MXPA01007106A - Display device of electronic apparatus provided with solar cell - Google Patents

Display device of electronic apparatus provided with solar cell

Info

Publication number
MXPA01007106A
MXPA01007106A MXPA/A/2001/007106A MXPA01007106A MXPA01007106A MX PA01007106 A MXPA01007106 A MX PA01007106A MX PA01007106 A MXPA01007106 A MX PA01007106A MX PA01007106 A MXPA01007106 A MX PA01007106A
Authority
MX
Mexico
Prior art keywords
visual display
solar cell
solar
plate
display device
Prior art date
Application number
MXPA/A/2001/007106A
Other languages
Spanish (es)
Inventor
Murakami Tomomi
Tanaka Yoshiya
Yamaguchi Katsuyuki
Sakamaki Shinichi
Original Assignee
Citizen Watch Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Citizen Watch Co Ltd filed Critical Citizen Watch Co Ltd
Publication of MXPA01007106A publication Critical patent/MXPA01007106A/en

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Abstract

The display device of an electronic apparatus, wherein a circularlypolarizing plate consisting of a linearly polarizing plate (42) and a 1/4 lambda plate (43) is disposed between a solar display plate (41) and an inner frame (46) for fixing a solar cell (44) -carrying module (45) to an external case to thereby make undiscernible the border line between the inner frame (46) and the solar cell (44), a gate trace formed by injection molding of the inner frame (46), and the solar cell element dividing lines of the solar cell (44), whereby a design spectrum for the solar display plate (41) can be widened, the color of the solar display plate (41) can be thickened to give a high-grade touch to the device, and a timepiece outer shape of various designs can be formed due to the presence of the inner frame.

Description

VISUAL DEVICE DEVICE OF ELECTRONIC DEVICE PROVIDED WITH SOLAR CELL Technical Field The present invention relates to a visual display device for an electronic device comprising a solar cell, for example, an electronic device, such as a watch, an electronic calculator, a radio, a battery charger, and more particularly the watch.
BACKGROUND ART With reference to Figure 26, a conventional example of a clock structure having a solar cell 305 will be described in detail. Figure 26 (a) is a front view showing the inside of a watch case viewed from above, and Figure 26 (b) is a schematic sectional view showing the inside of the watch case. As shown in Figure 26, when light is incident on a solar visual display board 301 of a clock from outside, the light is transmitted through visual display board 301 to reach solar cell 305. Then the solar cell 305 is such a mechanism, that the optical energy is converted into electrical energy, which is charged into a battery or capacitor referred to as a secondary battery that is provided in a module 307, and can store electricity, and in a simultaneous manner, the The module 307 is driven in such a way that a minute hand 301 and an hour hand 309 are moved which are fixed to the central axis 308. In this case, the solar visual display board 301 is placed between the minute hand 310 and the hour hand 309 and solar cell 305. Furthermore, the module 307 indicates a pulse portion in the clock. In recent years, the power generation efficiency of the solar cell has been improved, the power consumption of a module has been reduced, and in addition, the performance of a battery has been improved. Consequently, even when the external shape of a solar cell is much smaller than ever, a minute hand and an hour hand can be driven. On the other hand, increasingly greater degree of freedom has been required for the external shape of a watch case, depending on the diversification of the watch design. A half frame 306 is placed on the outside of the solar cell 305 and the module 307, in such a way that the degree of freedom with respect to the design of the external shape of the clock can be improved. As shown in Figures 26 (a) and (b), the solar cell 305 and the module 307 are fixed through the medium frame 306 to an external box, which is not shown. Moreover, the minute hand 310 and the hand of the hours 309 are linked to the central axis 308 extended from the module 307, and are rotated through the driving force applied from the module 307. In addition, the control board visual display 301 is provided to cover the solar cell 305 and the middle frame 306. The middle frame 306 is provided with a hook mechanism in order to fix the module 307 to which the solar cell 305 is fastened, which is not shown . When the module 307 is adjusted in the middle frame 306, the solar cell 305 and the module 307 are fixed to the middle frame 306, and they are accommodated in the outer box, and therefore, they are fixed thereon. The solar cell 305 has two kinds of substrates, i.e. the substrates formed of a glass and a resin. For both, the solar cell itself has a small thickness. In addition, there is a possibility that the formed glass substrate may be shattered by a stress, such as a shock during or after assembly. The substrate formed of resin could be deformed by a tension thereof during bonding. For a method of attaching to the watch case, therefore, the solar cell 305 and the middle frame 306 are not fixed, but the module 307 and the middle frame 306 are fixed. In the case of the substrate formed of resin, it is it can provide a metal plate on the underside of solar cell 305, in order to improve the reliability of rigidity and electrical connection.
In addition, in the case where the solar display board 301 comes into contact with the solar cell 305, the power generation efficiency of the solar cell 305 could be reduced due to a defect or the like. Accordingly, the average frame 306 also has the function of preventing the reduction of power generation. When the solar visual display board 301 is superimposed on the solar cell 305, the middle frame 306 protrudes slightly upwards from the upper face of the solar cell 305, such that the middle frame 306 comes into contact with the deployment board. visual solar 301 sooner than the solar cell 305. Furthermore, in the case in which the module 307 having the solar cell 305 fixed thereto is incorporated, in the average frame 306, the incorporation can be easily carried out, and productivity can be improved if the external shape of solar cell 305 is coincident with that of module 307, as shown. As described above in detail, the middle frame in the clock parts is a member that has an important role. As shown in Figure 26 (a), a limit line 303 between the solar cell 305 and the middle frame 306 normally requires a tolerance for the watch assembly work, and the tolerance is seen black through the solar visual display board 301. Moreover, a material of plastic for the medium frame 306 in consideration of ease of molding, cost, shock absorption, and the like, and the medium frame 306 is manufactured by injection molding to correspond to the different outer boxes. Accordingly, a gate track 304 is formed on the upper face of the middle frame 306 due to injection molding, and the gate track 304 is also seen through the solar visual display board 301. Furthermore, in the case where the solar cell is divided into some elements to maintain a previously determined voltage and current, the refractive index of the light is varied depending on the difference in material between a portion of the cell and a portion of dividing line, and it is also seen a dividing line of the solar cell element 302 through the solar visual display board 301. According to the knowledge of the present inventors, this phenomenon occurs notoriously when the solar visual display board 301 is black or blue. Figure 26 shows an example where the dividing line 302 of the solar cell element has a cross shape, and the boundary line 303 between the solar cell 305 and the middle frame 306 has the shape of a black ring over the boundary between a portion of sloping line and a dotted portion. To know a technique for viewing this solar cell element divider line with difficulty, a method has been conventionally proposed to be known from Japanese Patent Publication Number Hei 5-38464. In Japanese Patent Publication Number Hei 5-38464, only one color diffusion board is provided between the solar visual display board 301 and the solar cell 305. However, the diffusion board has the function of diffusing the light. Accordingly, the boundary line 303 between the solar cell 305 and the middle frame, the gate track 304 generated by injection molding the middle frame, and further, the dividing line 302 of the solar cell element, are seen with difficulty. As a result, they are necessarily white so that the tone of the solar display panel 301 provided above is affected. According to an experiment performed by the present inventors, if only the color diffusion board is provided between the solar visual display board 301 and the solar cell 305, the black solar visual display board looks gray, which is not preferable with respect to the design. Moreover, a white solar visual display board has diffusion effects by itself. Therefore, even when the diffusion board is not used, the phenomenon that the dividing line 303 between the solar cell 305 and the medium frame 306, the gate track 304 generated by injection molding of the medium frame 306, and the dividing line of the solar cell element 302 is seen through the solar visual display board 301. Accordingly, it is not necessary to provide the diffusion board of Japanese Patent Publication Number Hei 5-38464. Normally different designs are given through the solar visual display board 301. If there is a phenomenon that the boundary line 303, the gate track 304 and the dividing line of the solar cell element 302 are seen as described above, it is affected adversely the quality of the design of a watch. More specifically, in this case, a decoration or similar to a part of the solar visual display board 301 or its entire surface should be given, in order to hide the aforementioned phenomenon. Accordingly, the design for the solar visual display board 301 is restricted, so that a high quality feel for a watch is eliminated. In the three phenomena that adversely affect the quality of the design, as described above, the dividing line of the solar cell element 302 can be considerably improved by giving a protective coating formed of an epoxy resin having Si02 particles distributed thereon. the entire surface of the solar cell 305. Moreover, there is a possibility that the gate track 304 generated during the injection molding of the middle frame 306 is also improved by changing the position of the gate. However, the limit line 303 between the solar cell 305 and the middle frame 306, that is, the tolerance for the clock assembly work can not be avoided, and is the most damaging, and measures are taken with difficulty. In the experiment carried out by the present inventors, the colors of the solar black and blue solar display boards are made to be deeper, and a high quality feeling can be obtained for the articles by deeper colors, and, in addition, it is possible to eliminate the drawback that observation occurs through the solar visual display board described above. However, the transmitted light does not completely reach the solar cell itself, in such a way that the power generation efficiency is reduced, and the operation of the clock is stopped. Moreover, when the tone of the middle frame is adapted to that of the solar cell, it is possible to eliminate the drawback of observation being caused through the solar visual display board described above. However, the boundary line between the solar cell and the middle frame is seen, so that this drawback can not be completely eliminated. In addition, when thinly applying a white paint to the side of the solar cell of the blue solar visual display board having a blue resin therein, it is possible to eliminate the phenomenon that the boundary line 303 between the solar cell 305 and the frame 306, the gate track 304 generated by injection molding of the middle frame 306, and further the dividing line of the solar cell element 302, are seen through the solar visual display board 301. However, the color depth of the The solar visual display board 301 is removed by the diffusion function of the white paint, in such a way that the high quality feeling disappears for the individual solar visual display board. In other words, the formation of a diffusion layer can not obtain sufficient effects. On a visual display board, such as a watch face, different colors and patterns are applied to the surface or to the back of the visual display board, or to both, in order to give a feeling of high quality (value added) in some cases. The coloring is done by printing the surface of the material that is going to be the visual display board, or manufacturing the visual display board from a resin containing a pigment, for example. Moreover, in the case of a metal visual display board, the pattern is formed on its surface by etching, a mat processing, or the like. In the case of a visual display board formed of resin, a pattern is formed by injection molding the resin in a mold having the pattern formed therein. However, the aforementioned visual display boards are not satisfactory with respect to the depth of a pattern, a three-dimensional effect, and the like.
In consideration of these circumstances, it is an object of the present invention to provide a visual display device for an electronic device comprising a solar cell and a middle frame, for fixing the solar cell and a module to an external box where it can be made that the necessary light and sufficient reach to the solar cell, that a high quality sensation can be given, and in addition, that it is possible to increase the variation in the design, where a decorative property is greater, and where the depth of the pattern and the three-dimensional effect are excellent.
Disclosure of the Invention The present invention has been made to solve the problems of the conventional technique described above, and to achieve the aforementioned object, and provides a visual display device for an electronic device, which comprises a solar cell, wherein a circular polarization plate is provided to transmit light on the front side of the solar cell in a direction of incidence of light. In a circular polarization plate constituted by a linear polarization plate and a phase difference plate, the linear polarization plate and the phase difference plate are provided in this order in a direction of incidence of light. As a result, the light reflected by a surface of the solar cell can be blocked, and the boundary line between the solar cell and the middle frame can not be seen, the gate track generated by injection molding of the middle frame, and the line divider of the solar cell element, through the circular polarization plate. As a result, the tone of the solar visual display board is not affected. Moreover, it is not necessary to hide the three drawbacks through a pattern in the form of strips or the like. Therefore, the variation in the design of the solar visual display board can be increased. In addition, a solar visual display board having a deep color can be used, so that a high-quality feel in the articles can be obtained visually. By directly giving the mark, such as a numeral, to the linear polarization plate by means of printing or the like, the function of the solar visual display board can also be given to the linear polarization plate itself. Moreover, the present invention is characterized in that the surface of the circular polarization plate is provided with a solar visual display board constituted by a resin substrate having a pattern, an inorganic substrate having a pattern or a thin film er decorative or a combination thereof. Therefore, the decorative property is large, the pattern becomes rich, and an excellent three-dimensional effect can be obtained. Through a combination of two or more patterns or two or more materials, moreover, it is possible to manufacture a visual display board that has a better feeling of beauty than ever before. Therefore, the variation of the design can be increased. By means of this structure, it is possible to provide a visual display device for an electronic device comprising a solar cell capable of maintaining the necessary and sufficient energy generation efficiency of the solar cell, giving a feeling of high quality, and increasing the variation in design.
BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a schematic sectional view showing the inside of a watch case according to a first embodiment of the present invention. Figure 2 is a schematic sectional view showing the inside of a watch case in accordance with a second embodiment of the present invention. Figure 3 is a schematic sectional view showing the inside of a watch case according to a third embodiment of the present invention. Figure 4 is a schematic sectional view showing the inside of a watch case according to a fourth embodiment of the present invention.
Figure 5 is a schematic sectional view showing the inside of a watch case in accordance with a fifth embodiment of the present invention. Figure 6 is a schematic sectional view showing the inside of a watch case according to a sixth embodiment of the present invention. Figure 7 is a schematic sectional view showing the inside of a watch case in accordance with a seventh embodiment of the present invention. Figure 8 is a schematic sectional view showing the inside of a watch case in accordance with an eighth embodiment of the present invention. Figure 9 shows the inside of a watch case in accordance with a ninth embodiment of the present invention; Figure 9 (a) being a schematic sectional view showing the inside of the watch case, and Figure 9 (b) being a front view showing the inside of the watch case viewed from above. Figure 10 is a schematic sectional view showing the inside of a watch case in accordance with a tenth embodiment of the present invention. Figure 11 is a schematic sectional view showing the inside of a watch case in accordance with a eleventh embodiment of the present invention. Figure 12 is a schematic sectional view showing the inside of a watch case in accordance with a twelfth embodiment of the present invention. Figure 13 is a schematic sectional view showing the inside of a watch case in accordance with a thirteenth embodiment of the present invention. Figure 14 is a partially amplified sectional view showing a solar visual display board in accordance with the thirteenth embodiment of the present invention. Figure 15 is a schematic view showing the steps of a method for manufacturing a resin substrate having a pattern in accordance with the present invention. Figure 16 is a schematic view showing a method for forming the resin substrate having a pattern, through a thermal press, in accordance with the present invention. Figure 17 is a schematic view showing another method for forming the resin substrate having a pattern, through a thermal press, in accordance with the present invention. Figure 18 is a partially amplified sectional view showing a solar visual display board in accordance with a fourteenth embodiment of the present invention. Figure 19 is a partially amplified sectional view showing a solar visual display board in accordance with a fifteenth embodiment of the present invention. Figure 20 is a partially amplified sectional view showing a solar visual display board in accordance with a sixteenth embodiment of the present invention. Figure 21 is a partially amplified sectional view showing a solar visual display board in accordance with a seventeenth embodiment of the present invention. Figure 22 is a partially amplified sectional view showing a solar visual display board in accordance with a tenth-eighth embodiment of the present invention. Figure 23 is a partially amplified sectional view showing a solar visual display board in accordance with a nineteenth embodiment of the present invention. Figure 24 is a partially amplified sectional view showing a solar visual display board in accordance with a twentieth embodiment of the present invention. Figure 25 is a partially amplified sectional view showing a solar visual display board in accordance with a twenty-first embodiment of the present invention. Figure 26 shows the state of the interior of a watch case according to a conventional example; Figure 26 (a) being a front view showing the inside of the watch case seen from above, and Figure 26 (b) being a schematic sectional view showing the inside of the watch case. Figure 27 is a perspective view showing the operation principle in accordance with the present invention. Figure 28 is a diagram in which the light emitted from a phase difference board is divided into the directions x in and in accordance with the present invention. Figure 29 is a diagram of table XY, showing the direction of oscillation of the light emitted from the phase difference board according to the present invention.
BEST MODE FOR CARRYING OUT THE INVENTION The embodiments of the present invention will be described below. First of all, the function of a circular polarization plate will be described with reference to Figures 27 to 29.
The circular polarization plate is usually made by attaching a linear polarization plate 111 formed from a film material to a 1/4"plate, 112 formed of a film material with an adhesive layer. As a matter of course, if the circular polarization plate has the circular polarization function, other structures and members can be used. Moreover, the linear polarization plate can have a structure such that a thin film of iodine-absorbing polyvinyl alcohol is spread in one direction, and molecules are configured in parallel, and walled with acetylbutylcellulose. In addition, a lens or group of lenses can be used to collect light in one direction. Because the mirror reflection can be suppressed, the linear polarization plate is used to improve contrast or reduce eye fatigue. The linear polarization plate 111 has a type of absorption or a type of reflection. An absorption axis or a reflex axis is orthogonally present to the transmission axis. When natural light for oscillation in all directions is incident on the linear polarization plate 111, as shown in Figure 27, only light is transmitted in the same oscillatory direction as the transmission axis. In the type of absorption, the incident light on the linear polarization plate 111 is absorbed in the polarization plate. Moreover, the type of reflection has the function of reflecting the incident light on the linear polarization plate 111 from a surface of the polarization plate. The embodiments according to the present invention will be described using an absorption type linear polarization plate and a l / 4? as the linear polarization plate and the phase difference plate if a special description is not given. The transmitted light polarized in one direction is incident at an angle of 45 ° with respect to the axis of delay of the phase difference plate. In this case, the phase difference plate represents the plate of l / 4 ?, 112, and divides the incident light at 45 ° in the x and y directions for greater convenience, and considers both maximum amplitudes as 1, as shown in Figure 28. An abscissa axis indicates an angle, and an ordinate indicates an amplitude, and the relationship between the wavelength and the phase is such that a wavelength is 360 ° (?). If the axis of delay of the phase difference plate is set in the direction y, the presence of the phase difference plate causes the light transmitted through the phase difference plate to be delayed by l / 4? phase only in the y direction. Suppose the case where the light advances by 3/4 wavelength through the plate of l / 4 ?, 112. The light does not delay in the x direction, and is delayed by l / 4? in the direction y, as shown in solid line from a waveform shown in the chain line of individual points. Accordingly, a point A (-1, 0) is obtained in Figures 28 and 29. Moreover, when the light further advances by l / 4 ?, a point B (0, 1) is obtained in Figures 28 and 29 in the same way. When the time passes additionally as shown in Figure 29, the light advances from point C (1, 0) to point D (0, -1) in the same way. Accordingly, the light passing through the plate of l / 4 ?, 112, is converted from linear polarized light to circular polarized light, as shown in Figures 27 and 29. The light thus circularly polarized is reflected through the surfaces of an average frame 113 and solar cell 114, and is incident on the plate of 1/4 ?, 112, again inversely to the direction of advancement, as shown in Figure 27. In the same manner to the one described above, the light becomes light having a plane of oscillation in a direction perpendicular to the direction of incidence on the plate of l / 4 ?, 112, and the light thus obtained is vertical to the transmission axis of the linear polarization plate 111. Accordingly, the light can not pass through the linear polarization plate 111, such that the reflected light is blocked. The linear polarization plate 111 and the 1/4"plate 112 are combined to form a circular polarization plate. In this case, it has been known that the incident light is reflected by approximately several percentages per boundary surface, if in general boundary surfaces having different refractive indices are present. In the case of air and glass, incident light is reflected by approximately 4 percent. Therefore, it is preferable that the number of limit surfaces be reduced as much as possible. In accordance with the foregoing, it is preferable that the linear polarization plate 111 and the 1/4"plate 112 are stacked in a state of close contact, or bonded with an adhesive or glue. Although the linear polarization plate 111, the plate of l / 4 ?, 112, and the middle frame 113 are square in shape, and the solar cell 114 is circular in Figure 27, other different shapes corresponding to the design can be used.
(First Mode) The explanation of the circular polarization function has been made, and a first embodiment will be described in detail below with reference to Figure 1. As shown in Figure 1, a clock having a solar cell comprises a solar cell 13 electrically connected to a module 14, and a minute hand 17 and an hour hand 16 that are fixed to a central axis 15. A circular polarization plate A is provided which includes a linear polarization plate 11 and a plate of l / 4 ?, 12, between the hands 16 and 17 and the solar cell 13. With this structure, the dividing line of the solar cell element of the solar cell 13 can not be seen through the circular polarization plate constituted by the plate. polarization 11 and the plate of l / 4 ?, 112. Moreover, because the reflected light is eliminated, the color of the surface of the linear polarization plate 11 is deepened, in such a way that a High quality feeling in the article. In the present embodiment, the marking of a numeral is directly given to the linear polarization plate 11 by means of printing, to provide the function of a solar visual display board. Moreover, it is desirable that the circular polarization plate A, constituted by the linear polarization plate 11 and the plate of 1/4? 12, have a flat direction positioned by an external box, which is not shown, with respect to the assembly work of a clock. In the following modes, because the effects are not affected, the description of the minute and hour hands will be omitted if there is no special condition. In the same way as in the following embodiments, although the components are shown separated from each other for greater convenience of description in the drawings, they are actually incorporated in a state of close contact, for example, appropriately in a state of adhesion, link and welding with an adhesive, an adhesive or similar.
(Second Modality) As shown in Figure 2, a circular polarization plate A is provided which includes a linear polarization plate 22 and a plate of 1/4? between the solar cell 24 and the solar visual display board 21, which has light transmission. Consequently, the dividing line of the solar cell element of the solar cell 24 can not be seen through the solar visual display board 21, so that the variation in the design of the solar visual display board 21 is increased. , the color of the solar visual display board 21 is deepened, in such a way that a high quality feeling of the articles is obtained. In a work to assemble the watch, first of all, a module 25 is manufactured, and simultaneously the external shapes of the visual display board 21, the solar cell 24, the linear polarization plate 22, and the plate of l / are processed simultaneously. 4? 23, through press molding or the like, and overlap with a structure shown in Figure 2 in an outer box, which is not shown, so that a finished watch is obtained. According to the above, it is desirable that the circular polarization plate constituted by the visual display board 21, the solar cell 24, the linear polarization plate 22, and the plate of 1/4? 23, have the same external forms.
(Third Mode) In the present embodiment, Figure 3 shows the structure of a clock where a module 34 having a solar cell 33 in an external box 39 is fixed through an intermediate frame 35. A polarization plate is provided. circular A constituted by a linear polarization plate 31 and a plate of l / 4? 32, above the middle frame 35, between the minute hand 37 and the hand of the hours 36, which are fixed to a central axis 38 and to the solar cell 33. Through this structure, the limit line between the solar cell 33 and the middle frame 35, the gate track generated by injection molding of the middle frame 35, and in addition, the dividing line of the solar cell element of the solar cell 33 through the circular polarization plate A constituted by the linear polarization plate 31 and the plate of 1/4? 32. Furthermore, it is desirable that the circular polarization plate A be provided to cover the solar cell 33 and the middle frame 35, as shown. Because the reflected light is removed, the color of the surface of the linear polarization plate 31 is deepened, so that a high quality feel of the articles can be obtained. In the present embodiment, the marking of a numeral is directly given to the linear polarization plate 31 by printing, to provide a function as a solar visual display board. Moreover, the average frame 35 is provided. Accordingly, different external shapes of the watch can be obtained with respect to the design, in the following embodiments, because the effects are not affected, the description of the outer box will be omitted.
(Fourth Mode) Also in the present embodiment, Figure 4 shows the structure of a clock where a module 45 having a solar cell 44 is fixed through the middle frame 46 in an external box, which is not shown. In the present embodiment, the circular polarization plate A constituted by the linear polarization plate 42 and the plate of 1/4? 43, is provided between the middle frame 46 and the solar visual display board 41. Through this structure, the boundary line between the solar cell 44 and the middle frame 46, the gate track generated by injection molding of the middle frame 46, and in addition, the dividing line of the solar cell element of the solar cell 44, through the visual display board 41, in such a way that the variation in the design of the solar visual display board 41 can be increased. In addition, the color of the solar visual display board 41 is deepened, so that a high quality feeling of the articles can be obtained. Furthermore, an average frame 46 is provided. Accordingly, different external shapes of the clock can be obtained with respect to the design. In the present embodiment, furthermore, a color visual display board including a dye, a pigment and the like, is used for the solar visual display board 41, for example. Accordingly, although the tone has only one black color in the third embodiment, the visual display board may have colors. Therefore, it can be seen that the practical use can be improved in a considerable way with respect to the design. Moreover, it is desirable that the circular polarization plate A constituted by the linear polarization plate 42 and the l / 4"plate, the middle frame 46, and the solar visual display board 41, have the same external shapes with respect to to the assembly work.
(Fifth Mode) Also in the present embodiment, Figure 5 shows the structure of a clock where a module 56 having a solar cell 55 is fixed through an average frame 57, in an external box, which is not shown . In the present embodiment, a circular polarization plate B having a linear polarization plate 52, a plate of l / 4? 53, and a plate of l / 2? 54, stacked. The circular polarization plate B is provided between the middle frame 57 and the solar visual display board 51. With this structure, the same effects can be obtained as those of the fourth mode. It has been known that the provision of the plate of l / 2? 54 can amplify a wavelength region where light can be blocked, and a wide-band type circular polarization plate can be obtained. In the same way as the plate of l / 4 ?, the plate of l / 2? it includes an axis of delay, and has the function of delaying incident light in that direction by l / 2 ?.
(Sixth Modality) As shown in Figure 6, a solar visual display board 61, a linear polarization board, is bonded 62, and a plate of l / 4? 63, through an adhesive layer 68, and then pressurized and molded. Accordingly, an integral visual solar display board of circular polarization plate C is manufactured. The integral visual solar display board of circular polarization plate C is provided above a solar cell 64 having a diffusion layer 67 preformed on its upper surface. Also in this case, in a similar manner, the boundary line between the solar cell 64 and the middle frame 66, the gate track generated by injection molding of the middle frame 66, and in addition, the dividing line of the element can not be seen. of the solar cell of the solar cell 64, through the solar visual display board 61. As a result, the variation in the design of the visual display board 61 can be increased. In addition, the color of the visual display board is deepened Solar 61, in such a way that you can get a high quality feeling of the items. Even more, the middle frame 66 is provided. Accordingly, different external shapes of the watch can be obtained with respect to the design. In general, it has been known that the incident light is reflected by approximately several percentages for each of the boundary surfaces having different refractive indices. In the case of air and glass, incident light is reflected by approximately 4 percent. Therefore, it is preferable that the number of boundary surfaces be reduced as much as possible. By applying to the present embodiment, when two film materials are inserted, i.e., the linear polarization plate 62 and the plate of 1/4? 63 between the solar visual display board 61 and the solar cell 64 having the diffusion layer 67 formed thereon, the number of boundary surfaces is increased through the insertion of the films, in such a way that the light is reduced transmitted to the solar cell 64. However, when the solar visual display board 61 and the linear polarization plate 62, and the linear polarization plate 62 and the l / 4? 63, through an adhesive layer 68, respectively, as in the present embodiment, the number of boundary surfaces is reduced from 7 to 3. As a result, the light transmitted to the solar cell 64 can be further improved, and it can be improved plus the power generation efficiency, comparing with the case where the adhesive layer 68 is not provided. In order to perform the accommodation in an external box, which is not shown, moreover, a processing of the external shape, and also a perforation processing is required to penetrate with an external arrow, which is not shown. If three layers are bonded by adhesive layers, the processing is done only once, in such a way that the steps can be simplified, and the cost can be reduced. Comparing with the box where the three layers are processed separately, in addition, it is possible to prevent movement when the three layers are linked. As a result, the quality of the design can also be improved. In addition, referring to a work to assemble a clock in accordance with the present embodiment, the diffusion layer 67 is first formed on the surface of the solar cell 64, is linked to a module 65, and then fits in the middle frame 66. At the same time, the solar visual display board 61, the linear polarization board 62, and the board of l / 4? 63 through the adhesive layer 68, and then the processing of the external shape and the perforation are carried out by means of a press or the like. Subsequently, as shown, they are superimposed on an external box, which is not shown. For 1? So much, you get a finished clock. In the present embodiment, because the solar visual display board 61, the linear polarization plate 62, and the plate of l / 4? 63 are bonded through the adhesive layer 68, can be treated as a member. Consequently, the work to assemble a clock can be performed more easily in these modalities.
(Seventh Modality) As shown in Figure 7, a solar visual display board 71, a linear polarization plate 72, a plate of l / 4? 73, a solar cell 74 and an intermediate frame 76, as shown, and are bonded with an adhesive layer 77. Also in this case, in the same manner as in the sixth embodiment, the boundary line between the cell can not be seen. solar 74 and the middle frame 76, the gate track generated by injection molding the middle frame 76, and further, the dividing line of the solar cell element of the solar cell 74, through the solar visual display board 71, of such that the variation in the design of the solar visual display board 71 can be increased. In addition, the color of the solar visual display board 71 is deepened, so that the high quality feeling of the articles can be obtained . Moreover, the average frame 76 is provided. Accordingly, different external shapes of the clock can be obtained with respect to the design. Also in the present embodiment, in the same manner as in the sixth embodiment, the number of limit surfaces provided between the visual display board 71 and the air is one, and transmission may be further improved than in the sixth mode, and You can also improve the power generation efficiency.
(Eighth Mode) In the present embodiment, the solar cell 83 is larger than the external shape of the module 84, and the external shape of the middle frame 85 for fixing the module 84 to an external box, which is not shown, is equal to that of the solar cell 83. In the present embodiment, the solar cell 83 completely covers the boundary line between the middle frame 85 and the module 84 and a gate track generated by injection molding of the mid frame 85. Therefore, the quality of the visual display is not reduced. By inserting a linear polarization plate 81 and a plate of 1/4", a dividing line of the solar cell element of the solar cell 83 can be prevented.
(Ninth Mode) The present embodiment provides a clock structure where a solar cell 94 and a module 95 are fixed through an intermediate frame 96 to an external box, which is not shown. Then a circular polarization plate A consisting of a linear polarization plate 92 and a plate of 1/4? 93, above the middle frame 96. In addition, a liquid crystal display panel 91 is provided above them. The liquid crystal display panel 91, which has an external shape smaller than that of the solar cell 94, is provided above the circular polarization plate A.
Accordingly, the light transmitted through the linear polarization plate 92 and the plate of 1/4? 93 reaches the solar cell 94, and energy is supplied to the panel of the liquid crystal display, to display the time by the electromotive force of the solar cell 94. Also in the present embodiment, in the same way as in the seventh embodiment , the boundary line between the solar cell 94 and the middle frame 96, the gate track generated by injection molding of the middle frame 96, and in addition, the dividing line of the solar cell element of the solar cell 94, can not be seen, in such a way that the variation in the design can be increased, and a feeling of high quality of the articles can be obtained. In the present embodiment, the liquid crystal display panel displays the time of 12 o'clock in the afternoon.
(Tenth Modality) A linear polarization plate has a type of absorption and a type of reflection. In the present embodiment, a reflex-type linear polarization plate having a reflex axis orthogonal to the transmission axis is used. In the event that a circular polarization plate is constituted by the reflective-type linear polarization plate and a plate of l / 4 ?, and inserted between a solar visual display board and a solar cell, a mirror-type linear polarization plate 42 'is used as a linear polarization plate 42 as in other embodiments, for example, as shown in Figure 10. In this case, the boundary line between the solar cell 44 and the middle frame 46, the gate track generated by injection molding the middle frame 46, and in addition, the dividing line of the solar cell element of the solar cell 44, through the solar visual display board 41. As a result, the variation in the design of the solar visual display board 41 can be increased in the same manner as in the fourth mode. In the case of a blue solar visual display board, the brightness is reduced and the blue color of the solar visual display board is made deeper by using the absorption-type linear polarization plate, and the blue color is reproduced of the solar visual display board faithfully using the reflective type linear polarization plate. Furthermore, in the case of a black solar visual display board, the brightness is also reduced, and a high quality feeling can be obtained by using the absorption-type linear polarization plate, and the brightness of the black color of the solar visual display board to approximate a gray color by using the reflective type linear polarization plate. As described above, the color of the solar visual display board is changed in a deeper direction by the use of the absorption-type linear polarization plate, and a high-quality feeling can be obtained visually regardless of the color of the board of solar visual display. The type of absorption is different from the type of reflection in that the oscillation in a direction perpendicular to the transmission axis of the linear polarization plate is absorbed in the linear polarization plate, or is reflected from the surface of the linear polarization plate. Therefore, they perform the same actions for transmitted light, and have the same functions as circular polarization plates.
(Eleventh Modality) As shown in Figure 11, a diffusion layer 47 is formed between the solar display panel 41 and the linear polarization plate 42 in the structure of Figure 4. Through this structure, they can not be seen the boundary line between the solar cell 44 and the middle frame 46, the gate track generated by injection molding the middle frame 46, and further, the dividing line of the solar cell element of the solar cell 44, more than those of the fourth modality, in such a way that the variation in the design of the solar visual display board can be increased 41.
In addition, the color of the visual display board 41 becomes deeper, a high quality feeling of the articles can be obtained. Moreover, the middle frame is provided. Accordingly, different external forms of a clock can be obtained with respect to the design. In the present embodiment, when the solar visual display board 41 is subjected to injection molding, the concave-convex shapes previously formed in a mold are transferred to the surface opposite the linear polarization plate 42 of the solar visual display board 41 , in such a way that a diffusion layer is formed. As described in the Background of the Invention, the simple formation of the diffusion layer is not sufficient.
By using a circular polarization plate in this manner, the aforementioned effects can be produced.
(Twelfth Modality) As shown in Figure 12, a diffusion layer 48 is formed between the linear polarization plate 42 and the l / 4? 43 in the structure of Figure 4. Accordingly, the boundary line between the solar cell 44 and the middle frame 46, the gate track generated by injection molding of the middle frame 46, and in addition, the dividing line can not be seen. of the solar cell element of the solar cell 44, more than those of the fourth embodiment, in such a way that the variation in the design of the solar visual display board 41 can be further increased. Additionally, the color of the board becomes deeper of solar visual display 41, and you can get a feeling of high quality articles. Moreover, an average framework is provided. Accordingly, different external forms of a clock can be obtained with respect to the design. In the present embodiment, oxide particles are dispersed in an adhesive layer between the linear polarization plate 42 and the 1/4"plate. 43, in such a way that the diffusion layer is formed.
(Thirteenth Mode) As shown in Figure 13, a clock structure 100 according to the present embodiment is set, a solar cell 102 and a module 104, through an intermediate frame 106, to an external box, which it is not shown. A circular polarization plate A consisting of a linear polarization plate 101 and a plate of 1/4"is provided. 103 above. medium frame 106. In addition, a solar visual display board 108 is provided above them. As shown in Figure 14, the solar visual display board 108 is constituted by a resin substrate body 110, and a portion of pattern 112 formed on its upper surface. It is preferable that the resin substrate 110 is formed of a thermoplastic resin, and in addition, a resin selected from the group consisting of polyvinyl chloride, an acrylic resin and polycarbonate. In the present invention, it is particularly preferable that acrylic resin or polycarbonate be used. The thickness of the resin substrate 110 is preferably about 50 to 500 microns, and more preferably about 80 to 200 microns. The resin substrate 11 can be transparent or colored and translucent. A pattern is given to the resin substrate 110 by an injection molding method, for the injection molding of a resin in a mold having a pattern formed therein (which will be referred to hereinbelow as a "pattern mold"). "); a pattern transfer method for transferring a pattern onto a resin substrate through a thermal press using the pattern mold; or a method of machining using recording, rubbing or the like. In the present invention, in particular, the pattern transfer method is preferably employed. As a method of patterning the resin substrate 110, the pattern transfer method will be described below.
As shown in Figures 15 (A) to 15 (C), the pattern transfer method comprises the steps of making an electrical mold 120 having a pattern surface, and thermally pressing a patterned surface 122 molded into the mold electrical 120 against the resin substrate 110. When the electrical mold 120 having the pattern surface is to be manufactured, a surface pattern of an article 124 having a pattern is first molded through an electrical molding method. More specifically, article 124 having the pattern is subjected to electroforming. In the case where article 124 has no conductivity, a metallic film 126 is formed on the surface of article 124 to give conductivity to article 124. The examples of article 124 having the pattern include cloth, paper, slit, grain, pyroxene , leaf, petal, shell, leather, artificial substances that have different fine patterns (an artificial leather, engraving, setting) and the like. It is preferable to use cloth, paper, slit, grain, pyroxene, sheet, engraving and setting. As shown in Figure 15 (A), a pattern is formed on the surface of article 124 (the concavo-convex portions on the surface in Figure 15 (A) .In Figure 2, the back face of the article is omitted. 124. In order to give conductivity to the surface of article 124, first the surface of article 124 is cleaned, and then a metal film 126 is formed on the surface of article 124. Metal film 126 is formed by vacuum evaporation, Ionic plating, sputtering, non-electrolytic plating, silver mirror reaction or the like, for example, Although metallic film 126 is formed of a metal, such as silver or gold, or its alloys, and its thickness is not particularly restricted, it is a thickness of about 1 to 30 microns, preferably about 1 to 10 microns, is suitable In the case where article 124 has conductivity, as described above, it is not necessary to form the film metal layer 126. Next, the surface of the metal film 126 is subjected to removal, if necessary. When article 124 has conductivity, the surface of article 124 is directly subjected to removal. The removal can be done by injection of selenious acid. When the removal is performed, the electric mold 120 can be easily removed. As shown in Figure 15 (B), a metal is then deposited on the surface of article 124, or on the surface of metal film 126, through of electric molding (electroforming) to form the electric mold 120. As a material of the electric mold 120, a metal, such as nickel, copper or iron, or its alloys is preferably used. The thickness of the electric mold 120 is 100 to 300 microns, preferably 100 to 250 microns, and more preferably 100 to 200 microns. If the thickness of the electric mold 120 is established in this range, the resin substrate 110 is not deformed, and heat transfer can be performed well during thermal compression. The conditions of the electric molding are not particularly restricted, but are appropriately selected from conventional electric molding (plywood) conditions. The electric molding conditions will be briefly described to obtain the electric mold 120 having a thickness of 200 microns, by using a nickel metal. However, conditions should not be restricted by this condition. As a pretreatment, the surface of the article 124 having a pattern or the metallic film 126 is subjected to treatments of electrolytic degreasing, washing, neutralization with acid, washing, removal (potassium dichromate) and washing. Then electroforming is performed at 265 AH (IA / dm2) at a liquid temperature of 50 ° C, by using a nickel plating bath (450 grams / liter of nickel sulphamate, 40 grams / liter of boric acid). Accordingly, the electric mold 120 having a thickness of 200 microns is obtained. As shown in Figure 15 (C), then the electric mold 120 is removed from the surface of the article 124, or from the surface of the metal film 126. Accordingly, the electric mold 120 having a pattern surface is obtained. molded The electric mold 120 thus obtained is cut corresponding to the shape of a visual display board as intended, if necessary. As shown in Figure 16, the molded pattern is subsequently transferred to the resin substrate 110. In order to transfer the pattern to the resin substrate 110, the surface of the molded pattern of the electrical mold 120 is opposite to the queen substrate 110, and thermally compressed between a pair of upper and lower thermal presses 130 and 132. Although the conditions of the thermal press are varied depending on the material and the thickness of the resin substrate 110, a temperature of the thermal press in the vicinity is generally established. of the melting temperature of a resin, specifically is suitable from about 90 ° C to 180 ° C. In particular, it is preferable that the temperature on the side of the electric mold be set from 120 ° C to 140 ° C, and that a resin substrate temperature of about 40 ° C to 80 ° C be established in a thermal press machine .
Suitably the pressure of the thermal press is set at from about 20 to 100 ilograms / cm2. Moreover, it is preferable that the time required for the thermal press be established in about 10 to 180 seconds. Before the thermal compression of the resin substrate 110, a pre-heating is performed, in such a way that the time required for thermal compression can be reduced, and productivity can be improved. It is preferable that the preheat temperature is set at about 40 ° C to 80 ° C. If this pre-heating treatment is carried out, the time required for thermal compression can be reduced to approximately 10 to 30 seconds. Moreover, the electric mold 120 can be bonded to a thermal press head during thermal compression.
Accordingly, the resin substrate 110 and the electrical mold 120 can be easily removed from each other after thermal compression, so that productivity can be improved. Through thermal compression, the molded pattern 122 of the electric mold 120 is transferred to the resin substrate 110, and the electric mold 120 is removed. Accordingly, a resin substrate 110 having a pattern can be obtained. In addition, it is also possible to manufacture a transparent resin film having a pattern on both surfaces, thermally compressing the pattern surface of the electrical mold 120 against both surfaces of the resin substrate 110 at the same time or in a successive manner. In the case where thermal compression is to be performed on both surfaces at the same time, it is preferable that the electrical mold 120 be attached to the upper and lower heads of the thermal press. In the case where the thermal compression is going to be carried out in a successive manner on both surfaces, moreover, it is preferable that the thermal press works on one of the surfaces, then the resin substrate 110 is turned over, and the thermal press works on the other surface. The resin substrate 110 having a pattern is manufactured in an independent manner, one by one, in the method of manufacturing the resin substrate 110 having a pattern described above. However, it is also possible to obtain a resin substrate 110 having a pattern by producing the electric mold 120 having a plurality of patterns, thermally compressing the electric mold 120 against a plastic film, producing the resin substrate 110 having a plurality of pattern portions, and cutting the shape of a visual display board for each pattern. The resin substrate 110 having a pattern, thus constituted, is stacked in a state of close contact on the upper surface of the circular polarization plate A constituted by the linear polarization plate 101 and the plate of 1/4? 103. Alternatively, the resin substrate 110 is integrated via bonding using an adhesive, bond using an adhesive, film bond, fusion bond, high frequency bond or the like, for example. A pattern can be transferred to the resin substrate 110 before or after the bonding of the resin substrate 110 and the circular polarization plate A. After that the molded pattern of the electrical mold 120 is transferred in this way to the resin substrate 100 by the thermal press, the transfer of the pattern to the resin substrate 110 and the integration with the circular polarization plate A can also be performed simultaneously by using the thermal press, as shown in Figure 17, instead of stacking the substrate. resin 110 on the upper surface of the circular polarization plate A constituted by the linear polarization plate 101 and the plate of 1/4? 103, or integrating the resin substrate 110 with it. In a more specific way, as shown in the Figure 17, the circular polarization plate A constituted by the linear polarization plate 101 and the plate of l / 4? 103, the resin substrate 110 and the electrical mold 120, are provided between the pair of upper and lower thermal presses 130 and 132 in order. Then, the pattern 122 of the electric mold 120 is transferred to the upper surface of the resin substrate 110 by thermal compression at one time, and the resin substrate 110 is welded and integrated with the circular polarization plate A by heating the thermal press. In this case, it is desirable that an adhesive be interposed between the resin substrate 110 and the circular polarization plate A, because the integration can be easily performed, which is not shown. By this method, the pattern 122 of the electric mold 120 is transferred to the upper surface of the resin substrate 110 through the thermal compression at one time, and the resin substrate 110 is integrated with the circular polarization plate A by means of the heating of the thermal press. Therefore, work efficiency can be greatly improved. With this structure, the boundary line between the solar cell 102 and the middle frame 106, the gate track generated by injection molding of the middle frame 106, and in addition, the dividing line of the solar cell element of the cell can not be seen. solar 102 even more than in the fourth modality. As a result, the variation in the design of the solar visual display board 108 can be further increased. Additionally, patterns of cloth, paper, slit, grain, pyroxene, leaf, petal, shell, leather and different fine patterns are transferred as the portion of pattern 112 of the resin substrate 110 to the upper surface of the solar visual display board 108. Accordingly, the high quality feel of the solar visual display board 108 can be produced. In addition, it is possible to increase the variation in the design , where the decorative properties are greater, and the depth of the pattern and the three-dimensional effect is excellent. Therefore, the high quality feeling of the articles can be produced. Moreover, the middle frame is provided. Accordingly, different external shapes of the watch can be obtained with respect to the design.
(Fourteenth Modality) As shown in Figure 18, in a clock structure 140 according to the present embodiment, a solar cell 142 and a module 144 are fixed through an intermediate frame 146 to an external box, which does not it is displayed, in the same way as in the thirteenth modality. A circular polarization plate A consisting of a linear polarization plate 141 and a plate of 1/4"is provided. 143 above the median frame 146. In addition, a solar visual display board 148 is provided thereon. The solar visual display board 148 in accordance with the present embodiment includes a resin substrate 150 having a pattern, and a member of thin decorative film 152. Because the material and manufacturing method for the resin substrate 150 having a pattern are the same as those of the thirteenth embodiment, its detailed description will be omitted. The thin decorative film member 152 is not particularly restricted, but may be any of different film layer articles having a pattern, color or the like. Examples of the thin decorative film member 152 include a thin-film article formed of a natural material, such as cloth, paper, a sliced shell or a wood, a ceramic sheet, a polarizing film, a colored film, a electroforming sheet, an electrodeposited image, a recorded metal sheet (recorded image), a film in which a hologram (a hologram image) and the like are printed. The thickness of the thin decorative film member 152 is preferably about 5 to 300 microns, and more preferably about 10 to 200 microns. The resin substrate 150 is bonded to the thin decorative film member 152 by, for example, adhesion using an adhesive, bond using a glue, film bond, fusion bond, high frequency bond, or the like. In this case, the entire thickness of the visual display board 148, including the resin substrate 150 and the thin decorative film member 152, is not particularly restricted, but is preferably from 60 to 800 microns, and more preferably from 300 to 300 microns. 500 microns. Moreover, in the visual display board according to the present invention, it is desirable that light transmission (the range of visible light or wavelength: 600 nanometers) be 10 percent or more, preferably 20 percent. one hundred or more, and more preferably 30 percent or more, by an appropriate selection of material and thickness. Preferably, a visual display board having a light transmission such as a watch face of a type of solar charge pulse that has rece been extended on the market may be used. This is the same as in the following modalities. With this structure, the boundary line between the solar cell 142 and the middle frame 146 can not be seen, the gate track generated by injection molding of the middle frame 146, and in addition, the dividing line of the solar cell element of the cell solar 142, even more than in the fourth modality. As a result, the variation in the design of the solar visual display board 148 can be further increased.
In addition, a decoration that is present on the upper surface of the solar visual display board 148, such as a cloth, a paper, a slit, a grain, a pyroxene, a leaf, a petal, a shell, a leather and different patterns transferred ends, to be the pattern portion 152 of the resin substrate 150, and a decoration that is present thereunder, for example, a thin layer article formed of a natural material, such as cloth, paper, shell or wood , of the thin decorative film member 152, a polarization film, a color film, an electroforming sheet, or an electrodeposited image, produce a decorative property. Therefore, you can implement the design that has a three-dimensional effect and a feeling of high quality. As a result, the high quality feel of the solar visual display board 148 can be produced. In addition, it is possible to increase the variation in the design, where the decorative property is large, and the depth of the pattern and the three-dimensional effect are excellent . Therefore, the high quality feeling of the articles can be produced. Moreover, the middle frame is provided. Accordingly, different external shapes of the watch can be obtained with respect to the design.
(Dec. aquinta Modality) As shown in Figure 19, in the clock structure 160 according to the present embodiment, a solar cell 162 and a module 164 are fixed through an average frame 166 to an external box, which it is not shown, in the same way as in the thirteenth modality. A circular polarization plate A consisting of a linear polarization plate 161 and a plate of 1/4"is provided. 163 above the middle frame 166. In addition, on them, a solar visual display board is provided 168. The solar visual display board 168 in accordance with the present embodiment has a first resin substrate 170, a thin decorative film member 172, and a second resin substrate 174, provided in this order. The first resin substrate 170 and the second resin substrate 174 are formed of the same material as that of the resin substrate 110 of the visual display board 108 in accordance with the thirteenth embodiment. In the solar visual display board 168 in accordance with the present embodiment, it is not necessary to form a pattern on the first resin substrate 170 and the second resin substrate 174. However, the pattern can be formed on either or both of them in the same manner as in the resin substrate 110 of the visual display board 108 in accordance with the thirteenth embodiment. In this case, the same method as that described in the thirteenth embodiment can be used to form the pattern, and preferably, a pattern transfer method using a thermal press can be employed by means of a pattern mold. Moreover, the thin decorative film member 172 is the same as the thin decorative film member 152 in accordance with the fourteenth embodiment. Additionally, it is desirable that the thin decorative film member 172 be provided between the first resin substrate 170 and the second resin substrate 174, through one of adhesion using an adhesive, bond using a glue, film bond, bond using an adhesive, fusion bond, and high frequency bond, in consideration of mechanical strength, removal property and transmission. The thickness of the first resin substrate 170 in the solar display panel 168 is preferably 50 to 500 microns, and more preferably 80 to 200 microns. The thickness of the thin decorative film member 172 is preferably 5 to 300 microns, and more preferably 10 to 200 microns. The thickness of the second resin substrate 174 is preferably 50 to 500 microns, and more preferably 80 to 200 microns. The total thickness of the solar display panel 168, including the resin substrates 170 and 174 and the thin decorative film member 172, is not particularly restricted, but is preferably 110 to 1300 microns, and more preferably 300 to 500 microns. With this structure, the boundary line between the solar cell 162 and the middle frame 166, the gate track generated by injection molding of the middle frame 166, and also the dividing line of the solar cell element of the solar cell can not be seen 162 even more than in the fourth modality. As a result, the variation in the design of the solar visual display board 168 can be further increased. In addition, a decoration that is present on the upper or lower surface of the solar visual display board 168, such as a cloth, a paper, a slit, a grain, a pyroxene, a leaf, a petal, a shell, a leather, and different fine patterns transferred to be the pattern portion of the first resin substrate 170 or the second resin substrate 174, and a decoration that is present to half thereof, for example, a thin layer article formed of a natural material, such as cloth, paper, shell or wood, of the thin decorative film member 172, a polarization film, a color film, an electroforming sheet, or an electrodeposited image, produce a decorative property. As a result, you can get a design that has a three-dimensional effect and a high-quality feel. As a result, the high quality feel of the solar visual display board 168 can be produced. In addition, it is possible to increase the variation in design where the pattern depth and the three-dimensional effect are excellent. Therefore, the feeling of high quality in the articles can be produced. Moreover, the middle frame is provided. Accordingly, different external shapes of the watch can be obtained with respect to the design.
(Sixteenth Modality) As shown in Figure 20, in a clock structure 180 according to the present embodiment, a solar cell 182 and a module 184 are fixed through an average frame 186 to an external box, which does not it is displayed, in the same way as in the thirteenth modality. A circular polarization plate A is provided consisting of a linear polarization plate 181 and a plate of 1/4? 183 above the middle frame 186. In addition, there is provided on them a solar visual display board 188. The solar visual display board 188 in accordance with the present embodiment, has an inorganic substrate 190 having a pattern, and a member of thin decorative film 192 fixed to the inorganic substrate. The inorganic substrate 190 is formed of glass, sapphire crystal or ceramic plate, and preferably glass or sapphire crystal. The inorganic substrate 190 may be transparent or may be colored and translucent. A pattern is formed on the inorganic substrate 190 by machining, such as recording or rubbing, using hydrofluoric acid etching, using the electric forming method and the pattern transfer method a thermal press described in the thirteenth embodiment or the like. Moreover, the thin decorative film member 192 may be the same as the thin decorative film member 192 in accordance with the fourteenth embodiment. The thickness of the inorganic substrate 190 in the solar display panel 188 is preferably 50 to 500 microns, and more preferably 200 to 300 microns. The thickness of the thin decorative film member 192 is preferably from 5 to 300 microns, and more preferably from 10 to 200 microns. The total thickness of the solar display board 188, including the inorganic substrates 190 and the thin decorative film member 192, is not particularly restricted, but is preferably 60 to 800 microns, and more preferably 300 to 600 microns.
In this case, it is desirable that the inorganic substrate 190 and the thin decorative film member 192 be fixed by one of adhesion using an adhesive, bonding using an adhesive, bonding film, bonding using an adhesive, melting bond, and bonding. high frequency, in consideration of mechanical strength, removal property and transmission. With this structure, the boundary line between the solar cell 182 and the middle frame 186, the gate track generated by injection molding of the middle frame 186, and in addition, the dividing line of the solar cell element of the cell can not be seen. solar 182 even more than in the fourth modality. As a result, the variation in the design of the solar visual display board 188 can be further increased. Additionally, the pattern portion of the inorganic substrate 190 present on the upper surface of the solar visual display board 188, and the decoration that is present below. thereon, for example, a thin layer article formed of a natural material, such as cloth, paper, shell or wood, of the thin decorative film member 192, a polarization film, a color film, an electroforming sheet , or an electrodeposited image, produce a decorative property. Therefore, a design that has a three-dimensional effect and a high-quality feel can be implemented. Consequently, the high quality feel of the solar visual display board 188 can be produced. In addition, it is possible to increase the variation in design where the decorative property is large, and the depth of the pattern and the three-dimensional effect are excellent. Therefore, the high quality feeling of the articles can be produced. Moreover, the middle frame is provided. Accordingly, different external shapes of the watch can be obtained with respect to the design.
(Seventeenth Mode) As shown in Figure 21, in the clock structure 200 according to the present embodiment, a solar cell 202 and a module 204 are fixed through a medium frame 206 to an external box, which is not shown, in the same way as in the thirteenth mode. A circular polarization plate A is provided consisting of a linear polarization plate 201 and a plate of l / 4? 203 above the middle frame 206. In addition, a solar visual display board is provided on top of them. 208. The solar visual display board 208 according to the present embodiment is constituted by the stacking of an inorganic substrate 210 and a resin substrate 212. In this case, the materials of the inorganic substrate 210 and the resin substrate 212 are the same as those of the inorganic substrate 190 in accordance with the sixteenth embodiment, and the resin substrate 110 in accordance with the thirteenth embodiment, respectively. In the solar visual display board 208, it is not necessary to form a pattern on the inorganic substrate 210, and the resin substrate 212 and the pattern can be formed on either or both of them. In particular, it is preferable that the pattern is formed on the resin substrate 212, by using a pattern transfer method. The thickness of the inorganic substrate 210 in the solar display panel 208 is preferably 50 to 500 microns, and more preferably 200 to 300 microns. The thickness of the resin substrate 212 is preferably 50 to 500 microns, and more preferably 100 to 200 microns. The entire thickness of the solar display board 208, including the inorganic substrate 210 and the resin substrate 212, is not particularly restricted, but is preferably 100 to 1000 microns, and more preferably 300 to 600 microns. It is desirable that the resin substrate 212 and the inorganic substrate 210 be fixed through one of adhesion using an adhesive, bonding using an adhesive, bonding film, bonding using an adhesive, melting bond, and high frequency bond, in consideration of mechanical strength, removal property and transmission. With this structure, the boundary line between the solar cell 202 and the middle frame 206 can not be seen, the gate track generated by injection molding of the middle frame 206, and in addition, the dividing line of the solar cell element of the cell solar 202 even more than in the fourth modality. As a result, the variation in the design of the solar visual display board 208 can be further increased. Additionally, the pattern portion of the inorganic substrate 210 present on the upper surface of the solar visual display board 208, and the decoration that is present below. thereof, and that is the pattern portion of the resin substrate 212, such as cloth, paper, slit, grain, pyroxene, sheet, petal, shell, leather and different fine patterns transferred, produce a decorative property. As a result, a design that has a three-dimensional effect and a high-quality feel can be implemented. As a result, the high-quality feel of the solar display 208 board can be produced. In addition, it is possible to increase the variation in design where the decorative property is large and the depth of the pattern and the three-dimensional effect are excellent. Therefore, the high quality feeling of the articles can be produced. Moreover, the middle frame is provided. Accordingly, different external shapes of the watch can be obtained with respect to the design.
(Tenth-eighth Modality) As shown in Figure 22, in a clock structure 220 according to the present embodiment, it is fixed in a solar cell 222 and a module 224 through an intermediate frame 226 to an external box, which is not shown, in the same way as in the thirteenth modality. A circular polarization plate A is provided consisting of a linear polarization plate 221 and a plate of 1/4? 223 above the middle frame 226. Furthermore, a solar visual display board 228 is provided thereon. The solar visual display board 228 according to the present embodiment is formed only of the inorganic substrate 230. In this caseit is desirable that the material of the inorganic substrate 230 be the same as that of the inorganic substrate 190 in accordance with the sixteenth embodiment, and should be colored with a pigment or a dye. In the solar visual display board 228, moreover, it is not necessary to form a pattern on the inorganic substrate 203, but it is preferably formed. The total thickness of the visual display board 228 is not particularly restricted, but is preferably 100 to 1000 microns, and more preferably 300 to 600 microns. With this structure, the boundary line between the solar cell 222 and the middle frame 226 can not be seen, the gate track generated by injection molding of the middle frame 226, and in addition, the dividing line of the solar cell element of the cell solar 222 even more than in the fourth modality. As a result, the variation in the design of the solar visual display board 228 can be further increased. Additionally, a decoration of the pattern portion of the inorganic substrate 230 present on the upper surface of the solar visual display board 228, produces a decorative property , so that you can implement a design that has a three-dimensional effect and a feeling of high quality. Accordingly, the high quality feel of the solar visual display board 228 can be produced. In addition, it is possible to increase the variation in the design where the decorative property is large and the depth of the pattern and the three-dimensional effect are excellent. Therefore, the feeling of high quality in the articles can be produced. Moreover, the middle frame is provided. Accordingly, different external shapes of the watch can be obtained with respect to the design.
(Nineteenth Modality) As shown in Figure 23, in a clock structure 240 according to the present embodiment, a solar cell 242 and a module 244 are fixed through an average frame 246 to an external box, which does not it is displayed, in the same way as in the thirteenth modality. A circular polarization plate A consisting of a linear polarization plate 241 and a plate of 1/4"is provided. 243 above the middle frame 246. In addition, a solar visual display board 248 is provided thereon. The solar visual display board 248 in accordance with the present embodiment is formed by stacking a first inorganic substrate 250, a decorative film member. thin 252, and a second inorganic substrate 254. The first inorganic substrate 250 and the second inorganic substrate 254 may be equal to the inorganic substrate 190 in accordance with the sixteenth embodiment. In the solar visual display board 248, it is not necessary to form a pattern on the first inorganic substrate 250 and the second inorganic substrate 254, but desirably it is formed on either or both of them. Moreover, the thin decorative film member 252 may be the same as the thin decorative film member 152 in accordance with the fourteenth embodiment. The thickness of the first inorganic substrate 250 in the solar visual display board 248 is preferably 50 to 500 microns, and more preferably 200 to 300 microns. The thickness of the thin decorative film member 252 is preferably 5 to 300 microns, and more preferably 10 to 200 microns. The thickness of the second inorganic substrate 254 is preferably 50 to 500 microns, and more preferably 200 to 300 microns. The total thickness of the solar visual display board 248, including the inorganic substrates 250 and 254 and the thin decorative film member 252, is not particularly restricted, but is preferably 110 1300 microns, and more preferably 300 to 600 microns. It is desirable that the thin decorative film member 252 be fixed between the first inorganic substrate 250 and the second inorganic substrate 254 by one of adhesion using an adhesive, film bond, bond using an adhesive, fusion bond, and high frequency bonding. , in consideration of mechanical strength, removal property and transmission. With this structure, the boundary line between the solar cell 242 and the middle frame 246 can not be seen, the gate track generated by injection molding of the middle frame 246, and in addition, the dividing line of the solar cell element of the cell solar 242 even more than in the fourth modality. As a result, the variation in the design of the solar visual display board 248 can be further increased. Additionally, a decoration of the pattern portions of the inorganic substrates 250 and 254 that are present on the upper and lower surfaces of the visual display board 248, and a decoration that is present at half thereof, for example, a thin-film article formed of a natural material, such as cloth, paper, shell or wood, a polarizing film, a colored film, an electroformation sheet, or an electrodeposited image on the thin decorative film member 252, produces a decorative property. As a result, a design that has a three-dimensional effect and a high-quality feel can be implemented. Accordingly, the high quality feel of the solar visual display board 248 can be produced. In addition, it is possible to increase the variation in design where the decorative property is large, and the depth of the pattern and the three-dimensional effect are excellent. Therefore, the high quality feeling of the articles can be produced. Moreover, the middle frame is provided. Accordingly, different external shapes of the watch can be obtained with respect to the design.
(Twentieth Modality) As shown in Figure 24, in a clock structure 260 in accordance with the present embodiment, a solar cell 262 and a module 264 are fixed through an intermediate frame 266 to an external box, which does not it is displayed, in the same way as in the thirteenth modality. A circular polarization plate A consisting of a linear polarization plate 261 and a plate of 1/4"is provided. 263 above the middle frame 266. Furthermore, on top of them, a solar visual display board 268 is provided. The solar visual display board 268 in accordance with the present embodiment, is constituted by stacking a resin substrate 270, a thin decorative film member 272, and an inorganic substrate 274, in this order. In this case, the resin substrate 270, the thin decorative film member 272, and the inorganic substrate 274 may be the same as the resin substrate 110 in accordance with the thirteenth embodiment, the thin decorative film member 152 in accordance with fourteenth embodiment, and the inorganic substrate 190 in accordance with the sixteenth modality, respectively. Moreover, it is not necessary to form a pattern on the resin substrate 270, and the inorganic substrate 274, but desirably is formed on either or both of them. In this case, one or more resin substrates, thin decorative film members, and inorganic substrates may be used, and may have three or more layers, respectively. Moreover, the stack order of the resin substrate, the thin decorative film member and the inorganic substrate is not particularly restricted. Additionally, two or more kinds of resin substrates can be used. In a similar manner, two or more kinds of thin decorative film members and inorganic substrates, respectively, may be used. This solar visual display board 268 has the following preferred layer structures, including the structure shown in Figure 24: (1) resin substrate / thin decorative film member / resin substrate / inorganic substrate, (2) resin substrate / thin decorative film member / inorganic substrate / resin substrate, (3) thin decorative film member / inorganic substrate / resin substrate, and (4) inorganic substrate / thin decorative film member / inorganic substrate / resin substrate. In this case, the thickness of the resin substrate is preferably 50 to 500 microns, and more preferably 80 to 200 microns per layer. The thickness of the thin decorative film member is preferably 5 to 300 microns, and more preferably 10 to 200 microns per layer. The thickness of the inorganic substrate is preferably 50 to 500 microns, and more preferably 200 to 300 microns per layer. The total thickness of the solar visual display board 268, including the resin substrate, the thin decorative film member, and the inorganic substrate, is not particularly restricted, but is preferably 110 to 1300 microns, and more preferably 300 to 300 microns. 600 micras With this structure, the boundary line between the solar cell 262 and the middle frame 266 can not be seen, the gate track generated by injection molding of the middle frame 266, and in addition, the dividing line of the solar cell element of the cell solar 262, still more than in the fourth modality. Accordingly, variation in the design of the visual display board 268 can be further increased. Additionally, a decoration, such as a cloth, a paper, a slit, a grain, a pyroxene, a leaf, a petal, a shell, a leather and different fine patterns transferred to be the pattern portion of the resin substrate 270, a decoration of the pattern portion of the inorganic substrate 274, and a decoration of the thin decorative film member 272, such as a thin layer article formed of a natural materialfor example, a cloth, a paper, a shell or a wood, a polarization film, a colored film, an electroforming sheet or an electrodeposited image produce a decorative property. As a result, a design that has a three-dimensional effect and a high-quality feel can be implemented. As a result, the high-quality feel of the solar visual display board 248 can be produced. In addition, it is possible to increase the variation in design where the decorative property is large and the depth of the pattern and the three-dimensional effect are excellent. Therefore, the high quality feeling of the articles can be produced. Moreover, the middle frame is provided. Accordingly, different external shapes of the watch can be obtained with respect to the design.
(Vigesi first Modality) As shown in Figure 25, in a clock structure 280 according to the present embodiment, a solar cell 282 and a module 284 are fixed through a medium frame 286 to an external box, which is not shown, in the same way as in the thirteenth mode. A circular polarization plate A consisting of a linear polarization plate 281 and a plate of 1/4"is provided. 283 above the middle frame 286. Furthermore, a solar visual display board 288 is provided on top of them. The visual display board 288 according to the present embodiment is constituted by a metal plate 290. The metal plate 290 has a portion of window 292 of a visual display section formed in its central part through machining, such as drilling, and a pattern 294 is formed on its surface. Although the metal plate 290 is not particularly restricted to a metal, for example, phosphor bronze, titanium, stainless steel, such as SUS 304, a copper alloy, such as brass, nickel, silver or the like can be used. As a method for forming a pattern on the surface of the metal plate 290, a pattern forming method can be used to form a pattern through a press using a pattern mold and a machining method using recording, rubbing or the like . For the metal plate 290, it is also possible to use a thin metal film having a pattern shape which is obtained by forming a pattern on a metal substrate through a photoresist, plating the pattern with a metal, forming a thin metallic layer of pattern, coating of an adhesive on the surface of the thin metallic film layer, and removing the metal substrate. It is desirable that the metal plate 290 be fixed to the upper surface of the circular polarization plate A by bonding using a glue, film bond, bond using an adhesive or the like, in consideration of the mechanical strength, the removal property, and the broadcast. With this structure, the boundary line between the solar cell 282 and the middle frame 286 can not be seen, the gate track generated by injection molding of the middle frame 286, and in addition, the dividing line of the solar cell element of the cell solar 282 even more than in the fourth embodiment, in such a way that the variation in the design of the solar visual display board 288 can be further increased. Additionally, the decorative property of the metal plate 290 that is present on the upper surface of the board Solar Visual Display 288 can implement the design that has a three-dimensional effect and a feeling of high quality. As a result, the high-quality feel of the solar visual display board 288 can be produced. In addition, it is possible to increase the variation in design where the decorative property is large and the depth of the pattern and the three-dimensional effect are excellent. Therefore, the high quality feeling of the articles can be produced. Moreover, the middle frame is provided. Accordingly, different external shapes of the watch can be obtained with respect to the design. An auxiliary member formed of a transparent resin, such as polycarbonate, may also be provided between the solar visual display board according to each of the thirteenth to twenty-first modalities, and the circular polarization plate A, to adjust a portion between the circular polarization plate A and the solar visual display board to the thickness of an external box, which is not shown. Moreover, on the surface of the solar visual display board according to the embodiment of the present invention, a visual display portion (a clock time scale), the name of the manufacturer can be provided., the type and the like, which can be exhibited by means of printing or a decorative member (a letter of the hour, a mark or the like) to be manufactured by electroforming and fixed with an adhesive. In addition, although the description has been given only for the clock in the aforementioned embodiments, the present invention is not restricted thereto, but the same effects can be obtained, that is, the variation in the design can be increased, through of the use of other electronic devices having a solar cell, for example, an electronic calculator, a radio, a battery charger or the like. Accordingly, different changes can be made without departing from the scope of the present invention.
Effects of the Invention In accordance with the present invention, there is provided a circular polarization plate constituted by the linear polarization plate and at least one phase difference plate between the middle frame for fixing the module having the solar cell to the box , and the solar visual display board. Consequently, the boundary line between the solar cell and the middle frame, the gate track generated by injection molding of the middle frame, and in addition, the dividing line of the solar cell element of the solar cell can not be seen. As a result, the variation in the design of the solar visual display board can be increased. Moreover, the color of the solar visual display board is deepened, in such a way that a high quality feeling can be obtained in the articles. According to the present invention, furthermore, the surface of the circular polarization plate is provided with a solar visual display board constituted by a resin substrate having a pattern, an inorganic substrate having a pattern or a decorative film member thin, or a combination thereof. Therefore, the decorative property is large, the pattern becomes rich, and an excellent three-dimensional effect can be obtained. By a combination of two or more patterns or two or more materials, moreover, it is possible to manufacture a visual display board that has a better feeling of beauty than ever before. Therefore, the variation of the design can be increased.

Claims (31)

1. A visual display device for an electronic device, which comprises a solar cell, wherein a circular polarization plate is provided to transmit light on the front side of the solar cell in a direction of incidence of light.
2. The visual display device for an electronic device, which comprises a solar cell, according to claim 1, which further comprises a solar cell visual display board for transmitting light in addition to the solar cell, providing the circular polarization plate to transmit light between the solar cell and the solar visual display board.
The visual display device for an electronic device, comprising a solar cell, according to claim 2, wherein the solar cell, the solar cell visual display board and the circular polarization board have identical external shapes.
4. A visual display device for an electronic device comprising a solar cell and a middle frame for fixing a module having the solar cell to a box, a circular polarization plate being provided for transmitting light on the front side of the middle frame and the solar cell in a direction of incidence of light.
5. The visual display device for an electronic device comprising a solar cell, according to claim 4, further comprising a visual display board of a solar cell for transmitting light, the circular polarization plate being provided to transmit light between the board of visual display of solar cell and the middle frame.
The visual display device for an electronic apparatus comprising a solar cell, according to claim 5, wherein the solar cell visual display board, the middle frame and the circular polarization board have identical external shapes.
The visual display device for an electronic apparatus comprising a solar cell, according to any of claims 1 to 6, wherein the circular polarization plate comprises a linear polarization plate and a phase difference plate.
8. The visual display device for an electronic device comprising a solar cell, according to claim 7, wherein the circular polarization plate is placed on an external box in a planar direction.
9. The visual display device for an electronic device comprising a solar cell, according to claim 7, wherein an adhesive layer is formed over any of the boundaries between the solar visual display board and the linear polarization board , between the linear polarization plate and the phase difference plate, and between the phase difference plate and the solar cell or the middle frame.
The visual display device for an electronic apparatus comprising a solar cell, according to claim 7, wherein a diffusion layer is formed over any of the boundaries between the solar visual display board and the linear polarization board , between the linear polarization plate and the phase difference plate, and between the phase difference plate and the solar cell or the middle frame.
The visual display device for an electronic apparatus comprising a solar cell, according to claim 7, wherein the linear polarization plate transmits a linearly polarized component flipped in a constant direction, and absorbs a linear polarization component in a direction orthogonal to it.
The visual display device for an electronic apparatus comprising a solar cell, according to claim 7, wherein the linear polarization plate transmits a linear polarization component flipped in a constant direction, and reflects a linear polarization component in a direction orthogonal to it.
13. The visual display device for an electronic device comprising a solar cell, according to any of claims 9 to 12, wherein the phase difference plate is formed of a plate of l / 4 ?, or of the plate l / 4? and a plate of l / 2 ?.
14. The visual display device for an electronic apparatus comprising a solar cell, according to claim 13, wherein the circular polarization plate is provided with the linear polarization plate and the plate of 1/4? in this order, in the direction of incidence of light.
15. The visual display device for an electronic device comprising a solar cell, according to claim 14, wherein the circular polarization plate is provided between a hand and the solar cell.
16. The visual display device for an electronic apparatus comprising a solar cell, according to claim 14, wherein the circular polarization plate is provided between a liquid crystal panel and the solar cell.
17. The visual display device for an electronic device comprising a solar cell, according to any of claims 1 to 16, wherein the solar visual display board includes a resin substrate having a pattern.
18. The visual display device for an electronic device comprising a solar cell, according to claim 17, wherein the solar visual display board includes a resin substrate having a pattern, and a thin decorative film member attached to the substrate of resin.
The visual display device for an electronic apparatus comprising a solar cell, according to any of claims 1 to 16, wherein the solar visual display board has a first resin substrate, a thin decorative film member, and a second resin substrate provided therein.
The visual display device for an electronic apparatus comprising a solar cell, according to any of claims 1 to 16, wherein the solar visual display board includes an inorganic substrate having a pattern selected from glass, Sapphire crystal and ceramic plate.
The visual display device for an electronic apparatus comprising a solar cell, according to claim 20, wherein the solar visual display board includes an inorganic substrate having a pattern selected from glass, sapphire crystal and ceramic plate, and a thin decorative film member fixed to the inorganic substrate.
22. The visual display device for an electronic device comprising a solar cell, according to claim 20, wherein the solar visual display board is provided with an inorganic substrate selected from glass, sapphire crystal and ceramic plate and a resin substrate.
The visual display device for an electronic apparatus comprising a solar cell, according to any of claims 1 to 16, wherein the solar visual display board is provided with a first inorganic substrate selected from glass, glass of sapphire and ceramic plate, a thin decorative film member, and a second inorganic substrate selected from glass, sapphire crystal and ceramic plate.
24. The visual display device for an electronic apparatus comprising a solar cell, according to any of claims 16, wherein the solar visual display board utilizes one or more of a resin substrate, a decorative film member thin, and an inorganic substrate selected from glass, sapphire crystal and ceramic plate, in three or more layers.
25. The visual display device for an electronic device comprising a solar cell, according to any of claims 18, 19, 21, 23 and 24, wherein the thin decorative film member is a thin film article formed of a natural material, such as a cloth, a paper, a shell or a wood, a ceramic sheet, a film of polarization, a color film, an electroforming sheet, an electrodeposited image, a recorded image or a hologram image.
26. The visual display device for an electronic apparatus comprising a solar cell, according to any of claims 19 and 22 to 24, wherein a pattern is given to the resin substrate or the inorganic substrate.
27. The visual display device for an electronic device comprising a solar cell, according to any of claims 17 to 24, wherein the resin substrate or the inorganic substrate is a transparent or translucent colored substrate.
28. The visual display device for an electronic apparatus comprising a solar cell, according to any of claims 1 to 16, wherein the solar visual display board has a pattern, and includes a metal layer having a portion of open window.
29. A method for manufacturing a visual display device for an electronic apparatus comprising a solar cell according to any of claims 17 to 25, wherein the resin substrate or the inorganic substrate is integrally bonded with the circular polarization plate. through a thermal press when a pattern is to be transferred by a pattern transfer method through the thermal press using a pattern mold.
30. The method for manufacturing a visual display device for an electronic device according to claim 29, wherein the resin substrate or the inorganic substrate is bonded to the circular polarization plate with an adhesive interposed therebetween. The method for manufacturing a visual display device for an electronic device according to claim 29 or 30, wherein the pattern mold serves to mold a pattern of an article having the pattern, by utilizing a method of electrical training
MXPA/A/2001/007106A 1999-11-12 2001-07-12 Display device of electronic apparatus provided with solar cell MXPA01007106A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11-322329 1999-11-12

Publications (1)

Publication Number Publication Date
MXPA01007106A true MXPA01007106A (en) 2002-03-05

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