MX2014015540A

MX2014015540A - Metal-free reactive dyes, process for the production thereof and their use.

Info

Publication number: MX2014015540A
Application number: MX2014015540A
Authority: MX
Inventors: Roxana Barbieru; Han Yuan; Hyeong Kyu Kim; Xiao Tien Wong
Original assignee: Dystar Colours Distrib Gmbh
Priority date: 2012-06-18
Filing date: 2013-06-13
Publication date: 2015-06-23
Also published as: KR20150033612A; AU2013279553A1; EP2904051A1; CN104508052A; JP2015523436A; WO2013189814A1

Abstract

Metal-free reactive dyes, process for the production thereof and their use The present invention relates to reactive dyes of the formula (I), in which A, B, a and K are defined as given in claim, a process for preparing them, and their use for dyeing and printing hydroxyl-, amino-, and/or carboxamido-containing materials.

Description

PROCESS-FREE REAGENT DYES FOR ITS PRODUCTION AND USE The present invention relates to the technical field of reactive dyes for the dyeing and printing of amino-carboxy-containing material. Metal-free reactive dyes are known from the art and can be used as dyes. in different from the US Sin document in the context of the staining and printing of amino-containing material known dyes that are free of metals have a number of technical disadvantages such as unsatisfactory resistance to light and especially limitations to achieve more shadows dark such as navy blue violet and black shades of a level of general solidity it is now very much found that the dyes of the formula as described below show very advantageous properties with respect to the dyes. They include high accumulation in darker shades with high properties. solidity such as resistance to washing and contact resistance The abovementioned dyes of the formula are free of metals are superior in ecological performance and provide dyes that are very good. The present invention relates to dyes of the formula and their mixtures in A is a radical of diazo component as described further and B is a radical of the middle component as described further and K is a radical of the coupling component as described more is already an integer of 0 or and with the general condition that the dyes of the general formula contain at least one anchor and this invention relates to all types of tautomeric and geometric isomers of the dyes of the formula A is a radical of the general formula wherein each of R 1 a independently between is S03 OO is alkyl substituted with one or more substituents selected from the group consisting of or is alkyl interrupted by one or more heteroatoms such as ox igene or sulfur and substituted with one or more substituents selected from the group consisting of trialkyl or is where X is vinyl or a radical and Y is a removable group under alkaline conditions such as OPO3M or is a group of the general formula or wherein each one of R4 and independently between is S03M or is alkyl substituted with one or more substituents selected from the group consisting of acyloxy or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from A group consisting of acyloxy or R8 and independently of each other is alkyl or is alkyl substituted with one or more substituents selected from the group consisting of acyloxy or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of acyloxy or and each of R9 a independently between is alco xi oyb is an integer of 0 a and c is an integer of 1 a and when each of b and independently of R4 and R7 can have different meanings within the same remainder according to the meaning defined with yd is 0 or and RG is a Reactive anchor of the general formula or 3b wherein each of R14a independently between and R14 may additionally be a residue of the formula wherein R96 is SO3M or is alkyl substituted with one or more substituents selected from the group consisting of acyloxy oo is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of acyloxy and R13 is one of the groups selected from the general formula or wherein each of R23 and independently is cycloalkyl or is alkyl substituted with one or more substituents selected from the group consisting of acyloxy or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of acyloxy or each of R22 and independently from each other is SO3M or is alkyl substituted with one or more substituents selected from the group consisting of acyloxy or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of acyloxy and may additionally be where X is vinyl a radical wherein Y is a removable group under alkaline conditions such as OPO3M and R95 may be additionally where X is as defined with B is a radical of the general formula wherein each of a independently between is S03M or is alkyl substituted with one or more substituents selected from the group consisting of or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of or is where X is vinyl or a radical and Y is a removable group under alkaline conditions such as OPO3M or is a group of the general formula or where acy RG are as defined with K is a radical of the general formula or where D is a radical of the general formula as defined with and each of R27a independently between is SO3M or is alkyl substituted with one or more substituents selected from the group consisting of monoarylsulfamollo or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of monoarylsulfonyl or each independently of each other is heterocycloalkyl or is alkyl substituted with one or more substituents selected from the group consisting of monoarylsulphamoyl or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of te in oo is a reactive anchor where RG is as defined with or is a remainder of the general formula wherein RG is as defined with and R32 is SO3M or is alkyl substituted with one or more substituents selected from the group consisting of acyloxy or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of acyloxy and R33 is alkyl or is alkyl substituted with one or more substituents selected from the group consisting of acyloxy or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of aryloyl acyloxy and is an integer of 1 a and when e is R2 may have different meanings therein according to the defined meaning The alkyl groups appearing in this application can be straight or branched chain and are alkyl groups with groups alkyl by and The same logic applies to alkoxy groups concomitantly with alkoxy by methoxy and thioalkoxy groups with thioalkoxy by the cycloalkyl groups with cycloalkyl and especially with cyclopentyl and The term cycloalkyl comprises for the purpose of the present application substituted cycloalkyl groups and also cycloalkyl groups. A preferred group of this type is The preferred substituents are alkoxycarbonyl and the aryl groups that appear in this application with phenyl or the terms phenyl and naphthyl comprise phenyl and naphthyl not as well as the preferred substituents are bis alkoxycarbonyl or heteroaryl groups which appear in this application with benzoxazole or The term heteroaryl comprises the above groups in the form not in the form The preferred substituents are alkoxycarbonyl and the heterocycloalkyl groups with tetrahydrofuran or The term heterocycloalkyl comprises the above groups in the form not in the formpreferred are alkoxycarbonyl and Halogen with bromine or M with ammonium or an equivalent of an alkaline earth metal or an organic cation Particularly preferred embodiments of the present invention are dyes of the formula and their mixtures wherein each of R34 to independently between is S03M or is alkyl substituted with one or more substituents selected from the group consisting of or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of or is where X is vinyl or a radical and Y is a removable group under alkaline conditions such as OPO3M or is a group of the general formula or as defined with and each of R37 and independently between is heterocycloalkyl or is alkyl substituted with one or more substituents selected from the group which consists of monoarylsulfamollo or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substitute The one or more substituents selected from the group consisting of oo is a reactive anchor where RG is as defined with or is a moiety of the general formula as defined by In particularly preferred tints of the general formula each of R34 to independently between is alkyl alkoxy acyl or O is where X is vinyl or a radical and Y is a removable group under alkaline conditions such as or is where RG is as defined with or is where f is an integer from 1 to 3 and RG is as defined with and each of R37 and independently between is acyl or is a reactive anchor where RG is as defined with or is where g is an integer from 1 to 3 and RG is as defined with Other preferred embodiments of this invention are dyes of the general formula and their mixtures wherein each of R39a independently from each other is S03M or is alkyl substituted with one or more substituents selected from the group consisting of 5 0 or is alkyl ilo interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of or is where X is vinyl or a radical and Y is a removable group under alkaline conditions such as OPO3M or is a group of the general formula or as defined with and each of R39 a independently between may additionally be a group of the general formula as defined with and each of and independently between is heterocycloalkyl or is alkyl substituted with one or several substituents selected from the group consisting of monoarylsulfamollo or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of carba or is a reactive anchor where RG is as defined with or is a remainder of the general formula as defined with In dyes of special preference of the general formula each of R39 A is independently between alkyl and alkoxy acyl or is where X is a radical and Y is a removable group under alkaline conditions such as or is where RG is as defined with or is where h is an integer from 1 to 3 and RG is co or defined with and each of R45 and independently between is acyl or is a reactive anchor where RG is as defined with or is where i is an integer from 1 to 3 and RG is as defined with Other preferred embodiments of this invention are dyes of the general formula and their mixtures wherein is 1 and each of a independently between is S03M OO is alkyl substituted with one or more substituents selected from the group consisting of or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of or is where X is vinyl or a radical and Y is a removable group under alkaline conditions such as OPO3M or o is a group of the general formula or as was defined with and each of R50 and independently between is heterocycloalkyl or is alkyl substituted with one or more substituents selected from the group consisting of monoarylsulfamollo or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or several substituents selected from the group consisting of oo is a reactive anchor where RG is as defined with or is a residue of the general formula as defined with In particularly preferred dyes of the general formula each of R47 a independently from is alkoxy alkyl acyl or is where X is vinyl or a radical and Y is a removable group under alkaline conditions such as where RG is as defined with or is where k is an integer from 1 to 3 and RG is as defined with and each of R50 and independently between is acyl or is a reactive anchor where RG is as defined with or is where m is an integer from 1 to 3 and RG is as defi Other preferred embodiments of this invention are dyes of the general formula and theirs wherein 0 or 1 and each of R52a independently between is S03M or is alkyl substituted with one or more substituents selected from the group consisting of in or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of or is where X is vinyl or a radical and Y is a removable group under alkaline conditions such as OPO3M or is a group of the general formula or as defined with and each of R52a independently between may additionally be a group of the general formula as defined with and each of R58 and independently between is heterocycloalkyl or is alkyl substituted with one or more substituents selected from the group consisting of monoarylsulfamollo or is alkyl interrupted by one or more heteroatoms such as Oxygen or sulfur and substituted with one or several substituents selected from the group consisting of oo is a reactive anchor where RG is as defined with or is a moiety of the general formula as defined with In special preference dyes of formula 0 general each of R52 a independently between is alkyl acyl alkoxy or is X where vinyl or a radical and Y is a removable group under alkaline conditions such as or is where RG is as defined with or is where p is a number integer from 1 to 3 and RG is co defined with and 0 each and R independently between is acyl or is a reactive anchor where RG is as defined with or is where q is an integer from 1 to 3 and RG is as defined by other preferred embodiments of this invention are dyes of the general formula and their I wherein each of R61 and independently between is S03M or is alkyl substituted with one or more substituents selected from the group consisting of The alkyl is interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of or is where X is vinyl or a radical and Y is a removable group under alkaline conditions such as OPO3M or is a group of the general formula or as defined with and each of R63 and independently between is heterocycloalkyl or is alkyl substituted with one or more substituents selected from the group consisting of monoarylsulphamoyl or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of oo is a reactive anchor where RG is as defined with or is a moiety of the general formula as defined by In particularly preferred tints of the general formula each of R60 a independently between is alkyl alkoxy acyl or is X where vinyl or a radical and Y is a radical group movable in alkaline conditions such as or is where RG is as defined with or is where r is an integer from 1 to 3 and RG is as defined with and each of R63 and independently between is acyl or is a reactive anchor where RG is as defined with or is where s is an integer from 1 to 3 and RG is as defined with Other preferred embodiments of this invention are dyes of the general formula and theirs wherein each of R65 to independently between is S03M or is alkyl substituted with one or more substituents selected from the group consisting of or is alkyl interrupted by one or more heteroatoms such as oxygen sulfur and substituted with one or more substituents selected from the group consisting of or is where X is vinyl or a radical and Y is a removable group under alkaline conditions such as OPO3M oo is a group of the general formula or as defined with and each of R65 a independently between may additionally be a group of the general formula as defined by inió with and each of and independently between is heterocycloalkyl or is alkyl substituted with one of several substituents selected from the group consisting of monoarylsulfamollo or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of oo is a reactive anchor where RG is defined with or is a remainder of the general formula as defined with In special preference dyes of the general formula each of R65 a independently between is alkoxy acyl oo is where X is vinyl or a radical and Y is a removable group under alkaline conditions such as or is where RG is as defined with or is where t is an integer from 1 to 3 and RG is as defined with and each one of R71 and independently between is acyl oo is a reactive anchor where RG is as defined with or is where u is an integer from 1 to 3 and RG is as defined with Other fo Preferred embodiments of this invention are dyes of the general formula and theirs wherein each of R75 to R80 independently between is S03 or is alkyl substituted with one or more substituents selected from the group consisting of or is alkyl interrupted by one or several heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of or is where X is vinyl or a radical and Y is a removable group under alkaline conditions such as OPO3M or is a group of the general formula or as defined with and each of R81 and independently between is heterocycloalkyl or is alkyl substituted with one or more substituents selected from the group consisting of monoarylsulfamollo or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or several substituents selected from the group consisting of oo is a reactive anchor where RG is as defined with or is a remainder of the general formula as defined by In special preference dyes of the general formula each of R75 a independently between is alkyl alkoxy acyl or O is where X is vinyl or a radical and Y is a group removable in alkaline conditions such as or is where RG is as defined with or is where v is an integer from 1 to 3 and RG is as defined with and each and independently between is acyl or is a reactive anchor where RG is as defined with or is where w is an integer from 1 to 3 and RG is as defined with Other preferred embodiments of this invention are dyes of the general formula and their wherein each of R83 a so independent is S03M or is alkyl substituted with one or more substituents selected from the group consisting of or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consists of or is where X is vinyl or a radical and Y is a removable group under alkaline conditions such as OPO3M or is a group of the general formula as defined with and each of R90 and independently between may additionally be a group of the general formula as defined with and each of R92 and independently between is heterocycloalkyl or is alkyl substituted with one or more substituents selected from the group consisting of N-monoarylsulfamollo or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group which consists of monoarylsulfamollo or is a reactive anchor where RG is as defined with or is a moiety of the general formula as defined by In particularly preferred tints of the general formula each of R83 a independently between is alkyl alkoxy acyl oo is where X is vinyl a radical and Y is a removable group under alkaline conditions such as or is where RG is as defined with or is where x is an integer from 1 to 3 and RG is as defined with and each of R92 and independently between is acyl or is a reactive anchor where RG is as defined with or is where i is an integer of 1 to 3 and RG is as defined with The preferred examples of dyes of the formulas a are the compounds I1 to I140 listed in table 1 below and having the general formula Table 1 refers to the binding point of A and of tam refers to the point of attachment of B with A when a is refers to the other point of attachment of B when a is. Further examples of preferred dyes of formulas a are compounds I141 to I280 listed in table 2 below. and having the general formula I Table 2 No. I refers to the point of attachment of A and also refers to the point of attachment of B to A when a is refers to the other point of attachment of B when a is The present invention it also provides a process for the preparation of the dyes of the formula This process comprises diazotization of the compounds of the formula and reaction of the diazonium salts correspondingly obtained with a compound of the formula K to obtain the intermediate of the general formula In another step the diazo component is diazotized and coupled in the intermediary III to obtain the bisazo dyeing product of the general formula. Thus, the diazo component can be diazotized and coupled with the compound to obtain the intermediate. The intermediate is diazotized and is coupled with the compound to obtain the trisazo dyeing product of the formula General The reactions of in can be carried out by means of diazotization methods which are known to a person skilled in the art using sodium nitrite or nitrosylsulfuric acid in acid medium using inorganic acids such as sulfuric acid or phosphoric acid or their acid mixtures organic acids such as acetic acid or propionic acid or their can also be used Advantageously mixtures of inorganic acid with acids Coupling reactions can be carried out in by methods The compounds of the formula K are known and commercially available or can be synthesized by means of common chemical reactions known to an expert in the final product. It can also optionally be subjected to a reaction of For example a vinylizable reaction group such as sulfatoethylsulfonyl is converted into its form Such reactions are known to a person skilled in the art. They are generally carried out in a neutral to alkaline medium at a rate of 20 to 80 at a pH of 7 a The tinctures of the formula with reactive fibers containing reactive functional residues a The functional reactive rests to fibers refer to residues capable of reacting with the hydroxyl groups of materials the hydroxyl and thiol groups in the case of wool and silk or with the amino and possibly carboxyl groups of synthetic polyamides to form chemical bonds The dyes of the present invention are suitable for dyeing and the printing of modified or synthetic manufactured fibrous materials containing amino carboxamide and mixtures thereof by application methods described many times in the art for dyes Accordingly, the present invention also provides a process for dyeing and printing the fibrous materials mentioned above and mixtures thereof in which a dye or a mixture of dyes according to the present is used Examples of natural fiber materials as described above are vegetable fibers such as fibers of coconut fiber from fiber shell of fibers The fibers are fibers and fibers derived from animals such as fiber fiber wool as well as leather materials. Examples of fabricated and regenerated fibers manufactured are cellulosic fibers such as paper and regenerated cellulosic fibers such as rayon fibers of fiber acetate and triacetate and fibers The examples of fibrous materials Ethics as described above are materials of such as and fibers The aforementioned substrates for dyeing may be present in various such forms but without knitted fabric forming loops or dyes of the present invention and their salts or blends may be used as a dyed product only in dyeing or printing processes or it may be part of a combined product of three or several components in dyeing compositions. The dyes of this invention and its salts or mixtures are very compatible with other known dyes available in shops and stores. they can be used together with such dyes to obtain specific tones of similar technical performance. The technical performance includes solidity properties and although the water solubility of the dyes according to the invention is very also it can be used advantageously in continuous dyeing processes. dyes of the present invention can also be used in printing processes Particularly in textile printing Aqueous inks for digital printing comprising a dye of the present invention also form part of the subject matter of the present invention. The inks of the present invention comprise the dyeing of the present invention in amounts which are in with greater than by weight to weight and with maximum by weight in based on the total weight of the Las as well as the dyes of the present invention can if other dyes used in printing For the inks of the present invention for use in the flow process can be set a conductivity of to 25 by adding a useful electrolytes by lithium nitrate and nitrate of The inks of the present invention can include organic solvents at a total level of in the appropriate organic solvents by alcohol alcohols by alkylene glycols having 1 to 8 groups by lower alkyl ethers of alcohols by ethylene glycol monomethyl ethylene glycol monoethyl ethylene glycol monobutyl diethylene glycol monomethyl diethylene glycol monoethyl diethylene glycol monobutyl monohexyl diethylene glycol triethylene glycol monomethyl triethylene glycol monobutyl tripropylene glycol monomethyl tetraethylene glycol monomethyl tetraethylene glycol monobutyl tetraethylene glycol dimethyl propylene glycol monomethyl glycol monoethyl glycol monobutyl isopropyl tripropylene polyalkylene glycol such by monomethyl polyethylene glycol polypropylene glycol polyethylene glycol glycerol tridecyl polyethyleneglycol nonylphenyl such derivatives of such by such by ketones or such by alcohol ethers such by gamma alcohol plus ethyl-ethyl ether acetate of dimethoxypropane and the inks of the invention may also include additives by moderators of the viscosity at fixed viscosities in the range of a mPas in a temperature range of 20 to The preferred inks have a viscosity of at 20 mPas and the inks of particular preference have a viscosity of 15 Utility viscosity moderators include additives for polyvinylpyrrolidone and its copolymers thickeners alginates of galactomannanos cellulosic ethers no As other inks of the invention can include surface-active substances to fix surface tension from 20 to 65 that are adapted if necessary depending on the thermal process used or Useful surfactants include All inks with non-butyl diglycol surfactants and Inks of the present invention may also include additives for inhibiting the growth of fungi and bacteria in amounts by weight, based on the total weight of the inks. The inks may be prepared in a conventional manner by mixing The components in the inks of the present invention are particularly useful in inkjet printing processes to print a wide variety of particularly wool and fiber. The following examples serve to illustrate the Parts and percentages are in unless it is observed Other The relationship between parts by weight and pa The volume is that of kilogram a Example of sulfuric acid ester portions were suspended in 70 parts of 14 parts of bicarbonate were added The reaction vessel was cooled until using Chloride portions were added The reaction was stirred at a temperature of pH of for 3 After parts of acid were added and the pH was adjusted to using solution to that of The reaction was stirred at room temperature and pH of for 2 The product obtained was used in the next step without 0 parts of disulfonic acid were added The reaction vessel was cooled to using milliliters of 5 M solution of sodium nitrite were added to the mixture. After stirring for 10 parts of hydrochloric acid were added to the reaction mixture. it was stirred at h and then parts of acid were added. The product solution obtained above was cooled to using the diazonium salt was added The solution was slowly stirred while maintaining the pH in the reaction was stirred until complete to obtain the intermediate parts of acid were suspended in 50 parts of The reaction vessel was cooled until using parts of hydrochloric acid were added in the mixture After stirring for 10 minutes, milliliters of 5 M solution of nitrite were added. The reaction was stirred for 1 h and then portions of acid were added. The diazonium salt was added slowly to the solution previously synthesized while maintaining the pH in the reaction mixture. The reaction was stirred until the product was collected by filtration and dried to give portions of die 56 as a solid. For all the dyes of the formulas can be synthesized according to the method described above in the example Example of dyeing 1 3 parts of the dye I56 of this invention are dissolved in 2000 parts of water and 1 part of leveling assistant is added The base of the condensation product of a higher aliphatic amine and oxide of The pH is then adjusted to using acetic acid The staining bath is mixed with 100 parts of a woolen cloth The temperature rises to 40 in the course of 30 keeps at this temperature for 15 minutes and then it increases to 98 in the course of 58 minutes and the staining is carried out at this temperature for 90 A followed by cooling to 90 and removal of the material The woolen fabric is washed with water hot and treated in a manner and then spun and dried. Example of staining 2 2 parts of the tincture of this invention and 60 parts of sodium chloride are dissolved in 1000 parts of water and 12 parts of sodium carbonate and portions of sodium carbonate are added. an agent To the dyeing bath 100 parts of cotton woven cloth are placed The temperature of the dyeing bath is raised to 30 at a gradient of and maintained at this temperature for 30 minutes and then increased to 60 for 30 keeping this temperature Atura for another 60 After the dyed items are rinsed initially with running water for 5 The stained articles are neutralized to 50 using acetic acid during the. The articles are rinsed with boiling tap water for minutes followed by a final rinse for 20 minutes and the following are dissolved. in 2000 parts of water and 1 part of base leveling assistant of condensation product of an upper aliphatic amine and oxide of and 6 parts of acetate is added The pH is then adjusted to using acetic acid The staining bath is heated up to 50 for 10 minutes and then mixed with 100 parts of a woven cloth The temperature rises to 110 in the course of 50 minutes and then the staining is carried out at this temperature for 60 A followed by cooling to 60 and removal of the material The polyamide fabric is washed with hot water and soaped and then spun and dried. Example of staining 4 A textile fabric consisting of mercerized cotton is covered with liquor with 35 d calcium carbonate and 100 of urea and 150 of a solution of sodium alginate of low viscosity and then dried The absorption of the liquor is of The textile thus pretreated is printed with an aqueous ink containing of the tincture I56 of this of Mergal K9N and water using a drip ink jet print head on demand The print is dried by It is fixed by means of saturated stream to 102 for 8 The print is then rinsed in is subjected to a hot water wash with hot water at 95 it is rinsed hot and then becomes insufficient OCRQuality

Claims

1. Chemical compound of the formula (I) and its mixtures wherein A is a diazo component radical as described below; and B is a radical of the middle component as described below; and K is a radical of the coupling component as described below; and a is an integer of 0 or 1; and with the general condition that the dyes of the general formula (I) contain at least one reactive anchor; and this invention relates to all types of tautomeric and geometric isomers of the dyes of the formula (I). A is a radical of the general formula (la) wherein each of R1 to R3, independently of each other, is hydrogen, halogen, alkyl, I-acylamino, alkoxy, thioalkoxy, hydroxy, cyano, nitro alkoxycarbonyl, alkoxythiocarbonyl acyl thioacyl, aryloyl trifluoromethyl, acyloxy, aryloyloxy, cycloalkyl, aryl, heteroaryl, heterocycloalkyl, N-cinnamoylamino, SO3M or COOM; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, N-trialkylammonium, N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium , N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, halogen, cyano, SO3M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, N-trialkylammonium, N, N, N -triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl , heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is SO2-X, where X is vinyl or a radical -CH2CH2-Y and Y is a removable group under alkaline conditions such as OSO3M, SSO3M, OCOCH3, OPO3M or halogen; or is a group of the general formula (2a), (2b) or (2c) wherein each of R 4 and R 7, independently of each other, is hydrogen, halogen, alkyl, N-acylamino, alkoxy, thioalkoxy, hydroxy, cyano, alkoxycarbonyl, alkoxythiocarbonyl, acyl, thioacyl, aryloyl, trifluoromethyl, acyloxy, aryloyloxy, cycloalkyl, aryl, heteroaryl, heterocycloalkyl, S03M or COOM; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N-acylamino, halogen, cyano, SO3M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl , heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy or aryloyloxy; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N-acylamino, halogen, cyano, SO3M, COOM, nitro acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy or aryloyloxy; and each of R5, R6, R8 and R12, independently of each other, is hydrogen, alkyl or aryl; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N-acylamino, halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl , heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy or aryloyloxy; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N-acylamino, halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy or aryloyloxy; and each of R9 to R11, independently of each other, is hydrogen, halogen, alkyl, alkoxy or SO3M; and b is an integer from 0 to 6; and c is an integer from 1 to 6; and when each of b and c, independently of each other, is > 2, R4 and R7 can have different meanings within the same remainder according to the previously defined meaning; and d is 0 or 1; and RG is a reactive anchor of the general formula (3a), (3b) or (3a) 3b (3c) wherein each of R14 to R19 independently of each other is halogen; and R14 may additionally be a residue of the formula (8a) (8a) wherein R96 is hydrogen, halogen, alkyl, alkoxy, thioalkoxy, hydroxy, cycloalkyl, aryl, heteroaryl, heterocycloalkyl, S03M or COOM; or is alkyl substituted with one or more substituents selected from the group which consists of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N-acylamino, halogen, cyano, S03, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy or aryloyloxy; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N-acylamino, halogen, cyano, S03M, COOM, nitro , acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy or aryloyloxy; and R13 is one of the selected groups of the general formula (4a) or (4b); (4a) (4b) wherein each of R20, R23 and R94, independently of each other, is hydrogen, alkyl, cycloalkyl or aryl; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N-acylamino, halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl , heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy or aryloyloxy; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more selected substituents of the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N-acylamino, halogen, cyano, SO3M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy or aryloyloxy; and each of R21, R22 and R95, independently of each other, is hydrogen, halogen, alkyl, N-acylamino, alkoxy, thioalkoxy, hydroxy, cyano, alkoxycarbonyl, alkoxythiocarbonyl, acyl, thioacyl, aryloyl, sulfamoyl, trifluoromethyl, acyloxy , aryloyloxy, cycloalkyl, aryl, heteroaryl, heterocycloalkyl, S03M or COOM; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N-acylamino, halogen, cyano, SO3M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl , heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy or aryloyloxy; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N-acylamino, halogen, cyano, S03M, COOM, nitro , acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy or aryloyloxy; and R94 may additionally be -CH2CH2-S02-X, where X is vinyl or a radical -CH2CH2-Y, where Y is a removable group under alkaline conditions such as OSO3M, SSO3M, OCOCH3, OPO3M or halogen; and R95 may additionally be -S02-X where X is as defined above. B is a radical of the general formula (5a) - (5a) wherein each of R24 to R26, independently of each other, is hydrogen, halogen, alkyl, N-acylamino, alkoxy, thioalkoxy, hydroxy, cyano, nitro, alkoxycarbonyl, alkoxythiocarbonyl, acyl, thioacyl, aryloyl, trifluoromethyl, acyloxy, aryloyloxy, cycloalkyl, aryl, heteroaryl, heterocycloalkyl, N-cinnamoylamino, S03M or COOM; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, N-trialkylammonium, N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium , N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, halogen, cyano, SO3M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, -trialkylammonium, N, N, N- triarylammonium, N, -dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, halogen, cyano, SO3M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl , heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is SO2-X, where X is vinyl or a radical -CH2CH2- and Y is a removable group under alkaline conditions such as 0S03M, SSO3M, OCOCH3, OPO3M or halogen; or is a group of the general formula (2a) or (2b) where R4 to R8, b c and RG are as defined above. K is a radical of the general formula (6a) or (6b) where D is a radical of the general formula (la) as previously defined; and each of R27 to R29, independently of each other, is hydrogen, halogen, alkyl, N-acylamino, alkoxy, thioalkoxy, hydroxy, cyano, nitro, alkoxycarbonyl, alkoxythiocarbonyl, ureido, alkylureido, phenylureido, sulfamoyl, acyl, thioacyl , aryloyl, trifluoromethyl, acyloxy, aryloyloxy, carbamoyl, cycloalkyl, aryl, heteroaryl, heterocycloalkyl, N-cinnamoylamino, S03M or COOM; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, N-trialkylammonium, N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-Alkylsulfonyl-amino, ureido, alkylureido, phenylureido, halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl- carbamoyl, N-monoalkyl carbamoyl, N, N-dicycloalkyl carbamoyl, N, N-dialkyl carbamoyl, N-monoaryl carbamoyl, N, N-diaryl carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl- N-monoarylcarbamoyl, sulfamoyl, N-monocycloalkyl-sulphamoyl, N-monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N-dialkylsulphamoyl, N-monoaryl-sulphamoyl, N, N-diaryl-sulfamyl, N-monocycloalkyl-N-monoarylsulfamollo or N-monoalkyl-N-monoarylsulfamoyl; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, N-trialkylammonium, N, N, N -triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, ureido, alkylureido, phenylureido, halogen, cyano, S03M, COOM , nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl-carbamoyl, N, N-dicycloalkyl-carbamoyl, N, N -dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl-carbamoyl, sulfamoyl, N-monocycloalkyl- sulphonyl, N-monoalkyl sulfamollo, N, N-dicycloalkyl sulfamoyl, N, N-dialkyl sulfamollo, N-monoaryl sulphamoyl, N, N-diaryl sulfamollo, N-monocycloalkyl-N-monoarylsulfamollo or N-monoalkyl- N-monoarylsulphamoyl; and each of R30, R31, R73 and R74, independently of each other, is hydrogen, alkyl, acyl, thioacyl, aryloyl, cycloalkyl, aryl, heteroaryl, heterocycloalkyl or cinnamoyl; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N -aryl-amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-N-monocycloalkylamino, N-monoaryl-N-monocycloalkylamino, N , N, N-trialkylammonium, N, N, N-triarylambenium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, ureido , alkylureide, phenylureide, halogen, cyano, SO3M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl-carbamoyl , N, N-dicycloalkyl-carbamoyl, N, -dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl-carba moyl, sulfamoyl, N-monocycloalkyl-sulfamoyl, N-monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N-dialkylsulfamoyl, N-monoaryl-sulphamoyl, N, N-diarylsulfonyl, N-monocycloalkyl- N-monoarylsulfamollo or N-monoalkyl-N-monoarylsulphamoyl; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more selected substituents from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N-diarylamino, N-alkyl-N -aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-N-monocycloalkylamino, N-monoaryl-N-monocycloalkylamino, N, N, N-trialkylammonium, N, N , N-triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, ureido, alkylureido, phenylureido, halogen, cyano, SO3M , COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl-carbamoyl, N, N-dicycloalkyl-carbamoyl, N , N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl-carbamoyl, sulfamoyl, N-monocycloalkylsulfamoyl, N-monoalkyl -his lfamollo, N, N-dicycloalkyl sulfaoyl, N, N-dialkyl sulfamollo, N-monoaryl sulphamoyl, N, N-diarylsulphamoyl, N-monocycloalkyl-N-monoarylsulfamollo or N-monoalkyl-N-monoarylsulphamoyl; or is a reactive anchor RG, where RG is as previously defined; or is a remainder of the general formula (7a) (7a) where RG is as previously defined; and R32 is hydrogen, halogen, alkyl, N-acylamino, alkoxy, thioalkoxy, hydroxy, cyano, alkoxycarbonyl, alkoxythiocarbonyl acyl thioacyl, aryloyl trifluoromethyl, acyloxy, aryloyloxy, cycloalkyl, aryl heteroaryl, heterocycloalkyl, SO3M or COOM; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N-acylamino, halogen, cyano, SO3M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl , heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy or aryloyloxy; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N-acylamino, halogen, cyano, S03M, COOM, nitro , acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy or aryloyloxy and R33 is hydrogen, alkyl or aryl; or is substituted alkyl-with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N-acylamino, halogen, cyano, SO3M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy or aryloyloxy or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N- acylamino, halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy or aryloyloxy; and e is an integer from 1 to 6; and when e is > 2, R32 can have different meanings within the same remainder, according to the previously defined meaning.

2. Chemical compound according to claim 1 having the formula (la): wherein each of R34 to R36, independently of each other, is hydrogen, halogen, alkyl, N-acylamino, alkoxy, thioalkoxy, hydroxy, cyano, nitro, alkoxycarbonyl, alkoxythiocarbonyl, acyl, thioacyl, aryloyl, trifluoromethyl, acyloxy, aryloyloxy , cycloalkyl, aryl heteroaryl, heterocycloalkyl, N-cinnamoylamino, SO3M or COOM; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, N-trialkylammonium, N, N, N-triarylammonium, N, N-dialkyl-N- monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more selected substituents of the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, N-trialkylammonium, N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium , N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, halogen, cyano, SO3M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is S02-X, where X is vinyl or a radical -CH2CH2-Y and Y is a removable group under alkaline conditions such as OSO3M, SSO.3M, OCOCH3, OPO3M or halogen; or is a group of the general formula (2a), (2b) or (2c) as defined in claim 1; and each of R37 and R38, independently of each other, is hydrogen, alkyl, acyl, thioacyl, aryloyl, cycloalkyl, aryl, heteroaryl, heterocycloalkyl or cinnamoyl; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N -aryl-amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-N-monocycloalkylamino, N-monoaryl-N-monocycloalkylamino, N , N, N-trialkylammonium, N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, ureido , alkylureide, phenylureide, halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl-carbamoyl , N, N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N- monoalkylcarbamoyl, N-monoalkyl-N-monoaryl-carbamoyl, sulfamollo, N-monocycloalkyl-sulphamoyl, N-monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N-dialkylsulfamoyl, N-monoaryl-sulphamoyl, N, N-diarylsulfamoyl, N-monocycloalkyl-N-monoarylsulfamollo or N-monoalkyl-N-monoarylsulfamollo; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkyl -amino, N-monoaryl-amino, N, N-diaryl-amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-N-monocycloalkylamino N-monoaryl-N-monocycloalkylamino, N, N, N-trialkylammonium N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N -cinnamoylamino, N-alkylsulfonyl-amino, ureido, alkylureido, phenylureido halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N- monocycloalkyl-carbamoyl, N-monoalkyl-carbamoyl, N, N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl carbamoyl, sulphaoyl, N-monocycloalkylsulfamoyl, N-monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N-dialkylsulfamoyl, N- monoaryl-sulphamoyl, N, N-diarylsulphuryl, N-monocycloalkyl-N-monoarylsulphamoyl or N-monoalkyl-N-monoarylsulphamoyl; or is a reactive anchor RG, where RG is as defined in claim 1; or is a remainder of the general formula (7a) as defined in claim 1.

3. Chemical compound according to claim 1 having the formula (Ib): wherein each of R 39 to R 44 independently of each other is hydrogen, halogen, alkyl, N-acylamino, alkoxy, thioalkoxy, hydroxy, cyano, nitro, alkoxycarbonyl, alkoxythiocarbonyl, acyl, thioacyl, aryloyl, trifluoromethyl, acyloxy , aryloyloxy, cycloalkyl, aryl, heteroaryl, heterocycloalkyl, N-cinnamoylamino, S03M or COOM; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, N-trialkylammonium, N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium , N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, halogen, · cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, N-trialkylammonium, N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N- alkylsulfonyl-amino, halogen, cyano, SO 3 M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is SO2-X, where X is vinyl or a radical -CH2CH2-Y and Y is a removable group under alkaline conditions such as OSO3M, SSO3M, OCOCH3, OPO3M or halogen; or is a group of the general formula (2a) or (2b) as defined in claim 1; and each of R39 to R41, independently of each other, may additionally be a group of the general formula (2c) as defined in claim 1; and each of R 45 and R 46, independently of each other, is hydrogen, alkyl, acyl, thioacyl, aryloyl, cycloalkyl, aryl, heteroaryl, heterocycloalkyl or cinnamoyl; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N -aryl-amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-N-monocycloalkylamino, N-monoaryl-N-monocycloalkylamino, N , N, N-trialkylammonium, N, N, N-triaryl, N, N-dialkyl-N-monoarilamonio, N, N-diaryl-N-monoalkyl, N-acylamino, N-cinnamoilamino, N-alkylsulphonyl-amino, ureido , alkylureide, phenylureide, halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl-carbamoyl , N, N-dicycloalkyl- carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-oyl carba, N, N-diaryl-carbamoyl, N-monocyclo--N-monoarilcarbamoílo, N-monoalkyl-N-monoarilcarbamoílo, sulfamoyl, N-monocyclo--sulfamoyl , N-monoalkyl-sulfamoyl, N, N-diC-sulfamoyl, N, N-dialkyl-sulfamoyl, N-monoaryl-sulfamoyl, N, N-diaryl-sulfamoyl, N-monocyclo--N-monoarilsulfamo! I or N-monoalkyl -N-monoarylsulfamollo; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkyl -amino, N-monoaryl-amino, N, N-diaryl-amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-N-monocycloalkylamino N-monoaryl-N-monocycloalkylamino, N, N, N-trialkylammonium N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N -cinnamoilamino, N-alkylsulphonyl-amino, ureido, alkylureido, phenylureido halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N- monocycloalkyl-carbamoyl, N-monoalkyl-carbamoyl, N, N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, -aryl-carbamoyl or, N-monocyclo--N-monoarilcarbamoílo, N-monoalkyl-N-monoarilcarbamoílo, sulfamoyl, N-monocyclo--sulfamoyl, N-monoalkyl sulfamollo, N, N-diC-sulfamoyl, N, N-dialkyl sulfamoyl, N-monoaryl-sulphamoyl, N, N-diaryl-sulfamollo, N-monocycloalkyl-N-monoarylsulfamollo or N-monoalkyl-N-monoarylsulfamollo; or is a reactive anchor RG, where RG is as defined in claim 1; or is a rest of the general formula (7a) as defined in claim 1.

4. Chemical compound according to claim 1 having the formula (Ic): where j is 0 or 1; and each of R47 to R49 independently of each other, is hydrogen, halogen, alkyl, N-acylamino, alkoxy, thioalkoxy, hydroxy, cyano, nitro, alkoxycarbonyl, alkoxythiocarbonyl, acyl, thioacyl, aryloyl, trifluoromethyl, acyloxy, aryloyloxy , cycloalkyl, aryl, heteroaryl, heterocycloalkyl, N-cinnamoylamino, S03M or COOM; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N,, N-trialkylammonium, N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, N-trialkylammonium, N, N, N -triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, halogen, cyano, S03M, COOM, nitro, acyl, thioacyl , alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is SO2-X, where X is vinyl or a radical ^ CH2CH2-Y and Y is a removable group under alkaline conditions such as OSO3M, SSO3M, OCOCH3, OPO3M or halogen; or is a group of the general formula (2a), (2b) or (2c) as defined in claim 1; and each of R50 and R51, independently of each other, is hydrogen, alkyl, acyl, thioacyl, aryloyl, cycloalkyl, aryl, heteroaryl, heterocycloalkyl or cinnamoyl; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N -aryl-amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-N-monocycloalkylamino, N-monoaryl-N-monocycloalkylamino, N , N, N-trialkylammonium, N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, ureido , alkylureide, phenylureide, halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monoalkyloalkanoyl, N-monoalkyl-carbamoyl, N, N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl-carbamoyl, sulfamoyl, N-monocycloalkyl-sulfamollo, N-monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N-dialkylsulfamoyl, N- monoaryl sulfamollo, N, N-diaryl sulfamollo, N-monocycloalkyl-N-monoarylsulphamoyl or N-monoalkyl-N-monoarylsulfamyl; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkyl -amino, N-monoaryl-amino, N, N-diaryl-amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino,, N-dicycloalkylamino, N-monoalkyl-N-monocycloalkylamino N -monoaryl-N-monocycloalkyl-amino, N, N, N-trialkylammonium N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N- cinnamoylamino, N-alkylsulfonyl-amino, ureido, alkylureido, phenylureido halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl -carbamoyl-, N-monoalkyl carbamoyl, N, N-dicycloalkyl carbamoyl, N, N-dialkyl carbamoyl, N-monoaryl carbamoyl, N, N-diaryl- carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl-carbamoyl, sulfamoyl, N-monocycloalkylsulfamoyl, N-monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N-dialkylsulfamoyl, N-monoaryl-sulphamoyl, N, N-diaryl-sulfamollo, N-monocycloalkyl-N-monoarylsulphamoyl or N-monoalkyl-N- monoarylsulfamollo; or is a reactive anchor RG, where RG is as defined in claim 1; or is a remainder of the general formula (7a) as defined in claim 1.

5. Chemical compound according to claim 1 having the formula (Id): where n is 0 or 1; and each of R52 to R57, independently of each other, is hydrogen, halogen, alkyl, N-acylamino, alkoxy, thioalkoxy, hydroxy, cyano, nitro, alkoxycarbonyl, alkoxythiocarbonyl, acyl, thioacyl, aryloyl, trifluoromethyl, acyloxy, aryloyloxy , cycloalkyl, aryl, heteroaryl, heterocycloalkyl, N-cinnamoylamino, SO3M or COOM; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, N-trialkylammonium, N, N, N-triarylammonium, N, N-dialkyl-N- monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, aalqquuiillssuullffoonnyloyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, N-trialkylammonium, N, N, N -triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, halogen, cyano, SO3M, COOM, nitro, acyl, thioacyl , alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is S02-X, where X is vinyl or a radical -CH2CH2-Y and Y is a removable group under alkaline conditions such as OSO3M, SS03, OCOCH3, OPO3M or halogen; or is a group of the general formula (2a) or (2b) as defined in claim 1; and each of R52 to R54, independently of each other, may additionally be a group of the general formula (2c) as defined in claim 1; and each of R58 and R59, independently of each other, is hydrogen, alkyl, acyl, thioacyl, aryloyl, cycloalkyl, aryl, heteroaryl, heterocycloalkyl or cinnamoyl; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N -aryl-amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-N-monocycloalkylamino, N-monoaryl-N-monocycloalkylamino, N , N, N-trialkylammonium, N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N- acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, ureido, alkylureido, phenylureido, halogeno, cyano, SO3M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl-carbamoyl, N, N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N- mono-arylcarbamoyl, N-monoalkyl-N-monoaryl-carbamoyl, sulfamoyl, N-monocycloalkyl-sulphamoyl, N-monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N-dialkylsulfamoyl, N-monoaryl-sulphamoyl, N, N-diaryl sulfamollo, N-monocycloalkyl-N-monoarylsulfamollo or N-monoalkyl-N-monoarylsulfamollo; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkyl -amino, N-monoaryl-amino, N, N-diaryl-amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-N-monocycloalkylamino , N-monoaryl-N-monocycloalkylamino, N, N, N-trialkylammonium, N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino , N-cinnamoylamino, N-alkylsulfonyl-amino, ureido, alkylureido, phenylureido, halogeno, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl , N-monocycloalkyl carba oyl, N-monoalkyl carbamoyl, N, N-dicycloalkyl carbamoyl, N, N-dialkyl carbamoyl, N-monoarylcarba oyl, N, N-diaryl- carbamoyl, N-monocycloalkyl-N- monocarilcarbamoyl, N-monoalkyl-N-monoaryl-carbamoyl, sulphamoyl, N-monocycloalkyl-sulphamoyl, N-monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N-dialkylsulfamoyl, N-monoaryl-sulphamoyl, N, N-diarylsulfamoyl, N-monocycloalkyl-N-monoarylsulphamoyl or N-monoalkyl-N-monoarylsulfamollo; or is a reactive anchor RG, where RG is as defined in claim 1; or is a remainder of the general formula (7a) as defined in claim 1.

6. Chemical compound according to claim 1 having the formula (le): wherein each of R60, R61 and R62, independently of one another, is hydrogen, halogen, alkoyl, N-acylamino, alkoxy, thioalkoxy, hydroxy, cyano, nitro, alkoxycarbonyl, alkoxythiocarbonyl, acyl, thioacyl, aryloyl, trifluoromethyl, acyloxy, aryloyloxy, cycloalkyl, aryl, heteroaryl, heterocycloalkyl, N-cinnamoylamino, S03M or COOM; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, N-trialkylammonium, N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium , N, N-diaryl-N-monoalkylammonium, N- acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, halogen, cyano, SO3M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, N-trialkylammonium, N, N, N -triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, halogen, cyano, SO3M, COOM, nitro, acyl, thioacyl , alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is S02-X, where X is vinyl or a radical -CH2CH2-Y and Y is a removable group under alkaline conditions such as OSO3M, SSO3M, OCOCH3, OPO3M or halogen; or is a group of the general formula (2a), (2b) or (2c) as defined in claim 1; and each of R63 and R64, independently of each other, is hydrogen, alkyl, acyl, thioacyl, aryloyl, cycloalkyl, aryl, heteroaryl, heterocycloalkyl or cinnamoyl; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N -aryl-amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-N-monocycloalkylamino, N-monoaryl-N-monocycloalkylamino, N , N, N-trialkylammonium, N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, ureido , alkylureide, phenylureide, halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl carbamoyl, N-monoalkyl carbamoyl, N, N- dicycloalkyl carbamoyl, N, N-dialkyl carbamoyl, N-monoaryl carbamoyl, N, N-diaryl carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl carbamoyl, sulphamoyl, N-monocycloalkyl- sulfamoyl, N-monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N-dialkylsulfamoyl, N-monoaryl sulfamollo, N, N-diarylsulfamollo, N-monocycloalkyl-N-monoarylsulfamollo or N-monoalkyl- N-monoarylsulfame; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkyl -amino, N-monoaryl-amino, N, N-diaryl-amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, li-dieycloalkylamino, N-monoalkyl-N-monocycloalkyl-amino N -monoaryl-N-monocycloalkylamino, N, N, N-trialkylammonium N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N- cinnamoylamino, N-alkylsulfonyl-amino, ureido, alkylureido, phenylureido halogen, cyano, SO3M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl -carbamoyl, N-monoalkyl-carbamoyl, N, N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-car bamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl carbamoyl, sulphamoyl, N-monocycloalkyl-sulphamoyl, N-monoalkyl- sulfamoyl, N, N-dicycloalkyl sulfamollo, N, N-dialkyl sulfamoyl, N-monoaryl sulphamoyl, N, N-diaryl sulfamyl, N-monocycloalkyl-N-monoarylsulphamoyl or N-monoalkyl-N-monoarylsulphamoyl; or is a reactive anchor RG, where RG is as defined in claim 1; or is a remainder of the general formula (7a) as defined in claim 1.

7. Chemical compound according to claim 1 having the formula (If): wherein each of R65 to R70, independently of each other, is hydrogen, halogen, alkyl, N-acylamino, alkoxy, thioalkoxy, hydroxy, cyano, nitro, alkoxycarbonyl, alkoxythiocarbonyl, acyl, thioacyl, aryloyl, trifluoromethyl, acyloxy, aryloyloxy, cycloalkyl, aryl, heteroaryl, heterocycloalkyl, N-cinnamoylamino, S03M or COOM; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, N-trialkylammonium, N, N, N-triarylammonium, N, N-dialkyl-N-onanoarylammonium , N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, N-trialkylammonium, N, N, N -triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl · -N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, halogen, cyano, SO3M, COO, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is S02-X, where X is vinyl or a radical -CH2CH2-Y and Y is a removable group under alkaline conditions such as OSO3M, SSO3M, OCOCH3, OPO3M or halogen; or is a group of the general formula (2a) or (2b) as defined in claim 1; and each of R65 to R67, independently of each other, may additionally be a group of the general formula (2c) as defined above; and each of R71 and R72, independently of each other, is hydrogen, alkyl, acyl, thioacyl, aryloyl, cycloalkyl, aryl, heteroaryl, heterocycloalkyl or cinnamoyl; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N -aryl-amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-N-monocycloalkylamino, N-monoaryl-N-monocycloalkylamino, N , N, N-trialkylammonium, N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N- alkylsulfonyl-amino, ureido, alkylureido, phenylureido, halogen, cyano, SO3M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl carbamoyl, N, N-dicycloalkyl carbamoyl, N, N-dialkyl carbamoyl, N-monoaryl carbamoyl, N, N-diaryl carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N- monoarylcarbamoyl, sulfamoyl, N-monocycloalkylsulfamoyl, N-monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N-dialkylsulfamoyl, N-monoaryl-sulphamoyl, N, N-diarylsulphamoyl, N -monocycloalkyl-N-monoarylsulphamoyl or N-monoalkyl-N-monoarylsulphamoyl; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkyl -amino, N-monoaryl-amino, N, N-diaryl-amino, N-alkyl-N-aryl-amino, N-monocycloalkylaminoN, Li diecycloalkylamino, N-monoalkyl-N-monocycloalkyl-amino N-monoaryl-N-monocycloalkylamino, N, N, N-trialkylammonium N, N, N-triarylammonium, N, N-dialkyl-N- monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, ureido, alkylureido, phenylureido halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl , heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl-carbamoyl, N, N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N , N-diaryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl-carbamoyl, sulfamoyl, N-monocyclo--sulfamoyl, N-monoalkyl-sulfamoyl, N, N-diC-sulfamollo, N, N-dialkyl-sulfamoyl, N-monoaryl-sulfamoyl, N, N-diaryl-sulfamollo, N-monocyclo--N- monoarylsulphamoyl or N-monoalkyl-N-monoarylsulphamoyl; or is a reactive anchor RG, where RG is as defined in claim 1; or is a remainder of the general formula (7a) as defined in claim 1.

8. Chemical compound according to claim 1 having the formula (Ig): wherein each of R75 to R80 independently of one another, is hydrogen, halogen, alkyl, N-acylamino, alkoxy, thioalkoxy, hydroxy, cyano, nitro, alkoxycarbonyl, alkoxythiocarbonyl, acyl, thioacyl, aryloyl, trifluoromethyl, acyloxy, aryloyloxy , cycloalkyl, aryl, heteroaryl, heterocycloalkyl, N-cinnamoylamino, SO3M or COOM; or • is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, N- trialkylammonium, N, N, N-triaryl, N, N-dialkyl-N-monoarilamonio, N, N-diaryl-N-monoalkyl, N-acylamino, N-cinnamoilamino, N-alkylsulphonyl-amino, halogen, .ciano, SO3M , COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, N-trialkylammonium, N, N, N -triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, halogen, cyano, S03M, COOM, nitro, acyl, thioacyl , alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is SO2-X, where X is vinyl or a radical -CH2CH2-Y and Y is a removable group under alkaline conditions such as OSO3M, SSO3M, OCOCH3, OPO3M or halogen; or is a group of the general formula (2a), (2b) or (2c) as defined in claim 1; and each of R81 and R82, independently of each other, is hydrogen, alkyl, acyl, thioacyl, aryloyl, cycloalkyl, aryl, heteroaryl, heterocycloalkyl or cinnamoyl; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N -aryl-amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-N-monocycloalkylamino, N-monoaryl-N-monocycloalkylamino, N , N, N-trialkylammonium, N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl- N-monoalkyl, N-acylamino, N-cinnamoilamino, N-alkylsulphonyl-amino, ureido, alquilureldo, phenylureido, halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocyclo--carbamoyl, N-monoalkyl carbamoyl, N, N-diC-carbamoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocyclo--N-monoarilcarbamoílo, N-monoalkyl-N-monoarilcarbamoílo, sulfamoyl, N-monocyclo--sulfamoyl, N-monoalkyl-sulfamoyl, N, N-diC-sulfamoyl, N, N-dialkyl-sulfamoyl ·, N -monoaryl-sulfamoyl, N, N-diaryl-sulfamollo, N-monocycloalkyl-N-monoarylsulphamoyl or N-monoalkyl-N-monoarylsulphamoyl; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkyl -amino, N-monoaryl-amino, N, N-diaryl-amino, N-alkyl-N-aryl-amino, N-monocycloalkylamino, N, N-dicycloalkylamino, N-monoalkyl-N-monoalkylalkyl-amino N-monoaryl-N-monocycloalkylamino, N, N, N-trialkylammonium N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, ureido, alkylureido, phenylureido halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl-carbamoyl , N, N-dicycloalkyl-carbamoyl, N, -dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N-monocycloalkyl-N- mono-arylcarbamoyl, N-monoalkyl-N-monoaryl-carbamoyl, sulfamoyl, N-monocycloalkyl-sulphamoyl, N-monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N-dialkylsulfamoyl, N-monoaryl-sulphamoyl, N, N-diarylsulfamoyl, N-monocycloalkyl-N-monoarylsulphamoyl or N-monoalkyl-N-monoarylsulphamoyl; or is a reactive anchor RG, where RG is as defined in claim 1; or is a remainder of the general formula (7a) as defined in claim 1.

9. Chemical compound according to claim 1 formula (Ih): i wherein each of R83 to R91, independently of each other, is hydrogen, halogen, alkyl, N-acylamino, alkoxy, thioalkoxy, hydroxy, cyano, nitro, alkoxycarbonyl, alkoxythiocarbonyl, acyl, thioacyl, aryloyl, trifluoromethyl, acyloxy, aryloyloxy, cycloalkyl, aryl, heteroaryl, heterocycloalkyl, N-cinnamoylamino, S03M or COOM; or it is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, N-trialkylammonium, N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, halogen, cyano, SO 3 M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, N, N, -trialkylammonium, N, N, N- triarylammonium, N, N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, halogen, cyano, SO3M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy; or is S02-X, where X is vinyl or a radical -CH2CH2-Y and Y is a removable group under alkaline conditions such as OSO3M, SSO3M, OCOCH3, OPO3M or halogen; or is a group of the general formula (2a) or (2b) as defined in claim 1; and each of R83, R84, R85, R89, R90 and R91, independently of each other, may additionally be a group of the general formula (2c) as defined in claim 1; and each of R92 and R93, independently of each other, is hydrogen, alkyl, acyl, thioacyl, aryloyl, cycloalkyl, aryl, heteroaryl, heterocycloalkyl or cinnamoyl; or is alkyl substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N -aryl-amino, N-alkyl-N-aryl-amino, N-monocycloalkyl-amino, N, N-dicycloalkylamino, N-monoalkyl-N-monocycloalkylamino, N-monoaryl-N-monocycloalkylamino,, N, N-trialkylammonium, N, N, N-triarylammonium, N , N-dialkyl-N-monoarylammonium, N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, ureido, alkylureido, phenylureido, halogen, cyano, SO3M, COOM, nitro, acyl , thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl-carbamoyl, N, N-dicycloalkyl-carbamoyl, N, N-dialkyl-carbamoyl , N-monoaryl-carbamoyl, N, -aryl-carbamoyl, N-monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl-carbamoyl, sulfamoyl, N-monocycloalkylsulfamoyl, N-monoalkylsulfamoyl, N, N- dicycloalkylsulfamoyl, N, N-dialkylsulfamoyl, N-monoarylsulfamoyl, N, N-diarylsulphamoyl, N-monocycloalkyl-N-monoarylsulphamoyl or N-monoalkyl-N-monoarylsulfa mole or is alkyl interrupted by one or more heteroatoms such as oxygen or sulfur and substituted with one or more substituents selected from the group consisting of hydroxy, aryl, cycloalkyl, alkoxy, thioalkoxy, amino, N-monoalkylamino, N, N-dialkylamino, N-monoarylamino, N, N-diarylamino, N-alkyl-N-arylamino, N-monocycloalkylamino, N , N-dithylalkyl-amino, N-monoalkyl-N-monocycloalkyl-amino N-monoaryl-N-monocycloalkylamino, N, N, N-trialkylammonium N, N, N-triarylammonium, N, N-dialkyl-N-monoarylammonium , N, N-diaryl-N-monoalkylammonium, N-acylamino, N-cinnamoylamino, N-alkylsulfonyl-amino, ureido, alkylureido, phenylureido halogen, cyano, S03M, COOM, nitro, acyl, thioacyl, alkylsulfonyl, aryloyl, trifluoromethyl, heteroaryl, heterocycloalkyl, alkoxycarbonyl, alkoxythiocarbonyl, acyloxy, aryloyloxy, carbamoyl, N-monocycloalkyl-carbamoyl, N-monoalkyl-carbamoyl, N, N-dicycloalkyl-carbaraoyl, N, N-dialkyl-carbamoyl, N-monoaryl-carbamoyl, N, N-diaryl-carbamoyl, N- monocycloalkyl-N-monoarylcarbamoyl, N-monoalkyl-N-monoaryl-carbamoyl, sulfaraoyl, N-monocycloalkyl-sulfamoyl, N-monoalkylsulfamoyl, N, N-dicycloalkylsulfamoyl, N, N-dialkylsulfamoyl, N-monoaryl- sulfamoyl, N, N-diarylsulphamoyl, N-monocycloalkyl-N-monoarylsulfamollo or N-monoalkyl-N-monoarylsulphamoyl; or is a reactive anchor RG, where RG is as defined in claim 1; or is a remainder of the general formula (7a) as defined in claim 1.

10. Chemical composition consisting of two or more chemical compounds according to any of claims 1 to 9.

11. Chemical composition comprising one or more chemical compounds according to any of claims 1 to 9.

12. Aqueous solution for staining comprising one or more chemical compounds according to any of claims 1 to 9.

13. Process for producing chemical compounds according to claim 1 comprising the steps: a) diazotization of compounds of the formula (II), B) reaction of the diazonium salts obtained in step a) with a compound of the formula K to obtain an intermediate of the formula (III) c) diazotization of the component (A-NH2), cxl) optionally coupling the diazotized product of step c) with the compound (B-NH2) and cx2) diazotization of the coupling product of step cxl) d) coupling of the diazotized product from step c) with intermediate III to obtain the bisazo product of general formula (IV) in the case of step c) or coupling of the diazotized coupling product of cx2) with intermediate III to obtain the trisazo product of the general formula (VI), I

14. Use of a chemical compound according to any of claims 1 to 9, a chemical composition according to claim 10 or 11 or an aqueous solution according to claim 12 for dyeing fibers, as well as mixtures of such fibers selected from the group consisting of: vegetable fibers, seed fibers, cotton, organic cotton, kapok, coconut fiber from coconut shell; bast fibers, flax, hemp, jute, kenaf, ramie, rattan; leaf fibers, sisal, henequen, banana; stalk fibers, bamboo; fibers from animals, wool, organic wool, silk, cashmere wool, alpaca fiber, mohair, Angora fiber, as well as leather and leather materials; fibers manufactured, regenerated and recied, cellulose fibers; paper fibers, cellulosic regenerated fibers, viscose rayon fibers, acetate and triacetate fibers and fibers of.Lyocell; and synthetic fibrous materials, nylon, nylon-6, nylon-6,6 materials and aramid fibers.

15. Fiber and mixtures containing such fiber selected from the group consisting of: vegetable fibers, seed fibers, cotton, organic cotton, kapok, coconut fiber from coconut husk; bast fibers, flax, hemp, jute, kenaf, ramie, rattan; leaf fibers, sisal, henequen, banana; stalk fibers, bamboo; fibers from animals, wool, organic wool, silk, cashmere wool, alpaca fiber, mohair, Angora fiber, as well as leather and leather materials; fibers manufactured, regenerated and recied, cellulose fibers; paper fibers, regenerated cellulose fibers, viscose rayon fibers, acetate and triacetate fibers and Lyocell fibers; and synthetic fibrous materials, nylon, nylon-6, nylon-6,6 materials and aramid fibers comprising one or more chemical compounds according to any of claims 1 to 9 either in a chemical and / or physically bound form.