MX2016004837A - Formulaciones de solventes hibridos para la remocion total de azufre organico y la remocion de gas acido total. - Google Patents

Formulaciones de solventes hibridos para la remocion total de azufre organico y la remocion de gas acido total.

Info

Publication number
MX2016004837A
MX2016004837A MX2016004837A MX2016004837A MX2016004837A MX 2016004837 A MX2016004837 A MX 2016004837A MX 2016004837 A MX2016004837 A MX 2016004837A MX 2016004837 A MX2016004837 A MX 2016004837A MX 2016004837 A MX2016004837 A MX 2016004837A
Authority
MX
Mexico
Prior art keywords
total
removal
organic sulfur
acidic gas
solvent formulations
Prior art date
Application number
MX2016004837A
Other languages
English (en)
Spanish (es)
Inventor
Christophe R Laroche
Gerardo Padilla
John R Dowdle
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of MX2016004837A publication Critical patent/MX2016004837A/es

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493Selection of liquid materials for use as absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
    • B01D53/1468Removing hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
    • B01D53/1475Removing carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1487Removing organic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/102Removal of contaminants of acid contaminants
    • C10L3/103Sulfur containing contaminants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/10Inorganic absorbents
    • B01D2252/103Water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/202Alcohols or their derivatives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/202Alcohols or their derivatives
    • B01D2252/2023Glycols, diols or their derivatives
    • B01D2252/2025Ethers or esters of alkylene glycols, e.g. ethylene or propylene carbonate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/202Alcohols or their derivatives
    • B01D2252/2023Glycols, diols or their derivatives
    • B01D2252/2026Polyethylene glycol, ethers or esters thereof, e.g. Selexol
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/202Alcohols or their derivatives
    • B01D2252/2023Glycols, diols or their derivatives
    • B01D2252/2028Polypropylene glycol, ethers or esters thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/204Amines
    • B01D2252/20426Secondary amines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/204Amines
    • B01D2252/20431Tertiary amines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/204Amines
    • B01D2252/20478Alkanolamines
    • B01D2252/20489Alkanolamines with two or more hydroxyl groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/50Combinations of absorbents
    • B01D2252/504Mixtures of two or more absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/60Additives
    • B01D2252/602Activators, promoting agents, catalytic agents or enzymes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/24Hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/302Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/304Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/306Organic sulfur compounds, e.g. mercaptans
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/308Carbonoxysulfide COS
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • B01D2257/504Carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/54Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
    • C10L2290/541Absorption of impurities during preparation or upgrading of a fuel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
MX2016004837A 2013-10-30 2014-10-24 Formulaciones de solventes hibridos para la remocion total de azufre organico y la remocion de gas acido total. MX2016004837A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361897687P 2013-10-30 2013-10-30
PCT/US2014/062163 WO2015065842A1 (en) 2013-10-30 2014-10-24 Hybrid solvent formulations for total organic sulfur removal and total acidic gas removal

Publications (1)

Publication Number Publication Date
MX2016004837A true MX2016004837A (es) 2016-07-26

Family

ID=51869048

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016004837A MX2016004837A (es) 2013-10-30 2014-10-24 Formulaciones de solventes hibridos para la remocion total de azufre organico y la remocion de gas acido total.

Country Status (8)

Country Link
US (1) US10293299B2 (https=)
EP (1) EP3062912A1 (https=)
JP (1) JP2016536115A (https=)
CN (1) CN105658306A (https=)
CA (1) CA2927937A1 (https=)
EA (1) EA201690897A1 (https=)
MX (1) MX2016004837A (https=)
WO (1) WO2015065842A1 (https=)

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CA2927937A1 (en) 2013-10-30 2015-05-07 Dow Global Technologies Llc Hybrid solvent formulations for total organic sulfur removal and total acidic gas removal
MX2016004836A (es) 2013-10-30 2016-07-26 Dow Global Technologies Llc Formulaciones solventes hibridas para la remocion selectiva de sulfuro de hidrogeno (h2s).
US10159930B2 (en) * 2014-10-10 2018-12-25 Dow Global Technologies Llc Aqueous solution of 2-dimethylamino-2-hydroxymethyl-1, 3-propanediol useful for acid gas removal from gaseous mixtures
CN106479586A (zh) * 2016-12-05 2017-03-08 江苏汉光实业股份有限公司 环保型h2s脱除剂及其制备方法
CN107464669A (zh) * 2017-09-26 2017-12-12 绵阳鑫阳知识产权运营有限公司 可延长变压器油使用寿命的油枕气管
WO2019158591A1 (en) 2018-02-14 2019-08-22 Taminco Bvba Improved contaminant removal process
JP7421553B2 (ja) * 2018-11-19 2024-01-24 エクソンモービル テクノロジー アンド エンジニアリング カンパニー 並流ガス吸収方法及び強化された吸収体を有するシステム
US11090604B2 (en) 2018-11-19 2021-08-17 Exxonmobil Upstream Research Company Enhanced acid gas removal within a gas processing system
US20220135512A1 (en) * 2019-04-16 2022-05-05 Angus Chemical Company Low toxicity organic tertiary and quaternary amines and uses thereof
CN116262190B (zh) * 2021-12-13 2024-10-01 中国石油天然气股份有限公司 一种高适应性有机硫脱除溶剂及有机硫脱除方法
CN114699882B (zh) * 2022-03-11 2024-06-14 华东理工大学 高效吸收脱除有机硫化合物的醚胺类化合物及其设计方法和应用
WO2024180358A1 (en) * 2023-02-27 2024-09-06 Totalenergies Onetech Method for selective separation of hydrogen sulfide from a gas mixture

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MX2016004836A (es) 2013-10-30 2016-07-26 Dow Global Technologies Llc Formulaciones solventes hibridas para la remocion selectiva de sulfuro de hidrogeno (h2s).
CA2927937A1 (en) 2013-10-30 2015-05-07 Dow Global Technologies Llc Hybrid solvent formulations for total organic sulfur removal and total acidic gas removal

Also Published As

Publication number Publication date
US20160288046A1 (en) 2016-10-06
CN105658306A (zh) 2016-06-08
JP2016536115A (ja) 2016-11-24
EP3062912A1 (en) 2016-09-07
WO2015065842A1 (en) 2015-05-07
EA201690897A1 (ru) 2016-12-30
CA2927937A1 (en) 2015-05-07
US10293299B2 (en) 2019-05-21

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