MX2023014792A - PROCESS FOR OBTAINING TEREPHTHALIC ACID AND RECOVERING SODIUM HYDROXIDE FROM A SOLUTION OF SODIUM TEREPHTHALATE PRODUCED FROM REUSED POLYETHYLENEREPHTHALATE (PET). - Google Patents
PROCESS FOR OBTAINING TEREPHTHALIC ACID AND RECOVERING SODIUM HYDROXIDE FROM A SOLUTION OF SODIUM TEREPHTHALATE PRODUCED FROM REUSED POLYETHYLENEREPHTHALATE (PET).Info
- Publication number
- MX2023014792A MX2023014792A MX2023014792A MX2023014792A MX2023014792A MX 2023014792 A MX2023014792 A MX 2023014792A MX 2023014792 A MX2023014792 A MX 2023014792A MX 2023014792 A MX2023014792 A MX 2023014792A MX 2023014792 A MX2023014792 A MX 2023014792A
- Authority
- MX
- Mexico
- Prior art keywords
- pet
- terephthalic acid
- sodium hydroxide
- recovering
- reused
- Prior art date
Links
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 title abstract 9
- 238000000034 method Methods 0.000 title abstract 8
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 title abstract 6
- VIQSRHWJEKERKR-UHFFFAOYSA-L disodium;terephthalate Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=C(C([O-])=O)C=C1 VIQSRHWJEKERKR-UHFFFAOYSA-L 0.000 title abstract 3
- 230000001476 alcoholic effect Effects 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/14—Alkali metal compounds
- C25B1/16—Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
- C25B15/083—Separating products
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/01—Products
- C25B3/07—Oxygen containing compounds
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/042—Electrodes formed of a single material
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The present invention relates to a process for obtaining terephthalic acid and recovering sodium hydroxide from a sodium terephthalate solution produced from reused PET, the process comprising the following steps: i) placing a sodium terephthalate solution obtained from an anode-side PET hydrolysis process in an electrolytic cell; ii) placing an alcoholic medium on the cathode side of the electrolytic cell; iii) applying an electric current flowing through the anode side and the cathode side of the electrolytic cell; and iv) recovering terephthalic acid and sodium hydroxide. The method has been devised so as not to generate the by-products generated in the PET recycling process, in order to have a "green" process. Moreover, the method described does not require large amounts of water or energy.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/IB2021/055081 WO2022259026A1 (en) | 2021-06-09 | 2021-06-09 | Process for obtaining terephthalic acid and recovering sodium hydroxide from a sodium terephthalate solution produced from reused polyethylene terephthalate (pet) |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2023014792A true MX2023014792A (en) | 2024-01-11 |
Family
ID=84424788
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2023014792A MX2023014792A (en) | 2021-06-09 | 2021-06-09 | PROCESS FOR OBTAINING TEREPHTHALIC ACID AND RECOVERING SODIUM HYDROXIDE FROM A SOLUTION OF SODIUM TEREPHTHALATE PRODUCED FROM REUSED POLYETHYLENEREPHTHALATE (PET). |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20240271292A1 (en) |
| EP (1) | EP4353876A4 (en) |
| CN (1) | CN117858981A (en) |
| CA (1) | CA3221682A1 (en) |
| MX (1) | MX2023014792A (en) |
| WO (1) | WO2022259026A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN119776853B (en) * | 2025-03-13 | 2025-07-25 | 源天生物科技(天津)有限公司 | A process, system and application for electrolytic recovery of PTA from PET degradation liquid |
| CN119819680B (en) * | 2025-03-13 | 2025-07-11 | 源天生物科技(天津)有限公司 | Continuous production system, process and application for efficiently recycling refined PTA from waste PET |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4092230A (en) * | 1977-03-10 | 1978-05-30 | Suntech, Inc. | Electrochemical process for the manufacture of terephthalic acid |
| US4093528A (en) * | 1977-03-10 | 1978-06-06 | Suntech, Inc. | Terephthalic acid process |
| US5290404A (en) * | 1990-10-31 | 1994-03-01 | Reilly Industries, Inc. | Electro-synthesis of alcohols and carboxylic acids from corresponding metal salts |
| US5780704A (en) * | 1992-06-04 | 1998-07-14 | Mitsui Chemicals, Inc. | Process for treating plastic product |
| FR2697839B1 (en) * | 1992-11-09 | 1995-01-13 | Inst Francais Du Petrole | Improved process for recovering alkali metal terephthalate and alkylene glycol from polyalkylene terephthalates. |
| FR2767131B1 (en) * | 1997-08-06 | 1999-10-22 | Tredi | PROCESS FOR THE RECOVERY OF TEREPHTHALIC ACID AND, IF APPROPRIATE, SODA FROM A SODIUM POLYTEREPHTHALATE SOLUTION |
| JPH11302208A (en) | 1998-04-22 | 1999-11-02 | Akira Oku | Recovery of terephthalic acid and ethylene glycol from polyethylene terephthalate |
| JP2004250544A (en) | 2003-02-19 | 2004-09-09 | Kansai Tlo Kk | Method for recovering terephthalic acid from poly(terephthalic acid ester) |
| JP5314246B2 (en) * | 2003-12-11 | 2013-10-16 | アメリカン パシフィック コーポレイション | Electrolytic method for producing alkali alcoholates using solid membranes of ion-conducting ceramics |
| CZ301118B6 (en) * | 2006-09-08 | 2009-11-11 | Ústav chemických procesu Akademie ved CR | Chemical recycling process of waste polyethyleneterephthalate |
-
2021
- 2021-06-09 MX MX2023014792A patent/MX2023014792A/en unknown
- 2021-06-09 WO PCT/IB2021/055081 patent/WO2022259026A1/en not_active Ceased
- 2021-06-09 EP EP21944450.2A patent/EP4353876A4/en active Pending
- 2021-06-09 CN CN202180101442.3A patent/CN117858981A/en active Pending
- 2021-06-09 CA CA3221682A patent/CA3221682A1/en active Pending
- 2021-06-09 US US18/568,620 patent/US20240271292A1/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CA3221682A1 (en) | 2022-12-15 |
| US20240271292A1 (en) | 2024-08-15 |
| WO2022259026A1 (en) | 2022-12-15 |
| EP4353876A1 (en) | 2024-04-17 |
| CN117858981A (en) | 2024-04-09 |
| EP4353876A4 (en) | 2025-04-09 |
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