MX337318B - Proceso para la obtencion de material poroso adsorbente a base de silicatos, para reducir el contenido de azufre y nitrogeno en fracciones del petroleo. - Google Patents
Proceso para la obtencion de material poroso adsorbente a base de silicatos, para reducir el contenido de azufre y nitrogeno en fracciones del petroleo.Info
- Publication number
- MX337318B MX337318B MX2012012376A MX2012012376A MX337318B MX 337318 B MX337318 B MX 337318B MX 2012012376 A MX2012012376 A MX 2012012376A MX 2012012376 A MX2012012376 A MX 2012012376A MX 337318 B MX337318 B MX 337318B
- Authority
- MX
- Mexico
- Prior art keywords
- silicates
- sulphur
- oil fractions
- nitrogen
- reducing
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3234—Inorganic material layers
- B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28057—Surface area, e.g. B.E.T specific surface area
- B01J20/28064—Surface area, e.g. B.E.T specific surface area being in the range 500-1000 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/305—Addition of material, later completely removed, e.g. as result of heat treatment, leaching or washing, e.g. for forming pores
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3071—Washing or leaching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
- B01J20/3204—Inorganic carriers, supports or substrates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G55/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process
- C10G55/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only
- C10G55/06—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only including at least one catalytic cracking step
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
La presente invención se refiere al proceso de obtención de materiales porosos adsorbentes a base de silicatos con especies metálicas, para su aplicación en la reducción de contaminantes de azufre y nitrógeno en fracciones del petróleo: gasóleos ligeros y pesados, naftas y combustibles, tales como la gasolina derivada del proceso FCC (Fluid Catalytic Cracking). Por lo tanto, la invención comprende la selección, preparación y modificación y propiedades adsorbentes de materiales porosos a base de silicatos intercalados y/o impregnados con especies metálicas tales como Ti(O,OH)44-, Mg(O.OH)-, Zr(O,OH)44-, Fe(O;OH)22-, Al(O.OH)33-. También, opciones adicionales fueron consideradas, por ejemplo aquellas que comprenden a los metales de la 1a y 2a series de transición, tales como Cu+, Ni2+, Zn2+, Fe2+, Ag+, Co2+, Ti4+, V2+,5+, Cr3+ y Mn2+.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2012012376A MX337318B (es) | 2012-10-24 | 2012-10-24 | Proceso para la obtencion de material poroso adsorbente a base de silicatos, para reducir el contenido de azufre y nitrogeno en fracciones del petroleo. |
US14/062,522 US10010864B2 (en) | 2012-10-24 | 2013-10-24 | Process for obtaining adsorbent material based on porous silicates for reduction of sulfur and nitrogen in oil fractions |
US15/904,750 US10478801B2 (en) | 2012-10-24 | 2018-02-26 | Process for obtaining adsorbent material based on porous silicates for reduction of sulfur and nitrogen in oil fractions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2012012376A MX337318B (es) | 2012-10-24 | 2012-10-24 | Proceso para la obtencion de material poroso adsorbente a base de silicatos, para reducir el contenido de azufre y nitrogeno en fracciones del petroleo. |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2012012376A MX2012012376A (es) | 2013-10-16 |
MX337318B true MX337318B (es) | 2016-02-12 |
Family
ID=49919125
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2012012376A MX337318B (es) | 2012-10-24 | 2012-10-24 | Proceso para la obtencion de material poroso adsorbente a base de silicatos, para reducir el contenido de azufre y nitrogeno en fracciones del petroleo. |
Country Status (2)
Country | Link |
---|---|
US (2) | US10010864B2 (es) |
MX (1) | MX337318B (es) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10443001B2 (en) | 2016-10-28 | 2019-10-15 | Uop Llc | Removal of sulfur from naphtha |
CN107216909B (zh) * | 2017-06-08 | 2019-03-15 | 中国石油大学(华东) | 一种基于超分子作用的燃料油品磁性脱硫剂 |
WO2019087052A1 (en) * | 2017-10-31 | 2019-05-09 | Reliance Industries Limited | A process for reducing the content of sulfur containing compounds in a hydrocarbon feed |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060118493A9 (en) * | 1998-12-09 | 2006-06-08 | Chmelka Bradley F | Block polymer processing for mesostructured inorganic oxide materials |
US7005118B2 (en) | 2002-07-25 | 2006-02-28 | Instituto Mexicano Del Petroleo | Synthetic mesoporous material with radially assembled nanotubes |
US6699797B1 (en) * | 2002-12-17 | 2004-03-02 | Intel Corporation | Method of fabrication of low dielectric constant porous metal silicate films |
US7122688B2 (en) * | 2003-10-16 | 2006-10-17 | Iowa State University Research Foundation | Use of functionalized mesoporous silicates to esterify fatty acids and transesterify oils |
US8815200B2 (en) * | 2004-12-02 | 2014-08-26 | The University Of Vermont And State Agricultural College | Mesoporous inorganic oxide spheres and method of making same |
KR101213714B1 (ko) * | 2009-05-27 | 2012-12-18 | 한국세라믹기술원 | 전이금속염을 이용한 메조포러스실리카 나노입자의 제조방법 |
MX2017010160A (es) * | 2015-02-04 | 2018-06-06 | Pc Cups Ltd | Composiciones de catalizador metalosilicato (msc), métodos de preparación y métodos de uso en el mejoramiento parcial de materias primas de hidrocarburos. |
-
2012
- 2012-10-24 MX MX2012012376A patent/MX337318B/es active IP Right Grant
-
2013
- 2013-10-24 US US14/062,522 patent/US10010864B2/en active Active
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2018
- 2018-02-26 US US15/904,750 patent/US10478801B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
US20140110629A1 (en) | 2014-04-24 |
MX2012012376A (es) | 2013-10-16 |
US10010864B2 (en) | 2018-07-03 |
US20180178196A1 (en) | 2018-06-28 |
US10478801B2 (en) | 2019-11-19 |
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