MX9700816A - Complejos de biciclopentadienil-dieno. - Google Patents

Complejos de biciclopentadienil-dieno.

Info

Publication number
MX9700816A
MX9700816A MX9700816A MX9700816A MX9700816A MX 9700816 A MX9700816 A MX 9700816A MX 9700816 A MX9700816 A MX 9700816A MX 9700816 A MX9700816 A MX 9700816A MX 9700816 A MX9700816 A MX 9700816A
Authority
MX
Mexico
Prior art keywords
biscyclopentadienyl
complexes
group
halide
diene complexes
Prior art date
Application number
MX9700816A
Other languages
English (en)
Other versions
MXPA97000816A (es
Inventor
Francis J Timmers
David D Devore
James C Stevens
Robert K Rosen
Jasson T Patton
David R Neithamer
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26962891&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=MX9700816(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from US08/481,791 external-priority patent/US6465384B1/en
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of MX9700816A publication Critical patent/MX9700816A/es
Publication of MXPA97000816A publication Critical patent/MXPA97000816A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polyamides (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Catalysts (AREA)

Abstract

Se forman complejos de metales de transicion del Grupo 4 de bisciclopentadienilo, poniendo en contacto un complejo de haluro de metal del Grupo 4 de bisciclopentadienilo, hidrocarbilo, hidrocarbiloxi o amida con un dieno conjugado. Unicamente, el ansarac a la forma de haluro si se desea. Cuando se combinan con dichos cocatalizadores de activacion normales, o se activan con una técnica de activacion, los complejos forman catalizadores para olefinas de polimerizacion, diolefinas y/o monomeros acetilenicamente insaturados.
MXPA/A/1997/000816A 1994-08-02 1995-07-14 Complejos de biciclopentadienil-dieno MXPA97000816A (es)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US28492594A 1994-08-02 1994-08-02
US284925 1994-08-02
US284,925 1994-08-02
US08/481,791 US6465384B1 (en) 1994-08-02 1995-06-07 Biscyclopentadienyl diene complexes
US08481791 1995-06-07
PCT/US1995/008813 WO1996004290A1 (en) 1994-08-02 1995-07-14 Biscyclopentadienyl diene complexes

Publications (2)

Publication Number Publication Date
MX9700816A true MX9700816A (es) 1997-09-30
MXPA97000816A MXPA97000816A (es) 1998-07-03

Family

ID=

Also Published As

Publication number Publication date
WO1996004290A1 (en) 1996-02-15
BR9508889A (pt) 1997-09-30
MY113182A (en) 2001-12-31
DE69528781T2 (de) 2003-07-03
FI970429A (fi) 1997-01-31
CN1154668C (zh) 2004-06-23
AU3009095A (en) 1996-03-04
ES2137532T3 (es) 1999-12-16
ES2137532T5 (es) 2003-07-01
AU693578B2 (en) 1998-07-02
CA2195789A1 (en) 1996-02-15
NZ290066A (en) 1998-02-26
TW449604B (en) 2001-08-11
IL114790A0 (en) 1995-11-27
JPH10503517A (ja) 1998-03-31
EP0775148B1 (en) 1999-08-25
NO970441L (no) 1997-03-26
PL184500B1 (pl) 2002-11-29
PL318434A1 (en) 1997-06-09
RU2135508C1 (ru) 1999-08-27
CN1058015C (zh) 2000-11-01
JP3996184B2 (ja) 2007-10-24
CN1263894A (zh) 2000-08-23
DE69511707D1 (de) 1999-09-30
DE69511707T3 (de) 2003-10-16
CA2195789C (en) 2007-03-20
ATE183748T1 (de) 1999-09-15
EP0775148A1 (en) 1997-05-28
CN1156997A (zh) 1997-08-13
CN1260350A (zh) 2000-07-19
HUT77589A (hu) 1998-06-29
US5616664A (en) 1997-04-01
DE69528781D1 (de) 2002-12-12
US5527929A (en) 1996-06-18
IL114790A (en) 2002-05-23
EP0775148B2 (en) 2003-01-02
ES2182403T3 (es) 2003-03-01
FI970429A0 (fi) 1997-01-31
CZ31697A3 (en) 1997-05-14
ATE227300T1 (de) 2002-11-15
HU225300B1 (en) 2006-09-28
US5972822A (en) 1999-10-26
NO970441D0 (no) 1997-01-31
DE69511707T2 (de) 1999-12-16
CN1176093C (zh) 2004-11-17

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Legal Events

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FG Grant or registration
MM Annulment or lapse due to non-payment of fees