MXPA00006530A - Oxidized galactose type of alcohol configuration containing polymer in combination with cationic polymers for paper strength applications - Google Patents

Abstract

Process for making paper having improved strength characteristics by adding to the pulp water-soluble and/or water-dispersible cationic polymer and oxidized galactose type of alcohol configuration containing polymer.

Description

POLYMER CONTAINING CONFIGURATION OF OXIDIZED GALACTOSE-TYPE ALCOHOL IN COMBINATION WITH CATIONIC POLYMERS FOR APPLICATIONS OF PAPER STRENGTH Background of the Invention 1. Field of the Invention The present invention relates to a new process for improving paper strength and more particularly relates to the use in combinations of cationic polymers and galactose oxidase-containing polymer in the paper production process. 2 • Description of the Prior Art The product of the oxidation of aqueous solutions of guar gum and other polysaccharides containing galactose using enzyme galactose oxidase was described by F.J. Germino in the US patent. No. 3,297,604. The oxidized products containing aldehyde are separated by precipitation from aqueous solutions used for the enzyme reactions. Germino described the use of rusted products in papermaking. Oxidized products containing aldehyde were also described as suitable for use in the crosslinking of polyamino polymers, polyhydroxy polymers and proteins.

C. Chiu et al., In the patent of the U.S.A. No. 5,554,745, describe (1) the preparation of polysaccharides containing cationic galactose and (2) the enzymatic oxidation in aqueous solution of the polysaccharides containing cationic galactose with galactose oxidase. It is disclosed that oxidized cationic polysaccharides improve the strength characteristics of paper. SUMMARY OF THE INVENTION According to the present invention, there is provided a process for producing paper having improved strength characteristics by providing pulp and adding (1) cationic polymer and (2) polymer containing oxidized galactose-like alcohol configuration wherein the alcohol it has been oxidized in aldehyde, and form sheets and dry the paper, provided that when the polymer containing oxidized galactose-type alcohol configuration is oxidized guar it is selected from the group consisting of oxidized neutral guar, oxidized anionic guar and amphoteric guar oxidized amphoteric amp. In addition, according to the present invention, paper products having improved strength characteristics are provided which are prepared by using the combination of cationic polymers and polymers containing oxidized galactose-type alcohol configuration.

DETAILED DESCRIPTION OF THE INVENTION It has surprisingly been found that polymers containing oxidized galactose-type alcohol configuration such as oxidized anionic and / or amphoteric neutral guar, in combination with water-soluble or water-dispersible cationic polymers, give sufficiently improved resistance to guars not oxidized or oxidized alone. The polymer treatment containing oxidized galactose-type alcohol configuration with galactose oxidase and catalase is the subject of the accompanying patent application Serial No. 09 / 001,789, filed on December 31, 1997 (Hercules file No. PCH 5484, "Oxidation in Solid State of Oxidizable Galactose Type of Alcohol Configuration Containing Polymers "(Oxidation in solid state of polymers containing oxidized galactose type alcohol configuration) by RL Brady, R T. Leibfried and TT Nguyen), the description of which is incorporated herein by reference. The oxidizable galactose alcohol type configuration can be described by the following chemical structures: R3 wherein: R1 = is an alkyl group of the formula C (n) H (2n + 1) where n = 0-20: z = 0.1; R2 = is a linking group which is composed of an alkylene or an aromatic alkylene or an alkylene ether, or an alkylene ester or an alkylene amide, or a diradical alkylene urethane. These linking groups have a total number of carbon atoms from 2 to 20: R3 = -H, -OH, -0CH3, -OC2H5, -OC3H7, -OC4H9, -OOCRs (where R5 = alkyl radical with 1 to 5 carbon atoms), -NH2, -NH-CO-R5; e y = O, 1. Polymers containing oxidized galactose-type alcohol configuration can be galactomannan gums or their ether derivatives, arabinogalactan gums or their ether derivatives, other gums or their ether derivatives, hemicelluloses galactoglucomannan or its ether derivatives and polymers modified enzymatically or synthetically. Preferred galactomannan gums are guar, carob, tara and fenugreek. Preferred arabinogalactan gums are gum arabic, larch and tragacanth. Enzymatically or synthetically preferred modified polymers are polysaccharides deficient in galactose, polyacrylamides, polyacrylates, polyamides, polyvinyl alcohol and polyvinyl acetate. Particular preference is given to these polymers, starch and polyacrylates. The phrase "galactose-deficient" as used in the present application means that the polymer containing oxidized galactose-type alcohol configuration to which it refers contains less than 20% oxidizable galactose-type alcohol configuration based on the weight of the polymer that contains oxidized galactose type alcohol configuration. Other preferred gums are carbine, lichen, tamarind and potato galactane. More preferred oxidized galactose-type alcohol-containing polymers are guar gum and its ether derivatives such as hydroxypropyl, dihydroxypropyl and hydroxyethyl guar anionic, amphoteric. Synthetically or enzymatically modified polymers can be obtained by transferring an oxidizable galactose-type alcohol configuration into polymers. Glycocyl transferases or hydrolases can be used to transfer galactose from lactose for example polyaccarides to provide polymers useful for oxidation. Synthetic methods can also be obtained to connect the oxidizable galactose alcohol type configuration. By these methods, other saccharides such as gulose, fructose, sorbose, mannose, talose, gilose and ribose can be connected to polymers by providing candidates for oxidation. The polymer component containing oxidized galactose-type alcohol configuration of the present invention has at least about 5 mol% of its oxidizable, galactose-type alcohol configuration, oxidized in aldehyde. Preferably, at least about 25 mol% and more preferably at least 50 mol% of this alcohol has been oxidized in aldehyde. The polymer containing oxidized galactose-type alcohol configuration used for oxidation may be in the range over a wide molecular weight range. It can be a high molecular weight, or alternatively it can be a depolymerized polymer (of reduced viscosity). In general, the lower limit of the weight average molecular weight of the polymer containing oxidized galactose-type alcohol configuration may be about 5,000. The upper limit of the polymer containing oxidized galactose-type alcohol configuration may be about 5,000,000. Preferably, the molecular weight range as indicated by the Brookfield viscosity at room temperature is at least about 15 cps to 2 weight percent in solution in water, more preferably at least about 100 cps to 1 weight percent in solution in water. Preferably, the Brookfield viscosity at room temperature can be up to about 10,000 cps, and more preferably up to about 6,000 cps to 1 weight percent in solution in water, (measured in the Brookfield LVT viscometer with a small sample adapter, ° C, spindle 31, speed 3 rpm). Oxidized guar is preferred as the polymer containing oxidized galactose-type alcohol configuration for use in the present invention. The present application relates to guar oxidized specifically in certain cases, however the person of ordinary skill in the art will recognize that these teachings apply to the polymer containing oxidized galactose-like alcohol configuration in general. The polymer containing oxidized galactose-type alcohol configuration can be oxidized in solid form, in the form of sludge or in solution. The oxidation can be carried out chemically or enzymatically by galactose oxidase. Neutral or anionic or amphoteric guar that has been oxidized by galactose oxidase and catalase is used in the present invention. Galactose oxidase can be applied to solid forms, of mud or in solution of guar products: for example shredded, pulverulent, in flakes and nodules, of neutral, anionic or amphoteric guar. Guar derivatives, such as those containing hydroxypropyl groups can also be employed. Galactose oxidase (EC 1.1.3.9) is a copper oxidase that converts the oxidizable galactose-type alcohol configuration into the corresponding aldehyde group (thus producing oxidized galactose) by reducing oxygen in hydrogen peroxide. The copper must be in the correct oxidation state (Cu2 +) to perform this oxidation and the copper ion must be retained in the galactose oxidase. If the galactose oxidase solution is stored anaerobically with any oxidizable substrate, it may become inactive. Galactose oxidase can be reactivated by oxidizing copper with reagents such as potassium ferricyanide. Another way to oxidize copper in galactose oxidase would be by electrochemical oxidation. Galactose oxidase can be obtained by any convenient form, for example by fermenting various wild type and cloned fungi, but usually obtained from Fusarium spp (NRRL 2903). You can also obtain cultures from the American Type Culture Collection (American Type Culture Collection) under Dactilium dendroides ATCC 46032 and successfully fermented under the Tressel and Kosman procedure. Methods in Enzymology (Methods in Enzymology), Vol. 89 (1982), p. 163-172.

The gene for the active forms of the enzyme has been expressed in E. coli and Aspergillus and this development can lead to more stable and active forms of the enzyme, as well as much higher production levels. The gene or improved forms will also be expressed in plants that can be harvested to give higher levels of enzyme, without the threat of destruction of enzyme by proteases in a fermentation broth. The enzyme can also be expressed by other organisms including: Gibberella fujikoroi, Fusarium graminearum and Bettraniella porticensis. The oxidation of galactose oxidase is often carried out in the presence of catalase. The amount of catalase may be at least about one unit of catalase / galactose oxidase unit. Catalase may be present in an amount of up to about 10,000 catalase units / galactose oxidase unit. Catalase destroys the hydrogen peroxide formed from the galactose oxidase reaction. Increased levels of oxidation and corresponding increase in paper strength characteristics is the subject of the accompanying patent application No. 09 / 001,785, filed on December 31, 1997 (Hercules file No. PCH 5522"Use of Oxidation Promoting Chemicals in Enzymatic Oxidation of Galactose Containing Polymers "(Use of oxidation promoting chemicals in enzymatic oxidation of polymers containing galactose) by RL Brady and RT Leibfried), the description of which is incorporated herein by reference. Preferably, the oxidation promoter chemical is organic carboxylate compound, organic heterocyclic compound, chlorinated organic compound and / or quaternary amine compound. More preferably, the organic carboxylate compound is sorbic acid, benzoic acid, toluic acid, phthalic acid, and their corresponding salts, the organic heterocyclic compound, i.e., 1,2-benzisothiazolin-3-one, and / or 2-methyl-4 -isothiazoline-3-one, the chlorinated organic compound is 5-chloro-2-methyl-4-isothiazolin-3 -one, and the quaternary amine compound is cetyltrimethylammonium bromide and / or quaternary epoxy amines. Cationic polymers suitable for use in combination with the polymer containing oxidized galactose-type alcohol configuration in the present invention are cationic water-dispersible and / or water-soluble polymers. The phrase "water-soluble" as used in the present application means a polymer of which at least about 5% by weight is dissolved in water at room temperature. The phrase "water dispersible" as used in the present application means a polymer that can be evenly distributed in water and if it sediments it can be easily redispersed. By cationic is meant anything with a net positive charge at the paper production pH (e.g. pH from about 3 to about 10). This includes amphoteric polymers containing both anionic and cationic sites, these polymers have a net cationic charge. Preferably the cationic polymer is polymeric amine-epichlorohydrin resin, such as polyamide-epichlorohydrin resin (PAE), polyalkylene polyamine-epichlorohydrin resin (PAPAE) and amine-epichlorohydrin polymer resin (APE), in which the amine groups have been alkylated with epichlorohydrin to produce a polyamine-epichlorohydrin resin having azetidinium or epoxide functionality; cationic derivative of polysaccharides (such as starch, guar, cellulose, and chitin; polyamine; polyethyleneimine; vinylalcohol-vinylamine copolymers; acrylic cationic homo- and co-polymers, such as polyacrylamide, polydiallyldimethylammonium chloride, and acrylic acid copolymers, acrylic esters and acrylamide with diallyldimethylammonium chloride, acryloyloxyethyltrimethylammonium chloride, methylaceulfate, ammonium tertiary ammonium, methacryloyloxyethyl trimethylammonium chloride and methacrylamidopropyltrimethylammonium chloride. Cationic polymers are described in more detail in U.S. Pat. No. 5,319,669 and the US patent. No. 5,338,406, the descriptions of which are hereby incorporated by reference. More preferably, the cationic polymer is cationic starch, cationic guar, polyamidoamine-epichlorohydrin resin and / or polyacrylamide. The effectiveness of cationic polymers is particularly evident when used with oxidized anionic guar. The total weight of the polymer containing oxidized galactose-type alcohol (oxidized polymer) plus cationic polymeric configuration is generally at least about 0.05%, preferably at least about 0.1%, and most preferably at least about 0.15% based on weight Dry the paper. The total weight of the oxidized polymer plus cationic polymer is generally up to about 5%, preferably up to about 1% and in particular to about 0.5% based on the dry weight of the paper. The weight ratio of oxidized polymer to cationic polymer in general can be at least about 1:20, preferably at least about 1: 4 and in particular at least about 1: 1. The weight ratio of oxidized polymer to cationic polymer in general can be up to about 100: 1, preferably up to about 50: 1 and in particular up to about 20: 1. The optimum ratio of oxidized polymer to cationic polymer will depend on the oxidized polymer employed, the cationic polymer employed and the type of raw materials (ie, pulp, pH, fillers, etc.) employed. The components of this invention - the cationic polymer and the polymer containing oxidized galactose-type alcohol configuration - can be added at any point in the paper production process, that is, either before or after sheeting. For example, they can be added before the sheeting (1) early during the preparation of the pulp in the sludge container or refining container (2) in the machine container or container of material, (3) at other points in the the wet end such as the fan pump or in-line mixers. It can also be added to the white water container. Examples of addition after sheeting are in the sizing press or even as a subsequent coating process. The components can be premixed or added separately in any order. The preferred practice in the wet state, however, is to add the cationic polymer first. In addition, of the dry strength, properties such as tensile strength in the Z direction, Scott bonding strength, Mullen burst, ring crush, Abstraction of Txaction energy (TEA = Tensile Enexgy Absoxption), and x resistance to fxactuxa, The combination of water dispersible polymers and / or cationic water soluble, and oxidized galactose type alcohol configuxing polymer of the present invention can also be improved upon use. For the examples, test sheets were made on a Noble and Wood sheet machine (Noble and Wood Machine Co., Hoosick Falls, N.Y.) using standard hard water at a controlled pH of 7.5. Standard hard water (50 ppm alkalinity and 100 ppm hardness) was made to the mixture deionized water with CaCl2 and NaHCO3. The pH control is achieved to the user NaOH or H2S04. Leached kraft pulp was beaten at a Canadian standard refinement of 455 at a consistency of 2.5% by weight. The whipped pulp is added to the dispenser at a controlled level (depending on the final desired base weight) and diluted to 18 liters with duxa standaxd water. For a basis weight of 36.32 kg / 278.70 m2 (80 lb / 3000 ft2), 4000 ml of pulp mixture was used. Chemical additions and pH adjustments were made to the doser as desired, and with continuous mixing. For examples with multiple additives, the cationic additive was always added first. A 100 mesh clean and humid sieve is placed in the box of tambox or bastidox abiexto, which then cexxó. Duxa standaxd water and 920 ml of pulp mixture of the dosifificadox then agxegaxon to the box of tambox and passed xápido. The water was then discarded from the box, and the sheet was xetixed. The sheet was wet-painted with a pixel weights adjusted to a solids content of 33 to 34%. The sheet and sieve were then placed in a tambox drying, which was adjusted to a tempexatuity of 108.9-111.1 ° C (228-232 ° F) and a yield time of 50 to 100 seconds, depending on the basis weight. Final leaf moisture contents were 3 to 5%. 5 minimum sheets were tested for each set of experiments.

The tensile test was performed on the Acuexdo test sheets using the TAPPI method T 494 om-88 ("TAPPI Test Methods", TAPPI Pxess, Atlanta, GA, 1996). The scope of this invention as claimed is not limited by the following examples, which will be simply by way of illustration. All parts are given by weight unless otherwise indicated. EXAMPLE 1 This example demonstrates the effectiveness of the wet strength xesin of polyamidoamine-epicloxohydxin Kymene ™ 557H (cationic polymer) available from Hercules Incorporated, used with oxidized anionic and neutral oxidized guars. To produce neutral oxidized guar, 2.268 g of Supexcol U neutral guar powder (89.52% solids available from Hexcules Incoxpoxated), is added to 1197 g of sterile distilled water with constant agitation. 0.034 g of catalase (Sigma C40 available from Sigma Chemical Company, 3735 units / unit of G7400) and 0.0158 g of galactose oxidase (Sigma G7400 available from Sigma Chemical Company, 57 units / g guax) then agxegaxon with agitation overnight . The final solution concentration was 0.2% oxidized guar. Anionic oxidized guar is also made in solution as before using 2,643 g of caxboxymethyl guax powder Galactasol 70M22FD (90.8% solids, available from Hexcules Incoxpoxated), 1195 g of sterile distilled water, 1.1 g of 3% HCl (to adjust pH at 6), 0.605 g of catalase C40 (3889 units / unit G7400), and 0.2700 g of galactose oxidase G7400 (972 units / g of guar). Cationic oxidized guar is made in solution by mixing 6.6313g of cationic guar powder Galactasol SP813D (91.86% solids, available from Hercules Incoxpoxated), 2700 g of distilled water, 1026 g of 10% HCl, 1.5379 g of catalase C40 ( 3889 units / unit G7400), and 0.6863 g of galactose oxidase G7400 (972 units / g of guar). Leaves of pxueba to a base of 36.32 kg / 278.70 m2 (80 lb./3000 p.sz.), was made with leached kxaft pulp using a total additive level (Kymene MR + guar) of base pulp 1% dry weight. Table I shows the results for dry strength test. The use of Kymene ™ 557H oxidizes the dry strength in both oxidized anionic paxa guaxs and neutrals, and can sex as high as those obtained by oxidized cationic pox guax. Table I - Resistance to dry screening of oxidized guars with xesin Kymene ™ 557H Example 2 This example shows the effectiveness of cationic non-oxidized guar with oxidized anionic guar (AOG). AOG is made in solution as in example 1 when mixing 1900g of distilled water, 4,185g of Galactasol 70M22FD guar powder, 1.7g of 3% HCl, 0.038g of sodium benzoate, 0.1902g of catalase C40 (1852 units / unit G7400 ), and 0.2376 g of galactase oxidase G7400 (540 units / g guar). The mixture is stirred vigorously overnight. The cationic guar is (SP813D, not oxidized) is used as a 0.2% solution. Test sheets at a base of 36.32 kg / 278.70 m2 (80 lb / 3000 ft2), are made with leached kraft pulp using a total additive level of 1% pulp based. Table II shows the results for dry and wet tensile strength. The addition of cationic guar increases the dry and wet tensile strength of anionic oxidized guar. Table II - Dry and wet traction for AOG with cationic guar.

Example 3 This example shows the effectiveness of using cationic starch with neutral oxidized guar. The neutral oxidized guar is made in solution by mixing 1297.4 g of distilled water, 2,917 g of guax in flakes, (2.6 g dry) 0.4679 g of catalase C40 (3,704 units / unit G7400) and 0.2924 g of galactose oxidase G7400 (972) units / g guax). The solution mixes well two days before use. Cationic starch (Stalok 430, available from A.E. Staley Manufactuxing Co.) Paxa pxoducix is used as a 1% solution and the solution is baked at 90-100 ° C for 45 minutes before using it in pineapple leaves. Leaves of pxuebas to a base of 36.32 kg / 278.70 m2 (80 lb / 3000pies2), are made with leached kraft pulp using a total additive level of 1% pulp based. Table III shows the results for dry tensile strength. Cationic starch combined with oxidized guar neutxo (NOG) pxopoxciona high level in xesistencia of paper. Table III - Resistance to txacción paxa cationic starch with guars neutxos.

Example 4 This example illustrates the use of polyethyleneimine (Polymin P, available from BASF Coxpoxation) or cloxuxo polidiallildimetilamonio (RetenMR 203, from Hexcules Incorporated) with anionic oxidized guar. Oxidized anionic Guax is worked up with Example 1.

Leaves of pxueba of 36.32 kg / 278.70 m2 (80 lb / 3000pies2), elaboxan with kxaft leached pulp using anionic guax to 0.8% and 0.2% of RetenMR 203 or Polymin P based on the dry weight of the pulp. The cationic polymer is added to the pximexo feeder. The use of polymexos Polymin P or RetenMR 203 xesultaxá in paper with incxementada xesistencia to fxentexaction to that elaboxado with guax anionic 1% only. Example 5 This example illustrates the use of algaxxobo gum oxidized with xesin polyamidoamine-epichlorohydxin Kymene ™ 557H-. Algaxxobo gum is oxidized in accordance with the procedure to Supexcol U in Example 1. Leaves of 36.32 kg / 27.87 m2 (80 lb / 3000 pies2) are made with lixided kraft pulp, using 0.8% oxidized algarxobo gum and 0.2% of xesin Kymene ™ 557H based on the dry weight of the pulp. The KymeneMR xesina is added to the pximexo dosed. The use of xesina KymeneMR xesultaxá on paper with incxemented tensile strength versus that made with 1% oxidized locust bean gum only.

Claims (70)

1. CLAIMS 1. - Process for producing paper having improved strength characteristics, comprising providing pulp and adding (1) cationic polymer and (2) polymer containing oxidized galactose-type alcohol configuration wherein the alcohol has been oxidized in aldehyde, and laminar and drying the paper, provided that when the polymer containing oxidized galactose-type alcohol configuration is guar, it is chosen from the group consisting of oxidized neutral guar, oxidized anionic guar and oxidized amphoteric guar, wherein the configuration of the oxidizable galactose alcohol type is described by the following chemical structures: wherein: R1 = is an alkyl group of the formula C (n) H (2n + 1) wherein n = 0-20; z = 0, 1; wherein R 2 is a linking group which is composed of alkylene or an aromatic alkylene or an alkylene ether, or an alkylene ester or an alkylene amide, or a diradical alkylene urethane, wherein the linking group has a total number of carbon atoms. carbon from 2 to 20; where R3 = -H, -OH, -OCH3, -OC2H5, -OC3H7, -OC4H9, -OOCR5 (wherein R5 is an alkyl radical with 1 to 5 carbon atoms), -NH2, -NH-CO-R5; e y is 0, 1; and wherein the polymer containing oxidized galactose-type alcohol configuration is selected from the group consisting of oxidized galactomannan gums or their ester derivatives, oxidized arabinogalactan gums or their ester derivatives, other oxidized gums or their derivates étex, galactoglucomanan oxidized hemicelluloses or their dexivatives ester and modified polymers enzymatically or synthetically oxidized.
2. 2. The method according to claim 1, characterized in that the cationic polymer is soluble in water.
3. 3. The process according to claim 1, characterized in that the cationic polymer is dispersible in water.
4. 4. The process according to claim 1, characterized in that in the polymer containing oxidized galactose-type alcohol configuration, at least about 5 mol% of the oxidizable galactose-type alcohol has been oxidized in aldehyde. 5. - The effect of consistency with the claim 1, characterized in that the weight average molecular weight of the polymexo containing oxidized galactose type alcohol configuxation is at least about 5,000. 6. - The operation of confectomidad with the reivindicacion 1, caxactexizado because the molecular weight pxomedio in weight of the polymer that contains alcohol configuration of galactosa oxidized type is until apximximamente 5, 000, 000. 7. - The pxocedimiento of confoxmidad with the reivindicacion 1 , characterized in that the total amount of cationic and polymeric polymexo containing alcohol configuxation of oxidized galactose type added to the pulp is at least about 0.05% based on the dry weight of the pulp. 8. - The operation of confounding with the claim 1, cachactexized by the total amount of cationic polymer and polymer containing oxidized galactose-type alcohol configuration added to the pulp is at least about 5% based on the dry weight of the pulp . 9. - The method according to claim 1, characterized in that the weight ratio of the polymer containing oxidized galactose-type alcohol configuration to the cationic polymer is from about 1 to 20. 10. The process according to claim 1, wherein The weighting of the polymeox containing oxidized galactose-type alcohol configuxation to the cationic polymer is up to about 100 to 1. 11. The process according to claim 1, wherein the cationic polymer is selected from the group consisting of xesins. polymeric amine-epycloxyhydrin, polysaccha- rides, polyamines, polyethylene imine, vinyl alcohol-vinyl alcohol copolymers and homo- and co-polymer acrylics. 12. The process according to claim 1, characterized in that the polymer containing oxidized galactose-type alcohol configuxation is obtained by oxidation with galactose oxidase. 13. The process according to claim 1, characterized in that the cationic polymer and the polymer containing oxidized galactose-type alcohol configuration are added to the pulp before rolling. 14. The process according to claim 1, characterized in that the cationic polymer and the polymer containing oxidized galactose-type alcohol configuration are added to the pulp after rolling. 15. - The effect of consistency with claim 4, characterized in that the weight-average molecular weight of the polymer containing oxidized galactose-type alcohol configuration is up to about 5,000 to about 5,000,000, the cationic polymer is water-soluble or water-dispersible, The total amount of the cationic polymer and polymer containing oxidized galactose alcohol configuxation agxegado to the pulp is approximately 0.05 to approximately 5% based on the dry weight of the pulp, the pxopoxción in weight of polmexo containing configuxación alcohol type The oxidized galactose is from about 1:20 to about 100: 1, the cationic polymer is selected from the group consisting of polymexic amine-epycloxydrine xesins, polysaccharides, polyamines, polyethylenimine, vinyl alcohol-vinyl amine copolymers, and acrylic homo- and copolymers, and the polymer containing oxidized galactose alcohol configuxation has been obtained by oxidation with galactose oxidase. 16. The process according to claim 15, characterized in that in the polymer containing oxidized galactose-type alcohol configuration, at least about 25 mol% of the oxidizable galactose-type alcohol configuration has been oxidized in aldehyde. 17. The process according to claim 15, characterized in that the total amount of cationic polymer and polymer containing oxidized galactose-type alcohol configuration is at least about 0.1% based on the dry weight of the pulp. 18. The process according to claim 15, wherein the total amount of cationic polymer and polymer containing oxidized galactose-type alcohol configuration is up to about%, based on the dry weight of the pulp. 19. The process according to claim 15, characterized in that the polymerization by weight of polymexo containing oxidized galactose-type alcohol configuxation to the cationic polymer is about 1: 4. - 20. - The effect of consistency with the claim 15, which is chaxctexized, because the weighting of the polymer containing oxidative galactose-type alcohol configuxation to the cationic polymer is up to about 50: 1. 21. The process according to claim 15, characterized in that the polymeric amine-epichlorohydrin xesin is selected from the group consisting of amine-epichlorohydrin resin (PAE), polyalkylene polyamine-epichlorohydrin resin (PAPAE) and amine-epichlorohydrin polymer resin (APE), wherein the polymeric epichlorohydrin resin in the amine groups has been alkylated with epichlorohydrin to produce polyamine-epichlorohydrin resin having azetidinium or epoxide functionality; the polysaccharides have been selected from the gxupo consisting of starch, guax, cellulose, and chitin; acrylic cationic homo- and co-polymers are chosen from the group consisting of polydiallyldimethylammonium chlorides and acrylic acid copolymers, acylic acid and acylamide sulphides with ammonium diphenyl chloride, acryloyloxyethyl trimethylammonium chloride, metal methylsulfate acxi loi loxie ti 1 t xime ti lamonio, methacryloyloxyethyltrimethylammonium cloxuxo and methacrylamidopropyltrimethylammonium chloride. 22. The confounding method with claim 15, characterized in that the oxidized galactomannan gum is selected from the group consisting of oxidized guax, oxidized algaxxobo, oxidized taxa and oxidized fenugxeek gum, or its ether dexivates; the oxidized arabinogalactan gum is selected from the group consisting of oxidized tragacanth gum and oxidized arabic, oxidised alexce or its dexivated étex, the other oxidized gum is selected from the group consisting of oxidized carubin, oxidized lichens and oxidized galactane potato gum or its ether derivatives and synthetic or enzymatically modified oxidized polymers are selected from the group consisting of polysaccharides deficient in galactose, polyacrylates, polyacrylamides, polyvinyl alcohol and polyvinyl acetate. 23. The confounding process with the claim 15, cachactexized by the cationic polymer and the polymer containing oxidized galactose-type alcohol configuration is added to the pulp before rolling. 24. - The effect of consistency with the claim 15, cachactexized because the cationic polymer and the polymer containing oxidized galactose type alcohol configuration are added to the pulp after laminating. 25. The process according to claim 16, characterized in that the total amount of cationic polymer and polymer containing oxidized galactose-type alcohol configuration is from about 0.1% to about 1% based on the dry weight of the pulp, the The polymer composition containing oxidized galactose-type alcohol configuration to cationic polymer is from about 1: 4 to about 50: 1, the polymeric amine-epichlorohydrin amine resin is selected from the group consisting of polyamide-epichlorohydrin (PAE) resin, resin polyalkylene polyamine-epichlorohydrin (PAPAE) and polymexo amine-epichlorohydrin resin (APE), wherein in the polymeric amine-epichlorohydrin resin the amine groups have been alkylated with epichlorohydrin to produce a polyamine-epichlorohydroxy resin having azetidinium or epoxide functionality, the polysaccharides are have selected from the group consisting of starch, guar, cellulose, and chitin; the cationic acrylic homo- and co-polymers are selected from the group consisting of polydiallyldimethylammonium chloride and copolymers of acylic acid, acrylic esters and acrylamide with di-allyl dimethyl ammonium chloride, acyloxyloxyethyl chloride, and methyl methacrylate. methacryloxylate and 11-dimethylammonium, methacryloyloxyethyltrimethylammonium chloride and methacrylamidoptophoxymethyl-methylammonium chloride, the oxidized galactomannan gum is selected from the group consisting of oxidized guar, oxidized algarxobo, oxidized taxa, fenugreek oxidized gum, or their dexivated esters; the oxidized arabinogalactan gum is chosen from the gxupo consisting of oxidized alexce, oxidized gum arabic and oxidized tragacanth, or its ether derivatives, the oxidized gum oxide is selected from the gxupo consisting of oxidized carubin, oxidized lichen and gum arabic oxidized gum or its dexivates Etex, the oxidized synthetic or enzymatically modified polymer is chosen from the gxupo consisting of polysaccharides deficient in galactose, polyaxylates, polyaxylamides, polyvinyl alcohol and p-vinyl acetate and the viscosity of the polymexo containing configuxation of oxidized galactose-type alcohol is approximately 15 cps a 2% by weight in solution in water at approximately 10,000 cps to 1% by weight in solution in water. 26. The process according to claim 25, characterized in that the oxime-containing galactose alcohol-containing polymexo contains at least about 50 mol% of the configuxation of the oxidizable galactose-type alcohol has been oxidized in aldehyde. 27. The process of concluding with claim 25, wherein the total amount of cationic and polymeric polymexo containing oxidized galactose-type alcohol configuxation is at least about 0.15% based on the dry weight of the pulp. 28. The process of confounding with the claim 25, caxactexizado poxque the total amount of cationic polymer and polymer containing configuxación alcohol of galactosa oxidized type is up to approximately 0.5%, based on the dry weight of the pulp. 29.- The operation of confounding with claim 25, which is chaxctexized, because the polymerization of oxidized galactose-type alcohol-containing polymer to the cationic polymer is up to about 1: 1. - - The operation of consistency with the claim 25, characterized in that the weight ratio of polymex containing oxidized galactose type alcohol configuxation to the cationic polymer is up to about 22: 1. 31. The process according to claim 25, characterized in that the cationic polymer is selected from the group consisting of starch, guar, polyamidoamine-epichlorohydrin resins and acrylic copolymers. 32. The process according to claim 25, characterized in that the polymer containing oxidized galactose-type alcohol configuration comprises oxidized guar. 33. - The process according to claim 32, characterized in that the viscosity of the guar to be oxidized is at least about 100 cps in a 1% by weight solution in water. 34. The process according to claim 32, characterized in that the viscosity of the guar to be oxidized is up to about 6,000 cps to 1% by weight in water solution. 35. The process according to claim 25, characterized in that the cationic and polymexo polymer containing oxidized galactose-type alcohol configuxation is added to the pulp before being laminated. 36. The process according to claim 25, characterized in that the cationic polymer and oxidized galactose alcohol-containing polymer configuxation are added to the pulp after rolling. 37.- The reaction of confounding with the claim 26, characterized by the oxidized boron-containing alcohol configuxation containing oxidized boron, the total amount of the oxidized cationic and guar polymer from about 0.15 to about 0.5% based on the dry weight of the pulp, the ratio of oxidized guar to cationic polymer is from about 1: 1 to about 20: 1, the cationic polymer is selected from the group consisting of starch, guar, polyamidoamine-epichlorohydrin resins and acrylic copolymers and the viscosity of the guar to be oxidized is about 100 cps to 1% by weight of solution in water to about 6,000 cps to 1% by weight in water. 38.- Paper having improved dry strength, comprising (1) cationic polymer and (2) polymer containing oxidized galactose-type alcohol configuration, wherein the galactose-type alcohol has been oxidized in aldehyde, provided that when the polymexo contains configuxation oxidized galactose type alcohol is guax, it is chosen from the gxupo consisting of oxidized neutral guax, oxidized anionic guar and oxidized amphoteric guar, where the configuxation of oxidizable galactose alcohol type is decxied by the following chemical stxuctuxes: ll! wherein: R1 = is an alkyl group of the formula C (n) H (2n + 1) wherein n = 0-20; z = 0, 1; wherein R2 is a linking group which is composed of alkylene or an aromatic alkylene or an alkylene ether, or an alkylene estex or an alkylene amide, or a dixadical alkylene oxetane, wherein the bonding group has a total number of carbon atoms. caxbono from 2 to 20; wherein R3 = -H, -OH, -OCH3, -OCzHs, -OC3H7, -OC4H9, -OOCR5 (wherein R5 is an alkyl radical with 1 to 5 carbon atoms), -NH2, -NH-CO-R5; e y is 0 or 1; and wherein the polymexo containing oxidized galactose alcohol configuxation is chosen from the gxupo consisting of oxidized galactomannan gums or their dexivated estox, oxabinogalactan oxidized gums or their ester dexivatives, other oxidized gums or their dexivated étex, oxidized hemicelluloses galactoglucomannan or their dexivatives estox and enzymatically or synthetically oxidized modified polymexes. 39. The confounding role with the claim 38, caxactexized because the cationic polymer is chosen from the gxupo consisting of polymexic amino-epycloxydrine xesins, polysaccharides, polyamines, polyethylenimine, vinyl alcohol-vinyl amine copolymers, and homo- and co-polymers acyclic 40. The confounding paper with claim 38, characterized in that in the polymer containing oxidized galactose-type alcohol configuxation, at least about 5 mol% of the oxidizable galactose-type alcohol has been oxidized in aldehyde. 41. The paper according to claim 38, characterized in that the weight average molecular weight of the polymer containing alcohol configuration. of oxidized galactose type is at least about 5,000. 42. - The paper according to claim 38, characterized in that the weight average molecular weight of the polymexo containing oxidized galactose type alcohol configuxation is up to about 5, 000, 000. 43. - Confounding paper with claim 38, characterized in that the total amount of cationic polymer and polymer containing oxidized galactose type alcohol configuration is at least about 0.05% based on the dry weight of the paper . 44. - The paper according to claim 38, characterized in that the total amount of cationic polymer and polymer containing oxidized galactose-type alcohol configuration is up to about 5% based on the dry weight of the paper. 45. The confounding role with the claim 38, characterized in that the weight proportion of the polymer containing oxidized galactose-type alcohol configuration to the cationic polymer is at least about 1:20. 46. The paper according to claim 38, characterized in that the weight ratio of polymer containing oxidized galactose-type alcohol configuration to the cationic polymer is up to about 100: 1. 47. The paper according to claim 40, characterized in that the weight-average molecular weight of the polymer containing oxidized galactose-type alcohol configuration is up to about 5,000 to about 5,000,000, the cationic polymer is water-soluble or water-dispersible, the total amount of the cationic polymexo polymer containing oxidized galactose type alcohol configuxation is approximately 0.05 to approximately 5% based on the dry weight of the paper, the weight percent of the polymer containing oxidized galactose type alcohol configuxation is approximately 1:20 to about 100: 1, the cationic polymer is selected from the group consisting of polymeric amine-epichlorohydrin resins, polysaccharides, polyamines, polyethyleneimine, vinyl alcohol-vinyl amine copolymers, and acyl homo- and co-polymers; and the viscosity of the polymeox containing oxidized galactose-type alcohol configuxation is from about 15 cps to 2% by weight in solution in water to about 10,000 cps to 1% by weight in solution in water. 48.- The paper according to claim 47, caxactexizado poxque polyexica amine-epicloxhidxina xesina is chosen from gxupo consisting of xesina polyamine-epicloxhidxina (PAE), xesina polyalquilenepolyamine-epicloxohydrin (PAPAE) and polimexo resin amina-epicloxhidxina (APE) ), wherein in the polymeric amino-epichlorohydrin resin the amine gxupos have been alkylated with epidotoxoxydine paxa pxoducix a xesin polyamine-epycloxohidxin having azetidinium or epoxide functionality; the polysaccharides are chosen from the gxupo consisting of starch, guar, cellulose, and chitin; and acylic cationic homo- and co-polymexes are chosen from the group consisting of polydiallyldimethylammonium cloxuxes and acrylic acid copolymexes, acyl esters and acylamide with diallyldimethylammonium cloxux, acyloyloxyethyldimethylammonium cloxux, methacryloyloxyethyl trimethylammonium methylsulfate, methacryloyloxyethyltrimethylammonium and cloxuxo of acylamylamidopxopytimethylammonium me. 49. The paper according to claim 47, wherein the oxidized galactomannan gum is selected from the group consisting of oxidized guax, oxidized algaxrobo, oxidized tara and oxidized fenugreek gum, or higher ether, oxidized arabinogalactan gum is selected from the group which consists of oxidized LA1 and oxidized tragacanth gum or its ether dexivates, and the oxidized gum is selected from the gxupo consisting of oxidized carubin, oxidized lichen, and oxidized galactane potato gum or its exemplary derivatives. 50. The paper according to claim 47, characterized in that the polymer containing oxidized galactose-type alcohol configuration, is at least about 25% of the oxidizable galactose-type alcohol has been oxidized to the aldehyde. 51. The paper according to claim 47, which is chaxctexized by the polymer containing oxidized galactose-type alcohol configuxation, has been obtained by oxidation with galactose oxidase. .52.- The confounding paper with the claim 47, cachactexized because the total amount of cationic polymer and polymer containing oxidized galactose type alcohol configuration is at least about 2.1% based on the dry weight of the paper. 53. The paper according to claim 47, characterized in that the total amount of cationic polymer and polymer containing oxidized galactose-type alcohol configuration is up to about 1% based on the dry weight of the paper. 54.- The paper in accordance with claim 47, characterized in that the proportion of polymer containing oxidized galactose-type alcohol configuration to the cationic polymer is at least about 1: 4. 55.- The paper according to claim 47, characterized in that the proportion of polymer containing oxidized galactose-type alcohol configuration to the cationic polymer is up to about 50: 1. 56.- The paper in accordance with claim 50, which is chaxctexed because the total amount of cationic and polymex polymer containing oxidized galactose-type alcohol configuxation is up to about 0.1 to about 1% based on the dry weight of the paper or the pxopoxtion of Polymex containing oxidized galactose-type alcohol configuration containing polymer to cationic polymer is about 1: 4 to about 50: 1, the polymeric amine-epycloxydrine xesin is chosen from the group consisting of 1-xenosine 1 -amide-1-epichlorohydrin ( PAE), polyalkylenepolyamine-epichlorohydrin resin (PAPAE) and amine-epichlorohydrin polymer resin (APE), wherein in the polymeric amine-epizoxydrine xesin the amino groups have been alkylated with epidotoxin paxa pxoducir a polyamine-epichlorohydrin resin having azetidinium or epoxide functionality , the polysaccharides have been selected from the group consisting of starch, guar, cellulose, and chitin; the acylic cationic homo- and co-polymers are chosen from the group consisting of polydiallyldimethylammonium cloxux and acrylic acid copolymexes, acrylic esters and acylamide with diolyl di methyl ammonium cloxue, acyloyloxyethyl oximexylammonium cloxue, methylsulphate methyloxyethyltrimethylammonium methyloxyethyl methoxyloxyethyl methylammonium chloride and methacrylamidopropytrimethylammonium chloride, the oxidized galactomannan gum is selected from the group consisting of oxidized guax, oxidized algaxxobo, oxidized taxa, oxidized fenugxeek gum, or their ether dexivates; the oxidized axabinogalactane gum is selected from the group consisting of oxidized larch, oxidized gum arabic and oxidized tragacanth, or its ether derivatives, the other oxidized gum is selected from the group consisting of oxidized carubin, oxidized lichen and gum potato oxidized galactane or its derivatives ether, the oxidized synthetic or enzymatically modified polymexo is chosen from the gxupo consisting of galactose-deficient polysaccharides, polyacrylates, polyaxylamides, polyvinyl alcohol and ponivinyl acetate and the viscosity of the polymexo containing oxidized galactose-type alcohol configuration is about 100 cps at 1% by weight of solution in water to about 6,000 cps to 1% by weight in solution in water. 57. The paper according to claim 56, characterized in that the polymer containing oxidized galactose-type alcohol-containing polymexo contains oxidized guax and the cationic polymexo is selected from the group consisting of starch, guar, polyamidoamine-epichlorohydrin resins and acyl copolymers. 58. The confounding role with the claim 56, characterized in that the oxidized guax is at least about 50 mol% of the galactose-type alcohol that has been oxidized in aldehyde. 59. The confounding role with the claim 57, characterized in that the total amount of oxidized cationic and guar polymer is at least about 0.5% based on the dry weight of the paper. 60. The paper according to claim 57, wherein the total amount of cationic polymexo and oxidized guax is up to about 0.5% based on the dry weight of the paper. 61. - The confounding role with the claim 57, cachactexized because the proportion of oxidized guar in cationic polymer is at least about 1: 1. 62. - The confounding paper with claim 57, characterized in that the proportion of oxidized guar in cationic polymer is approximately up to 20: 1. 63. The paper according to claim 1, characterized in that the synthetic or enzymatically oxidized modified polymer is selected from the group consisting of polysaccharides deficient in galactose, polyacrylates, polyacrylamides, polyvinyl alcohol and polyvinyl acetate. 64. The confounding paper with claim 38, characterized in that the synthetic or enzymatically oxidized modified polymer is selected from the group consisting of galactose-deficient polysaccharides, polyacrylates, polyacrylamides, polyvinyl alcohol and polyvinyl acetate. 65. The paper according to claim 15, characterized in that the viscosity of the polymexo containing oxidized galactose-type alcohol configuxation is at least about 15 cps to 2% by weight of solution in water. 66 - The paper according to claim 15, characterized in that the viscosity of the polymer containing oxidized galactose type alcohol configuxation is up to about 8,000 cps to 1% by weight of solution in water. 67. The confounding paper with the claim 38, characterized in that the viscosity of the polymexo containing oxidized galactose type alcohol configuxation is at least about 15 cps to 2% by weight of solution in water. 68. The confounding paper with claim 38, characterized in that the viscosity of the polymer containing oxidized galactose-type alcohol configuration is up to about 8,000 cps to 1% by weight of solution in water. 69. The confounding paper with the claim 47, characterized in that the viscosity of the polymeox containing oxidized galactose type alcohol configuxation is at least about 100 cps to 1% by weight of solution in water. 70. The confounding paper with claim 47, characterized in that the viscosity of the polymer containing oxidized galactose-type alcohol configuration is up to about 6,000 cps to 1% by weight of solution in water.