MX374188B - Líquidos zwitteriónicos geminales ramificados, proceso de obtención y uso como modificadores de la mojabilidad con propiedades reductoras de la viscosidad. - Google Patents
Líquidos zwitteriónicos geminales ramificados, proceso de obtención y uso como modificadores de la mojabilidad con propiedades reductoras de la viscosidad.Info
- Publication number
- MX374188B MX374188B MX2014006223A MX2014006223A MX374188B MX 374188 B MX374188 B MX 374188B MX 2014006223 A MX2014006223 A MX 2014006223A MX 2014006223 A MX2014006223 A MX 2014006223A MX 374188 B MX374188 B MX 374188B
- Authority
- MX
- Mexico
- Prior art keywords
- betaine
- polyether
- bis
- zwitterionic liquids
- polar
- Prior art date
Links
- 239000007788 liquid Substances 0.000 title abstract 4
- 239000003607 modifier Substances 0.000 title 1
- 229960003237 betaine Drugs 0.000 abstract 4
- 238000004519 manufacturing process Methods 0.000 abstract 4
- 239000003921 oil Substances 0.000 abstract 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 235000019738 Limestone Nutrition 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 1
- 230000008901 benefit Effects 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000010459 dolomite Substances 0.000 abstract 1
- 229910000514 dolomite Inorganic materials 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 239000000295 fuel oil Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- 239000006028 limestone Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 239000012454 non-polar solvent Substances 0.000 abstract 1
- 239000002798 polar solvent Substances 0.000 abstract 1
- 239000010453 quartz Substances 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 239000011435 rock Substances 0.000 abstract 1
- -1 sandstone Substances 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052712 strontium Inorganic materials 0.000 abstract 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/584—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C227/14—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton from compounds containing already amino and carboxyl groups or derivatives thereof
- C07C227/16—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton from compounds containing already amino and carboxyl groups or derivatives thereof by reactions not involving the amino or carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
- C07C229/04—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
- C07C229/06—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton
- C07C229/10—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton the nitrogen atom of the amino group being further bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
- C07C229/12—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton the nitrogen atom of the amino group being further bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings to carbon atoms of acyclic carbon skeletons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
- C07C229/04—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
- C07C229/26—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having more than one amino group bound to the carbon skeleton, e.g. lysine
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/16—Amines or polyamines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/18—Quaternary ammonium compounds
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/24—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Geology (AREA)
- Mining & Mineral Resources (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Fluid Mechanics (AREA)
- Geochemistry & Mineralogy (AREA)
- Physics & Mathematics (AREA)
- Environmental & Geological Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
La presente invención se relaciona con el proceso de obtención y uso de líquidos zwitteriónicos geminales ramificados base bis-N,N-dialquil-N-poliéter-betaína o bis-N,N-dialquenil-N-poliéter-betaína o bis-N,N-dicicloalquil-N-poliéter-betaína o bis-N,N-diaril-N-poliéter-betaína, como modificadores de la mojabilidad de rocas como caliza, dolomita, arenisca, cuarzo o litologías heterogéneas, en presencia de salmueras con alto contenido de iones divalentes como calcio, magnesio, bario y estroncio, alta temperatura y alta presión en procesos de recuperación mejorada de petróleo para incrementar la producción de petróleo. Los líquidos zwitteriónicos geminales ramificados de la presente invención tienen además la propiedad de actuar como reductores de la viscosidad para aceites pesados con alto contenido de fracciones polares, tanto en operaciones de extracción y producción como de transporte y almacenamiento, permitiendo así incrementar el nivel de producción de este tipo de aceites. Una ventaja adicional que presentan los líquidos zwitteriónicos derivada de su estructura molecular es que pueden ser manipulados de tal forma que les permita ser solubles en agua, en hidrocarburo o en otros disolventes polares y no polares.
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MX2014006223A MX374188B (es) | 2014-05-23 | 2014-05-23 | Líquidos zwitteriónicos geminales ramificados, proceso de obtención y uso como modificadores de la mojabilidad con propiedades reductoras de la viscosidad. |
| CA2943679A CA2943679C (en) | 2014-05-23 | 2015-05-21 | Branched geminal zwitterionic liquids, obtaining process and their usage as wettability modifiers having viscosity reducing properties |
| BR112016024750-7A BR112016024750B1 (pt) | 2014-05-23 | 2015-05-21 | Líquidos zwitteriônicos germinais ramificados, processo para obtenção de líquidos zwitteriônicos germinais ramificados, e, uso de líquidos zwitteriônicos germinais ramificados |
| PCT/MX2015/000077 WO2015178753A1 (es) | 2014-05-23 | 2015-05-21 | Líquidos zwitteriónicos geminales ramificados, proceso de obtención y uso como modificadores de la mojabilidad con propiedades reductoras de la viscosidad |
| US15/313,545 US10689563B2 (en) | 2014-05-23 | 2015-05-21 | Branched geminal zwitterionic liquids, method for obtaining same and use thereof as wettability modifiers having viscosity reducing properties |
| US16/907,492 US10968381B2 (en) | 2014-05-23 | 2020-06-22 | Branched geminal zwitterionic liquids, method for obtaining same and use thereof as wettability modifiers having viscosity reducing properties |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MX2014006223A MX374188B (es) | 2014-05-23 | 2014-05-23 | Líquidos zwitteriónicos geminales ramificados, proceso de obtención y uso como modificadores de la mojabilidad con propiedades reductoras de la viscosidad. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2014006223A MX2014006223A (es) | 2015-11-23 |
| MX374188B true MX374188B (es) | 2025-03-05 |
Family
ID=54554331
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2014006223A MX374188B (es) | 2014-05-23 | 2014-05-23 | Líquidos zwitteriónicos geminales ramificados, proceso de obtención y uso como modificadores de la mojabilidad con propiedades reductoras de la viscosidad. |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US10689563B2 (es) |
| BR (1) | BR112016024750B1 (es) |
| CA (1) | CA2943679C (es) |
| MX (1) | MX374188B (es) |
| WO (1) | WO2015178753A1 (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111119819B (zh) * | 2020-01-21 | 2022-04-05 | 中国石油大学(华东) | 一种降低注聚驱油水井聚合物吸附的方法 |
| CN117431050B (zh) * | 2023-10-13 | 2025-07-04 | 陕西邦达诺环保科技有限公司 | Gemini型异构烷基磺基甜菜碱驱油剂及制备方法 |
| CN120519137B (zh) * | 2025-07-21 | 2025-11-18 | 克拉玛依市昊源天成能源科技有限公司 | 一种防硼耐盐聚合物悬浮乳液及其制备方法 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3643738A (en) | 1970-05-28 | 1972-02-22 | Marathon Oil Co | Wettability control in an oil recovery process |
| US4509951A (en) | 1984-06-13 | 1985-04-09 | Ethyl Corporation | Corrosion inhibitor for alcohol and gasohol fuels |
| US5013462A (en) | 1985-10-24 | 1991-05-07 | Pfizer Inc. | Method for improving production of viscous crude oil |
| US4769160A (en) | 1986-07-31 | 1988-09-06 | Ciba-Geigy Corporation | Use of organic fluorochemical compounds with oleophobic and hydrophobic groups in asphaltenic crude oils as viscosity reducing agents |
| US4842065A (en) | 1988-05-11 | 1989-06-27 | Marathon Oil Company | Oil recovery process employing cyclic wettability alteration |
| US5042580A (en) | 1990-07-11 | 1991-08-27 | Mobil Oil Corporation | Oil recovery process for use in fractured reservoirs |
| US6204297B1 (en) | 1996-11-26 | 2001-03-20 | Rhodia Inc. | Nonionic gemini surfactants |
| US5952290A (en) | 1997-11-26 | 1999-09-14 | Rhodia Inc. | Anionic gemini surfactants and methods for their preparation |
| DE10121724A1 (de) | 2001-05-04 | 2002-11-07 | Cognis Deutschland Gmbh | Geminitenside |
| DE10137925A1 (de) | 2001-08-07 | 2003-02-20 | Cognis Deutschland Gmbh | Geminitenside und Polyethylenglycol |
| US7041707B2 (en) | 2003-01-24 | 2006-05-09 | Nalco Company | Polyether polyesters having anionic functionality |
| EP1668288A1 (en) | 2003-10-02 | 2006-06-14 | Proflux Systems LLP | Method for reducing the viscosity of viscous fluids |
| GB0408145D0 (en) | 2004-04-13 | 2004-05-19 | Aubin Ltd | Crude oil mobility |
| US20090054368A1 (en) | 2007-07-06 | 2009-02-26 | University Of Saskatchewan | Substituted gemini surfactant compounds |
| US7608571B2 (en) | 2007-07-20 | 2009-10-27 | Rhodia Inc. | Method for recovering crude oil from a subterranean formation utilizing a polyphosphate ester |
| US7923416B2 (en) | 2008-11-06 | 2011-04-12 | Nalco Company | Method of reducing the viscosity of hydrocarbon fluids |
| MX2009013704A (es) | 2009-12-15 | 2011-06-15 | Mexicano Inst Petrol | Nuevos surfactantes geminales, proceso de obtencion y uso como inhibidores de corrosion multifuncionales. |
| MX2010012348A (es) | 2010-11-12 | 2012-05-15 | Mexicano Inst Petrol | Composicion base liquidos zwitterionicos geminales como modificadores de la mojabilidad en procesos de recuperacion mejorada de petroleo. |
| MX346225B (es) | 2013-06-28 | 2017-02-17 | Inst Mexicano Del Petróleo | Uso de liquidos zwitterionicos en la remocion e inhibicion del daño por depositos organicos, en formaciones productoras de hidrocarburos. |
-
2014
- 2014-05-23 MX MX2014006223A patent/MX374188B/es active IP Right Grant
-
2015
- 2015-05-21 WO PCT/MX2015/000077 patent/WO2015178753A1/es not_active Ceased
- 2015-05-21 CA CA2943679A patent/CA2943679C/en active Active
- 2015-05-21 BR BR112016024750-7A patent/BR112016024750B1/pt active IP Right Grant
- 2015-05-21 US US15/313,545 patent/US10689563B2/en active Active
-
2020
- 2020-06-22 US US16/907,492 patent/US10968381B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| MX2014006223A (es) | 2015-11-23 |
| US10689563B2 (en) | 2020-06-23 |
| BR112016024750B1 (pt) | 2022-08-02 |
| CA2943679C (en) | 2021-02-16 |
| BR112016024750A2 (pt) | 2017-08-15 |
| WO2015178753A1 (es) | 2015-11-26 |
| US20170335171A1 (en) | 2017-11-23 |
| CA2943679A1 (en) | 2015-11-26 |
| US10968381B2 (en) | 2021-04-06 |
| US20200317991A1 (en) | 2020-10-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |