JP2010217054A - Method for manufacturing timepiece dial, dial for timepiece, and timepiece - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a dial for a timepiece which presents a glossy and superior external appearance, to provide a method for enabling manufacturing of the dial for the timepiece with proper productivity and suitably, and to provide the timepiece equipped with the dial for the timepiece. <P>SOLUTION: The method for manufacturing the dial 1 for the timepiece includes a composition adding process, wherein a composition which includes small pieces 31 having the function of reflecting light and is provided with a slit and a hardening resin 32 and has flowability is added onto a base 2; the small piece deforming process wherein at least a part of the small piece 31 is curved or bent; and a hardening process wherein the hardening resin 32 is hardened. It is preferable that the small piece 31 have a heat-shrinkable layer, constituted of a heat-shrinkable material and a metal layer 314 constituted of a metal material. The small piece deforming process is performed by heat treatment, and the small piece is preferably deformed so that a part of the small piece may project from a main part being a portion other than the part. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

  The present invention relates to a timepiece dial manufacturing method, a timepiece dial, and a timepiece.

A timepiece dial is required to be practical, such as visibility, and to have decorativeness (aesthetic appearance). Conventionally, as a timepiece dial, a metal plate processed or a plastic substrate coated or coated with metal has been used.
In general, a timepiece dial uses letters and numbers (so-called time letters, etc.), scales, symbols, and various marks having functions such as indicating time. As a method for forming such an index, a printing method or a method of attaching and fixing a planting material called “typesetting” is widely used.
On the other hand, there is a great demand for a timepiece dial having a more excellent aesthetic appearance and a timepiece dial having a novel appearance.

In addition, solar watches (watches equipped with solar cells) have been highly evaluated from the viewpoint of ease of maintenance, resource saving, and resource saving.
A dial for a solar timepiece (a timepiece provided with a solar cell) is required to have a function (light transmittance) that transmits a sufficient amount of light so that the solar cell generates a sufficient electromotive force. For this reason, conventionally, a highly transparent plastic member has been used as a dial for a solar timepiece. However, plastics generally lack a sense of quality and are inferior in aesthetic appearance compared to metal materials such as Au and Ag. For this reason, a dial plate obtained by sticking a metal film made of a metal material and provided with an opening portion on a plastic substrate via an adhesive has been proposed (for example, see Patent Document 1). ).

  However, with such a dial, it has been difficult to achieve both excellent light transmission and aesthetic appearance. That is, in order to ensure light transmittance, when the aperture ratio of the metal film (the ratio of the area occupied by the opening to the entire metal film when the metal film is viewed in plan) is relatively high, Even though the presence is conspicuous and a metal material (metal film) is used, a sufficiently excellent aesthetic appearance cannot be obtained. In solar timepieces, generally solar cells exhibiting a dark color such as black or dark purple are used, but when solar timepieces are provided with such solar cells, openings and openings in the metal film Differences in color tone and brightness from other parts (parts covered with a metal film) become conspicuous, and as a result, the presence of the opening becomes very conspicuous, and the timepiece dial when applied to a watch The aesthetic appearance is particularly inferior. On the other hand, when the aperture ratio of the metal film is lowered for the purpose of improving the aesthetic appearance, the light transmittance is lowered, and the power generation efficiency of the solar cell is significantly lowered. Moreover, the manufacturing method of the above dial plates is also inferior in productivity.

JP 11-326549 A (see page 3, right column, line 35 to page 4, left column, line 11)

  An object of the present invention is to provide a timepiece dial exhibiting a glossy and excellent appearance, to provide a production method capable of suitably producing the timepiece dial with high productivity, The object is to provide a timepiece having a timepiece dial.

Such an object is achieved by the present invention described below.
The method for producing a timepiece dial of the present invention has a function of reflecting light, including a small piece provided with a slit and a curable resin, and providing a composition having fluidity on a substrate. Process,
A small piece deformation step of bending or bending at least a part of the small piece;
A curing step of curing the curable resin.
Thereby, the manufacturing method which can manufacture suitably the timepiece dial which exhibits the outstanding external appearance with glossiness with sufficient productivity can be provided.

In the timepiece dial manufacturing method of the present invention, the small piece deformation step is preferably performed by heat treatment.
Thereby, at least a part of the small piece can be bent or bent easily and efficiently, and the productivity of the timepiece dial can be made particularly excellent.
In the timepiece dial manufacturing method of the present invention, it is preferable that the small piece has a heat-shrinkable layer made of a heat-shrinkable material.
Thereby, in the small piece deformation process, the small piece can be bent or bent more suitably, the productivity of the timepiece dial can be made particularly excellent, and the aesthetic appearance of the timepiece dial is particularly excellent. Can be.

In the method for manufacturing a timepiece dial according to the aspect of the invention, it is preferable that the small piece has a metal layer made of a metal material in addition to the heat shrinkable layer.
Thereby, in the small piece deformation process, the small piece can be bent or bent more suitably, the productivity of the timepiece dial can be made particularly excellent, and the aesthetic appearance of the timepiece dial is particularly excellent. (Exhibiting a very high-quality appearance).

In the timepiece dial manufacturing method of the present invention, the curable resin is a photocurable resin,
In the curing step, it is preferable to perform light irradiation treatment at a temperature higher than that in the small piece deformation step.
Thereby, the productivity of the timepiece dial can be made particularly excellent. In addition, it is possible to more reliably prevent deterioration of the constituent material of the timepiece dial during manufacture, and the reliability of the manufactured timepiece dial can be made particularly excellent.

In the method for manufacturing a timepiece dial of the present invention, the curable resin is a thermosetting resin,
In the curing step, it is preferable to perform heat treatment at a higher temperature than in the small piece deformation step.
Thereby, without requiring a large-scale apparatus and facility, the curing process can be smoothly performed following the small piece deformation process, and the productivity of the timepiece dial can be made particularly excellent.

In the timepiece dial manufacturing method of the present invention, the small piece is preferably provided with a plurality of intersecting slits.
Thereby, the productivity of the timepiece dial can be made particularly excellent, and the aesthetic appearance of the produced timepiece dial can be made particularly excellent.
In the timepiece dial manufacturing method of the present invention, it is preferable that, in the small piece deformation step, the small piece is deformed so that a part of the small piece protrudes from the main body portion which is the other part.
Thereby, the aesthetic appearance of the timepiece dial can be made particularly excellent.

The timepiece dial of the present invention is manufactured using the method of the present invention.
Thereby, it is possible to provide a timepiece dial having a glossy and excellent appearance.
The timepiece dial of the present invention preferably has a light transmittance of 20% or more.
Thereby, the timepiece dial can be suitably applied to a solar timepiece.
The timepiece of the present invention includes the timepiece dial of the present invention.
Thereby, it is possible to provide a timepiece including a timepiece dial having a glossy and excellent appearance. In addition, since the timepiece dial has a great influence on the appearance of the entire timepiece, the timepiece having the timepiece dial as described above has an excellent aesthetic appearance as a whole.

  According to the present invention, it is possible to provide a timepiece dial having a glossy and excellent appearance, to provide a manufacturing method capable of suitably producing the timepiece dial with high productivity, A timepiece having a timepiece dial can be provided.

It is sectional drawing which shows suitable embodiment of the timepiece dial of this invention. It is a figure which shows an example of the shape of the small piece contained in a dispersed phase, (a) is sectional drawing, (b) is a top view. It is sectional drawing which shows suitable embodiment of the manufacturing method of the timepiece dial of this invention. It is a figure which shows an example of the shape of the small piece contained in a composition, (a) is sectional drawing, (b) is a top view. It is sectional drawing which shows suitable embodiment of the timepiece (watch) of this invention. It is a figure which shows an example of the shape of the small piece contained in a composition, (a) is sectional drawing, (b) is a top view. It is a figure which shows an example of the shape of the small piece contained in a composition, (a) is sectional drawing, (b) is a top view. It is a figure which shows an example of the shape of the small piece contained in a dispersed phase, (a) is sectional drawing, (b) is a top view. It is a figure which shows an example of the shape of the small piece contained in a dispersed phase, (a) is sectional drawing, (b) is a top view.

DESCRIPTION OF EXEMPLARY EMBODIMENTS Hereinafter, preferred embodiments of the invention will be described with reference to the accompanying drawings. Note that the drawings referred to in this specification show part of the configuration in an emphasized manner, and do not accurately reflect actual dimensions and the like.
The method for producing a timepiece dial of the present invention, as will be described in detail later, has a function of reflecting light, includes a small piece provided with a slit, a curable resin, and a fluid composition. It has a composition application step applied on top, a small piece deformation step that curves or bends at least a part of the small piece, and a curing step that cures the curable resin. In the small piece deforming step, the small piece is deformed so that a part of the small piece protrudes from the main body which is the other part. Explained.

<Watch dial>
FIG. 1 is a cross-sectional view showing a preferred embodiment of a timepiece dial of the present invention, FIG. 2 is a view showing an example of the shape of a small piece contained in a dispersed phase, (a) is a cross-sectional view, b) is a plan view.
As shown in FIG. 1, the timepiece dial 1 of the present embodiment includes a substrate 2 and a dispersed phase 3 in which a plurality of small pieces (glossy small pieces) 31 having a function of reflecting light are dispersed. .
Usually, the timepiece dial 1 is used so that the upper side in FIG. 1 faces the observer side (outer surface side) and the lower side in FIG. It is. In the following description, the upper side in FIG. 1 is referred to as “upper side”, and the lower side in FIG. 1 is referred to as “lower side” (the same applies to FIG. 3).

[substrate]
The substrate 2 has a function of holding the dispersed phase 3 including the small pieces 31 as will be described in detail later, and forms the main part of the timepiece dial 1.
The substrate 2 may be made of any material, but is preferably light transmissive. Thereby, with the outstanding aesthetic appearance of the timepiece dial 1, it can be suitably applied to a solar timepiece dial (a dial provided in a timepiece equipped with a solar cell) that effectively uses excellent light transmittance. . In the present invention, “having light transmittance” means having a property of transmitting at least part of light in the visible light region (wavelength region of 380 to 780 nm), and preferably transmitting light in the visible light region. The rate is 50% or more, and more preferably the light transmittance in the visible light region is 60% or more. The light transmittance as described above is, for example, a white fluorescent lamp (manufactured by Toshiba Corporation, inspection fluorescent lamp FL20S-D65) as a light source, and a solar cell having the same shape as the measurement target substrate under 1000 lux ( Current value (B) when power is generated in the same state as described above, except that a substrate to be measured is placed on the light source side surface of the solar cell, relative to the current value (A) when power is generated by the solar cell) Ratio ((B / A) × 100 [%]) can be adopted. Further, the light transmittance of a timepiece dial described later can be obtained in the same manner as described above. Hereinafter, unless otherwise specified, in this specification, “light transmittance” refers to a value obtained under such conditions.

  Examples of the constituent material of the substrate 2 include various plastic materials and various glass materials, but the substrate 2 is preferably mainly composed of a plastic material. The plastic material is generally excellent in moldability (freedom of molding), and can be suitably applied to manufacture the timepiece dial 1 having various shapes. Further, if the substrate 2 is made of a plastic material, it is advantageous for reducing the manufacturing cost of the timepiece dial 1. In addition, since plastic materials are generally excellent in light (visible light) transmission and also in radio wave transmission, the timepiece dial 1 is assumed that the substrate 2 is made of a plastic material. Can be suitably applied to a radio timepiece as described later. In the following description, an example in which the substrate 2 is mainly composed of a plastic material will be mainly described. In the present invention, “mainly” means a component having the highest content among materials constituting the target portion (member), and the content is not particularly limited, but the target portion (member) It is preferable that it is 60 wt% or more of the material which comprises, More preferably, it is 80 wt% or more, It is further more preferable that it is 90 wt% or more.

  Examples of the plastic material constituting the substrate 2 include various thermoplastic resins, various thermosetting resins, and the like. For example, polycarbonate (PC), acrylonitrile-butadiene-styrene copolymer (ABS resin), polymethyl methacrylate (PMMA). ), Etc., polyolefin resins such as polyethylene (PE) and polypropylene (PP), polyester resins such as polyethylene terephthalate (PET), etc., or copolymers, blends, polymer alloys, etc. mainly comprising these. These can be used, and one or more of these can be used in combination (for example, as a blend resin, a polymer alloy, a laminate, etc.). In particular, the substrate 2 is preferably composed mainly of polycarbonate and / or acrylonitrile-butadiene-styrene copolymer. Thereby, especially the intensity | strength as the timepiece dial 1 whole can be made excellent. Further, since the degree of freedom of molding of the substrate 2 is increased (easiness of molding is improved), even the timepiece dial 1 having a more complicated shape can be easily and reliably manufactured. Further, when the substrate 2 is made of a material containing at least one selected from polycarbonate (PC) and acrylonitrile-butadiene-styrene copolymer (ABS resin), the substrate 2 and the dispersed phase 3 are in close contact with each other. The property can be made particularly excellent. Polycarbonate is relatively inexpensive among various plastic materials, and can contribute to further reduction in production cost of the timepiece dial 1. The ABS resin also has particularly excellent chemical resistance, and the durability of the timepiece dial 1 as a whole can be further improved.

  In addition, the board | substrate 2 may contain components other than the above. Examples of such components include plasticizers, antioxidants, colorants (including various color formers, fluorescent substances, phosphorescent substances, etc.), brighteners, fillers, and the like. For example, when the substrate 2 is made of a material containing a colorant, variations in the color of the timepiece dial 1 can be widened.

The substrate 2 may have a substantially uniform composition at each site, or may have a different composition depending on the site.
Further, the shape and size of the substrate 2 are not particularly limited, and are usually determined based on the shape and size of the timepiece dial 1 to be manufactured. In the illustrated configuration, the substrate (base material) 2 has a flat plate shape, but may have a curved plate shape, for example.

Although the average thickness of the board | substrate 2 is not specifically limited, It is preferable that it is 150-700 micrometers, It is more preferable that it is 200-600 micrometers, It is further more preferable that it is 250-500 micrometers. When the average thickness of the substrate 2 is a value within the above range, when the timepiece dial 1 is applied to a solar timepiece, the light transmission of the timepiece dial 1 is sufficiently high, It is possible to more effectively prevent the self color from being seen through, and to make the aesthetic appearance (luxury feeling) particularly excellent. Further, when the thickness of the substrate 2 is within the above range, the timepiece to which the timepiece dial 1 is applied is effectively prevented from being thickened while the timepiece dial 1 is mechanically mechanical. Strength, shape stability, etc. can be made sufficiently excellent.
The substrate 2 may be formed by any method. Examples of the method for forming the substrate 2 include compression molding, extrusion molding, injection molding, and stereolithography.

[Dispersed phase]
On the substrate 2, a dispersed phase (dispersing part) 3 in which a plurality of small pieces 31 having a function of reflecting light are dispersed in a dispersion medium 32 is provided.
As shown in FIG. 2, the small piece 31 included in the dispersed phase 3 includes a main body 311 having an opening 3111 and a protruding piece 312 protruding from the edge of the opening 3111.

As described above, the timepiece dial 1 includes the protruding phase 312 and the dispersed phase 3 in which the small pieces 31 having a function of reflecting light are dispersed. Thereby, the reflective surface of the small piece 31 having the function of reflecting light faces in various directions, and the aesthetic appearance of the timepiece dial 1 is excellent. More specifically, when the reflecting surface of the small piece 31 faces in various directions, the light irradiated on the timepiece dial 1 can be reflected in various directions, and gloss such as that of diamond or cut glass is exhibited. It will have a high-class appearance with a feeling (glitter). In addition, when the material that reflects light is simply arranged in a plane, the appearance differs significantly depending on the viewing direction (the visual angle dependency of the aesthetic appearance is large). By dispersing the provided small pieces 31 in the dispersed phase 3, it is possible to reduce the viewing angle dependency of the timepiece dial 1, and even when observed from various directions and various angles, it is stable. And an excellent aesthetic appearance. Further, by including the small piece 31 provided with the protruding piece 312, the adhesion between the small piece 31 and the dispersion medium 32 in the dispersed phase 3 can be made excellent. Thereby, the durability of the timepiece dial 1 can be made particularly excellent. Further, by including the small piece 31 provided with the protruding piece 312, even if the light transmission of the timepiece dial plate 1 as a whole is sufficiently high, the observer can receive the back of the timepiece dial plate 1. It is possible to effectively prevent the side from being recognized. More specifically, it is possible to reliably prevent the small pieces 31 from adhering to each other and aggregate in the dispersed phase 3, and to ensure a distance (gap) between the plurality of small pieces 31. In this case, the light can be efficiently reflected (the light can be repeatedly reflected between the plurality of small pieces 31), so that the state of the back side of the timepiece dial 1 can be prevented from being directly recognized. It is possible to efficiently emit incident light from the surface opposite to the incident surface while improving the aesthetic appearance of the timepiece dial 1, and to improve the light transmittance of the timepiece dial 1 as a whole. It can be high enough. Therefore, when the timepiece dial 1 is incorporated in a timepiece, the timepiece dial 1 is surely excellent in aesthetic appearance as a whole timepiece even when applied to a solar timepiece or the like in which a solar cell is arranged on the back side. It can be. For this reason, the timepiece dial 1 can be suitably applied to a solar timepiece.
Thus, the timepiece dial 1 including the small piece 31 provided with the protruding piece 312 can be preferably manufactured with high productivity by a method described in detail later.

  The average particle diameter of the small pieces 31 is preferably 35 to 210 μm, more preferably 50 to 200 μm, and further preferably 70 to 180 μm. When the average particle size of the small pieces 31 is a value within the above range, the aesthetic appearance of the timepiece dial 1 can be made particularly excellent while the light transmittance is sufficiently excellent. Further, the durability of the timepiece dial 1 can be made particularly excellent. In the present invention, the particle size of a small piece refers to the value of the diameter of a perfect circle having the same peripheral length as the peripheral length when the small piece is viewed in plan.

  The average thickness of the small pieces 31 (the average thickness of the main body portion 311) is preferably 8.5 to 36 μm, more preferably 11 to 32 μm, and still more preferably 16 to 29 μm. When the average thickness of the small pieces 31 is a value within the above range, the incident light can be efficiently reflected in the small pieces 31, and the aesthetic appearance of the timepiece dial 1 can be made particularly excellent. .

  And in this embodiment, the small piece 31 has the resin layer 313 comprised by the resin material (especially what the heat shrinkable material mentioned later thermally contracted), and the metal layer 314 comprised by the metal material. is there. With the small piece 31 having such a configuration, the adhesiveness between the small piece 31 and the dispersion medium 32 is particularly excellent, and the aesthetic appearance of the timepiece dial 1 is particularly excellent (an extremely superior luxury). It has a sensation of appearance).

The resin layer 313 only needs to be composed of a material including a resin material, and may include, for example, a colorant such as a pigment or a dye, or an additive such as an antioxidant or a plasticizer.
The average thickness of the resin layer 313 is preferably 7.8 to 35.9 μm, and more preferably 10.0 to 31.8 μm. Thereby, the aesthetic appearance and light transmittance of the timepiece dial 1 can be made particularly excellent while the productivity of the timepiece dial 1 is made particularly excellent.

  Examples of the metal material constituting the metal layer 314 include Fe, Cu, Zn, Ni, Mg, Cr, Mn, Mo, Nb, Al, V, Zr, Sn, Au, Pd, Pt, Ag, and the like. Among them, an alloy containing at least one kind (for example, bronze, brass, white or the like) can be mentioned, among which Cu, Al, Au, Pt, and Ag are preferable. Thereby, the aesthetic appearance of the timepiece dial 1 to be manufactured can be made particularly excellent.

  The average thickness of the metal layer 314 is preferably 0.01 to 4.8 μm, and more preferably 0.02 to 3.5 μm. When the average thickness of the metal layer 314 is within the above range, the metal constituting the metal layer 314 in the small piece 31 while effectively preventing the resin layer 313 from becoming relatively thin. The texture of the material can be fully exhibited. Thereby, the aesthetic appearance of the timepiece dial 1 can be made particularly excellent while the productivity of the timepiece dial 1 is made particularly excellent. Further, the light transmission of the timepiece dial 1 can be made particularly excellent.

  The content ratio of the small pieces 31 in the dispersed phase 3 is preferably 5 to 40 vol%, more preferably 7 to 35 vol%, and further preferably 10 to 33 vol%. When the content ratio of the small pieces 31 in the dispersed phase 3 is a value within the above range, the aesthetic appearance of the timepiece dial 1 is particularly excellent while sufficiently improving the light transmittance. it can. Further, the adhesion of the dispersed phase 3 to the substrate 2 can be made particularly excellent.

The dispersion medium 32 constituting the disperse phase 3 is in a solid state and has a function of preventing the plurality of small pieces 31 from aggregating.
The dispersion medium 32 is composed of a cured product of a curable resin. Thereby, the adhesiveness between the dispersed phase 3 and the substrate 2 and the adhesiveness between the dispersion medium 32 and the small pieces 31 can be made particularly excellent, and the durability of the timepiece dial 1 can be made excellent.

The dispersion medium 32 may contain a component other than the resin material, but preferably has light transparency. Thereby, with the outstanding aesthetic appearance of the timepiece dial 1, it can be suitably applied to a solar timepiece dial (a dial provided in a timepiece equipped with a solar cell) that effectively uses excellent light transmittance. .
When the refractive index of the dispersion medium 32 constituting the dispersed phase 3 is n _M , and the refractive index of the constituent material of the substrate 2 is n _B , it is preferable that the relationship | n _M −n _B | ≦ 0.18 is satisfied. , | N _M −n _B | ≦ 0.07 is more preferable, and | n _M −n _B | ≦ 0.04 is more preferable. By satisfying such a relationship, the aesthetic appearance of the timepiece dial 1 can be made particularly excellent.

Further, when the refractive index of the dispersion medium 32 constituting the dispersed phase 3 is n _M , and the refractive index of the constituent material of the resin layer 313 of the small piece 31 is n _R , a relationship of | n _M −n _R | ≦ 0.18 Is preferable, the relationship | n _M −n _R | ≦ 0.07 is more preferable, and the relationship | n _M −n _R | ≦ 0.04 is more preferable. By satisfying such a relationship, the aesthetic appearance of the timepiece dial 1 can be made particularly excellent.

The average thickness of the dispersed phase 3 is preferably 25 to 500 μm, more preferably 30 to 400 μm, and further preferably 40 to 350 μm.
The light transmittance of the timepiece dial 1 is preferably 20% or more, more preferably 30% or more, and even more preferably 35% or more. Thereby, the timepiece dial can be suitably applied to a solar timepiece.

<Manufacturing method of timepiece dial>
Next, the manufacturing method of the timepiece dial 1 described above will be described.
FIG. 3 is a cross-sectional view showing a preferred embodiment of the method for producing a timepiece dial of the present invention, FIG. 4 is a view showing an example of the shape of a small piece contained in the composition, and (a) is a cross-sectional view. FIG. 4B is a plan view.

  The manufacturing method of the present embodiment includes a substrate preparation step (1a) for preparing a substrate (base material) 2, a small piece (glossy small piece) 31 'having a function of reflecting light, and a curable resin 32'. A composition applying step (1b) for applying a composition having the following on the substrate (base material) 2, a small piece deformation step (1c) for bending or bending at least a part of the small piece 31 ′, and a curable resin 32 ′. And a curing step (1d) for curing the solid dispersion medium 32.

[Board preparation process]
First, the substrate 2 is prepared (1a).
As the substrate 2, those described above can be used.
In addition, various cleaning processes may be performed on the surface of the substrate 2 prior to a process described later. Thereby, for example, the adhesion between the substrate 2 and the dispersed phase 3 can be made particularly excellent.

[Composition applying step]
Next, a composition containing a small piece 31 ′ and a curable resin 32 ′ is applied on the substrate 2 (1b).
The method for applying the composition is not particularly limited, and examples thereof include a screen printing method, an octopus printing method, an ink jet method, a spin coating method, and a brush coating method. Among these, by using the screen printing method, the aesthetic appearance of the obtained timepiece dial 1 can be made particularly excellent while the productivity of the timepiece dial 1 is made excellent. Further, when the dispersed phase 3 is formed in a predetermined pattern on the substrate 2, the dispersed phase 3 having a desired shape and pattern can be easily and reliably formed. In addition, when manufacturing a plurality of timepiece dials 1, the composition can be repeatedly applied in a predetermined pattern while preventing variation among individuals, so that the watch has excellent quality stability. The dial 1 can be suitably applied to mass production. Further, by using the screen printing method, it can be suitably applied to mass production of the timepiece dial 1 having excellent quality stability.

In the present embodiment, a case where the composition applying step is performed using a screen printing method will be described as a representative example.
In screen printing, a screen plate 6 is used. The screen plate 6 is provided with a mesh 61 composed of wires 611.
In this step, the upper surface of the screen plate 6 (the surface on which the composition is disposed) is pressed with the squeegee 7 in a state where the composition is disposed on the screen plate 6 having the mesh 61 constituted by the wires 611. To do.

The composition used in this step includes a small piece 31 ′ and a curable resin 32 ′.
In the present embodiment, the small piece 31 ′ includes a heat shrink layer 313 ′ made of a heat shrink material (heat shrink material before heat shrink) and a metal layer 314 ′ made of a metal material, Further, it is a flat plate provided with a slit 315 ′. Since the small piece 31 ′ has such a configuration, the heat shrinkable layer 313 ′ is irreversibly thermally contracted in a subsequent step (small piece deformation step), and the small piece 31 ′ is preferably curved or bent. it can. In particular, by providing the slit 315 ′ as shown in FIG. 2, the small piece 31 ′ can be efficiently converted into the small piece 31 having the protruding piece 312 in the subsequent step (small piece deformation step). As a result, the aesthetic appearance, durability, etc. of the timepiece dial 1 finally obtained can be made particularly excellent easily and reliably. Further, when the composition containing the small pieces 31 ′ passes through the mesh 61 of the screen plate 6, the small pieces 31 ′ can be suitably elastically deformed, and it is ensured that the mesh 61 of the screen plate 6 is clogged. Thus, the productivity of the timepiece dial 1 can be made particularly excellent.

Examples of the heat-shrinkable material constituting the heat-shrinkable layer 313 ′ include polyolefin resin materials such as polyethylene, polypropylene, ethylene-propylene copolymer, ethylene-vinyl acetate copolymer, and vinyl chloride resins such as polyvinyl chloride. Examples thereof include resin materials such as fluorine resins such as materials, silicone resin materials, perfluoroalkoxyalkanes (PFA), and tetrafluoroethylene-hexafluoropropylene copolymers (FEP). When the heat-shrinkable layer 313 ′ is composed of the above resin amount, the dispersion stability of the small pieces 31 ′ in the composition can be made particularly excellent and stable over a long period of time. In addition, the timepiece dial 1 can be manufactured. Moreover, in the timepiece dial 1 to be manufactured, the adhesion between the small piece 31 and the dispersion medium 32 can be made particularly excellent, and the durability of the timepiece dial 1 as a whole can be made particularly excellent. .
In addition, as the heat shrinkable layer 313 ′, for example, a sheet material made of a resin material (particularly, a resin material as described above) was heat-stretched and then cooled while maintaining the stretched state. A sheet material can be used.

As described above, the small piece 31 ′ is provided with the slit 315 ′ (see FIG. 2).
By the way, the composition containing many small pieces and curable resin generally has a high viscosity, and it is difficult to perform screen printing stably. For this reason, when an attempt is made to produce a timepiece dial having a dispersed phase as described above using a composition containing glossy pieces and a curable resin, it is necessary to increase the pressing force during printing. Therefore, it is difficult to make the timepiece dial sufficiently productive. In addition, since a large load is applied during printing, there is a problem that the life of the screen plate is remarkably shortened. In order to solve such a problem, it is conceivable to reduce the content rate of the small pieces or to reduce the size of the small pieces. In such a case, the aesthetic appearance of the obtained timepiece dial is sufficiently provided. It was not possible to make it excellent. Therefore, as a result of intensive studies for the purpose of solving the above-mentioned problems, the present inventor has included the above-mentioned problems by including small pieces provided with slits in the composition used for screen printing. Found out to solve. This is considered to be due to the following reasons.

  That is, in general, when a high-viscosity composition including small pieces (particularly, plate-shaped small pieces) and a curable resin is subjected to screen printing, the small pieces contained in the composition increase resistance during screen printing. As a factor, a large pressing force is required, but when the small piece contained in the composition has a slit as in the present invention, when the pressing force acts, a part of the dispersion medium is a small piece. It will pass through the slit, and the resistance during screen printing can be reduced, and the small pieces are easy to move in the composition, clogging of the mesh is effectively prevented, and the dispersed phase formed is The small pieces are uniformly dispersed. As described above, the productivity of the timepiece dial can be improved and the aesthetic appearance of the obtained timepiece dial can be made excellent.

  In the present embodiment, as shown in FIG. 2, the small piece 31 ′ is provided with a plurality of intersecting slits 315 ′. Thereby, the resistance at the time of screen printing can be further effectively reduced, so that the productivity of the timepiece dial 1 can be further improved, and a small piece having a protruding piece 312 having a suitable shape. The dispersed phase 3 containing 31 can be easily and reliably formed, and the aesthetic appearance of the manufactured timepiece dial 1 can be made particularly excellent.

In particular, in the configuration shown in FIG. 2, two slits 315 ′ are provided so as to be orthogonal to each other. Thereby, the effect mentioned above is exhibited more notably.
In the present embodiment, the small piece 31 ′ has a substantially square shape when viewed in plan. Thereby, the effect by having slit 315 'mentioned above can be exhibited more notably, and the productivity and aesthetic appearance of timepiece dial 1 can be made especially excellent.

  The small piece 31 'as described above is preferably manufactured as follows. That is, the small piece 31 ′ is formed on a plastic sheet material (a sheet material having a thickness corresponding to the thickness of the heat shrink layer 313 ′) by a vapor deposition method such as vacuum deposition, sputtering, or ion plating. It was obtained by forming a metal layer (a metal layer corresponding to the thickness of the metal layer 314 ′) and then cutting into a predetermined size (a size corresponding to the small piece 31 ′) to form a slit 315 ′. It is preferable. Thereby, it is possible to easily and surely obtain a small piece 31 ′ that can be suitably used for manufacturing a timepiece dial 1 having excellent adhesion between the heat shrinkable layer 313 ′ and the metal layer 314 ′ and having an excellent aesthetic appearance. it can.

The curable resin 32 ′ is in an uncured or semi-cured state.
As the curable resin 32 ′, a resin material that is cured by energy rays (for example, heat (heat rays), light (including light other than visible light such as ultraviolet rays), electron beams) can be used. A curable resin, a photocurable resin, an electron beam curable resin, or the like can be used.
When a photocurable resin is used as the curable resin 32 ′, the productivity of the timepiece dial 1 can be made particularly excellent. Further, deterioration of the constituent material of the timepiece dial 1 at the time of manufacture can be prevented more reliably, and the reliability of the manufactured timepiece dial 1 can be made particularly excellent.

In addition, when a thermosetting resin is used as the curable resin 32 ′, a curing process is required subsequent to the small piece deformation process (first heating process), as described in detail later, without requiring a large-scale apparatus or facility. The (second heating step) can be performed smoothly, and the productivity of the timepiece dial 1 can be made particularly excellent.
The composition may contain components other than the small piece 31 ′ and the curable resin 32 ′ described above. Examples of such components include various solvents (functioning as a dispersion medium for dispersing (solid / liquid dispersion) the small pieces 31 ′ and a solvent for dissolving the curable resin 32 ′), dispersants, thermoplastic resins, and the like. Can be mentioned.

  The viscosity at 25 ° C. of the composition containing the small pieces 31 ′ and the curable resin 32 ′ is preferably 8000 to 20000 cps, more preferably 12000 to 19000 cps, and further preferably 15000 to 18000 cps. . When the viscosity of the composition is within the above range, the effect of the small piece 31 having the slit 315 ′ is more remarkably exhibited during screen printing, and the productivity of the timepiece dial 1 is further improved. It can be. Moreover, when the viscosity of the composition is within the above range, the dispersed phase 3 having a relatively large thickness can be suitably formed. As a result, for example, when the dispersed phase 3 is formed in a predetermined pattern on the substrate 2 (when the dispersed phase 3 is selectively formed on a part of the substrate 2), the timepiece dial 1 The three-dimensional effect can be made particularly excellent, and when the timepiece dial 1 is applied to a solar timepiece, the reflection of light can be suitably reflected inside the disperse phase 3, so that the timepiece The light transmission of the timepiece dial 1 as a whole can be made particularly excellent while the aesthetic appearance of the timepiece dial 1 is made excellent.

  The screen plate 6 used in this step includes a wire 611 at least near the surface made of polytetrafluoroethylene, the mesh roughness is 20 to 120, and the diameter of the wire 611 is 50 to 120 μm. It is preferable that Thereby, the effect by having the small piece 31 having the slit 315 'is more remarkably exhibited during screen printing, and the productivity of the timepiece dial 1 can be further improved.

As described above, it is preferable that the screen plate 6 used in this step is provided with the wire 611 at least near the surface made of polytetrafluoroethylene, but the entire wire 611 is made of polytetrafluoroethylene. More preferably, it is constituted by Thereby, the effects as described above are more remarkably exhibited.
Further, as described above, the mesh roughness of the screen plate 6 used in this step is preferably 20 to 120, more preferably 30 to 100, and 50 to 70. Further preferred. Thereby, the effects as described above are more remarkably exhibited.
As described above, the diameter of the wire 611 constituting the screen plate 6 used in this step is preferably 50 to 120 μm, more preferably 50 to 90 μm, and 60 to 70 μm. Further preferred. Thereby, the effects as described above are more remarkably exhibited.
As a constituent material of the squeegee 7, for example, urethane rubber, silicone rubber, various synthetic rubbers, various metals and the like can be used, and among them, urethane rubber is preferable.

[Small piece deformation process]
Next, the small piece 31 ′ constituting the composition is deformed into a curved or bent small piece 31 (1c). In particular, in the present embodiment, the heat contraction layer 313 ′ is thermally contracted to deform the small piece 31 ′ so that the protruding piece 312 becomes the small piece 31 protruding from the main body 311. Thereby, the aesthetic appearance of the timepiece dial 1 to be obtained can be made particularly excellent.

  Further, in the present embodiment, instead of adjusting the composition for forming a dispersed phase using a piece that has been curved or bent in advance, in the composition containing a curable resin, by bending or bending the piece, Small pieces (curved or bent pieces) can be more reliably prevented from enclosing air, etc., and problems such as deterioration of aesthetic appearance due to the presence of bubbles in the formed dispersed phase are more reliably generated. Can be prevented.

When the small piece 31 ′ has a heat shrink layer 311 ′ made of a heat shrink material as in the present embodiment, this step can be performed by, for example, heat treatment. Thereby, the small piece 31 ′ can be bent or bent easily and efficiently, and the productivity of the timepiece dial 1 can be made particularly excellent. Further, when the small piece 31 ′ has a heat shrinkable layer 311 ′ made of a heat shrinkable material as in the present embodiment, the small piece 31 ′ is more suitably curved by performing this process by heat treatment. Alternatively, it can be bent, and the aesthetic appearance of the timepiece dial 1 can be made particularly excellent.
The heat treatment in this step is performed under the condition that the curable resin does not completely cure.

[Curing process]
Next, the curable resin 32 ′ is cured to obtain a solid dispersion medium 32, and a dispersed phase 3 in which a large number of small pieces 31 are dispersed (solid / solid dispersion) in the solid dispersion medium 32 (1 d). Thereby, the timepiece dial 1 is obtained. In the dispersed phase 3 formed in this manner, the reflecting surfaces of the plurality of small pieces 31 face in various directions, and the resulting aesthetic appearance of the timepiece dial 1 is excellent. In addition, since the dispersed phase 3 is obtained by dispersing small pieces 31 (particularly, the small pieces 31 having the protruding pieces 312 in the present embodiment) having at least a portion curved or bent, the small pieces 31 are dispersed in the dispersion medium (curing portion). ) Is securely fixed to 32, and the small piece 31 is effectively prevented from falling off when the timepiece dial 1 is used. Therefore, the timepiece dial 1 is excellent in durability and reliability.

Curing of the curable resin is performed by a method according to the type of the curable resin. For example, when the curable resin is a thermosetting resin, it can be performed by heating, and when the curable resin is a photocurable resin, it can be performed by irradiation with light (energy rays).
In particular, when the curable resin is a photocurable resin and this step is performed by light irradiation, the productivity of the timepiece dial 1 can be made particularly excellent, and the timepiece dial at the time of manufacture can be improved. 1 can be reliably prevented, and the reliability of the manufactured timepiece dial 1 can be made particularly excellent.
Further, when the curable resin is a thermosetting resin and this step is performed by heating, the timepiece dial 1 is manufactured with high productivity without requiring a large-scale device, facility, expensive device, or facility. Can do.

<Clock>
Next, an example of the timepiece of the present invention provided with the timepiece dial 1 of the present invention as described above, particularly an example of a solar timepiece will be described.
The timepiece of the present invention has the timepiece dial of the present invention as described above. As described above, the timepiece dial of the present invention is excellent in decorativeness (aesthetic appearance). The timepiece dial is a member that has a particularly great influence on the appearance of the entire timepiece among various members constituting the timepiece. For this reason, the timepiece provided with the timepiece dial as described above has an excellent aesthetic appearance as a whole. Further, as described above, the timepiece dial of the present invention is excellent in light transmittance. For this reason, the timepiece of the present invention provided with the timepiece dial as described above can sufficiently satisfy the required requirements as a solar timepiece. As a part other than the timepiece dial (the timepiece dial of the present invention) that constitutes the timepiece of the present invention, known parts can be used, but an example of the configuration of the timepiece of the present invention is described below. explain.

FIG. 5 is a cross-sectional view showing a preferred embodiment of the timepiece (watch) of the present invention.
As shown in FIG. 5, a wristwatch (portable watch) 100 as a solar watch of this embodiment includes a trunk (case) 82, a back cover 83, a bezel (edge) 84, a glass plate (cover glass) 85, and the like. It has. Further, in the case 82, the timepiece dial 1 of the present invention as described above, the solar cell 94, and the movement 81 are accommodated, and further, hands (pointers) not shown are accommodated. . The timepiece dial 1 is provided between a solar cell 94 and a glass plate (cover glass) 85.
The glass plate 85 is usually made of transparent glass or sapphire having high transparency. Thereby, while being able to fully exhibit the aesthetics of the timepiece dial 1 of the present invention, a sufficient amount of light can be incident on the solar cell 94.

The movement 81 uses the electromotive force of the solar cell 94 to drive the pointer.
Although omitted in FIG. 5, in the movement 81, for example, an electric double layer capacitor for storing the electromotive force of the solar cell 94, a lithium ion secondary battery, a crystal oscillator as a time reference source, and a crystal vibration A semiconductor integrated circuit that generates a driving pulse for driving a clock based on the oscillation frequency of the child, a step motor that drives the pointer every second in response to this driving pulse, and a wheel that transmits the movement of the step motor to the pointer A row mechanism is provided.
The movement 81 includes a radio wave receiving antenna (not shown). And it has the function to perform time adjustment etc. using the received electromagnetic wave.

The solar cell 94 has a function of converting light energy into electric energy. The electric energy converted by the solar cell 94 is used for driving the movement.
In the solar cell 94, for example, a p-type impurity and an n-type impurity are selectively introduced into a non-single-crystal silicon thin film, and a p-type non-single-crystal silicon thin film and an n-type non-single-crystal silicon thin film are used. It has a pin structure provided with an i-type non-single-crystal silicon thin film with a low impurity concentration in between.

A winding stem pipe 86 is fitted into and fixed to the barrel 82, and a shaft 871 of a crown 87 is rotatably inserted into the winding stem pipe 86.
The body 82 and the bezel 84 are fixed by a plastic packing 88, and the bezel 84 and the glass plate 85 are fixed by a plastic packing 89.
Further, a back cover 83 is fitted (or screwed) to the body 82, and a ring-shaped rubber packing (back cover packing) 92 is inserted in a compressed state in these joint portions (seal portions) 93. Has been. With this configuration, the seal portion 93 is sealed in a liquid-tight manner, and a waterproof function is obtained.

  A groove 872 is formed on the outer periphery of the middle portion of the shaft portion 871 of the crown 87, and a ring-shaped rubber packing (crown packing) 91 is fitted in the groove 872. The rubber packing 91 is in close contact with the inner peripheral surface of the winding stem pipe 86 and is compressed between the inner peripheral surface and the inner surface of the groove 872. With this configuration, the space between the crown 87 and the winding stem pipe 86 is liquid-tightly sealed, and a waterproof function is obtained. When the crown 87 is rotated, the rubber packing 91 rotates together with the shaft portion 871 and slides in the circumferential direction while being in close contact with the inner peripheral surface of the winding stem pipe 86.

The portable watch (watch) as described above is required to have particularly excellent durability (for example, impact resistance) among various watches. For this reason, the timepiece dial 1 capable of obtaining excellent durability as well as excellent aesthetic appearance can be more suitably applied.
In the above description, a wristwatch (portable clock) as a solar radio timepiece has been described as an example of a clock. However, the present invention is applicable to other types of clocks such as a portable clock, a table clock, and a wall clock other than a wristwatch. Can be applied similarly. The present invention can also be applied to solar timepieces other than solar radio timepieces.

As mentioned above, although preferred embodiment of this invention was described, this invention is not limited to these.
For example, in the above-described embodiment, the case where the substrate 2 forming the dispersed phase 3 has a shape and size corresponding to the timepiece dial 1 has been mainly described. After forming the dispersed phase, the sheet-like member may be processed into a timepiece dial by stamping or the like.

  Moreover, when manufacturing the timepiece dial of the present invention, steps other than those described above may be provided. For example, a step of forming a coat layer may be provided. As a result, for example, the color tone, etc., can be adjusted to further improve the aesthetic appearance of the timepiece dial, or the weather face, water resistance, oil resistance, scratch resistance, abrasion resistance of the timepiece dial as a whole Various properties such as discoloration resistance can be improved. Such a coat layer may be removed, for example, when a timepiece dial is used.

Further, the timepiece dial of the present invention may not include the base material used in the manufacturing method as described above as a constituent part thereof. For example, as described above, the timepiece dial of the present invention may be configured by removing the base material after forming the dispersed phase on the base material.
In the above-described embodiment, the case where the dispersed phase 3 is provided on the entire surface of the substrate 2 has been mainly described. However, the dispersed phase 3 is a part of the substrate 2 (for example, an index such as a time character). It may be provided only in the part corresponding to Further, the dispersed phase 3 may be provided on both sides of the substrate 2.

  In addition, the timepiece dial according to the present invention has a function of reflecting light in a dispersion medium made of a resin material, and at least part of the timepiece dial is made of a dispersed phase in which curved or bent pieces are dispersed. The entire timepiece dial may be composed of a dispersed phase. Moreover, a part of parts constituting the timepiece dial (for example, a planting material used as an indicator of time letters or the like) may have a dispersed phase as described above.

In the above-described embodiment, the case of using a small piece having a heat shrink layer and a metal layer made of a heat shrink material is representatively described for producing a timepiece dial. The small piece used in the above may have, for example, a colored heat-shrinkable layer (having a function of reflecting light) and a substantially colorless resin layer (a resin layer that does not substantially heat-shrink). .
In the above-described embodiment, the small piece in the composition is typically described as being deformed to have a protruding piece, but the small piece in the composition imparts the composition onto the substrate. Any shape can be used as long as it is deformed after being deformed.

  In the above-described embodiment, the small piece contained in the composition has been described as having two linearly intersecting slits. However, the small piece contained in the composition has one slit. It may have, and it may have three or more slits. In addition, the slit may have a curved shape and / or a bent shape when the small piece is viewed in plan. Examples of small pieces having such slits include those shown in FIGS. 6 and 7. When such a composition containing small pieces is used, in the finally obtained timepiece dial, the light irradiated to the timepiece dial is changed in various directions because the reflecting surface of the small pieces faces in various directions. It can be reflected in the direction, and a high-quality appearance with a glossy feeling (shiny feeling) like that of diamond or cut glass can be obtained. When a composition containing small pieces as shown in FIGS. 6 and 7 is used as the composition, the small pieces contained in the dispersed phase of the manufactured timepiece dial are shown in FIGS. 8 and 9, respectively. It has such a structure.

Next, specific examples of the present invention will be described.
1. Manufacture of timepiece dial (Example 1)
A watch dial (solar watch dial) was manufactured by the following method.
First, a base material having the shape of a watch dial (solar watch dial) is produced by injection molding using polycarbonate, and then a necessary portion is cut out and unnecessary burrs are cut and polished. As a result, a substrate was obtained. The obtained substrate was substantially disc-shaped and had a diameter: 27 mm × thickness: 300 μm.

Next, this substrate was cleaned. The substrate was first washed with a neutral plastic detergent for 30 seconds, then neutralized for 10 seconds, washed with water for 30 seconds, and washed with pure water for 60 seconds. Then, it dried for 20 minutes in oven (80 degreeC).
A composition containing a small piece (glossy piece) and an uncured curable resin (photocurable resin) was applied to one main surface of the substrate thus cleaned by screen printing (composition) Application step). As a glossy piece constituting the composition, a sheet material (sheet corresponding to the heat shrink layer) obtained by thermally stretching a sheet material composed of polyvinyl chloride and then cooling while maintaining the stretched state. A metal layer made of Al was formed on one main surface of the material) by vacuum deposition, and then the sheet material was cut into a square shape (substantially rectangular parallelepiped shape) to form a slit. As shown in FIG. 4, the small piece was provided with slits on two diagonals of a square. The length of each slit was 70 μm. Moreover, the content rate of the polyvinyl chloride in the sheet | seat material (heat-shrinkable layer) comprised with the polyvinyl chloride was 99.9 wt% or more. The Al content in the metal layer provided on the surface of the sheet material (heat shrinkable layer) made of polyvinyl chloride was 99.9 wt% or more. The viscosity of the composition used in this step at 25 ° C. was 17000 cps. As the screen plate, a screen plate having a mesh made of polytetrafluoroethylene wire, having a mesh roughness of No. 70 and a wire diameter of 60 μm was used. Moreover, as a squeegee, what was comprised with the urethane type rubber was used.

Next, the substrate provided with the composition was subjected to heat treatment at 100 ° C. for 10 minutes. Thereby, as shown in FIG. 2, the small piece (glossy piece) contained in the composition was curved as a whole, and a protruding piece was formed on a part thereof.
Next, it is gradually cooled to room temperature (20 ° C.), and then the curable resin is cured by irradiating ultraviolet rays from the surface side to which the composition of the substrate is applied, and the small piece having the protruding piece becomes the curable resin. A dispersed phase dispersed in the cured product (dispersion medium) was formed (curing step). As a result, a watch dial (solar watch dial) as shown in FIG. 1 was obtained. The average thickness of the formed dispersed phase was 200 μm. The average particle size of the curved glossy pieces contained in the dispersed phase was 120 μm. Moreover, the average thickness of the resin layer of the glossy small pieces contained in the dispersed phase was 25 μm. Moreover, the average thickness of the metallic layer of the glossy small piece contained in the dispersed phase was 1.0 μm.
In addition, the thickness of a board | substrate, a dispersed phase, a small piece (resin layer, metal layer), etc. were measured in accordance with the microscope cross-section test method prescribed | regulated by JISH5821.

(Examples 2 to 5)
A watch dial (solar watch dial) was manufactured in the same manner as in Example 1 except that the configuration shown in Table 1 was adopted.
(Example 6)
As the curable resin constituting the composition for forming the dispersed phase, a thermosetting resin is used instead of the photocurable resin (ultraviolet curable resin), and in the curing step, 150 ° C. is used instead of the ultraviolet irradiation. A timepiece dial (solar timepiece dial) was manufactured in the same manner as in Example 1 except that heat treatment was performed for 10 minutes.
(Examples 7 to 9)
A watch dial (solar watch dial) was manufactured in the same manner as in Example 6 except that the configuration shown in Table 1 was adopted.

(Comparative Example 1)
A timepiece dial (solar timepiece dial) was produced in the same manner as in Example 1 except that the small pieces contained in the composition for forming the dispersed phase were not provided with slits.
(Comparative Example 2)
The above examples except that the small pieces contained in the composition for forming the dispersed phase were those having a resin layer composed of an acrylic resin (resin material that is not a heat shrink material) instead of the heat shrink layer. In the same manner as in Example 1, a timepiece dial (solar timepiece dial) was manufactured.

In addition, the board | substrate used by each said Example and each comparative example has the transmittance | permeability of visible light when using a white fluorescent lamp (the Toshiba company make, fluorescent lamp FL20S-D65 for a test | inspection) as a light source, It was 80% or more.
Table 1 summarizes the configuration and the like of the watch dial (solar watch dial) of each example and each comparative example. In the table, polycarbonate is PC, acrylonitrile-butadiene-styrene copolymer (ABS resin) is ABS, polyvinyl chloride is PVC, ethylene-vinyl acetate copolymer is EVA, and acrylic resin is PMMA. Moreover, in the table, in the column of the average thickness of the small piece, the thickness of the resin layer and the metal layer is shown in parentheses in this order after the average thickness (the thickness of the main body) as the whole small piece. . Further, the refractive index of the dispersion medium in the dispersed phase is n _M , the refractive index of the constituent material of the substrate is n _B , and the refractive index of the constituent material of the small resin layer included in the dispersed phase is n _R. Moreover, the content rate of the material shown in Table 1 in each site | part of the timepiece dial was all 99 wt% or more. In each of the above embodiments (the present invention), each of the small pieces included in the dispersed phase of the timepiece dial has a protruding piece protruding from the edge of the opening. On the other hand, in each comparative example, such a protruding piece did not exist.

2. Productivity evaluation of timepiece dials For each of the above examples and comparative examples, by repeatedly performing the above-described method, an attempt was made to produce 100 timepiece dials. Evaluation was performed according to the following three-stage criteria.
A: Excellent in productivity.
B: Productivity is slightly inferior.
C: Productivity is inferior.

3. Appearance evaluation of watch dial (solar watch dial) For each watch dial produced in each of the above examples and comparative examples, the surface on which the dispersed phase of the substrate is provided on the black solar cell. It arrange | positions so that the surface of the other side may oppose, and in such a state, it observed visually from the surface side in which the disperse phase of the board | substrate was provided, and evaluated these external appearances according to the following seven steps criteria. . Visual observation was performed from the normal direction of the substrate (direction of viewing angle 0 °) and the direction inclined by 73 ° from the normal line of the substrate (direction of viewing angle 73 °), and each direction was evaluated.

A: It has an extremely excellent appearance.
B: It has a very excellent appearance.
C: It has an excellent appearance.
D: It has a good appearance.
E: Appearance is slightly poor.
F: Appearance is poor.
G: The appearance is extremely poor.

4). Viewing angle dependency of the appearance of a watch dial (solar watch dial) First, for each watch dial produced in each of the examples and comparative examples, a dispersed phase of a substrate is provided on a black solar cell. It was arranged so that the surface opposite to the formed surface was opposed. In such a state, the brightness L ₀ [cd / m ² ] in the normal direction (direction of viewing angle 0 °) of the substrate on the surface side where the dispersed phase of the substrate is provided is inclined by 73 ° from the normal of the substrate. The luminance L ₇₃ [cd / m ² ] in the measured direction (direction of viewing angle 73 °) was measured, and the viewing angle dependency of the appearance of the timepiece dial was evaluated according to the following five-stage criteria.

A: L ₇₃ / L ₀ is 0.90 or more.
B: L ₇₃ / L ₀ is 0.85 or more and less than 0.90.
C: L ₇₃ / L ₀ is 0.80 or more and less than 0.85.
D: L ₇₃ / L ₀ is 0.70 or more and less than 0.80.
E: L ₇₃ / L ₀ is less than 0.70.

5). Evaluation of Light Transmittance of Watch Dial (Solar Watch Dial) The light transmittance of each watch dial manufactured in each of the above Examples and Comparative Examples was evaluated by the following method.
First, the solar cell and each watch dial were placed in a darkroom. Thereafter, light from a white fluorescent lamp (light source) separated by a predetermined distance was made incident on the light receiving surface of the solar cell alone. At this time, the power generation current of the solar cell was A [mA]. Next, light from a white fluorescent lamp (light source) separated by a predetermined distance as described above was made incident on the upper surface of the light receiving surface of the solar cell with a wristwatch dial overlapped. In this state, the generated current of the solar cell was B [mA]. Then, the light transmittance of the timepiece dial represented by (B / A) × 100 was calculated and evaluated according to the following six criteria. It can be said that the larger the light transmittance, the better the light transmittance of the timepiece dial. The timepiece dial was superimposed on the solar cell so that the surface side on which the dispersed phase of the substrate was provided faced the white fluorescent lamp (light source). Further, as the white fluorescent lamp, a white fluorescent lamp (manufactured by Toshiba, fluorescent lamp for inspection FL20S-D65) was used.

A: 36% or more.
B: 32% or more and less than 36%.
C: 26% or more and less than 32%.
D: 20% or more and less than 26%.
E: 15% or more and less than 20%.
F: Less than 15%.

6). Evaluation of radio wave permeability The radio wave permeability of each timepiece dial manufactured in each of the above Examples and Comparative Examples was evaluated by the following method.
First, a watch case and a wristwatch internal module (movement) equipped with an antenna for receiving radio waves were prepared.

Next, a wristwatch internal module (movement) and a wristwatch dial were assembled in the watch case, and the radio wave reception sensitivity in this state was measured. At this time, the timepiece dial was such that the surface of the substrate on which the dispersed phase was provided faced the outer surface.
Based on the reception sensitivity in a state where the wristwatch dial is not incorporated, the reduction amount (dB) of the reception sensitivity when the wristwatch dial is incorporated was evaluated according to the following four criteria. It can be said that the lower the radio wave reception sensitivity is, the better the radio wave transmission of the wristwatch dial is.
A: No decrease in sensitivity is observed (below the detection limit).
B: A decrease in sensitivity is observed at less than 0.7 dB.
C: The decrease in sensitivity is 0.7 dB or more and less than 1.0 dB.
D: The decrease in sensitivity is 1.0 dB or more.

7). Durability Evaluation Each watch dial plate manufactured in each of the above Examples and Comparative Examples was subjected to a thermal cycle test as shown below to evaluate durability.
First, the watch dial is placed in a 15 ° C. environment for 1 hour, then in a 75 ° C. environment in 2 hours, then in a 15 ° C. environment in 1 hour, and then in a −25 ° C. environment in 2 hours. Left to stand. Thereafter, the ambient temperature was returned again to 15 ° C., which was set as one cycle (6 hours), and this cycle was repeated a total of 8 times (total 48 hours).

Thereafter, the appearance of the watch dial was visually observed, and the appearance was evaluated according to the following four criteria.
A: Dispersed phase, small piece floating, peeling, etc. are not recognized at all.
B: Dispersed phase, little floating of the piece is not recognized.
C: Dispersed phase, small pieces are clearly lifted.
D: Dispersed phase, cracks and peeling of small pieces are clearly recognized.
These results are shown in Table 2.

As is clear from Table 2, all of the timepiece dials of the present invention have an excellent aesthetic appearance, small visual angle dependency, and an excellent aesthetic appearance even when observed from various directions and angles. It was presented. Moreover, the timepiece dial of the present invention was excellent in light transmittance. Further, the timepiece dial of the present invention was excellent in durability. In addition, the timepiece dial of the present invention was excellent in radio wave permeability. In the present invention, a timepiece dial can be manufactured with excellent productivity.
On the other hand, in each comparative example, a satisfactory result was not obtained.
Further, a timepiece (solar timepiece) as shown in FIG. 5 was assembled using the timepiece dials obtained in each Example and each Comparative Example. Each timepiece thus obtained was tested and evaluated in the same manner as described above, and the same results as described above were obtained.

  DESCRIPTION OF SYMBOLS 1 ... Timepiece dial 2 ... Board | substrate (base material) 3 ... Dispersion phase 31 ... Small piece (glossy small piece) 311 ... Main-body part 3111 ... Opening part 312 ... Projection piece 313 ... Resin layer 314 ... Metal layer 32 ... Dispersion medium ( Curing part) 31 '... small piece (glossy small piece) 313' ... heat shrink layer 314 '... metal layer 315' ... slit 32 '... curable resin 6 ... screen plate 61 ... mesh 611 ... wire 7 ... squeegee 94 ... solar cell 81 ... Movement 82 ... Body (case) 83 ... Back cover 84 ... Bezel (edge) 85 ... Glass plate (cover glass) 86 ... Winding pipe 87 ... Crown 871 ... Shaft part 872 ... Groove 88 ... Plastic packing 89 ... Plastic Packing 91 ... Rubber packing (Crown packing) 92 ... Rubber packing (Back cover packing) 93 ... Junction (seal) 100 ... Watch (portable watch)

Claims (11)

A composition application step of providing a composition having fluidity on a substrate, having a function of reflecting light, including a small piece provided with a slit and a curable resin;
A small piece deformation step of bending or bending at least a part of the small piece;
A method for manufacturing a timepiece dial, comprising: a curing step for curing the curable resin.   The timepiece dial manufacturing method according to claim 1, wherein the small piece deformation step is performed by heat treatment.   The timepiece dial manufacturing method according to claim 1, wherein the small piece has a heat-shrinkable layer made of a heat-shrinkable material.   The timepiece dial manufacturing method according to claim 3, wherein the small piece includes a metal layer made of a metal material in addition to the heat shrinkable layer. The curable resin is a photocurable resin,
5. The timepiece dial manufacturing method according to claim 1, wherein in the curing step, a light irradiation process is performed at a temperature higher than that of the small piece deformation step. The curable resin is a thermosetting resin,
The timepiece dial manufacturing method according to any one of claims 1 to 5, wherein in the curing step, heat treatment is performed at a temperature higher than that of the small piece deformation step.   The timepiece dial manufacturing method according to claim 1, wherein the small piece is provided with a plurality of intersecting slits.   The timepiece dial manufacturing method according to any one of claims 1 to 7, wherein, in the small piece deformation step, the small piece is deformed so that a part of the small piece protrudes from a main body portion that is a part other than the small piece. .   A timepiece dial manufactured using the method according to claim 1.   The timepiece dial according to claim 9, wherein the timepiece has a light transmittance of 20% or more.   A timepiece comprising the timepiece dial according to claim 9.

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