MX339095B - Desulfuracion oxidativa usando un catalizador de titanio (iv) y organohidroperoxidos. - Google Patents

Desulfuracion oxidativa usando un catalizador de titanio (iv) y organohidroperoxidos.

Info

Publication number
MX339095B
MX339095B MX2013000819A MX2013000819A MX339095B MX 339095 B MX339095 B MX 339095B MX 2013000819 A MX2013000819 A MX 2013000819A MX 2013000819 A MX2013000819 A MX 2013000819A MX 339095 B MX339095 B MX 339095B
Authority
MX
Mexico
Prior art keywords
catalyst
titanium
oxidative desulfurization
removal
hydroperoxide
Prior art date
Application number
MX2013000819A
Other languages
English (en)
Other versions
MX2013000819A (es
Inventor
Kyle E Litz
Jennifer L Vreeland
Original Assignee
Auterra Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Auterra Inc filed Critical Auterra Inc
Publication of MX2013000819A publication Critical patent/MX2013000819A/es
Publication of MX339095B publication Critical patent/MX339095B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C07D333/76—Dibenzothiophenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1691—Coordination polymers, e.g. metal-organic frameworks [MOF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2239—Bridging ligands, e.g. OAc in Cr2(OAc)4, Pt4(OAc)8 or dicarboxylate ligands
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/12—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Lubricants (AREA)

Abstract

La desulfuración oxidativa (ODS) es una alternativa atractiva a la tecnología de hidrodesulfuración (HDS) debido a su baja energía requerida para la remoción de especies de azufre refractario, tales como el dibenzotiofeno (DBT), a partir de las corrientes de petróleo pesadas. El diésel que contiene DBT se puede oxidar usando un catalizador de titanio(IV) heterogéneo y un organohidroperóxido oxidante, tal como hidroperóxido de ter-butilo (TBHP), hidroperóxido de cumilo (CHP) y/o hidroperóxido de etilbenceno (EBHP), el cual resulta eficaz para la oxidación selectiva y la remoción de compuestos de azufre refractarios a partir del combustible diésel.
MX2013000819A 2010-07-20 2011-07-19 Desulfuracion oxidativa usando un catalizador de titanio (iv) y organohidroperoxidos. MX339095B (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US36584210P 2010-07-20 2010-07-20
PCT/US2011/044439 WO2012012368A1 (en) 2010-07-20 2011-07-19 Oxidative desulfurization using a titanium(iv) catalyst and organhoydroperoxides
US13/185,552 US8283498B2 (en) 2010-07-20 2011-07-19 Oxidative desulfurization using a titanium(IV) catalyst and organohydroperoxides

Publications (2)

Publication Number Publication Date
MX2013000819A MX2013000819A (es) 2013-03-22
MX339095B true MX339095B (es) 2016-05-10

Family

ID=45494147

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2013000819A MX339095B (es) 2010-07-20 2011-07-19 Desulfuracion oxidativa usando un catalizador de titanio (iv) y organohidroperoxidos.

Country Status (8)

Country Link
US (1) US8283498B2 (es)
EP (1) EP2595747B1 (es)
CN (1) CN103037965B (es)
BR (1) BR112013001539A2 (es)
CA (1) CA2804312A1 (es)
MX (1) MX339095B (es)
RU (1) RU2581473C2 (es)
WO (1) WO2012012368A1 (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104475165B (zh) * 2014-12-12 2016-08-17 哈尔滨工业大学 一种氧化脱硫催化剂的制备方法
US10246647B2 (en) 2015-03-26 2019-04-02 Auterra, Inc. Adsorbents and methods of use
US10450516B2 (en) 2016-03-08 2019-10-22 Auterra, Inc. Catalytic caustic desulfonylation
US11046894B2 (en) 2018-08-31 2021-06-29 Amin Bazyari Mixed oxide nanocomposite catalyst-adsorbent for oxidative desulfurization of liquid hydrocarbon fuels
US10894923B2 (en) * 2018-10-22 2021-01-19 Saudi Arabian Oil Company Integrated process for solvent deasphalting and gas phase oxidative desulfurization of residual oil
US10703998B2 (en) * 2018-10-22 2020-07-07 Saudi Arabian Oil Company Catalytic demetallization and gas phase oxidative desulfurization of residual oil
US10800981B2 (en) 2019-02-13 2020-10-13 Saudi Arabian Oil Company Process for producing diesel fuel from olefinic refinery feedstreams
CN110280258B (zh) * 2019-08-02 2022-05-17 北京高新利华科技股份有限公司 一种柴油加氢精制催化剂及其制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3668117A (en) * 1970-03-17 1972-06-06 Texaco Inc Desulfurization of a preoxidized oil
US3873587A (en) * 1973-08-20 1975-03-25 Atlantic Richfield Co Production of peroxytitanium complexes from organic hydroperoxides
US6500219B1 (en) * 2001-03-19 2002-12-31 Sulphco, Inc. Continuous process for oxidative desulfurization of fossil fuels with ultrasound and products thereof
EP1403358A1 (en) 2002-09-27 2004-03-31 ENI S.p.A. Process and catalysts for deep desulphurization of fuels
AU2008262567B2 (en) * 2007-05-03 2013-05-16 Auterra, Inc. Product containing monomer and polymers of titanyls and methods for making same
WO2009120238A1 (en) * 2008-03-26 2009-10-01 Applied Nanoworks, Inc. Sulfoxidation catalysts and methods and systems of using same

Also Published As

Publication number Publication date
WO2012012368A1 (en) 2012-01-26
US8283498B2 (en) 2012-10-09
EP2595747A1 (en) 2013-05-29
US20120022272A1 (en) 2012-01-26
CA2804312A1 (en) 2012-01-26
MX2013000819A (es) 2013-03-22
RU2581473C2 (ru) 2016-04-20
CN103037965A (zh) 2013-04-10
EP2595747A4 (en) 2014-02-12
BR112013001539A2 (pt) 2016-07-19
EP2595747B1 (en) 2019-07-03
RU2013106744A (ru) 2014-08-27
CN103037965B (zh) 2015-12-02

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