MX2015009643A - Inhibidor de corrosion derivado de aceites vegetales y su procedimiento de obtencion. - Google Patents

Inhibidor de corrosion derivado de aceites vegetales y su procedimiento de obtencion.

Info

Publication number
MX2015009643A
MX2015009643A MX2015009643A MX2015009643A MX2015009643A MX 2015009643 A MX2015009643 A MX 2015009643A MX 2015009643 A MX2015009643 A MX 2015009643A MX 2015009643 A MX2015009643 A MX 2015009643A MX 2015009643 A MX2015009643 A MX 2015009643A
Authority
MX
Mexico
Prior art keywords
nace
reacted
sour
imidazoline
production process
Prior art date
Application number
MX2015009643A
Other languages
English (en)
Inventor
Estrada Martínez Arquímedes
Tobón Cervantes Amalia
NAVARRO ORDOÑEZ Nancy
Luis Benítez Aguilar José
Original Assignee
Inst Mexicano Del Petróleo
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inst Mexicano Del Petróleo filed Critical Inst Mexicano Del Petróleo
Priority to MX2015009643A priority Critical patent/MX2015009643A/es
Priority to US15/217,086 priority patent/US10221368B2/en
Publication of MX2015009643A publication Critical patent/MX2015009643A/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G75/00Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general
    • C10G75/02Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general by addition of corrosion inhibitors
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/54Compositions for in situ inhibition of corrosion in boreholes or wells
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/14Nitrogen-containing compounds
    • C23F11/149Heterocyclic compounds containing nitrogen as hetero atom
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/207Acid gases, e.g. H2S, COS, SO2, HCN

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Metallurgy (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Lubricants (AREA)

Abstract

La presente invención comprende la síntesis y formulación de inhibidores de la corrosión para el control de la misma que presentan los ductos de acero al bajo carbón, que transportan diferentes combustibles característicos de los productos obtenidos en las refinerías o procesos petroquímicos. Además no excluye su aplicación en procesos de refinación del petróleo crudo como lo es en Torre Atmosférica y Vacío, entre otras. La composición consta de un nuevo activo tipo imidazolina, que se caracteriza por ser derivado de aceite vegetal comercial de uso para consumo humano. Dicha imidazolina es obtenida en dos etapas, la primera es la obtención de la imidazolina a partir de cualquiera de los aceites vegetales comerciales, procedentes del girasol, canola, soya, cártamo, maíz y sus mezclas. Este aceite reacciona con una de las poliaminas polialquiladas semejantes como dietilentriaminas (DETA), trietilentetramina (TETA) y tetraetilenpentamina (TEPA). En la segunda etapa, la imidazolina obtenida de la primera etapa se hace reaccionar con 1 a 3 moles de un ácido carboxílico que puede ser de 2 a 6 átomos de carbono. El producto obtenido es formulado con el 50 a 60% peso de un solvente aromático y un 10 a 20% peso de un alcohol. Las nuevas composiciones fueron evaluadas en medio amargo bajo el método NACE TM0172 y ASTM G 185, y en medio amargo y dulce en el método NACE ID182, por lo que son aptos al pasar las pruebas como indica la norma NRF-005-PEMEX-2009, para ser aplicación en los ductos.
MX2015009643A 2015-07-27 2015-07-27 Inhibidor de corrosion derivado de aceites vegetales y su procedimiento de obtencion. MX2015009643A (es)

Priority Applications (2)

Application Number Priority Date Filing Date Title
MX2015009643A MX2015009643A (es) 2015-07-27 2015-07-27 Inhibidor de corrosion derivado de aceites vegetales y su procedimiento de obtencion.
US15/217,086 US10221368B2 (en) 2015-07-27 2016-07-22 Method of inhibiting corrosion using a corrosion inhibitor derived from vegetable oils

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MX2015009643A MX2015009643A (es) 2015-07-27 2015-07-27 Inhibidor de corrosion derivado de aceites vegetales y su procedimiento de obtencion.

Publications (1)

Publication Number Publication Date
MX2015009643A true MX2015009643A (es) 2017-01-26

Family

ID=57882261

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015009643A MX2015009643A (es) 2015-07-27 2015-07-27 Inhibidor de corrosion derivado de aceites vegetales y su procedimiento de obtencion.

Country Status (2)

Country Link
US (1) US10221368B2 (es)
MX (1) MX2015009643A (es)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114456148A (zh) * 2022-01-11 2022-05-10 中海油天津化工研究设计院有限公司 一种配伍性良好的油田缓蚀剂及其制备方法

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CN109576712B (zh) * 2018-11-28 2020-01-03 华中科技大学 改性氧化石墨烯制备的二氧化碳缓蚀剂及其制备方法
US11466210B2 (en) 2019-02-13 2022-10-11 King Fahd University Of Petroleum And Minerals Biomediated-titanium nanocomposite for corrosion protection
CN110219006A (zh) * 2019-06-28 2019-09-10 金澳科技(湖北)化工有限公司 一种减缓烟气脱硫氯离子腐蚀的缓蚀添加剂
CN111020597B (zh) * 2019-12-23 2022-01-04 西安三维科技发展有限责任公司 一种气井油管用油溶性缓蚀剂及其制备方法
CN111518030A (zh) * 2020-03-26 2020-08-11 陕西驭腾实业有限公司 一种咪唑啉天然气减阻剂及其合成方法及应用
CN112064033B (zh) * 2020-09-08 2021-09-28 中山大学 一种协同控制微生物腐蚀金属的方法及其应用
US11866664B2 (en) 2021-06-10 2024-01-09 Saudi Arabian Oil Company Green corrosion inhibitor from waste vegetable oil for oil and gas applications
US11667829B1 (en) 2022-03-22 2023-06-06 Saudi Arabian Oil Company Corrosion inhibition compositions and methods of use
US11649393B1 (en) 2022-03-22 2023-05-16 Saudi Arabian Oil Company Corrosion inhibition compositions and methods of use
US11866666B1 (en) 2023-01-20 2024-01-09 Saudi Arabian Oil Company Methods for corrosion reduction in petroleum transportation and storage

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US2205754A (en) 1939-03-04 1940-06-25 Standard Oil Dev Co Corrosion inhibitor
US2330524A (en) 1941-06-16 1943-09-28 Alox Corp Corrosion inhibitor
US2668100A (en) 1951-11-15 1954-02-02 Nat Aluminate Corp Corrosion inhibitor for liquid hydrocarbons
US3623979A (en) 1967-06-29 1971-11-30 Texaco Inc Composition and process for inhibiting corrosion in oil wells
US3758493A (en) 1967-06-29 1973-09-11 Texaco Inc Acid imidazolines carboxylic acid salts of 1-aminoalkyl-2-polymerized carboxylic fatty
US3846071A (en) 1969-02-12 1974-11-05 Petrolite Corp Process of inhibiting corrosion by treatment with phosphate-cyclic amidine salts
DE3109826A1 (de) 1981-03-14 1982-09-23 Basf Ag, 6700 Ludwigshafen Inhibitoren gegen die korrosion von h(pfeil abwaerts)2(pfeil abwaerts)s und co(pfeil abwaerts)2(pfeil abwaerts) in wasser-in-oel-emulsionen
US4388214A (en) 1982-02-26 1983-06-14 Basf Aktiengesellschaft Imidazoline based corrosion inhibitors which inhibit corrosion caused by CO2 and H2 S
GB9116684D0 (en) 1991-08-02 1991-09-18 Exxon Chemical Patents Inc Corrosion inhibitors
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US5322630A (en) 1992-05-14 1994-06-21 Exxon Chemical Patents Inc. Amine derivatives as corrosion inhibitors
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US8399386B2 (en) * 2009-09-23 2013-03-19 Nalco Company Foamers for downhole injection

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114456148A (zh) * 2022-01-11 2022-05-10 中海油天津化工研究设计院有限公司 一种配伍性良好的油田缓蚀剂及其制备方法

Also Published As

Publication number Publication date
US20170029960A1 (en) 2017-02-02
US10221368B2 (en) 2019-03-05

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