MX341855B - Hydropyrolysis of biomass for producing high quality liquid fuels. - Google Patents
Hydropyrolysis of biomass for producing high quality liquid fuels.Info
- Publication number
- MX341855B MX341855B MX2013011082A MX2013011082A MX341855B MX 341855 B MX341855 B MX 341855B MX 2013011082 A MX2013011082 A MX 2013011082A MX 2013011082 A MX2013011082 A MX 2013011082A MX 341855 B MX341855 B MX 341855B
- Authority
- MX
- Mexico
- Prior art keywords
- biomass
- producing
- liquid fuels
- hydropyrolysis
- high quality
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
- C10G3/46—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof in combination with chromium, molybdenum, tungsten metals or compounds thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/60—Controlling or regulating the processes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
- C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
- C01B2203/0822—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel the fuel containing hydrogen
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
- C01B2203/0827—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel at least part of the fuel being a recycle stream
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1247—Higher hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1258—Pre-treatment of the feed
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1011—Biomass
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4081—Recycling aspects
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/04—Diesel oil
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Abstract
A self-sustaining process for producing liquid fuels from biomass in which the biomass is hydropyrolyzed in a reactor vessel containing molecular hydrogen and a deoxygenating catalyst, producing a partially deoxygenated pyrolysis liquid, which is hydrogenated using a hydroconversion catalyst, producing a substantially fully deoxygenated pyrolysis liquid and a gaseous mixture comprising CO and light hydrocarbon gases (C1-C4). The gaseous mixture is reformed in a steam reformer, producing reformed molecular hydrogen, which is then introduced into the reactor vessel for hydropyrolizing the biomass. The deoxygenated liquid product is further processed to produce diesel fuel and gasoline.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/419,535 US20100251600A1 (en) | 2009-04-07 | 2009-04-07 | Hydropyrolysis of biomass for producing high quality liquid fuels |
PCT/US2010/001019 WO2010117436A1 (en) | 2009-04-07 | 2010-04-05 | Hydropyrolysis of biomass for producing high quality liquid fuels |
Publications (1)
Publication Number | Publication Date |
---|---|
MX341855B true MX341855B (en) | 2016-09-05 |
Family
ID=42824996
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2011010501A MX2011010501A (en) | 2009-04-07 | 2010-04-05 | Hydropyrolysis of biomass for producing high quality liquid fuels. |
MX2013011082A MX341855B (en) | 2009-04-07 | 2010-04-05 | Hydropyrolysis of biomass for producing high quality liquid fuels. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2011010501A MX2011010501A (en) | 2009-04-07 | 2010-04-05 | Hydropyrolysis of biomass for producing high quality liquid fuels. |
Country Status (13)
Country | Link |
---|---|
US (1) | US20100251600A1 (en) |
JP (1) | JP5789596B2 (en) |
CN (2) | CN104845654B (en) |
AU (1) | AU2010235214C1 (en) |
BR (1) | BRPI1015303B1 (en) |
CA (1) | CA2756819A1 (en) |
EC (1) | ECSP11011432A (en) |
MX (2) | MX2011010501A (en) |
MY (1) | MY175354A (en) |
PE (1) | PE20121004A1 (en) |
RU (1) | RU2535343C2 (en) |
UA (2) | UA109635C2 (en) |
WO (1) | WO2010117436A1 (en) |
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WO2011060556A1 (en) * | 2009-11-18 | 2011-05-26 | G4 Insights Inc. | Sorption enhanced methanation of biomass |
WO2011138356A1 (en) * | 2010-05-07 | 2011-11-10 | Basf Se | Process for preparing synthesis gas and at least one organic, liquid or liquefiable value product |
US8853475B2 (en) * | 2010-12-15 | 2014-10-07 | Uop Llc | Process for producing a renewable hydrocarbon fuel |
US8841495B2 (en) | 2011-04-18 | 2014-09-23 | Gas Technology Institute | Bubbling bed catalytic hydropyrolysis process utilizing larger catalyst particles and smaller biomass particles featuring an anti-slugging reactor |
US8859831B2 (en) * | 2011-08-02 | 2014-10-14 | Gas Technology Institute | Removal of hydrogen sulfide as ammonium sulfate from hydropyrolysis product vapors |
IN2014CN02732A (en) * | 2011-11-14 | 2015-07-03 | Shell Int Research | |
US20150094503A1 (en) * | 2011-11-14 | 2015-04-02 | Shell Oil Company | Catalyst for producing hydrocarbons |
US9068126B2 (en) * | 2011-12-14 | 2015-06-30 | Uop Llc | Methods for deoxygenating biomass-derived pyrolysis oil |
US9163181B2 (en) | 2012-06-20 | 2015-10-20 | Uop Llc | Methods and apparatuses for deoxygenating biomass-derived pyrolysis oil |
US8816144B2 (en) * | 2012-10-04 | 2014-08-26 | Gas Technology Institute | Direct production of fractionated and upgraded hydrocarbon fuels from biomass |
CN103265968A (en) * | 2013-06-04 | 2013-08-28 | 北京林业大学 | Preparation method of high-value bio-oil based on comprehensive pyrolysis |
US20150152336A1 (en) * | 2013-12-04 | 2015-06-04 | Lummus Technology Inc. | Co-current adiabatic reaction system for conversion of triacylglycerides rich feedstocks |
FI20136345L (en) * | 2013-12-31 | 2015-07-01 | Upm Kymmene Corp | An integrated process for the production of hydrocarbons |
US9650574B2 (en) | 2014-07-01 | 2017-05-16 | Gas Technology Institute | Hydropyrolysis of biomass-containing feedstocks |
WO2016009333A1 (en) | 2014-07-17 | 2016-01-21 | Sabic Global Technologies B.V. | Upgrading hydrogen deficient streams using hydrogen donor streams in a hydropyrolysis process |
US9938466B2 (en) * | 2014-09-05 | 2018-04-10 | Gas Technology Institute | Use of carbon dioxide generated by hydropyrolysis for process inertization |
US10392566B2 (en) | 2015-04-27 | 2019-08-27 | Gas Technology Institute | Co-processing for control of hydropyrolysis processes and products thereof |
CN105170032A (en) * | 2015-10-09 | 2015-12-23 | 中国科学院过程工程研究所 | Reaction device used for pyrolyzing furnace and directed at high temperature pyrolysis steam catalytic hardening and tempering |
EP3380585B1 (en) * | 2015-11-23 | 2020-05-27 | Shell International Research Maatschappij B.V. | Conversion of biomass into a liquid hydrocarbon material |
CA3004679A1 (en) * | 2015-11-23 | 2017-06-01 | Shell Internationale Research Maatschappij B.V. | Conversion of biomass into a liquid hydrocarbon material |
US10377953B2 (en) * | 2016-11-09 | 2019-08-13 | Phillips 66 Company | Fluidized upgrading/hydrostabilizing of pyrolysis vapors |
CN108079910B (en) * | 2016-11-21 | 2020-01-17 | 北京华石联合能源科技发展有限公司 | Reactor for controlling cracking hydrogenation by upstream differential speed and application thereof |
US10787610B2 (en) * | 2017-04-11 | 2020-09-29 | Terrapower, Llc | Flexible pyrolysis system and method |
CN110208451B (en) * | 2019-04-26 | 2022-05-24 | 合肥工业大学 | Online detection system and method for bipolar miniature fixed bed reactor combined with photoionization mass spectrometry |
KR102478550B1 (en) * | 2020-11-19 | 2022-12-19 | 한화토탈에너지스 주식회사 | Method for producing high purity normal paraffin from biomass |
CN113648937A (en) * | 2021-08-27 | 2021-11-16 | 浙江大学 | System for directly preparing liquid fuel by biomass integrated hydrogenation, pressurization, catalytic pyrolysis and on-line upgrading |
CN114854453B (en) * | 2022-03-22 | 2023-03-28 | 北京科技大学 | Preparation method of biomass hydrogen-rich micro powder and synthesis gas for blast furnace injection |
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2009
- 2009-04-07 US US12/419,535 patent/US20100251600A1/en not_active Abandoned
-
2010
- 2010-04-05 PE PE2011001776A patent/PE20121004A1/en active IP Right Grant
- 2010-04-05 RU RU2011144858/04A patent/RU2535343C2/en active
- 2010-04-05 CA CA2756819A patent/CA2756819A1/en not_active Abandoned
- 2010-04-05 BR BRPI1015303-9A patent/BRPI1015303B1/en active IP Right Grant
- 2010-04-05 JP JP2012504669A patent/JP5789596B2/en active Active
- 2010-04-05 AU AU2010235214A patent/AU2010235214C1/en active Active
- 2010-04-05 CN CN201510140464.7A patent/CN104845654B/en active Active
- 2010-04-05 MX MX2011010501A patent/MX2011010501A/en active IP Right Grant
- 2010-04-05 MX MX2013011082A patent/MX341855B/en unknown
- 2010-04-05 CN CN201080015232.4A patent/CN102378748B/en active Active
- 2010-04-05 WO PCT/US2010/001019 patent/WO2010117436A1/en active Application Filing
- 2010-04-05 MY MYPI2011004768A patent/MY175354A/en unknown
- 2010-05-04 UA UAA201113017A patent/UA109635C2/en unknown
- 2010-05-04 UA UAA201113018A patent/UA106609C2/en unknown
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2011
- 2011-11-01 EC ECSP11011432 patent/ECSP11011432A/en unknown
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US20100251600A1 (en) | 2010-10-07 |
JP5789596B2 (en) | 2015-10-07 |
ECSP11011432A (en) | 2012-06-29 |
AU2010235214C1 (en) | 2013-09-12 |
CN104845654B (en) | 2018-09-14 |
CN104845654A (en) | 2015-08-19 |
WO2010117436A1 (en) | 2010-10-14 |
BRPI1015303B1 (en) | 2018-08-07 |
BRPI1015303A2 (en) | 2016-10-04 |
JP2012523473A (en) | 2012-10-04 |
AU2010235214B2 (en) | 2012-11-15 |
CA2756819A1 (en) | 2010-10-14 |
PE20121004A1 (en) | 2012-08-01 |
UA106609C2 (en) | 2014-09-25 |
MY175354A (en) | 2020-06-22 |
RU2011144858A (en) | 2013-05-20 |
AU2010235214A1 (en) | 2011-10-27 |
MX2011010501A (en) | 2011-10-19 |
RU2535343C2 (en) | 2014-12-10 |
CN102378748B (en) | 2015-05-13 |
UA109635C2 (en) | 2015-09-25 |
CN102378748A (en) | 2012-03-14 |
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