non-living materials, such as, preferably, synthetic materials, glues, glues, paper and cardboard, leather, wood and wood products and paints. In a very special way, the materials to be protected against the attack of insects are made of wood and wood products. By wood and wood processing products, which can be protected by means of the agents according to the invention or of the mixtures containing them, it should be understood, for example: construction wood, wooden beams, railway sleepers , parts for bridges, ribs for boats, wooden vehicles, boxes, pallets, containers, telephone poles, wooden coverings, wooden windows and doors, wooden plywood, plywood boards, carpentry works or wood products, they find application, in a very general way, in the home or in the construction industry; The active compound combinations can be used as such, in the form of concentrates or of usual formulations in general such as powders, granules, solutions, suspensions, emulsions or pastes. Said formulations can be prepared in a manner known per se, for example by mixing the active ingredients with at least one solvent or diluent, emulsifier, dispersant and / or binder or binding agent, water repellent, optionally drying agents and UV stabilizers and, if appropriate, colorants and pigments and other processing aids. The insecticidal agents or concentrates to be used for the protection of wood and wood materials contain the active compound according to the invention in a concentration of 0.0001 to 95% by weight, in particular 0.001 to 60% by weight. weight. The quantity of the agents or concentrates used depends on the type and origin of the insects and the environment. The optimum application amount can be determined respectively by means of series of tests prior to application. In general, however, it is sufficient to employ from 0.0001 to 20% by weight, preferably from 0.001 to 10% by weight of the active product, based on the material to be protected. A solvent or a mixture of organochemical solvents and / or a solvent or mixture of organo-chemical, oleaginous or oil-like solvents, which are difficult to volate and / or a solvent or mixture of polar organochemical solvents, is used as solvent and / or diluent. and / or water and, if appropriate, an emulsifier and / or humectant. Oomo organo-chemical solvents - preferably used as oleaginous or oil-based solvents, with an evaporation index above 35 and a flame point above 30 ° C, preferably above 45 ° C. By way of such water-insoluble, oil-soluble or oleaginous-type solvents which are difficult to volatile, corresponding mineral oils or their aromatic fractions or mixtures of solvents containing mineral oils, preferably benzine for tests, petroleum and / or alkylbenzene, will be used. Advantageously, mineral oils with a boiling range of 170 to 22 ° C, benzine for tests with a boiling range of 170 to 220 ° C, spindle oil with a boiling range of 250 to 350 ° C, petroleum or either aromatic hydrocarbons with a boiling range of 160 to 280 ° C, terpene oil and the like. In a preferred embodiment, liquid aliphatic hydrocarbons having a boiling range of 180 to 210 ° C or a high boiling point mixture of aromatic and aliphatic hydrocarbons having a boiling range of 180 to 22 ° C and / or spindles and / or monochloronaphthalene, preferably a-monochloronaphthalene. Organic solvents, which are difficult to volatile, oleaginous or oleaginous, with an evaporation index above 35 and with a flame point located at above 30 ° C, preferably above 45 ° C, can be partially replaced by light or medium volatility organochemical solvents, provided that the solvent mixture has an evaporation index above 35 and a point of flame located above 30 ° C, preferably above 45 ° C, and that the insecticidal-fungicidal mixture is soluble or emulsifiable in this mixture of solvents. According to a preferred embodiment, a part of the solvent or mixture of organochemical solvents or a solvent or mixture of aliphatic, polar organochemical solvents will be replaced. Preference is given to using aliphatic organochemical solvents containing hydroxyl and / or ester and / or ether groups, such as, for example, glycol ether, steres or the like. As organic-chemical binders, synthetic resins and / or setting drying oils, known per se, dilutable with water and / or soluble or dispersible or emulsifiable in the organic-chemical solvents used, will be used within the scope of the present invention. especially binders consisting of or containing acrylic resin, a vinyl resin, for example polyvinyl acetate, polyester resin, oli-condensation or polyaddition resin, polyurethane resin, alkyd resin or modified alkyd resin, phenolic resin, resin hydrocarbon such indeno-coumaron resin, silicone resin, vegetable drying and / or drying oils and / or physical drying binders based on a natural and / or synthetic resin. Synthetic resin, used as a binder, can be used in the form of an emulsion, dispersion or solution. Bitumen or bituminous substances can also be used as binders up to 10% by weight. In addition, dyes, pigments, water-repelling agents, odor correctors and inhibitors or anticorrosive agents known per se and the like can be used. It is a matter of preference to use, as an organochemical binder, at least one alkyd resin or a modified alkyd resin and / or a drying vegetable oil in the medium or in the concentrate according to the invention. Preferably, alkyd resins having an oil content greater than 45% by weight, preferably from 50 to 68% by weight, are preferably used according to the invention. The aforementioned binder can be partially or completely replaced by a fixing agent (mixture) or by a plasmidifier (mixture). These additives should avoid volatilization of active products as well as crystallization or precipitation. Preferably they replace 0.01 to 30% of the binder (referred to the 1-00% of the binder used). The plasticizers are from the chemical cysase, from the esters • of phthalic acid such as dibutyl, dioctyl or benzylbutyl phthalate, esters of phosphoric acid, such as tributyl phosphate, esters of adipic acid, such as di- (2-ethylhexyl) adipate, stearates such as butyl stearate or amyl stearate, oleates such as butyl oleate, glycerin ethers or high molecular weight glycol ethers, glycerin esters as well as esters of p-toluenesulfonic acid. The fixing agents are chemically based on polyvinylalkyl ethers such as polyvinyl methyl ether or ketones such as benzophenone, ethylenebenzophenone. Suitable as solvent or diluent is water, optionally in admixture with one or more of the aforementioned solvents or diluents, emulsifiers and organochemical dispersants. "Especially effective protection of the wood is achieved by impregnation processes on an industrial scale, for example, vacuum, double vacuum or pressure processes, while combinations of the active products according to the invention can be used. for the protection against the proliferation of organisms on objects, especially on the bodies of uques, taices, networks, constructions, port installations and signaling installations, which come into contact with seawater or brackish water. The proliferation of organisms due to sessile Oligochaeten, such as calcareous tubicides as well as due to the bivalves and species of the lepadomorphs group (sea acorns), such as various types of Lepas and Scalpellum or due to types of the group of the balanomorphs. { barnacles), such as Balanus species, or Polii-cipes, increase the resistance to friction of the boats and lead, as a consequence of a greater consumption of energy and also due to the frequent stays in dry dock, to a clear increase of the Operating costs. In addition to the proliferation of organisms due to algae, for example Ectocarpus sp. and Ceramium sp., has a special significance in particular the proliferation of organisms due to sessile groups of entomostráceos, which are grouped under the name of Cirripedia (crustáceos cirrípedos).

It has now been found, surprisingly, that the combinations of the active compounds according to the invention have an excellent anti-fouling effect (antiproliferation of organisms). - By using the combinations of the active compounds according to the invention, the use of heavy metals, for example, in the sulfides of bis- (trialkyltin), tri-n-butyltin laurate, tri-n chloride, can be abandoned. -butyltin, cuprous oxide (I), triethyltin chloride, tri-n-butyl- (2-phenyl-4-chlorophenoxy) -tin, tributyltin oxide, molybdenum disulfide, antimony oxide, polymer butyl lithium, phenyl- (bispyridine) -bismuth chloride, tri-fluoride -n-butyltin, manganese ethylenebistiocarbamate, zinc dimethyldithiocarbamate, zinc ethylenebistiocarbamate, zinc and copper salts of 2-pyridinium-1-oxide, bisdimethyldithiocarbamoylcycline ethylenbistiocarbamate, zinc oxide, cuprous ethylene-bisdithiocarbamate (I), thiocyanate copper, copper naphthenate and tributyltin halides or the concentration of these compounds can be decisively reduced. Furthermore, antifouling paints ready for application contain, if necessary, other active ingredients, preferably algicides, fungicides, herbicides, molluscicides or other antifouling active agents. - As components of the combination for the anti-fouling agents, according to the invention, preferably, are suitable such as 2- tere. -butylamino-4-cyclopropylamino-6-methylthio-l, 3,5-triazine, Dichlorophen, Diuron, Endothal, Fentinacetat, Isoproturon, Methabenzthiazuron, Oxyfluorfen, Quinoclamine and Terbutryn; fungicides such as _3, S-cyclohexylamide dioxide of benzo [b] -thiophenecarboxylic acid, Dichlofluanid, Fluorfolpet, 3-iodo-2-propynyl-butylcarbamate, Tolylfluanid and azoles such as Azaconazole, Cyproconazole, Epoxyconazole, Hexaconazole, Metconazole, Propiconazole and Tebuconazole; molluscicides such as Fentinacetat, Metaldehyd, Methiocarb, Niclosamid, Thiodicarb and Tri-methacarb; or traditional anti-fouling agents such as 4,5-dichloro-2-octyl-4-isothiazolin-3-one, diiodomethyl paratrysulfone, 2- (N, N-dimethylthiocarbamoylthio) -5-nitrothiazyl, potassium, copper, sodium salts and of zinc of 2-pyridinium-l-oxide, pyridine-triphenylborane, tetrabutyldistannoxane, 2,3,5,6-tetrachloro-4- (methylsulfonyl) -pyridine, 2,4,5,6-tetrachloroisophthalonitrile, tetramethylthiuram disulfide and , 4,6-trichlorophenylmaleinimide. The anti-fouling agents used contain the active compound combinations according to the invention in a concentration of 0.001 to 50% by weight, in particular 0.01 to 20% by weight. The anti-fouling agents according to the invention also contain, in addition, frequent components, but not limited thereto, such as for example those described in Ungerer, Chem. Ind. 1985, 37, 730-732 and Williams, Antifouling Marine Coatings, Noyes, Park Ridge, 1973.

The antifouling paints contain, in addition to the active ingredients, algaecides, fungicides, molluscicides and insecticides according to the invention, especially binders. Examples of recognized binders are polyvinyl chloride in a solvent system, chlorinated rubber in a solvent system, acrylic resins in a solvent system especially in an aqueous system, vinyl chloride / vinyl acetate copolymer systems in the form of aqueous dispersions or form of systems in organic solvents, butadiene / styrene / acrylonitrile rubbers, desiccant oils such as linseed oil, resin esters or modified resin esters in combination with tars or bitumens, asphalt as well as epoxy compounds, small amounts of chlorinated rubber, chlorinated polypropylene and resins vinyl. If appropriate, the paints also contain inorganic pigments, organic pigments or dyes, which are preferably insoluble in seawater. In addition, the paints may contain materials such as colophonium to enable a controlled release of the active products. The paints may also contain plasticizers, modifying agents that influence the rheological properties as well as other traditional components. Also in self-polishing an iinc systems it can The compounds according to the invention or the aforementioned mixtures are incorporated. The combinations of active products, according to the invention, are suitable for combating animal pests, especially insects, arachnids and mites, which occur in closed enclosures, such as, for example, houses, manufacturing facilities, offices, cabins of motor vehicles and the like. . These can be used to combat these pests in insecticide products for the home. These are active against sensitive and resistant types as well as against all stages of development. To these pests belong: From the order of the Scorpionidea, for example, Buthus occitanus. From the order of the Acariña, for example, Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, lyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae. From the order of the Araneae, for example Aviculariidae, Araneidae. From the order of the Opiliones, for example Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium. From the order of the Psopoda, for example, Oniscus asellus, Porcellio scaber.

From the order of the Diplopoda, for example, Blaniulus guttulatus, Polydesmus spp .. From the order of the Chilopoda, for example, Geophilus spp ..

From the order of the Zygentoma, for example, Ctenolepisma spp., Lepisma sacharina, Lepismodes inquilinus. From the order of the Blattaria, for example - Blatta orientalies, Blatella ermánica, Blatella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa. Of the order - of the Saltatoria, for example, Acheta domesticus. From the order of the Dermaptera, for example, Forfícula auricularia. From the order of the Isoptera, for example, Kalotermes spp., Reticulitermes spp. From the order of the Psocoptera, for example, Lepinatus spp., Liposcelis spp. - From the order of the Coleptera, for example, Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha Dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum. From the order of the Diptera, for example, Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp. , Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp. , Fannia canicularis, Musca domestica, Phlebotomus spp, Sarcophaga carnaria, Simulium spp. , Sto oxys calcitrans, Typula paludosa. From the order of the Lepidoptera, for example, Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella. From the order of the Siphonaptera, for example, Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis. From the order of the Hymenoptera, for example, Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp. , Tetramorium caespitum. From the order of the Anoplura, for example Pediculus humanus capitis, Pediculus humanus corporis, Phthirus pubis. From the order of the Heteroptera, for example, Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans. The application is carried out in aerosols, non-pressurized spraying agents, for example aerosols by pumping and spraying, automatic devices for the generation of aerosols, nebulizers, foam generators, gels, products for evaporators with platelets for the evaporators of cellulose or synthetic material, liquid evaporators, gel and membrane evaporators, fan-driven evaporators, evaporative systems without energy consumption or passive, paper against moths, sachets against moths and gels against moths, in the form of granules or powder, in dispersible baits or in bait stations. All plants and parts of plants can be treated according to the invention. By plants, all plants and plant populations, such as desired and unwanted wild plants (including crop plants of natural origin), will be understood in this case. The crop plants can be plants that can be obtained by conventional methods and cultivation and optimization or by means of biotechnological and genetic engineering methods, including transgenic plants and including plant varieties that can be protected or not through the right of protection of plant varieties. By parts of the plants should be understood all the parts and aerial and underground organs of plants, such as buds, leaves, flowers and roots, being able to indicate in an exemplary way leaves, needles, stems, trunks, flowers, bodies -of fruits, - fruits and seeds as well as roots, tubers and rhizomes. The harvests as well as vegetative and generative reproductive material, for example seedlings, tubers, rhizomes, layering and seeds, also belong to the parts of the plants. The treatment, according to the invention, of plants and -of the -parts of the plants with the products active, is carried out directly or by action on its surroundings, on its environment or in the storage enclosures, in accordance with the usual treatment methods, for example by immersion, spraying, evaporation, nebulization, spreading, application to brush and, in the case of reproduction material, especially in the case of seeds, also by coating with one or several layers. As already indicated above, all plants and their parts can be treated according to the invention. In a preferred embodiment, plants and plant varieties as well as parts thereof of wild origin or that are obtained by conventional methods of biological cultivation, such as crossing or fusion of protoplasts, are treated. In another preferred embodiment, plants and varieties of transgenic plants are treated, which have been obtained according to genetic engineering methods, if appropriate in combination with conventional methods (genetically modified organisms) and their parts. The expression "parts" or "parts of plants" or "components of plants" has been previously explained. In accordance with the invention, plants of the plant varieties customary in the trade or in use will be treated with particular preference. In accordance with the types of plants or "well Plant varieties, their location and growth conditions (soil, climate, vegetation period, food) can also be presented by means of the treatment according to the invention additive effects ("synergists"). In this way, for example, smaller amounts of application and / or enlargements of the activity spectrum and / or a strengthening of the effect of the products employable according to the invention are possible, better growth of the plants, greater tolerance to high temperatures or low, greater tolerance against drought or against the salt content of water or soil, greater floral yield, easier harvesting, acceleration of maturation, higher yields of crops, higher quality and / or higher nutritive value of collected products, greater storage capacity and / or transformation of the products collected, which go beyond the expected effect itself. The plants or varieties of transgenic plants (obtained by genetic engineering) to be treated preferably according to the invention belong to all the plants, which have acquired genetic material through modification by genetic engineering, which provide these plants with particularly advantageous valuable properties. ("characteristics") . Examples of such properties are, better growth of plants, greater tolerance to high or low temperatures, greater tolerance to drought or against the salt content of water or soil, greater floral yield, easier harvesting, acceleration of ripening, higher yields of crops, higher quality and / or greater nutritional value of the products harvested, greater storage capacity and / or transformation of the harvested products. Other examples, especially noteworthy for such properties, are the greater resistance of plants to animal and microbial pests, such as against insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as greater tolerance of plants against certain active herbicide products. As examples of transgenic plants will be cited important crop plants, such as cereals (wheat, rice), corn, soybeans, potatoes, cotton, tobacco, rapeseed as well as fruit tree plantations (with the fruits apple, pear, citrus and grape ), especially corn, soybeans, potatoes, cotton, tobacco and - colza. As properties ("characteristics"), the greater resistance of plants to insects will be pointed out by means of the toxins generated in plants, especially those generated in plants by the genetic material from Bacillus Thuringiensis. { for example by means of the genes Cry? A (a), ry? A (b), Ory? A (c), OrylIA, OrylIIA, CryIIIB2, Ory9c, Cry2Ab, Cry3Bb and CrylF as well as their combinations), (referred to below as "Bt plants"). As properties ("characteristics"), the greater tolerance will be especially pointed out. of plants against fungi, bacteria and viruses by systemically acquired resistance (SAR), systemin, phytoalexin, elicitors as well as resistance genes and proteins and toxins expressed accordingly. As properties ("characteristics"), in particular, the greater tolerance of the plants to certain herbicidal active substances, for example imidazolinones, sulfonylureas, glyphosate or Phosphinotricin (for example "PAT" gene). The respective genes, which provide the desired properties ("characteristics") can also be presented in combination with each other in transgenic plants. Examples of "Bt plants" include maize varieties, cotton varieties, soya varieties and potato varieties, which are marketed under the trade names YIELD G-ARD® (eg corn, cotton, soybean), KnockOut® ( for example corn), StarLink® (for example corn), Bollgard® (cotton), Nucot-n® (cotton) and NewLeaf® (potato). Examples of plants that tolerate herbicides include corn varieties, cotton varieties and soybean varieties, which are marketed under the trade names Roundup Ready® (tolerance to Olyphosate, for example corn, cotton, soybean), Liberty Link® (tolerance to Phosphinotricin, for example rapeseed), IMI < ® (tolerance to imidazolinones) and STS® (tolerance to sulfonylureas, for example corn). As herbicide-resistant plants (conventionally cultivated with tolerance to herbicides), the varieties marketed under the name Clearfield® (for example corn) can also be cited. Evidently these indications are valid also for the varieties of plants that are developed in the future or that are commercialized in the future with these properties ("characteristics") genetic or that are developed in the future. The plants indicated can be treated in a particularly advantageous manner, according to the invention, with the active ingredient mixtures according to the invention. The preferred ranges, indicated above, for the mixtures, are also valid for the treatment of these plants. It should be noted especially the • treatment of the plants with the mixtures specially cited in this text. The good insecticidal and acaricidal effect of the combinations of the active compounds according to the invention is apparent from the following examples. -While the products-individual assets present points weak in their effect, the combinations show an effect that goes beyond the simple addition of the effects of the active products. There is a synergistic effect in the case of insecticides and acaricides provided that the effect of the combination of the active products is greater than the sum of the effects of the active products applied individually. The expected effect for a given combination of two active products can be calculated in accordance with S.R. Colby, Weeds, 15, (1967), 20-22) as follows: if X represents the degree of destruction, expressed in% of the untreated controls, when the active product A is used in an amount of mg application / ha or at a concentration of mg / ha, Y represents the degree of destruction, expressed in% of the untreated controls, when the active product B is used in an application amount of ng / ha or at a concentration of ng / ha, and E represents the degree of destruction, expressed in% of the untreated controls, when the active products A and B are used in amounts of application of m or n / ha or at a concentration of m and n / ha, then X-Y E = X + Y 100 If the actual effect is greater than the calculated one, then the -combination is superadditive in terms of its destructive effect, that is, a synergistic effect is present. In this case, the actual degree of destruction, observed, must be greater than the value calculated from the formula previously indicated for the expected degree of destruction (E). After the desired time the destruction is determined in%. In this case 100% means that all the animals have been destroyed; 0% means that no animal has been destroyed. Application examples Example A Test with yzus persicae Solvent: 7 parts by weight of dimethylformamide. Emulsifier: 2 parts by weight of alkylaryl polyglycol ether. To obtain a suitable preparation of active compound, 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier and the concentrate is diluted with water, containing emulsifier, to the desired concentration. Cabbage leaves (Bra-ssica .olera-cea) are treated, which are strongly attacked by the uraznero aphid (Myzus persica-e), by immersion in the preparation of the product. active of the desired concentration. After the desired time the destruction is determined in percentage. In this case 100% means that all the aphids were destroyed; 0% means that no aphids were destroyed. Destruction values determined are calculated according to the Colby formula (see page 41 of the German text). In this test they show a synergistically reinforced activity, compared to active products, used individually, for example, the following active product combinations, according to the present invention: Table A Harmful Insects for Plants Test with Yzus Persicae * gef = effect found ** ber. = effect calculated in accordance with Colby's formula It is noted that, with reference to this date, the best method known to the applicant to carry out the said invention, is the one that clearly emerges from the present diption of the invention.

Claims (5)

CLAIMS Having described the invention as above it is claimed as -property what is contained in the following claims: 1.- Agents- characterized in that they contain a combination of active products, with synergistic activity, constituted by anthranilic acid amides of the formula (I) wherein A1 and A2 signify, independently of each other, oxygen or sulfur, X1 signifies N or -CR10, R1 signifies hydrogen or means alkyl having 1 to 6 carbon atoms, alkenyl having 2 to 6 carbon atoms, alkynyl having 2 to 6 carbon atoms or cycloalkyl with 3 to 6 carbon atoms substituted respectively, if appropriate, once or several times, the substituents, independently of each other, between R6, halogen, cyano, nitro, hydroxy, alkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 atoms of carbon, alkoxycarbonyl with 2 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, dialkylamino with 2 to 8 carbon atoms, cycloalkylamino with 3 to 6 carbon atoms,. { alkyl with 1 to 4 carbon atoms) cycloalkylamino with 3 to 6 carbon atoms or R 11, R 2 signifies hydrogen, alkyl with 1 to 6 carbon atoms, alkenyl with 2 to 6 carbon atoms, alkynyl with 2 to 6 carbon atoms , cycloalkyl with 3 to 6 carbon atoms, alkoxy with 1 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, dialkylamino with 2 to 8 carbon atoms, cycloalkylamino with 3 to 6 carbon atoms, alkoxycarbonyl with 2 to 6 carbon atoms or alkylcarbonyl with 2 to 6 carbon atoms, R3 means hydrogen, R11 or means alkyl with 1 to 6 carbon atoms, alkenyl with 2 to 6 carbon atoms, alkynyl with 2 to 6 carbon atoms, cycloalkyl with 3 to 6 carbon atoms respectively substituted, if appropriate, once or several times, the substituents being independently selected from R6, halogen, cyano, nitro, hydroxy, alkoxy with 1 to 4 carbon atoms, halogenalkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, alkylsulfinyl with 1 at 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, alkoxycarbonyl with 2 to 6 carbon atoms, alkylcarbonyl with 2 to 6 carbon atoms, trialkylsilyl with 3 to 6 carbon atoms, R11, phenyl, phenoxy or a ring heteroaromatic with 5 or 6 members, it being possible to replace each phenyl, phenoxy or heteroaromatic ring with 5 or 6 members and the substituents being independently chosen from one to three residues W or one or more residues R12, or R2 and R3 can be linked together and form the ring M, R4 means hydrogen, alkyl having 1 to 6 carbon atoms, alkenyl having 2 to 6 carbon atoms, alkynyl having 2 to 6 carbon atoms, cycloalkyl having 3 to 6 át carbon atoms, halogenalkyl with 1 to 6 carbon atoms, halogenalkenyl with 2 to 6 carbon atoms, halogenalkynyl with 2 to 6 carbon atoms, halogencycloalkyl with 3 to 6 carbon atoms, halogen, cyano, nitro, hydroxy, alkoxy with 1 to 4 atoms carbon, haloalkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms; alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, halogenalkylthio with 1 to 4 carbon atoms, haloalkylsulfinyl with 1 to 4 carbon atoms, halogenalkylsulfonyl with 1 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, dialkylamino with 2 to 8 carbon atoms, cycloalkylamino with 3 to 6 carbon atoms, trialkylsilyl with 3 to 6 carbon atoms or means phenyl, benzyl or phenoxy substituted respectively, if appropriate, once or several times , it being possible to choose the substituents, independently of each other, between alkyl with 1 to 4 carbon atoms, alkenyl with 2 to 4 carbon atoms, alkynyl with 2 to 4 carbon atoms, cycloalkyl with 3 to 6 carbon atoms, haloalkyl with 1 at 4 carbon atoms, halogenalkenyl with 2 to 4 carbon atoms, halogenalkynyl with 2 to 4 carbon atoms, halogencycloalkyl with 3 to 6 carbon atoms, halogen, cyano, nitro, alkoxy with 1 to 4 carbon atoms, halogenalkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, alkylamino with 1 to 4 atoms from carbon, dialkylamino with 2 to 8 carbon atoms, cycloalkylamino with 3 to 6 carbon atoms, (alkyl) cycloalkylamino with 3 to 6 carbon atoms, alkylcarbonyl with 2 to 4 carbon atoms, alkoxycarbonyl with 2 to 6 carbon atoms, alkylaminocarbonyl with 2 to 6 carbon atoms, dialkylaminocarbonyl with 3 to 8 carbon atoms or trialkylsilyl with 3 to 6 carbon atoms R8 respectively stand for, independently of one another, hydrogen, halogen or mean alkyl with 1 to 4 carbon atoms, halogenalkyl with 1 to 4 carbon atoms, R12, G, J, -OJ, -0G, - S (0) pJ, -S (0) pG, -S (0) p-phenyl substituted respectively, where appropriate, the substituents being independently selected from one to three residues W or from R12, alkyl with 1 to 10 carbon atoms, alkenyl with 2 to 6 carbon atoms, alkynyl with 2 to 6 carbon atoms, alkoxy with 1 to 4 carbon atoms or alkylthio with 1 to 4 carbon atoms, each substituent may be substituted, independently from Yes, by one or more substituents chosen s between G, J, R €, halogen, cyano, nitro, amino, hydroxy, alkoxy with 1 to 4 carbon atoms, halogenalkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, alkylsulfinyl with 1 a 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, halogenalkylthio with 1 to 4 carbon atoms, halogenalkylsulfinyl with 1 to 4 carbon atoms, halogenalkylsulfonyl with 1 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, dialkylamino with 2 to 8 carbon atoms, trialkylsilyl with 3 to 6 carbon atoms, phenyl or phenoxy, where appropriate each phenyl or phenoxy ring may be substituted and the substituents may be chosen, independently from each other, from one to three residues W or one or more residues R12, respectively, independently of each other, a carbocyclic or heterocyclic ring, non-aromatic, with 5 or 6 members, containing, if appropriate, one or two members in the ring chosen from the group C (= 0), SO or S ( = 0) 2, and which may be substituted, if appropriate, by one to four chosen substituents, independently of one another, between alkyl having 1 to 2 carbon atoms, halogen, cyano, nitro or alkoxy with 1 to 2 carbon atoms , or meaning independently, alkenyl with 2 to 6 carbon atoms, alkynyl with 2 to 6 carbon atoms, cycloalkyl with 3 to 7 carbon atoms, (cyano) cycloalkyl with 3 to 7 carbon atoms,. { alkyl with 1 to 4 carbon atoms) cycloalkyl with 3 to 6 carbon atoms, (cycloalkyl with 3 to 6 carbon atoms) alkyl with 1 With 4 carbon atoms, each cycloalkyl, (alkyl) cycloalkyl and (cycloalkyl) -alkyl, optionally substituted by one or more halogen atoms, J may each stand independently, a heteroaromatic ring with 5 or 6 members, optionally substituted, it being possible to choose the substituents, independently of each other, between one to three residues W or one or more residues R12, R6 mean, independently of each other, -C (= E1) R19, LC (= E1) R19 , -C (= E1) LR19, -LC (= E1) LR19, -0P (= Q) (OR19) 2, -S02LR18 or - LS02LR19, meaning each E1, independently of each other, O, S, N-R1S, N-OR15, NN (R15) 2, NS = 0, N-CN or N-N02, R7 means hydrogen, alkyl with 1 to 4 carbon atoms, halogenalkyl with 1 to 4 carbon atoms, halogen, alkoxy with 1 to - 4 carbon atoms, halogenalkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms carbon, halogenalkylthio with 1 to 4 carbon atoms, haloalkylsulfinyl with 1 to 4 carbon atoms, haloalkisulphonyl with 1 to 4 carbon atoms, R9 means haloalkyl with 1 to 4 carbon atoms, halogenalkoxy with 1 to 4 carbon atoms, halogenoalkylsulfinyl with 1 to 4 carbon atoms or halogen, R10 means hydrogen, alkyl with 1 to 4 carbon atoms, halogenalkyl with 1 to 4 carbon atoms, halogen, cyano or halogenalkoxy with 1 to 4 carbon atoms, R11 mean respectively independently, alkylthio having 1 to 6 carbon atoms, alkylsulfenyl with 1 to 6 carbon atoms, halogenalkylthio with 1 to 6 carbon atoms, halogenoalkylsulfenyl with 1 to 6 carbon atoms, phenylthio or phenylsulfenyl respectively substituted, if appropriate, from one to three times, the substituents being independently selectable from the list formed by W, -S (0) nN (R16) 2, -C (= 0) R13, -L (C = 0) R14, -S (C = 0) LR14, -C (= 0) LR13, S (0) nNR13O (= 0) R13, -S. { .0) nNR13C (= 0) LR14 or -S. { 0) nNR13S (0) 2LR14, L mean respectively, independently of each other, O, NR18 or S, R12 respectively mean, independently of each other, -B (0R17) 2, amlno, ~ SH, thiocyanate, trialkylsilyloxy with 3 to 8 atoms of carbon, alkyl disulfide with 1 to 4 carbon atoms, -SF5, -C (= E) R19, -LC (= E) R19, C { = E) LR19, -LC (= E) LR19, -OP (= Q) (0R19) 2, -S02LR19 or -LS02LR19, Q means O or S, R13 respectively mean, i depending on each other, hydrogen or mean alkyl with 1 to 6 atoms carbon, alkenyl with 2 to 6 carbon atoms, alkynyl with 2 to 6 carbon atoms or cycloalkyl with 3 to 6 carbon atoms substituted, respectively, one or more times, the substitutes being able to be chosen, independently of each other, between R 6, halogen, cyano, nitro, hydroxy, alkoxy with 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, dialkylamino with 2 with 8 carbon atoms, cycloalkylamino with 3 to 6 carbon atoms or (C 1 -C 4 alkyl) cycloalkylamino with 3 to 6 carbon atoms, R 14 signifies independently, independently of each other, alkyl having 1 to 20 carbon atoms , alkenyl with 2 to 20 carbon atoms, alkynyl co n 2 to 20 carbon atoms or cycloalkyl with 3 to 6 carbon atoms substituted, if appropriate, one or more times, the substituents being independently selected from R6, halogen, cyano, nitro, hydroxy, alkoxy, 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, dialkylamino with 2 to 8 carbon atoms, cycloalkylamino with 3 to 6 carbon atoms or (alkyl with 1 to 4 carbon atoms) cycloalkylamino with 3 a 6 carbon atoms or optionally substituted phenyl, it being possible to choose the substituents, independently of each other, between one to three residues W or one or more radicals R 12, respectively mean, independently of one another, hydrogen or mean haloalkyl with 1 to 6 atoms of carbon or alkyl with 1 to 6 carbon atoms substituted, if appropriate, one or more times, the substituents being independently selected from cyano, nitro, hydroxy, alkoxy with 1 to 4 carbon atoms, haloalkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, haloalkylthio with 1 to 4 carbon atoms, halogenoalkylsulfinyl with 1 to 4 carbon atoms, halogenoalkylsulfonyl with 1 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, dialkylamino with 2 to 8 carbon atoms, alkoxycarbonyl with 2 to 6 carbon atoms , alkylcarbonyl with 2 to 6 carbon atoms, trialkylsilyl with 3 to 6 carbon atoms or phenyl, optionally substituted, it being possible to choose the substituents, independently of each other, between one to three residues W or one or more residues R12, or N (R15) 2 means a cycle, which forms the ring M, R? e means alkyl with 1 to 12 carbon atoms or halogenalkyl with 1 to 12 carbon atoms, or N (R16) 2, means a ring, which forms the ring M, R17 respectively mean, independently of each other, hydrogen or alkyl with 1 to 4 atoms carbon, or B { OR1) 2 means a ring, in which both oxygen atoms are linked through a chain with two to three carbon atoms, which may be substituted, if appropriate, by one or two chosen substituents, independently of each other, between methyl or alkoxycarbonyl having 2 to 6 carbon atoms, R18 respectively meaning independently, hydrogen, alkyl having 1 to 6 carbon atoms or halogenalkyl having 1 to 6 carbon atoms, or N (R13) (R18) means a cycle , which forms the ring M, R19 respectively mean, independently of each other, hydrogen or mean alkyl C-on 1 to 6 carbon atoms substituted -respectively, if appropriate, once or several times, the substituents being independently selectable from each other, between cyano, -nitro, hydroxy, alkoxy with 1 to 4 carbon atoms, halogenalkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, halogenalkylthio with 1 to 4 carbon atoms, halogenalkylsulfinyl with 1 to 4 carbon atoms, halogenalkylsulfonyl with 1 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, dialkylamino with 2 to 8 carbon atoms, C02H, alkoxycarbonyl with 2 to 6 carbon atoms, alkylcarbonyl with 2 to 6 carbon atoms, trialkylsilyl with 3 to 6 carbon atoms or phenyl, optionally substituted, the substituents can be chosen, independently from each other, from one to three radicals W, halogenalkyl with 1 to 6 carbon atoms, cycloalkyl with 3 to 6 carbon atoms or phenyl or pyridyl respectively substituted, if appropriate, one to three times per W , meaning a ring respectively substituted, if appropriate, from one to four times, containing, in addition to the nitrogen atom, to which the pair of substituents R13 and R18, (R15) 2 or (R1) is linked. 6) 2, from two to six carbon atoms and, if necessary, in addition, another nitrogen, sulfur or oxygen atom and substituents can be chosen, independently of each other, from alkyl with 1 to 2 carbon atoms, halogen , cyano, nitro or alkoxy with 1 to 2 carbon atoms, W mean respectively, independently of each other, alkyl with 1 to 4 carbon atoms, alkenyl with 2 to 4 carbon atoms, alkynyl with 2 to 4 carbon atoms, cycloalkyl with 3 to 6 carbon atoms, haloalkyl with 1 to 4 atoms carbon, halogenalkenyl with 2 to 4 carbon atoms, halogenalkynyl with 2 to 4 carbon atoms, halogencycloalkyl with 3 to 6 carbon atoms, halogen, cyano, nitro, alkoxy with 1 to 4 carbon atoms, halogenalkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, alkylamino with 1 to 4 carbon atoms, dialkylamino with 2 to 8 carbon atoms, cycloalkylamino with 3 to 6 carbon atoms, (alkyl with 1 to 4 carbon atoms) cycloalkylamino with 3 to 6 carbon atoms, alkylcarbonyl with 2 to 4 carbon atoms, alkoxycarbonyl with 2 to 6 carbon atoms, C02H, alkylaminocarbonyl n 2 to 6 carbon atoms, dialkylaminocarbonyl with 3 to 8 carbon atoms or trialkylsilyl with 3 to 6 carbon atoms, n mean respectively, independently of each other, 0 or 1, p mean respectively, independently of each other, 0, 1 or 2, being present, in the case where (a) R5 means hydrogen, alkyl having 1 to 6 carbon atoms, halogenalkyl with 1 to 6 carbon atoms, halogenoalkenyl with 2 to 6 carbon atoms, halogenoalkynyl with 2 to 6 carbon atoms , halogenalkoxy with 1 to 4 carbon atoms, halogenalkylthio with 1 to 4 carbon atoms or halogen and (b) R8 means hydrogen, alkyl with 1 to 6 carbon atoms, halogenalkyl with 1 to 6 carbon atoms, halogenalkenyl with 2 a 6 carbon atoms, haloaquinyl are 2 to 6 carbon atoms, halogenalkoxy with 1 to 4 carbon atoms, halogenalkylthio with 1 to 4 carbon atoms, halogen, alkylcarbonyl with 2 to 4 carbon atoms, alkoxycarbonyl with 2 to 6 carbon atoms. carbon, alkylaminocarbonyl with 2 to 6 carbon atoms or dialkylaminocarbonyl with 3 to 8 carbon atoms, (c) at least one substituent, chosen from R6, R11 and R12 and (d), when R12 is not present, at least one R6 or R11 is different of C 2 -C 6 -alkylcarbonyl, C 2 -C 6 -alkoxycarbonyl, C 2 -C 6 -alkylaminocarbonyl and C 3 -C 8 -alkylaminocarbonyl and the compounds of the general formula (I), include, in addition the N-oxides and the salts, and, at least, an insecticide active product of the following groups 2 and 3, chosen among A) (thio) phosphates (group 2), preferably (2-1) Azinphos-methyl (known from US 2,758,115) and / or (2-2) Chlorpyrifos (known from US 3,244,586) and / or (2-3) Diazinon (known from US 2,754,243) and / or (2-4) Dimethoat (known by the US publication 2,494,283)
1. I . { 2-5) Disulfoton (known by the publication DE-A 91 76 68) and / or (2-6) Ethion (known from US publication 2,873,228) H5C2 ° > .p S, S I_.0C, 2H "5 OC2H5 OC2H6 and / or (2-7) Fenitrothion (known from publication BE-A 0 594 669) known for the publication DE-A 11 (known for the publication DE-A 15 and / or (2-10; Malathion (known by the US publication ., 578,562) and / or (2-11) Methidathion (known by the publication DE-A L6 45 982) and / or (2-12) Oxydemeton-methyl (known by the publication DE-A 94 73 68) and / or (2-13) Parathion (known by the publication DE-A 81 11 52) and / or (2-14) Parathion-methyl (known by the publication DE -A 81 41 42) and / or (2-15) Phenthoat (known for the publication -GB-A 834 '814) -. 3 and / or (2-16) Phorat (known by the US publication 2,586,655) and / or 5 (2-17) P-hosal-on. { known for the publication DE-A 24 31 192) 05 and / or (2-18) Phosmet (known from US 2,767,194) and / or (2-19) Phoxim (known from the publication DE-A 12 38 902) and / or (2-20) Pirimiphos-methyl (known from DE-A 14 45 949) and / or (2-21) Profenophos (known by the publication DE-A 2__l9 ---_ 62-) and / or (2-22) Prothiophos (known for the publication DE-A 21 11 414) and / or 10 (2-23) Tebu-pirimphos (known by the publication DE-A 33 17 824) 15 .0 and / or (2-24) Triazophos (known for the publication DE-A 12 99 924) 20 and / or .5 (2-25) Chlorfenvinphos (known from US publication 2,956, -073) -25" and / or (2-26) Dichlorphos (known from GB-A 775 085) 10 and / or (2-27) Dicrotophos (known by the publication BE-A 55 22 84) 15 and / or (2-28) Mevinphos (known by the publication US 2,685,552) and / or (2-29) Monocrotophos. { known for the publication DE-A 19 64 535) -25 ' and / or (2-30) Phosphamidon [known from US publication 2,908,605) and / or (2-31) Acephat (known by the publication DE-A 20 14 027) and / or (2-32) Methamidophos (known from US publication 3,309,266) H3C-SJPLNH2 I OCH, and / or (2-33; Trichlorfon., Known from US publication 2,701,225) and / or B) carbamates (group 3), preferably (3-1) Carbaryl (known from the US publication). 2,903,478) and / or (3-2) Fenoxycarb (known by the publication EP-A 0 004 334) and / or (3-3) Formetanat (known by the publication DE-A 11 69 194) and / or (3-4) Formetanat hydrochloride (known from DE-A 11 69 194) and / or (3-5) Methiocarb (known from the publication DE-A 11 62 352) and / or (3-6) Methomyl (known by the US publication 3,639,620) and / or (3-7) Oxamyl (known by the publication DE-A 17 68 623) and / or - (3-8) Pirimicarb (= Piri or). { known from GB-A 1 181 657) And / or (-3-9-) Prepox-u-r -. { -eoBoeido- or - la- ^ ub-ueaci-on- DE- - 14-- and / or (3-10) Thiodicarb (known from the publication DE-A 25! 30 439)
2. 2. - Agents according to claim 1, characterized in that they contain at least one active product of the group of anthranilic acid amides of the formula '< I-11 ' wherein R means hydrogen or alkyl having 1 to 6 carbon atoms, R means alkyl having 1 to 6 carbon atoms, which is substituted, if appropriate, by R 6, R4 means alkyl having 1 to 4 carbon atoms, halogenalkyl having 1 to 2 carbon atoms, halogenalkoxy having 1 to 2 carbon atoms or halogen, Rs means hydrogen, alkyl having 1 to 4 carbon atoms, halogenalkyl with 1 to 2 carbon atoms, halogenalkoxy with 1 to 2 carbon atoms or halogen, R6 means -C (= E2) R19, -LC (= E2) R19, -C (= E2) LR19 or -LC (= E2) LR19, meaning each E2, independently of each other O, S, N-R15, N -OR15, NN (R15) 2, and meaning each L, independently of each other, O or NR18, R7 means haloalkyl with 1 to 4 carbon atoms or halogen, R9 means haloalkyl with 1 to 2 carbon atoms, haloalkoxy with 1 to 2 carbon atoms, S (0) p- halogenoalkyl with 1 to 2 carbon atoms or halogen, R15 signifies, independently of one another, hydrogen or, for example, halogenalkyl having 1 to 6 carbon atoms or alkyl having 1 to 6 carbon atoms substituted, optionally, the substituents being independently selected from cyano, alkoxy with 1 to 4 carbon atoms, halogenalkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, alkylsulfinyl with 1 to 4 carbon atoms, alkylsulfonyl with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms , halogenoalkylsulfinyl with 1 to 4 carbon atoms or halogenalkylsulphonyl having 1 to 4 carbon atoms, R18 is respectively hydrogen-or alkyl having 1 to 4 carbon atoms, R19 signifying, respectively, independently of each other, hydrogen or alkyl having 1 to 6 carbon atoms; carbon, p mean, independently of each other, 0, 1, 2.
3. 3. Agents according to claim 1 or 2., characterized in that they contain, at least, an active product of group 2 and / or of rupe 3, chosen from (2-2) Chlorpyrifos,. { 2-31) Acephat, (2-32) Methamidophos, (3-1) Carbaryl, (3-5) Methiocarb, (3-10) Thiodicarb.
4. 4. Agents, according to claims 1, 2 or 3, characterized by containing anthraminic acid amides of the formula (I) and, at least, an active product of group 2 and / or group 3 in the proportion of 50: 1 up 1:50
5. 5. Use of a mixture with synergistic activity, as defined in claims 1, 2, 3 or 4, for the fight against animal pests. . - Procedure for obtaining agents pesticides, characterized in that a mixture is combined with synergistic activity, as defined in claims 1, 2, 3 or 4, with spreading agents and / or surfactant substances. 7. - Procedure for the fight against animal pests, characterized in that mixtures with synergistic activity, such as those defined in claims 1, 2, 3 or 4, on pests and / or their environment, are actuated. . RES UM ENDELAI NV ENCI Ó N The invention refers to new combinations of active products, insecticides, which are constituted by anthranilic acid amides (group 1), on the one hand and, on the other hand, by other active products, insecticides, chosen between the group of (thio) -phosphates (group 2) and / or between the group of carbamates (group 3) and that are suitable, in a very good way, for the fight against animal pests, such as insects .