MX2017014435A - Polimerizacion por emulsion de esteres de acido itaconico. - Google Patents

Polimerizacion por emulsion de esteres de acido itaconico.

Info

Publication number
MX2017014435A
MX2017014435A MX2017014435A MX2017014435A MX2017014435A MX 2017014435 A MX2017014435 A MX 2017014435A MX 2017014435 A MX2017014435 A MX 2017014435A MX 2017014435 A MX2017014435 A MX 2017014435A MX 2017014435 A MX2017014435 A MX 2017014435A
Authority
MX
Mexico
Prior art keywords
itaconic acid
emulsion polymerization
esters
ester
weight
Prior art date
Application number
MX2017014435A
Other languages
English (en)
Inventor
Durant Yvon
Jiang Bo
Tsavalas John
Original Assignee
Itaconix Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Itaconix Corp filed Critical Itaconix Corp
Publication of MX2017014435A publication Critical patent/MX2017014435A/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F22/10Esters
    • C08F22/12Esters of phenols or saturated alcohols
    • C08F22/14Esters having no free carboxylic acid groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/22Emulsion polymerisation
    • C08F2/24Emulsion polymerisation with the aid of emulsifying agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F22/10Esters
    • C08F22/12Esters of phenols or saturated alcohols
    • C08F22/16Esters having free carboxylic acid groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04Acids; Metal salts or ammonium salts thereof
    • C08F220/06Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10Esters
    • C08F222/12Esters of phenols or saturated alcohols
    • C08F222/14Esters having no free carboxylic acid groups, e.g. dialkyl maleates or fumarates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F267/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00
    • C08F267/06Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00 on to polymers of esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/16Syndiotactic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La presente descripción se refiere a un método para la polimerización por emulsión de un ácido itacónico que contiene funcionalidad de éster, por ejemplo, los ésteres de alquilo de ácido itacónico conocidos como itaconato de alquilo. Más específicamente, un éster de polímero de ácido poli-itacónico se produce mediante polimerización por emulsión y contiene más de 50% en peso de un éster de ácido itacónico junto con un tamaño de partícula y niveles de peso molecular y sindiotacticidad seleccionados.
MX2017014435A 2015-05-11 2016-05-11 Polimerizacion por emulsion de esteres de acido itaconico. MX2017014435A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201562159514P 2015-05-11 2015-05-11
PCT/US2016/031798 WO2016183164A1 (en) 2015-05-11 2016-05-11 Emulsion polymerization of esters of itaconic acid

Publications (1)

Publication Number Publication Date
MX2017014435A true MX2017014435A (es) 2018-04-10

Family

ID=57249594

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2017014435A MX2017014435A (es) 2015-05-11 2016-05-11 Polimerizacion por emulsion de esteres de acido itaconico.

Country Status (10)

Country Link
US (1) US9932421B2 (es)
EP (1) EP3294779B1 (es)
JP (1) JP2018514634A (es)
KR (1) KR20180006401A (es)
CN (1) CN107849163B (es)
BR (1) BR112017024375A2 (es)
CA (1) CA2985805A1 (es)
MX (1) MX2017014435A (es)
PL (1) PL3294779T3 (es)
WO (1) WO2016183164A1 (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11814475B2 (en) * 2021-12-09 2023-11-14 Itaconix Corporation Asymmetric and symmetric monomer mixtures of esters of itaconic acid and corresponding copolymers

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009151837A1 (en) 2008-05-16 2009-12-17 University Of New Hampshire Polycarboxylic acid polymers
JP2013514453A (ja) * 2009-12-16 2013-04-25 ユニバーシティ・オブ・ニュー・ハンプシャー イタコン酸のエステルの乳化重合
US9012027B2 (en) * 2009-12-17 2015-04-21 Dsm Ip Assets B.V. Aqueous emulsion
US8420758B2 (en) * 2010-03-11 2013-04-16 Itaconix Corporation Regulated and continuous polymerization of polycarboxylic acid polymers
AU2013214125B2 (en) * 2012-02-03 2016-05-26 Dsm Ip Assets B.V. Polymer, process and composition
WO2013113938A1 (en) * 2012-02-03 2013-08-08 Dsm Ip Assets B.V. Use of a polymer composition
EP2970542B1 (en) 2013-03-15 2019-07-24 Lubrizol Advanced Materials, Inc. Itaconic acid copolymers
CN107406557B (zh) * 2015-02-13 2020-02-11 帝斯曼知识产权资产管理有限公司 水性聚合物乳液

Also Published As

Publication number Publication date
WO2016183164A1 (en) 2016-11-17
US20160333127A1 (en) 2016-11-17
EP3294779A4 (en) 2018-11-14
CA2985805A1 (en) 2016-11-17
CN107849163A (zh) 2018-03-27
KR20180006401A (ko) 2018-01-17
EP3294779B1 (en) 2024-07-03
JP2018514634A (ja) 2018-06-07
PL3294779T3 (pl) 2024-09-02
CN107849163B (zh) 2020-09-25
BR112017024375A2 (pt) 2018-07-31
EP3294779A1 (en) 2018-03-21
US9932421B2 (en) 2018-04-03

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