MX338573B - Proceso para la fabricacion de esteres vinilicos de acido carboxilico alfa, alfa-ramificado. - Google Patents

Proceso para la fabricacion de esteres vinilicos de acido carboxilico alfa, alfa-ramificado.

Info

Publication number
MX338573B
MX338573B MX2013011169A MX2013011169A MX338573B MX 338573 B MX338573 B MX 338573B MX 2013011169 A MX2013011169 A MX 2013011169A MX 2013011169 A MX2013011169 A MX 2013011169A MX 338573 B MX338573 B MX 338573B
Authority
MX
Mexico
Prior art keywords
alpha
carboxylic acid
manufacture
blocking
vinyl esters
Prior art date
Application number
MX2013011169A
Other languages
English (en)
Other versions
MX2013011169A (es
Inventor
Denis Heymans
Original Assignee
Momentive Specialty Chem Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Momentive Specialty Chem Inc filed Critical Momentive Specialty Chem Inc
Publication of MX2013011169A publication Critical patent/MX2013011169A/es
Publication of MX338573B publication Critical patent/MX338573B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/126—Acids containing more than four carbon atoms
    • C07C53/128—Acids containing more than four carbon atoms the carboxylic group being bound to a carbon atom bound to at least two other carbon atoms, e.g. neo-acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/56—Crotonic acid esters; Vinyl acetic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F18/02—Esters of monocarboxylic acids
    • C08F18/04—Vinyl esters
    • C08F18/10—Vinyl esters of monocarboxylic acids containing three or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Catalysts (AREA)

Abstract

La invención se refiere a un proceso para la fabricación de los ésteres vinílicos de los ácidos carboxílicos a,a-ramificados que comprende las siguientes etapas: - isomerizar y convertir una alimentación de olefina con CO y agua bajo las condiciones de la reacción de Koch para fabricar un ácido con una relación de isómeros no bloqueadores (NB) contra los isómeros bloqueadores (B) de NB/B arriba de 1.5, en donde un isómero bloqueador siempre tiene un átomo de carbono terciario en la posición alfa del ácido carboxílico y en la posición beta del ácido carboxílico, mientras que un isómero no bloqueador tiene átomos de carbono primario en la posición beta del ácido carboxílico, - convertir el ácido resultante en un éster vinílico.
MX2013011169A 2011-04-07 2012-04-03 Proceso para la fabricacion de esteres vinilicos de acido carboxilico alfa, alfa-ramificado. MX338573B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11002898A EP2508502A1 (en) 2011-04-07 2011-04-07 Process for the manufacture of alfa,alfa branched carboxylic acid vinyl esters
PCT/EP2012/001478 WO2012136353A1 (en) 2011-04-07 2012-04-03 Process for the manufacture of alpha, alpha-branched carboxylic acid vinyl esters

Publications (2)

Publication Number Publication Date
MX2013011169A MX2013011169A (es) 2013-11-01
MX338573B true MX338573B (es) 2016-04-22

Family

ID=43983358

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2013011169A MX338573B (es) 2011-04-07 2012-04-03 Proceso para la fabricacion de esteres vinilicos de acido carboxilico alfa, alfa-ramificado.

Country Status (8)

Country Link
US (1) US9260374B2 (es)
EP (2) EP2508502A1 (es)
JP (2) JP2014517814A (es)
KR (1) KR101577516B1 (es)
CN (1) CN103459364A (es)
CA (1) CA2830477C (es)
MX (1) MX338573B (es)
WO (1) WO2012136353A1 (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110144163B (zh) * 2018-12-29 2021-04-16 武汉疏能新材料有限公司 一种透明疏水涂料、透明自清洁薄膜及其制备方法和应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3068256A (en) 1960-08-17 1962-12-11 Exxon Research Engineering Co Process for producing carboxylic acids
JPH0615494B2 (ja) * 1987-06-23 1994-03-02 出光石油化学株式会社 カルボン酸の製造方法
DE69524113D1 (de) * 1994-09-29 2002-01-03 Idemitsu Petrochemical Co Verfahren zur herstellung von monocarbon- und/oder dicarbonsaeuren
DE19908320A1 (de) 1999-02-26 2000-08-31 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Vinylestern aus Butenoligomeren
JP3350709B2 (ja) * 1999-10-08 2002-11-25 独立行政法人産業技術総合研究所 ロジウムカルボニル触媒を用いた第三級カルボン酸およびそのエステルの合成方法
AU2001254628A1 (en) * 2000-02-02 2001-08-14 Resolution Research Nederland B.V. Manufacturing process for the preparation of alpha-branched carboxylic acids having a decreased content of beta-branched isomers
EP1281700A1 (en) * 2001-07-31 2003-02-05 Resolution Research Nederland B.V. Manufacturing process for the preparation of alpha, alpha-branched alkane carboxylic acids providing esters with an improved softness

Also Published As

Publication number Publication date
US9260374B2 (en) 2016-02-16
KR20130137240A (ko) 2013-12-16
WO2012136353A1 (en) 2012-10-11
CN103459364A (zh) 2013-12-18
MX2013011169A (es) 2013-11-01
CA2830477A1 (en) 2012-10-11
CA2830477C (en) 2016-08-02
EP2694464A1 (en) 2014-02-12
JP2014517814A (ja) 2014-07-24
EP2508502A1 (en) 2012-10-10
KR101577516B1 (ko) 2015-12-14
US20140303387A1 (en) 2014-10-09
JP2016188201A (ja) 2016-11-04

Similar Documents

Publication Publication Date Title
SG195227A1 (en) Process for preparing high purity and crystalline dimethyl fumarate
MY153613A (en) Method for synthesizing an omega-amino acid or ester from a monounsaturated fatty acid or ester
NZ601757A (en) Eicosapentaenoic acid-producing microorganisms, fatty acid compositions, and methods of making and uses thereof
SG2013034418A (en) Process for the continuous transvinylation of carboxylic acids with vinyl acetate
MX353128B (es) Tubo de protección con cerrojo y aparato de manufactura del mismo.
UA100016C2 (en) Process for the production of methyl acetate
MY153851A (en) Carbonylation process for the production of methyl acetate
MY155045A (en) Process for the carbonylation of dimethyl ether
TW200942513A (en) Process for the preparation of fatty acid alkyl esters
MY156980A (en) Hydrogenation of fatty acids using a promoted supported nickel catalyst
ZA201400309B (en) Microorganism for converting carbon dioxide to aliphatic carboxylic acids via formic acid intermediate
MY171087A (en) Method for the production of polyols and uses thereof
SG10201803827UA (en) Microbial oil, production method for microbial oil, concentrated microbial oil, and production method for concentrated microbial oil
MY156726A (en) Process for producing fatty alcohols by hydrogenation of fatty acid triglycerides on a copper-containing heterogeneous catalyst
WO2012036913A3 (en) Bio-renewable plasticizers derived from vegetable oil
UA116465C2 (uk) Спосіб карбонілювання
MX2016005052A (es) Preparacion de compuestos homoalilicos por reaccion de precursores de ciclopropilvinilo con acidos bronsted.
WO2013052487A8 (en) Processes for producing acrylic acids and acrylates
SG195111A1 (en) Process for preparing methacrylic acid
MX338573B (es) Proceso para la fabricacion de esteres vinilicos de acido carboxilico alfa, alfa-ramificado.
EP2571842A4 (en) PREPARATION OF AROMATIC CARBOXYLIC ACIDS
SG153794A1 (en) Fatty acid compositions of methyl ester for esterquats production suitable for fabric softener
EP2492258A4 (en) PROCESS FOR PREPARING A TRICYCLODECANE MONO-METHANOL MONOCARBOXYLIC ACID DERIVATIVE
WO2008153708A3 (en) Reaction product of rhodium-catalyzed methanol carbonylation
GB201011091D0 (en) A catalyst and a process for the production of ethylenically unsaturated carboxylic acids or esters

Legal Events

Date Code Title Description
FG Grant or registration